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HomeMy WebLinkAbout1964 KELLOGG AVE; ; CB044097; PermitCity,.of Carlsbad 1635 Faraday Av Carlsbad, CA 92008 Commercial/Industrial Permit Permit No: CB044097 Building Inspection Request Line (760) 602-2725 Job Address: Permit Type: Parcel No: 1964 KELLOGG AV CBAD Tl Sub Type: Lot#: Status: Valuation: 2120930200 $155,000.00 Construction Type: COMM 0 NEW Applied: Occupancy Group: Project Title: Reference #: •GIA 5000 SF Tl FROM O_FFICE/ WAREHOUSE TO SAM!= Entered By: Plan Approved: Issued: Applicant: TOM COSTELLO 5345 ARMADA DR 92008 603-4032 Building Permit Ac;ld'I Building Permit Fee Plan Check Add'I Plan Check Fee . Plan Check Discount Strong Motion Fee Park Fee LFM Fee Bridge Fee BTD #2 Fee BTD #3Fee Renewal Fee Add'I Renewal Fee Other Building Fee Pot. Water Con. Fee Meter Size Add'I Pot. Water Con. Fee Reel. Water Con. Fee Inspect Area: Plan Check#: Owner: JORKEN L LC 1964 KELLOGG AVE CARLSBAD CA 92008 $71.5.96 Meter Size $0.00 Add'I Red. Water Con. Fee $465.37 Meter Fee $0.00 SDCWAF-ee $0.oo CFO Payoff Fee $32.55 · PFF $0:00 PFF (CFO Fund) $0.00 · Licen·se Tax· $0.00 _License Tax (CFO Fund) $0·.oo · Traffic Impact Fee $.0.00 _ ' traffic. Impact (CFO Fund) , $0.00 PLUMBING T-OTAL 1 $0.oo a.ECTRICAL TOTAL.. $0.00 MECHANICAL TOTAL $0.0Q Master Drainage Fee SewerFee $0.00 ~edei;, Parking Fee $0.0Q . Additional Fees ISSUED 11/09/2004 SB 12/20/2004 12/20/2004 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $160.00 $21.50 $0.00 $0.00 $0.00 $0.00 'i '· , '' TOtAL PERMIT FEES $1,395.38 Total Fees: $1,395.38 Total Payments Tb Date: $465.37 BatarmJ)'1.f!Y20/04 00§~38.1~1 02 ~ANS LIN STORAGE ATTACHED -:;-~r-~ Inspector: EX~JIREO PERMIT GDP 7i' ts: z. -PERMff HAS EXPIRED IN J,CCORDANCE Wilt! C.B.C. SECTION 100.4.4 AS AMENDf:D BY C.M.C.18.04.030 DATE~ SIGNATURE-tkJ.i:=~---- FINAL APPROVAL Date: Clearance: NOTICE: Please take NOTICE that approval of your project includes the "Imposition" of fees, dedications, reservations, or other exactions hereafter collectively referred to as "fees/exactions.' Y O\J have 90 day~ from the date this permit was issued to protest imposition of these fees/exactions. If you protest them, you must followthe protest procedures set forth in Government Code Section 66020(a), and file the protest and any other required information with the City Manager for processing in accordance with Carlsbad Municipc1I Code Section 3.32.030. Failure to timely follow that procedure will bar any subsequent legal action to attack, review, set a~ide, void_, or annul their imposition. You are hereby FURTHER NOTIFIED that your right to protest the specified fees/exactions DOES NOT APPLY to water and sewer connection fees and capacity changes, nor planning, zoning, grading or other similar application processing or service fees in connection with this project NOR DOES IT APPLY to any fees/exactions of which vou have orevfouslv been aiven a NOTICE similar to this or as to which the statute of limitations has oreviouslv otherwise exoired, 930-01 .& !!ti. CITY OF CARLSBAD BUILDING DEPARTMENT 1635 Faraday Ave., Carlsbad, CA 92008 FOR OFFICE USE O~ PLAN CHECK NO. L.-,j::o l/ l/ O 17 EST. VAL. --'=5"::;_!;;=-..,_C)O....:;-:;t).-:-::=--= 4,6Sf,37 Lot No. Subdivision Name/Number· 3o <81-4,~ Assessor's Parcel # . · 2.1 z... -b9.b -c:,-z.. Existing Use &\-._. Plan Ck. Deposit VaUdated Bvtft Date I ?f i 11/09/04 0002 01 Unit No. 2. Proposed Use -~ QAY--< ~ # of Bedrooms # of Bathrooms -tr';;;::t:~?;: ::~&£:ff.?::;;.: ·:-~_:7c:::~I"'.?::-i1·~1~· · (Sec. 7031.5 Business and Professions Code: Any .City or County which requires a permit to construct, alter, improve, demolish or repair any structure, prior to its issuance, also requires the applicant for such permit to file a signed statement that he is licensed pursuant to the provisions of the Contractor's License Law [Chapter 9, commending with Section 7000 of Division 3 of the Business and Professions Code] or that he is exempt therefrom, and the basis for the alleged exemption. Any violation of Section 7031.5 by any applicant for a permit subjects the applicant to a civil penalty of not more than five hundred dollars [$5001). Name Address City State/Zip Telephone# State License# _________ _ License Class _________ _ City Business License # _______ _ Designer Name Address City State/Zip Telephone State License# _________ _ !§;:>:\:,WJ)RKERST'coMPENSA;TIONc 7""': ....... '""',--~----. -_-_, .-,,~" .. · -.... ' , . '' · ·-~··: .. .. · .. :.,: .· .:;~-:;;:::.:;".T7;':;-:~7~.;2;;::z0,:::.·:;:r,;c~':"""-'"'.'ii7:~ .. ;· .z::::,0:r::--1:, Workers' Compensation Declaration: I hereby affirm under penalty of perjury one of the following declarations: D I have and will maintain a certificate of consent to-self-insure for workers' compensation as provided by Section 3700 of the Labor Code, for the performance of the work for which this permit is issued. D I have and will maintain workers' compensation, as required by Section 3700 of the Labor Code, for the performance of the work for which this permit is issued. My worker's compensation insurance carrier and policy number are: Insurance Company____________________ ·Policy No.____________ Expiration Date _______ _ (THIS SECTION NEED NOT BE COMPLETED IF THE PERMIT IS FOR ONE HUNDRED DOLLARS [$100] OR LESS) D CERTIFICATE OF EXEMPTION: I certify that in the performance of the work for which this permit is issued, I shall not employ any person in any manner so.as to become subject to the Workers' Compensation Laws of California. WARNING: Failure to secure workers' compensation coverage is unlawful, and shall subject an employer to criminal penalties and civil fines up to one hundred thousand dollars ($100,0001, in addition to the cost of compensation, damages as provided for in Section 3706 of the Labor code, interest and attorney's fees. SIGNATURE. ______________ -,--'--------------DATE _______ ~_ t%:'.:>s&wNeR~liu1iDeR;'o1:c1As'At10N:· · · .. · 2 :..,. '. ;. : ~. :· .. ,, : · :": -~·~c< ::·:·-·.~:,,·, :.>~.· . · ----~-..... cc ...... '/'~ I hereby affirm that I am exempt from the Contractor's License Law for the following reason: 0 I, as owner of the property or my employees with wages as their sole. compensation, will do the work and the structure is not intended or offered for sale (Sec, 7044, Business and Professions Code: The Contractor's License Law does not apply to an owner of property who builds or improves thereon, and who does such work himself or through his own employees, provided that such improvements.are not intended or offered for sale. If, however, the building or improvement is sold within one year of completion, the owner-builder will have the burden-of proving that he did not build or improve for the purpose of sale). 1i2f' I, as owner of the property, am exclusively contracting with licensed contractors to construct the project (Sec. 7044, Business and Professions Code: The /c;;ntractor' s License Law does not apply to an owner of property who builds or improves thereon, and contracts for such projects with contractor(s) licensed pursuant to the Contractor's License Law). D I am exempt under Section ______ Business and Professions Code for this reason: 1. I personally plan to provide the major labor and materials for construction of the proposed property improvement. D YES ONO 2. I (have / have not) signed an application for a building permit for the proposed work. 3. I have contracted.with the following person (firm) to provide the proposed construction (include m~me /address/ phone number/ contractors license number): 4. I plan to provide portions of the work, but I have hired the following person to coordinate, supervise and provide the major work (include name / address / phone number/ contractors license number): _____________________________________________ _ 5. I will provide some of the work, but I have contracted (hired) the following persons to provide the work indicated (include name/ address / phone number / type of work):~~=----=-:-:-------:::;::::~~~;;::~~&~~~;;;~;::.:_:_:_~-----------;-;---;;---:::;.~---------- f'ROPERTY OWNER SIGNATURE~-''-::--::-'-.,,....~~---:----:-------:----:----:----:----:-::-=---:-=--DATE// ~Cz ~~'{) r~Jrice.L.~1;lril1~~~£t1,Q'f.lJio1t@N.il'f-~tl[Eft ,~.tsSJ.1,P-.1N'~:p,e~..1v11rs."c;>t-f!-Y~-:,x::~ .. :-::; .. :-~·<:":TDJ:~,-,:1Ei;;sziz.:II.t:::2::.1:::::;:5:I~2:;::-:~t:;.:";:,':::·:' Is the applicant or future building occupant required to submit a business plan, acutely hazardous materials registration form or risk management and prevention program under Sections 25505, 25533 or 25534 of the Presley-Tanner Hazardous Substance Account Act? D YES D NO Is the applicant or future building occupant required to obtain a permit from the air pollution control district or air quality management district? D YES D NO Is the facility to be constructed within 1,000 feet of the outer boundary of a school-site? 0 YES D NO IF ANY OF THE ANSWERS ARE YES, A FINAL CERTIFICATE OF OCCUPANCY MAY NOT BE ISSUED UNLESS THE APPLICANT HAS MET OR IS MEETING THE REQUIREMENTS OF THE OFFICE OF EMERGENCY SERVICES AND THE AIR POLLUTION CONTROL DISTRICT. ifL~;;i:i:t.Q~~IJ..'~PJ:t.QN.i~.et,!!:5JN~t~ID:W'9Y.:::.;::;:0,::c0 .::.~· • .::.-:::_ ::_· __ ~--.. ,,;,,;·:..,,; • ,~ -::_ •• , ..• · ... , ... "·· I hereby affirm that there is a construction lending agency for the performance of the work for which this permit is issued (Sec. 3097(i) Civil Code). LENDER'S NAME LENDER'S ADDRESS -::;,-::.-~-:-----:_---~-------------------------}lt v~APPLICANji(CER1ilFICATiO~, -----t _:,,.,,. ~ ,-;;, ~-:~;~-=-~ 0,, -_; __ ~;.v,__._~--w::-~,:::-:~~ h·,::-J, · ~;; ,:-.:a:J::;,-~:~?§;:Li~/?:-:7.;.2:~-~·s,: --~~~\7~~:-I~;T:~:'.:Y~_::! ~-:~·=:{ r certify that !'have read the application and state that the above information is correct and that the information on the plans is accurate. I agree to comply with all City ordinances .ind State laws relating to building construction. I hereby authorize representatives of the Citt of Carlsbad to enter upon the above mentioned property for inspection purposes. I ALSO AGRl:E TO SAVE, INDEMNIFY AND KEEP HARMLESS THE CITY OF CARLSBAD AGAINST ALL LIABILITIES, JUDGMENTS, COSTS AND EXPENSES WHICH MAY IN ANY WAY ACCRUE AGAINST SAID CITY IN CONSEQUENCE OF THE GRANTING OF THIS PERMIT. OSHA: An OSHA permit is required for excavations over 5'0" deep and demolition or construction of structures over 3 stories in height. EXPIRATION: Every permit issued by the building Official under the provisions of this Code shall expire l:)y limitation and become null and void if the building or work authorized by such permit is not commenced within 180 days from the date of such permit or if the building or work authorized by such permit is suspended or abandoned at any time after the work is commenc r eri ay~ 4 4 Uniform Building Code), APPLICANT'S SIGNATURE -~~~,,,C...--~~---------~~----- YELLOW: Applicant DATE //-f-Ot PINK: Finance City of Carlsbad i=i 1i•t!iili•i•J4·Eliii,t4111 August 10, 2005 TOM COSTELLO 5345 ARMADA DR CARLSBAD CA 92008 RE: BUILDING PERMIT EXPiRA TION PERMIT TYPE: TI Permit Number: CB044097 Issue Date: 12/20/04 ADDRESS: 1964 KELLOGG AV PLEASE CALL FOR AN INSPECTION IF WORK IS COMPLETE Our records indicate that your building permit will expire 'by limitation of time on 9/4/05. The provisions of UBC, Section 106.4.4 as amended by the Carlsbad Municipal Code state: "EXPIRATION. Every permit issued by the Building Official under the provisions of this code shall expire by limitation and become null and void if the building or work authorized by such permit is not commenced within 180 days from the date of such permit (unless issued prior to 7/1/99 which is one year from date of permit), or if the building or work authorized by such permit is stopped at any time after the work is commenced for a period of 180 days or if the building or work authorize<;! by such permit exceeds three calendar years from the issuance date of permit. Work shall be presumed to have commenced if the permittee has obtained a required inspection approval of work authorized by the permit by the Building Official within 180 days of the date of permit issuance. Work shall be presumed to be stopped if the. permittee has not obtained a required inspection approval of work by the Building Official within each 180 day period upon the initial commencement of work authorized by such permit. Before such work can be recommenced, a new permit shall be obtained to do so, and the fee, therefore, shall be one-half the amount required for a new permit for such work, and provided that no changes have been made or will be made in the original plans and specifications for such work, and provided further that such suspension or abandonment has not exceeded one year. In order to renew action on a permit after expiration, the permittee shall pay a new permit fee. · Any person ·holding an unexpired permit may apply for an extension of the time within which work may commence under that permit when the permittee is unable to commence work within the time period required by this section for good and satisfactory reasons. The Building Official may extend the time for action by the permittee for a period not exceeding 180 days on written request by the permittee snowing that circumstances beyond the control of the permittee have prevented action from being taken. No permit shall be extended more than once. Please check below fndicating your intentions and return this letter to us. Project abandoned. A new permit will be obtained prior to commencing work. No fee extension requested for 18'0 days. (attach a letter of explanation) Renewal permit requested. If the project has been completed and only a final inspection is needed, please call the inspection request line at (760) 602-2725. If you have any questions, please contact the Building Inspection Department at (760) 602-2700. Christine Wanschek Office Specialist 1635 Faraday Avenue • Carlsbad, CA 92008-7314 • (760) 602-2700 • FAX (760) 602-8560 @ l! 11111f Carlsbad · Final Building Inspection· Dept: Building, Engineer,ing Planning CMWD St Lite <Fire Plan Check #: Permit#: CB044097 Project Name: GIA 50O0-SF Tl FROM OFFICE/ WAREHOUSE TO SAME Address: 1964 KELLOGG AV Contact Person: KEVIN HEISER Sewer Dist: CA Phone: 8585186889 Water Dist: CA Date: 03/07/2005 Permit Type: Tl . Sub Type: COMM Lot: 0 .......................................................................................................................................................... ~;pee~~ Date #~ Inspected: · '.?la S-Approved: ~ Disapproved: __ Inspected Date By: Inspected: Approved: Di~approved: __ Inspected Date By: Inspected: Approved: Disapproved: __ ........................................................................................................................................................... Comments: ___ ...;.... ________________________ -- .,, Inspection List Permit#: CB044097 Type: Tl Date . Jri_~pection_!~m 01/07/2008 92 Compliance Investigation 03/07/2005 34 Rough Electric· 03/07/2005 89 Final Combo 03/01/2005 34 Rough Electric 02/17/2005 17 Interior Lath/Drywall 02/11/2005 24 Rough/Topout 02/08/2005 14 Frame/Steel/Bolting/Weldin 02/08/2005 21 Underground/Under Floor 02/08/2005 22 Sewer/Water Service 02/08/2005 24 Rough/Topout 02/08/2005 34 Rough Electric 02/08/2005 44 Rough/Ducts/Damper's 02/01/2005 11 Ftg/Foundation/Piers 02/01/2005 12 Steel/Bond Beam 01/28/2005 11 Ftg/Foundation/Piers 01/28/2005 12 Steel/Bond Beam 01/26/2005 11 . Ftg/Foundation/Piers 01/20/2005 17 Interior Lath/Drywall , 01/19/2005 17 Interior Lath/Drywall 01/19/2005 17 Interior Lath/Drywall 01/11/2005 14 Frame/Steel/Bolting/Weldin 01/11/2005 34 Rough Electric Monday, January 07, 2008 COMM Inspector Act GIA 5000 SF Tl FROM OFFICE/ WAREHOUSE TO SAME Comments __ , ________ ---·-· "" RI can I expire. OLD/OLD TP AP NEW MSB, TRANS RE-FEED, SUB PNLS TP NR NOT COMP. TP PA new msb for seo only TP AP TP AP TP AP T-CEIL SEISMIC UP GRADE TP AP TP AP TP WC TP AP NEW CEIL LITES TP WC TP AP TRK DOCK LEVELER, PRINT PRESS PAD TP AP TP NR TRUCK DOCK, PRINT PRESS THICK SLAB NEED SOILD ENG. NOTE TP NR TP NR TP NS INSP 1/19 TP PA DMZ WALL TP AP. INFILL WALL TP co TP co Page 1 of 1 j) City of Ca-rlsbad Bld.g Inspection Request For: 03/07/2005 Permit# CB044097 Inspector Assignment: TP ---Title: GIA 5000 SF Tl FROM OFFICE/ Description: WAREHOUSE TO SAME Type:TI Job Address: S1.1b Type: COMM 1964 KELLOGG AV Phone: 8585186889 Inspector: /4-Suite: Location: AP.PLICANT TOM COSTELLO Owner: JORKEN L L C Remarks: Total lime: CD Descripti'on 19 . Final Structural 29 Final Plumbing 39 Final Electrical 49 Final Mechanical Lot 0 Act Comment . ~ .. Requested By: KEVIN HEISER Entered By: KAREN i!f1_ ,Virr u;nyt-, . --,---------------------------- 3!L_ ______ ,IJ/J -- Associated PCRs/CVs lns12ection Histo!Y Date pescription Act 03/01/2005 34 Rough Electric PA 02/17/2005 17 Interior Lath/Drywall AP 02/11/2005 24 Rough/Topout AP 02/08/2005 14 Frame/Steel/Bolting/W aiding AP 02/08/2005 21 Undergro~nd/Under Floor AP 02/08/2005 22 Sewer/Water Service AP 02/0.8/2005 24 Rough/Topout WC 02/08/2005 34 Rough Electric AP 02/08/2005 44 Rough/Ducts/Dampers WC 02/01/2005 11 Ftg/Foundation/Piers AP 02/01/2005 12 Steel/Bond Beam AP 01/28/2005 11 Ftg/Foundation/Piers NR 01/28/2005 12 Steel/Bond Beam NR 01/26/2005 11 Ftg/Foundation/Piers NR 01/20/2005 17 Interior Lath/Drywall NS 01/19/2005 17 Interior Lath/Drywall AP lnsp Comments TP new msb for seo only TP TP TP T-C!=IL SEISMIC UP GRADE TP TP TP TP NEW CEIL LITES TP TP TAK DOCK LEVELER, PRINT PRESS PAD TP TP TRUCK DOCK, PRINT PRESS THICK SLAB NEED SOILD ENG. NOTE TP TP TP INSP 1/19 TP INFILLWALL "-' Carlsbad 04-4Q97 12/16/04 DATE: 12/16/04 JURISDICTION: Carlsbad PLAN CHECK NO.: 04-4097 EsGil Corporation In Partnersliip witli (jovernment for '.Bui{aing Safety . SET: II · PROJECT ADQRESS: 1964 Kellogg Ave. PROJECT NAME: GIA Print S~op TI :D The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes. • The plans transmitted herewith will substantially comply with the jurisdiction'.s building codes when minor deficiencies identified below are resolved and checked by building department staff. D The plans transmitted herewith have significant deficiencies identified on the enclosed check list · and should be corrected and resubmitted for a complete recheck. D The check list transmitted herewith is for your information. The plans are. being held at Esgil Corporation until corrected plans are submitted for recheck. D The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person. D The applicant's copy of the check list has been sent to: • Esgil Corporation staff did not advise_the applicant that the plan check has been completed. D Esgil Corporation staff did advise the applicant that the plan check has been completed. Person contacted: Telephone#: Date contacted: (by: ) Fax #: Mail Telephone Fax In Person @) {C_.; • REMARKS: A. The note clouded in red on sheet A0.1 must be made to the city set of plans.)! Sheets A0.1, A3.0, S1 .0 , M1 .1 & M2.1 are replacement sheets. Architect must proyide the city a set of these replacement sheets which must be incorporated into the city set of plans. By: Chuck Mendenhall · Esgil Corporation D GA D MB D EJ D PC walk In Enclosures: trnsrntl.dot EsGil Corporation Iii (l'artnersliip witli <]oTJernment for (Bui(aing Safety DATE: 11/23/04 JURISDICTION: Carlsbad .. PLAN CHECK NO.: 04-4097. PROJECT ADDRESS: 1964 Kellogg Ave. PROJECT NAME: GIA Print Shop TI . .SET:I ~ CJ PLAN REVIEWER CJ FILE · ·o The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes. D The plans transmitted herewith will substanti~y_c0m-p1fWith the jurisdiction's building codes when min9r deficiencies identified below ate resolved and checked by building department staff. D The plans transmitted herewith have significant deficiencies ide-ntffied on the enclosed check list and should be corrected and resubmitted for a complete recheck. • The check list transmitted herewith is for your information._ The plans are being held at Esgil Co_rporation until corrected plans are submitted for recheck. . . . . D The ·applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person. • The applicant's copy of the check list has been sent to: Tom Costello 5345 Armada Dr., Carlsbad, CA 92008 D Esgil Corporation staff did not advise the applicant that the plan check has been completed. • Esgil Corporation staff did advise the applicant that the plan check has been completed. Person contacted: Tom Costello Telephone#: (760) 603-4032 Date contacted:({/;,IJ/0{ (by~ . ·Fax·.#: (760) 603-4296 Mail 0elephone )v Fax Vin Person D REMARKS: V('(\ By: Chuck Mendenhall _ Esgil Corporation D GA D MB D EJ D PC Enclosures: 11/12/04 trnsmtl.dot 9320 Chesapeake Drive, Suite 208 + San Diego, California 92123 + (858) 560-1468 + Fax (858) 560-1576 "' Carlsbad 04-e4097 11/23/04 PLAN REVIEW CORRECTION LIST TENANT IMPROVEMENTS PLAN CHECK NO.: 04-4097 OCCUPANCY: Fl TYPE OF CONSTRUCTION: VN ALLOWABLE FLOOR AREA: no change . 'SPRINKLERS?: Yes REMARKS: DATE PLANS RECEIVED BY JURISDICTION: DATE INITIAL PLAN REVIEW COMPLETED: 11/23/04 FQREWORD (PLEASE: READ):· JURISDICTION: Carlsbad USE: Print Shop ACTUAL AREA: 6300 Remodel Only STORIES: two HEIGHT: no change OCCUPANT LOAD: 25 DATE PLANS RECEIVED BY ESGIL CORPORATION: 11/12/04 PLAN REVIEWER: Chuck Mendenhall This plan review is limited to the technical requirements contained in the Uniform Building Code, Uniform Plumbing Code, Uniform Mechanical Code, National Electrical Code and state laws regulating energy conservation, noise attenuation and access for the disabled. This plan review is based on regulations enforced by the Building Department. You may have other corrections based on laws and ordinances enforced by the Planning Department, Engineering Department, Fire Department or other departmen~s. Clearance from those departments may be required prior to the issuance of a building permit Code sections cited are based on the 1997 USC. The following items ·listed need clarification, modification or change. All items must be satisfied before the plans will be in conformance with the cited codes and regulations. Per Sec. 106.4.3, 1997 Uniform Building Code, the· approval Of the plans does not permit the violation of any state, county or city law. To speed up the recheck process, please note on this list (or a copy) where each correction item has been addressed, i.e., plan sheet number, specification section, etc. Be sure to enclose the marked up list when .you submit the revised plans. TENANT IMPROVEMENTS WITHOUT SPECIFIC ENERGY DATA OR POLICY SUPPLEMENTS (1997UBC) tiforw.dot J Carlsbad P4-4097 11/23/04 Please make all corrections on the original tracings, as requested in the correction ·list. Submit three sets of plans for commercial/industrial projects (two sets of plans for residential projects). For expeditious processing, corrected sets can be submitted in one of two ways: 1. Deliver all corrected sets of plans and calculations/reports directly to the City of Carlsbad Building Department, 1635 Faraday Ave., Carl~bad, CA 92008, (760) 602-2700. The City will route the plans to EsGil Corporation and the Carlsbad Planning, Engineering and Fire Departments. 2. Bring one corrected set of plans and calculations/reports to EsGil Corporation, 9320 Chesapeake Drive, Suite 208, San Diego, CA 92123, (858) 560-1468. Deliver all remaining sets of plans and calculations/reports directly to the City of Carlsbad Building Department for routing to their Planning, Engineering and Fire Departments. NOTE: Plans that are submitted directly to EsGil Corporation only will not be reviewed by the City Planning, Engineering and Fire Departments until review by EsGil Corporation is complete. 1. The printing shop is classified as an F-1 Occupancy. There is no occupancy separation required between the F-1 and ht existing Band S1 occupancies. Provide a descrjption of the type of inks and types and quantities of cleaning solvents to be used ·in this operation to show that the print shop is an F-1 and Not an HS (hazardous) occupancy. 2. If the operation uses Class I, II or HIA liquids mechanical ventilation is required that will provide 6 air changes per Hour per UBC 1202.2. 3. Include as part of the plans mechanical plans that show the required ventilation is provided for the employees within the print shop per UBC 1202.2.1 (15 CFM of outside air per occupant). 4. Provide a note on the site plan indicating the previous use of the tenant space or building being remodeled. Section 106.3.3. 5. Provide a description of the quantities and types of printing inks and solvents used in the print shop. Show that there are no hazardous materials stored and/or used within the building which exceed the quantities listed in UBC Tables 3-D and 3:.E. · · To speed up the review process, note on this list (or a copy) where each correction item has been addressed, Le., plan sheet, note or detail number, calculation page, etc. The jurisdiction has contracted with Esgil Corporation located at 9320 Chesapeake Drive, Suite 208, San Diego, California 92123; telephone number of 858/560-1468, to perform the plan revi.ew for your project. If you have any questions regarding these plan review ·items, please contact Chuck Mendenhall at Esgil Corporation. Thank you. J Carlsbad 04-4097 11/23/04 IV ALUATION AND PLAN CHECK FEE JURISDICTION:. Carlsbad PLAN CHECK NO.: 04-4097 PREPARED BY: Chuck Mendenhall DATE: 11/23/04 . ' BUILDING ADDRESS: 1964 Kellogg Ave. BUILDING OCCUPANCY: Fl TYPE OF CONSTRUCTION: VN BUILDING AREA PORTION (Sq.Ft.) Tl 6300 - i Air Conditioning Fire Sprinklers TOTAL.VAl-UE . Jurisdiction-Code cb I Bldg·. Permt Fee by Ordinance ffl I Plan Check Fee by Ordinance iJ Valuation ·Reg. VALUE M.J.ltiplier l'v'bd. City Est , By Ordinance · Twe.of'Review:· . ~ Complete Review D Structural Only D Repetitive F~e ... I . Ir$) Repeats · D Other · D. Hourly T Hour * .Esgll Plan· Review Fee ,, ,, ,, ,, Comments: ($) 155,000 155,000 $715.96] $465.37) $400.9~ Sheet 1 of 1 macvalue.doc J ,• .. , DESCRIPTION Amount PL.A TE FIX(SCRA TCH REMOVER) QUART . 4 R '$CRATCH REMOVER QUART 4 RAPID FIXER BOX(SQT-A/1"802-B MAKES 5 GALI-ON) 1 :A-60.0PORLESS B&R WASH 5 GALLON PA.IL 1 AR$-Ml,.\ALCOHOL SUBSTITUTE 5 GALLON PAIL . 1 . EMERALlP JRZ FOUNTAIN SOLUTION 5.GA~LON PAIL, 1 INKOTE SPRAY(NON-AEROSOL ANTl~SKINNING SPRAY) QUART/S 4 METERING ROLLER CLEANER AL T(STRONG) GALLON 1 DN'-SM NEGATIVE MACHINE DEVELOPER 5 GALLON ,(2 X 2.5 GALLON) 2 FN'-6 FINl$HER NEGAT!VE(MACHINE FINISHER). GALLONS 2 LH.~DPR2 AQUEOUS POSITIVE REPi..E.NISHER (CTP} GALLON 2 LH-D.PW2 AQUEOUS POSITIVE DEVELOPER(CTP) ~ GALLON(2.5 GALLON X 2) 1 SG STORAGE GUM GALLON . 1 GLASS CLEANER AEROSOL CAN 12 SV\/ELL(BLANKET REPAIR).3-0UNCE jAR · 3 TAKE IT ·OFF 1-LB JAR 2 . TR-YE BLUE(OFFSET PLATE CLEANER) QUART 12 V-120 WASHS GALLQNPAIL 1 ijLACK PHOT-0-INK-CARTRIDGE UJ._ TRAOHROME 220ML F/STYLµS PRO 9600 1 · CYAN INK 'CARTRIDGE UL TRACHROME 220ML F/STYLUS PRO 9600 1 :LIGHT BLACK INK CARTRIDGE UL TRACHROME 220ML F/STYLUS PRO 9600 1 LIGHT CYAN. INK CARTRIDGE UL TRACHROME 22QML F/STYLUS PRO 9600 1 LiGHT MAGENTA .INK CARTRIDGE UL TRACHROMl= 220ML F/STYLUS PRO 9600 1 MAGENTA INK CARTRDIGE UL iRACHROME 220ML F/STYLUS PRO 9600 1 REPLACEMENT INK MAINTENANCE TANK 1 . REPLACEMENT PRINTER CUTTER BLADE 1 YELLOW INK CARTRIDGE UL TRACHROME 240ML j=/5_TYLUS PRO 9600 1 :SLACK INK FOR IRIS 43Y WIDE 2/PK 1 CYAN INK FOR IRIS 43Y WIDE 2/PK 1 MAGENTA INK FOR IRIS 43Y WIDE 2/PK 1 YELLOW INK FOR IRIS 43Y WIDE 2/PK · 1 ENOVATroN METAL PLATE DELETiON PEN-TYPE F/i=INE TIP 5 E.NOVATION METAL PLATE DELETION PEN-TYPE F/LARGE TIP 5 'ENO.VATION METAL PLATE DELETION PEN-TYPE F/MEDIUM TIP 5 .l;NOVATION.SILICONE SPRAV(AEROSOL) 20 OUNCE CAN(11 OZ-NET) 6 DUST-OFF CLASSIC REFIL,.L 10,.oz. CAN 5 WD-4.0 LUBRICANT/SPRA Y(AEROSOL) 11-0UNCE CAN . .6 SUPER 77 SPRAYADHESIVE(51% VOC) 24 FLUIDOUNCE(NETWT 16.5 OZ) 6 Sova Ink 50 Lbs BUILDING PLANCHECK CHECKLIST DATE: /( tf i tfl/ PLANCHECK NO.: su1LmNGA oR ss: cu lf f;f. '¥~ PROJECT DESCRIPTION: .- ASSESSOR'S PARCEL NUMBER: d,(;). -a1ii ENGINEERING DEPARTMENT APPROVAL· ~ ES VALUE: DENIAL The item you have submitted for review has been . approved. The approval is based on plans, information and/or specifications provided in your submittal; therefore any changes to these items after. this date, including field modifications, must be reviewed by this office to insure continued conformance with applicable codes. . Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to build. Please attached report of deficiencies marked with . Make necessary corrections to plans or specifi ti ns for compliance with applicable codes an standards. Submit corrected plans and/or specifications to this office for review. A Right-of-Way permit is required prior tq construction of the following improvements: By: Date: -. · .. :,.,-:, --, ::.·:( ·,::,.-·:;,·:', ·,:"<,,:: r :1, ;·:· •• ,_,._,-~ ;?-.. ;-<· .,·-:,':,.--F~~-0FFI_CJ~LJJ~E O~l;Y,·-' :c ·,:" ·',, ;,' ', · ,,,-.. ; __ ·,_ ENGINEERIN<fAU"tf.10RlZ4,T:I_ON_JO:IS~QE B_!J}LDlN~ PERMIT:.<:·,,' .' ,,,: _; ::· _ -':--· \~;()·:::_:;'.;,,: :;'.?'/.'',,_l.":>'.''~:;.:··,i',~:·::;\_>,:::::;:)?/:;·):/:;:/.ti;.\',;.,,;,·~:::!:'.~:;~t:\i'.{?~:1'~.b,~!~;_-~:,:1 :_-::::~.·~.-.-_ -:•.:, Dedication Application Dedication Checklist Improvement Application Improvement Checklist Future Improvement Agreement Grading Permit Application Grading Submittal Checklist Right-of-Way Permit Application Right-of-Way Permit Submittai Checklist and Information Sheet Sewer Fee Information Sheet H:IWORD\DOCS\CHKLST\Bulldlng Plancheck Cklst Fonn (Generic),doc ENGINEERING DEPT. CONTACT PERSON Name: JOANNE JUCHNIEWICZ City of Carlsbad Address: 1635 Faraday Avenue, Carlsbad, CA 92008 Phone: (760) 602-2775 CFD INFORMATION Parcel Map No: Lots: Recordation: Carlsbad Tract: A-4 1 Rev, 7114/00 0, 1sr D D D 0 BUILDING PLANCHECK CHECKLIST SITE PLAN 1. Provide a fully dimensioned site plan drawn to scale. Show: A. North Arrow F. Right-of-Way Width & Adjacent Streets B. Existing & Proposed $tructures G. Driveway widths C. Existing Street Improvements H. Existing or proposed sewer lateral D. Property Lines I. Existing or proposed water service E. Easements . J. Existing or proposed irrigation service 2. Show on site plan: A. Drainage Patterns 1. Building pad surface drainage must maintain a minimum slope of one percent towafds an adjoining street or an approved drainage course. 2. ADD THE FOLLOWING NOTE: "Finish grade will provide a minimum positive drainage of 2% to swale 5' away from building." B. Existing & Proposed Slope!:> and Topography C. Size, type, location, alignment of existing or proposed sewer and water service (s) that serves the project. Each unit requires a separate service, however, second dwelling units ancl apartment complexes are an exception. b. Sewer and. water laterals should not be located within proposed driveways, per standards. 3. Include on title sheet: A. Site address B. Assessor's Parcel Number C. Legal Description For commercial/industrial buildings and tenant improvement projects, include: total building square footage with the square footage for each different use, existing sewer permits showing square footage of different uses (manufacturing, warehouse, office, etc.) previously approved. EXISTING PERMIT NUMBER DESCRIPTION BUILDING PLANCHECK CHECKLIST DISCRETIONARY APPROVAL COMPLIANCE D D D 4a. Project does not comply with the following Engineering Conditions of approval for Project No. _______________________ _ D. D D 4b. All co_nditions are in compliance. Date: _________ _ D 0 D D D DEDICATION REQUIREMENTS 5. Dedication for all street Rights-of-Way adjacent to the building site and any storm drain or utility easements on the building site is required for all new buildings and for remodels with a value at or exceeding $15,000, pursuant to Carlsbad Municipal C0de Section 18.40.03Q. Dedication required as follows: ________________ _ Dedication required. Please have a registered Civil Engineer or Land Surveyor prepare the ·appropriate legal description together with an 8. ½" x 11" plat map and submit with a title report. All easement documents must be approved and signed by owner(s) prior to issuance of Building Permit. Attached please find an application form and submittal checklist for the dedication process. Submit the completed application form with the required checklist items and fees to the Engineering Department in person. Applications will not be accept by mail or fax. Dedication completed by: _______________ Date: ___ _ IMPROVEMENT REQUIREMENTS D . 6a. All needed public impro.vements upon and adjacent to the building site must be constructed at time of building construction whenever the value of the construction exceeds · $75,000, pursuant to Carlsbad Municipal Code Section 18.40.040. Public improvements required as follows: _______ ___._ ____ _ Attached please find an application form and .submittal checklist for the public improvement requirements: A registered Civil Engineer must prepare the appropriate improvement plans and submit them together with the requirements on the attached checklist to the Engineering Department through a separate plan check process. The completed application form and the requirements on the H:IWORD\DOCSICHKLST\Buildlog Pianclleci< Ckist Fonn (RIDDLE• HARVEY7•12•00).doc 3 Rev. 12/26196 I 'o/ D · D· ·o D D D D D D D D D D D D D D D · BUILDING PLANCHECK CHECKLIST checklist must be submitted in p.erson. Applications by mail or fax are not accepted. Improvement plans must be approved, appropriate securities posted and "fees paid prior to issuance of building permit. , Improvement Plans signed by:--"""'-'--------Date: ---- 6b. Construction of th~ p·ublic improvements may be deferred. pursuant to Carlsbad Municipal Code Section 18.40. Please submit a recent property title report or current grant deed on the property and processing fee of $310 so we may pr~pare the necessary Future Improvement Agreement. This agreement must be signed, .notarized and approved by the City prior to issuance of a Building permit. Future. public improvements required as follows: Sc .. Enclosed please find· your Future Improvement Agreement. Please return agreement signed and notarized to the Engineering Department. Future -Improvement Agreement.completed by: Date: 6d. No Public Improvements required ... SPECIAL NOTE: Damaged or defective· improvements found adjacent to building site must be repaired to the satisfaction of the City Inspector prior to' occupancy. · GRADING PERMIT REQUIREMENTS ,. The conditions that invoke the need for a grading permit are found in Section 1 f 06.030 ·of the Municipal Code. 7a. Inadequate information available on Site Plan to make a determination on grading requirements. Include accurate grading quantities (cut, fill import, export). 7b. Grading Permit required. A separate grading plan prepared by a reg·istered Civil Engineer must be submitted tog.ether with the completed application form attached. _ NOTE: The Grading. Permit must be issued and rough grading approval obtained prior to issuance of a Building Permit. Grading lnspe<?tor sign off by: ~---------Date: 7c. Graded Pad Certification required. (Note: Pad certification may be required even if a grading permit is not required.)·· H:IWORDIDOCSICHKLST\Bulldlng Plancheck Cklsl Fonn.(Generic 7-14·00).doc 4 Rev. 7/14100 BUILDING PLANCHECK CHECKl,.IST 1ST 2ND 3RD D D [J 7d .No Grading Permit req_uired. D D D 7e. If grading is not required,.write "No Grading" on plot plan. D D D D D D D -D D D D D MISCELLANEOUS PERMITS 8. A RIGHT-OF-WAY PERMIT is required to do work in City Right-of-Way and/or private work adjacent to the public Right-of-Way. Types of work include, but are not limited to: street improvements, tree trimming, driveway construction, tying into public storm drain, sewer and water utilities. Right-of-Way permit required for: 9. INDUSTRIAL WASTE PERMIT If your facility is located in the City of Carlsbad sewer service area, you need to contact the Carlsbad Municipal Water District, located at 5950 El Camino Real, Carlsbad, CA 92008. District personnel can provide forms and assistance, and will check to see if your business enterprise is on the EWA Exempt List. You may telephone (760) 438-2722, extension 7153, for assistance. Industrial Wc1ste permit accepted by: Date: 10. NP DES PERMIT Complies with the City's requirements of the National Pollutant Discharge Elimination System (NPDES) ·permit. The applicant shall provide best management practices to reduce surface _pollutants to an acceptable level prior to discharge to sensitive areas. Plans for such improvements shall be approved by the City Engineer prior to issuance of grading or building permit, whichever occurs first. · 11. Cl R~d fees are attached · ,n'};~; required WATER METER REVIEW 12a. Domestic (potable) Use Ensure that the meter proposed by the owner/developer is not oversized. Oversized meters are inaccurate during low-flow conditions. If it is oversized, for the life of the meter, the City will not accurately bill the owner for the water used. • All single family dwelling units received "standard" 1" service with 5/8" service. H:\WORO\DOCSICHKLST\Bulldlng Plancheck Cldst Form (Generk:J.doc 5 Rev. 7/14/00 ... D D ·o BUILDING PLANCHECK CHECKLIST • If owner/developer proposes a size other than the ·"standard", then owner/developer must provide potable water demand calculations, which include total fixture counts and maximum water demand in gallons per minute (gpm). A typical fixture count and water demand worksheet is attached. Once the gpm is provided, check against the "meter sizing schedule" to verify the anticipated meter size for the unit. • Maximum service and meter size is a 2" service with a 2" meter. • If a developer is proposing a meter greater than 2", suggest the installation of multiple 2" services as needed to provide the anticipated demand. (manifolds are considered on case by case basis to limit multiple trenching into the street). 12b. Irrigation Use {where recycled water is not available) Aff irrigation meters must be sized via irrigation calculations (in gpm) prior to approval. The developer must provide these calculations. Please follow these guidelines:. 1. If the project is a newer development (newer than 1998), check the recent improvement plans and observe if the new irrigation service is reflected on the improvement sheets.· If so, at the water meter station, the demand in gpm may be listed there. Irrigation services are listed with a circled "I", and potable water is typically a circled "W". The irrigation service should look like: STA 1+00 Install 2" service and 1.5: meter (estimated 100 gpm) 2. If the improvement plans do not list the irrigation, meter and the service/meter will be installed via another instrument stJch as the building plans or grading plans (w/ a right of way permit of course), then the applicant must provide irrigation calculations for estimated worst-case irrigation demand (largest zone with the farthest reach}. Typically, Larry Black has already reviewed this if landscape plans have been prepared, but the applicant must provide the calculations to you for your use. Once you have received a good example of irrigation calculations, keep a set for your reference. In general· the calculations will include: • Hydraulic grade line • Elevation at point of connection (POC) • Pressure at POC in pounds per square inch (PSI) • Worse case zone (largest, farthest away from valve • Total Sprinkler heads listed (with gpm use per head) • Include a 10% residual pressure at point of connection 3. ·In general, all major sloped areas of a subdivision/project are to be irrigated via separate irrigation meters (unless the project is only SFD with no HOA). As long as the project is located within the City recycled water H:IWORDIDOCSICHKLST\Bulldlog Plancheck Cklst Fann (Generic).doc 6 Rev. 7/14/00 D D 0 DD BUILDING PLANCHECK CHECKLIST -service boundary,. the City intends on switching these irrigation services/meters to a new recycled water line in the future. 12c. Irrigation Use (where recycled water is available) 1. Recycled water meters are sized the same as the irrigation meter above. 2. If a project fronts a street with recycled water, then they should be connecting to this line to irrigate slopes within the development. For subdivisions, this should have been identified, and implemented on the, improvement plans. Installing recycled water meters is a benefit for the applicant since they are exempt from paying the San Diego County Water Capacity fees. However, if they front a street which the recycled water is there, but is not live (sometimes they are charged with potable water until recycled water is available),. then _the applicant must pay the San Diego Water Capacity Charge. If within three years, the recycled water line is charged with recycled water by CMWD, then the applicant can apply for a refund to· the San Diego County Water Authority (SDCWA) for a refund. However, let the applicant know that we cannot guarantee the refund, and they must deal with the SDCWA for this. 13. Additional Comments: H:IWORD\OOCSICHK!.snBUikllng Plancheck Cldst Fonn (Generlc).doc 7 Rev. 7/14/00 14 December 2004 City of Carlsbad Engineerjn_g .De_partment 1635 Faraday Ave. Carlsbad, CA 92008 Attention: Joanne Juchniewicz RE: Plan Check Resubmittal No., 044097 1964 Kellogg Ave. Carlsbad, CA 92008 RCA+A Roh.,.,1 R Coffi•n Architncl & A,;.<;ocr.--it,•~ 3111 SocondAvcmw Suite 3 Corona def Mar. CA 92625 949 7€0 8668 T 949 7599)81 F rcottccarch.:~icarthlirk net 1. Please refer to the "Project Information" on the revised sheet A0.1 for the existing and proposed square foot-tabulations. They are stated as follows: Existing Occupancy Rating: Proposed Occupancy Rating: Existing Office Area: (B Occupancy) First Floor: Second Floor: Existing Warehouse Area: Proposed Office Area: (B Occupancy) First Floor: Second Floor: Proposed Warehouse Area: F-1 Occupancy: S-1 Occupancy: B, F-1, S-1 B, F-1, S-1 4,481 s.f. 3,690 s.f. 32,660 s.f. 4,481 s.f. 3,690 s.f. 32,660 s.f. 11,283 s.f. 21,377 s.f. ~ _,.·· . PLANNING/ENOINEERINC APPROVALS RESIDENTIAL RESIDENTIAL ADDITION MINOR ( < $10,000.00) · PLAZA CAMl'1fO REAL CARLSBAD COMPANY STORES VILLAC&· FAIRE COMPLETE OFFICE BUILDING · OTHER ------------------'"----------- PLANNER . 11 !A_ ~--1--/-11-f-+Lu--7~------DATE //-(}q .. ~ If ENCINEER DATE ------------------,---- nn,-r/Ule-Jnl"ll"l'lirJDJ~ftnift,. e ..... , ........ _. •--.. -,,-, .. Carlsbad Fire Department 044097 1635 Faraday Ave. . Carlsbad, ·CA 92008 Plan Review Requirements Category: Fire Prevention (760) 602-4660 . Date of Report: _12_1_01 ___ 12_0_0_4 _______ _ Building Plan Reviewed by: J{'-()~w~ Name: Tom Coste ----------------------Address: 5355 Armada Drive City, State: Carlsbad CA 92008 Plan Checker: ____________ Job#: _o4_4_09_7_----"---- Job Name: GIA , · !3ldg #: CB044097 ----------------....-----'---"';..._::::..,__ Job Address: 1964 Kellogg Ave Ste. or Bldg. No. ____________________ ____;._ ~ Approved D Approved Subject to D. Incomplete Review FD Job# The item you have submitted for review has been approved. The approval is based on plans, information and / _or specifications provided in your submittal; therefore any changes to these items after this date, including field modifications, must be reviewed by this office to insure continued conformance with applicable codes and standards. Please review carefully all comments attached as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements. The item you have submitted for review has been approved subject to the attached conditions. The approval is based on plans, information and/or specifications provided in your submittal. Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements. Please resubmit to this office the necessary plans and / or specifications required to indicate compliance with applicable codes and standards. The item you have submitted for review is incomplete. At this time, this office cannot adequately conduct a review to determine compliance with the applicable codes and·/ or standards. Please review carefully all comments attached. Please resubmit the necessary plans and/ or specifications to this office for review and approval. 1st 044097 2nd FD File# 3rd Other Agency ID POOR QUALITY ORIGINAL S " ·.··_~.::..:_i}."<}\ .'. •.. ~;.~~~--.... ·· .. , •.::i-:'···2-. :. . ····· ::·.:~,---~~!:,-~: ... -;: ii:·;.~.;~:\~b:r"' , · .·.--~ ·: ·· ... _. · ;:_ .· :.-·· .-.. ~ . . · .. :,:' .,,<··-·. . , ,.·,· ..... ,.,:-· · · .-.-, 3M General Offices: · . ····. . . ~.; . ///:·:.: . ; .-'i . .-·.:,;\\( :· -.:, · < ·:._'~~~~~er·.<· . ·.-. . :.·. · ·· ).' ... , .. J: :.. <,r:.:-_. .. , . · ·.'· . :: St. Paul, Minnesota 55144:19.00 .. ' .. · · · · · <}r::.-.: .:)-:·r.;-·~ i_ · .. :., 61217~3J1:.~ ··/: _ :_. .. _, . -.. :::_-/, --~, =,.--:::.\ ·.,-,:.i_-\·: :·· · .. ·-·.: .. _:;; __ ..... _ .. ;_.,.. ..,,; · . ·: . . ·· : D~.ms . No. 1 0 ~_:-617 ~J082 :>-.. :: · .. · . ·! .:.· ·· · · . ~ '.! ·.::. ·, .. 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"·· · ... . ~~.:-· .. ~.:·::(-:·:·· 7, PRECAUTIONARY INFDRMAII~N . · (con:tinuedl-~ · .. _ · .· · · ·· . .-.. =·~ _·:·_·.·.~-~:-;;: __ ... _: .. ;.>.'~-_: __ :-.'':. ,:., .. \;,:::/:', -:; .·. ,.-. .-: i> . ..:.·.'ACGIH1>A.m~ri·can Cord~rence_: of--:'Gciv.ei-nm_erital''Xn.dust.ria~:: .. tfys;i_i~r,i~.ts?,,.::: ... :-./ :.· ...... ··t<· '.: __ ,-..:: :::~ .. ?-,:,.,.-··:-._; ~~~A./\-~.f.~~-~~.~~r;>r~;; -.~ .. ~:t:~:t:y'.-.~~r:~-~~-1 t~.:-:A._d_~?-,~-~~-:tr.~~1~.~-i\·=::;:..;-r---<~:\:t)\Y/\T;.1., . ·: .. : .,:·>---.\.' a, HEALTH HAZARD·.DATA·· ... · ·.. . ..... ·, ·.··· r ·.·: ... •,)' '•,, ::,>\'=*,':',~~:,-,·:~--·•:!.•, ....... -:.:_. ·. -:·: .. · .. · ...... :. . .·/ _::_'.:·=,:· ':'·i· .-·:·:,:-. :.> .. . :·: ':}t).-( :.'/:·;: :/ ,::-:\\--:-:: .. -:_.:;.;· :'·',: ··,· ,:.:_;: ·, ·, ·:·-.:-'. ;, : ' ...... .. _;~ :(:;;,_;.;:;~~~~~·~;:~,~!Ff.!~:·:~~~ '{rr~~·~::~:,~~d. ~~~)'.~~~l '.?·"~d, ~>\~~.:~.~·.:-;:;01:~b;; ·.:.-< .:_ · <-· :_ :::f:·'··::. :·:skin<Conta_c.t i':· -~uses: sever'!!! ·s.~in.: 'irr.ita:tio~:-.'ao·c1 .. :mil,d buro;;;_·C?.1'.'1. :··:~}-~-hl.::::'(fX· : .. :;·: ·:/.f >ft}\:;/: :;~::::::-:tt:~~::,i:::~t; .. ~1::1~1~::.1~~ :-?~r~~!:!,:t:~1:-r:-:::·i·-i-~;}~}%:.;:ri~/liJt7 . . .· .. c.,.. -;:',. ·-,Pr-olongad:·exposur·a ,'of·. vapor may'· ca.use' k'idn~y .cha.ng_es· a_nd:.nervous';-_;,::_:; .. _.,fr:::;_,:f · . . . .-::. ··y· ·:'-' .. ; .. sv~~8f!1:. impai.rme~t~';.( ~ymp1:om~i(111av.-.,.~~~1~:~e:·,~ea9a,~,f:J~ ,.. :,9~-~~;in~.-S1~.:;,i.n£!µf?~,: .. r~,:i' · · ·· ·· · ;.·. · v0111:i. t:i.og · and unconsc:i.ousness ·,·".t';, .. .-.-,\ .... ;,,,.· · · . ,·· .. , ·.,, .. ', ... · · .··i.···"· .,, ... , ..... , .. , .... ,,, ·,1 . .. . .., . ·.·. ·. :::·;-~ i'.?:-\:.\\:~,~~;~·il~:~ )\:.! ·i:s~:~~··.::~;-~1~:i_;t_f-~~!t!~ttitr~~If i-~--~:~jYf ;}i~=-3i,~)!i~~tit~;;htf ·.· ::·.'· . ·:.:.:·\·:.~;::-·:.t, dan:iag,_::, ._.;Aspi-rat~·on. of, _:t})e.-··.Hc;'-!i'~,_:_into;-._th_e ·· !ur)°ss ·may·.-c~1;1s'e ·lµ.p~O::i..:.::g\;:::~,:-. · _ ',:, ·.: ,·,.=!:''·':··'·.damage: .. u,d.-·:~deatn· ... -:~,,-Symptoll1$. may-;1ncl.ude· vom1 ting/ ·:c1bdomJ.naJ:: pain, '·r:.'::i:''·-~·:,;i/{,, ... :.);· . .-,::, i/':<::(:}:"·:/ d~~-~r.h.~;~ '~~.f_w·~~:~r'.8~~ _::. ::/;~_j//::_:;_ .i\i/;0 :}},\/?) .':·:_.-(\·~!.\i\\:/ /:\/-:).<-;.:_,:·'. r )>:}{:_,(2::{{tt<~1 ... ·· .. -·: ·· ._:_·: ~--.~. ,SECTION CHANGE· DAT~S . ·. -·· ·.-·r· ·:· ;-.· · · · · . . . . . •·• ·.:.:;, > ~. · z ";.,..m;~~~ : ,:: ': s~c~z 0~.C."fil~~~;'.~iN~E,;; .~~~c.~1~~: 1:9a~ · ~'!~~,<~ / ;_;, :;;;;~~l,~~f t~~ . ·· . ··. ,. ENV!I\QN •. DA.TA.· ...... SECTXDN .. CHANGED·.SINCE-.. MARCH 14., 1989-lSStra -'', .-'i·:\;:: ,,.·;.i.-·,;,,, ,i;,:, ·;:: :-; .... i._ .. · -..: .-· ..... __ .. >)(>· :·:· _:_ l/:-, .. :.-,· '-=:·-/·\·/ -'i. ·:-:.lf;':i.ft<·-?.-.. ,.".':-:. :-:-':<(: . i.: .. ·. :';,;-::._.;;.:/-.:->-,· ·.:~:::._;.\tti';~-.:··r~'.:,-:YGt, -1~! ..... ··.: \·_;. ·.,· <. ':..'_:;'.;_'.'. .. _·_Th~ 4ntormation · Ol'.J. this Data.:_St)~_ef_ reP.r-e~en~s· our ;_c1.1,:-re,nt··.· data ~nd. ·. be~t .. ·.::_~'f('·' .·' :::_: :.::,•·.,.:.·.;:-:= .. op:i.nJ.,on as. -to .the .Pr-ope~.=. -µs~ _1n::, · h:andhl'!sr of ,th:1:s ·.· produ~i: ·under normal";-::::J:?' ·· · · .. · :: · :,:'_°,_" ·c:ondit:ions ,·, . Any ·.Lise .'of :the _.pr-oduct··whi~h-is: nQ-t: .in ·:conformanca with ·-this·:-:1--:',)?: .... y,i:':.' · ···· · Data. Sha~t or which :involv,s using 1:he . product in :combination with -any· · :: _·-_:;i:_/C -. other product 01·· any o-ther process is 'the· responsibility of -1:he user;·· . · · ·: ·:-:, <:_._.,,.,.,_._.. __ - • • • ,i • ~ • •• ' ~ ••• •• • ••• • ••• • • • •' •• •• • • • •• .. :·. i .• ·.. . : 962t-E:0909L. ~ j • REASON REVISED: Update; Supersedes All ·Previous Revisions. , .. ·,_,_---------.,....,...,,...-~-----------,----------------------SECTION 2 • HAZARDOUS INGREDIENTS/SARA III INFORMATION REPORTABLE COMPONENTS CAS NUMBER VAPOR PRESSURE MM HG@ TEKP WEIGHT PERCENT -----------------------------------------------------------------------------~--------------- Petroleum Naphtha 8052-41-3 2.0 68°F 18 OSHA PEL: 500ppm, ACGIB 1LV: lOOppa MINERAL SEAL OIL 64741-44-2 0.1 68°F 13 OSHA PEL: 5mg/M3, ACGIB 1LV: 5mg/M3, STEL: 10llg/M3 As Mist Diptopylene Glycol Methyl Ether· 34590-94-8 0.17 68°F 3 OSHA PEL: l()()ppa, ACGIB TLV: lOOppm, STEL: 150pp11 * E~hylene Glycol 107-21-1 0.12 68°F 2 OSHA PEL: n/e, ACGIH TLV: 100mg/M3 Celling as Mist ,,,.-... Hazardous Air Pollutant ~acetone Alcohol 123-42-2 l.O ss°F 2 OSHA :PEL: 50ppm, ACGIH .TLV: 50ppm * Indicates toxic chemical(sl subject to the reporting requirements of Section 313 of SARA Title Ill and of 40 CFR 372. All ingredients are listed on the EPA TSCA Inventory. SECTION 3 -PHY~CAL/CtiEMICAL CHARACTERISTICS BOILING RANGE/POINT: >212°F VAPOR DENSITY: Heavier than air. EVAPORATION RATE: Slower than water. V.0.C. (EPA MHTIIOD 24): 2.94 lb/gl V APO:R PRESSURE .(UM HG tD 20 • C) : 0. 20 SOLlIBILITY IN WATER: Less Th~ 5% APPEARANCE i\ND ODOR: V.'hi..te Paste -Petroleum Odor SPECIFIC GRAVITY (H20=1): .92 ·. ·SEC'tION 4 • FlRE AND EXPLQSION HAZARD DATA FLASH POINT: 107°F FLAMMABLE LIMITS rN AIR BY VOLUME-LOWER: .1.0% EXTINGUISHING MEDIA: Foam, CO2, Dry Chemical. t~lAl ~G l)ROCEDURES~ METHOD USED: TAG CC UPPER: 14.4% A in any lire, wear sell-contained breathing apparatus (MSHA/NlOSH approved) and full protective gear. Water may not be iective to extinguish fire. Use water spray to cool fire-exposed containers and to protect personnel. UNUSUAL ARE ANO EXPLOSION HAZARDS: Treat as Petroleum Fire. SS~i>EOSOSl. 8Hl ·-. . .: ,. TAKE-IT-OFF MATERIALSAFElY DATA SHEET i Revised: Page: 2 January 2, 2003 _.r ' SECTlON 5 -REACTI\IITY DATA ____ _:_ __ ---~~~~~~!..!...=!!!.!::~---------- TAKE-IT-OFF ~ODUCT CODE: B014255 Avr MATERIAL SAFETY DATA SHEET SECTION 1 "'. MANUFACTU.RE~ IDENTIFICATION MANUFACTURER'S NAME: Day Interna~ional Chemical Products Div. ADDRESS 905 South Westwood Avenue Addison, Illinois 60101 Page: 1 Revised: January 2, 2003 mus CODES: H FR p 1 2 0 X EMERGENCY PHONE: 800-424-9300 NAME OF PREPARER: DAY Chemical-Prod. Di-v .. INFORMATION PHONE: 800-336-8276 DATE.PRINTED: 01/02/03 ) ·-, i .- TAKE-IT-OFF MATERIAL SAi=ElY DATA SHEET 11 SECTION 5 • REACTIVrlY DATA STABILITY: Stable CONDITIONS TO AVOID: Avoid heat, sparks. flame qnd other sour.ces of ignition. tK:OMPAT131L.ITY. IMATERIAI.S TO AVOID): Avoid mixing with strong oxidizing agents. HAZARDOUS DECOMPOStrlON:OR BYPRODUCTS: Burning will produce oxides ot carbon and dense smoke. HAZARDOUS POLYMERIZATION: Will Not Occur. SECTION 6 -HEALTH HAZARD DATA INHAIATION-HEALlH RISKS AND·SYMPTOMS OF EXPOSURE: Revised: Page: 2 January 2, 2003 Brealhing high concentrations of vapors will cause irritation of the nose and throat. Signs of central nervous system depression such as headache, drowsiness, diz.zlness and nausea may be experienced with overexposure. SKIN ANO EYE CONTACT HEALTH RISKS~ SYMPTOMS OF EXPOSURE: ·.,-.._in anq ey~ contact may ca1.,1se moderate to severe irritatt.on. SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Single prolonged exposure is not likely to result in the product being absorbed through the skin in harmful amounts. NGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Ingredients in this product are toxic. Ingestion may cause nausea, moderate gostro-intestinol irritation, diarrhea and possible damage to vital organs. Follow first aid _procedures. HEALTH HAZARDS (ACUTE AND CH~C): . This product may cause mild to moderate lrrlfofion upon contact with eyes and mild Irritation to skin. Ethylene glycol has been identified as a probable birth defect hazard based on laboratory animal data. CARC~ITY: NTPCARONOGEN: No IARC MONOGRAPHS: No OSHA REGUlATED: No This product contains no known carcinogens. MIDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Skin contact may aggravate pre-existi~g dermatltls. lnhalati~n of vapors.may aggravate pre-existing asthma like conditions. EMERGENCY AND FIRSTAIO-~EDURES: INHALATION: Remove victim to fresh air. Give oxygen if breathing Is labored. Apply artificial respiration if not breathing. Seek medical help. SKIN: Remove_ all contaminated clothing and shoes.Wash with soap and water. Do not reuse clothing and shoes until cleaned. EYES: Flush eyes with plenty of water while removing.any contact lenses. Hold eyelids open and continue .,......_,·,shing for at least 15 minutes. INGESTION: DO NOT INDUCE vomiting. If vomiting occurs spontaneously, keep head below . ,,ps lo prevent aspiration of liquid int~ fhe lungs. Seek medical attenfioh lmmedlately. ssa-t-E:ososl. l:::IIEI -:_ . } .- TAKE-rt-OFF DJlU· MATERIAL SAFETY DATA SHEET ~I ., . secnoN 7 • _PRECAUl'IONS FOR SAFE HAN DUNG AND USE STEPS TO BE TAKEN IN CASE MATERIAL IS REI.EASED OR SPIU.ED: Revised; Page: 3 January 2, 2003 Eliminate all Ignition sources. Spllls should be diked and must be kepi from entering the sewer. Sook up with absorbent or transfer liquid into a closed container for later disposal. Use spark-proof tools and explosion proof equipment. WASTE DISPOSAL METHOD: If this product as supplied, becomes a waste ft Is regulated by RCRA as Ignitable Waste, EPA 1.D. #D001. Suitable methods of disposal include reclamation and fuel blending. Contact a Licensed Hazardous Waste Hauler for more Information. PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORING: containers should. be grounded and bonded before transferring product. Store in the original closed container away from sunlight, excess heat, sparks, flames and other sources of ignition. Avoid skin or eye contact. Avoid breathing vapors. When transferring or using this product, wear proper personal protective equipment. Store and handle as a Combustible Liquid. OTHER PRECAUTIONS/DOT INFORMATION: DOT Proper Shipping Nome: Combustible Liquid n.o.s. (Naphtha), Hazard Class: Combustible Liquid, ID No.: NA1993, Packing Group: Ill. Non-bulk packagings are not regulated as. per 49CFR 173:150 (fl{2J. Product Is classlfled as an OSHA Closs II Combustible Liquid. Sewer disposal Is governed byEPA Regulations (Clean Water Act). which controls local sewer authorities (P01WI. sewer di$posal of spent product may be restricted by discharge limits for specific chemicals set by the POTW and end of pipe chemical.levelsof1he individual user. Check with the local PO1W before·sewer disposal. SECTION 8 -CONTROL MEASURES .5PIRATOR'f·PROTECTION: The use of respiratory protection is advised when con,centrations exceed 1he established exposure limits in SECTION 2. Depending on the airborne concentration, use a .respirator with appropriate organic vapor cartridge (NIOSH approved) . . YEN11LATION: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits in SECTION 2, ad<:1itional gen~ralventilotion or local exhaust systems may be required. PROTECTIVE GLOVES: Wear solvent resistant gloves made of nitrile or butyl n,ibber. EYE PROTECTION: Wear safety glasses with side shields. 011-IER PROlECTIVE CLO'JHIIIG OR EQUIPMINT: . A personal protective :rating of X means you must see your supervisor for guidance. OSHA regulations (29CFR Part 1910, Subpart II require employers to evaluate Personal Protective Equipment requirements in the workplace. WORK/HYGIENIC FiRACTICES: Wash with soap and water after product contact with skin. -. SECTION 9 -DISCLAIMER ,,.,--.-. . ,e information on this MSOS is believed to be accurate. as of the date shown In SECTION 1. Since the use of this product is not under the control of DAY Chemical Pro.ducts Division, it is the user's responsibility fo determine what constitutes safe usage for a particular product. This form may be reproduced in quantities necessary to meet your requirements. 96GvE0909l. l:IIS WdOE=E vOOG l.O oaa {.. _,,-..., ( e:·d 1. \ MATERIAL, SAFETY DATA SHEET Thie Anchor MSOS intcirnation provided on tlti.B s·ita ie .updated on a monthly basis and cOT1plie11 wit.h OSHA' s Razard -Coam!WlicatiOl'l. Standard (CPR l.910. i:zoo) and the Ameri<:an Nati00.al Standards llltltitute {ANSI) Standard ~or ~tarial Safety Data Sheets (1\llfSI z,00.1). Finished Goods Cataiog ?:l;l9 • A-60 (R) ODORL&SS "1a.·PIJRPOSB JWLLBR/B~ WASE Manufacture~ Name ANCEOR Ll'l'HICllMKO, A SDBSIOlARY 01!' PUJI RmlT SECTION l -COMPANY IDENTIFICATION Catalog/ Sub-asselllbly ~untler: 7119 ANCHOR LI7BKBMl(O, A SUBSID:u.RY' 01' FUJI HUNT 50 Uidustrial Loop JJ~rth Orarige Park.,. n 32073 TRAHSPORT~ION QMERGENCISS (24SR Inside US'/Ca~da 800·424·9300 Outside US/Canada 703-527-l8!7 (accepts collect calla) MBOICAL BNB~IES [2tffR) Proear 1177-935-7387 :Nc:5•Bt<BRGENCY BHS Info Gene.ral Info 904-264.-3500 800-354-2300 FOR, I)l!JUS'I'RIAL USE ~LY •••• , .OSB ONLY 1!.B DIRECTSD •••••• 00 NOT TAD INTERNALLY SECTION 2 -COMl?OS.ITION / INFO.RMATIO~ ON INGREDIENTS Ingredient.a A1iphl!.tic Hydro<:~ Al.iphatio Petroleum Dia till.a tea Arooatic Eydroc11rbon CUme:ne Ethyl Ben~ene No::iylphencil Bt::hoxylatea Xy~ene (mu:ed isomeral C"8 ltwnber Wt.I' OBEA PBL (n,g/m3) 64742·88-7 15·301 lOOppnt 64742-,,-a 20-4.ot s 647,2·95·6 30•501 NE 98-82-8 1-51 2461 370 S'?B.t. l00-41-4 0.1-11 l.00 ppm · PBL 901&-4S-9 1-s• NB 1330~20·7 1-s• 434 TIO.; 651 .STBL 95•63•6 15-301 1118 AOOIH (!ag/1113) lOOppm. 5 :w :145; 365 STEL 190 ppRl TWA1 1.25 ppm STBL Ira 435 TlfA; 655 S'!'J!:L Im JlB•NOt Bstabl~sbed ST!L•Sbort Term.Exposure Lilllit C..Ceiling Limits .~2/10/.2001 Pagel 96G-vE0909l. l:H~ ' .. , \. .. ,.,.--.,. ·-.-~ ANCHOR LITHKE.MKO, A SUBSlDIARY OF FUJI HUNT -7119 -A-60(R) ODORLESS ALL-PURPOSE ROLLER/BLAN SECTION 3 -HAZARDS IDENTIFICATION BMERGENqY OVBRVI EW A1lPeara11ce, Clear, cola:r'leaa, J:iquid odor: Mil4 eolvent Avoid contact with ,eyes,. ekin or clothing. Avoid breathing: mi11t or vapor. Do not; awallo'!. Wear che~cal safety gogsiles & neoprene glove• and apron, Wash. tllo::-ougnly atter halldling. Keep contaiDer aloaed when :c.ot in use. trae only with aqeqµate ver.tilation. May produce hazardous gases under fire conditions. During e111ergencies, wear equipment to protect eyes, alti:a aod respiratory tract. DiJce or absorb &pills to keep ra.aterial aod ru:a-off from en~eric.g .sewer o~ wate:n,aye. Use water ·spray to cool conta:zera and disperse vapors. Box m.iy contain r:ultiple contairiers having multipl.e components. co:.aul t all MS:QSa. HMIS: Eealth: 2 NFPA: Health: 2 :Flain..'"13.bility: ::2 Flall\fflB.bHity: ,2 Reactivity, O .Reaotiv.l:ty: 0 Protection: :B Spec. Haz. : l"LAM Hazard Rating: o • Minimal ·1 • Slight 2 * Moderate 3 x $erioua 4 • Severe A = Glove• B • Glovl!a " Goggles C • Gloves, Go99lea " Apxo D • Face Shield, Gl.oves,. Goggles 4 Apron UN NO: NAl.993 QOT Gtr.rOE: SRG Guide 128 .......... 'fl'***'*"*•••****"***,, ........ , • .,.,. .. *""***+*'**•• fl"'*"*'*''**-•***••**+* ......... ff'*** ... "" ..... ... Potential Health BEfecta: Skin: Contact causes irritation. Eyes, Cauae, irritation. Inhalat~on: Irritant to respiratory tract ana nrucoue menihranea. Ingeat;ion: Ingestion of product: may cause nausea and vomiting, Cor.ditions· aggravated by expoaura: · Norie expected except those aaaociated with acute effects. SECTION 4 ~ FIRST AID MEASURES Eye cont.act: Immecilately flush with COOL water for 15 minutes. Call a physician. Skin.contact, physician. J:ngestion: physician. In.bale t.ion: In case of skin contact; wash wit:.~ soap and water tor is minutea. Call a ·In caaa 0£ ingeet1on.; do .aot drinK water. Do not .induce vonu.ting. Call. a lffllll8diately remove victi~ to freall air. cal.l. a physician. SECTIONS -FIRE FIGHTING MEASURES Flar.mable Properties ?lash Point: 105 deg F Autoign.i tion Temperature: H/A. deg F ·sxpl!oaion r..irnits: Lower: NIA vol.:\:: Upper: N/A vol.\',: OSHA Claaa :n (i:::CJ (CC) Not Teat.ed Conibuetibl.e Liquid Ext:ingui•hing Media: Choose extinguishing 111edia suitable for tbe aurrounding material.a, 11uch as water spray, dry chemical, aloOhol foam or carbon dioxide. Unsuitable Bxtinguishii:,g Media: No reatriaticns on media based on knowledge of this material. Fire ·Pighting Inatructiona: , Water spray should be uaed to cool fire e:,tposea containers and/or to dieper11e un•ignited vapors. use NlOSB/MSHA. approved positive pressure self-contained breathing apparatus when any JAterial is involved in a fire. Bvaouate area and fi94t fire frOII\ a safe distance. Call your J.ocal fire 12/10/2001 Page 2 ssc?vEososz. l:IHl WdQE:E lO oaa __J ' ~. (.. ... ..... ~ ANCHOR LI'l'HKEMKO, A SUBSlDIARY·OF ~UJ.I HUNT -'7119 -A-60(R) ODORLESS ALL-PURPOSE ROLLER/BLAN pH Value: voe (lbs/gal): 1:f/0 &.&S (USBPA Method 24) Photocherv.ically Reactive SECTION 10 -STABILITY AND REACTIVITY Hazaxdous Polymerization: Hazardous polymerization WILL NOT occur if product is used And stored as directed. ·Product ia ata.ble /.f _used and stored as directed. Hazardous Decompoaition Products: oxides of Nitrogen; Oxides of carbon; Oxides of. Sulfur Materials and conditions to Avoid: Keep containers and liquida away fron all potential sources of ignition. Keep away frcma e:xcees h<!at. Avoid COlltact with strong oxidizers, istrong ,acids and strong bases. SECTION 11 -TOXICOLOOICAL INFORMATION Product ID.formation LOSO (oral, rat): Acute overexpoeure: ~o Data Availal:lle Skin, eye, mucous mer.bnme a~d respiratory tract irritant. Chronic Overexposure: Prolo~9ed or .repeated expoaure can cause.allergic akin reactio:o, ar.emia aad weakness. R~peated ingeation may oause central neTVous system depreesio~ and kidney damage. Prolonged or repeated akin contact t11ay cause 1ens,l.ti:.u1.tion. Ingredient information: swallowing of Hydroc~rbcm.s can cause 1ung damage. Repeated exposure to ,ffydrocarbona can cause dermatltia. SEGTION 12 -EqOLOG+CAL INFO~TION Ecotoxioity ~ata: No Data Available chemical ~ate Oata: No Data Available SECTION 13 -PISl>OSAL CONSIDERATIONS Haza;tdOus Waste Cbaractertstic: 0001 Recomendaticn: Diepose of contaminated p:roduct ,. emc;,ty containers and materials used in cleaning up·epilla or leal<.8 in a ~armer approved for this 111aterial. Consult appropriate federal, atate and local regulatory agencies to ascertain proper diapoaal procedure&. Discharge of processing effluent to-the ae~er IIIAY require a periuit. DO NOT discharge effluent solution• to septic systems. Material. if spilled, tUy exhibit 11flallllllable• hazardous waste characteristics. SECTION 14 -TRANSPORTATION INFORMATION Ground· Shipping·Info.IT11atioo Proper Shipping Name: Cornbu&tib~e Liquid, N.o,s, (contain& Petrgluem Naphtha) ,Hazard Class: 3 UN/NA Nu.mber, W.1993 Pacxing Group: PG!!? Air (ICAO/IATA) Shipping Information Proper Shipping Name: Plafll'Mble tiguid, N.6'.s. (Contains Petroleum Naphthas) Hazard C~ass: 3.3 llN No: llN:J.993 12/10/2001 Page 4 96Gi,E0909l. l::!I s . ... ANCHOR LITHJCEMKO, A SUBSIDIARY OF FUJI HCJ:NT -7ll.9 -A-60(R) ODORLESS ALL-PURPOSE ROLLER/BLAN ~ Packing Gro\lp: l?GIU ... ----.... .-·· Subsidiary Riak: :None UN/poT Labels Needed: Coml)uatibl e I FlillT1!1litlle Inte,:cnational Maritime Organizatio4 (IMO) Addit:i.cmal. .Shipping ClaH: IMOG Coile: IMDC 334.5 :mdt. Code: Amdt.2?•9-l. HTS Code: HTSi13707.90.6000.8 Product is labeled ir. aqcordanae witb. us D.O.T. H CPR. Further in.fonution, Please cali (9U) ~o-4-3'500 f:>r fu.rtl:ie:r D·.O.T. information, SECTION 15 -REGULATORY INFORMATION '**Note! The i:::ig:n:cUent ic.formatic;,n l,i11ted :i.n thi11 aection is p.ovided fo:r reporting requirementa as dictated by·USBPA, state and local regulation. If -iogredie:nt i's listed in th.is sect.ion but not i::l s .. ction 2, then the COJlccntration of this :i.ogredient is below de minumis (J.eas than 0.1t): ·U.S. FEDERAL R!iGUIATIO.'lS: 313 • SARA Title III Section 313 (-lO CFR 372 --Toxic Reieaee Inventory) 355 SARA Title IXI Section 302 (40 c~ 35S Eittreiaely H&.zardou.s SUbatanceJ 302 • SARA Title III Section 304 (40 CFR 302 --.Eaza:rdoue .Su.b8tance List) CffA • clean Water Act 'Priority Pollutants List · CM • Clean Air Act lS90 Hazarclou. Air Contalllinanta HAP "' Clean Air Act -HON Rule • HAPs -Ingrediente CAS Number 3:,3 355 302 C'.fA CAA Alipl;latic Hydrocarbon 647-4.2-88-7 N N N N N Alipbat!c Petrolem 647'62-47-8 N N l1 N N Distillate& Aromatic Hydrocarbon 64?42-95-6 N lit N N N cumens .98·82•8 y N y N y Ethyl Benzene 100-41-4 y ]ll y y '{ Nony1ph_eno1 Ethoxylatea 9016-45-9 N .N lf N 'I Xyle:ce (mixed· isomere) 1330-20-7· 'i ·N y N y l,2,4•Trimethylbenzene !iS-63•6· y N .N N lf TSCA l.:I (bl Export N"otification •••None required~••~ TOXICITY INFORMATION: IRCl • IA.RC Group· 1 Bulll&?I Carcinogens tist IRC2 • IARC Group 2 Bun>an carcinogens ti.st ( limited :human oat a) IRC3 • IARC Group'2B Human carcinogens List (sufficient animal data) :N'l'P .• NTP l':'.nown carei:c.oge:ns Liec OSHA • OSHA. Known carcinogene Liat Ingredients CAS Number IRCl IRC2 IRC3 NTP OSF.A AlipAatic Hy~ocarbon 64742-88-7 N N N N N Aliphatic Petroleum 6,1,2-n-e lf N N 'N ~ Distillates Aromatic Eydroca~bo::l 64742-95•6 :N N N N 1' Cumene 98-82-8 N N N N N Ethyl. Benzene 1oq-u--1 :N N y. N N Nonylphenol Ethoxylatea 901G-45·9 ?I N N N N Xylene (raixed i-ao~ra) 1330-20-7 N N N N N 1,2,4-Trimethylber.2ene 95·63·-6 N N N N N STATB REGULATIOliS: KAP N }I N y y y y N FL• Florida Raz&rd::,us Substance List MI ,. Michigan Critical Materials Lill't NJ• New Jersey Right-To-Know List MA• Maasachusetta Right-7o-Know List MN• Minnesota Eazardoua subata:oce List PA• Pennsylv.mia !l.igbt-To-know List 12/10/2001 Page 5 9SZv€0909l. ', . .,...--.... ( t.. ·d ·---~ ANCHOR LITHKEMKO,. A SUBSIDIARY OF FUJI HONT -7119 -A-GO(R) ODORLESS ALL-P.URPOSE ROLLER/BLAN Iilgredient.a CAS Number PA NJ' MN MI MA. E'L ·JUiphatic Hydrocarbon 64742-88--7 ti :N, N N N N A1iphatic Petroleum G4.742--17·8 N N N N N N DietiJ.latea Aromatic Hydrocarbon G~'T42•95-6 N N N N N N cumene .98·82-8 y y y N y y Btl:iyi. 13en:z:ec.e 100-41-4 y y y N y y Noc.ylph:enol Ethoxylatee 9016-45:.9 N N ~ I( N N Xylene (miMd ie0tner11) 1330-20•7 y l' y y y y 1.2,,-Trimethylbe=ene 95-lp-6' y 'i N N y N The follo.,j,ng information is required by the State of California'• Safe Drink- ing Water and Toxic Enforceraent Act of 1986 er Proposition 65. This regulation does not address cli 11\inimua levels; therefore, even trace anounta of chemicals included on the~e lists 111U•t be noted with.the •safe Harbor• wording. WARNING: Enown to t:he State of Cali:tornia to cause cancer, ·CAB N!JM!IIIR CHEMICAL NA.MB 75-07-O 7l.-43-2 123-91.-l 75-.21-8 50•00-0 ACBTALOSl!YO:S: BBNZBNB i, .fi--OIOXAN!i: E'l'Hl{LBNE OXIDE FORMALDlmYDE' (GAS) WAlOIING: Kno1or.1 to the State of California to cause dbelopmental toxicity, CAS NIJMBER CHIIMICAl., NAME 71-43-2 BBNZBNB 108-88-3 TOt.Ulllm WARNING: K:zlo..n to the Seate of California to cause female reproductive effects CAS NUMBER CHEMICAL lil'AMS: 75-21•8 ETH'a.!:NB OXIOB WARNING: :Know:. to the State of California to cau11e 111ale :reproductive effect.•, CAB NUMBER Clm1'!]:CAJ., NAME 71-43•2 . BENZENE SECTION 16 -omER INFORMATION Thie informa.tio;i. ie provided withoU:t warranty, 'I'he inf=mation ie believed to he·correct. Thia informat~on should·be used to make an independent detertt1inatiqn of the methods to aafeguard workere end the MViromient. 12/10/;!001 Page 6 962-vEOSOSL l:I I~ ..._• . ...--..... MATERIAL SA.FET'.i DATA SHEET Tbe Jmohor MSOS infoxrn<lticm provided on this site 1a updated on a monthiy ba.s1B and COll1Pl1ee with OsaA's Mazard· Communicati:on Sta::idard tCJ'll. 1910.1200) aod the Arleriaan NatiOllal Staadarda Institute (1'RSI) Standard for Material. Safety pata Sheets {ANSI Z4QO.l). Finished Goods Catalog 2964 -EMBRALO (R) JRZ ACID J!OtnnAIR SOL~ •• Manufacturer Name I ANCH<Ja LITHDHJ:0, A SUBSIDIARY OF FtJ~ BUNT SECT~ON l -COMPANY IDENTIFICATION catalog / sub-a.sumi:ily Number: 2·siu Al!CHOR.. L:t'I'EIJ!Mm, A SUBSIDIAltY 07 FUJI RtlllT 50 rnd.strial Loop North Orange Park, !L J2o?3 TRAHSPORT~Tlotf BMB:RGRNCIB,9 l2¼liR Imoide OS/Canada' eoo-i:i-t-930O Outside OS/Canada 703-527-3987 (accept& collect calla) MSDiCAt, BlmRGENClBS (2'4BR) Proaar ~-:BKERGl!ZifCY BRB Info oe:aeral InfO 877-.935-7387 904•264-3500 aoo-354-23O0 l'OR INOUSTRIAL us~ om,y ..•... trSB ONLY AS D~:aBm'BD •••••• DO 00'1' ·TAICB INTBRNALL'i SECTION 2 -COMPOSITION/ INFORMATION ON INGREDIENTS :i;ngredie_nta Acetic: .Acid carboxylic Acids Alllmonium Jfitr•te <:arl>Oxylic acid Derivative Butyl Cellotolve Carboxylic: Acids Gum Arabic Propylene Glycol. Sul:latituted C,iu-bomonocycle su.ccinic .,_cid Water ~~-1,-1 i-st OSBA pm, (mg/113) :25 1:14-04·9 . o.s-1, st s 6484•52-2 l•St NE TSRN 06-083!i o.s-1. st NE •331•5020 1i1-7&-2 s-~oa TSRN 06-0836 1•51 •331-S031 900C-01-5 l•5% 57•55•6 7-kSI TS:RJf 06-1•5% 1225789-5006 110-1s-6 1-s~ 7732•18-S SJ-7Ot 240 skin NE NB N2 NB ACGIH (119/m3l 25 '.!WA; 37 STBL 5 :ME NE 96.6 akin m: Ni•Not Eeta.bliahed STi~-Short Term Exposure ~imit C•Ceiling Lim1ta 01/18/2002 Pagel ssavEosost. l::IHl Wdti:;:i:; vOOa LO oaa L • ANCHOR LITI!l(EMKO, A SUBSIDIARY OF FUJI HUNT -2~64 -EMERALD(R) JRZ ACID FOUNTAIN SOLUTION ·SECTION 3 -HAZARDS :;i:DEN'l'IFICATION BM!mGBNCY OVBRV!BH • •******* ....................... +• ••••** ................... * ... '*****'***"*~ **** .. ***** , ....... * .. *** Appearance: Cl.ear, green, aqueous liquid Odor: Mild odor ·Avoid contact with eyes, ekin or cl.othing. Avoid breathing niat or vapor. Do not swallow. Wear oheniclt.l. safety goggle• & neoprene glovea and aproo. 'liesh _tboroughl.y after handling. Keep ce>ntailler <:1l011ed when not in use. U11e only with adequate ventilation. May produce hazardous gases Ullder C'ir.e c<;111ditione. Duri129 emergencies, wear equipment to protect eyes, skin and respiratory tract. Dike or. ab111orb spill.a, to keep rnater.tal alld ·run-off from ectering sewer or waterways. Use water spray to cool co.~talnera acd disperse vapors. Box may contain nultiple containers having nnµtiple components. Consult all MSDSa. mlIS, NEPA: Health, 2 Health: 2 Flammability, l l'lammabil.ity: l Rea.ctivity: o Reactivity: o Prot.ection: B Spec. Haz. : None Hezard Rating: 0 • Minimal l • Slight 2 • Moderate 3 • Seriollll 4 • Severe A • Gloves B • Gloves & Goggles C • Gloves, Goggles S. .Ap:ro D 2 Face Shield, Gloves, Goggles , Apron ON ·No: None Dor GDi:DE: ERG Guide 50 *'**' ... *'***•••••••••*•••••••• .................... *_ ................... *''*****• ... , ••• *** •+•*'* ••+ Potential Health Effects: Skin: Co~tact cau.sea irritation. Eyes: Causes irritatio.~. Inhalation, Irrita.~t· to respiratory tract and mucous membran.es. Ingestion: Inge•tion of product may cause nausea and vODiting. Conditions aggrava-ted by exposure: ' Allergic reaction to gum arabic may cause respiratory distress and ,sensitivity. Carc~ogenieity: IARC: N NTP: N OSHA: N SECTION 4 -FJRST AID MEASURE$ Bye Contact: Innnediately flush with COOL water for 1s·minutes. Call a physician. S~in co:1tac:t1 pbyaicia.n. Ingestion: In case of s~in contact; wash with 11oap tu;d -water for 15 mi.lutes. Call a Inhaiat.ion: rn case of ingestion; in.dµce ·v=itin9_ upon niedica1 advice. call a physician. Imnediately remove victim to fresh air. Call a phyaici~n. SBcrION 5 -Fl::RB FIGH~ING MRASURE:S Plallxtlable Properties ?lash ·point.: Autoignition Tempe:cature: Bxplosion Limite: Lower: Vpper: >200 N/A. N/A. 'R/A. Deg F deg F vol.t: ·vol.t: TCC (CC) Not. Tested ~xtii:gui1hing Media: Choose extinguishing inedia suitable for the suri:ounding materials, such as water spray, dry ohesnical, aloohol foam or carbon dioxide. ·Uneuitable Ebtt.in9ui1bing Y.edia, No reatrictian1 on media ba.1ed on knowledge of this. ~terial.. ?ire Fighting Instructions, Water spray should be used to cool fire exposed containers and to disperse om-ignited va.pors. U•c NIOSH/HSEA e.pprovcd. positive pre11urc ael:-contai:led breathing, apparatua when 111&terial h•• ignited or becomee invol.ved in a fi~e. Try to remove material containers from fire area 1£ oan be acc9111plish.ed without risk to persollllel. Ol/18/2002 Page 2 9SGvE"0909l WdlE=E vOOG LO oaa _,-... (' ANCUOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT -2964 -EMERALD(R) JRZ ACID FOUNTAIN SOLUTION Evacuate area_ and fight fire f:rO!'II, a safe di•tance. Call your local fire department. ·wear positive preaaure, "breatb.ing apparatus and protect.eyes And skin. Use water to cool ·fi.i:e-e.xpoaecl containerc, to p;,::otect peraac.nel and to disperse vapors ;uid spills. Fire 'lliedia run~off <:a::i. damage the envi1'0Z:ll'ellt;. Dike ac.d collect n>edia u•ed to fight fire. SECTION 6 -AC¢IDBNTAL RELEASE MEASURES Small Spille: For atDall incidental spills and leaks wear chemical aafety goggle•, and neoprene gloves and apro~ or coveralls. Isolate area of spill by diking. Stop eourc;e of leak. Add dry ab•or:bent. ci.,an up and P,ll!'"' in ac. approved o.o.T. <:ontainer and aeal. Wash all conta-mina.ted clothing before reuse, and discard conta.mit!Altecl leather shoes. Large Spille: For larger apille requir:lngeme.rgency responge, neoprene boots ac.d respiratory protection may also be requir~d. Foliow OSHA regulations and mosa recCll[l!lendations for respirator use (29 CFR 1910,134 and NIOSI! Pub. 87-108) an emergency reeponee (see 29 en 1910.120). Isolate area of apill by diking. St:op aou:rce of leak. Add dry al)sorbent. Clean up and plaoe in an approved D.o.T. contai~er and aeal. Ka~h all contami::.ated clothing befi>re reuse, and dilc~rd contamL-iated leather shoes. Call t!le emergency telephone number sbown on tbe front or this uheet. SECTION 7 -HANDLING/ STb~GE ll'.andli:ng-: Avoid oont.;:r,ct with. eye;s, skln or clothing. Avoid breatru.ng mist or vapor. Do· not awallow. ·Wear chemical safety goggiee and neoprene glavee and apron. Waah thorougbly after handling. Keep container closed when not in use. Use only-with adequate ventilatiOD. Storge, Store in a cool, dry, well-ventilate;d area away froi:n all aourcea of ignition. ieep containe;ra closed when not in use. SECTION 8 -EXPOSURE CONTROL AND PERSONAL PROTECTION \l'entilaticn: Good general ventilation ahould be aufficient for moet processing operations. Vent work area to enaure aixborna concentrat;:icna a~ below tile current occupational .expoa11re limita. Ten 110). -or more ro0111 air cb.angea per hour containing a ninimun of 151 fresh ai~ will ·meet these requirementa. Consult .AS~ 62-1,s9 for further :requirements. P,e:rsonal Prot~ctive Bquipment Respi.i:atory Protection, If used u,nder normal operating conditions and with adequate ve~tilation, :respiratory protection ia not regu.ired. However-, refer to OSHA 29 CFR 1510. l ... Skin Protection: ,Bye Protection, Cheonioal reaiatant glove& Chemical safety goggles SECTION 9 -PHY~ICAL ANO CHEMICAL PROPERTIES Appea:r.acce, Clear, green, Odor, Mild odor Change in Physical State, Boiling PPint;: >100 -Melting Point: N/D Specific Gravity, 1.07 Vapour l?reeaw:e, -1·7 Viac0aity, N/A ·solul>ilit:y in Water: lOOt 01/18/2002 .Page 3 aqueous liquid deg C deg·F SSZ:vEOSOSl Wdte:e vOOG lO oea ' ' L . -~·" I MATERIAL SAFETY DATA SHEET The Anchor MSI>S i~omatio::i provided on chis Git:e is u~ted 0ll a ,o,ntbly basi• and cOIT\pliea with OSl:IA'• Hazard COll!ll.Uµe&tio:i. Standard ICFR 1910.1200) -nd the American National Statldaroa Instituce (ANSI) standard t= ~.at•rial Safety Data Sheets !ANSI z,00.1). Finished Goods Catalog 708 • INKOTB SP~ A!ITI-SXINNDIG AGEi.ff Manufacturer Name 1.NCliOll Ll'l'BKIMKO, A SUBSIDIARY OF FUJI MONT S.BCTION 1 -COMPANY IDlsN':t'IFICATION Catal09. / Sub•asser:ibly ~unt>er:· 7438 ANCHOR LITEX!i:MIOl,. A SOJISIDURX OP PIJJI lltm'r 50 Induscr.l.al Loop Horth Ozaog,e Park, PL 3.2073 'I'RANSPCmTATION BMERGBIJCI:SS (2413:R X~&ide OS/C.atlada 800-424-9300 Outside US/Canada 703-527·3887 (accept• collect calls) i-.&OICAI.. m-!BRGEllCIES (24HR) Prosar NO:i,f-EMER~Ell'CY W!S Info Ge!lenl Info 877-935-7387 90t-.26t-3500 800•35(-!:1300 pcm UlDUSTRIAL USE gNl,Y •••••• OSI!: ONLY 7IS ·oIREC'l'SD •••••• 00 NOT TAXS INTE!WALLY S&CTION 2 • COMPO~ITlON / INFORMATION ON INGREDIENTS Ingredient:& Aliphatic ~ydr0<lai'1:Xln ,Bucylated lfydroxtoluene Aliphatic erdrocarbon .2,2,4~Trimetbyl-1,3· Pentanediol Dii•obutyrate C1.S lfwllber 604.2-88-7 UB-37--o· 617'.'2-53-6 6846-50•0 Wt . .t 30-50% J,-5,t 30-50% .10-201 OSKA PBL (mg/1'113) lOOpp,n l,O NI? NS ACGIH 11119/ffll) 100ppm 10 HE NB NB•Hot Bst:abli~ed S'l'lilt,•Short Ten. Bxposure Limit C•Ceilillg Limits SECl'ION 3 -HAZARDS IDENTIFICATION EMBRGBNC't OVBRVIEW ••**~ ....... .,, ................ *****"*'*"*•** ................................. ~ ....... -... ·*••+*****'*' Appearance: Clear·, color lea a, 11.quid ·Odor: Mil.d odor Avoid contact witb eyea, i:k..i.n or clothi~-Avoid br.eathlng llli.llt o't' vapor. Do 1·1 · u I not awa ov. Uear d oa~ safety goggles & cbetllical ratistant glovee. Wash thoroughly after handling. Ji:eep 00.lltainer cl.011ed w))ep Jlat in use. t111e onl.y 01/18/2002 Pagel SSZ-vEOSOSl l:lHl ,,.,.-..._ l • d ,ANCHOR LITHKEMJCO, A SUBSIDIARY O? FUJI HUNT -2964 -EMBRALD(R) JRZ ACID FOUNTAIN SOLUTION pll Value: voe llb11/~11.l): 3 .a, l..8ll (DSBPA Metbod, 24) Non-PbotoC:.=ioally Reac,tive SECTION 10 -STABILITY Am) REACTIVITY Hazardous Poly,aerization: Hazardous polymerizatioII MILL NOT occur i-f product is used and .scored as directed. Product is stable if uaed and stored as directed. Hazarqoua Decompogition Products: oxides of Sulfur; oxide• of carbo:11 0..:1.de• of Nitrogen, Almlonia Materials and Conditione·to Avoid, This product CO."ltai;:ia ~ am=ia compound,, Co not allow thi11 aolutiOll to come in_ coc.tact with household or industrial ble!Jcbea (Sodiwn HypQOhlorite). Nixing of these cbe11\icala can result in the release of bazardou.a or toxic gaaea. Inhalation of tbeae gaaes may cause severe respiratory irritation. Kc:ep contai.r.era ar.d liquids away fro,u all potec.tial source's of ignition. ~ep away from excess heat. Avoid contact with strong oxidi:.era, strong acids a:od stri:ing l:laaea. SECTION 11 -TOiict>LOGICA,L INFO~TlON Product Information LDSO (oral, rat): No Cata Availal:>le Acute overexposure: Bk.in, eye, 11\ucou11 membrane and respirato~y tract irritant • . Chronic OVere:x:posure: Prolonged or repeated akin contact ~y cauae allergic reaotion and de:i:matitia. Ingredient inforinatia::i: Chronic overexposure to Butyl Celiosolve in high concentrations has caused anemia, liver and blood abn=alitiea, and kiooey and lung damage in laboratory animals; nay eauae materna1 toxicity. SECTION 12 -ECOLOGic:AL INFORMATION Ecotoxicity Data; No Data Available, Chemical Fate Cata: No Data Available SECTION 13 -DISPOSAL CONSIDERATIONS ~a:ardoua Waste Characteristic: ll'one Reooltlll1endatio:n, D~spoee of contanunated product, empty containers and materials ~aed ill clca,;iin~ up spille or leaks in a manner approved for this JMtcrial. consult appropriate federal,, state a=i.d local regulatory agenciea to ascertain proper disposal procedures. Discharge o~ processing effluent to the ~ewer111ay require a pe%1\\it_ DO NOT discha:cge effluent aoluticma to sept.io systems. SECTION 14 -TRANSPORTATION l~FORMATION G~ound Shipping XnfoJ:T11a~l= Proper Shipping Nall'LC: Cllemicals, :N.O.I., Not D.O.T.' regulated. Kazard Class: None UN/NA Number: Noc.e Packing Group: None Air (ICAO/IATA) Shipping Informai:ion. Proper .'!hipping Name: C!l:lemicaJ,a, N_,O.I.., Not_D,O,'l'. ::-egulated. Hazard Class: None tm_No: N::>ne D1/18/2002 Page 4 96c?i,E0909l l:II~ '. • f ANCHOR LITHKEMKO, A SUBSIDIARY OF .FUJI HUNT., .2.964 -EMERAW(R) JR.Z ACID FOUNTAIN SOLUTION ~ Packic.g Groµp: No,:ie ,.-.. ,..---... Subsidiary Risk: None inf/DOT li~ela Needed: None I~tei:natio::.~l Y,aritir.ie O~nization (IMO) Aclditiooal Shippi,:ig Class: IHDG Code: Not Applicable Amdt. Cede: Alnd~. N/A ETS ·code: Not Applicable Product is labeled in accordance with US· D.O.T. O CPR, Further information: Pieaae call (.90-l) 264.-"3500 for ·further D.O.T. infoxmat,ior.. SECTION 15 -REGULATORY INFORMATIQN **Note: The iogredient i:c.forlll&tion .liated ia thia section ia provided for reporting r"quirements aa dictated by US.EPA, state and local regulation. If ingredient ~s listed ~n this section but oot in section 2, then the concentration of thia ingredient ia below de m.i:numis (less than O.lt). U.S. PEDBRAL REGULATIONS: 313 • SARA Title III Section 313 c,o CFR 372 3·55 • SARA Title III Section 302 (4,0 CF1t 3SS 302 • SARA Title IU Section 30t '(,i;O CF!t 302 CtUt. • Clean lfater Act ·P.rio:rity Pollutari.tll List To,d:c ~eleaae Inventory)· Extremely Hazardous Subatance) Hazardous Substar.ce -~ist) CAA = CleaA Air Act 1990 F.az:ud011s Aiz;-cont1111inBnt• HAl•~ Clean Air Act -fiON Rule -HA.Pa Ingredients CIUl Number 313 355 Acetic Ac:l,d 64-19•7 N N Carboxylic Acids· 12~· 04-9 N N A'rrrnoniun Nitrate Gu~-s2-::i y y Carboxylic acid Derivative TSRN Ol!i-0836 N N -331-5020 Butyl Cellosolve lll• 76-:2 y N Cart?oxylic .Acide TSRN 06-0836 N N -331-5031 Gum-Arabic 9000•01•5 N' N Propylene Glycol S?-55-6 N lf Subatituted Carbomonocyale TSRN 06-N N 1225789-5004 Succ_inic Acid 110-15-6 l)1 N lfater 7732-18-S N N TSCA 12 (b) Export Notification c.-.s HOMBa CHliHl:CAL NAM'E 107-.21-1 ETHYLENE GI.YCOI. 7439-92•1 LBAO TOXICITY INFOR1"J\~ION: IRCl ~ ~ARC Group 1 Hwaan Carcinogens Liat 302 CWA CAA y H N 'I N N y lf N N N N r N y N N N M N N N N .N N N N N N N N .N N IRC2 • IARC Group 2 l!W:lan Carcinogens List {limited human data) I:R.C3,. IARC Group 2B Human carcinogens List (sµffieient animal data} NTf • NTP Kr.own Carcinogens List OSHA. OS.Im IC:lo~n C~cinogens Lilt Ingred.1.ente CAS·?lUlllber IRCl IRC2 I:R.C3 NTP OSHA Acetic Acid 64-19-? .N lf N N N carboxylic Acids i:1-i-04-9 ll' .if N N N Ammonium Nitrate 6il84•S:1·2 l'I N N N N Ca:rp:,,cylic acid Deriv•tive TSIUI 06•0836 N N N M N -331-5020 Butyl Celloaolve u::.-Tt-2 N N N M N ca~boxylic Acida TS!m 06•0836' ~ N N M N 01/18/2002 Page 5 sszte:ososL. HAP N N N N y N N .N N N N WdE:E=E i-OOZ lO oaa _,,--..._ ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI .HUNT -2964 -EMBRALD{R) JRZ ACID FOUNTAIN SOLUTION -331-5031 Gun Arabic 9000·.Ql,-S N N N N N Propylene Glycol 57-55-6 N N N-N N Substituted c:arboio~ooycle TS:RN 06-N N H N N ::ns1s9-soo, s11ecbiic: Acid 110-15·6 N 211 N N N Water 7?32-18•5 ·N N 1f N -N ST.!l.1E Rl!GOLA'l'IONS: PL " Florida suardous sll.batance Liat. MA • Maaeaohusett1 ~ight•To-iecow List 11I • Micbiga:ri critical Materials List. MN .. Minnesota Ha2iardou& Sull11tance Liat NJ• New Jersey :Right·To•J:now Liat PA• Pen.~sylva:nia Righl:-To·:Know List Il'l9r1?diei:J.ts CAS Number PA NJ MN MI MA l't. Acetic: Acid 64-19-7 y y y N y y Carboxyl-ic Acids. 12•-..o•-9 y y y N 'Y N l;tmlonium Nitrate 64E4--S2-2 y y y N y y carboxylic acid Derivative TSRH 06•0836 N N ?I N N lf -331-5020 Butyl cellosolve lll-76-2 y y '! N y y Carboxylic Acid& TSRN' 06-0836 ·N N N N N N -331•5031 GW11·Arabic 90·00-01-5 N 'l ,II! N N N Propy.lene Glycol 57-55·6 y N 't N :ti N Substituted CarbolllO:!loc::YCle TSRl\1 06-N N N N N :N l.225769-5004 Suecinic -Acid l.10•1:S·E l! N N N N N Waterc 7?32-18-5 N N N N u N The follo~ing inforT11atio* is req11-ired hy ·the State of California's Safe Drink- ing Water and Tox~c Enforcement Act of 1986 or Proposition 65. Thie regulaticxn does not addreaa di minimue levels1 therefore, even trace amounts of chel'llicals included on these liet• ltlUSt be noted with the •safe Harbor• wording. WAJillDlG: Kc.ow to the State of t:alit:orni.a to cause cimcer: C1IS NOMBER CEEMICAI. NNI.B 7-l-39·'92-1 I,EAl) WARNil!C: ICnow::l to the State of california to cause developmental to~icity: CAS Nll'MBBR CHB14ICAL NAME 7439-92~1 I,EAIJ 7439-.97-6 WARNING: :K:lown to the State of Califqrnia to cause female reproduc:tive effects CAB NtlM!IKR CHEl'!ICAL NAME 7439-92~1 LEAD WARNINQ: tcnown to the State of California. to cause male reproductive effects: CAS NlJMIIER CHrMICAL HAMB 7439~92-1 LBAO SECTION 16 -OTHER INFORMATION Thie information is provided without warranty. The information is believed to be co·rrect. 'l'hi11 information should be used to make e.n in.dependent determination of the metbode to safeguard workers and the environment. Page 6- 96Zv€0909l ti I~ Wd88=E vOOZ lO oaa ,,--.,,, .. ~ •... .. ...... 1 MATERIAL SAFETY DATA SHEET The Anchor MSDB i~pmation provided on thia sit:e is updated on a 110.0.thly basis and complies wit.h OSIIA's ffazard CtllnlaUnication Standard ,(CFR 1910.1200) and the American National Standards Instituee (AlfSI) Standard for Material Safety Data Sheets (WI Z•00.1). rinished Goods Catalog 7 4 3 8 -INKOTI S P1UIY lllrl'I-SKtllllfmG A.GE!lt' Manufacturer Name 1'NCROR L·ITHKEMI«l, A SUBSIDIARY OF FUJI HCJNT SECTION 1 -COMPANY IDENTIFICATION Catalog / SUb-asaembly Ru!'llber: 7438 ANCltOR. L!Tlil;2MIW, A SUBSIDIARY OF PDJI HUNr 50 Industrial Loop Rorth orat1ge Park, PL 32073 TRANBPORTATlON IU!ERGEHCI£S (l4.ER Inside ,US/Canada 800·42•-9300 Outside US/Canada 703-527-3887 ·(accepts collect call.s) MEOXCAL IOOmGBIJCI£S C24l!R) P.:rcisa:t N<'.11!1-~ENCY EHS Info Gene:ral Info 8?7-935-7387 90,-:11;,4,-ssoo 800-354.-2300 FOR !:NDUSTRIAL US8 CSIL'i .••••• 11S1! ONLY, AS DIRECTS:I) •••••. DO ~ TNtB INTBRBALLY SECTION 2 -COMPOSITION/ INFORMATION ON INGREDIENTS Ing:redienta Aliphatic Hydrocarbon Butylated Hydroxtoluene AliM&t:!.c Hydrocarbon ·2,2,4~Trimethyl-l, 3- l>entanedio~ Diiaobu.tyrate CM N\u'aber 64:742-811-'7 128-37-0 64.742-53-t; 68-l6-50-0 \ft.I' OSHA PBL (rcq/m3) 30-501 lOOppm 1-st 10 30-~01 )IE 10-201; NB ACGIB (mg/m3) lOOppIII le) NE !JR Ni•Not Bsta~liahed STBL-Sbert· Tex,n,&:xpoaure Limit c.ceiling Lilllits SECTION 3 -BAZARDS IDENTIFICATION BMBRGElilCY ,OV8ltVIE11 ................... *" '**•• .. ******"'*'*****• *** ,, •• ., ••• tr••**•**" ............ -..... * .... ~·· t-+• ..... . -Appearaoce: Clear, co~orless, liquid odor, Mi l.d odor Avoid ·oontact w:l:th eye1>, skin or clothing. Avoid breath:i.ng ll'li6t or vapor. ·Do not swallow. Wear chemical aafety goggles~ chemical reaietant gloves. Wash t;boroug!:lly after handling. !:eep ooi:itainer cloaed vhen not in uee. U•e only 01/18/2002 Page 1 96ZvE09O9l. ~--.. ANCHOR LlTHKEMKO, A SUBSIDIARY OF FIJJI HUNT -7438 -·rNKOTE SPRAY ANTI-SKINNING AGENT with adequate v~ntilation. May produce ha~ardous gases under fire oonditiona. Ou.ring emergenciea, ~ar .equipment to protect eyei!, akin and reapiratoxy tract. Dike or abaorti spills to keep material a::id nm-oft from entering sewer or waterways. Use ~ater spray to coo1 containers and disperse vapors. Cor,wlt MSDS for addito:iaJ. information .• IDl;IS: Healtl:l:. i NFPA: Health: 1 Flam.ability: 2 Flananab.i:lity: 2 Reactivity: O React-iv:l.ty: O Protection: B spec. H~.: 00MB Ba~ard Rating: o. • MinimAl 1 • Sligbt 2 • Moderate 3 • Serious 4 ~ seveJ:e A = Gloves J3 • Glove• &. Goggles C • Glc,v.ea, Go~lea .. Apro o : Face Sllield,. Glove&, Goggles &. Apron 1 UN NO: 00'1' GUIDB: 'BRG Guide 128 ·······~······~•+••···········~··*k····················~··•*********~•*'**•*• Potential Eealth i!facts, Skin: Contact causes irritation. Eyes: Causes irritation. Inhalation: Irritant to reapirato:ry tract and mucow, membranes. Ingestion: Ingestion of product 111ay cause nausea and v0111~ti.:.g. Conditions.aggravated by exposure, None expected. except those associated with ~cute effects: SECTION 4 -FIRST AID MEASURES Bye Co:1tact, Skln Contact: physician. icgeation: phys:!,aian. inhalation: l'lll!llediately flu.sh with coo~_water tor is minutes. call a pbysician. ~n case of skin contact, waeh with 11oap and water ·for 15 ndnutea. Call a In case of ingestion; do not ch:-ink. water. oo not. induce vomiting. Call a I1M1ediate1y ==ve·victim to fresh ai~. Call~ physician. SECTION 5-' FIRE FIGHTING MEA.SURBS Flammable Properties Fl..aah Point,, Autoignition Temperature: Explosion L~mit11: Lower: Opper: Extinguishing Hedia: 159 deg P II/A deg l' l'l/A vol.'\: II/A vol.I: (TCC) (CC) Not Tested osa. ClaH IIIA Combustible Liquid Choose extinguis:o.ing media su~table for the surrounding -teriala, aucb as water apray., dry chemical, alcohol .Coaro. or carbon dioxide. Unsuitable Extinguishing Media, No res.tric;,tions on ni.eclia based on kno'llledge of t~is material. Fire Fighting rnatxuctions, Water spray should be used to cool fize exposed containers an.cl to diaperse un-ignited vapors. Use NIOSE/MSHA approved poait~ve preasure self-contai:.ed breathing apparatus when material baa· ignited or beQcmes involved in a fire. Try to remove materiai containers from fixe area if can be ~ccomplll!hed without risk. to· personnel. Evacuate ~rea and fight Ure frO'lll a safe distance. Ca11 yi;,ur local, tire departrne.nt. Wear poeitive preeaure, breathing apparatus and protect: eyes and akin. U8e water to cool fire-exposed ccntain:era, to ~rotect personnel and to disperse vapors and spills. Fire 111e:lia run-off car: damage the environment. D:ike and collect media used t;o fight fire. SECTION 6 -ACCIDENTAL :RRLEASE MEASURES Small Spills: 01/18/2002 Page 2 9SZvE0909l t!Hl ,• --_:~CHOR LITHKEMKO, A -SUBSIDIARY OF F'JJI HUNT -7438 -INKOTE SPRAY ANTI-SKINNING AGBNT For amall incidental spills and leaks wear oh.emical safety gogglea, and neoprene gloves and a?ron or coveralls. Isolate area.of -spill by diking. stop 110urce of l:ealt. Add dry absorbent, ·Clea.n up and· place 'in an approved o.o:T. container and. aeal. Waah all conte.minated clot'.!:lill!J before reuse, and discard contami.~ated leather ahoea. i.uge Sp.ills: For larger spills requiring emexgency reapona~, neop=e boots and respiratory protection may also be req.iired. :Pellow OSKA regulations a::id NIOSH· reconwnendations for respirator uae (29 CPR 1910.134· and,NIOSH Pub. !?·108) an emergency reepon,e (see 29 CFR l!lO .12·0) ·• Isolate area of ,spill by diking. Stop· source of leak. :Add dry absorbent-. Clea:n up and place in an approved D.O,'l', container and aeal. Wash all cootaminat:ed clothing before reuae, and diacard oonta~inated leather aboea. Call the C!r.)ergency telepbone number shown on the front oft~• aheet. SECTION 7 -HANDLING/ STORAGB Ha;,~ing: Avoid contact with eye1, akin or clothing. Avoid breatbL~g miat·or vapor. Do not awall.0'1!, Wear chemical aafety gogglea and neop.rene gloves and ap:z:on. Wasb thoroughly after handling, Jteep contai:nex-cl.011ed when not in use. Uae only with adequate ventilation. Storge: score in a cool, dry, well•ventilated area a.way from all sources of i9nition. Keep containers eloeed when not in use. SEC'I:ION 8 -BXPOSURE CONTROL AND PERSONAL PROTECTION Ventilation, Good general ventilation ahould be sufficient for most processing operationa. Vent work area to enwre airborne concentrations are below the current occupational exposure limi.t.s. Ten llO) o:r 1110re room air cbanges per hour ,,.....__ containing a rninimum o.f 1st fresh air will meet these requirements., Consult ABHRAS 62-1989 for ·further requ.irementa. P~rsonal Protective Equipment Respiratory Protectioa: If used under il.Ormal operating conditions and witb. adequate ventilation, respiratory p:rr;,tection ia not required. However, refer to OSHA 2.9 CFR 1910,1 "· Skin Protection: ifye Prot,ection: Chemical re1iat~t gloves ·Chemical safety goggles SECTION 9 -PHYSICAL AND CHEMICAL PROPSRTIES Appearance., Clea:i=, colorleea,. Odor: Mi1d odor Cha.~ge in Phyaical State: Boiling Point: 405- MeltiJ:19 Point·: Specific Qravity: Vapour P:i,essure·: Viascosity: Solubility in Water: pH Value: 367 N/D 0.85 N/A »IA 0\: N/D liquid deg 'fl deg F "ate,:•l lllllllig Ill 20C voe (lbs/gal·) , 5. 60 (US2PA Methlld .:a; Non-Photochemical1y Reactive SECTlON 10 -STABILITY AND· REACTIVITY Hazardous Polymerizatio~: Hazardous polymerizati.on WILL NOT occur i.t: pX'0-'uct is use4 acd 1tored as directed. Product is &table if used and atored a~ directed. 01/18/2002 Page 3 962ii>E0909l. l:JHl .. " -oi-•• 0ANCHOR LirnKEMKO, A SUBSlDIARY OF FUJr HUNT -7438. -INKOTE SPRAY ANTI-SKINNING AGENT Huaxdous oecompo1itio:i. Produces: O:xidea of Nitrogen; Oxides of Carbon .Materials and Conditiou to Avoid: Keep. container• and liquids away fr.0111 all. pot.ential •ow:ees of ignition. Keep away from exccaa heat. Avoid contact with strong ox!dizera, 1tron9 acids and atro:ug bases. . SECTION 11 -TOXICOLOGICAL INFORMATION Product Infort:1ation -LDSO (oral, rat) : Acute overexposure: No Oata Available Skin, eye, TI\UCOUB nietr.br~• and respiratory t:ract i=itant. Cru::onic Overexposure: "rolonged or repeated ii:halati.on may ·cause anemia and damage to the )d~eye, liver and blood ayste~. Prolonged or repeated inhalation nay cause central ~er voua 1yatem depression. i>x;olonged or ±e~ated akin-contact l!laY cause dermatit ·is. Ingredient information: Swallowing of Hydrocarbo= can cause lung damage. ~epeated exposure to Hydrocarbon& can cause den1atitie. SE:CTION 1~ -ECOLOGICAL INFORMATION Bcotoxicity Data·, No Data Availal,le Cherni<:al Fate Data: lfo Data Availal:lle SECTION 13 -DISl?OSAL CONSID~RATIONS ~aaardcu11 Waste Characteristic, Ho:ne Reconnendat.ion: Dispose of contaminated product, empty container• and materials used in clealllng up spills or lealca in a mane.er approved for thia material. Consult appropriate federal, state ax,.d local regul~tory agencies to ascertain proper dispo11al procedures. Discharge of proceesing .effluent to the 11ewer may require a peXlllit. DO NOT d.iecharge effluent eolutiona to aeptic &yete!IIIS. SECTION 14 -TRANSl?ORTATION INFORMATION Gro\l:ld Shipping Information Proper ShippiJl9 NAme: Combustible Liquid, ~.o.s. (contains Petroluem '.Naphtha) Hazard Clas a: 3. UN/N1\ Number: NAl.9.93 Packing Grcup; PGIII Air (lCAO/IATA) Shippir,g Infonnati0n Proper Shipping Naf'l!C: Chemicals, H.O.I., Not ~:O:T-regulated. Eazard Claaa: No= CH ?>To, No.'le Packing Gio~: Nona SubsidiaryRi•~: None UN/DOT Label& Ne·eded: OOm.buet:i.ble 'Inte:rna_tional Maritime Org;t..'li:i:at::.on (IMO) Add:/,tional Shipping Clase: ·IMOG Code: Not Applicable Ar.ldt. COde: Arndt.. N/A !{TS Code, N::,t Applicable Product is labeled in accordance vith US D.O.T. ,9 en. Further intor111&ti·oo: Plea&c cai~ (S04l ~64-35D0 for further D.O.T. info:nnation. 01/18/2002 Page 4 96.:?vEOSOSl. 8HI ,.~,-.... .-, f ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT -743B -INICOTE SPRAY ANTI-SKINNING AGENT SECTION 15 -REGULATORY INFORMATION ••Note:-The ingredient idorau:1tion listed i.~ this section is provided for reporting-requirement& as dictated by USEPA, atate and local regulation, If ingredient ie listed in this aection but not in Section 2, then the concentration of this ir.greaient is below-de m_multi.s (less than O.lt). U.S. l'EDBRAL RBGUI,ATIORS: 313 SARA ritle III Section 3i3 (40 CFR 372 •• 355 • SARA Title III Section 302 (•o CFJ!. 355 302. -sAAA Title III Section 304 <•o CF.R 302 CWA • Clean Na'ter Act Priority Pollutants. Liat Toxic Release Inventory) ~~tremely Hazardous SUbstance) Ha:z:ardous Sul:latance List) CAA • Clean Air Act J.9!'0 HA:z:ardcu~ Air contalnillants HAP • Clean Air Act.· EON ~le -EAPa rngrei:Uent• Al.ipha.tic Hydrocarbon Butylated Hyd:roxtoluene Aliphatic Hydrocarbon 2,2,4-Trimethyl-J.,3- Pentanediol Diisobutyrate TSCA 12 (bl ·Expoxt Notification •••None required**** TOXICITY nlFORJQl,TION: CAB Number 6474.2-88-7 :.28-37•0 6-474.:Z-53-6 ·68'1~-.50-0 IRCl • !ARC Group 1 Hw:ian Carci:cogens List 313 355 N N N !If N ll N N 302 N· N N N CWA ~ N N N IRC2 • IAAC Group 2 Hur:.an carcinogens List (limited h~ltlAn data) CAA m,.p N N N N N N N N rn.c3 • :tARC Group 2B ·Hur.an Carcinogens i.iat (11utfic.ient ll.llimal data) NTP .. NTP ~own Ca.rcinogens List OSF.A = osa I<novn carci:2oge:ca List !tigred.ients CAS .. Nwnber IRC1 IRQ J:RC3 :N':.'P OS!!A Aliphatic Hydrocart:on 647.U-88-7 N )I II N N Eutylated Hydroxtoluene 128-37-0 N N N ·N ll Aliphatic Hydrocarbon 647'2-53-6 N N N N N 2,2,4-Trimethyl·l,l-68~6-50·0 N N N :N N Pentanediol Diisobutyrate ST~TB REGULATIONS: FL 2 Florida Hazardous Subatilllce List MA• ll!assacbusetta Right-To-Know Liat Mi = Michigan Critical Material& List MN -Min:aeeota Eazardoua Substance ~ist NJ• New Jereey Rig~t-To•I<now Lise PA e P=ylvania Right·To-l<now List Ingredients CAB Number PA BJ MN MI MA P'1, Aliphatic Hydrocarbon 6'742-88-7 N llf N N N N •utylated Hydroxtoluene 128-37-0 y y y N· y y Aliphatic Hydrocarbon ~4742-53-6 N N N N y N 2,2,4-Trimethyl-1,3-, GU6•50·0 N :N N N N N Pentanediol Diisobutyrate The followiag information is required by tbe St4te of California's Safe Drink· itig water.and Toxic &:nfoxcement Act of 1986 or Preposition 65. Thia regulation .doea !lOt addresB di mir.imU& level111 therefore, even trace amounts of chewicals included on these lists nust be noted with the •safe Harbor• wording. WARNING: Xno1on1 t.o the State of Cal:'..fornia to oaUGe cancer: "'*'**None Listed"•** WA11NING, ll:n0wn t.o the State cf California to cauee developmental toxicity: ****None Listed*!"** lfARNING, Known to the State p£ californla to cause fel'llllle reproductive effects **••No~ listed•*** WARNING, xnoim to the State of Californi"a to cause 11\ille reproductive effects: "***None listed**** 01/18/:2002 Page 5 ss~v8ososl l:IU:l --.ANCHOR LI'I'HKEMKO, A SUBSIDIARY OF FlTJ~ HUNT -7438 -INXOTB SPRAY ANTI-SKINNING AGENT SECTION 1.6 .., OTHER .Im'ORMATION Thi• infc:rma.t:ion is provided .,ithout warranty. The i:il!o%1Mtion ia believed to be correqt.. Thil information should be used to l"\\ake an independent detemina.tion of tha methods to &afeSJUard worl<ers and th~ environment. Ol/18/2002 Page 6 sszvEososl. !:lHI Wdvf;:f; v002 ~O oaa at · d J. MATERIAL SAFETY DATA SHEET The Ancbo:r MSOS in£omation provided on this site ia updated o;i a. rilonthly basis and complies with osp~·•a Eazard C'olmnunicat~on Standard (C17R 1910.1200) and the American Hatioz:.al Standards Institute (AllSl) Stan~d for Material Safety Data Sheeta (ANSJ: HOO .1) .• Finished Goods Catalog 76G~ • MB'l'SRI»G ROLLIIR CL~·AJ.T MBTBRING/PIPZ CLEJWB~ Manufacturer Name ANCHOR LITEKEHKO, A· StnJBIPIARY OF 'FUJI Htim' SECTION 1 -COMPANY IDE~IFICATION Catalog / Sub-assembly ifuaber, 7666 AHCHOR. LI'l'l!KE)IKO, A StraSIDIAll.Y O!' PU.T.I HtlNT so Industrial Loop Nort.ll orange Park, FL 32073 Tltl\N!lPORT~TION BMBRGEblClBS (24HR In.11ide OS/Canada B00-42¼-9300 Outside US/C.¢ada 703-527•3887 (accept• collect calla) MEDICAL El!IBRGEMCil.s (2.uiR) Proaar NOM-~ENCY BHS lnto Gei,.exal :Info 904-26-4.-3500 800-354-2300 P'OR !NDUS'l'RIAL USB ONLY •••••• USS ONLY M ·DI:RBCTEO •••••• DO. NOT TAKB Ill'I'2RNAI.LY SECTION 2 -COMPOSITION/ INFORMATION ON INGREDIENTS Ingredients CAS Number Wt.t OSBA PBL ACOIH (mg/ml) {llg/1113) Acet.cm.e 67-64-l 10-201 1B00 TlfA; l.78D TWA1 2400 STEL 2380 STXI, Aliphatic Hydrocarbon 64742-89-8 S0-70t JlB NE Heptane 142-82·5 10-201 ~ NB Isopro_pano;i. 67·ri3-0 5-lOt 980 'l'k7.; 983 TWA; 1225 STBr. 1~30 STBL Nl!..Not Ba~abl.isbed STEL•Short Term &><poaure Limit C-.Ceilillg Limit& SEqTION 3 -HAZARDS IDENTIFICATION EMERGENCY OWR.VJ:.E:lf .. 'fl> ... tr**•*'*'·•••••_,.. ............ ,,, ..... • :ft.,..T •il+*•••1t•..-**"* flt11r "'**'+«+ ** **••-11••• ..... *"'.,_, ......... ... ~ppearance: Clear, colorless· liquid. Odor: Sol.vent odor Avoid contact with eyes, Bk.in or clothing. Avoid breathing mist or vapor. Do not swull.ow. tiear cbentl.cal safety goggiea • chernioal resistant gloves. Waall 01/15/2002. Page 1 96G-vE0909L. l::IHl Wd-ve::e: -v002 L.O oaa tI ·d ANCHOR LITHKBM.KO, A SIJBS,IDIARY OF F'U,J'I HUNT -, 7666 -METERING ROLLER CLEANER-ALT METERING/PIP tho:rou.ghly after handl.ing. ir.eep oontainer cl.osed wh~ not ill uee. Uae only with adequate vent;la~i=. May produce hazardous gases under'fire c:onditia,:u,. During e,nergencie&, wear equipment to protect eyee, •ld:n and respiratory tract. Dike or abaor:b spil.la to k~ep ma.terial and run-off from entering sewer or watervaya. Uae water spray to ·cool CODtainers and disperse vapors . consult MS?S for addi tOllal info;,na tion. KKIS: NFPA: }iealtb: 2 Health: 2 Flanir:labl:l:1 ty: 3 FlatM.ability: 3 Re,act·i vi ty : O Reactivity: 0 Protection: B Spec. Hu • : :rL1J'! Hazard Ratin:1: o Minimal J. • Slight. 2 • Moderate 3 = Serious 4 • Severe A• Glaves B • Gloves & Goggle& c • Cloves, Goggle• & Apro o • Pace Shie~d, Gloves, 0099le~ & Apron UN NO: UN19~3 Dar qtJi:OE: ERG Guide l.21! Potential Health ELfects: Skin: c=tact causes irritation; Eyes: Causes i=itat~on. Inhalation: Irritant to respiratory tract: and llll.lCOUII memllrane11. Ingestion: Ingestion of produ.ct rnay cause nausea and vomiting. Conditions aggravated by expoaur11: None ,ex:pect:ed except: those assoc·lat~d ,with acut::e effecta. SECTION 4 -FIRST AID ME;ASURES Eye Contact: ITM\ediately flush with COOL water for 15 :minutes. call a physician. Skin Contact: physician. tngestion: pllysicia.-i. 'tllhalation: In case of skin contact; wash with soap and water for. 1s· minutes. Call a In case of ingestion; do not drink water. Do not induce vomiting. Cal.la Immediately re111ove victim to fresh air. Call a physician. SECTION 5 -FIRE FIG~TING MEASURES Plamr.uwle Properties Fla sh ,Poir.t: Autoignition Temperature, Explo11ion Li111its., Lower, trpper: Bxticguishing Media: 10 N/A N/A N/A deg p deg F vol,.t: vol. .. t: (TCC) (CC) Not Tested OSHA Class IB Pla~ble Liquid Chooee ,ext:in91.1isht129 media suitable !or the surr0Wldi09 materials, such .as water spray, d:ry chemical, alcO:'lol foam or carbon dioxide. Um,;uitable Extinguishing Media:· No restrictions onnedia,based en knowledge ~f th~s lll!lterial. Pirc Fighting Instructions: Water spray should be used to cool fire expoeed contai~ere and to disperse un-igoited vapor&. Use NIOSH/1'1SWl..approved positive pressure self-contained breathing apparatus when ~aterial bas ignited or becomes involv-ed in a fire. ·Try to remove mater~al COlltainers f.rcm fire ax-ea if. can be· accomplished. without risk to pereoooel. llvacuate area and fight fi·re from a safe di&t~ce. Call your local fire department. We~r positive preasure, breathing apparatus atld protect:: eyes and skin. use water to cool fire-exposed containers, to protect personcel and to disperse vapors and spills. Fire media run-off can da111a9e the env~ronment. Dike and collect media used to fight fire. 01/15/2002 Page 2 9SGvE:0909l. l::lHl AN.CHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT -7666 -METERING ROLLER CLEANER-ALT METERING/PI!? SECTION 6 -ACCIDENT)µ, REI.EA.SE . MEASURES. Sff!lllll Bpi1ls, For eiuaJ.l incidental spills an4 leaks wear chemical safety goggles, and neoprene glaYea and apron or c011erall&. Isolate area of spill hy dikill9. stop sou:rce of ltoak.· Add dry absorbent. Clean up and. place in an approved D.O.~. container and seal. Waah all contami~ated clothing before reuse, and discard oontallli.nated leather ehoea. Large Spill!': l'::>r larger spilis requiring e111Crgency resp=se, r.eoprep.e boot:a and respirato:ry p~otectian may also he required. Follow QSBA :regulations and NIOSE recommendation• for respirator use (29 CPR 1910.13~ and NIOSH Pub. 87-108) an emergency response (see 29 CFR 1910.120). Ieolate area of spill by' diking. ·Sto_p source of leak. Add dry abeorbent. Clean up and place in an approved o.o.T. container and seal. Waab all contaminated clothing before reuse, a.~d discard contartlnated leather shoes. Call the emergency telephOlle number show:i on the front of this sheet. SECTION 7 -HANDLlNG / STORAGE aa.,c:Uii:.g, Avoid contact with eyes, akin or c1othiog. Avoid breathing mist or vapor. Do not swallow. Wear cgenical safety goggles and neoprene gloves and a~ron. Wash thoroughly after handling. Keep container ciosed when not ·in use. Use only with adequate vent:ilation. St6rge: Store in a cool, dry, well-ventilated area away fro~ a11· sources of ign.ition. keep contai."'ler" ol01Sed when not in use. SECTION 8 -EXPOSURE CONTROL AND PBRSONAL PRQTECTION Vent·ilat ion: . ..--.. Good general ve~tilation shouJ.d be sufficient £or raoat proce•aing operat~ona. 2 t • d Vent worlt ~a to ensure airbor:ie concentrations are &elow tbe current occup~tional expoaure l.ill!i·ta. ·Ten (10) or more· rooiii eir changee per hour containing a lllinimim of is, fresh air will meet these requirernenta. Consult AS:s:RAE 62-1989 for further requirements. Personal Protective Equipment ~espiratory Protectipn: If uaed under normal op~rating conditions and with adequate ventilation, respiratory protection is not required. However, refer to OSHA 29 CFR 1910.1 4. Skin Protection: Eye -ProteotJ.on: Chemical re~iatant gloves Chemical ~afety goggles SECTION 9· -PHYSICAL AND CliEMICAL PROPERTIES Appearance: ciear, colorleaa liquid odor, Sol ~r.t odo.r Change in Physical State: Boiling Point: 285-deg F Mei ting Po"int: . Specific Gravity: Vapour Pressure, Vimcosity: solubility in Hater, pH Val,ue: 212 N/D a. 12 31.00 N/A 20:t N/0 deg F . Water•l 'IM'Bg 11 ~oc voe {lbs/«;Jall , 5.25 (USl!!PA 1".etbcd 2-4) Non-Photocl)einically Reactive Page 3 962v80909L --- ANCHOR Z:.ITHKEMKO, A SUBSIDIARY OF FUJI HUNT -7666 -METERING ROLLER CLEANER-ALT ME'I'BRING/PIP SECTION 10 -STABILITY Wil ~ACTIVITY B.azardous Polymerization: Hazardous polymerization WILL NOT occur if product· ia used acd· stored as dii::eoted. Product is stable if use.d .and •torec1 as directed. Hazaxdous Decornpositicn Products: ·Oxides of Nitrogen; Oxides of carbon Materials and COnditioi:a to Avoid: JCeap containers and liguida away ~rom all p9t:ential s011rces of igniJ:ion. JCeep away from excess heat. ~void ~ontact with strong oxidizers, st:r:ong acids and etrong bases. SECTION 11 -TOXICOLOGICAL INFORMATION Product Information 'LD50 (oral, rat): No Data Availal:i1e .A.:ute Overexposure: Skin,· eye, mucoua membrane and respiratory tract i:r:ritant. 9hronic Overellposure: Prolonged or repeated inhalation may caus·e anemia and dama!:Je t:o the kidneys, l iver !ll'ld blood system. Prol.o:19ed or-repeated inhalation may c.ause cent,;al ner voua system depression. Prolonged·or repeated skin contact may cause de:rmat.i t is. Ir:i,g,:edieot info:rmatio:l: Sw&l"lowing of Hydrocarbons can ciluc&e lung damage. Repeated exposure to Hydrocarbons aa.11 cause dermatitis. SECTIO~ 12 -ECOLOGICAL lNFORMATION Ecotoxicity Data: No Data Available Chemical Fate Data, No Data Available. SECTION i3 -DISPOSAL CONSlDBRATIONS Hazardous Waste Characteriat.ic·: 0001 Reoonrnendation: Disp.ose of contaminated product, e11pty containers and materials used in ·Cleaning up spills or leaks in amaruier approved for thi• 111aterial. Consult appropriate federal, state and local regulatory agencies to ascertain proper d~sposal. procedures. Discharge of processing effluSllt to the sewer ruiy . require a permit. DO NOT discharge effluent eolutiwis to aeptic systel!\11. J'{aterial, if spilled, nay exhibit "flammable" huardcus waste characteristic•. SECTION 1-4 -TRANSElORTATlON INFORMATION Gro'Uild. Shipping InfoX'fflllt.ion Proper S~pping N'a11e: FlBT1111able Liquid, N.o.s. (Contains Petroleum NaphU!as, lsopropanoll Ba2:a:t'd Class: 3 tlN/llA lllumber: .tJNl993 Packing Group: PGIX Air (ICAO/IATA) Shipping Info~tion ero~r Shippi.ng Nane: Flanrnable Liquid, M.o.s. (Co~t.ains Petroleum Naphthas, Isopropanoll Hazard Clase: 3. 2 ~No: Packing Group: Subsidiary Risk: tm/OOT Labels Nee:Sed: UN19.93 rou: None Plalfflable International ~.aritime Organizatioo (IMO) Additio1:1al Shipping Class: IMDG Code: IMOO 3271 01/j;S/2002 Page 4 e: t • d. 962i>E0909l. !:IHI _,,,-.._ t, t • d ANCHOR LITHKEMICO, A SUBSIDIARY OF' FUJI HUNT -7666 -METERING ROLLER CLEANER-ALT METERING/PIP Arndt. Code: Arndt.27.-94. HTS Code: RTSll38],4.B0.·oooo.o P:rOduct ia l.abel.ed in accoxdanca with tJS -D.0-.T. 49 CPR. i;'urther information: Please call (904) 264-3500 for further O.O.T. information. SEC'TION 15 -REGULATORY INFORMATION ••Note: The i:lgredient in:fomation l.isted in !:his section is provided for reporting reqiiirementa aa dictated by t1sBPA, ats.te and l.ocal regulation. If ii,gredient is listed in this section but not in Section 2, then the co::.cei:itration of this ingredient i• below de 11inumla (l~H than O .1%).. U.S, FEDERAL RliGULATlOJ{S, 313 • SARA Title I1I Section 31.3 (40 CFR 372 --Toxic Releaae Inventory) 35S • SARA Title -I-II Section 302 (40 CFR 355 --Bxtremely Hazardoua Substance) 302 a SAU Title III Section 304 (40 CFR 302 •• Hazardous Substance List) CWA • Clean Water Act Priority Pollutants Liat CM a Clean Air Act 19.50 Hazardous Air eontaTILinants HAP " Clean Air Act -HON Rule • HAPS Ingredient& Acetone Al.iphatic Hydrocarbon Heptane Ieopropanol TSCA l2(b) CM WMBBR 67-64-l 6.28-63-7 lU•78·6 67-63-0 Bxport_Noti~ication . CHEMICAL HAMB ACBTONB N-»riL ACBTATB ETHYL11CSI'ATB ISOPROPAIIOL TOXICITll' Iln>O~TION: O.S Number 67-64·1 6'4742•8,!J-B l.42--82-5 67-63•0 IRCl • IARC Group l. Buman carc:inogens List. 313 3S5 N N N N N N y N 302 OIA 'l N N :N· N N N N IRC2 • IARC Group 2 Human carcinogens List tlim-ited buman -data) CM N N .N N IRC3 • IARC Group 25 Human Ca~cJ.Dogena 1,iet (sufficient ani-mal data) .NTP • NTP l<nOwn carcio.oge.ne Liet. OSHA • OSHA Known Carcinogens Li1t Ingre_die1_1u CAS Number IRCl. IRC2 IR.Cl NTP OS!iA Acetone 67-64-1 N N N N N Aliphatic Hydrocarbon 6474:2°89-8 N' N N N N Heptane 142•8.2•5 N N N N N Iaopropanol 67•63-0 N N N N N STATB REGULATIONS: HAP N N N N FL s Florid~ Hazardous Subatance List. ~I• Michi9an crit~cal Materials Li•t NJ• Hew Jersey Right-To-Know Liat. MA.• Massachuaetta R.ight•To-ltnow List MN• Micneaota Huardoua Substance lAet PA• PeDT.sylvania Right-To-Know List IngJ:ecµents C1'.S Number PA NJ MN MI MA Ft Aceton.e 6?·64i-1 y y y N y y Ali~batic By~ocarbon 64742-89•8 H N N N N ·lit Heptane 14:1-9,-s y y y N y y Iaop~panol 6?·63-0 y y y N y ~ The ,followin9 information i• required by the Sta~e of Califo,;-:i:l:a• a Safe Drink• ing Water and Toxic Knforceinent Act. of 1986 or P%oposition-65. 'l'his regulation. does n·ot ,e.dd~&s di iu:li..u• levels; therefore, even trace amount.11 of chemi~11ls ino~uded on these list& must be noted-with tlle •Safe Harbor" wording. 01/15/2002 Pages 962,ti;EOSOSl. l:l I~ -, St· d, ANCHOR LITHKEMICO, A SUBSIDIARY OF FUJI HUNT -7666 -METERING ROLLER CLEANER-ALT METERING/PIP _WARll'ING: 1Cl1own to the State of California to cauee cancer: CAS lltlMBEll CHEMICAI. ~ 71-43-2 BmJZSNB 94•59-7 SAFROLB Wt.RNI?ro: :KnOllll'I to the State of California to call8e deveioproe~tal toxicity: CAB lll.llllBBR CHEMICAL NAME 71-43-2 BENZJIHE 108-SB-3 TOLtl'ENE !URNING: ltno""'1 to the State of California to ca~se fe~le reproductive effects ****None liated•••• W~ING: Known to the State of California to-cause male reproductive effects: C>.S NUMBBR CEEMICAL N1,1',ll 7-l•i3-2 BENZENE SECTION 16 -OTHER INFORMATION Tllie information ia provided w.l.tl:lo11t warranty-. The information b beJ.ieved to be correct. This info~tion shoµld be ueed to make an independent det:erminat:io.11 of the met.'lOds to safegua-rd workers -and the environment. 01/15/2002 Page 6 96GvE0909l. !:l!f'.l POOR QUALITY ORIGINAL S ' . ,fi'?:;;;1,f(~ i . • '.;: :' r ·· /: : . -:: !Y''' ' .,,. .,, .... '"'"'.''''''''''' ·.,. : .. ·:--:/,:·,.-.::··.--·.--<ooA'XER:CAL: s·A~ETY··.·.DATA SHEET ~--:,,•_.,, .. -; ... ~ ..... , ... .. . . . .: · .:,. · -:·· ·.-· ·. · _.',. 1 :·N'umbe'r: 5.4110240!. ,, .:· .... ,.=_:·;;_ .- ' .i:::_/ .. {/_:_:: .\ ... • :·d:;;j_',{_r ;{_::_\~_!_'~-~ ;1,1;;r~~~~~~~;~;f ~~ 9 8 a' . : ' :-~----· . . .... ~ :Material-_.Identification _-·_ ··: . --~- .· .. : ·:· ''• •,:;,,:_. •J":.:,:} ;:.:,,:·~ • • •:',L,~::: I~ •.) .·:.-:··,.: . .-, ... :,:.:···Trade Narn~·--··oN-SM·beveloper"-·-.:,:. · : .. · -._;· .. -· ·· ··.· ·. · _·. ~ .! .~r,.t·~ t~ ~~ ~ .. -~-··:. ..····:, .. .,. .. : ... , .. :.-·~: . • .. :· ..... --··· ,..,.,: T ... -,::-: .J· . .1 .. ·-.:~:·· •••• ,· ·t· .. : .• ·,·· -r ., i . :· :::--· .. ·. ·-.. .··.; r,: ._! . ~ . . . . ·;: ': \. --i ._r' ~ .. , ..... ·. ·:· .... · .. -· ~--.'.':_ .... : -·i--} ~ ... . . . . , .'··.· ,•: .t.:-·- ,: . 9 t • d 962-vEOSOSl l::IHl WdSE=E -t,,002 lO oaa . C (./"""'-. · ("- , ' ll ·d Section V -Reactivity Data stability : stable Incompatibility: Avoid strong acids and oxidizing .agents Decomposition ( ByprQduct ): None i?olymerization: Wi-11 not occur _ --~-~-~-------~----------------~ .Section VI -Health Hazard Data Health Haz·ards: May irritate skin and eyes by direct contact LDSO: >iO,OOOmg/kg ( oral, rats) Triethanolarnine may be a skin sensitizer carcinogenicity: None of the ingredients is listed by NTF, IARC or OSHA as a carcinogen. signs and Symptoms of Exposure: Irritation First Aid Procedures: In case of contact with.skin or eyes, ·rinse witb plenty of water and get medical attention. ------------------------------- Sectiqn VII -Precautions fo~ Safe Handling and Use Steps to Be Taken in Case Mate~ial is Spilled: .Neutraiiz,e with weak acid and flush to s~wel:'. with plenty of ·water or soak up with dry ab$orbent material. consult with Fed,eral, State and Loe.al Regula,tory Agencies for appropriate disposal methods. Waste Disposal: Neutralize with weak acid and flu$h to sewer with plenty of water, if permitted. Consult with Federal, ·state and Local Regulatory Agencies for appropriate disposal methods. Precaution to Be Taken in Handling and Stqring: Keep container.closed and store in Gool area. Avoid contact with skin and eyes. ~ ---------------.... ~_ -~ ----------- Section VIII -Control Measures Respiratory Protection: Not normally required. Recommended Ventilation Protective Gloves Eye Protection Protective Cloth : Latex type glove is r.ecommended : Recommended : Apron or lab coat is recommended -------------------------------- Section IX -Shippi:ng Inf o-rrna tion Hazard Class t1N Number NFPA Rating Not applicable ,. H-2 F-0 R-0 96ZvE0909l. ·~ :.: . -· : .. \·. ' . -~ ; ... : . ,,.- .... -....... .--·---. 03/07/0:l 22: l2r;-42 Plea.:,~ DeliYer To:->1-7606034086 FUJI CHEM DIVISION Page 013 ,r', r- 81 • d JD 'w!IFUJl·flLM Material Safety O~ta Sheet Issue Date: 09/21/9Q Revision Date: 09121/99 Page 1af 6 SECTiON 1 -CHEMICAL PROOUCT ANO COMPANY IDENTIFICATION-. . Product (Trade) Name: FN-6 FUJI PLATE FINISHING GUM Pn,duct Code: 558151-45 supplier: Fuji Photo Film U.SA. Inc. 555 Taxler-Road, Elmsford,'NY 10523 Chemical Emergen~ies (24 Hrs): [BOO) 424-9300 {CHEMTREC) Medical Emergencl~s {24 Hrs): (202) 625-3333 (Gapltol Polson Control Center) General Product Information {9am-5pm E.S.T.): (91-4) 769-8100 or (800) 755-3854 Fujifilm.MSDS F~back Telephone (24 Hrs): (888) 354-3854 SECTION 2 -COMPOSITION I INFORMATION ON INGREDiENTS lngredlentw CASNo. •.4 b~Weight OSHA PEL ACGIHTLV $t~rch derivative 9049-76-7 10-20 % NE 1-.E arabicgum · 9000-01-5. 1-5% NE NE benzyl alcohol 100-51-6 1 -5% NE NE ethyleneglyc.ol-107-21-1 1 -5% NE NE starch, i;,hqsphate 11120-02-8 1. :5 % NE NE wat~r 7732-18-5 60-80 % None Nona NE-Not 6s1ablshed PEL-Permissible Eiiposure Llmt TLV-itreshold UmitVak.le iWA-Time Weighted Average SECTION 3 -HAZARD IDENTIFICA TlON EMERGENCY OVERVIEW . The product is liquid and is/has odorl~s Caution: May cau:.e irri13!:ion to the skin and eyes. Allergic reaction to gum arab,ic may Ciiluse respiratory distress and skin s~nsitivity. t ox10 gases m;iy ce re1easeo uncier r1re conamom;. Wear equipment to protect ey!'S, skin and respiratory tract. Dike or absorb spills to keep material and ruo-off from entering $CWer or wateMaya. U$e water to cool containers and disperse vaPOrs. HMIS Rating• Health 1 Fire 0 R~ctivity 0 Prolt!ction C NFPA Rating• Health 1 F;re 0 Reactivity 0 Specific Hazards None Ha2ard·rat1ng O::. mlnlmal 1= &light 2 =· rnodtrate S = serious 4 =·severe • see section 1e . C• gloves, goggles and apron UNNO: None ERG GUIDE NO: None NE: Not EstabtiShed NiAv: Not Available N/Ap: Not Applicable N: No Y:Yes ssavE:ososl l:!Hl WdlE:=E: voo~ lO oaa -~- 03/07/01 22:12:42 Please Deliver To:->17606034086 FUJI CHEM DIVISION Pa.ge 014 ti, FUJI.FILM Material Safety Data Sheet lssu~ Date: Qg/21/99 R~vlsion bate: 09/21/99 Potential_ Flaalth Ett,cts from Oveni!Xposure Skin: Eyes: Inhalation; Ingestion: Conditions Aggravattd by Exposure: Are Components Listed as Carcinogens: May cause irrito.tioh to the s:an. Ailergi,:: reaction to gum ambic 111clY ~use respiratory distress and skin sensiti'v'.it!/. May cause irritatior. May cause irritation. May C<".iUse allergic type respiratory irritation. May cause irritation ID t!",e ga!'.trobtestinal tract an-:1 l'.mmach May cause. nausea and vorrii1ing. Skin sensitivity, asthma. IAR.C: N NTP: N OSHA: M SECTION 4 -FIRST AID MEASURES Eye Contac:t: Skin Co rrtac:t: ·Ingestion: lnh~lation: Irrigate with f10.,:,.1ing water immeci;1tely and conti,,uousiy for 15 minutes. Consult medical personnel. Immediately fh.;sh with pl~nty _of wnter for at !eas1"'! 5 minutes while removing contaminated clothir,g. Consult a physician or transpo,-t to er,,ergency faciiily immediately. Remove to fresh ai.-. Consult-a ph1sk;ian if resp:rator/ Irritation i:s exoe1ienced. SECTION·~ -FIRE FIGHTING MEA$URES Flammable Properties Flash Point: Autoignition T~mperaturc: E>1ploslon Limits: Exting11i11~ing Media: Unsuitable Extinguishing Media: Fi~ Fightil'!g lnstrui:tions: N/Av deg C Not :::ombustib1e N/Av degC NQ! combustib:e. Lower: N/Ap vol.% 1\:/Ap Upper. I\J/Ap v~!.% N/Ap Water. W"9ter fog, ca;bor. dioxide, foam, d-y cl1emic:ah,. None under nc,rmal conditicns. Keep containers cool·by spraying with w-ater. Evacuate area arid fight fire from a safe r.listel'\Ce We.:ir oositive press,re demand breat,ing apphrat.Js and protect eyes·snd skin. Use water to cool 'ire-exposed containers, 10 protect perso~ne! 11.nd io disperse vapors and spiils. Wat~r runoff ca ri damage the environment. Dike and co!le-;t wate, used to fight fire. -----------------------------------....,..--------------NE: Not Estai:illstied N/Av: Not Available ·NiAp; NotAppllcabie N:1'-;o Y:Yes 6 t • d 96G-vE0909?, l::IHl 03/07/01 22:12:42 Please Deliver To:->17~O6O34986 FUJI CHEM DIVlSION Page 015 ----· r"- oz·d ta FUJIFILM Material Safety Data Sheet Issue Date: 091:21199 Revision D.lt.e: Page Sor 6 SECTION 6 -ACCIDENTAL RELEASE MEASURES Small Spills: Large !pills: Wear adequate personal prct':ictive equipment, see Se~:ticn 8 (E.v.posure Co11trols/Pe,-so/\af Protection). Spills sliould be contained by, and covered v.~th suitable abi;;orbem material and remc-vsd for ,.Jisposal. Dispose of according io local and naliona! regulations. Prevent from entering into soil, waterNays and groundwater. For larger spills requirinS eme.rgency response, neoprene boots and respiratory protection may al~ be req•Jired. Follow OSHAregulatio:,s and NIOSH recommendatbns for respiratory.protection (sea 29 CFR i910.1:34 a:1d NIOSH pub. 87-108} ar.d emergenc:11 ;esponse (see 29 CFR 11;110:120). Hold in properl',1labaled OCT apprcv~ y1aste container. Dike large spills to minimize the-spill area. ltlaterial can cause er.\.i.-onmental damage. SECTION 7 -HANDLING f STORAGE Handling: Avoid ey<!--and skin contact. Wash 1horough1y after hantlliiig. Wash t:a.nds and exposed skin before eajni;,, clrinking or smoking and after work. Use only ·n weilventiiatsd·area __ K.i!oep ::orit11iners tlghtiy dosed. Store in-a ':"611 ve'ri!.ila\e-:i, cool, dry area. SECTION i3 -EXPOSURE CONTROLS AND PERSONAL PROTECTION Personal Protective Equipment Re,piratory Protection: Skin Protection: Eye Protection: Good general. ventilation should be sufficient. for most processing operations. VMt work area \Q ensure airl;;or1e ,:oncentmtions are belovv the current occupational exposure limits. 1Ci or-more room air changes per hour containing a minimum of ~5% fresh air, wm meet the.~e requjrements. Cons.iii ASHRAE 62·1~89 fer further requirements. No respiratory protection needeo under normal conditions. Good ger.er:a! ventiiation should be su'ficient Necorene er butyl'rubblll' should be 1,1fect1vG glove matE-rials. Use chemicel safety goggles. E)'e wash station $hoald be locateo in immediate 'Nork area. SECTION 9 -PHYSICAL AND CHEMICAL PROPERTIES Appearance: Liq:;Jd Cotor: Colorles! Odor: Odor:ess S:hanga in Ph:z:sical State Melting Point : --o de.g C Boiling Point: -100 oegC Specific:: Gravity: 1.1D NE: Nb'I Established l\l/Av: Not Available N/Ap: Not Applicable N:No Y:Yes 96Zi>E0909l.. WdlE=E i>OOZ lO oaa ,.,..--,.., 03/07/01 ZZ:12:t2 Plea5o Deliver To: ··>17606034086 1::-'U,JI CHEM DIVISION Pa.ge 016 ~ FUJIFl'LM Material Safety Data Sheet Issue Date: 09/21,99 Revi~ion Date: ;)9/21/99 Page 4ot 6 ·vaporP-renute: Viscosity; Solubility ii Water: pH-Value: voe: N/Av N/Av N/Av miscible 3.'I g/! (20 <q 2.28 lbs/ gal\on.(Max) SECTION 10 • STABILITY AND REACTIVITY Hazarcj0us Polymerizai:iori: Hazardous Oec:amposition Products: ts.stable under normal·storage condition~. In case of thermal decompositior: poisonous and irritant gases/fumes can be released. CO2, S02 Materials and Coriditions to Avoid: Strong ba~es, Oxidizers. Avoid high temperatures, open flame, sparks and dire~t sunlight. SECTION 11 -TOXICOLOGICAL INFORMATION Product lnform!!!.!m Oral LOSO: Dermal LD50: Primary Skin Irritation lnde,c: Primary Eye Irritation Ind~:. Ac:ute Overexpas ure; Chrr;,ni1. Overexpc;sure: Ingredient Information CASNo. Com122nenl 9049-76-7 starch <:! erivative 90C'0-01-5 arabic~um 100-51-G ber.z,•I alcohol 107-21-1 ethylerieglycol t 1120-02-8 starch, pho~phate F\lrther information:, N/Av N/Av N/Av N/Av mg/kg Ttst Animal: Nl,A.v Test Animal: NfAv Test Animal: N/Av iestAnimal: N/Av Contaet r'na~ cause irritation to the skin apd eyes. May be irritating to the respir-atory tract May cause allergic type respiratory reaction. May be irritation to the gastrointestir.al tract May cause vomiting, diarrhea; abdominal pe.hs and ceamping. Contact.c;iermatitis. Gum arabic is an aller~en that may Ciluse hives, and eczemic rashes. May cause Central Nervous System depression. Ethylene Glycol has shO'MI" teratogenic effects. LD50 Cmgfk9l Test Animal 218 Rats tNAv. Rats 1,230 Rats ~700 Rats NfAv· Rats None. NE: Not Es!atillshed N/Av: Not Available N/Ap: NotAppllcable N: No Y:Yes 96Gi,E:0909l. ,.,---.., 03/07/01 22:12:42 Please Deliver T,o: ->17606034086 FUJI CHEM DIVISION Po.ge 017 ~.FUJIFILM Material Safety Data Sheet Issue Date: 09/21/g~ Revision-Date: OOf.21/99 Page 5of 6 SECTION 12 ~ ECOLOGICAL INFORIVIA TION Ecotaxicity Data! Chemical Fate Oata: Ingredient Information CAS-No. Component 0049.75.7 starch deri\iative lf...00~01 -5 arabic gum 100-51-6 ben2}'l alcohol 107-21-1 ethyleneglycol 11120·02"8 starch, phosphate Aftelr 48 hours of contact with sewage m;crobes the product did not show gross inhibition (cidal) to organisms at conc.entrations c1t or gre;;ter than 5D% (500,000 ppm) using test method PRO/BIQiE SFT/AC 232-7. The product is considered readily .biodegradable a·:cording to OECD guidelines because it WaQ found to degrade more than 80% by Soluble Organic Carbon Reduct1Qn (SOC) method. (test method PROlBIO-E 'SFT/AC 232-7). Fish Toxicity Fish Organism LCOO N/Av t-J!Av LCSO N!Av N/Av LC~O N!Av LCSO N/Av N/Av LC50 N'Av N/Av SECTION 13 -DISPOSAL CONSIDERATIONS Hazardous Waste Charai.teri&tic: Not classified as RCRA-H.!lzardous Waste. Recommendation: DO NOT discharge to septic systems. Disehar~ing this material lo a sev>'er may require a 1>ermit Consult appropriate federal. stG1e and local regulatcry agencies to ~!iCertain proper di$posal procedures. Dispose of contaminated product, empty containers and.materials used in cleaning up spills or leaks in e manner ~pproved for this rnater:al. SECTION 14-TRANSPORTATION INFORMATION Ground-Component Shipplrtg Name:Not Regulated. Hazard Claw: NoM UN /NA No.! Ncne Pa<:king Grou p:Norie Other lnstruc:1ion_s: Prodµct 1s_lat>eled ir. accordancev.m, U.S. 49CF'R. Air-lCAO I IATI\ Prcper Shipping Name: Class: IJN•No~: Pac:kins group: Subsidiary Risk: Labels: Passenger aircraft: CarS10 airr;;raft only: Kit Shipping Name: Furtlier information: Not Regulated. None None None None None P:aciking Instruction: Picking Instruction: NIA,:, None ~~one Mai.: Max.: Not regulated bi'· any med~ er transportation, NE: Not Established N/Av: Not Available N/Ap: Not Applicable N: No 96Z,t,E0909l. Nc:,ne None Y:Yes l:IHl OS/07/01 22:12:42 Plea$e Deliver 'l'o; -> 17606034C,86 F1J1H CI-i.EM DlVISlOtl Page 018 .~ ~FUJIFILM Material Safety Data Sheet Issue Date: 09/21/99 R~vision D;ate: S~CTION 15-REGULATORY iNFORM,.TION U.S. Federal Regulation· OSHA: SARA Title Ill, 302: Hazard Cornmun:cotio:1 Rule. 29 C:FR, Hl10 ·120ci Ustad Extr.emeiy '"::a.;::~rdous .;:;u~Sli\nt.u ln 40 CFR ~f.5 Page 6of 6 SARA Title Ill, 313: SARA Tithl Ill requires submission oi a:.nual re,oor::S tor Tcxic, Ri<;easEi lr.ventory ror oern:r. . SiCc=ides SARA CERCLA RQ: Accidental raler.$~ of susbstan,:es ai:lcve tne Reportable Q1.1sn1iiy (Ri:l1 iis,e<:i OEl0'N r&quire repo11ng under tnis st.:,tute. CAA: cw~: · TSCA el(pcirt: rSCA Certificati::,n; Fe,derz!I Reau1atorv Information Ingredient . Starch Oerh·a;ive ar:a'::llc gum oenzyl alcohol ~hyleneglycol Starch, phos~te State Regulatory Information Ingredient Starch Q-.!rivalive ara~ic ;um. · ber,zyl alcohol . eti1yieneglycol St'31rc:,, phosphate ·C!ea:1 Alr. -~~. Hin:ar1ous Air Pollutar,ts Clean Water Act, Primity Poll;.;tants E.<port Certiric.;,tion-r~uired pe,-1"SCA Section 4. 5 or 12lb) All ingret:lients co:nply '/.1!th EPA TSCfa, regul~fa:ns. SJlltA. TSCA CASNumtm fil'.l,2...~lpxP9rt~f~ 0049-76-7 N N N N N ~OiJ-01-5 N :,~ "' hi N ~ 00-51-6 1--1 i'\! r-1 {'i N 107-21-1 N y 'y y N 1 ·1120.02.a 1--1 N N r·J N CA CAS N1..11nbfr Prop65 fb M8 !'!'!! 0049-76-7 N N N N 9000-01-5 N N N l'J 10(1-51-6 N y M N 107-::11-1 N y 1\1 N ·11120-02-8 N N l'J N California Prnposilion 65 Warning: None. . . SECTION 16 -OTHER INFORMATION For indui:;triai use only. Kop av4y from chfldten. g1I~BQ N N N lina, RO= 5DOCI i:,<iunds (u7:J kg) N .lfil! !!!1 ~ I../ fJ N 1·.1 y N y .. , y y V '( N ~J N NFPA and HMIS ratings are intended to permit speedy general identification cif the extent of particlllar acute h,iizarcis. These haz:ard ratings involve inte•pretalions or data which may vary botween companies. All of ihe !nfo!mclt=or, cont-ained ir. :nis MSDS must be considered in order to correctly addr.:$S the .safe heindling r;;f this product This 1nrormation is provided witi10ut·1,•arranty. The informat.ic11 is believedto·be-9orrect. This inforrnation !ihouid !:>e ·used to mak11 an independent de1£,rmination of the methods to safe1,1u;3rd workers ard t:ie environment. NE: Not Es1ablished N/Av: Not Available N!Ap· Not Applt~.ble N·: No Y:Yes 962vEOSOSL. 8Hl r-, 03/07/01 22:12:42 Plea-ae Deliver To:->17606034086 FUJI CHEM DIVISION .-. I{ Cv"MERIAL SAfi':tnTY-DATA SH11'ET 870119 -Fuji LH-DPR2 Digital T.heraa.i. · Pas ,~l[at~.'. Dev Replen FUJI PHOTO FILM USA, INC. SECTION l. -CCMPANY IDENTIFICATION Page Revised Replaces Printed Catalog/ Sub-assembly Nurr.ber! 746632 FUJI PHOTO FIL!'II USA, INC . Tech...~ical Contact! P11ge 007 1 of 6 6 (01/98 fi/05/97 6/16/00 555 Ta:x:ter Road Elmsford, NY 10523 Non-Emergency No. Emergency No. Emergency No. (Outside tJS & 1-800-473-3854 1-800-424-9300 '.i.-703-527-'38Fl7 Canada.I SECTION 2 -a:MPOSI'l'ION / INFORMATION ON INGREDIENTS Ingredients Potassium Hvdroxide Glucit.ol - CAS Number 1310-58-3 Sb-70-4 7732-18-5 Wt.% OSHA !?EL (m9/n13) 2 C ACGIH Water NE=Not Established STEL:::Short. Term 5-10% 20-25~ 65-70% Exposure NTI: NE Limit SBCTION 3 -HAZARDS IDENTIFiciTION EMERGENCT OVERVIEW (mg/m3) 2 C NB NE C=Ceiling Lim~ts ************~************~*****•******~****~********************************* .l\.ppearance :. Clear, colorless, aqueous liquid Odor: No cdor Avoid contact with eyes, skin or clothing. Avoid breathing mist or vapor. Do not swallow. Wear chemical safety goggl~s & neoprene gloves and ap:ron. Wash tho~oughly after handling. Keep container closed when not in use. Use only _wi_th adequate ventilation. May produce hazardous gases under fire · conditions. During emergencies, wear equipment to protect eyes, skin and respiratory t:ract. Dike er absorb spills to keep .material and run-off from entering s~wer er waterways. Use water.spray to cool containers and disperse vapors. Box may contain rr.'l.1lti-ple container-a ha:vihg multiple components. Consult all MSDSs. HMIS: Health: 3 Nc'PA: Health: 3 Flaromabilit:y: o Flammability: c Reactivity: o Reactivity: O Protection: c Spec. Haz. : CORR Hazard Rating: o = Minimal 1 = Slight 2 -= Mode.rate. 3 = Serious 4 ::: severe A= Gloves B = Gloves & Goggles C = Gloves, Goggles & Apron D = Face Shield, Gl:)ves, Goggles & Apron .UN NO: UN1814 DOT GUIDE: ERG Guide .154 *****•**•**************~******************~**************~******************* Potential Health Effects: Skin:. Corrosive Eyes : May ca.use serioua damage to eyes. Inhalation! Corrosive to respiratory tract and mucous mernbranes. Ingestion: Corrosive Conditions aggravated by~exposure: None expected except. those assoc.iated with <',Cute effects. ssavEOSOSl. l::lHl 1,,.-...· ~. 03}07/01 22: 12:42 Plea:,e Deli-v·er 'I'o: ->17606034086 FUJI CHEM DIVISION MATTI_p.!!CT:.~Y .DATA SHEET 87011·9 -Fuji LH--DPR2 DigitaJ. Thermal Pos Plate Dev RepJ.p..n EUJI PHOTO FILM .USA, INC~ Page Rf~vised Replace,:; P~inted Pi,,ge 008 2 r)r-Ei· 6/01/98 6/05/97 6/1.6/00 SECTION 4 -FIRS'r AID J'1EAS=c=-URE=-c.ccs'---____________ _ Bye Contact: Skin Contact: IngP.stion: Inhalation: Irrrne9-ii;1tely.flush with COOL water ::or 1.5 minutes. Call a physician. . In case of skin contact; imrr.ediat€ly flush with cool water for lS minutes. Call a physician. In r.ase of ir:i.ge.stion; seek irrtmediate rredic-:al attention. Immediately :i:\;imove "·ictim to fresh air. Call a physician. SECTION 5 -FIRE I.?IOHTING MilASURES :?larr.maole ·Proper::ies Flas:i Point: None c.er-:J. F' A'llt,.:,igni tion Tempe::::::-ature: Ni A deg F Tixplosion Limits: Lower: N/A vol.%: TJpper: N/A vol.%: (TCC) (cc:, Not Tested E:x:tinguishi::i.g Media; . Cheese ext:i:nguishing med=.a suitable for the surrou.~din~ mat.erialo, such as watci:r: spray; dry d:1e.mical. alcol1ol foam or carbon d:.ox.1de. Unsuitable I:lxtihguishing Media.: ·No restrictions on media basec. on knowlecge of th:.s material. Fi~e Jighting Instructions: · water spray should be used to cool fire e:.~posed containe~s and ~o disperse un-ign.i.ted vapors. Use NIOSH/MSHA. approved po.sitiv~..! pressure self-contained .breathing apparatus when material has ign:-t.ed or becomes in·To~ved in a fire. Try to remove mai::erial containers :from fire area :i.:: can be accorrplished without risk to personnel. Evacuate area and fight fi:re from a sate d:i,stanc.e. Call your lor.:al fire departrnenL W.ear positive p~e~sure, breathing apparatus and. protect eyes and skin. Use water to cool ~ire-exp?sed co1;i.tainers, t.,, protect personnel and to disperse vapors and spills. :Fire rr:edia run-off ca.'1 damage c.he environment;. Dike and collect media used to fiq.Jht ::ire. SECTION E; ·· :ACCIDENTAL RELEAS'B MEASURES ------------------ small Spills: Fo~ incidential spiils and leaks, wear checnical safety goggles, chemical :r-esistant. gloves and an apron or co-.reralJ_s. For ::.pill:::: requirir1g ernergency resi;:.onse. such as larger spills or spills in confined spaces where TLV /?E:., is exceeded, boots and respir~tory p?:.·ot.ection may als,:, b<;? required. Follow OSHA. :regul~t.ions a.."l.ci NlOSH recommendations fr;r resp:.rat.oi:: use (see 29 C?'R 191.0 .1.34 ,m~d 'NIOSH Pub. 87-108) and emergency res·P.ons.e (see 29 CFR 1910.120). Isolate area of s.pill i1y c.H.ki:i1g . .StOJ:) scurce of leak. Adel dry abscrbent. Clean up and place in an approved DO'r ::1onta:.ner and seal. Wash all contaminated clothing. befo,:e reuse ::1--r:id discard cont.arninai.ted leather shoes. Large Spills: . See Serial l Spills. 9f;>i:!i,E0909l.. l::lHJ WdBE=E vOOi:! lO oaa ,,.---.... { I . ----· 03/07/01 22:l2;4i ?lei,,ee Deliver To: ->17606034086 FUJI CHEM DIVISION 870119 -Fuji LH-DPR2 Digital Thermal Pas Plate Dev Replen FUJI PHOTO FILM USA, INC. ?age ?.e·.·ised Replace..!'i P:d.nted Page 009 -··-Jor-7 6/01/98 f./05/97 6/16/00 .Handling: Avoid contact with eyes, ski:ri. or clCJt:hing. Avoid breathing mist: or vapor. Do not sw~llow, Wea~ chemical safety goggles and n~oprene gloves and apron. wash thoroughly afte:r handlinq. Keep container closed when nor: in use. t:se on.ly with adequat:.e vent . .i.la::ic;i11. storge: St.b:t:e in. a cool, chy, well--venti.lat:ed area. Kc~p con::.ai~er c::.osed when not in "1..1se .. SECTION 8 -EXPOSURE. CONTROL AND _PERSONAL PROTE<;'!f_CJ!! _____ ., ___ _ Ventilation: Local, mechanical exhaust. ventilatio::-i. recornr,,enc.ed t.o minimize emplc,yee exposure to mist and vapors (fume hood, etc.j. Ventilation should satisfy ASHRAE 62-1989 requirements. Fresh oui::do01.· air should be s..;:r,.--plied greater than 20 cfm per person.. Insure adeq,..i.at:e rnixi.ng in t:.he a1~ea where this prcx.lu<.:t is used. Personal Protective Equipment: Respirat.orv Protecticr1: :tf u.sed under normal operating conditions and with ' adequate ven!:.il.3.tion, respira:::ory protection is not Skin Prot-ectic-r:i.: .Il'.fe Protection: required.· However, refer t.o OSHA. 29 CFR 1910.13 4. Neoprene glo'1es and afa:i;n Chemical sa·fety gogg:i.es ---~-----S_E_CT_·I_ON_._9-_-_P.J_IYSICM, A~D CBE~~QU, _f~q_PE13,1'_~§. .. _. Appearance: clear, colorless, aqueou,s Odor: No odor Chap.ge in Physical. State: Boiling Pt >212 Melti.nci Pt. None Specific Gravity: 1.13 deg F dE;?q 1'' Vapour Pressure~ Approx. 1.4 Visc;osity: N/r .. Solubility in Wa1:.e:t"! Complete pH Vaj_ue: ·14 voe (lb.s/gall : o liquid g/1. mm Eg SECTION 1.0 -STABILITY AND REACT.rvI'l'Y ----'-----------'--'-'-'----'---- Ha :z a rd o t.i. s Polymerization: Hazardous polyme:r·ization WILL NOT occur. if prodw.:\t is used ar.d st.or:ecl as · directed. Product is stable if used and ss:ored as directed. Ha2ardous Decomposi ticn p.rcducts: Oxides of Nitrogen; Oxide,s of Ca.:bon Materials-and c,:m.ditions to Avoid: Keep away from e:xcess heat. Avoin r.rnita,ct. with ,;;trc:ng oxid.i.:-::er-s, strong acids a.~d st.roes bases . t • d 96~-vEOSOSl. cl 19 Wdov:e: voo~ l.O oaa ,,,,--.., .. 0~/07/01 22:12:42 Plea.Se Deliver To:->17606034086 FUJI CREM DIVISION 870119 -Fuji LH~DPR2 Digit.al Th~rma.J,. Pos P].ate Dev Replen. FUJI PHOTO FILM USA, I}'JC. SECTIOO. 1.1 -TOXICOLOOICAL INFORMATION Prciuct. Infotma~ion LDSO (oral, rat): >2000 mg/kg Acute Overexposure: . corrosive to all tissues contacted. Page Revised R~places Printed Chron.h-! · Civerexp<"J::=;u:i::P.: Prolonged or repeated skin contact \MY cause allergic reaction ~nd dermat:.it.is. Ingredient info~~iation: No ether inforrnat: io1·i.. SBCTirn 12 -· ECOLOGICAL INFORMATICN Ecotoxicitv Data: No Data Available Chemical Fate Data: No Data Available SECTION 13 -DISPOSAL OONSIDERATIONS Hazardous Waste Characteristic·: . . D002 ·Re.comr~rnlation: Page 010 4 of 6 6 /01(98 E/05/97 6/16/00 "Dispose of contaminated product, empty ~ontaineks and materials used in cl·eaning up spills or leaLks in a manner approved fer chis material.. consult /..-..._ appropriate federal, .state and local regulai:.o:r:y agencies to ascertain prope1.· disi:x:,sal pz.·.ocedures. Discharge of processii:ig effluent: to the se.wer may require a permit. DO NOT discr.arge ef.flu~nt solutions to septic systems. Material, if spilled, may exhibit 11 corro.sive 11 hazardous wast:e characteristics. SECTION 14 -. TRZ\NSPOR'mTION INFO.RMhTION Domestic DOT Shipping -Hazard Class: UN Number: Packing Group:. International Maritim-.':! IM!.IG Code: Arndt. Code.~ ETS Code; Product is iabeled in Class: Potassium Hydroxide, Solution 8 u1U814 PGlI O;rganization (:tMO) Additional Shipping Cl.ass: IMDG 82H Arndt.-. 27-94. HTS#3707.90.E000.8 accordance with us D.O.'I'. 49 CFR. Passenger Ail·craf t Packing Instructions: Do not air ship. T'ne quantity contained in this package excee~s IATA requireme::1ts for shipment by ·ai:i;-. !i"-1::::ther information: P.!.ea.se call (BOO) 4'73-3854 for fi,1:r.:·ther D.O.T. information. ssave:ososl ~I~ Wdov:e: vooa lO oaa ..,,--.. i \ 0~/07/01 22:12:42 Please Deliver To:->17606034086 FUJI CHEM DIVISION MATfiRIAL SAFBTY DATA SH¥,JIT_ 870119 -.Fuji LH-DPR2 Digii:..a.1 'thermal Pos Plate Dev Replen roJI PHOTO FILM USA, INC. SECTION 15 -REGUIATORY INFOBMATION U.S. ?EDERAL REGULATIOHS: Page Revised Replac~:; Printed Po.go 011 5 of 6 6/01/98 6/05/97 E/16/00 313 --SARA Title·III Section 313 (40 CFR 372 --Toxic Release Inventory) 355 302 CWA = "" SA.~ Title III Section 302 (40 CFR 355 --Extremely Hazardous Substance) SARA Title III section 304 (40 CFR 302 --Hazardous Substance Listi Clean Water Act Prk;rity Pollutants List CAA = Clean Air Act 1990 Hazardous Air Contaminants HAP = Clean Air Act -HON Rule -HAPs Ingredients . Potassium Hydroxide Gluci-col Water TSCA 12(b) Export Notification *w*None ~equired**** TOXICITY INFORMATION: CAS Number 1310-58-3 50-70-4 7732-18-5 IRCl = IARC Group 1 Human Carcinogens List 313 N N N 355 N N N 30.2 y N N CWA N N N CM N N N lRC2 lJ\..RC Group 2 H.::.man Carci~iogens List: (limited human data) IRC3 = IARC Group 2B Humap Carcinogens List (sufficient animal da~a) NTP = N'I'P Knowr~ Carcinogens List OSHA = OSHA K:t1o"'n Carcinogens List Ingredients Potassium Hydroxide Glucitol Water STATE REG1JI.J:'.TIONS: CAS Number 1310-58-3 50-70-4 '7732-18-5 IRCl IRC2 N N N N N N IRC3 N N N NTP N N N OSHA N .N N HAP N N l'T FL= ~lorida Hazardous Substance List MI= Michigan critical Materials List NJ= New Jersey Right-To-Know List M..~ = Massachusetts Right-To-Know L:.st MN= Minnesota Hazardous Substance List PA = Pennsylvania Right-To-Know I,ist Ingredients Potassium Hydroxide Glucitol Water: CAS Nuli'J:)er 1310-58-3 s0.:.7.0-4 77°32-18-5 :!?A NJ MN' MI y y y N N N. N N N N N N MA ?L y y N N N·. N The _following information is required by the State of california·s Safe Drink- ing Water and Toxic Enforcement Act of 1986 or Proposition 65. This regulation does not address di mini:nus levels; therefore, even trace amounts of chemicals included on these lists :nust be llOted with the "Safe Earbor 1r wording. WARNING: Known to the State of caJ.if o~ia to ca,.1se cancer: ****None Listed**** WARNING: Y..nown to the State ·Qf California to cause development.al toxicity: ***.;,N'one Llste.d·lr*•·* WARNING: Y..nown to the State of California to cause female reproductive effects ****None listed**** WARNING: ~own to the State of Californi-a to cause male reproduct.i ve effects: S6GvEOSOSL. l::IU:l _.,,.,......_ -~ 0~/Q7/01 22 :.12: 42 Please Deli vetr To: -->1'7806034 086 FU,H CHEM DIV [S ION Page 012 MA'T'11RD\I.:71A~·r·rsJittA'srnm'r __ _ 870119 -Fuji Lff,-DPR2 Digital Ther.m.:iL Pos J?ia.t~ Dev Replen FUJI P.HOTO FILM USA, me. SECTION 15 -REGULN10RY INli'OR.MAT:ION" (Cont.) SECTION 16 -OTH.:Ji IN.FORMATION Page Revis,:!d Replal."~e.s P:::::-inted 6-or~ 6/01/98 6/05/97 6/16/00 ·-·-·-----··---- ---------------- This infr.>rmation. is prov lded without wa.rrant.y. The :'..nfrn:rr.at ion is believed to be correct. This informatior:. sh9uld .be. u.;;ed to make an independent c.et~rrnination of the methods to safeguar.d workers a·nd the env.ironrne:nt. 96ZvE0909l. l:H£l _.,,-.., ,• ·. ---· ! 03/07/01 22:12:42 Plea5e Deliver. To:-> l. 7806,034088 FUJI CHEM DIVISION t?- r-'.ATERIAL SAFETY DA7A SHEET 281100 -Fuji LH-DPW2 Digital Thermal Positive Plate Dev. FUJI .PHOTO FILM USA, INC. Page Revised Replaces Printed Page 001 l of 6 10/01/99 9/13/99 6/16(00 SECTION .1 -ca,,n>nNY IDENrIFICT1.TI=O=N ___________ _ Catalog / Sub-assembly Nurober: 2.81120 FUJI PHOTO FILM USA, INC. Tecnnical contact: 555 Ta:x:ter Road Elmsford, NY 10523 Non-Em~rgency No. Emergency No. Emergency No. {Outside tJS &: ::.-800-473-3854 l-800-424-9300 1-703-527-3887 car~ada) SECTION 2 -COMPOSITION / INFORMATION Cti INGREDIENTS Ingredients Tripotassium Citrate Potassium Hydroxide Glucitol Water C:AS Numher 866-84-2 1310-58--3 50-70-·4 7732-1:8-5 Wt-..% 1-5% l·-5~ 1-5% 90-95% OSHA PEL (mg/m3) NE 2 C NE NE ACGIH (mg/m3 J NE 2 C NE NE ~E=Not Established STEL=Short Term Exposu~e Limit C=Ceiling Limits SECTION 3 -HAZARDS IDENTIFICA.TIOO EMERGENCY OVERVIEW ************************************~**************************************** Appearance! Clear, colorless, aqueous liquid Odor: No odor Avoid contact with eyes, skin or clothing. Avoid breathing mist or vapor. Do not swallow. Weai· chem::.cal safety gogg.les & neoprene gloves and apron. Wash thoroughly after handling. Keep container closed when not in use. use only with adequate ventilation. l\'!ay produce hazardous ga.ses under fire conditions. During emergencies, waar equipment: tc., prot.ecr. eyeR, skin and respiratory tract. Dike or absotb spills to keep material and run-off from entering sewer or waterways. Use water .spr.ay to cool containers and disperse vapor.s. Bo~ may contain mul!:i,.ple containers having r..-n.,,ltipl-e :::cmponents. Consult all MSDSS. HMIS: Health: 2 Flammability~ 0 Reactivity: 0 Protectioc: C NFPA: Health: 2 Flamrrability: 0 Reactivity: a Spec·. Haz.: CORR Hazard Rating: b -Minimal 1 .... Slight 2 -Moderate 3 serious ,4. -Severe A = Gloves B = Gloves & G.c:-..,ggles C = Glov~s, Goggles & Apron b Face Shield, Glct;.,e.s, Goqgles & A.oron UN NO: :JN:l.814 DOT GUIDS: ERG Guide 154 ********•*****************************************************•****•*****•••• Potential Health Effects: Skin! Cont:act: ca1.1se·s severe irritation. ti~·es =· Corrosive Inlialat.ion: Corrosive to respirato:i.y tract a.nd tn~ci.,us membranes. J:nge.stior:: Corrosive s·d 962t,E0909l.. 03/07/01 22:12:42 Pl9a.s·e DeliV<~r To:-.>17606034086 FVJI CHEM DIVISION Page 002 PA'rER!XL-SAi.~--:ml'A:S:-!$1':-·------·· 281100 -Fuji LH-DPW2 Digital Thermal Positive Plat~ Dev. FUJI ~ FILM USA, INC. Page --·--20T-6 Revised lC/01/99 Replac~s 9/13/99 P:::-int.ed 6/16/00 SECT'IOO 3 -HAZARDS IDEm'IFICATICN (Cont.) -~---------------- Condii::ior;is aggravated by expo~\1ra: None ·expected except thcs.: as,soc.:i.atea with acute effects. Ii:ye Contact;: Irrune~iately £ lus:'i with COOL water f.q:c ::,5 mi:1.utes. call a physician. · Skin Contact:: r.n case of skin contact; imt~:e~lia":.ely tlush with cool water for Ingestiqn~ I'nhalation: 15 rnimltes., Call f physiciaI_l, _. . . In c~.se of ingest :i.on; seek llT.rnec:uat.~ rr.-ed:\.'=.al at: ti::nticn. Ir:nmediately 1:emove victim to f:i:esh air. Call a physician. SECTION 5 -.FIRE FIGHTING MEASURES F1.aLrrnable. Prope:r:t· ies Plash Point: Autoignition Tempe r·at.1.1re: Explosion Limits: Lower: Up~r: Extinguishing M:edh~: None. N/:i=l. NiA N/ll. c5.eg J.i' deg "J' vo.1.%: V•:::>1.%: (TCC) (CCi Not Tested Choose e;-:t:inguishing media suitable for the surrou::1-:.t1ng mate:=--:.al.s, such as water spray, dry chemical, alcchol foam or carbon &iox.::.de. ,,..-., Unsuitable Bxtinguishing Medi-a: No rest:::·.ictions on medi~ based on knm..,.:..edge cf l:.hts ;T,c1terial. Fire :Jighti""g Instructions: Water spray should .be 1.J.sed b .. , cool fi::::e exposed cc,11tainers and to disperse ur.1.-ignited. vapors. Use t\TIOSH/MSHA ap·f>i.-oved posit.ive. pre.ss-..:::::e self-con:c .. ,dned breathing apparatus when material has ign.1.te6 or becomes involved in a. fire. Try t::o rerriove rn.ate:r-ial con::~iners from fi:t:e a.re;;;. if can be accomplished w:i.tl1ou::. :dsk to pei:son.nel. · Evacuate area and fight £ire frcn c1 safe d.ist:ar:i.ce. Ct.\ll your local !:ire departmerit. Wear pos iti ·..re pressu.::-e, breathing apparatus and protect eyes and skin. Use water to cool fire-exposed qontainers, =o nrotect personnel .and to disperse. vapors an.cl ?Pills. Fire media run-off i::a:n darr.age t:1.e environment. Dike and collect media usec to fight f.~r~ . . SECTION 6. -_ACCIDENTAL REI.JlASE Mru\f~URES Small :Sp,il ls: For incidenti,"S.l spills and l,::aks, wea~ chemical safety goggles, chemical resistant gJ.oves and a.n apron or coveralls. For: s:uills reouiring emergencv response, such as larger spills or spills in confi11ed spaces where Tl.iV/PEL .. is exceeded, boots and :r:espii.-atory protE.ction ~a.y also be required.. 9"ol.low OSHA regi..zlations anq. NIDSH recor:1t,endat.ic,rn,: .for re.ap.:'..rator use (se~ 29 C3'R 1910. 134 and NIOSH Pub. 87 --106) and emergency re.sponse (s.ee 20 c-:-R. 1910.1:20). rsolat~ area ·Of spil3. by di.king. Stop source of leak. Add c.:z:y absc,rbent. Cliean up a."ld pJ ace in an apprcv,~d DO'I' contai1,e::::-and s:=.:;.l. Wash ss~-ve:ososl.. l::JHl WdO-v=e: -vooa l..O oaa 03/07/01 22:12:42 Plea-se Deliver To:->-17606034086 FUJI CHEM DIVISION Page 003 ---MA.TU:RIAL SAFEW-OATA SHE.t;;T ~-2811.00 -Fuj.i LH-DPW2 Digital 'I'herma.i Positive Plate Dev. J FUJI PHOTO FILM USA, J:NG. Page Revised Re:places Printed 3 0~ 10/01/99 9/13/99 G/16/00 . r""'"· SECT:ION 6 -ACCIDENTAL RELEASE MEASURES (Cont.) all contaminated clothing before reuse and di.scare. contaminated leat.her shoes. · Large Spills: See Small Spills. SECl'ION 7 -HANDLING/ STORAGE Handling: Avoid contact wit:h eyes, skin or cloching. Avoid breathing mist or vapor. Do :not swallqw. Wear chemical safet.y goggles and neoprene gloves a..d apron. Wash thoroughly after handling. Keep container clcised ween not. in use. use only with adeq,.,1.a!:e ventilation. Storge: Store .in a c~ol, dry, well-ventilated ai:ea. Keep contai::1.er closed when not in use. SECTION 8 -EXPOSURE CONTROL Airn"""PERS(iiUU; PROTECTION Ventilation: Local, mechanical exhaust ventilatior-... recommended to m.iniroize employee ~xpcsure to mist and vapors {fume hood, etc.). Ventilation should satisfy ASHR.Zill 62-1989 requireme .. n.ts .. Fresh outdoor air should be suppJ.iecl gr-eater Uia..-:i 20 cfm per person. Insure adeq-..1ate mixing in the area where this , product is used. Personal Protective Equipment Respiratory Protection: If used under normal·operatin~ conditions and with Skin Protection: Eye Prot;.ection: adequate ventilation, respiratoty protect.ion is not required. However, refer to OSHA 29 CFR 1910,13 4. treop1·ene gloves and apron Chemical safety goggles SECTION 9 -PHYSICAL AND. CHEMICAL PROPERTIES Appearance~ Clear, colorless, aq<Jeous liquid Ocor~ No odor Change in Phyfdca,l Boiling Pt Melting Pt Specific Gravity: y~pour.Pressure: Sta.t.e.: V1SCOS'J. ty: 8olub~lity in Water: PH Value: · >212 None qeg F deg F 1.04 Approx. 14 N/A. Complete 13.2 a/1 mm Hg voe abs/gal) : 0 (Minµs wated 962irE:0909l. 1:!Hl .,-...., 03/07/01 2i:12:42 Plea.Se be.liver ·To:->178O0O34O86 FUJI CHEM DIVISION ~JATERIAL SAFETY DATA SHGET 2811D0 -Fuji LH-DPW2 Digital Thermal Positive Plate Dev. FrrJI PHOTO FILM USA; INC. SEC:TION l.O -STABILI.TY AND REAC.rrvITY Page Revised Replac-;es Printed Page 004 4 of 6 10/0:../99 9/13/99 6 /16/00 Hazardous Polymerization: Hazardous polymeriza.tion WILL NO'!' occl.lr if produ,;t is used and st.area. as directed. Product. is stable if used and s-tored as directed. Eazardous Decomposition Produqts: Oxide.:i of Ni~rogen; Oxides of Ca,rhL·m Materia.ls and Conditions trJ Avoid: Keep awa~, from excess heat. Avoid contact with strong oxidizers, strong acids and strong bases. SECTION 11 -TOXICOLOGICAL INFORMATION :Prcd1.1ctr. Info:tmatioz: IDSO {oral, rat): >2000 mg/kg. Acute overexposure: Mild~y· irritating to skin. Corrosive to eyes. Chronic Overexposure: Prolonged or ·repeated skin. contac::::. rn;:i.y cause ailergic reaction and dercr:atit.is. Ingredient information: No othe:.:: information. SECTICN 12 -ECOLOO'ICAL :INFORMATION Ecotoxicity Data~ No Data zwailable Chemical Fate Data: No Daca ~~railable SECTION 13 -DISPOS.AL CON'SIDERAI'IOOS Hazardous was~e characteristic: D002 Recomrnendat ion: Dispose of cont~minated product, empty containers and rnacerials used in cleaning up spills or leaks in a manner appr:oved for this material. Consult appropriate federal, state ar~d local regul~tory agencies to ascertain proper disposal p?::acedures. Discharge of pror:=essing efflt.:em: to the· se.wer may reqµi.re a perrn:..t. DO NOT disc);).arge e·£flueni:. sc,.lut:ions to septic systerri.s. Material, if ·spilled, t'l\c1.Y exb.ibit 11 corros::.ve" haza:t::dcus wast.e characi::.et·istic.s. SECTION 14 -T.RANSPORTATION INFORMATION Domestic OOT Shipping Haza.rd Class: UN Nurnber :. Packing Group: Int.ernational Maritime !MlXl Code: .?>.mdt.. Code : Class: Potassium Hydroxide, Solution 8 u1-Tl8l'l FGIII Organization (IMC) Ad~iticnal Shipping c~ass: IMDG 82.14 11.mdt. 27-94 .. 962-l:,E:OSOSL HHl r--. 03/07/01 Z2:12:42 Plea5e Deliver To;->17606034086' FUJI CHEM·DIVISION 281100 -Fuji LB-DP'H2 Digital Thermal Positive Plate Dev_ FUJI PHOTO FILM USA, INC. SECTION 14 -TRANSPORTATICN .INFORMATION (cont. ) HTS Cede : '!ITS#3 7 07 . 9 0. G oo·o. B Product is labeled in acco:i:·dance with US D.O.T. 49 Cf.R. Passenger Aircraft Pa.eking '.rnstr1.;ctions: Page Revised ReplaCAB Printed Pa.ge 005 5 of 6 10/01(99 9/13/~9 6/16/00 Do not air shi.p. T'ne qt·lantity ci;-intaineci in thi!'i pac:kag·e e-xr:e~ds IATA requirements· for shipt!lent .by aiiri. Ei..1rther information: Please cali (800) 47.J-.3854 for furthe:x:-D.O.T. informat:.ion. SECTION 15 -REGOIATORY INFORMATION U.S. ~EDERAL REGtJI.ATIONS: 313 = SAP.A Title !II Section 313 (40 crR 372 --Tc,xic Release Inventory) 355 -SARA Title lII Section 302 (llO CFR 355 --Extremely Hazardous Substance) 302 = SARA Tit:te III Section 304 {40 CFR 302 --Hazardous Substance Listi CWA = Clean Water Act l?riori.ty l?ollutant.s List Ingredients Tripotassium Citrate l?otassium Hydroxide Glucitol Water CAS Numbei- 866-84-2 1310-58-3 30-70-4 7732-.i..8-5 313 N N 1'J N 355 N N N N 302 N 'I. N N CWA N N N N TSCA 12(b) Export Notif~Gation _,........__. * * *Ntme requii~ed* * * * ,,,--... TO:XICITY INFORMATIOW: IRCl ~ IARC Group 1 Huroan carcinogens List IRC2 -IARC Group 2 Burr.an Carcit:iogens Li~t ·(limited human data) IRC3 = IARC Group 2B Human ~arcinogens List (sufficient animal data) NTP = NTl? Known Car-cinoqens List Ingredients CAS Number Tripotassium citrate 8ti6-84-:2 Potassium Hydro,-:.ide 1310-58-3 Gluci~ol 50-70-4 Water 7732-18-5 ·sTATE REGULATIONS: FL = .?lorida Haza1:do1.,1.s Substance List M~ = Massachusetts Right-To-Know 1.,ist, MI = Michiga.n Critir.::al Materials List MN= Minnesota Hazardous Substance L~st NJ~ New Jersey RiGht-To-Know List PA= Pennsylvania Right-To-Know List Ingredients CAs· Number Tripotassium Citrate 866-~4-2 Potassium Hydroxid~ 1310-58-3 Gluc.itol 50-70-4 s·d 96~vE09.0.9l. IRC1 IRC2 IRC3 NTP N N N N N N N N N N N N N N N N PA N,1 Mt'[ MI lVf.A ?L N N N N N N y y y N y y N N N N N !-l l::H~ i_,-. .. \ ·; 1.. __ , •• 03/07/01 22:l2;42 Please Deliver To:->17606034086 FUJI CHEM DIVtSION !ATJ.m:"!li:[""sJ.i"FTifTJ_J'.m.T".ASrornr-------Pige -E=-1 .. ev·is-e~l 2su.oa -Fuji L'B-DPW2 Digital Thermal Poi,d.ti·ve Plate Dev·. FOJI PHOTO FILM USA, INC. R~pl;::i_r.~~i; P:r!.nted W.:1.ter 7?.32·-18-5 N N N Pa.ge 006 ~ of 6 10/0l/99 9 /13/99 'c. (2.6/C0 The fellowing information ::.s reqµired .by the: St.ate cf Califo.l.-n.:.c:l 's Safe .Drink-· ing Water and Toxic Enforcement. Act of 198'6 or·Propositic-n 65. This regulation do~s not-0 address di mini1T,us. levels; l:hen'!l:rJre, even tr~"'lr:e omo1;ntE'i of chemicals inclu:ied 011 these list:s must be note.d with the 11 Safe. Ea1::bor11 wording. WARNING: Known t,:, the State *·***None Listed**** WARNING: Known co the state ****N'one .Listed**** WAR!'JING~ Y-nown to i:he state *~ k*tfc-,ne listed**** WARNING: Y..no1,1,n t:o the State *•*·*t{one listed**** EXPOSURE INFORr-.m.TION: 1996 American Confe:i:.·ence of Ingredients · •rripotassium Ci,;:rate Potas$:.um Hydroxide Glucitol Water ot' California to cauee c.1£ ca:ifornia to c·ause of Cal.ifo:rnia to cause of c.al i for-n.i.a to cause Go....-emment.al Industrial Time Weighted Ave:r:ages [ TWJ"\.) : NE I\JE NE NE OSHl\. Permissible Expo~ure In.gredient,s Limits , l?BLs) TWA! 'I'ripotasaium Ci':rate Potassium Hydro;dde Gl1")citol Water J;r.gredients . ':I'ripo·c:as.:1ium cit:rat.e Potass~um Hydroxide Glucitol · Wate.r NE KE ~E NE Skin: NE NE NE NE can,.::er: dev·~lop1nental to:dcil:y: female reproductive effects ma.:ie reprod~ct:ive effect.s: Hygienists (ACGIE) : 3hort. Term E>..--posi.ire Lfod.ts1 <s·rELsl : NE NE Nli: NE Ceil.ing Limits: NE NE NE NE SECTION 16 -OTHER ~"'ORMATION-------------·-··------------------------------------- This :.n.Eormation is provided '-'!'"ithout warranty. The :i.nfonnation is i:>elie•,•ed to. be co.rrect. This info.r.mation 8houlq. be u.!::led t.o m .. ':lke an ir:dependent dete:rminatioz1 of tlle methods t-_o safeg.:.ard workers and the environment. ot·d 96ZvE0909l. Wdtv:e: vOOZ lO oaa POOR QUALITY ORIGINAL S -,r'· .. '"-·-,:." -- .. .. --... "[ t ; d --···-.. MA-ltkiAL ~AttlV UAIA )Ht~I~ Contafrter Size: 12 qt/c:,se or 4 galicase Oat!!: March 13, 1990 Product Numb@r: Qt~ 5581-2001 and Gal• SS81-1999 Process Volume Hade: Used undiluted · Stgnaturt of Prepar~r= St!CTIOH I -MATERIAL IOltNT.t.~ICATIOH Trade. Name: Fuji $8· Storagt · Gilili-. . Chemical Family: K~ros~ne mixture with aliphat1e and·aro~atic naptha solvents Manufacturer/Oistr1butor: Fuji Photo Film U.S.A .• INC. . 1aes Ha~ilton P~rkway It~sca, ll 60143 . ·PS-Plate Product lnfonnation Numbar: (70B)-773-7200i exten~ion 6203 Emergency Telephone Numb4!r: CHEMTREC: 1-800-424-9300 SECTION II-!NCRtOIENT lNFORMATION CASI OSHA PEL REGULA.TEO BY Gum Arabic 9000-01-5 Gum extenders 90'50·36-6 recom. 109mg/m3 Kerosene 8008-20-6 O,F Asphalt 8052-42~4 F Medium Aliphatic Naptht 647~2-88-1 .. lOOppm 0 64742-95-6 0 lifht Aromat1c N~pth* Xy o1 lQS.jS-3 25ppn't l.OOppm ~ A,C,O,E,F Water 7732-18·5 . R£f\!LAT£P ey toQl Pi§tRIPTlOII A• CtRCLA U.zard!J~s Sul>tttn~ Llsl . 8 • SAAA TlTL£ 11( £xtrati*ly Hat•rdou1 Sub1t1n0• List (S!Ction 302J C • SARA TITL£ nt Toxic C:ht!illle1111 list (Section lU) < < < < < < < > .L 1cm 10% 5% 2,; 1" 1" lt 61 o -os!IA List.ct Hautdous Chtt!ltcal I, 1ARA tlTL~ lll (!!~tlol'I 311/312 He2:atdou~ Chfl!llcalt E -~C~~ ~,t•tdoui Vest• . ~·DOT Ka2,rdoui $~b,tance G -t~llfornla PRO~ ·$5 C*tca1 S1crtoN III• PHYSiCAL CHARACttRISTICS Spectftc Gravity SolubiHty tn Wat~r pH Value Odor Appearance :1.074 : Partial :NA : Tar-H ke odor :Dark brown -~n,tJ1!ion % Volitiles '(by Vol): 73 . , voe (by wfigh.t): _ 6 Density: l.07-g/m1; 8.9 lb/gal Flash point: 12& F (iCC) SECTtON IV -FiRI AHO ExP~OSlON HAzAlD DATA Ftre and· hplosion Huard Nont; Flub ftoint: lZ& F (TCC) E:xlinguishing Medb · : Any lpplttiiblt to prt.n,ry ctU$e af' fir~. _ _ Thit product w½ll not ~upport combustion. F1re Ftghting Ir:tstruc:tions : Waar self-co1'htned bre1thing apparatus. SECTION V • REAC'fiVlTY DATA Stibi1ity : stable Polymtrtzaiion : W111 not occur. JncampatibiHty: None known. . Oecompos1tion (or byproduct): Hydrucarbon vaport if expo$ed to f1re. 96G-vED909l. ti I ~ / . ,,;J.f: ~ ,•• ' ... -:;. ... ~ . . StCTION VJ -HtALtH HAZA~b DAtA HEALTH HAZARDS! NQne exp~cted ror normal handling. May cause respiritory tract irritation, h~adache, and stupor. tnJ@~tiort mty caus~ irritation to stomach and i,nhstfnes. ConUd: may cause eye and skin irr1tatit>n. CARCrNOGENCITY: t'one of the ingredients are Hst,d by HTP,· tARC or OSHA as a car~,nogen. ~ong term over-exposure to most petroleum hydrocarbons may cause liver or kidn~y injury. 5-IGNS & SYMPTOMS OF EXPOSUR~: Primary rouh of entry • irihal at ion. Can also be absorbed by dermal, eye contact, ,njestion. Symptoms include headache, dizziffjss~ nausea, irritation of the mucous membran~s, r@splratory tract or mild narco~is at high concentrtlions, trr1tstfon to eyes. s~in, &nd dfgQ$ti¥e tract. May aggravate an existing dermatitis, FIRST AID PROCEDURES·: In case of ~ye or skin contact, flush immediately wtth plenty of waler for 15 minutes. WHh eyf! ccmtict, seek hm,edhte physfcan 4ttenHon. If sw~llowed. drink two. glas$"es of milk or water and seek immediate physican alt@ntion. Oo not induce vom1t1ng. If inhaled, mov@ to fresh air. SECTio~ VII -~~tCAUTlOHS ~o-·SAtt HAHbitHG AND Ust: SPILLS/LEAK.~ Absorb with sand, v~rmicu1He pr suihblo absorbMt and place . 1 n closed conhin*r fo.-dhs,oul. Wash ~pi11 $it& with soap and w~t@r after mat~rtal pickup 1s compl~te. Cottsult with Fed~ral, stita and/or local regulatory agenctes for 4ppropriate disposal ~ethods. WASTE DISPOSAL: Consult with Feder~l. Stitt and/or 1aca1.rogulatory agencies for approprhU disposal me\hodi. Discharge effluent to ~anihry sewage _..-...,_ treatment p-hnt, H parmitt~d. .Do not dhpose into a s@i>tk tank or leach field without -totiducting M engiheering study and gainfng proptr- regulatory authority . Do not dhcharge onto th~ ground Qr into storm dratns ·or fnto siJrrface water bodies. 2 r ·d HANbLING/STORAGE PRECAUTIONS: Oo not inhale·. Av~id contact wHh @yes and $kin. Oo not swallow. Keep contiintr.closed and stor@ in cool ventt-la.ted area. Do n<'t freez'9. Do not stort with tncarr,patiblet. ·Respfratoty Protection VehtiUlton Prottction G1ove~ : Not normally requi~id. t R~com~ttdtd. ·eyt Prol~ction · Prot,ctiv~ Clothing ~ Butyl. rubber o~ n@opren@ glove. : Chtmtcal Safety goggles. : Ntuprent or ch~micll resi~ttve apron or coverall StCTtON IX -Sttu•,tN«a lffFORMA1'tON Hazard Clu!I UN Number NF~A Rating HMIS Rit:fng : Not applktble Hot api,Hcable H·1 ; F-i ~ R-0 H-1 ; F-2 : t\·O ; PP-C 962vEO909l. TOTAL P.05 l:IHJ CT) .... 0.._ to en N -t (I') 0 to 0 to ~ a: .... t!) E a. N v .. (I') -t 0 0 C\J r-- 0 0 QJ 0 \ ) llt, VARN PRODUCT~ COMPANY: INC. Corporate Hadquancrs, 175 Routic: 2~. Oaklmd, NJ. 07436 Td: (2GIJ UH4500 ..... , llGIJ H7-2DM. C,,1,1,-; \"A&Nl'IOO OAXUNl>RAC',..C:O. NJ Tela, 1:,0.1,12 HATERIAL SAn:TY DI\TA SHEET PROOUC:T MAME: TRut BLUE PMTl: CLEAIIER USE, PLATE~ COT SHii'PDIG N/\ltr., COtll'O\JIID, ·cu;ANI!I; r.:::ou:::o , DOT CODE, NA l\\~2 cctmUSTieU: LIQUID, N.e.;;. :mo CODE: c~ ::.. j l!i\ZAlillGUS 111\TERIALS IDCllTirICi\.TIOX SYSTE:l: ,HHXS) m:.i.LT!f, 1 Fl.Nllt.t.BILIT'l: :? REACTIVITY, It) P£RSCNJ\L PRvTCCTIC·N: B 0 • llini11al 1 • sligt\t · ~ • llerd-:ratc 3 " Sevi!re 4 • l:xt·r-:"-? ~ % Glasses B ~ Glssses ~nd Glnve~ SF:l':TIOII II -PR!:PA."..'.-:"iON INFOPJIATil)H Jia llat.scn-co·,ernment Reg\llatory A!fair~ C~.-;mt.sc-·;a:n Pi:odu::ts !:oa.i,ar.y, Il\c. Telept\c:-,e Number i 312} 54'.:-8600 Dace 'ot F:-,.i_;arat:1on, ,.pri-1 L, 19!:.~ 3£CTTON III -HAZ.".F.:•:!.'S WGREDIE?lT§ DJGi,EOI!:NT .::AS I :;stll'. ACSII! l Wf!". PEL TLV ·f:c:C. 1. v t! & p N.wtlt!'la ( ca-c 101 [ e~ 3:? -.,1--1 ; ;("" "" Ar?matic p@-crc-leum (6.47~i-~s--.: ! , dist1H.lt.~ iC9-Cl:!) ). .'IC':i1.: _Acid _ "(,;4-19-1} 10 All ingr'!di~nts appear on tile £FA TSCA In•;-,,a-:.-ary .. · ;oo 100 10 SECTION !V • Etr-1:;:ROllttENT;J. .Di\TA !\. s.~AA '!'ITU: III. INF0l,ll'l0rrcN ;02 !{'\1 ·:ra.~:!::NT. ru;·.~ ~l::". -r..'! INGREOIE!fl' I tHS RQ EHS TfQ l .SECTION 313 3111;,~ CATEGOP.TES ! ! ~ •~ contains, crimethylben=ene (:•I •fOOTNOTES: I?-~ co, • l. R!:PORTABU: ~UANTIT'l OF EX'l'REIIELY HA:!AP.DOUS SUBSTANCE, SE:CTI-'.lN ~0: • :?. Tl!R£SHOLD PLJ\NNlNG ljUAI-IUTY. ElC'l'REIIELY HA:Zl\ROOUS SIJBSTl\llCE:, S!:CTION ~02 3. TOXI!: CHElllC!U.. SECTION 313 4. HAZAAD CATCGORV FOR SARA SECTION )lt:~1:-: RBPORTIHG HEAL.Tl{ li-1 • Ilil:C!>L'l.'1":: (ACUTE) HA::Al'.C; H-~ ~ DBLJ.YED (CHROllr:: HAZMD PH'/SICAL P-3 a FIR& HAZAAD; P-4 ~ Sl.'i::iEll P.£1.tAsE or P~SURE HA::!\l'.[I; P-5 -REACTIVE HAZARD ll. C&RC:U\ T»FOPJIATIOH • EPA Cor,jlreh-.ns~·:'.! Z:nv1rc,vne11tal Rezpor,M, ,:,mpens,,t1cn and Liability Act. Undec EP,t,.-CE;RCLF, (Superfund! rel,oase~ t" "'.'"• l)nct. 't \later may be report.able to the National Response Center •. 0.::,o-4.::4 ·:.•,t'I: (Circumstances surrounding the material. quantity, threat r..~ -:r:,·, ::-,,,.,.,nr. and clean-up determ1ne rcportabilityJ. ~~n-r~portable. C. RCRA INFOIUIATiuN -UNO~ EPA -RCRA (40 crR 261.:1), EPA lfoft!!: lh:ml"J<er IX>0l Igni~le waste N.o.s. · O. onu:R REPORTING IllFOllt-1/\TION: 270 gr:lllls per lit:er (:?.~~ poun~s p,., ~jllon: Volat:ile Orqanic Co111POund3 -Cal1.!omia. Rule 1130. Phct."lr:h.--:aic:.t.lly re,.cti·:,• -California Rule l0:?. No 1n9redi,.nt.:s found on •.hi! :".;lit=n,n !.1;;:t - Proposiclon 65 '") -~-\~ ) 1'AIXlUCT IWlll:1 nuz BLUB PNil! 2 VMJr PIIOOIJCTIS· caa>AMY Q;TIQI Y -PHYBICAL PAD 1. STJITlh B1tM Uqw.4 -!wo,l'ha-R 2. ODClh Hild 3. ODOR 'l'HRBSIIJUI, 25 Pfilll 4, SftlCD'IC GRAVITl1 1.01) 5, yJIP0j PUSSlllUI I 21°<: (~h 5.8 6. VRPOR DIOIStft' (ADl•l), 1.3 1. EVAPORATIOII RATE l91m!L M:ITATE-1), e.09 e. BOII.:tJC PODn'(InitiU), 102°<: 215°F ,9. nEE%DG l'ODIT, c-leOc c:1,or lG. plh 2, 1 U. SOLUDILl'l'Y DI lfA1'ER, ~ SljCTIOW Yl -[W QB 1iRVl§IQI t0ZN!P' 1. O)MDITIOIIS QF FLNtiABILiff, Th1a, pCQC\uct ill collbuatihla. Keep away troa hlgh ~llt soun:H, aparlta, or open flaaea. 2, tEAll5 or !lJ'?IMCTI0111 Ory cbeai:c-1, foaa or carbon dioxide e~llher. 3, !1Nill PODrr, 54oC 1290, ,. U?PEll rlN*IIIBILITr LJMIT, 7.(ll\ s. LONE!\ !'LP.HIW!ILITY LIMIT, 9.8\ 6. Atm:>-I~ TDtl'!'JIM'URE, c.ssOc B51Qr 7, HAZAlWOUli CCOlUSTIOI P~, OxidH of Carl>on sp:n:011 vn --REAC'fl'VI'lJ' DM'A 1. COlllDITIOlfll UNDER llHIOf 'Dll PIOlUCT IS CHOIICALLY IBISTMU:, Thi11 pXQduct 1:s stable under all no:cul condit1ona of wse. 2, JXCK>ATmll.ITf OF lmlER Clm<ICALS, Avoid C!a1tact. with •t:r<JlllJ oxidizing aater1al.a 3. HIIZANX)UlS DllCOl1POSITIOII PJIIXXICTS• I/A SilCTJOI VJil -;ancatOOICAL ffl)P!jR\'m! 1. A:ltlT!l or !lfflt'i, Tht priMry i-wta ot entry 111 :lnhalat.ion 2. 1iCll'1'Z !l1!nrrS ~ mostlllt Inhalation cm product respiratory irrttatian, wia)c:nee11, and Nluaea. This prodllct pwduce11 only IWl<'r irritation to akin .and eyes. 3, CHIIOIIIC nT!lC'rS 01 nl'OStJJII, There are no chronic eUecta lcnoWn or elq>eCt4d. 4. THI ~U> LlMIT VAUJI (TLV), 'lbe TLV tor thia product ill 300llOII bued on. toldcolc,gteal data of ind1Vidual ingredicnta and other. products ot 111.ailar conaUtut1oa, 5. DlUTJ\ller 'tO SKlJh H114 1ttit.aUQI\ and itdling uy 0001r with prolonged c:onta(:t, 6. smrr.xu.'tIOII, llo in,p;ed1.ear.a 1n 1:hia product. axe lcnawa to cause a Hn11itiz1ng effect, 7. CJIRCDIOG£IIIClff1 Ila 1n11red11nta an conddered 'CO ~ earcln09t0ic. V .... g_ co. O') N V C') 0 co 0 co t'-- a: .... (!) :t: 0.. C') V .. (T) V 0 0 N r-- 0 0 QJ 0 ) fft0IXJC'l' iwe, ftl1Jll Mm ·r/lGB a m .vxu -mrrrou:w;rot VUll l'RCDIJCtS CCll'Nl"Y a. fJ!OPt!lVjS 1cont.illuedl JIEPRODUCll1iJ: !OJ:ICITY', Thill 11roduet. baa n.ot bHn ahown to be a rep:rod\lCt.1.ve hazard'. 9. 'lERRATOGEXICITY, ~}!ct.~IICt hu not been ahown to pxoduce bi~ 1e. MUTJIGEMICITY, Thie product bu not be•±l ahovn to CllUM 4-ge to ctu:oaoaoee11, U. SYIIZAGIS'?IC ~. Tbin:11!· iJI no dat& availabl•. SlX:'1'.IOII D'. -nEVEl!IJYJi HEASJIJUe 1, PBR90IW, 1'JI01'tX."'l'IVE llQUil'IIDIT I •ear g~owa and gla .. es to protect aJCin and eyea. l. EIIGDlmDIG OOll"l'ROLS, )lo apeclal control• are nectHary u, w,e this prcduc:;. 3. D CA8E or LZ:A1t OR SPILL, . soaJc up aa,.11 spills on ab•orbent ·and shovel into Aon-hazardous r:etuee. Use 99ap w· water to clean neidue, ,. 1IJIS'?E DISPOSN,.i Dilutet! aooterial -y be di11posable in aWl!r. rollow all local, •tate, and fedcal ngulau0011, · 5, IWIIDLIIIG noc:EDllllES, BIDt-Y eontainen MY caotain fi-..ble V~I'II or hazardoua ,Hsidue11. rollov ~at1on11 for fi111tY contuner disposal. Use p~r hygienic pnu:tices 11! ~r:e i• proouc:i. contact vith skin. Wash With IOIIP and vat.er. 6. S'1alMZ Jlll()IJDDIDlTS' Store in cool, dry area &'Illy traa sunlight and high haat .sources. SZCTIDII J: -m.sT AID HEN!YP£$ l. li!liSI Hald eye lids open end rinse with .,.ter for :1:ive llirw.ua. Contact: fhyaicisn it irritation penist.s. · 2. SKD, lfub with soap and water. 3. IJl:iEST?Olfr keap victia ca.la. Matni11ur oxygen if breaming is difficult.. Do not induce VOlliting. seek aedical at.tent.ion :uaid.iauly. •-DIHAIATIO!f, Hove victill to fresh .Ur. 5. IIO'l'E 10 MIYSIClAII '1'her11! 1• no IIPl!Citie 11Jlt1dote. Tnat 1!uaa and use 111JPPOrtive care. n pro<llct 11 1.nOellUd wtl: best gettent. Petz:olaia diat1.llat.ea can cause liw,r and kidney ... ge, but; uy produce chnieal ~uaonitia if int.oduc:ed into lung11. ' ' ~-- ") l"ROOUC'f JWOl, TlWE BLUE. Pl.GI 4 ) VlWf !ll(UJCTS CQtPNJlr l'he optiCfta e:r:pr .. aed henin are those of qualified t;xPert.s Vitbin Varn Pnidueu CClaClaftY,.Inc:., and its auppliera. We .believe that the into:raation contained Ml"ll!il\ ii curttnt a.a of tha dau oi thie Hat.erlal Satety Dat.a Sheet. S:lllce ~ uae. of thi·s :1.1\foraaticm and uie11e opiniona and uic conditiona of µae of the Product are not Within. the control of Varn Produc:ta CDll()any, Inc., it ii the .user'• obli-,.tloo to detexaine the coridit1on11 of safe :uH of the pi-oduct. ?ti:leral law reqw.na persona nce1Y1.ng the HaUdal :s.atecy Data sheet to study it artfully. becoae aware of the hazard•, if any, of the prodtct involved. In the int.eNR Of IIUety you ahould (1) not.if.y your el!IJloyeH, agenta, mid, CCll!.uaeton of the lntoru.tion on thia 111\Ht, (2) fumilll:! a copy to each of :rour cuatoaars for the product, and (3) ~est Your cus~rs to intor11 their eaployees and custoaen u well, 'fflIS lOIIH HAY 8E JIEnOOUCED IJx:l\LLY. \._ ,., U) ... 12..a. tO (l') C\J v ·('!) 0 CD . 0 CD r-- a: .... (!) I: a. C') v .. Cl) v 0 0 C\I ['- 0 0 a, i::a . ) t1 · VARNPRODUCTSCOMPAN~INC ' ' . Corporate Hca<iqu~m:rs: 175 Route 208, Oakbn4, N.J. 07436 T.t· 111>IJ H7--. Fa,., ,:io,, ,,,.,.,~ •. c_,VAa!<PIIOD OAIUAN~aCt.NCO. NJ Tclc,,a 1~12 W.TEIUAL 6t-n:n DATA 511Ctt PJIOllUCT IINIE• ~ V--120 Jl!)'l' :sHIPPJJC KAME: catPOUIID, cuwmiG LIQUID 11·.0.S. MWDOOS MATERIALS IDENTIFICATION SYSTEH, USE, BLNIKET fc JIOLLER WASH 1lO'l' COO!i, 11A' 1993 nil CCllE, CLASS-.l, 3 IIEAL'l'ff: 2 n»tfABILlTY, 2 UAC'?IVITY: GI PERSOMAL .PROnlCTIOII, B 0 • Kin1-l 1 • Slight 2 • Moderate 3 • Seven, • • lxtreae A -Glao~e• D -Glaaaea and Glove~ §ICTION II -l'IIEPWTIOIJ PD"QRK'ITION ~ia lfataon--Gove:cnaent Regulatory Affair• CM•i•t-Varn Produeu· Coapany, Inc • Telephone Xl.mber (312) 543-8609 Dat:e of P:reparation,. April 1. 1989 stCTIQJI III -lfAW!POUS m;;REDIEll'l'S DIGREDIEMT CAS • .OSHA M.'Glll w.xr. iu;c. PERCEIIT PEL TLV i. Atollatic Petroleum Diat.illau ·[&4742-95-6) lN 2. Stodtl&.rd Solvent [&6~2-41-3) 1410 le0 3. Dipropylene glyco'l a.ethyl ether (345,e-,f-8) 100 100(Sk1nJ All ingred1enu appear on the EPA 'l'SCA Inventory. . SECTION IV -£IIVIJ!QIIHDIT/IL DATA A. ·.SARA TITLE III INFORMAnOJI, · · ,c50\ <45\ <10\ DGREDn:N'f I •~-EHS J10 ·~-'EKS Tl'Q 0 3-SECTIOII 313 •t-311/312 CATEGOP.~ Product (llhole) ---------P-3 u Conu1ns: Xylene (3\) ei-ne (·1\) tri.91:thyi.benune (25\) •?OO'l'll)TCS, COl COl COl 1000 5e00 • 1-JIQ'OI\TABLE OIJNl'l'ITY or E%1'1\EKCLY HA7J\RllOUS SUBS'?A!ICE, ScctIOlf 302 • 2. THRE311JUI PIJ\IOIDk; QUNIIITY, EXTREHELY IIAZARDOUS SUBSTNICE, SECTIOM 302 • 3. 'l'OllC OIIMICAL, SECTIO)I 313 • 4. HAZARD Cl.TD.ORY FOR SARJ\ SECTION 311/312 IIEPORTING ~TH H-1 • De:DIATE (ACUTJ:) HAV.RD; 11-2 • DEu.'YEI> (CIIROllIC) KAZARll PHYSICAL P-3 • FIJIE JIA7.MD; l'-4 • SUDOEN IIELEASE Of PRESSIJRE IIA%ARD; P-5 • REACTIVE H1.ZMil e. a:RCI.,\ IIII'O~TlOH -EPA -C011prehensive J:n.vironaenu.l Responee, Coepenaauon and Liabiliw Act.. Under EPA-c!.RCLII. (Supertund) reluau to air, land, or water aay bl, r•pon.able co uie Jlat.ional ReaponH Cenbr, 800-424-8se2 (Clrcuaatancea aw:roundinO' th• uurial, quantity, tlireat to erwiron.ent lllld clean•up det.era1ne reportability). R.O. • 190 poundl! apilled for petroleWD diatillat.e1. ' C. RCII.\ Dl!'OIOl'1fi0N -llllDEll 1:PA -RCM ( 40 CrP. 21il. 21) r It th111 product: becoaes a warrt.e aater1al, it would b.. clu•ified •• spent non-halogenated 110lvent, :&PA vuu ID tPee3. r,. ona RZPORTDIG DlrORW,nOII, 83J graa ·per liter 1,.,, pound• per gallon) volatile organic co11P0111\4s-Cel1.fotn1a 11111• 113111. This product 1• photochni.cally reactive-C.lifomia llule 1e2. lfo ingndiant.a are found on the California Liat Proposition 65. ("' ) r· ) fl!ODIIC'l' IIAH&: WASH v-12e PAGE 2 Vl\R)I PR90tJCTS CUG'A>IY SECTJOX V -l'HYSICAL MTA 1. STAT!i1 Yellw liquid 3. ODOR 'n!RESHOU> 1 15 ppa 5. VAl'OR PRESSURE.@ 2l~C ("'*19), 3.0 7. llVAPOIIATIOK RATE (8ll'l'YL ACJ:TATE-1), 0.22 'J. l'UZ:ZIIIG .POINT: -30oC • 220J' 11. OOU/Bn.ITY l.N lll'.TER: E:11Uls1Ues 2, ODOll1 ,.,1ld petrolellll 4. SPZCD'IC GJU>.VlTr 1 8. 85 6, VAPOR DEll3:rrr (Alll•l), 4.5 a. IIOILDIG PoDIT(Initiilll, 100°c 320":r 9. pH, lleutral StcTIOJ! YI -?IRE QR E:tPUlSX9H ~ 1. COIIPITIOllS or n,.)W,BIU'l'Y 1 Thia p-roduet is cOllbu11t1ble. Do not use in .ir.u ot high heat. sparlta, or .open n-s:. 2. HEAllS or -~CTIOll, Use dry chemical, tou, or cart>on dioxide •ningui11hers. 3. FLASH ronrr, 41°c 1e6'T 4. UPPJ:11 FINIW!ILITY LIKtT: 6.Sl 5. UlWER FLNflABIU1'Y LDlIT, 1.9l G. iwro-IGHITIOlf TEHl'?ll\AttJR&, 30S°C 581°1' 7. HAZAJIDOUS cot!BUSTIOll PROOtlC'l'S: Oxides of carbon SEC'rlOII Vli -I\EN;'?IVITY __ Pl\TA 1. CONDITIOllS Ulllltll IIHICH THC 'PJI00IJC'r IS CHEHICW.Y tlNSTABLE, This product 1s at.able under all not11111l condition• ot use. 2. lllCOHPATI!IU.ITi OF Ol'HSR CHEMICALS: Avoid contact w1.th st1'Qfl!I oxidiz.tng aaterial•. 3, ~ OECOHPOSITION PRODUCTS, Not applicable. stmON VII -'l'OIICQWic>,L PllOPERTIES 1, ROtm: or llllTRY, Tile pr:i.11.uy route of ent.ry i11 inhalation. 2. ACUTE crn:CTS OF EXPOSURE, If liquid ill gplehed into •ves, it vu:(' cause 11t.ron9 i=itation ..nd burning. Inhalation can proouce rupiratory irritation, wealm.eas. an~ nau~a. 'Ingestion of pet.t:ole1111 di1Ullatea can prCldllCe p11llionary · ··· edeaa, gaatro-irri~tlan, duage to vit.al organs. coea, and death. - J. CHR£>Nic E?TI:CTS or EXPOSURE, Re~ated and abusiw, inhalation ot pet.role1a distillau vapors can produce pul1t011Ary ~ cardiova•cular, and central nervous IJY!lt.e• etreets. Repeat.a •kin contact. v:ill dry and crack 111tin. 4, THE THRESHOLD LIKIT VALUE (TLVJ, The TLV for thb product. in 100 ppa based on ~:i:icol.ogical data of individual in9red1ent11 and o'ther products ot suiqar constituticin, .; CD .... ll.. CD en C\J .,. (T) 0 co 0 co r-- a: .... ) l'ROWC'1' ~, WAS1t v-120 Pl'IGl.: 3 SECTION VI? -T9JICO:tf)GICAL PROPERTIES (Continued} S • IRIIITAM<;Y TO SICIR, VlWl PMOIJe'l'S oo«PAKY Petroleua d1st1llates will reaove natural 110ist.ure and cauae drying and cracking. · · 6. Sr.llSITIU.TIOM 1 Ko ingr@dients in th1s·product arc .known to cause a sens1tiz1ng effect. ,. CAllCIJIOGEHICITY, Ko ingredients are considered to be carcinogenic. 8 , JtEPl«lDUCl'IVE TOXICITY' 1 This pr(lduet has not bun ahown to be a. reproductive ~zard . 9. 1'EJIAATOGDnCITY, . This prOduc::t has not been'sho\ln to produce binh defects. _ 10. tlll'IIGEIIICiTt', ~is product has not been shown to ca=e damage to chr0110so11e~. 1-1. S1111El1GISTIC PRODUCTS, There is no data available. SECTION n -PREVglTIIIE -~ 1. l'El!SOIIJ\L PROTECTIVE EQUIFl;M, Wear gloves and glasses to protect akin and eyes .. 2. DIGDIEDllJIC CONTROLS, Insun adequate venr.Uatton so that vapor concentration is AAint:ained below the threshold Hait value. 3. lN CASr; or LUX 0R SPIIJ..: Soak up ... all spills on olbaorbent and shovel 1nto non-~azardous re!ui,c. Use soap and water to clean residue. Dike large spills and keep product fro• enterinoi the 11e.,,.r. Turn off all nearby.BOurces of ignition. JCeep unauthorized personnel away froii a.rea, Call the local fitt department, Soak up on non-reactive absorbent aatertal. Clean up crew .should vear rubber boots and use J:\lbber 11hovcl. Place aaterial in a covered container for la~r disposal. C!l 4 . lf1'STE DISPOSAL, l: Cl. (T) st .. (T) ..,. 0 0 C\l r-- 0 0 QJ Q Give waste aaterial to an authorized hazardous waste hauler. s. IWIOLDIG Pl'\OCtDURES: Eapty containcni llllY contain flaamable vapors or hatai:dous residues. Follow regulationa for eapty ccntainer disposal. Grcll'.nd i:ant.ainer:. when t.ranlferring product. , 6 • STORAGC llD;lllllDmRTS, fltor• in uool, dry •ro AVAY t.r011 •wilight 611d hJgh heat :murce,. S&CTIOll t -F'I1\ST AID ~ 1. llYES, Hold eye Uda cp!n and rinse 111th va.t.or fer five alnut.es. Contact. a phyatclan if irriution per•tat11. 2, mcrN, Waah •kin W1 th "°~I> anrl u11t-.,r. \,._, ') • ... PRODUC'I' IIIANt, WASH V-120 PN;& 4 S§CTIOJI X -·FIRST·AI!) H!;ASUl!ES (Continued) 3. IHGliSTIOII, ") I VAR» PIIOOOC'lS CIJHPAIIY 1Ceep :victia cal-.. Adil1n1ater oxygen U breathing is difficult. Do not indu<:e vci111ting: S.ek 11edical attention ~diately. 4. Ill!IALA'l'IOJr, Moye vi.ct.ill to freSh air. Apply artificial respirati.ol) if breathing hu .topped. 5. HOTE TO PHYSICIAN If product b ing,su:d use -be11t judgeaent, Petroleua d1St1llatea can cause liver and kidney daaa9e, but aay produce cheilical pne,aonitis 1f introduced into lunos. · · " The options expre11sed·h•rein are~ of qualified expert.a within Varn Produi:u Coapany, Inc,, and it.s supplief'I!, We believe that the· iofo111at1on contained h&rein 1s curnnt as of the date ot thb Material Safety Data Sheet, Since the use of this intoraation and these ,opinions and the conditions o! uae of th~ product are not within the control of Vam Producu· COl!'fW\y, Inc,, it 1!1 the uaer•s obl19at10n t.n detera!ne the eorl41tions, of safe UH of the product., Federal lav requirea puaona receivi%19 the Material Safety Data 1heet to 21tudY it carefully, bec011e ~ware of the hazards, if any, of the .product invalved. In the interest of safety yau •hould (1) notify yaur employees, agents, lUld contractQr:, of the infol'Jliltion on thie .sheet, (21 fumbh a copy to ea.ch of your custoaers tor the product, and (3) request your c::ustcmers to infora their employees ar,d ;:u11t:0r.eris 1111 well. 'l'IIIS FORH W.Y BE III:PROllUCED I..DCMJ. Y. .... ...... ,; '' / . l. I • d MATERIAL SAFETY DATA SHEET Plate Deletion Pen MEDIUM IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 1s·e:cTION 1. CHEMICAL PRODUCT ANO COMPANY IDENTIFICATION I Product Name . Plate Deletion Pen MEDIUM Product Code 55812006· MSD~ Code 55812006 Product Size 12 pens Distributor Manufacturer Fuji Photo Film, U.S.A., Inc. Fuji Photo FIim, U.S.A., Inc. 1285 Hamiltqn Parkway 555 Taxter Road Itasca, IL 60143 USA Elmsford, NY 10523 USA (708)773-7200 (914)789-8100 Prepared by .Fuji Photo Firm U.S.A., Inc. Revision Date 3/13/95 Issue date 3/20/95 I SECTION 2· •. COMPOSITION AN,D INFORMATION ON INGREDIENTS Ingredient Tetrahydrofuran Benzyl Alcohol CAS Number 109-99-9 100-51-6 7664-39-3 Weight% -48 20 Hydrofluoric Acid I s~cTtON J. HAZARDS IDENTIFICA rioN · . IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 "Ink" in pen is a dear, co10·r1ess liquid. May produce aclid smoke and fumes In fire conditions. Wear equipment to protect eyes, skin and respiratory tract. Dike or absorb spills to keep material and run-off from entering seweror wa1eiways. Use water spray to cool containers and disperse vapors. 10 HMIS Rating Health 2 Fire 3 Reactivity 1 NFPA Rating Health 2 Fire 3 Reactivity 1 Protection C Specific Hazards None Hazard rating O = minimal 1=·slight 2 • moderate 3 =·serious .f • severe C • gloves, goggles and apron UN None. ERG Gulde 34 Potential Health Effects Skin: ~ Inhalation: Contact causes irritation. May be absorbed through skin. May cause skin bums. Contact causes irritation. May ca.use bums with ·permanent eye damage. Causes irritation to respiratory tract. May cause headache, dizziness and a "high• feeling. May cause breathing difficulties and coughing. Ingestion: Causes irritation to stomach. May cause vomiting, diarmea and abdominal cramping. May hav~ effects on the blood. Hydroftuorte acid m~.Y have effects on reproduction. c9nditions aggravated by exposure . No ~pecific conditions known, Carcinogenicity Are any ingredients listed as carcinoge,ns? IARC? N NTP? N OSHA? N ss·zve:ososl. l::J If) Wde:v:e: v002 l.O oaa ' ' ' ' ,,. .,-...._ ;-'· L:I S;.=E:..::.CT.:..:· 1.;.;;;.0.;,.;;.N_;,4;.... • .:.....;Fl~R~ST.;_. ;;...;;Al:.=;;.D....:..;M;;..;;.;EA~SU.:... R~E~S;.....__ ___ ..;___ __________ __.I . Inhalation: Ingestion: Flush eyes with large amounts of w.ater ror at least 15 minutes. See a medical doctor immediately. Flush skin with large amounts of.water. Remove contaminated clothing. See a doctor if rash, redness or irritation develops. Move to fre.sh air.' If victim is having difficulty breathing, give oxygen if available. If victim is not breathing, start CPR. Get immediate medical attention. Do not induce vomiting or give anything by mouth without emergency medical instructions. Immediately seek medical _attention. Call poison control center at (202)625-3333. If victim is unconscious, trained personnel should start CPR. N_ever·give an unconscious person anything by mouth. !SECTION 5. FIREFIGHTING MEASURES Flash P9tnt Upper Flammable Limit f>utoignitlog Temperature Extinguishing media .s<J°c byJ1s Not available No·t available Lower Flammable Limit Not available Choose media suitable for surrounding materials. No media restrictions based on knowledge of material. Firefighting Instructions Evacuate area and fight fire from a safe distan~. Wear positive pressure demand breathing apparatus and protect eyes and skin. Use water to cool fire-exposed containers, to protect personnel and to disperse vapors and spills. Water runoff can damage the environment. Dike and collect water used to fight fire. May produce acrid smoke and fumes In fire conditions. !SECTION 6. ACCIDENTAL RELEASE Keep· unnecessary and unprotected personnel from entering tt,e spill area. Wear appropriate protective clothing. See E><posure Controls section. Absorb spill with inert material, sweep up and hold in property labelled DOT co.ntainer for dlsposal. Dike large spills to minimize the splll area. Material can cause environmental damage. Prevent material from contaminating sell or entering sewer or bodies of water. (§ECTION 7 .. HANDLING ANO STORAGE HandUng Storage Wash thoroughly after handling. Avoid contact with skin. Avoid contact with eyes. Avoid breathing mist, dust, vapors or fumes. Hannrut if swallowed. Keep caps closed when not in use. Store in. coot, dr;, well-ventilated area .away from Incompatible materials listed in Section 10. fSECTION 8 •. EXPOSURE CONTROLS AND PERSONAL PROTECTION Ventilation Regulrements: Exhaust to satisfy the requirements or ASH RAE 62·1989. Ensure good mixing with fresh air supplied at a minimum of 0.5 cf m/ft2· Persona, Protective Equipment: ~-Use chemical splash goggles. Be certain ey.ewash is in the work area. 8 t • d Wear neoprene, nitrite or other chemical resistant gloves and apron or lab coat. A respirator ls not generally required. R~fer to 29CFR 1910.134. 96GvE0909L. 1::1 I~ Pagd cf ,4 !1112008 ' ' . ~ ..---... Exposure Guidelines: . Ingredient OSHA PEL ACGIHTLV Tetrahydrofuran 200 ppm (TWA) 200 ppm (TWA) Benzyl Alcohol Not established Not established Hydrofluoric Acid 3ppm (TWA) 3 ppm (c) TWA= time weighted average STEL = short term limit (c) = ceiling ! SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance.i. "lnkM Is a clear colorless llquld Boiling Point: approx. 65°C Specific Gravity: 1.01 Vapor Pressure: 88 mm Hg Odor: Odor Threshold; Slight organic No data Reactivity with Water; None Melting Point: No data 0 . Evaporation Rate; Not available freezing Point: No data st."' Percent Volatile; approx. 70 Solubility in_ 'Natet; miscible gj::I;. N/A Water-Oil Partition Coefficient; !SECTION 10. STABILITY AND REACTIVITY Percent yoc;' Vapor Densityi No data Hazardous polymerization will not occur if product is used and stored as directed. Product is stable if used and stored as directed. Not available 2.47 Hazardous Decomposition ·Products: Materials to avoid; Strong acids. Hydorgen fluoride gas. Hydrocarbon vapors. · Strong bases. Conditions to avoid: Excessive heat. Open flames. Sparks. 1s·ecr10N 11. TOXICOLOGICAL INFORMATION LD10: Not available Acute Overexposure; lrr1tating by contact with skin end eyes. Hydrofluoric acid causes severe, slow-~ea1ing bums. Irritating to respiratory tract. May cause headache, dizziness and narcosis. Irritating to gastrointestinal tract. May cause vomitinQ, diarrhea and abdominal cramps. gbroqjic Qve[txposure; May cause liver and kidney damage. Hydrofluoric acid Is an experimental teratogen. lntenti<>hal concentration and inhalation of vapors may .cause respiratory stimulation foilowed by collaps. May cause anemia and leukopenia. Page3 of 4 Ul12D0t 96Z_v€0909l. !:JI~ Wdi,-1,:8 vOOZ lO oaa \ ' ., .. ~-- r ,,,----...__ !SECTIO.N 12. ECOLOGICAL INFORMATION Ecot9xicity Datg None available. yhemical Fate Data None av.ailable. I SECTION 13. DISPOSAL CONSIDERATIONS . Discharging this material to the· sewer may require a permit. Do not discharge to septic systems. Observe all local, state and federal regulations when disposing of this material. Material ctoes not exhibit hazardous waste characteris1ics. !SECTION 14 •. TRANSPORTATION INFORMATION Component ooj Shipping Naroti Not DOT regulat.ed~ Hazard Cllist.t None Kit DOT Shipping Name UN Number: None This Is a single component prOduct. Hazard Class; ·None UN Number; None other lnstructjons: Product is labelled in accordance with U.S. 49CFR. ( SECTION 15, REGULATORY INFORMATION Canadia!J §A.Ba Ingredient ma .b!B 311/312 T ~trahydrofuren y y y ·Benzyl Alcohol y y y Hydrofluoric Acid y y y All ingredients comply with EPA TSCA requirements. !SECTION 16. OTHER INFORMATION . . Packing Group: None Packing Group: None Clean . Ql!iJl CAL Al[ Water Prop 65 N N N y N N N y N This inform~tlon Is provided without warranty. The Information is believed to be correct. This information should be used 10 make an Independent determination of the methods to safeguard workers and the environment. 96Zii'E0909l. l::H El Pagt4 of 4 H81200I Wdvv:E i,OOZ ~O oaa • < " (..,. • 3-11-1997 2: 10PM FROM P.2 /'· • ?age: l MATE-RIAL SAFETY DATA SHEET Printed F0r coatings, Resins and Relat~d Materials . Revised 03/ll/97 03/11/97 •••====•••c•M••~~x~e•~•••a••-~•••~~~~-•~====~••••s==••~•••••*•••••=~=•-•••••M•= SECTION I -PR01'UC'l' INDENTIFICATION -----~-------------------------------------------------------------------------Manufacturer: INX International In~ Co. 455~ Sheila Street Information Phone: 1-800-726-4657 Emergency Phone: l-800-535-5053 INFOTRAC Phone: l-800·535-5053 comm~rce .90040 CA ------·-------------------·-----·-- Product Class: SHEETFED (DRIER ADDEO) INKS ! OS S/OPEN EUROOL .• FRO .BLACK 'l'l41 SP--89901 Hazard. Ratings: none-> extreme 0 ---> 4 Health l Fire• J. Trade Name· : Reac_tivity -o Product Code : C.A.S. Number: N/A (MIXTURE) JOSE APOSTOL LAB TECH Personal Protection -B Prepared By Title .. :::=!i=a:111"••:::r=•• ... •a===:=11:1•••~•••-WK••~===--••,•=Z=-~=a:~•••::sa:.-•11.t_.••••=====bl••--•r:1:=2:1-.. ••-===•••• SECTION II -HAZARDOUS INGREDIENTS --------------~------~-----------------·---------~----------------------------- CAS # Weight :t --~ Exposure ~~m1ts ----VP ACG!H/TLV OSAA/PEL mm HG Ingredients CARBON BLACK (DUST FORM ON~Y) 1333-86-4 20-50 3.5 mg/M3 3.5 Carbon Black has been ~ecl~ssiti~d by IARC as a Class 2E .r--.. carcinogen. Refer t.o Section V for additional information. J ETROl.EUM DISTILLATES N/AV 5-20 5 mg/M3 S .. ETROLEOM DISTILLATES 8042-47-5 5-20 5 mg/M3 5 COBALT COMPOUNI} PETROLEUM PISTILLATE·S N/A (MIXTURE)< 1. 8042-47-s s-20 0.02mg/M3 5 mg/M3 5 mg/M3 mg/M3 mg/M3 N.S. mg/M3 N/AP N/AV • J. @ 70F N/AP . l *** ALL Ingredie:fts in this produc-:. are listed in the 1'.S.C.A. @ ?OF Inventory. Cobalt and copalt oornp.ounds are Group :2:S carc;lnogens by IARC. Ingredients not specifically l~sted above are interpreted to be non-hazardou~ per the OSHA Hazard Communication Stanaa~d .. - N.E. = Not Establi$hed SECTION III -PHYSICAL DATA ----------M----------~---~------~--~--------------~-----------------~----------Boiling Range: 465 -sao Deg. F Ev~p. Rat~. Slower than n-B~tyl Acetate Volatiles vol~ 29.l Wgt% 22.7 Appearance: COLO.RED PASTE, P!!:TROLEUM ODOR Vapor Density: Liquid Density: Wgt p~r gallon: Spec. G~avity: Heavie~ than Air. Heavier than Water. B.81 Pounds. 1.05762 ••M•••~=~--~~~••••~••••••=~~•••••s••~•••••••-·-~w•es==a~•••=~~=~••••z~•~a•••=•• SECTION lV -FIRE AND EX~LOSION HAZARD DATA ----••------w--------~---•------------~----•------•-------------------•••------Flammability Class; IIIB F.lash Point": 265 F ,l?MCC LEL1 1.10% UEL: 6.00~ ~--.... ssavEOSOSl. ' -,- 3-11-1997 2:10PM FROM P.3 ,,..--_1age: 2 INX International link Co. Material Safety Data Sheet for: OS $/OPEN BCTROGL.PRO.BLACK Tl4(SP-89901) •Z~~==~--•••:~==••=·~--~~-~---·••••~-~~---~--~•&xsze==•••~•••~==•k~••••n=~••=== SECTION IV -FIRE AND EXPLOSION HAZARD DATA (cont.) ---~---------------------------------------------------------------------------•EXTINGUISHING MEDIA: Foam -Alcohol Foam -Dry Chemiqal -carbon Dioxide -SPECIAL FIREFIGHTING PROCEDURES-: Self-contained breathing app~ratus recommended for firefighters. Water may be u~ed to cool closed containers to prevent pressure build-up, auto-ignition, or explosion under extreme neat. -UNUSmu:.. FIRE & EXPLOSION HAZARDS: Dense smoke cons·isting of oxides of carbon .are generated during combustion. Closed contain~rs ma¥ explode under extreme heat. ••~•••=~=~~~••m:2=~-~--~~-~z••~~---•••••~:s~===•••-••===s••~~~~•••xe==~----••c= SECTION V . -HEALTH HAZARD DATA ----------------------------~--------------~--------------------------· ------PERMISSIB·LE EXPOSURE LEVEL: see Hazardous Ingredients, Seotion II. -EFFECTS O? OVEREXPOSURE: PRIMARY ROUTES OF ENTRY: Skin, inhalation & eyes as spray mist. EYES: Can caus~ irritation upon direct cont~ct. SKIN: can cause irritation, defatting, and dermatitis upon pro- longed·and repeatea contact. INHALATtON: Can cause irritation to nasal and respi~atory tract upon repeated hreathtng of vapc~ or tti~t. May cause nausea and dizzines$ to some individuals. r, INGESTION; Can caµse gastrointestinal irritation, nausea, and vomiting. Aspira.tion into the lungs can cause chemical pneumonit;i,s. CARCINOGEN STATUS: Unless st·ated below, no ingredients have been c_lassified as a carcinogen by I.ARC', NTP, or OSHA. Rat inhalation tests with high dust levels of carbon black have ·caused IARC to recla.saify carbon black a$ a Class 2B carcinogen. However, !ARC concluded that Hthere-is inadequate evidence in humans for the carcinogenicity of carbon black". Moreover, the iack of an exposure pathway via dust inhalation in printing inks would preclude the carbon black health ef{ects studied by.~ARC. IMC.Monograph Vol. 52 states "There is inadequate evidence for the carcinogenicity of cobalt ancl cobalt c9tnpounds in humans." The study concludes that cobalt and cobalt compounds axe possibly carcinogenic to humans (Group 2B). The cobalt compound in th.is product was not eval~ated for carcinogenicity. -Fl;RST AID; _,,---...., EYES: Flush with copiou~ amounts of water for at least 15 mins. If i:l:"ritation persists, seek medical attention. SKIN: Wash wich wate~less hand cleaner and then soap and water. Remove contaminated clothing and wash before resuse. INHAr..A.TION: Remove person to f~esh air. If breathing becomes difficult, give oxygen. If breathing has stopped, give CPR ~nd SEEK IMMEDIATE MEDICAL ATTENTION. INGESTION: 00 NOT INDUCE VOMITING,. seeK medical atte~tion. SS2vE0909l. 1:!Hl 3-11-'-1 997 4 = 1 1 PM P.4 .,--...., ·)age: 3 i:NX International Ink Co. Mat~rial Safety Data Sheet for: OS S/OPEN EUROOL.PRO.BLACK T14{SP-8990i) SECTION vr -REACTIVITY DATA --~------7-----------------~-~-------------------------------------------------STABLITY:. ( ] Unstable HAZARDOUS POLYMERIZATION: -INCOMPATIBILITY [x] Stable ( J M&.y occu:r [xl Will not occur Avoid contact with strong oxidizers { ie • nitric acid) -CONDITIONS TO AVOID: A~oid .extreme temperatures and open flames. -HAZARDOUS DECOM~OSITION PRODUCTS: carbon dioxide, carbon monoxide, and various hydrocarbons. SECTION VII -SPILL OR LEAK PROCEDURES -------------~------------------~-----------------------------------------------STEPS TO BE TAKEN I~ CASE z..mTERIAL IS RELEASED OR SPILLED Remove all-ignition so~rees. Ventiiate eonfined spaces. vse an absorbent material such as clay or kitty litter and transfer to metal containers· for proper disposal. Prevent runoff from entering waterways and sewers. Adhere to any applicable spill orctinan~es. -WASTE DISPOSAL M~THOD: Dispose of in accordance with all local, state, and federal regulations. SECTlON VIII -SPECIAL PROTECTION INFORMATION: -------------------------------------~ --------------------.--------------RESPIRATORY PROTECTION: Respiratory protection usually not req~j,.red. If TLV or PEL is exceeded, use a NIOSH approved vapor respirator, -VENTILATION: General mechanical ventilation is expected to be adequate. -PROTECTIVE GLOVES: ·Impervious gloves recommended when handl~ng product. -'EYE PROTECTION: Safety glasses recommended as good industrial hygiene. -0.THER PROTJi:CTlVE EQUIPMENT: None expected. Minimize contact as good induE;itrial hygiene~ ••c••••azs••••••~••••5====~~~~Q••w••~=~•••==a-•~M••••••••=-•-~••••===••w•=~s•~• SECTION IX -SPECIAL ~RECAUTIONS ----. ----... ---·--------------. -----. ---------------.. -.. ----------... --------------... -- -PRBCA-qTIONS TO BB TAKEN IN HANDLING AND STORING; Store in a cool dry place with·adequate ventilation. Keep closed when not in use. Conijult S~ction VI for ~dditional orecautions. -OTHER P~ECAUTIONS: ft _,,,.-.__ Do not eat or drink in work areas where solvents are present. Wash hands and face before and a~ter ~sing the product. ~his p~oduct contains Diethylene Glycol Butyl Ether,CAS#112-34-5 a chemical .subject to TSCA 12{b) export .regulations. 9$2-t,,EOSOSl. l:JHl / · ,. 3-11-1997 2: 12PM P.5 .. ,.,-:---,... · ·itge: 4 . .INX Inte:r:na tional Ink Co. Ma~erial Safety Data Sheet for: OS S/OPEN EUROGL.PRO.B!ffi..CK Tl4(SP-B990l} . . ••••£:a:"-=••s•~~~tc::!•••llllli•••••••=s•!!!l~R!R•--•••••~z:s_===•-=c•••••••~=:=!:z••=:a:•••,..••••••••• SECTION X -AI>DITIONA;L REG~TOR¥ INFORMATION ----------~------~----------------------~---------------------------------------SARA TITLE IlI SECTION 313= This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Eme~gency Planning and Community Right To. Know Act of l9B6 and of 40 CFR 372; l?ercent by CAS# Chemical Name Weight -----,-------- N/A (MIXTURE) COBAL'l' COMPOUND O • 55 -PROP. "65 (.CARCINOGEN): WARNING: 'l'his product· contains a chemical known to the state of California to cause cancer. CAS# Chemical Name ----------~------------------" None -PROF. 65 (TERATOGENIC): WARNING: Tbis proa~ct contains a chemical known to the state of Galifornia to cau~·e birth defects or other reproductive harm. CAS# Chemical Name · None . .,,...---,"?RO.P. 65 (BOTH CARCINOGENIC AND TERATOGENIC) : WARNING: This product may con~ain a chemical known to the state of California to cause cancer or birth defects or other reproductive harm CAB#. chemical N~me None -DISCI..AIMER: The information provided herein is strictly for compliance to th8 OSHA Hazard Communkation Standard, 29 CFR 1910 .12 0·0 (g} . 'Nothing contained herein cons.tit'llte$ a specification nor does it guarantee warranty for said product. . .--------------···----9SZvE0909l. 1:J Hl Wdsv:i:: vooa l.O oaa · -Dec· 08 2004 11: s·dAM '"· GIA 7606034296 -=#-,;; oc 8 GIA GEMOLOGICAL lNST!TlJTE Ot: ~lUC.-.. TO: Gene Walsh COMPANY: Wal_sh Engineers FAX NUMBEII.: . {858) 541-0787 PHONE NUMJIER: R'E: Kellogg Building 0 URGENT gf FOR REV!'EW NOTES/COMMENTS: FAX TRANSMITTAL SHEET FROM: Tom Costello DATE: .. 12/8/2004 TOTAL 1\0, OF PAGES INCllJDING COVER: 15 !>ENDER'S PHONE NUMIIE!I.: .760-603-4032 YOlJR 11.EFE,RENCE NUMBER: 0PLEASE COMMENT 0 REPLY· 0 PLEASE RECYCLE P· 1 'Dec -b,B 2004 11: 50AM GIA ,/ ---/ DE:c-,0e-,e04 09 :04 AM INK M'AKERS INC ~::. .. ·.~-.!..:.-~~-.,.,,:,.=-=-·-~--· 760603429S 132372~3-~~~ F'.02 '*·** •••• * *""* *. ** **'**** **"' *'* ** ...... ·~ •** *"* * * **** * ........................... * * **'* ..... * ** * * MATER I~ L S ~PITY DAT A SHE BT •** .. ***** 1 N K MAK e ~ s, IN c. qqq"' .. _ .............. * ............ ii*****-*****•* .... ** ... * ...... ***** **1t* * *** **** *,. ...... **'Ill'*** Lataat Revision Date •.• 08/19/02 SQY $BT PROCESS c:a:; Print date .....•...... ,12/08/04 ............................ *** .. *****'********"'** .. ***** .. ************~*~************ .. **** kilCiliQ.li 1 PBOJIDGt !PiN'IU+CA'titON PRODUCT ,NIIMB • •. • • • •• , • • • • • • • .-•••• COMPANY NAME •• ' • . • •. • • • • . • • • . ..•• COMPANY APDRBSS •••. • • , •••••••••• COMPANY PHONi •....• , • , ......• , .. TR,AD-3 N»tB . . .. . ,, •-~ • ~ . . . . • • • . .. . . . .. INK MAKERS INC. 6681 EAST 26TH STR!ET (213) 728-7500 COMMERCS,CA ********•••-• .. •••••••••**********·*************************•*******W********* SECTION' l IJUARpogs INGBBRIIJNTS _ / HAZARD CATA W Hnllll& -'-BI-- •••• ~ ............................... ********•+•••••*****·· .. ··············***** SiCTIO?i 4, ms I@ DATA BOILING/MELTING POINT,, •....•.. , 500-600 t VAPOR PRBSSURE, •....• , ...•.. ,, .. N/A VAPOR DENSITY. • • • • • • • • • . • • • . • • . • HEAVIER 'THAN AIR (VOC} -PERCENT VOLATILE BY WT. . • LESS THAN 1 \-LESS THAN 10 GRAMS/LITER SPECIF.IC GRAVITY OR SULK DENSITY' WT./GAt,, •• :. 8.l # APPROX, SOLtiBlLiri IN WATSR .. , ..•••..•.. INSOLUAB~E ,SVAPORATION RATE •• , • . • • • . • • • • • • • St.OW-ER THAN BUTYL ACETATE APFEARANCi •••.• ' .••• ' •. ' I ' • • • • • • BtUB PASTE ODOR •••••••••••• , • , • , •••.•••..• ~ RESINOUS _ *************········ .. ~··········•••••+•••••·····~·············* .. ••••••*••••• -a3CTION .S rru ANP BXPLQSIQN HAZARD PATA FLASH POINT D F .•••••••• I •••••••• ,FLAMMASLB CLASSIFICATION,, ... ,,. F~ILITY LIMITS IN AlR ti V) EXTI~UISING MBOIA.~ .... , ...• ,,. _SPECIAL FIRB FIGHTING PROCBOU'RiS ASOVE 230 F CLASS 111B COMBUSTABLE-NOT D,0.T,REGULATED _N/A . C02,0RY CHEMICAL, FOAM,WATBRFOG WATER MAY BE INBFFECT!VE BUT CAN BE tJSEO TO COOL CONTAINERS BXPOSED TO.HEAT OR FIAME -- UNUSUAL FIRR « EXPLOSION HAZARDS PROTECT CLOSED CONTAtNERS FRO~ PRBSSURB BUILD-VP AND POSSIBLE RAPTORE WH!N EXPOSSD TO EX'rRMB HEAT ········**····~·*-····· .. ········· .. ··········~···~··~···* .. *******************• SECTION 2 :&MiRGSNQX iNP 1!'.ISS'I AU> m,snURES SIIK ......... ~,,h affected, 1re11 with water Yhilc rnovini coat1minated clothing, Set it~ediate 1edit1l attention. L,unaer mtHinted elQtkin9 ~efort reu,e. 1rrs •...•.•.. rlu1t eytt tith geaeroat 11ouut1 of vater for at le,1t 15 miautes. Get ineaiate ~idicil atte~tion. IJGl~?!O!.,,.lf ,.,110,ed, DO BOT r10uc1 YOKitiiG. Dilutt vitb r•ter or iilk ind call a phytici1u i11ediately. Rever give fl;id1 or i14uce vOllitinf if tne victia is-uncon1cioo1 or aaving convulsion,. IJBAL~TIOI ... Move ta frevb-iir. lid, 1n oreathing, if n,c111ay, end get i1nedi1ttmedical 1ttentioa. •~*******•••*••~····~··~•*••••*•*****•**~*******•••+•~·····~······•**•·····*· ~ECTIPN s REACT!YIT';( PA'IA PRODUCT STABILI1'Y'., ..•..•.•.••.• CONPITlONS TO AVOID .......... ,,, CHEMICAL INCOMPATIBILITY .. , •.... STAllLB HBAT,SP.ARKS,FLAME OR EXCESSIVE TEMPERATURE STRONG OXIDIZERS p.2 GIA • Dec ba 2004 1-1:SOAM ~Ec-0i~20e4·~~=0~ AM .• -. .. ....:,.;......;..· --------'-~~~_:!~~-RS l NC 7606034296 132;5728~:i:5'3 P.05 SOX ill' PllQCJSS -CXAN ·······•**•···························•*•***•**•····· .. ··· .. ····••*******•••••• SSCt:U2N § BBACTIYl'U' DATA CONT'D HAZAADOVS OBCOMPOSITION PRODUCTS CARBON OIOXIOE,CARBON MONOXtOB,OXIDBS OP NITROGEN lJA.!:AROOUS POL'YMERlZATlON, •. ,. • • • • WILL NOT OCCUR conoslVE TO MB'I1At .••.•.• ;...... NIA OXIDIZER ••• , •.• , •••.• , ••••••. , • , N/A .................. ** .......................... ** ................ **"* ....... ,,, .... ** ................. . SSC'l'IQN,.9 IUCil,L eBA'tictiQN INPQRMA,TIOB ·aJSPlUTOlt PIOflCTIOI •• , ..• 110&1/KSlll· appra,,d ~rg1nic vapor rt1pir1t0r w~en v1por1 ire gtQertted 1~ove tha pet1i11,tle li11it. nnr.uuor ................. Loc1i txbiutt to co:trol-to rtconenae~ P.I.L._ ·11or1cr1v1 CI.0Tlt•o ••••..•.. c10,e1, co,1t1ll1, aproa,, ~oota · a, nec,11aty to prevt:t skiD contact. JYI PlO?lcttOX .............. ~11Jc,1 goggles. OTBII PliCAtmOIS ........... Slonr •ftu bln4li119 tbh product. ~ln11 clathiug 1ho11ld b~ worn daily. !yevub fouiitaint 1lovld he e11ilr 1ece,1ible. ******•***~···················•*********••·•~•••••******••••················· SECTION 1 P !NYIBQNMJW'I'Al:t _Wlra . SPit.L OR I,EAK PROCII>URBS .... , , . . THIS IS NOT A RBGULAT.BO PROPUCT. SPILLS SHOULP BE CONTA!NlfD,ABSORBBD,AND PLACED IN SUITABLB CONTAINJRS ,OR DISPOSAL IN A LICBNSBD ~ACILITY ANO IN ACCOJU>ANCJ WITH LOCAL,S1'A'I'B,AND fBD!IRAL LAWS. WAST3 PlSPQSA+i METHOD, .......... INCINIRAtE ,r.ND BURY AT A LICENSED FACILITY 00 NOT OISCHARGJ INTO WATBRWAYS OR SBWER. SYSTEMS. . CON'l'AlN'ER DISPOSAL ••..•.••...•.• XNCIN!RATB oa BURY AT A LlCBSBD FACILITY ANO IN ACCO.RDA.NCI WITH t.OCAL,S'l'ATB,AND P'IORBAL LAWS. p.3 'Dec be 2004 11:50AM ~EC-08~2804'0~:86 AM GIA t NK MAKERS . I NC . j,_ ________ ......._ ____ ,,__.--·-·---·-· ---· 7SOS03429S 13237283:5::;~ P. 04 ••••************•·················································*······· MAT BR t AL SA.Fi TY DAT A $HS ET ********* . INK MAK g RS, .INC. ***********•·····················~··········•*******************········· i~~eet Revision.Date, •. 08/19/02 soY .SU J?RQCSSS MAQi,NTA Print date •.. , ... , ..... 12 / 08/04 ·································**·········································· 81C:+0N 1 fRQPm::t XPJNTIFIWlQN PRODUCT NllMS ...... , .•......•.. ,. SOY SIT PROCESS MAGBNTA COMPANY NAME • • • • • • • • • • • . .• • • • . • • • INX· MAKERS INC • COMPANY ~DRESS ...... , .•...•..•. 6681 BAST ~6TH STRSET COMMBRC:S,CA COMPANY PHONE ••• , ••••••••••• , • • • (213) 728-1500 TRADB NAME ...•....•.•.•....•.••. SOY SBT PRC>CBSS MAGENTA ............... .,.. * ...... * ••••••• **** ............ 'A' ....... '***'*,.. .................. --.... -.............. ... SIQTION 3 Ul\lWIDQYS UPREQICHIS I HAZARD PATA cmmt um W:JP!HI UY·UA im · ....... ~ ............................................ ~·** ..................................... _ •••••• SIC'XPli 4 R1JX'SICAL DAI.A BOiuXNG/MSLTING POINT •.. , ... , ••. 500-600 F VAPOR PRESSURE., .......•.•...•.. N/A VAPOR l:>E?iSI'l'Y ••••••••.•••••••••• HEAVIER THAN AIR {VOC} ~ PBRCEN'l'. VOLATILE BY .WT. • . LESS '!'HAN l-1 LESS THAN J.O GRAMS/LITER 8PBCIPIC GRAVITY 0~ BULK DINSI'l'Y ·WT./GA~.-8,3 # APP~OX. SOLUBILITY IN WATER ....•.••••.•• INSOLUABLE !VAPOAATlON RA'I'B; , , • , ••••••. ·• • • • SL0gf.ER THAN BUTYL ACETATB APP~B .•••.•.. , ••. I • • • • • • • • • R'ED PASTE OOOR ....... , ...... , . . • , .... , •..•• , • RBS IN6US ·~·-························-~·· .......................................................... . SIQ::tQN 5 r;BS »ID SXfI&S!ON HA?-A8P PATA FLiA.SH POINT op, , .• , ....•.. , . , , .. PLANMABLE CLASSfFICATION ....... . F,LAMMABILITY Ll:MI'l'S IN AIR (t V) ilXT!NGOISING MEDIA., .• , •• , •• ,.,. SPBCIAL FIRE FIGHTING PROCBDURES ABOVE: 230 ft CLASS 111a COMBUSTAB~E-NOT D.O.T.REGULATEO N/A. C02,0R~ CHEM!CAl,, FOAM,WAT.2RFOG WATBR MAY BB tNBFF£C'l'lVE BVT CAN' BE USBD TO ~L CONTAINBRS BXPOSBD TO H2AT OR Ft.AMX . UNUSUAL-FI.RB, EXPLOSION HAZARDS PROTECT CLOSED CONTAlNBRS FROM PRESSURE BUILD-UP AND POSSIBLE RAPTURE-MIEN BXPOSED TO EXTRM! HBAT *•** ... .,,,.. ...... .,, .. ** ....... ,,,. _.,,. *"'*'******· .,.. .......................... **"'*'* **· *•***** "'*** *'* , 31C'fIPX Z IMPGlfflCX ANQ ftR8T AIP PiPCIPXIBBS ·ma .. , ..... , luh • ~frctad-arta~ ,t tb riter tllilt rnoviDg comminated clothing. Get imudiate 1edical nttntion. Launder co11t111m1d clothing bt!ote rem. . 1ns ••••••.•. 11u1~. 1y11 with gtA1rov1 Jll)ijDtl of r1ter for it lt11t 15 1inut,s. Get i11edi1te medical attention. rx~1s1101 ...• 1f.!•1llo,!d1 DO JOT·l~D1CI VOffitrra •. D~lute ,tth water or 11ilk and call I phy1ician i11111edi1tely. re,ar give f 1 u2d1 or udm vo•H111i it tbt vict111 11 1111con1ciou1 or having convuhion,. mAwlnOJ ... llo~t to fm~ air. lid i11 bmthi111, if nmmy, aJJd get. i11~edi1te aedical attt.t1ti011. ··-~·~·· .. ················*·•*********·•·······~·············*~···~-····*****' SECTIQN :B ilA~XYITX PATA PRODUCT STAB?LITr, ••••.• , •••• , , • . STABLE CONDITIONS TO AVOID, ............ ~1,SP~KS,tLAMS OR EXCESSIVE TEMPBRATURJ CHBMICAL INCOMPA'.I"I·BIL!T'f. : • • • • • • S'n.ONG OXIDIZ:SRS p.4 'Dec ~8 ~004 11:50AM GIB t1,Ec-as.:i.2a04 •e":J :e6 ~M · ! INK MQKERS XNC ----:----"-------.-------;_J..;_.1.:;..•,.;,;:..;.....-__ 7S0S034296 1:5237283S59 P.0:5 sox s;rr PBCCISS &GENTA ***~*W*********••••••••••••••••••******~***********~*****•**~**************** SBc:t;tQN~ QAC,:IVIIX. PATA CONT' .O HAZARDOUS OBCOMPOSI~ION PRODUCTS CARBON OIOXIOE,CAABON MONOXIDB,OXI.OBS OF NITROG2N HAZAROOU'S POi.YMBRIZ~tION •....••• WILL NOT OCCUR. CORROSIVE TO MZTAL •••• , •.•.• , .•• N/A OXIDIZER, ••.••••••••••• , .••. , • • . N/A. ···························~·························•***·*····~············· lBSPlU!ORY PJOflC1!01 .•....• IOSI/M&ll· approved or11~ic .vapor reip!rator when vipor1 are 9ener1te4 a~ove th! per~i,eible liait. vr,rmnor .. , ................ ~ocll ellh1111t to co1trol to mor.ilde4 P .u. PIOTICflVI Cl.OTIIiG .•..••.• ,Gl~,e,, cortrtll,, 1pt0n1, booti · lS_nec1111r1 to pr&rtnt rkia contact. IYI liOtlCTIOI .............. Cheaicll gog-gln. ~!Ill Pl!CAUfIOIS, .•••.••••• Sbow1r afttr h&a4licg tlil prod~ct. Clein clothing ehO\lld be worn daily. iyew11h fo~nt1in1 ahovld be ndly mmible. ••••••••••••,•****•••-•••••••••••~•w•••****•*******~*••••*********•**********• ·&iC'tIPU 10 J?filB~ DATA SPIL~ OR LBAX PROCBI>URBe •••••••• WASTS DISPOSAL METHOD ....•••.•.• CONTAINER D!Sl)OSAJ:a ••.••••••.•••• THIS IS NOT A RBGutA~ED iRODUC'l'. SPILLS SHOOLI) BS CPNTAINBO,ABSORBEO,ANt> PLACBD IN SUITABLE CON'rAlNiRS POR DISPOSAL IN A LICEN$B]) PACXLITY AND IN ACCORDANCE WITH J:,,OCAL,STATE,AND FltDSRAL LAWS. INCINEAATB AND BURY AT A LICENSED FACILITY PO NO'l' DISCHARGE INTO WAnRHA\'S OR SEW.SR SlST.EMS~ . INCl~BRATE OR. SURY AT A LICBSlm FACILITY AND IN ACCORDANCE WITH LOCAI..,STA'tli:,ANI> FJj:OltEAL LAWS • p.5 ' Dec bB 2004 11: 51AM VEC-084 2804;09;07 ~M __ , GIA INK MAKERS INC -------.--.. -..--· 7606034296 P. 06 •*··················································~···*~····~•••••*••*** MAT BR I AL ~APE TY DAT A SHE BT ***•••••• . l N K MA~ BR s·, I~ C, qqq•••• **** ••• **********•••• ................. *'* *'* *'*** .......... .,,. ···~ ····-··· ,_, •••• ** •••• Latest Revision Oate •.• 08/19/02 SQX SC PRQQJSS XJ:Lipw Print date .. ,.;,., .•.•• 12/08/04 ****··········· .. ··········· .. ·········*········ .. ····~ .. ···••••****•••• .......... . SBC'lQN .l fi.QDU¢'r IPM+EICA'fIQH . PRODOC'I' N.A.tt2E .. t • • • , • • • • • t • • .. • • • I • COMP~-NAMt° • • • • • • • • .. • • • . .. .. ., • , • • COMPANY' APDRBSS. , •.••••••••••• , •• COi,tPAN'1 ·PRONE ••• , •• , •.•. , •• , , , ••. 'l'RAl)S N.AJ-f I.,• • • • 1 I • 1 ., a • • • • t 'a .. • t 1. t • INK MAKERS INC. 6681 BAST 26TH STRJET (219) 728-7500 . COMMERCE,CA ....................................................... *················ .. ········-····· $1CTIOl'f-3 HAaBPQOS XMiMPXBml I ffAZAAP DATA tHIIIUU ).......,n __ ill.Jll &IRQU.ULI PII ~--·····································*******••••••••**************•******* SICT;tQN 4 :eJiXSU:,U, PA.TA BOILING/MBLTING POINT., .•. , •• , •. 5()0-600 F VAPOR PR.BSSURE ...•••.. ,, , , ••• , •• ~/A VAPOR·DSNSITY .... , ..•• , .. ,, ... ,, HEAVIER THAN AIR (VOC}-~SRCBNT VOLATI~~ BY WT .•. LISS TliAN l t ·LESS THAN' 10 GRAMS/LITER SPBCIPIC GRAVITY OR BUliK DENSITY 8.2 #/GAL. APPROX. SOLUBILITY IN WATBR ........••..• INSOLOA8LS BVAPORA~ION AATB.,, •.........•.. SLOWBR THAN BUTYL ACETATZ APPBARAACB •.....•.• , •...••.• ,, •. YELLOW PASTE ODOR, • , •••• , •.••• ·, , •. , •••• , •••.• , RB.SINOUS ·····~*····························*******··················**********~······ SJcTrQN 5 ltRB A?W-l,XPtQSIQN UBMBP PATa PLASH POINT O 7!. . , • •. • • • • • • • • • • •• , ·PI.AMMABLB CLASSIFIC!AT!ON,, ..... . FLAMMABILIT\' I:.lMITS IN AI:lt ( I V) EXT;~UISING MEDIA,, ........ , .. . SPECIAL fIU FIGHTING PROCEDURBS UNUSUAL ,IRE & SXPLOSION KAZARDS ABOVE 230 P CLASS 111B COMBUSTABLE-NOT 0.0.T.REGUL~T!D N/A CO2,ORY CHEMICAL, FOAM,WATERFOG WATBR MA~ BE INBPFEc-l'IVE BUT CAN SE USED TO COOL COm"AIN'BRS BXPQSSl:J TO HEAT OR FLAMB _ PR0f2CT CLOSU> CONTAINERS FROM PRESSURE BUILD-UP AND POSSISLB RAPTURE WHBN EXPOSED TO IX'l'RMS HEAT ····****·····················••+••*******•*******~··························· ssa+AN 'Z R?gRGJNCX pp lIBS'X AlP PRQCEX?YUS urr ......... tub attecud nm with vmr while UU\li,g-mtuihated clothing. vet iMedhtt a1edical ittentian. Lmdu copea1ia,t1t clotbiag before re~1!. lliS .......... 1h11b eyu vith generous 111oa1t1 0! rater for tt Hut 15 rainutea. Get i11111ediat1 11edical 1tt111t1011. IKQISTlo, .... rr 1wallov,~, »o Rot rrouei ,onxrrr;. Dilute wit~ iiter·or mLlk end call, ptyaician i11t111di1tely. Jerer give !luidt or illdl!ce vo1H1111 U the victi, it momion or lltvLni tOD'f1Jlsiou. Ili1LlTIOJ •. ,Kove to treth 1it: lid ia bre,tking,. it ~•ce111y, ind git inedlate aedicil attention. •••••****•***••••••-••••~~*****•******•••••••••~~••••••••••••••••w• .. •••••w••• 81¢fIOH 8 iJ.'ACTXYI'll PATA PROPt,7CT STABILITY, ••••.•••• , , , • . ST~L:S · CONDITIONS TO AVOID •••..•.•••• ; , • ~IK1P,cSPARXS, .FLAMB OR BXC!SSIVI 'I'SMPSRATtraB p.6 'D~c ba 2004 ll:51RH GIA ~EC-08~2004•e9:~a ~M I . .., .., NK MFIKERS INC _______________ ....i,, ___ _____ ?606034296 l'.3237283~59 P.07 p.7 SQX SET UQCB$S Xit.lriQH ·················-······********•••••••*•*******·················~•********** SICTlotf ,g RPCTl.VITY PATA . CONT ID MAZAR.OOQ'S .OBCOMPOSITION PRODUCTS CARBON I>IOXIDB,CARSON MONOXIDl,OXIDSS OF NITROGBN HAZARDOUS POLYMBRtZATION •••• ,... WILL N01' OCCUR CORROSIVE 'TO METAL ••. I ' ••• I •• I • • N/ A . OXIDIZER ••.• ' ....• I • • • • • • • • • • • • • W/A ••••t•••*****•···········~··········••***••··························~······* SIO'IQN 9 WC:XAL PiQTECXION UlFOWl'lON RHPilATOU PJ011C1IOJ, ..•• ,.n0£1/KSiA· apprond org,nie vapor reapintor Oen vapm are gnmted &Do,.e tbt penimble · li1ie. \'IITIL1tror.. ....... , ........ Local 11b1U1t to coatrol to mounded P.J.L. PlOt!CTIVI c~OT!r5G., ••...•. Glave,, ~onr•111, 1pron1, b0ot1 • ,a nece1111y to pr!~tnt ekia ~ont1ct. IT! PROTICT!OJ •••••........• C~11ic1l go9gle1. OTHil PilCAUTIOIS .•.•.•.•••• Sho,er aftet b1~dlicJ thi1 ptodv~t. Cle1Q clothiag should be ,orn diily. BytWith fountain• · .abo~14.be 1asi1y 1c~t11i0lt, ****************··············~···~·····••*••···········-··~··*****•********* SJ$CT1Q?f 10 ENYIRQNMQTAt PATA SPILL OR LEAK PROCEDURES .. , ....• WASTE DISPOSAL M.BTKOD, .•..•...•• CONTAINBR DISPOSAL ...•...•...•.. THIS IS NOT A. RSGULATBD PRODUCT. SPILLS SHOULD BB ·CONTAINSD,ABSORB:2D,.AND PLACBP IN SUITABLE CONTA!NERS FOR.DISPOSAL IN A L?CBNSED FACILITY AND IN ACCORDANCS WITH LOCAL,STATZ,AND P'EDERAti LAWS. INCIN2RATB ANl') BURY AT A LICBNSBO FACILITY 1)0 Nor D?SCMARGB INTO WATE~WAYS OR SEWER SYSTEMS. INC1Nll:R.ATB OR BORY AT A LICBSBD PACILITY AND !N ACCORDANCE W!TH LOCAI.,STATE,ANI> FEDR:BAL LAWS. ~ Dec 08 2004 11:51AM GIA VEC-08~2084,89:08 AH _ .. _. ____ r __________ .,.,_:_"'~'2,:.,R_~ ... ~~:.---760603429S 132<572e<5·5S9 P.ea ****•**•*********•~••••*******•***************~******•*********•·········· MAT BR I AL SA F J TY O A·T A ·SHEET ••******* ! N K MAX·! R $, INC. gqq* .. *** **** ••• ** •••• ...,. ~ ....... * .. ·'*' "'*"'***• *** 1t ** ·-·;, ** •••••• .,,. ** *'* •• *'**** *'* * •••• ~~test aevision Date ... os/19/02 SOY SiT PROCSSS SIJ\CK :rrint date ........ , .. , .12/0 B/04 ............................................................................................ SICTIQH l iBQPI!cr IPBNl:IFICA'I'IQN PRODUCT NAME . • ..••.•• , , ••.••...• COMPANY -NAME •••• · .•••• , •••. ; ••• ;,, COMPANY ADO~BSS,,., ............ . COMP.ANY PHONE ...... ,, .••. ,, ....• INK M,>.KERS INC, 6681 EAST 26TH STREBT (213) 728•7500 COMMSRCE,CA TR,ADB N~B ,, .. ., ... t •••• , " t •• ' • I ... .. .............. ~ ........................................... **************•******** .. ** s1~10N_,l ~s Xtm&EPI£N'l'$ L HAZARD PATA CHQ!Clt WJISl JOKE cas, MUQEI _t ... Kt--Il.Y·l!l Ut..ill. iEPOttJJLi QIX SETIQN 4 BOILING/MELTING POINT .... , .... ,, VAPOR I'RESSURZ. . . . . . . . . • I • • • • I •• VAPOR. DENSITY •..•...• I I • I I •• I ••• J;~g~tr~~~~T;o~T;t~KB~~IITY SOLUBILITY IN NATER ............ , EVAPORATION RATS. I ••••••••••••••• APPEARANCE I •• ' •••.•• I • • • • • ••••••• ODOR. •.......... t •••••••••••••••• ' 500-600 P "n/A HEAVIER THAN AIR LBSS THAN 1 % -LESS THAN 10 GR,/LITSR WT./GAL, •• 8.4 # APPROX. INSOLUAllLE SLOWER THAN BUTYL ACSTATE BLACK PASTE , RESlNOUS ~·························*····················~*************************•••• &SCTIPM 5 lI&B NlP.IXRJ,Q8lQN AAZAAP PAIA P'LASH POINT 0 P, , , .• , , •.• , .• , . , , , FLAMMABLE CLASSIFICATION.,, ...•. F'LAMMABILITY ttMITS IN AIR (t V) EXTINGOISING-MSOXA ....•..•...•.. $PEC?AL FIRE FtGHTING PROCEDURES ABOVB 230 P' C!J!,.SS lllB COMBUSTASLE-NOT P.O,T,RBGUI.ATEO N/A C02,DRY CHSMICAL, FOM,~ATBRFOG ""ATSR MAY BE INEFFEC'l"IVB BUT CAN BE t7SBO TO coo~ CONTAINERS EXPOSBD TO HEAT OR 'FLAMS . t'1Q'USUJl.L FIRE• EXPLOSION HAZARDS PROTECT CLOSED CO~A!NERS FROM PRBSSURS SUtLD~UP llND POSSlBLB RAP'I't1RE WON !aPOSEO TO SXTRMS HBAT , * ** ,...,. ***'***"'**'*'*• * ............ , •••• * .,. • *** ................ ***•* ** ** ** * •*+•.,, ..... *** ..... * ... . SiQ'IQN 7 RJEBGJNCX AND FIBST UP EBQCEPUBSS mr. · ..... '. ,Wuh 1~!ected am~ rith ·mer rbile rmvillg coJJtui.oated clotbing. Get inediate 11edical attention. £&under co1t1~in1:e4 clothing before reu11, £YU .. ,··• ... r}iaa eye, with JtUTOUI JIOUnt1 cf lllte~ tor I~ lmt 15 infoutel. Get im;edhtt 11ediCil attelltion. lJGISTION •. · ,ff _!nllor!d, DO l'OT I~DUC! vo11m~G .. ll~lute wit~_vater or 1Hk nd call I phy11cha inediately. never give fltadt ar aduce Y~lli~ag .t the ,1ct1~ 11 \lllCOHC!OU er bJViDg COllVUlSiDIII, .,lwmzo,. · J!ove to ,tre,b, air. A1.d iD bnathillf, if memy,. •nd get imdine medi~al atte11ti0n. ,***"'·*············•••*••················~········~···············********~• BCTION a UACTI,vn·x PATA ·PlODOCT STABILITY .. , ....•.•..... STABLE · a~NDITIONS TO AVOID ........ ,,,,, HEAT,SPARXS,F~AME OR EXCSSSIVE T!MPBRA'I'UR! ,.;nEMICAL INCOMPA.TIBILin',, •...•• !511i:Jffa ,OXIDIZBRS p.8 'Dec 08 2004-11:SlAM GIA D~c-0s-~0e4 109 :09 i:tl'f ;;· I ·; , INK MAKERS INC I' I I~ __ : '!°"' __ :.__.....,:.__:!_ ___ .:..:.;.:".!{ • .:::} • \,L ... ~ ... ~•.!,:•,: _,,_ -• .- 7S06034296 132372835'59 P.0SI SQX SET .l?BOCl!iSS awt .............................................. *****•*****·***·"''*.,, ............... fr ...... **** ...... "'* ........ . aiCTIQN .a UACIXYXtt DATA CONT• O aAZARDOUS DBCOMPOSITION PRODUCTS CARBON DIOXID2,CA1U30N MONOX!DB,OX~DES OF NITROGEN HAZARDOUS.POLYMERIZATION .•...... WI~L NOT ocam CO.RltOSIVE TO MtTAL •••••..••. , ..• N/A OXlDIZlUt •••• , • • . • • • • • • • • . • • • • • • • N/A ...... ~ ...................... ~ ............ ~ ................................................... ~ ....... . ilCt:CQli i SRSCt;At RRPTBC'l::tQN UttOBMAIJQN XJSPIAA10RI PlOTICTlOI .•..... J1o;i/HSIA· approved organic tapor 1t1pirator whee vaport are gener,t,d ibove the perai,1able lilit. vnmmo1 ................. ~oell exhmt to c-ontrol tc mow,~ed P.1.L. ~aonmn CLOTiUG ......... Glover, covtnlh, 1prou, ~oon -u memry to prevent akin cont1ce. n• PIOTIC?!Of.,, ........... Clleilieal 90991u. OTHll f!ICAIITIOJS •.••••••••. Sh~war afttr ·halldliai this .product, Cle~, clotking should bt vorQ daily. Eye~a,h foun~a1n1 1hauld be t11ily 1ccet1i~le, •*···········~·••*••••············· .... ···································~···· 5:ECXIPN · lQ. ENVIRQNDHTAL. DUA SPILL OR LEAJC PRQCBDUUS .•.•.• · •• WASTI DISPOSAL METHOD ..••.•.•• ,. CONTAINER DISPOSAL .....•.....•.• TRIS IS NOT A RBGULATED PROtJUCT. SPILLS SHOULD BB CONTAIN!D,ABSORBSD,ANO PLACED IN SUITABLI CONTAINERS POR DISPOSAL IN A LICJfflSBD PACILITY AND IN ACCORDANCE WITH LOCAL,,STA'l'!,AND FEOBRAL LAWS. INCINERATE AND BURY A~ A LICENSED FACILITY DO NOT OISCHAII.GB INTO WATERWAYS OR SBWER SYSTFJtIS, INCINEAAT2 OR BURY AT A LIC~SEO FACILITY ~ IN J\CCORDANCE WITH LOCAL,STATS,AND FEOREAL LAWS. p.S • Dec bB 2004 11:52AM GIA 7606034296 MATERIAL SAFETY DATA SHEET The Anchor MSDS jn£ormatian provided on this site is updated on a monthly basis aJJd conplies with OSHA'-11 aa:a-rd Col!'dllw:iication St'l.tl<:ard ('CFR 1910, 1200) and t't.e American National seatiaa:rdll Institute (ANSI) Standard for ~taria.l Safety Data Sheets ·(,;Nst· Z4'00.1). Finished Goods C,atalog 2013 -AR$-1'1L AI,COHOt. SIJBSTITOTB Manufacturer Name 1JlC:!OR LI'.I1il<EMKO, A StJIISIDIARY OF F(JJI ·HtJNT SECTION 1 -COMPANY IDENTIFICATION Catalog/ Sul:1-asaelllbly Number: 2013 ANCHOR LI:TR!CEMIOO, A SUBSIDIARY OF FU.JI HONT sc Ifiduatrial t.oop North -orange Puk, FL 32073 'TAANSPOR'l'ATION EMBRGBNCIES 12',!l:R) rnsid• us/Canada 800-424-9300 Ou.tsid_e US/Canada 703-527-3887 (accept111 collect calls) MEDIC,U. :iM!t!WENCIBS (241G) Prosu-877-935-7387 ~-EMERGENCY- EHS Info General In~o 904-264-3500 800-354-2300 FOR lllDllSTll.IAL USE ONLY ••• , •• US:&: ONLY .AS DIRECTED._., •• DO NOT TAKE IN'rBBN.P.LLY! SECTION 2 --coMPOStTION / INFORMATION ON INGR,?DIENTS Ingreclienti. CAS Number Wt,\-,OSHA E'BL ACGIH (aj/ml) -(mg/r:13) Butyl Cellosolve 111-76-2 70-90, :140 skin 96.6 &ltin Gly~~l Adipat:.e Surfa~t-nt 9003-11-6 0,5-1,5\-)li: NJ Pxopylene Glycol 57-SS-6 0.5-l.S\-NE NE Wate:r 1732--18-5 7-l.'St l{E NB Acet:ylenic Oiol TSRN 3-71 NB NE 05995500- '84'20 NE=Mo·t E&tahlished STE!,,•Short Texm Bxposure Li1111'l:. C•Ceilin9 Limits SECTION 3 -HAZARDS IDENTIFICATION EMERGENCY OVBRVlEW i .............................. ******••• .................. *'**'*'*'* ............ _. ................ *•'** ........... ... AP~~aranoe, Clebr, color, aqu110u• liquid Odor, Mild Odor Avoid contact "'ith eye11, i.kin o'r clothing. Avoid breathing mist or vapor. Do Revisi9n Date ~ 09/22/20.0:,3 P~ge l p. 10 ' Dec 108 2004 11: 52AM GIA 7606034296 :ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJ,I HUNT -2013 -ARS-ML ALCOHOL ST,lBSTlTUTE not swallow. wear chetnictl safety goggles & neoprene gloves and apron. Wa6h thoroughly .after handling, 'Keep container elosed when not in use. Use only with adequate ventilation. May produce hazardous gasea ender fire conditioxie.. Duriog -rgencies, wear equipr.1ent to .pi-otect eyes, i;Jdn and respiratory tract. Dike or absorb spills to keep ~aterial: and: run•otf from entering sewer or wateniays. Use water spray to cooi containers and disperse vapors. Box may contain multiple ·containers having multi,ple components. Consult all V.SPSs. mus, He;ilth: 2 Plal1X!\!lbility, l Reactivity: 0 Protection: 3 "N?'PA: }lealth: 2 Fla1!11Nlbility1 ); 'Reactivity: 0 Spec. Raz., None l!aza:rd Rating: 0 • Mini,nal l -Slight 2 a.Moderate 3-. ·serious " "' severe A • Gloves B.,. tlloves f. Gogglea C" Gloves, Goggles i. Apron D • Faca Shield, Gloves, Goggles ".Apron UN 1110, None DOT GUIDE: ERG Guide 111 **'r••**•******•••••*~*•••~•r•**•••-•t*••~••••••~•••••••~•+w••••~9••~•••~•••• Potential Health Effects: Sk:in: Contact cause• irrita'tion. , Eyes: causes irritation. lnnalation, Irritant to respiratory tract and uucous membranes. lnge1tion: ·Inge11tion o'f produce. 111,Qy cause nausea and vomiting. Cortditions aggravated by expoaure, None expected except those ~saociated with acute effects. 'R SECTION 4 -FIRST AID MEASURES :Eye contac;:t, Skin Contact: physician. Illl!!\ediately flush with COOL water for 15 minutes. Call a physician. In ca~e of akin contact; wash with soap and water for 1s minutes. call a Ingeetiot'!, Seek illll!'ediate !n caae of ir:igestion; do not drink ~ater. Do not induce vomiting. medical attention. Call a physician. Inhalation: I11111ediately re1110ve victim to fresh air. Call & phyaician for further recommendllt: ions . SECTION 5 -'FIRE FrGHTING MEASURES FlatT1T1able Properties Plash l?oint: AutOi\;jnitibn Tlmparatu~e, Explosion Li~its, Lower: Upper: Extinguishing Media: ;,,~00 N/A NiA N/A Deg F O.eg F vol.t: vol.I 1 TCC ~CC) Net Tested Choose extinguishing media a~itabla for tbe av.nol.lllOing material•, cuch aa water spray, dry chemical, alcohol foam or carbon dioxide. Ur.suitable ~xtinguisbing 'Media: No reaeri ccioru1 on inedia based on knOwledge of· this materiAl, Fire Fighting Instructions: 'Water apray ahouldbe used to cool fire ·exposed containers a,id to diapsrse ur.-ignited vapora. Uae NIOSH/~SHA appro~d positive pressure self-contained breathing apparatus .wben material has ignited or becomes involved in a fire. Try to remove material: containers from tire area if can be accoTI1pliished without risk to personnel. Evacuate area .and fight fire from a safe distance. Call your local fire depa.r'crr,ent.. Wear positive prenure, breathing apparatus and proc.ect eyess and skin, Use water to cool .f~re-expoaed containers, to protect personnel and to disperse· vapors and spills. ·P'ire media -run-off can damage t:be environmen't:. ':like and collect media uaed to figl;t iire. Revision Date -09/22/2003 ·page 2 p. 11 ' Dec '08 2004 11:52AM GIA 7606034296 ' <I MtCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT -2013 -ARS-ML ALCOHOL SUESTI'.TUTE SECTION 6 -·ACCIDENTAL RELEASE MEASURES small Spills, For emall incidental spills aod leaks wear chemical ~afety goggles, and neoprene glovea and apron or coveralls. r1olate erea of a~ill by diking. Stop s~urce of leak. Adq. dry absorbent. Clean up and p1ace in an approved D .0-. T, container and seal. Mash all conta.minated clothing be:ore reuse, snd -diacard dontamina·ted· leather shoes. Large Spills: For larger spills requiring e111ergency response, neoprene boots and respiratory pr'oi:ec·tion may also 'be aquhed. 'Follow OSHA regulations and NlOSlt recommendations for :reepirator uee (29 CFR 1910-, 134 and NIOSH Pub. 87-l.08) and . eMergency response {aee 29 CPR 1910.120). Isolate area of spill by dild.ng. St:01> source of leak. A~ di:y absor~nt, Clean. up 40.d place in an 1.pproved D.O, T. container and seal. Wa•h all contall\itlated cl:o·thing before reuse, and discard conta~inated leather shoee .. Call the emergency telephone null\ber sl-.own on th• front of \:.bis aheet. · _SECTION 7 -HANDLING/ STORAGE tls.ndling: Avoid contact with eyes, skin or clothing. Avoid breathing miat or vapor, ·0o -not swallow, Wear cheic.cal safet,y· goggles and neoprene glove8 and apron, Wash thoroughly after handling. Keep container closed ~hen not i.ri use. Ose only with adequ.,te ventilation, Storage: Store in a cool, d:z:y, well-ventilated area away from all sources of ignition, Keep·c®~ainer~ closed when no~ in use. SECTION 8 -EXPOSURE CONTRO~ AND PERSONAL PROTECTION Venl:.ilat:.ion: Good general ventilation should be sufficient for most processing operations. Vent work area to eMute airbetne eor,,cefitratio_n; are below· th~ current occupational exposure limits. Ten {10) or lTIOre room air c'hanges per hour containing a minimWTt of 1$% fresh air wil.l meet these requirements. consult: :11.SlmAR 62-l-9B9 for further :equirements. Personal P~otective Bquipment Respiratory Protect.ion: If uaed UDder normal operating.conditions and with adequate ventilation, respiratocy prot:acticn i& Pot. :required. llowever, i:-efer to OSBA '29 CFR l9l0.l.3 "· Skin Protecciom 'Eye 'Protection, Che1ni_cai resistant:. gloves Chemical aafety goggles SECTION 9 -PHYSICAJ, A1>.'D CHEMICAL PROPERTIES Appearance: ciear, color, aqueous liquid Odo:r, Mild odor - Char.g~ in Physical Boiling P?i.nt, Melting l'oint: Specifl~ Gravity: Vapour Pressure: State,1 >100 N/0 0.92 NP Viscosity, So1ubi1ity in Water: ·!lii va.1...,,., N/A 1ooti ND voe lll:ls/gail : 6.48 deg C deg F Water•l 1!lllHg Iii ·2oc (USEPA Method 2-4) SECTION 10 -STAJ3ILITY ANO REACTIVITY Hazardous Polyl!l&rization: Hazardous polymeriza~ion ~ILL NOT occu:c if product: is used and stored as Revision Date~ 09/22/2003 Page 3 p. 12 ' Dec 108 2004 11: 52AM GIA 7606034296 ¢ "-' ANCHOR LITHKEMKO, A SUBSIDIARY OF FUJI HUNT -2013 ARS-ML ALCOHOL SUBSTITUTE directed. ~reduct i• stable if used aod stored. as.directed. Hazardous Decorrpo.sition Products: Oxides of Nitrogen; Oxides of Carbon Materials and conditions to Avoid: Xeep contai~rs a.nd liquid• away from all _pccential sources of.ignicior., Kee~ aw~y fro~-exceas beat. Avoid contact ~ith strong oxidizers, strong acids and strong bases. SECTION 11 -TOXICOLOGICAL INFORMATI'ON Product Information LDSO {oral, rat}: No Data Available Aeute Overexposure: Skifl:, eye, mucous membrane and respiratory tract irritant. Cb~onic overexposure: ·~rolongad or repeated skin contact may cause allergic reaction and dermatitis. Ingredient info:rmation, Chronic overexposu::re to -au·tyl C:etloeolve in high concentrations has caused anemia, liver and blood abnor~a.litieg, and kidney and lcng damage in laboratory· animals:. may cause maternal toxicity. SECTION 12 -ECOL0GICAL INFORMATION Ecotoxicity Data: No Data Avail.able ·chemical Fate Data: No Data Avaiiable SECTION 13 -~ISPOSAL CONSID~RATIONS ~az~rdous Waste Charactaristic: Ncina Reco!Mletld:ltion, Dispose o~ contaminated prcduct, empty containers·~ materials used in cleaning up sp~lla or leaks in a manner approved for this material. consult appropriate federal, a'tate and local regula'tory agencies to ascertain proper ·disposal procedures. Discharge of proce~sing effluent to the se~er may require a per.nit. DO NOT discharge effluent solutions to septic systems. SBCTION l4 -TRANSPORTATION INFORMATION Ground Shipping Information Proper shipping :Mame: Che11ica.ls, N.d.l., Not D.O.T. regulated,. Hazatd c1a~s1 None W/NA Number: None P.tcking Group: None Ai.er '(Iel!.0/Il\TA) Shipping lnforma'tion Proper Shipping Name: Chem~cals, N.O.I., Not D.O.T. regulated. Hazard Class: None tlN No: None Packing Group: None Subs-idiary Risk: None trN/DO'I' Label• Needed-: llone Inteniational Maritime Organization (IMO) Additional Shipping Clase: IMDG Code: Not Applicable J>.mdl:. Code: Aa\dt. N/'A R'l'S Code, Not ilipplicable Product is lllbel6d in accordance with us .D.O.T. 49 CFR. F~rther information: Fleaee can (904) 26'4-3500 for further o.o.T. infc:irmation. Revision Date -09/22/2003 .Page 4 p. 13 ' Dec •as 2004 11: 52AM --,,.. -r -,._ -· ---·· . -· . GIA ?606034296 ANCHOR LITHKEMKO, A SUBSIDIAR'll' OF'FUJI HUNT -20i3 -ARS-ML luiCOHOL SUBSTITUTE SECTION 15 -REGUIATORY INFORMATION· '*·*Note: The ingredient infonation listed. in thie. aection i,;f p:rovided for reporting requirement a as dictated by USEPA, state and -local regulation. lf · in~~editmt is liated in this 1ection ·but not in sectioti 2, then the concentration of this ingredient ia below de minumis (less than O.lt). U.S. FEDERAL RBGULAT!ONS1 313 • SARA Title III section 313 (GO CFR, 372 355 • SARA Title III Section 302 (40 CFR 355 302 • SARA Title II,I Section 304 (40 CFR 302 Toxic ~elease :Inventory) Extremely Hazardous Substance} Hazardoue substance List} CWA • Clean Water Act Priority Pollu~anta Lise CAA • Cl.ean Ai:r Act 1990 lfazarci011e Air COC1taminents HAP • Cl~an Air Act -HON Ru.le -:HAPS Ingredients O.S Number 313 355 Butyl Cellosolve lll-76-2 y N Glycol· Ad,ipa'te Surfactant 90113-11-5 N N Propylene Glycol 5?-55-6 N N Water 7732-18-5 N N Ace'tylenic biol TSRN N N 05995500- S420 TSCA 12 (b)· Export Notitication CAS NUMBER ·CHEMICAL Nl\ME 107-21-1 'STKXLBNE GLYCOL TOXICITY INFORMATION: IRCl • IARC Group l Hu!fl&tl Carci~091ot!D LiBt 302 OlA y N N N N lll N N N N :tRC2 • IAAC Group 2 Human Carcinogena List (lin1ited hl.lltlan data) CAA y N N N N IRC3 • IARC Group 2~ Human CArcinogens Liet (~~fficient animu data} 'N'rP "' NTl> lCnown Carcinogens List OSHA= OSHA Known· Carcinogen• Li&t Ingredienta CA.S Nun,ller IRCl IRC.l IRC3 NT!? OSHA 'Butyl Ce;llosolve lll-7&-2 'N 11 N N 11 Glycol Adipate Surfactant 9003-1'1-6 N N 'N· N N Propylene Glycol 57•55-6 N ll N N }I Water '77:l2-l.ll-5 'N ll N N N Acetylenic: Diol TSRbl N N N N '}! 0S995500- S420 STA1E REGut.ATIONS: HAP y N N N N PL-= Florida Hazard01J.a Substance Li11t ·MA • Masliachu11etts Ri'ght-To-KnO'lf List MI-. Michigan critical Materia.ls List MN• Minneso1=,a Hazardous Substance List NJ• New Jersey Right-To-Xnow List PA• Pennsylvania Right-To-Know List Ingredients CAS N\lnlber PA NJ MN MI MA FL Butyl Cellosolve n1-16-2 )'. y y N 'l '[ Glycol Adip,ate Surfactant 9003-U-6 N 1-i N N N N l?ropylene Glycol 57-55-6 y N y N N N ·water 7732-18-5 N, N N N N N Acetylenic Diol TSRN }I N N N N N 05995500- S'120 The following-designation is used only for those facilities that have air permits in oonattainment areas for ozone t Non-Photochemically Reactive Revis-ion Date -09/22/2003 Page 5 p. 14 c Dea'OB 2004 -ll:52AM GIA -··---·-· ... ·-·· ?SOSO342SS . _ANCHOR LITHXEMKO, A SUBSIDIARY' OF ruJi HUNT -2013 -ARS-ML ALCOHOL SUBSTITUTE SECTION l~ -OTHER INFORMATION This information is provided ~ithout warranty. The information is believed to be -correct. This :l.nfo:rmation should ·be uaed to :make an inciepeDdent aeterrnitiatit>n Of the mtit:hode to safeguard wo~ke·ta atid. the enviro~nt. Revision Date -0'3/22/2003 Page 6 p.15