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Home My WebLink About2271 COSMOS CT; ; CB950455; Permitn n T r n T N G PERMIT Permit No CB950455B U I L, D I N G P h K M -L project. No A9500651 05/31/95 15 04 Development No Page 1 of 1 0,,,4-pJob Address 2271 COSMOS CT Suite Permit Type INDUSTRIAL TENANT IMPROVEMENT 211005/31/95000101 02 Parcel No 213-050-41-00 ^-^ C_PRMT 2465-00 Valuation 471,484 Construction Type II1N a™rP# Status ISSUED Occupancy Group B-2 Hetuicnc.ff Applied 04/03/95 Description 18134 SF T 1 Apr/Issue 05/31/95 Entered By MDP Appl/Ownr BUCHANAN, TED 519 438-9222 2632 LUCIERNAGA STREET, CARLSBAD, CA 92009 "' --,.,. j <„. '" .-'>**//"" //,y«>esN Collected S> Credits •«** *** Fees Required *•**- '.'-.HVrils-ll---^-^ -< Fees 3,727.0CT /^ Tnt-aV^r^ts-\ 00 Adjustments ,' y ^ --/^ T^ >?S& - \ 1,26200 Total Fees f''r .;; '" ' :''7'v-;. -,.„; /Balance/Due. v 2,465 00 ' M~-.- / ' " uV Units-/'. F^ee^Uni't Ext fee DataFee description ; , - ....:; / x-.,-^... •<. :^.::-'.:':~:'-~^ ^^/_ ; }.^?_s_ 1 r-—r-r- ^ :~ ^/^' // ,,,\ *:-•- -i 1 1942 00Building Permit | p - .. - £ ^ . .- ^. i ,r y} , 12b2 OQ Plan Check | \;-:-/ ; ,\4*^ •*/• *? \''r,'! v X ; S3 00 Strong Motion Fee \ <^_ /;..- "i ^ //9/-<C\'" / ' / 327 00 Additional Plan Check Fees-,; ' ^ ;;., > ,, '], ,; ^ (,' c^V.;;./ / / 3630 00 * BUILDING TOTAL ^ \ xx, 7c "' % I: \. ,' ,. / N Enter "Y" for Plumbing Issue Fee/ VX «.^t,-•-'. - / 10 00 Y Enter "Y" for Electrac Issuex/ee >:,:."..,,...„ /r , 2S so'0o Remodel/Alter Per AMP, ;,. "v . -x > i?,: .^wu<-, \'V-' V"^ 60 00 , * ELECTRICAL TOTAL VV'^-'V* > "^ ""- '-AX-V-"'"' / ^ 15 00 YEnter 'Y' for Mechanical IssuevFee> , , i:, , \ -.,; ' / g Q0 Install Furn/Ducts/Heat Pump si ;, // /> •••. / (' '> ;\ ..V ^ ••- ^. ' » ^ 13 Q0 Each Exhaust Fan " - , :> '••-•••'' '"' ••"' " 37 00 * MECHANICAL TOTAL " _ - ' em APPROVAL L'NSP. A~ DATE CITY OF CARLSBAD 2075 Las Palmas Dr , Carlsbad, CA 92009 (619) 438-1161 PERMIT APPLICATION City of Carlsbad Building Department 2075 Las Paltnas Or , Carlsbad, CA 92009 (619) 438-nei 1 PERMIT TYPE 1 A O COMMERCIAL QNEW ^TENANT IMPROVEMENT B D INDUSTRIAL DNEW D™*"1 IMPROVEMENT c PRESIDENTIAL DAPARTMENT QCONDO QSINGLE FAMILY DWELLI DDUPLEX [^DEMOLITION DISLOCATION QMOBILE HOME QEL DMECHANICAL np°°L DSPA DETAINING WALL QSOLAR NG OADDITION/ALTERATION ECTRICAL QPLUMBING |~1 OTHER 2. PROJECT INFORMATION PLAN CHECK No <AS i s b a-) i t/f-VEST VAL 7 / I, <-{. \ ' _ PLAM CK DEPOSIT / / L f^O *— VALID BY ^-\\'\le^\ f^ DATE ' I A'jQW 1324 04/03/95 0001 01 02 C-PRMT 1262.00 FOR OFFICE USE ONLY Address 2<Z^( Nearest Cross Streets LOS LEGAL DESCRIPTION Lot 1 <: CHECK BELOU IF SUBMITTED RB2 Energy Calcs L% ASSESSOR'S PARCEL -^ 1 * jo Subdivision L MAJ ! Structural Calcs ?> - O *>€> - - Name/Number Unit No d2 Soils Report Ql Addressed Envelope ^.| CO EXISTING USE Phase No PROPOSED USE DESCRIPTION OF WORK , BLDG SO FTG \ , 3. 4 5 6. 7 CONTACT PERSON , NAME-fEO A i^UC-HAlsJ AN! i A^OT. ADDRESS "Z^^Z. L-U C\ E^. Si A>6j A "^T. CITY ^. ' *& A^ STVf ZIP CODE ^\'%fOOC\ DAY TELEPHONE ^ ^ & - ^ Z. ?S "^ZL- SIGNATURE <~>L ^>V ^1 - J^> US jL OC^\OL^^ APPLICANT Q CONTRACTOR PROPERTY OWNER ,,ki AUC ^w A L i^1™ 19 x^ C^T^ ^yy E. 1 19NAMb r? Jm^Ji^ -- ^~ C^ | | | | | o( |*» ^ ciTYVlAwiUATTAia RBAC.M CONTRACTOR _ ^ ..:;:: DPk STATE LIC # SIGNATURE DESIGNER NAME CITY WORKERS' COMPENSATION D AGENT FOR CONTRACTOR gjfoWNER Q AGENT FOR OWNER Cr» . ADDRESS A(t-*»v/ «* STATE ZIP CODE ^J "2.O 6&* DAY TELEPHONE ^" ^ [- ( ^^ | OWNER OLESSEE GTENANT ADDRESS 1 I I 2. £>Ol2,ANf "0(2* . STATE CA zlp CODE ^\O ?-Z-£^ DAY TELEPHONE ADDRESS STATE ZIP CODE DAY TELEPHONE LICENSE CLASS CITY BUSINESS LIC # TITLE DATE ADDRESS STATE ZIP CODE DAY TELEPHONE STATE LIC # Workers' Compensation Declaration I hereby affirm that I have a certificate of consent to self insure issued by the Director of Industrial Relations, or a certificate of Workers' Compensation Insurance by an admitted insurer, or an exact copy or duplicate thereof certified by the Director of the insurer thereof filed with the Building Inspection Department (Section 3800, Lab C) INSURANCE COMPANY POLICY NO EXPIRATION DATE Certificate of Exemption I certify that in the performance of the work for which this permit is issued, I shall not employ any person in any manner so as to become subject to the Workers' Compensation Laws of California SIGNATURE DATE 8 OWNER-BUILDER DECLARATION Owner Builder Declaration I hereby affirm that I am exempt from the Contractor's License Law for the following reason [""] I as owner of the property or my employees with wages as their sole compensation, will do the work and the structure is not intended or offered for sale (Sec 7044, Business and Professions Code The Contractor's License Law does not apply to an owner of property who builds or improves thereon,, and who does such work himself or through his own employees, provided that such improvements are not intended or offered for sale If, however, the building or improvement is sold within one year of completion the owner builder will have the burden of proving that he did not build or improve for the purpose of sale ) P"l I as owner of the property, am exclusively contracting with licensed contractors to construct the project (Sec 7044 Business and Professions Code The Contractor's License Law does not apply to an owner of property who builds or improves thereon, and contracts for such projects with contractor(s) licensed pursuant to the Contractor's License Law) [~] I am exempt under Section Business and Professions Code for this reason (Sec 7031 5 Business and Professions Code Any City or County which requires a permit to construct, alter, improve demolish, or repair any structure, prior to its issuance, also requires the applicant for such permit to file a signed statement that he is licensed pursuant to the provisions of the Contractor's License Law (Chapter 9, commencing with Section 7000 of Division 3 of the Business and Professions Code) or that he is exempt therefrom, and the basis for the alleged exemption Any violation of Section 7031 5 by any applicant for a permit subjects the applicant to a civil penalty of not more than five hundred dollars [S500]) SIGNATURE DATE COMPLETE THIS SECTION FOR MOM RESIDENTIAL BUILDING PERMITS ONLY Is the applicant or future building occupant required to submit a business plan, acutely hazardous materials registration form or risk management and prevention program under Sections 25505 25533 or 25534 of the Presley Tanner Hazardous Substance Account Act' Is the applicant or future building occupant required to obtain a permit from the air pollution control district or air quality management district7 DYES QNO Is the facility to be constructed within 1,000 feet of the outer boundary of a school site' DfES QNO IF ANY OF THE ANSWERS ARE YES, A FINAL CERTIFICATE OF OCCUPANCY MAY NOT BE ISSUED AFTER JULY 1 1989 UNLESS THE APPLICANT HAS NET OR IS MEETING THE REQUIREMENTS OF THE OFFICE OF EMERGENCY SERVICES AND THE AIR POLLUTION CONTROL DISTRICT i CONSTRUCTION LENDING AGENCY I hereby affirm that there is a construction lending agency for the performance of the work for which this permit is issued (Sec 3097Ci) Civil Code) LENDER'S NAME LENDER'S ADDRESS 10 APPLICANT'S SIGNATURE I certify that I have read the application and state that the above information is correct 1 agree to comply with all City ordinances and State laws relating to building construction I hereby authorize representatives of the City of Carlsbad to enter upon the above mentioned property for inspection purposes I ALSO AGREE TO SAVE INDEMNIFY AND KEEP HARMLESS THE CITY OF CARLSBAD AGAINST ALL LIABILITIES JUDGMENTS, COSTS AND EXPENSES WHICH MAY IN ANY WAY ACCRUE AGAINST SAID CITY IN CONSEQUENCE OF THE GRANTING OF THIS PERMIT Expiration Every permit issued by the Building Official under the provisions of this Code shall expire by limitation and become null and void if the building or work authorized by such permit is not commenced within 180 days from the date of such permit or if the building or work authorized by such permit is suspended or abandoned at any time after the work is commenced for a period of 180 days (Section 303(d) Uniform Building Code) APPLICANT'S SIGNATC/^T'! T [OWNER QCONTRACTOR PHONE APPROVED BY DATE WHITE File YELLOW Applicant PINK Finance PERMIT! CB950455 DESCRIPTION: 18134 SF T.I, CITY OF CARLSBAD INSPECTION REQUEST FOR 02/01/96 TYPE: ITI JOB ADDRESS: APPLICANT: CONTRACTOR: OWNER: 2271 BUCHANAN, COSMOS TED CT PHONE: PHONE: PHONE: INSPECTOR AREA TP PLANCK# CB950455 OCC GRP B-2 CONSTR. TYPE 11 IN STE: /"•) LOT: 619 438-922: REMARKS: MW/TERRY/740-7579 SPECIAL INSTRUCT: INSPECTOR TOTAL TIME: —RELATED PERMITS— CD 19 29 39 49 PERMIT! CB880631 SE940025 AS940018 CB940416 FS950011 AS950041 FAD95009 CB951775 CB960116 TYPE ELEC SWOW ASTI ITI FIXSYS ASTI FADD MISC ELEC STATUS EXPIRED ISSUED ISSUED EXPIRED ISSUED ISSUED ISSUED ISSUED ISSUED LVL DESCRIPTION ST Final Structural PL Final Plumbing EL Final Electrical ME Final Mechanical ACT COMMENTS ***** INSPECTION HISTORY ***** DATE DESCRIPTION 011896 Final Combo 081795 Final Combo 081795 Final Combo 073195 Final Combo 072795 Final Combo 071995 Frame/Steel/Bolting/Welding 071995 Rough Electric 071795 Frame/Steel/Bolting/Welding 071795 Rough/Topout 071795 Rough/Ducts/Dampers 071795 Rough Electric 071395 Frame/Steel/Bolting/Welding 071395 Rough Electric 071195 Interior Lath/Drywall 071095 Exterior Lath/Drywall 071095 Rough Electric 070795 Rough Combo 070695 Shear Panels/HD's ACT CO NR CO CO CO AP AP CO CO CO CO CO CO AP AP AP NR AP INSP TP TP TP TP TP TP TP TP TP TP TP TP TP TP TP TP TP TP COMMENTS TITLE 24 ISSUES NOT RESOLVED SEE NOTICE TITLE 24 ISSUES 1 HR T-BAR GRID 1 HR TILE WRAP/2X4 LITE FIX LITE WELL 1HR ENCSMNT @ TEAR APPL'N OVR CEIL LITES INCOREC ENDURANCE RM ENDURANCE ROOM RELOCATE LITES § ENGR RM NOT READY @ SITE INT PNLS @ ENDUR RM 02/02/96 INSPECTION HISTORY LISTING FOR PERMIT* CB950455 DATE INSPECTION TYPE 02/01/96 Final Combo 02/01/96 Final Combo 01/18/96 Final Combo 01/18/96 Final Combo 08/17/95 Final Combo 08/17/95 Final Combo 08/17/95 Final Combo 07/31/95 Final Combo 07/27/95 Final Combo 07/27/95 Final Combo 07/19/95 Frame/Steel/Bolting/Wel 07/19/95 Frame/Steel/Bolting/Wel 07/19/95 Rough Electric 07/17/95 Frame/Steel/Bolting/Wei 07/17/95 Rough/Topout 07/17/95 Rough Electric 07/17/95 Rough/Ducts/Dampers 07/17/95 Rough Combo 07/13/95 Frame/Steel/Bolting/Wel 07/13/95 Frame/Steel/Bolting/Wei 07/13/95 Rough Electric 07/11/95 Interior Lath/Drywall 07/11/95 Interior Lath/Drywall 07/10/95 Exterior Lath/Drywall 07/10/95 Exterior Lath/Drywall 07/10/95 Rough Electric 07/07/95 Rough Combo 07/07/95 Rough Combo 07/06/95 Shear Panels/HD's 07/06/95 Shear Panels/HD's 07/03/95 Shear Panels/HD's 07/03/95 Shear Panels/HD's 07/03/95 Interior Lath/Drywall 07/03/95 Interior Lath/Drywall 07/03/95 Interior Lath/Drywall 06/30/95 Frame/Steel/Bolting/Wei 06/30/95 Frame/Steel/Bolting/Wel 06/30/95 Rough Electric 06/30/95 Rough Electric 06/29/95 Interior Lath/Drywall 06/29/95 Interior Lath/Drywall 06/27/95 Frame/Steel/Bolting/Wel 06/27/95 Frame/Steel/Bolting/Wel 06/27/95 Rough Electric 06/27/95 Rough Electric 06/22/95 Shear Panels/HD's 06/22/95 Shear Panels/HD's 06/22/95 Frame/Steel/Bolting/Wel 06/22/95 Frame/Steel/Bolting/Wel 06/22/95 Rough Electric 06/22/95 Compliance Investigatio 06/21/95 Rough/Topout 06/20/95 Frame/Steel/Bolting/Wel INSP ACT COMMENTS RI TP RI TP RI TP TP TP RI TP RI TP TP TP TP TP TP RI RI TP TP RI TP RI TP TP RI TP RI TP RI TP RI TP TP RI PK RI PK RI PK RI TP RI TP RI TP RI TP TP TP TP RI RI AP RI CO RI NR CO CO RI CO RI AP AP CO CO CO CO RI RI CO CO RI AP RI AP AP RI NR RI AP RI CO RI AP NR RI PA RI PA RI PA RI AP RI AP RI AP RI AP AP PI PI RI MW/TERRY/740-7579 MW/TERRY/740-7579 BJN/TERRY/740-7579 TITLE 24 ISSUES NOT RESOLVED SEE NOTICE MW/TERRY/740-7579 TITLE 24 ISSUES MW/TERRY/740-7579 1 HR T-BAR GRID 1 HR TILE WRAP/2X4 LITE FIX LITE WELL 1HR ENCSMNT @ TEAR RS/TERRY/740-7579 MW/TERRY/740-7579 APPL'N OVR CEIL LITES INCORECT MW/TERRY/740-7579 ENDURANCE RM BJN/TERRY/740-7579 ENDURANCE ROOM RELOCATE LITES § ENGR RM RS/TERRY/740-7579 NOT READY § SITE RS/TERRY/740-7579 INT PNLS § ENDUR RM RS/TERRY/740-7579 SHORT NAIL INT.ENDUR RM RS/TERRY/740-7579 INTERIOR OFFICES NOT READY RS/TERRY/740-7579 NON-RATED OFFICES RS/TERRY/740-7579 NON-RATED OFFICES RS/TERRY/740-7579 SHAFT LABS ONLY MW/TERY/740-7579 ENDURANCE RM MW/TERY/740-7579 WALLS END RM MW/TERRY/740-7579 ENDUR RM EXT MW/TERRY/740-7579 ENDUR RM GUSSETS CEILING LITES R & D CONF ON 1 HR LOBBY DRINK FOUNTAIN HANOI-REQ MW/TERRY HIT <RETURN> TO CONTINUE... 02/02/96 INSPECTION HISTORY LISTING FOR PERMIT* CB950455 DATE INSPECTION TYPE 06/20/95 Frame/Steel/Bolting/Wel 06/20/95 Frame/Steel/Bolting/Wel 06/20/95 Rough/Topout 06/20/95 Rough/Topout 06/20/95 Rough Electric 06/20/95 Rough Electric 06/16/95 Frame/Steel/Bolting/Wel 06/16/95 Frame/Steel/Bolting/Wel 06/14/95 Frame/Steel/Bolting/Wel 06/14/95 Frame/Steel/Bolting/Wei 06/14/95 Frame/Steel/Bolting/Wel 06/14/95 Rough Electric 06/14/95 Rough Electric 06/12/95 Shear Panels/HD's 06/12/95 Shear Panels/HD's 06/12/95 Frame/Steel/Bolting/Wei 06/12/95 Rough Electric 06/12/95 Final Electrical 06/12/95 Final Electrical 06/12/95 Compliance Investigatio 06/09/95 Compliance Investigatio 06/08/95 Compliance Investigatio 06/06/95 Frame/Steel/Bolting/Wel 06/06/95 Interior Lath/Drywall 06/05/95 Interior Lath/Drywall 06/05/95 Exterior Lath/Drywall 06/05/95 Exterior Lath/Drywall 06/01/95 Rough Combo INSP ACT COMMENTS TP TP RI TP RI TP RI PK RI TP TP RI TP RI TP TP TP RI TP TP TP TP TP RI PD RI PD RI AP AP RI AP RI AP RI CO RI AP AP RIwe RIwe PA AP RIwe PI PI PI AP RI PA RIwe RI SHAFT RM A-35 § ENDUR.RM EXT. MW/TERRY F.S.RELOC @ RM 111 MW/TERRY SHAFT RM MW/TERRY UTL SUPT/NO SIGNOFF/TILE IN MW/TERRY/740-7574 DBL SHR @ GRIND RM & ENDUR LAB GUSSETS@GRIND RM/ATTCH § STUDS MW/TERRY/740-7574 MW/TERRY/740-7579 WALLS SHARD GRIND RM LG CO SM WALLS SHARD GRIND RM LG MW/TERRY/740-7579 CORR REVIEW CONF. 1 HR WALLS, CONF. WALLS N/INCL 1 HR CORR MW/TERRY/740-7579 BJN/PERRY/740-7579 MW/TED HIT <RETURN> TO CONTINUE... CITY OF CARLSBAD BUILDING DEPARTMENT NOTICE DATE "7/7 /A )" LOCATION PERMIT NO. 438-3550 2075 LAS PALMAS DRIVE TIME <~ r "fts FOR INSPECTION CALL 438-3101 RE-INSPECTION FEE DUE? FOR FURTHERJNFORMATION, CONTACT YES PHONE BUILDING INSPECTOR CODE ENFORCEMENT OFFICER i CITY OF CARLSBAD NO BUILDING INSPECTION DEPARTMENT 000125 JOB ADDRESS CENUS TRACT NO PERMIT NUMBER PLAN FILE NUMBER CONTRACTOR V OWNER OR PERMITTEE NAME MAIL ADDRESS FOR ~ OWNER OR C CONTRACTOR D VIOLATION READ REVERSE SIDENOTE PRESENT THIS NOTICE WHEN MAKING APPLICATION FOR PERMIT D D D D NO PERMIT - STOP WORK - REMOVE CONSTRUCTION, OR OBTAIN PERMIT AND MAKE ANY WORK COMPLY WITH BUILDING LAWS (See comments on reverse side regarding penalty fees) CONSTRUCTION NOT IN ACCORDANCE WITH APPROVED PLANS AND PERMIT - STOP WORK MAKE EXISTING WORK COMPLY WITH APPROVED PLANS AND PERMIT OR REMOVE IT CALL PLANING DEPARTMENT AT 438-1161, CONCERNING VIOLATION OF ZONING REGULATION LISTED BELOW STOP WORK - UNTIL AUTHORIZED TO CONTINUE BY THE INSPECTOR CONTACT CODE ENFORCEMENT OFFICER AT 438-1161 D CONTACT INSPECTOR AND ARRANGE FOR APPOINTMENT AT 438-3550 D CORRECTIONS LISTED BELOW MUST BE MADE BEFORE WORK CAN BE APPROVED D PAY REINSPECTION FEE (See Back), THEN D CALL FOR REINSPECTION AT 438-3101 D CORRECTIONS REQUIRED PARTIAL APPROVED D WORK DESCRIBED BELOW HAS BEEN INSPECTED AND IS APPROVED f} ^ ^ r ^ THE ACTIONS OR CORRECTIONS INDICATED ABOVE ARE REQUIRED WITHIN MUNICIPAL CODE REQUIRES PENALTY FEES WHEN WORK HAS BEEN STARTED WITHOUT PERMIT . DAYS THE CARLSBAD IN 13 (Rev 2/86) OFFICE TEL NO 7 00 A M TO 8 00 A M 300PM TO 4 00 P M MONDAY THRU FRIDAY BUILDING ELECTRICAL HEATING PLUMBING REFRIGERATION COMBINATION ESGIL CORPORATION 9320 CHESAPEAKE DR., SUITE 208 SAN DIEGO, CA 92123 (619) 560-1468 DATE May 31, 1995 JURISDICTION Carlsbad PLAN CHECK NO 95-455 SET IV PROJECT ADDRESS 2271 Cosmos Ct. PROJECT NAME Taylor Made Golf TI and Addition (APPLICANT JURISDICTION a PLAN REVIEWER a FILE X] The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person The applicant's copy of the check list has been sent to Esgil Corporation staff did not advise the applicant that the plan check has been completed Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Ted Buchanan ephone # apptDate contacted 5/31/95 (by kc) REMARKS 1 The architect mked-m the tfqyss shown on the plans 2 Plans hand-carried by the architect to the City By Kurt Culver Esgil Corporation Q GA D CM Enclosures PC log trnsmtl dot ESGIL CORPORATION 9320 CHESAPEAKE DR., SUITE 208 SAN DIEGO, CA 92123 (619) 560-1468 DATE May 25, 1995 a APPLICANT JURISDICTION Carlsbad a PLAN REVIEWER a FILE PLAN CHECK NO 95-455 SET III PROJECT ADDRESS 2271 Cosmos Ct. PROJECT NAME Taylor Made Golf TI and Addition The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person 2<j The applicant's copy of the check list has been sent to Ted Buchanan 2632 Luciernaga St Carlsbad 92009 Esgil Corporation staff did not advise the applicant that the plan check has been completed Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Ted Buchanan Date contacted 5/z£ (by Kc ) Telephone # 438-9222 REMARKS By Kurt Culver Enclosures Esgil Corporation n GA n CM n PC 5/18/95 tmsmtidot Carlsbad 95-455 III May 25, 1995 RECHECK PLAN CORRECTION LIST JURISDICTION Carlsbad >t PROJECT ADDRESS 2271 Cosmos Ct. DATE PLAN RECEIVED BY ESGIL CORPORATION 5/18/95 REVIEWED BY Kurt Culver PLAN CHECK NO 95-455 SET III DATE RECHECK COMPLETED May 25, 1995 FOREWORD (PLEASE READ): This plan review is limited to the technical requirements contained in the Uniform Building Code, Uniform Plumbing Code, Uniform Mechanical Code, National Electrical Code and state laws regulating energy conservation, noise attenuation and disabled access This plan review is based on regulations enforced by the Building Department You may have other corrections based on laws and ordinances enforced by the Planning Department, Engineering Department or other departments The following items need clarification, modification or change All items must be satisfied before the plans will be in conformance with the cited codes and regulations Per Sec 303 (c), 1991 Uniform Building Code, the approval of the plans does not permit the violation of any state, county or city law A Please make all corrections on the original tracings and submit two new sets of prints to ESGIL CORPORATION B To facilitate rechecking, please identify, next to each item, the sheet of the plans upon which each correction on this sheet has been made and return this sheet with the revised plans C The following items have not been resolved from the previous plan reviews The original correction number has been given for your reference Please contact me if you have any questions regarding these items D Please indicate here if any changes have been made to the plans that are not a result of corrections from this list If there are other changes, please briefly describe them and where they are located on the plans Have changes been made not resulting from this list? QYes QNo Carlsbad 95-455 III May 25, 1995 10 From the referenced list i 5 Corridor 134 must be made wider where doors 4 and 1 (from the lunch room) face each other Please review Title 24 11 A For the new exit door added to the lunch room, show panic hardware on the door there Additionally, show an exit sign at the door on the electrical plans C As shown, the stair does not exit into a corridor at the ground level Rather, the stair opens into a "room" (the "Production" is a room), which is prohibited E (i) The plans show an option to use a fire rated suspended ceiling for the corridor Fire dampers will be required for each mechanical penetration through the ceiling, then, AND the plans must detail how recessed light fixtures will be installed in the ceiling (n) A duct is shown going into Room 108 that also serves the corridor A fire damper will be required there 30 Please show a 3" seismic gap on the plans, per the calculations MECHANICAL 3 Adequate ventilation still isn't shown for Rooms 140, 146 and 147 NOTE Turbine vents do not qualify to provide ventilation 6 If wet grinding will be done (as stated in your response), why don't the plumbing plans show the associated plumbing'? 9 Room 142 will now have ventilation provided to it from the existing office area Since Room 142 wasn't previously conditioned (refer to the roof plan), it is a newly conditioned area and energy documentation is required If you have any questions regarding these items, please contact Kurt Culver of Esgil Corporation at (619) 560-1468 Thank you ESGIL CORPORATION 9320 CHESAPEAKE DR., SUITE 2O8 SAN DIEGO, CA 92123 (619) 560-1468 DATE May 11, 1995 a APPJJCANX-^^ Ja^JURISDICTION^ JURISDICTION Carlsbad Q-PtAN a FILE PLAN CHECK NO 95-455 SET II PROJECT ADDRESS 2271 Cosmos Ct. PROJECT NAME Taylor Made Golf TI and Addition The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck X] The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person The applicant's copy of the check list has been sent to Ted Buchanan 2632 Luciernaga St Carlsbad 92009 Esgil Corporation staff did not advise the applicant that the plan check has been completed XI Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Ted Buchanan C/AAJS *M^C^//oC ) Date contacted fl/zfe" (by \&_ ) Telephone* 438-9222 2<] REMARKS As allowed by the City, this project is now being reviewed under the 1994 UBC Additional plan check fees are due By Kurt Culver Enclosures Esgil Corporation [X] GA [g] CM G PC 5/3/95 tmsmtidot CB 95-455 II May 11, 1995 RECHECK PLAN CORRECTION LIST JURISDICTION Carlsbad PROJECT ADDRESS 2271 Cosmos Ct. DATE PLAN RECEIVED BY ESGIL CORPORATION 5/3/95 REVIEWED BY Kurt Culver PLAN CHECK NO 95-455 SET II DATE RECHECK COMPLETED May 11, 1995 FOREWORD (PLEASE READ): This plan review is limited to the technical requirements contained in the Uniform Building Code, Uniform Plumbing Code, Uniform Mechanical Code, National Electrical Code and state laws regulating energy conservation, noise attenuation and disabled access This plan review is based on regulations enforced by the Building Department You may have other corrections based on laws and ordinances enforced by the Planning Department, Engineering Department or other departments The following items need clarification, modification or change All items must be satisfied before the plans will be in conformance with the cited codes and regulations Per Sec 303 (c), 1991 Uniform Building Code, the approval of the plans does not permit the violation of any state, county or city law A Please make all corrections on the original tracings and submit two new sets of prints to ESGIL CORPORATION B To facilitate rechecking, please identify, next to each item, the sheet of the plans upon which each correction on this sheet has been made and return this sheet with the revised plans C The following items have not been resolved from the previous plan reviews The original correction number has been given for your reference In case you did not keep a copy of the prior correction list, we have enclosed those pages containing the outstanding corrections Please contact me if you have any questions regarding these items D Please indicate here if any changes have been made to the plans that are not a result of corrections from this list If there are other changes, please briefly describe them and where they are located on the plans Have changes been made not resulting from this list? QYes QNo 5 Regarding the technical report The floor plan included within it shows two control areas For the foam storage control area, revise the plans to show complete one hour separation for the area This includes the framing over the room and any penetrations (doors, ducts, etc ) 6 a) Obtain the City's approval to use the 1994 UBC b) The 1994 UBC contains a requirement for smoke dampers, in addition to fire dampers Please review the plans and determine if smoke dampers are required CB 95-455 I! May 11, 1995 c) For the non-rated corridor exception to be used, ICBO has interpreted in the past that the office area must have a fire wall between it and the non-office portions This will require a rated wall (with rated doors/windows) between the office portion and the manufacturing area Alternately, fire rate the corridors and then the wall between the office/manufacturing may be non-rated d) Show on the plans that any relocated or new lights at the suspended ceiling will be provided with adequate seismic restraint, per the 1994 UBC 7 Label on the plans any fire rated corridors (by cross-hatching, etc) 10 From the separate disabled access list 4 b) For the door at the bottom of the ramp at the computer room, show the 18" strike edge requirement c) Show on the plans the 12" push side requirement for the existing restroom doors at the left hand side of the floor plan 5 The doors at Room 106 must have 5' in the direction of door swing The corridor there must be made wider ALSO, corridor 134 must be wider where doors 4 and 1 (from the lunch room) face each other 11 A Two exits are required from the lunch room As shown, those exits will now converge (since the corridor no longer continues westward), which is prohibited B Show on the plans that the lobby by grid H/2 is an existing fire rated corridor (inspector to verify) C The upper level corridor must be continuous all the way to the exterior At the west side, the corridor/stair opens into Production Room 107, which is prohibited The area from the stair to the exterior must be maintained as an exit corridor and cannot have any rooms or uses along the way D Provide fire separation from Room 108 (AND the rooms next to it) to the exit corridor leading from the stair E The as-builts show that rooms used to occur in the area where Corridor/Room 107 will be located Those rooms likely didn't have fire-rated ceilings Since those areas will now be part of the rated corridor system, provide various cross-sections in those areas, showing how the fire-rated corridor will be constructed F Previous editions of the Code required only wire glass at rated corridors The new Codes require 3/4-hour windows The plans show some windows are being relocated As such, they must comply with current Codes G Provide fire separation between the corridor and Room 109 19 This correction from the previous list still applies 21 Provide the cross-sections at altered areas of the corridors 26 The area in question was a rated corridor previously 30 Provide calculations to justify the seismic gap shown The Code requires that the actual deflection be multiplied by 3Rw/8 to determine the seismic separation See next sheet for outstanding PME corrections CB 95-455 II May 11, 1995 PLUMBING, MECHANICAL AND ENERGY CORRECTIONS PLAN REVIEWER: Glen Adamek • MECHANICAL (1994 UNIFORM MECHANICAL CODE) 3 Provide mechanical plans showing existing and proposed HVAC equipment, ducts and access to equipment The through the wall room heat pumps must be in outside walls Not through the interior wall into the Production Area The required outside air for mechanical is not provided, and the units are not designed for interior installations See UBC, Section 1202 2 1 for mechanical ventilation requirements 6 Detail exhaust ventilation systems, including the required dust collection systems for Shaft Grinding Lab (146), and exhaust ventilation system for the Chemical Storage Locker (145) Show Compliance with the following a) Detail the exhaust outlet clearances as per UMC, Section 609 10 b) Detail required exhaust ducting system showing i) Duct support as per UMC, Section 609 6 n) Fire protection as per UMC, Section 609 7 in) Clearances from combustibles as per UMC, Section 609 8 iv) Protection from physical damage as per UMC, Section 609 9 v) Minimum conveying velocities as per UMC, Section 505 4 and Table No 5-A vi) Ducts conveying explosives or flammable vapors, fumes or dusts shall extend directly to the exterior of the building without entering other spaces UMC, Section 505 1 vn) Required duct cleanout every 10 feet UMC, Section 609 4 • ENERGY CONSERVATION 9 The plans show existing unconditioned space is now being conditioned New conditioned space is Endurance Lab (140), Machine Shop (142), Driving Enclosure (147), and Shaft- Grinding Lab (146) Provide complete energy designs for the proposed changes in envelope, lighting, and mechanical systems Provide the completed ENV-, LTG-, and MECH- forms showing Energy compliance 11 The corrected, completed and signed ENV-1, LTG-1, and MECH-1 forms must be imprinted on the plans Note: If you have any questions regarding this plan review list please contact Glen Adamek at (619) 560-1468 To speed the review process, note on this list (or a copy) where the corrected items have been addressed on the plans ELECTRICAL PLAN REVIEW PLAN REVIEWER: Chuck Mendenhall 1 Provide multiple switch light controls so that the lighting can be reduced by one half in a uniform pattern in offices 114 & 115 CB 95-455 II May 11, 1995 2 Reference the exit signs shown on the lighting plan to the light fixture schedule The schedule indicates the exit signs are fixture type X but these are not referenced on the lighting plan 3 The shaft grinding area appears to be a Class II Div 2 hazardous location Note on the plans that all electrical equipment, switches, panels, fixtures and receptacles will comply with NEC Article 502 The hazardous materials report does not cover the grinding area The dust produced, if graphite, is an ignitable material and electrical equipment, switches, fixtures, and receptacles in this area are regulated by the NEC not the Fire Code or the UBC Note: If you have any questions regarding this electrical plan review list please contact the plan reviewer listed above at (619) 560-1468 To speed the review process, note on this list ( or a copy) where the corrected items have been addressed on the plans CB 95-455 II May 11, 1995 JURISDICTION Carlsbad VALUATION AND PLAN CHECK FEE PREPARED BY Kurt Culver BUILDING ADDRESS 2271 Cosmos Ct. PLAN CHECK NO 95-455 DATE May 11, 1995 BUILDING OCCUPANCY TYPE OF CONSTRUCTION BUILDING PORTION Air Conditioning Fire Sprinklers TOTAL VALUE BUILDING AREA (sq ft) VALUATION MULTIPLIER VALUE ($) Building Permit Fee Plan Check Fee $ $ Comments Plans have now been reviewed for compliance with the 1994 UBC Additional Esgil fee = 3hours(5)8715/hr =261 75 Sheet 1 of 1 valuefee dot ESGIL CORPORATION 9320 CHESAPEAKE DR., SUITE 208 SAN DIEGO, CA 92123 (619) 560-1468 DATE April 11, 1995 a JURISDICTION Carlsbad a PLANREVIEWER a FILE PLAN CHECK NO 95-455 SET I PROJECT ADDRESS 2271 Cosmos Ct. PROJECT NAME Taylor Made Golf TI and Addition The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck [X| The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person X] The applicant's copy of the check list has been sent to Ted Buchanan 2632 Luciernaga St Carlsbad 92009 X Esgil Corporation staff did not advise the applicant that the plan check has been completed Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Date contacted (by ) Telephone # REMARKS By Kurt Culver Enclosures Esgil Corporation ^ GA 1^ CM D PC 4/4/95 tmsmtidot Carlsbad 95-455 April 11, 1995 PLAN REVIEW CORRECTION LIST TENANT IMPROVEMENTS PLAN CHECK NO 95-455 OCCUPANCY B-2? TYPE OF CONSTRUCTION HI-N, spr. ALLOWABLE FLOOR AREA n/c SPRINKLERS'? Yes REMARKS DATE PLANS RECEIVED BY JURISDICTION DATE INITIAL PLAN REVIEW COMPLETED April 11, 1995 JURISDICTION Carlsbad USE Research/Development ACTUAL AREA 18134 STORIES 2 HEIGHT n/c OCCUPANT LOAD to be determ. DATE PLANS RECEIVED BY ESGIL CORPORATION 4/4/95 PLAN REVIEWER Kurt Culver FOREWORD (PLEASE READ): This plan review is limited to the technical requirements contained in the Uniform Building Code, Uniform Plumbing Code, Uniform Mechanical Code, National Electrical Code and state laws regulating energy conservation, noise attenuation and access for the disabled This plan review is based on regulations enforced by the Building Department You may have other corrections based on laws and ordinances enforced by the Planning Department, Engineering Department, Fire Department or other departments Clearance from those departments may be required prior to the issuance of a building permit Code sections cited are based on the 1991 UBC The following items listed need clarification, modification or change All items must be satisfied before the plans will be in conformance with the cited codes and regulations Per Sec 303 (c), 1991 Uniform Building Code, the approval of the plans does not permit the violation of any state, county or city law To speed up the recheck process, please note on this list (or a copy) where each correction item has been addressed, i.e.. plan sheet number, specification section, etc. Be sure to enclose the marked up list when you submit the revised plans. LIST NO 40, TENANT IMPROVEMENTS WITHOUT SPECIFIC ENERGY DATA OR POLICY SUPPLEMENTS (1991UBC)tiforw dot Carlsbad 95-455 April 11, 1995 1 Please make all corrections on the original tracings and submit two new sets of prints, to Esgil Corporation, 9320 Chesapeake Drive, Suite #208, San Diego, CA 92123, (619)560-1468 2 Each sheet of the plans must be signed by the person responsible for their preparation, even though there are no structural changes Business and Professions Code 3 Plans and calculations shall be signed by the California state licensed engineer or architect where there are structural changes to existing buildings or structural additions Please include the California license number, seal, date of license expiration and date plans are signed Business and Professions Code 4 UBC Section 304 requires the Building Official to determine the total value of all construction work proposed under this permit The value shall include all finish work, painting, roofing, electrical, plumbing, heating, air conditioning, elevator, fire extinguishing systems and any other permanent equipment Please provide a signed copy of the designer's or contractor's construction cost estimate of all work proposed 5 A complete description of the activities and processes that will occur in this tenant space should be provided A listing of all hazardous materials should be included The materials listing should be stated in a form that would make classification in Tables 9-A and 9-B possible The building official may require a technical report to identify and develop methods of protection from hazardous materials Section 901 (f) PAST EXPERIENCE WITH THESE TYPES OF FACILITIES HAS SHOWN THEM TO BE [PARTIALLY] "H" OCCUPANCIES THIS APPLIES TO THE STORAGE AND GRINDING USES 6 Provide a statement on the Title Sheet of the plans that this project shall comply with Title 24 and 1991 UBC, UMC and UPC and 1990 NEC REVISE THE "NOTES" ON SHEET T1 7 Show any existing fire rated area separation walls, occupancy separation walls, demising walls, shafts or rated corridors Identify and provide construction details for proposed new fire rated walls 8 Identify existing walls to be removed, existing walls to remain and proposed new walls Identify bearing walls, non-bearing walls, and shear walls 9 Show safety glazing in the following locations, per Section 5406(d) a) Where the nearest edge of glazing is within a 24-inch arc of either side of a door in a closed position (unless there is an intervening wall between the door and the glazing or if the glazing is 5'-0" or higher above the walking surface) THERE ARE MANY WINDOWS THAT AREN'T Carlsbad 95-455 April 11, 1995 SHOWN AS TEMPERED SOME EXISTING WINDOWS WILL HAVE TO BE CHANGED, DUE TO NEW/RELOCATED DOORS NEAR THEM b) Glazing greater than 9 square feet with the bottom edge less than 18" above the floor and the top edge greater than 36" above the floor (unless the glazing is more than 36" horizontally away from walking surfaces or if a complying protective bar is installed) 10 The tenant space and new and/or existing facilities serving the remodeled area must be accessible to and functional for the physically disabled See the attached correction sheet Title 24, Part 2 11 Provide an exit analysis plan (may be 8 1/2" x 11" or any convenient size) THE ORIGINAL CORRIDOR SYSTEM HAS BEEN ELIMINATED PROVIDE A COMPLETE EXIT PLAN OF ALL AFFECTED AREAS, SHOWING OCCUPANT LOADS AND EXIT PATHS 12 Rooms with more than 10 occupants may have one exit through one adjoining room Revise exits to comply Section 3303(e) 13 Exit signs are required whenever two exits are required Show all required exit sign locations Section 3314 (a) WITH THE NEW PLAN, IT APPEARS THAT ADDITIONAL EXIT SIGNS ARE REQUIRED 14 Note on the plans "All exits are to be openable from inside without the use of a key or special knowledge" In lieu of the above, in a Group B occupancy, you may note "Provide a sign on or near the exit doors reading THIS DOOR TO REMAIN UNLOCKED DURING BUSINESS HOURS" This signage is only allowed at the main exit Section 3304(c) 15 Corridors serving 30 or more occupants shall have walls and ceilings of one-hour construction IT APPEARS THAT RATED CORRIDORS WILL BE REQUIRED AS PART OF THE NEW EXITING SYSTEM IF ITS DESIRED TO NOT RATE THOSE CORRIDORS, USING THE "OFFICE" EXCEPTION IN THE CODE, SEE THE CORRECTIONS BELOW 16 Section 3305(g), Exception 5 does not apply to common corridors where the corridor serves as an exit for non-office areas (manufacturing, warehouse, etc) 17 Section 3305(g), Exception 5 is applicable only for corridors on one floor, the corridors on the lower level(s) must be rated if these lower corridors have openings into them from other levels 18 If non-rated corridors are used per Section 3305(g), Exc 5, provide a reference to the corridors on the floor plan, noting a) Corridors are non-rated per Section 3305(g), Exception 5 b) Smoke detectors shall be maximum 30' on center Carlsbad 95-455 April 11, 1995 c) Power supply shall be dedicated branch circuit Circuit disconnecting means shall be accessible only to authorized personnel and shall be clearly marked FIRE ALARM CIRCUIT CONTROL, with a lock-on device 19 If a tenant space utilizes Section 3305(g), Exception 5, then that tenant space shall be separated from adjacent spaces by a demising wall constructed as for a one-hour corridor wall 20 Clearly show where the non-rated corridor system terminates and a rated corridor system commences 21 Provide a complete architectural section of the corridor, or exterior exit balcony, showing all fire-resistive materials and details of construction for all floors, walls, ceiling and all penetrations Section 3305(g) 22 Provide a note on the plans stating "Penetrations of fire-resistive walls, floor- ceilings and roof-ceilings shall be protected as required in UBC Sections 4304 and 4305" • MISCELLANEOUS 23 On sheet AB-1, please clarify the note "Strut splice at floor framing " 24 Please clarify the construction shown on sheet AB-2, etc Are the dark lines representing proposed construction'? Much of what is shown there conflicts with sheet A-1, etc 25 If any of the work on the "AB" sheets will be new, additional corrections may follow 26 On sheet A1, Room 107 used to be the rated corridor serving as the exit for the ground floor AND upper level stair Justify removing this rated corridor 27 Provide structural calculations to justify detail 3/A2 Also, specify on the plans that special inspection is required for the epoxy 28 Specify what will be stored on each of the decks It may be that a live load higher than 124 psf may be required 29 Provide lateral load calculations 30 Provide a seismic separation between the existing concrete walls and the new framing Carlsbad 95-455 April 11, 1995 31 Justify not providing a footing below the new bearing walls The bearing values given in soils reports assume a footing to be a minimum depth (typically 12") BELOW grade At the surface of soils, the allowable bearing value would be much less Provide a recommendation from the soils engineer 32 See below for PME corrections 33 To speed up the review process, note on this list (or a copy) where each correction item has been addressed, i e , plan sheet, note or detail number, calculation page, etc 34 Please indicate here if any changes have been made to the plans that are not a result of corrections from this list If there are other changes, please briefly describe them and where they are located in the plans • Have changes been made to the plans not resulting from this correction list? Please indicate Yes Q No a 35 The jurisdiction has contracted with Esgil Corporation located at 9320 Chesapeake Drive, Suite 208, San Diego, California 92123, telephone number of 619/560-1468, to perform the plan review for your project If you have any questions regarding these plan review items, please contact Kurt Culver at Esgil Corporation Thank you PLUMBING, MECHANICAL AND ENERGY CORRECTIONS PLAN REVIEWER: GlenAdamek • PLUMBING (UNIFORM PLUMBING CODE) 1 Provide complete plumbing plans showing changes in the existing plumbing Including designs and calculations for changes as follows a) Provide complete water line sizing calculations, including the water pressure, pressure losses, water demands, and developed pipe lengths b) Provide gas line plans and calculations, showing pipe lengths and gas demands UPC Section 1219 c) Provide dram, waste and vent plans 2 New or relocated water closets and associated flushometer valves, if any, shall use no more than 1 6 gallons per flush and shall meet performance standards established by the American National Standards Institute Standard A112 19 2, Carlsbad 95-455 April 11, 1995 and urinals and associated flushometer valves, if any, shall use no more than one gallon per flush and shall meet performance standards established by the American National Standards Institute Standard A112192 H&S Code, Section 17921 3(b) • MECHANICAL (UNIFORM MECHANICAL CODE) 3 Provide mechanical plans showing existing and proposed HVAC equipment, ducts and access to equipment 4 Show the size, location and type of all heating and cooling appliances or systems 5 Provide smoke detection in supply and return air ducts for required automatic shut-off controls as per UMC, Section 1009 6 Detail exhaust ventilation system compliance with UMC Chapter 11 a) Detail the exhaust outlet clearances as per UMC, Section 11070) b) Detail required exhaust ducting system showing i) Duct support as per UMC, Section 1107(f) ii) Fire protection as per UMC, Section 1107(g) MI) Clearances from combustibles as per UMC, Section 1107(h) iv) Protection from physical damage as per UMC, Section 1107(i) v) Minimum conveying velocities as per UMC, Section 1105(b) and Table No 11-A vi) Ducts conveying explosives or flammable vapors, fumes or dusts shall extend directly to the exterior of the building without entering other spaces UMC, Section 1105(a) 7 Provide data on proposed hazardous material to be stored and used Clearly show types of material, amounts of materials, required ventilation, containment requirements, drainage requirements, and detail required spill controls UBC, Chapter 9 and UFC a) Clearly show the amounts of each type of hazardous material to be stored and in use Carlsbad 95-455 April 11, 1995 b) Clearly show where in the buildings each type of hazardous material is being stored or used c) Provide calculations for required containment in each area of the buildings, as per UBC, 902(e) d) Provide a written response to show how Spill Control and Drainage are being handled as required in UBC, Section 902(c) & (d) e) Provide the required manual shutoff control for ventilation equipment as per UBC, Section 905(b) f) For fumes or vapors that are heavier than air, exhaust shall be taken from a point within 12 inches of the floor UFC, section 80 301 (m) 5 • ENERGY CONSERVATION 8 NOTE Plans submitted after January 1, 1993 must comply with the new energy standards 9 Provide complete energy designs for the proposed changes in envelope, lighting, and mechanical systems Provide the completed ENV-, LTG-, and MECH- forms showing Energy compliance 10 Show the daylit areas and required daylit area lighting controls for new or relocated lighting in daylit areas Title 24, Part 6, Section 131(c) 11 The completed and signed ENV-1, LTG-1, and MECH-1 forms must be imprinted on the plans Note: If you have any questions regarding this plan review list please contact Glen Adamek at (619) 560-1468 To speed the review process, note on this list (or a copy) where the corrected items have been addressed on the plans ELECTRICAL PLAN REVIEW PLAN REVIEWER: Chuck Mendenhall 1 Show or identify new loads proposed for the existing equipment Provide panel schedules for existing panels PC, PD & PE Show the total new and existing loads to these panels 2 Indicate mam service size (amperage rating) and the total load demand on the service Include all existing and new loads Carlsbad 95-455 April 11, 1995 3 Provide multiple switch light controls so that the lighting can be reduced by one half in a uniform pattern The switches must be located within sight of the lights which they control (CCR) Title 24, Sec 131 a-b 4 Show exit signs on the lighting plan(s) at all required exits and specify them as being self-luminous or having a second source of power ( battery or generator) This is required when two exits are required per the UBC UBC 3314 and NEC 700- 16 5 In all occupancies where the exit system serves 100 or more occupants, provide a minimum of 1 foot-candle of emergency illumination at the floor level and specify a second source of power for the emergency illumination (battery or generator) UBC 3313 & NEC 700-16 Clearly show on the lighting plans the exit path from the building and the emergency illumination 6 The shaft grinding area appears to be a Class II Div 2 hazardous location Note on the plans that all electrical equipment, switches, panels, fixtures and receptacles will comply with NEC Article 502 Note: If you have any questions regarding this electrical plan review list please contact the plan reviewer listed above at (619) 560-1468 To speed the review process, note on this list ( or a copy) where the corrected items have been addressed on the plans DEPARTMENT OF STATE ARCHITECTURE-NON RESIDENTIAL TITLE 24 DISABLED ACCESS REQUIREMENTS • PEDESTRIAN RAMPS A path of travel with a slope exceeding 1 20 (5%) shall be considered a ramp per section 3307(a 1) Handrails are required to be provided at each side of ramps APPLIES TO THE RAMP AT THE COMPUTER AREA (AND ANY OTHER RAMPS ALONG A PATH OF TRAVEL) Ramps shall have a minimum width of 48 inches Ramps serving primary entrances to building having an occupant load of 300 or more shall have a minimum clear width of 60 inches Section 3307(b1)2 Landings are required at the top and bottom of all ramps, per section 3307(d 1) The bottom landing shall be a minimum of 72" in the direction of travel and the top landing shall be a minimum of 60" x 60" • DOORS The width of the level area, on the side to which a door (or gate) swings, shall be as follows per section 3304(i 1) a) Extend 24" past the strike edge of the door for exterior applications b) Extend 18" past the strike edge of the door for interior conditions MANY DOORS DON'T COMPLY Carlsbad 95-455 April 11, 1995 c) *Extend 12" past the strike edge on the push side if door has latch and closer 5 *Per section 3304(i 1)2 B, the level area at floors or landings shall have a length at least 60" in the direction of door swing and at least 48" (or 44" if doors don't have latches or closers) in the direction opposite the door swing NOTE See Figure 33-2 REVIEW ALL DOORS • STAIRWAYS AND HANDRAILS 6 Handrails are required on each side of stairs, per section 3306(i 1)1 THESE PROVISIONS APPLY TO THE NEW STAIRS 7. Handrails shall extend a minimum of 12" beyond the top nosing and 12" plus the tread width beyond the bottom nosing SHOW THIS ON THE FLOOR PLANS Carlsbad 95-455 April 11, 1995 VALUATION AND PLAN CHECK FEE JURISDICTION Carlsbad PREPARED BY Kurt Culver BUILDING ADDRESS 2271 Cosmos Ct. PLAN CHECK NO 95-455 DATE April 11, 1995 BUILDING OCCUPANCY B-2? TYPE OF CONSTRUCTION III-N, spr. BUILDING PORTION Tl and Addition Air Conditioning Fire Sprinklers TOTAL VALUE BUILDING AREA (sq ft) 18134 VALUATION MULTIPLIER 26 VALUE ($) 471484 471484 Building Permit Fee Plan Check Fee Comments $ 1941 50 $ 1261 98 Sheet 1 of 1 valuefee dot PLANNING/ENGINEERING APPROVALS PERMIT NUMBER CB ADDRESS DATE RESIDENTIAL RESIDENTIAL ADDITION MINOR « $10,000.00) TENANT IMPROVEMENT PLAZA CAMINO REAL VILLAGE FAIRE OTHER / PLANNER COMPLETE OFFICE BUILDING DATE ENGINEER DATE C \WP51\FILES\BLDG.FRM Rev 11/15/90 . 7 5 'Plan Check No Planner DAVID RICK PIANNING CHECKLIST Address "Z-21 i o3 Phone 438-1161 ext APN: (Name) Type of Project and Use "f 1. Zone i/i Faoliaes Management Zone t> V V ** M •»• « •a a o Oaf Legend l5 5 S S i D cle [If property in, complete SPECIAL TAX CALCULATION WORKSHEET provided by Building Department) [tern Complete [tern Incomplete - Needs your action 1, 2, 3 Number in circle indicates plancheck number where deficiency was identified Environmental Review Required: YES NO V TYPE DATE OF COMPLETION: Compliance with conditions of approval? If not, state conditions which require action. Conditions of Approval an n /rDiscretionary Action Required: YES NO / TYPE DATE:APPROVAL/RESO. NO. PROJECT NO OTHER RELATED CASES: izmn Compliance with conditions of approval? If not, state conditions which require action. Conditions of Approval California Coastal Commission Permit Required: YES NO «/ DATE OF APPROVAL: San Diego Coast District, 3111 Camino Del Rio North, Suite 200, San Diego, CA. 92108-1725 (619) 521-8036 Compliance with conditions of approval? If not, state conditions which require action. Conditions of Approval nn nn QTl a 0DD G3T] D Inclusionary Housing Fee required: YES NO (Effective date of Inclusionary Housing Ordinance - May 21, 1993.) Site Plan: Zoning* 1. Provide a fully dimensioned site plan drawn to scale Show North arrow, property lines, easements, existing and proposed structures, streets, existing street improvements, nght-of-way width, dimensioned setbacks and existing topographical lines. 2. Provide legal description of property, and assessor's parcel number Setbacks: ana Front: Int. Side- Street Side: Rear: ^ 2. Lot coverage: u-V 3. Height: 4. Parking: Additional Comments Required Required Required Required Required Required Spaces Required Guest Spaces Required Shown Shown Shown Shown Shown Shown 'Z-O Shown ^^ Shown OK TO ISSUE AND ENTERED APPROVAL INTO COMPUTER DATE PLNCK.FRM City of Carlsbad 95066 Fire Department Bureau of Prevention Plan Review: Requirements Category: Building Plan Check Date of Report' Monday. May 1.1995 Contact Name Ted Buchanan Reviewed by.^ Address 2632 Luciemaga St City, State Carlsbad CA 92009 Bldg. Dept. No 95-455 Planning No. Job Name Taylor Made Golf Job Address 2271 Cosmos Ste. or Bldg No. The item you have submitted for review has been approved The approval is based on plans, information and/or specifications provided in your submittal; therefore any changes to these items after this date, including field modifica- tions, must be reviewed by this office to insure continued conformance with applicable codes. Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements. D Disapproved - Please see the attached report of deficiencies Please make corrections to plans or specifications necessary to indicate compliance with applicable codes and standards Submit corrected plans and/or specifications to this office for review. For Fire Department Use Only Review 1st 2nd 3rd CFD Job# 95066 File* Other Agency ID 2560 Orion Way Carlsbad, California 92008 (619) 931-2121 y of Carlsbad 95066 Fire Department • Bureau of Prevention General Comments: Date Of Report' Monday. May 1.1995 Contact Name Ted Buchanan Address 2632 Luciemaga St City, State Carlsbad CA 92009 Bldg. Dept. No. 95-455 Planning No. Job Name Taylor Made Golf Job Address 2271 Cosmos Ste or Bldg No. Chemical storage room requires fee from Fire Dept for use-$160 00 This permit will be amended to show that flammable and combustible liquids will be stored inside storage cabinets inside the storage room that have safety standards conforming to Article 79, Uniform Fire Code 1991 and the foam storage will either have portable burms.storage one container high or a recognized report on the spill control that will negate the burms The foam storage will also comply to Article 79, Uniform Fire Code 1991 2560 Orion Way • Carlsbad, California 92008 • (619) 931-2121 City of Carlsbad 95066 Fire Department • Bureau of Prevention Plan Review: Requirements Category: Building Plan Check Date of Report Monday, May 1,1995 Reviewed by Contact Name Ted Buchanan Address 2632 Luciemaga St City, State Carlsbad CA 92009 Bldg Dept No 95-455 Planning No Job Name Taylor Made Golf Job Address 2271 Cosmos Ste or Bldg No. Approved - The item you have submitted for review has been approved The approval is based on plans; information and/or specifications provided in your submittal; therefore any changes to these items after this date, including field modifica- tions, must be reviewed by this office to insure continued conformance with applicable codes Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements. Disapproved - Please see the attached report of deficiencies Please make corrections to plans or specifications necessary to indicate compliance with applicable codes and standards Submit corrected plans and/or specifications to this office for review. For Fire Department Use Only Review 1st 2nd 3rd Other Agency ID CFD Job# 95066 File* 2560 Orion Way • Carlsbad, California 92008 • (619) 931-2121 City of Carlsbad 95066 Fire Department • Bureau of Prevention General Comments: Date of Report Monday, May 1,1995 Contact Name Ted Buchanan Address 2632 Luciemaga St City, State Carlsbad CA 92009 Bldg Dept No 95-455 Planning No Job Name Taylor Made Golf Job Address 2271 Cosmos Ste or Bldg No. Chemical storage room requires fee from Fire Dept for use-$160 00 This permit will be amended to show that flammable and combustible liquids will be stored inside storage cabinets inside the storage room that have safety standards conforming to Article 79, Uniform Fire Code 1991 and the foam storage will either have portable burms.storage one container high or a recognized report on the spill control that will negate the burms The foam storage will also comply to Article 79, Uniform Fire Code 1991 2560 Orion Way • Carlsbad, California 92008 • (619) 931-2121 City of Carlsbad 95066 Fire Department • Bureau of Prevention Plan Review: Requirements Category: Building Plan Check Date of Report Monday. April 24,1995 Reviewed bv: fl i-v£l A Contact Name Ted Buchanan Address 2632 Luciemaga St City, State Carlsbad CA 92009 Bldg Dept No. 95-455 Planning No Job Name Taylor Made Golf Job Address 2271 Cosmos Ste or Bldg No D Approved - The item you have submitted for review has been approved The approval is based on plans, information and/or specifications provided in your submittal, therefore any changes to these items after this date, including field modifica- tions, must be reviewed by this office to insure continued conformance with applicable codes Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements Kl Disapproved - Please see the attached report of deficiencies Please make corrections to plans or specifications necessary to indicate compliance with applicable codes and standards Submit corrected plans and/or specifications to this office for review For Fire Department Use Only Review 1st 2nd 3rd Other Agency ID CFD Job# 95066 Rle# 2560 Orion Way • Carlsbad, California 92008 • (619) 931-2121 City of Carlsbad 95066 Fire Department - Bureau of Prevention General Comments: Date of Report Monday, April 24.1995 Contact Name Ted Buchanan Address 2632 Luoemaga St City, State Carlsbad CA 92009 Bldg Dept No 95-455 Planning No Job Name Taylor Made Golf Job Address 2271 Cosmos Ste or Bldg No Chemical storage area requires stricter requirements and scrutiny of chemicals and quantities Are any other areas that are being increased also increasing the hazards7 2560 Orion Way • Carlsbad, California 92008 • (619) 931-2121 City of Carlsbad »»o«« ••' Fire Department • Bureau of Prevention Plan Review: Requirements Category: Building Plan Check Date of Report Friday, April 14.1995 Reviewed by. Contact Name Ted Buchanan Address 529 Elm steB City, State Carlsbad CA 92008 Bldg Dept No 95-455 Planning No Job Name Taylor Made Golf Job Address 2271 Cosmos Ste or Bldg No D Approved - The item you have submitted for review has been approved The approval is based on plans, information and/or specifications provided in your submittal, therefore any changes to these items after this date, including field modifica- tions, must be reviewed by this office to insure continued conformance with applicable codes Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements E3 Disapproved - Please see the attached report of deficiencies Please make corrections to plans or specifications necessary to indicate compliance with applicable codes and standards. Submit corrected plans and/or specifications to this office for review For Fire Department Use Only Review 1st 2nd 3rd Other Agency ID CFD Job# 95066 Rle# 2560 Orion Way • Carlsbad, California 92008 • (619) 931-2121 City of Carlsbad 95066 Fire Department • Bureau of Prevention General Comments: Date of Report Friday. April 14,1995 Contact Name Ted Buchanan Address 529 Elm SteB City, State Carlsbad CA 92008 Bldg Dept No 95-455 Planning No Job Name Taylor Made Golf Job Address 2271 Cosmos Ste or Bldg No Chemical storage area requires stncter requirements and scrutiny of chemicals and quantities Are any other areas that are being increased also increasing the hazards? 2560 Orion Way • Carlsbad, California 92008 • (619) 931-2121 Requirements Category: Building Plan Check 95066 Deficiency Item Pending 14 Provide Technical Report To determine the acceptability of technologies, processes, products, facilities, materials and uses attending the design, operation or use of a building or premises subject to the inspection of the department, the chief is authorized to require the owner or the person in possession or control of the building or premises to provide, without charge to the jurisdiction, a technical opinion and report The opinion and report shall be prepared by a qualified engineer, specialist, laboratory or fire-safety specialty organization acceptable to the chief and the owner and shall analyze the fire-safety properties of the design, operation or use of the building or premises and the facilities and appurtances situated thereon, to recommend necessary changes Page 2 04/14/95 TED A. [BUCHANAN, FACILITIES . w & .e- i. __.L< _:____....... | i J I 7 1 fe> Ci. S •$/ I - i.JSTtofe AfijE. es. .1 I. -. -f i i _L .^-. i I I i I r~rj ! ._! I 1__LI i i i i i ! i—( 1— - * j i T ''-'t'! UL I i I i a i x' (^ / <? f <75l'-(t-t/-fx-2- I ~" "}~ ' ~ . _r ..... Li. :.. 1 i. \ I II•• [. , | I , | __ 20P-iVt> _._DF/DF .-U.L-: i •S6.L. ! i .,"5 | TR-3 r i ! , 2 i T3.FL.i """; i' i! I i I I' ! ~ r "~r~ f i" i ! i p J.I _l—J-UC.-7---4i | i ' ' f i i_ i j i I—_ j_.i_i! | I>OOPS_j i i j I i 4-xil 2. .jfe..LJD. F. i i ! i _i •*M--4- oys.1 !.. .... t~r _!_t_i [.-..]- L jss«o» tA _ a..J^6 4o F J_ uLju0jr_jj54.7M,l*.K-^! i i i T \i ! l j i _J__.Lv|L4. Jo..)&MINI xU<- fc^csK __Oc — >-UJaVI =T-_ T •SHX>€5T _,_ <K^^ ij1 11i1 i ! 2!i1 —*.^~+^^** '.?, — ^.^ :o ^fi^W- _! RELlMfs. ^ •»•- V/--I ^• ^ ! ! ti /( :r.^.f ^> s - (?00 r« P L ^ i i : .Dr . 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PAULA FRIEDMAN HAZARDOUS MATERIALS SPECIALIST DEPARTMENT OF ENVIRONMENTAL HEALTH HAZARDOUS MATERIALS MGMT DIV 338 Via Vera Cruz San Marcos P O Box 85261 MS N562 San Diego CA 92186-5261 (619) 940-6809 FAX 940-2925 0 To [\ Jan From ll_Joe 3-27-95 Re Copy of Technical Opinion Report 1 Covei letter report for your info 2 For Ted Buchanan Full report with attachments (MSDS's included) u -ENVIRONMENTAL AND RISK MANAGEMENT, INC. 2434 Vine\ard Avenue Suite 203 Escondido California 92029 March 23, 1995 Colleen Balch Fire Prevention Officer CITY OF CARLSBAD FIRE DEPARTMENT 2560 Orion Way Carlsbad, California 92008-7280 RE Re-Modeling, Assembly Facility Technical Opinion Report Taylor Made Golf Inc 2271 Cosmos Court Carlsbad, California 920009 Dear Ms Balch, Environmental and Risk Management, Inc (ERMI) has been contracted by Taylor Made Golf Inc (Taylor Made) to conduct a technical opinion report and hazardous materials inventory evaluation with respect to the proposed building plans submitted to the City of Carlsbad The proposed building plans are for the interior remodeling and construction of an inside second control area for the bulk storage of several types of foam products This technical opinion report focuses on the characterization and quantity of material to be stored in this room with respect to the Uniform Building Code and the Uniform Fire Code requirements (1994 edition) The new control area/matenal storage room is a Type III Group B Division 2 occupancy control area, located on the floor level, by the loading dock Two of the control areas walls are the exterior concrete walls and the other two are constructed with a one hour fire rating The room is fully sprmklered and a ventilation rate of 350 cubic feet per minute The foam storage room is 312 square feet The foam materials to be stored in this room will not migrate beyond the confines of the room should a leak or spill occur, therefore a secondary containment dike has not been incorporated in the design When exposed to air the materials will solidify immediately The Existing Taylor Made facility is located at 2271 Cosmos Court in the City of Carlsbad The facility is a Type III non rated fully sprmklered mixed office/manufacturing facility The occupancy classification is Group B, Division 2 The basic allowable floor space for a Type III Group B occupancy is 8,000 square feet The proposed facility maintains two permanent side yards and an approved automatic fire sprinkler system, Telephone (619) 737 3125 • Fax (619) 737 3126 which will allow for up to 36,000 square feet of floor space for product manufacturing purposes (as per Uniform Building Code, 1994 edition) The proposed quantities of flammable combustible, and hazardous materials will not exceed the exempt quantities specified in the Uniform Building Code Tables 9A and 9B ERMI has included a hazardous materials inventory summary and a Uniform Building Code / Uniform Fire Code Table 9A and 9B summary with the report The production activities Taylor Made currently performs at the facility includes the attachment of the club head to the golf club shaft and the application of the hand grip The club head is glued to the shaft using the Part A epoxy resin adhesive and Part B hardener Small quantities of the combined resin/hardener will be in use at any one time (10 gallons or less), and the neat material will be stored in 5 gallon cans The proposed quantities of flammable, combustible, and hazardous materials used and stored at this facility are below the exempt quantities allowable for this building Taylor Made is currently developing the Hazardous Materials Business Plan which will incorporate this new construction, which will be submitted to the San Diego County Department of Health Services, Hazardous Materials Management Division Copies of the Material Safety Data Sheets for the materials outlined here in this report are included as an attachment If you have any questions regarding this report or require additional information please contact me at (619) 737-3125 Sincerely, Craig Douglas Director Regulatory Affairs Division LOR M\DE GOLF CORPORATION 2271 COSMOS COURT C\RI,SB\D, CALIFORNIA 92009 HAZARDOUS MATERIALS USE AND STORAGE SUMMARY BlILDINGLWOUT Office Areas Reslrooms Existing Golf Club Production And Asscmb} Area Control Area No 1 Existing Supplv Area (Cham Lini.) Shipping AndReceiMng (Cham Link) Propped Foam Slora RoomControlArta \o 2 Loading Dock Exuung Ouiside Chemical StorageArea REFERE.NCETO UBC/ UFC TABLES 9A & 9B Area Description Flammable Liquid I-B Combustible Liquid 11 IU-A IU-B Irritants (IRR) Other Health Hazard (OHH) Water Reactne Le>ell Construction T>pe QUANTITY OF HAZARDOUS MATERIALS SUMMARY Gallons in Open Use S\ stems Proposed / (Allowed) Golf Club Production & Assembh 8 / (30) 10 / (60) 207(160) 40 /(Unlimited) 30 / (200) 30 / (200) 10 /(Unlimited) Gallons in Closed Use S\ stems Proposed / (Allowed) Golf Club Production & Assembh 16 / (120) 30 / (240) 8C / (660) 60 / (Unlimited) 55 / (1000) 55 1(1 000) 10 /(Unlimited) CONTROL AREA No 1 Tvpe-lII Group B-2 - Division 2 Occupancj fullv sprinkler equipped Quantities listed abo\e are based upon the piesent pei milted amounts Inside Storage Capacity Proposed / (Allowed) [Gallons] Foam Storage Room 07(120) 20 / (240) 07 (660) 8857 (Unlimited) 9057(1000) 905(1000) 905(Unhmited) CONTROL AREA No 2 T\pe-III Group B-2 - Division 2 Occupancy Control Area sprinkler equipped ventillation rate of 350 CFM 1 hour fire rating 312 square feet area o•t—t S - O </i O "c5 •S 5 ^5 •*-•cd rt 3Nrtac 5 w Sr 2^i i «0 U J5 .2U» IIM C = g P ^e i i) 5 —^ ° 5 7 30 £ co J u u T" C 3 —2" <r s £ £ st —s c •3 Cj§ c- „ «. 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'0 -t w 2 ^— ^ "5 ^ si J •2 ~= % *t 7 5 H" -5 ^ 'O 'O o ~t "T r f^ r'*) OC ^ C^ 00 *"" •— '2 o 5 2 o § o 0 rs A-Componenl-Polymcric Isocyana(PDL 729-3 M)Diphcnylmclhanc 4 4-Dusoc}Higher Ollgomcrs of MDIPhenyl Isocyanatca,o "•Q g J-1 1 1'O ""* ^u t:1 1 1 "0 ~ - = — - 55•~> C. "3 J - 3 -S -Mill ac. g O Lu 90 rM •f w «— •— ' "j•% — ^ u — •5 "i S ? ^§ =• S u & o M M "3S * S z "oC- oc0I B-Componcnt-Polymcnc Alcohol(PDL 729-3 M)Hydroxyl Terminated Poly(01Tcnary Aminesi OCT IS '94 15 37 FROM UflN UJRTERS RND ROGERS TO 9311933 PflGE 002 NUMBER MSDS NO DQ6O2OCR EFFECTIVE DATE 03/22/94 PRODUCT DBE VAN UATERS & ROGERS INC MATERIAL SAFETY DATA SHEET PAGE 001 VERSION 001 ORDER NO PROD NO VAN UATERS «, ROGERS J NC , SUBSIDIARY OF UNIVAR £100 CARILLON POINT , KIRKLANO (206)889-3400 , UA 98033 EMERGENCY ASSISTANCE FOR EMERGENCY ASSISTANCE INVOLVING CHEMICALS CALL <80OM24-9300 FOR PRODUCT AND SALES INFORMATION CONTACT YOUR LOCAL VAN UATERS & ROGERS BRANCH OFFICE AT VU&R SAN DIEGO 619-262-0711 NATIONAL CTY, CA PRODUCT NAME: DBE MSDS * DQ6O2OCR 01 CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification Fo rmula Molecular Ueight Tradenames and Synonyms : CH300CCCH2>n-COOCH3, n=2 , Avg 159 and 4 ALIPHATIC DIBASIC ESTERS - DBE DIBASIC ESTER DIBASIC ESTER MIXTURE Company Identification 02 COMPOSITION/INFORMATION ON INGREDIENTS Compo nents Material DIMETHYL GLUTARATE CAS Number 1119-40-0 Y. 55-75 CCT IS '54 15 37 FROM UflN UJflTERS flND ROGERS TO 9311988 PflGE 003 REPORT NUMBER 971 VAN UATERS *. ROGERS INC. PAGE OO2 MSOS NO OQ6020CR MATERIAL SAFETY DATA SHEET EFFECTIVE DATEi O3/22/94 VERSION. 001 PRODUCT- DBE ORDER NO PROD NO DIMETHYL ADIPATE 627-93-O 10-25 DIMETHYL SUCCINATE 106-65-0 19-26 03 HAZARDS IDENTIFICATION * Potential Health Effects DBE may irritate skin, eyes, nose and throat May cause blurry vision. HUMAN HEALTH EFFECTS! Skin contact may cause skin irritation uith discomfort or rash Eye contact may cause eye irritation uith discomfort, tearing, or blurring of vision. Inhalation may cause irritation of the upper respiratory passages, with coughing and discomfort Some individuals who have been overexposed by inhalation or skin contact experienced blurry vision. The mechanism of blurred vision in humans is unknown Based on observed effects from animal studies, we believe that some symptoms of pre-existing eye disease coulcl be aggravated by overexposure to this material Carcinogenicity Information None of the components present in this material at concentrations equal to or greater than 0 1% are listed by 1ARC, NTP, OSHA or ACGIH as a carcinogen. 04 FIRST AID MEASURES * First Aid INHALATION If inhaled, immediately remove to fresh air If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician SKIN CONTACT Flush skin with water after contact Uash contaminated clothing before reuse. EYE CONTACT In case of contact, immediately flush eyes uith plenty of uater for at least 15 minutes Call a physician. OCT 18 '94 15 37 FROfl UfiN UflTERS flND ROGERS TO 9311983 PftGE 004 REPORT NUMBER' 971 VAN WATERS & ROGERS INC PAGE OO3 MSDS NO! DQ6020CR MATERIAL SAFETY DATA SHEET EFFECTIVE DATE: 03/22/94 VERSION OO1 PRODUCTi DBE ORDER NO PROD NO INGESTION If swallowed, do not induce vomiting. Immediately give 2 glasses of water. Never give anything by mouth to an unconscious person Call a physician. Notes to Physicians Activated charcoal mixture may be beneficial Suspend 50 g activated charcoal in -40O mL water and mix well. Administer 5 mL/kg, or 350 mL for an average adult. 05 FIRE FIGHTING MEASURES * Flammable Properties Flash Point 10O C <212 F) Method TCC Flammable limits in Air, % by Volume LEL : O 9 UEL i 8 0 Autoignition j 37O C (698 F) Actual Autoignition Temperature <AID can be affectrd by the concentration of vapors and oxygen, vapor/air contact time, pressure, volume, catalytic impurities, etc Process conditions should be analyzed to determine if the AIT's may be higher or lo uer Vapor forms explosive mixture uith air Hazardous gases/vapors produced in fire are carbon monoxide. * Extinguishing Media Uater Spray, Foam, Dry Chemical, C02. Fire Fighting Instructions Keep personnel removed and upwind of fire Dear self-contained breathing apparatus Wear full protective equipment Cool tank/container uith water spray. 06 ACCIDENTAL RELEASE MEASURES Safeguards CPersonnel) NOTE, Review FIRE FIGHTING MEASURES and HANDLING (PFRSONNEL) sections before proceeding with clean-up Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up CCT 18 '94 15 33 FROM URN LJflTERS flND ROGERS TO 9311988 PftGE 005 REPORT NUMBER. 971 VAN UATERS & ROGERS INC PAGE- 004 MSDS NO DQ4020CR MATERIAL SAFETY DATA SHEET EFFECTIVE DATE 03/22/94 VERSIONt O01 PRODUCT. DBE ORDER NO PROD NO Initial Containment Remove source of heat, sparks, flame, impact, friction or electricity Dike spill Prevent material from entering sewers, waterways, or low areas Spill Clean Up Recover free liquid for reuse or reclamatson Recover undamaged and minimally contaminated material for reuse and reclamation Soak UP with sawdust, sand, oil dry or other absorbent material 07 HANDLING AND STORAGE Handling (Personnel) Avoid breathing vapors or mist, Avoid contact with eyes, skin, or clothing. Uash thoroughly after handling Storage Do not mix with strong oxidants, acids, or alkalies Store in a uell ventilated place Keep container tightly closed 08 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Use sufficient ventilation to keep employee exposure belou recommended liaits. Personal Protective Equipment EYE/FACE PROTECTION Uear safety glasses. Uear coverall chemical splash goggles when possibility exists for eye and face contact due to splashing or spraying material. RESPIRATOR A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits Protection provided by ail—purifying respirators is limited. Use a positive pressure ail—supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where an—purifying respjrators may not provide adequate protection OCT 18 '94 15 33 FROM URN UJRTERS RND ROGERS TO 9311988 PRGE 005 REPORT NUMBER. 971 MSOS NO1. DQ6020CR EFFECTIVE DATE 03/22/94 PRODUCT DBE VAN UATERS & ROGERS INC MATERIAL SAFETY DATA SHEET PAGE: 005 VERSION- 001 ORDER NO: PROD NO PROTECTIVE CLOTHING Dear impervious clothing, such as gloves, apron, boots, or whole bodysuit as appropriate Recommended glove and clothing material Butyl Rubbei. Exposure Guidelines Exposure Limits DBE PEL (OSHA) TLV <ACGIH> AEL (Du Pont) : None Established • None Established : 1,5 ppm, 1O mg/m3, 8 Hr. 1UA This limit is Tor USE AEL is Du Pont's Acceptable Exposure Limit Uhere governraentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence 09 PHYSICAL AND CHEMICAL PROPERTIES * Physical Data Boiling Point Vapor Pressure Melting Point X Volatiles Evaporation Rate Solubility in Uater Odor Odor Threshold Form Co lo r Specific Gravity 10 STABILITY AND REACTIVITY Chemical Stability Stable. Incompatibility with Other Materials Incompatible or can react with strong oxidizers, acids, alkalies. 194-225 C (385-437 F> 0 2 ram Hg <3 20 C <68 F) '-20 C C-4 F) 10O UTX <2 20 C <68 F) <0 1 (Butyl Acetate=l O) 5.3 U1X Q 20 C (68 F) Sweet 0.1 ppm 100% detection O.O1 ppm SOX detection Liquid Co lor less 1 092 Q 20 C (68 F> QCT 18 '94 15 38 FROM UflN UlflTERS flND ROGERS TO 9311983 PRGE 007 REPORT NUMBER 971 VAN UATERS «, ROGERS INC PAGE OO6 MSDS NO i OQ6020CR MATERIAL SAFETY DATA £>HEET tFFECTIVE DATE. 03/22/V4 VERSION OO1 PRODUCT- DBE ORDER NO PROD NO Decompo sit 10 n Decomposes with heat Polymerization Polymerization will not occur, 11 TQXICOLOGICAL INFORMATION Animal Data Inhalation 4-hour LC50• >11 mg/L in rats Inhalation 1-hour LC50• HO 7 mg/L in rats Skin absorption LD50 s >2,25O mg/kg in rabbits Oral LD5O 8,191 ing/kg in rats The mixture is a mild to severe skin irritant and a moderate eye irritant, but is not a skin sensitizer in animals Toxic effects described in animals from exposure by inhalation include upper respiratory tract irritation A single 4-hour exposure to 60 ppm caused transient corneal opacity and transient increases in the distance from the cornea to the anterior surface of the lens of the eye Toxicity described in animals from repeated exposure by inhalation include decreased weight gain, absolute and relative liver weight decrease, and degeneration of olfactory epithelium (nasal tissue) Toxicity described in animals from repeated exposure by ingestion include ueight loss, but there were no pathological abnormalities noted A single application of 1O uL to the eye caused corneal opacity, The administration of 10-100 uL of a similar mixture caused corneal opacity, transjent increases j.n corneal thickness, and transient corneal anesthesia. A single application of approximately 60 mg/kg to the skin caused transient increases in the distance from the cornea to the anterior surface of the lens of the eye The mixture does not produce genetic damage in animals, or in bacterial cell cultures, but it was positive in one study with cultured mammalian cells Animal testing indicates that this mixture does not have developmental, or reproductive effects I"? ECOLOGICAL INFORMATION Ecotoxicologica1 Information OCT 18 '94 15 39 FROM UflN UflTERS RND ROGERS TO 9311988 PRGE 008 REPORT NUMBER! 971 VAN UATERS *, ROGERS INC PAGE. OO7 USDS NO DQ6O20CR MATERIAL SAFETY DATA SHEET EFFECTIVE DATE-. 03/22/94 VERSION i OOl PRODUCT DBE ORDER NO PROD NO AQUATIC TOX1CITY DBE 9£ hour LC50 - Fathead minnows- 18-24 rag/L Moderately toxic 48 hour LC50 - Daphnia magna. 112-15O mg/L 13 DISPOSAL CONSIDERATIONS * Uaste Disposal Treatment storage, transpo rtat 10 r\, and disposal nrnsi be in accordance uith applicable Federal, State/Provincial, and Local regulations Recover nonusable free liquid and dispose of xn approved and permitted incinerator. Recover nonusable free liquid and dispose of in approved and permitted biological treatment system. Recover contaminated water and dispose of in approved and permitted biological treatment system Remove nonusable solid material and/or contaminated soil, for disposal in an approved and permitted landfill Do not flush to surface water or sanitary seuer system 14 TRANSPORTATION INFORMATION Shipping Information NOT REGULATED AS A HAZARDOUS MATERIAL BY DOT, IMO, OR IATA Shipping Containers Tank Cars • 170,OOO Ibs Tank Trucks \ 42,OOO Ibs. Steel Drums • 485 Ibs 15 REGULATORY INFORMATION U S. Federal Regulations TSCA Inventory Status • Reported/Included TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 Acute • Yes Chro nic No Fire No Reactivity : No Pressure I No OCT 18 '94 15 39 FROM URN IJftTERS RND ROGERS TO 9311988 PftGE 009 REPORT NUMBER' 971 VAN UATERS 8, ROGERS INC PAGE OOB MSDS NO: DQ6020CR MATERIAL SAFETY DATA SHEET EFFECTIVE DATfc. 03/22/94 VERSION OO1 PRODUCT. DDE ORDER NO PROD NO HAZARDOUS CHEMICAL LISTS SARA Extremely Hazardous Substances No CERCLA Hazardous Substance No SARA Toxic Chemical ! No Canadian Regulations CLASS D Division 2 Subdivision B - Toxic Material ^fcin or Eye Irritant 14 OTHER INFORMATION NFPA, NPCA-HMIS NPCA-HMIS Rating Health 1 Flamraability 1 Reactivity 0 Personal Protection rating to be supplied by user depending on use conditions. * Additional Information The hydrogen cyanide concentration in this product i«; so lou <<10 ppm) as to be to xico logically insignificant when thi<3 pi-oduct is used as a solvent However, when this product is chemically reacted with alcohols, and methanol is recovered from that reaction and purified for reuse by distillation, concentration of highly volatile impurities such as hydrogen cyanide to toxicologically significant levels can occur in the waste stream from this process Processors using this product as a raw material shouid be auare of this potential hazard # Indicates updated section. End of MbDS OCT 18 '94 15 39 FROM VflN LJflTERS fiND ROGERS TO 93119S8 PfiGE 013 REPORT NUMBER 971 VAN UATERS & ROGERS INC PAGE- OO9 MSDS NO DQ6020CR MATERIAL SAFETY DATA SHEET EFFECTIVE DATE- 03/22/94 VERSION' OOi PRODUCT. QBE ORDER NO. PROD NO : f-QR ADDITIONAL INFORMATION CONTACT. MSDS COORDINATOR VU&R SAN DIEGO DURING BUSINESS HOURS, PACIFIC TiME (206)889-3400 10/18/94 15.30 PRODUCT CUST NO ORDER NO NOTICE - ** VAN UATERS & ROGERS INC. ("VIJJ.R") EXPRESSLY DISCLAIMS ALL EXPRESS OR IMPLIED UARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, WITH RESPECT TO THE PRODUCT OR INFORMATION PROVIDED HEREIN, AND SHALL UNDER NO CIRCUMSTANCES BE LIABLE FOR INCIDENTAL OR CONSEQUENTIAI DAMAGES ** ALL INFORMATION APPEARING HEREIN IS BAbED UPON DATA OBTAINED FROM THE MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES UHILE THE INFORMATION IS BELIEVED TO BE ACCURATE, VU&R MAKES NO REPRESENTATIONS AS TO ITS ACCURACY OR SUFFICIENCY CONDITIONS OF USE ARE BEYOND VUiRS CONTROL AND THEREFORE USERS ARE RESPONSIBLE TO VERIFY THIS DATA UNDER THEIR OUN OPERATING CONDITIONSvTO DETERMINE UHETHER THE PRODUCT IS SUITABLE FOR THEIR PARTICULAR PURPOSES AND TH£^ ASSUME ALL RISKS OF THEIR USE, HANDLING, AND DISPOSAL OF THE PRODUCT, OR FROM THE PUBLICATION OR USt OF, OR RELIANCE UPON , INFORMATION CONTAINED HEREIN THIS INFORMATION RELATES ONLY 10 THE PRODUCT DESIGNATED HEREIN, AND DOES NOT RELATE TO ITS USE IN COMBINATION UITH ANY OTHER MATERIAL OR IN ANY OTHER PROCESS *** END OF MSDS * * A *•* TOTPL PflGE 010 ** OCT 18 -94 15 36 FROM UfiN UfiTERS AND ROGERS TO 9311988 PRGE 001 Van Waters & Rogers Inc. subsidiary of Univar 2100HAFFLEYAVE. NATIONAL CITY, CA 91950 PHONE (619)262-0711 FAX (619) 474-2820 DATE_ TO COMPANY LOCATION FAX NUMBER FROM FAX COVER SHEET FROM SAN DIEGO loo Number of pages including this cover COMMENTS Oct 24 1994 14:42:48 EDT FEOH: EflSTHflH CHEH UT HSG8 88448734-885-1 PAGE 881 OF 818 EASTMAN Eastman Chemical Company 1993Wbwtr FAX DELIVERY 10 TOTAL PAGES INCLUDING COVER RELAYED VIA XPEDITE SYSTEMS INC TO JOE ALBORN TEL/EXT FROM LITERATURE SERVICES TEL/EXT 239546S SUBJ 14914 XPEDITE REFERENCE NUMBER 8440734 ORIGINATOR REFERENCE NUMBER TO REPLY VIA TELEX, PLEASE DIAL 189800048 Neither Eastman nor its marketing affiliates shall be responsible for the use of this information, or of any product, method or apparatus mentioned, and you must make your own determination of its suitability and completeness for your own use, for the protection of the environment, and for the health and safety of your employees and purchasers of your products No warranty is made of the merchantability or fitness of any production,and nothing herein waives any of the Seller's conditions of sale Oct 24' 1994 14-43 11 EDT FROM1. EASTHAH CHEH UT MSG8 88448734-885-1 PAGE 882 OF 818 EASTMAN Eastman Chemical Company 1993Winner MATERIAL SAFETY DATA SHEET 00000079/F/USA Approval Date 10/31/1993 Tint Date 10/24/1994 'age 1 i CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 3roduct Name EASTMAN1 DEP Plasticizer Jroduct Identification Number(s) SPC 149m •lanuf ac turer/Supplier Eastman Chemical Company, Kingsport, Tennessee 37662 iSDS Prepared by Product Safety Department, Eastman Chemical Company, <ingsport, TN 37662 -or Emergency Health, Safety & Environmental Information, call 800-EASTMAN For Emergency Transportation Information, call CHEMTREC 800-424-9300 or call 300-EASTMAN For Other Information, call your Eastman representative or the Eastman operator 515-229-2000 (USA) Chemical Name diethyl 1,2-benzenedicarboxylate Synonym(s) PM 00080-00, KAN 900124, ( diethyl phthalate Molecular Formula C12H1404 Molecular Weight 222 24 Product Use plasticizer — —- — — — — -—^ — — —*--——^ — ^ — — -—-———-——•—- — —•—_—.—_— — •— — — ™ — —-— — —«— — — — — ——- — — -——,___.^__.— ——.„_ — -——-_._•—--_„_____ 2 COMPOSITION/INFORMATION ON INGREDIENTS Weight X - Component - (CAS Registry No ) 100 diethyl phthalate (000084-66-2) — — — —___ — —. — _ — — — _ — — — —— — —— — — — — — — — — —— — — — — — — — —— — —— — —— — — — ————. — — .— — _ — — — _____—___________„ 3 HAZARDS IDENTIFICATION LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL HMIS Hazard Ratings Health - 1, Flammability - 1, Chemical Reactivity - 0 NFPA Hazard Ratings Health - 0, Flammability - 1, Chemical Reactivity - 0 NOTE HMIS and NFPA ratings involve data and Interpretations that may vary from Ott 24 1994 14.43138 EDT FROM: EASTMflN CHEM UT MSG8 88440734-085-1 PAGE 083 OF 810 ompany to company They are intended only for rapid, general identification of Oct 24 1994 14 43:53 EDT FROM: EflSTHAH CHEM UT MSG« 88448734-885-1 PflGE 884 OF 818 MATERIAL SAFETY DATA SHEET 00000079/F/USA approval Date 10/31/1993 Tint Date 10/2H/199H 'age 2 he magnitude of the specific hazard Ta deal adequately with the safe handling if this material, all the information contained in this MSDS must be considered FIRST-AID MEASURES nhalation If symptomatic, move to fresh air Get medical attention if symptoms jersist lyes Any material that contacts the eye should be washed out immediately with vater Get medical attention if symptoms persist Wash with soap and water Get medical attention if symptoms occur ngestion Seek medical advice 5 FIRE FIGHTING MEASURES Ixtinguishing Media water spray, dry chemical, carbon dioxide (COS), foam Special Fire-Fighting Procedures Wear self-contained breathing apparatus and protective clothing Hazardous Combustion Products carbon dioxide, carbon monoxide Jnusual Fire and Explosion Hazards none 5 ACCIDENTAL RELEASE MEASURES Absorb spill with vermiculite or other inert material, then place in a container for chemical waste For Large Spills Flush spill area with water spray Prevent runoff from entering drains, sewers, or streams 7 HANDLING AND STORAGE Personal Precautionary Measures No special precautionary measures should be needed under anticipated conditions of use Prevention of Fire and Explosion Keep from contact with oxidizing materials Storage Keep container closed 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Oct 24 1994 14.44.28 EDT F80«: EASTHflN CHEM UT MSG8 88448734-885-1 PfiGE 885 OF 018 MATERIAL SAFETY DATA SHEET 30000079/F/USA :jproval Date 10/31/1993 -znt Date 10/24/1994 age 3 <posure Limits ACGIH Threshold Limit Value (TLV) 5 mg/m3 TWA OSHA (USA) Permissible Exposure Limit (PEL, 1989 Table Z-l-A values or section-specific standards) 5 mg/m3 TWA antilation Good general ventilation (typically 10 air changes per hour) should a used Ventilation rates should be matched to conditions Use process nclosures, local exhaust ventilation, or other engineering controls to maintain irborne levels below recommended exposure limits espiratory Protection If engineering controls do not maintain airborne oncentrations below recommended exposure limits, an approved respirator must be orn Respirator type mist If respirators are used, a program should be nstituted to assure compliance with OSHA Standard 29 CFR 1910 134 ye Protection It is a good industrial hygiene practice to minimize eye ontact kin Protection It is a good industrial hygiene practice to minimize skin ontact ecommended Decontamination Facilities eye bath, washing facilities PHYSICAL AND CHEMICAL PROPERTIES Physical Form liquid Color colorless Odor odo rless Odor Threshold not available Specific Gravity at 20±C (68±F) (water =1) 1 12 Vapor Pressure at 20+C (68 + F) 0 0005 mbar (0 0004 mm Hg) Vapor Density (Air =1) 77 Evaporation Rate not available Boiling Point 297 + C (5B7±F) Melting Point -m±C (-42±F) Viscosity at 20±C (68±F) 1 24 mPa s or cP Solubility in Water at 20±C (68±F) 0 12 g/L - pH not applicable - Octanol/Water Partition Coefficient log P = 0 62 - 1 04, P = 4 - 11 - Flash Point (Setaflash closed cup) 160±C (320±F) - Lower Explosive Limit at 187±C (369+F) 0 75 volume X - Upper Explosive Limit not available - Autoignition Temperature (ASTM D 2155) 457±C (855±F) - Sensitivity to Mechanical Impact insensitive at 100 kg-cm - Sensitivity to Static Discharge Material is unlikely to accumulate a static charge which could act as an ignition source Dct 24 1994 14.44.58 EDT FROM1 EftSTttAN CHEM UT MSG» 88448734-BB5-1 PAGE 886 OF BIB MATERIAL SAFETY DATA SHEET OOOOOQ79/F/USA pproval Date 10/31/1993 nnt Date 10/24/19914 age 4 0 STABILITY AND REACTIVITY tabilxty stable ncompatibility Material can react with strong oxidizing agents azardous Polymerization will not occur 1 TOXICOLOGICAL INFORMATION fFects of Exposure Inhalation Low hazard For usual industrial handling or commercial handling by trained personnel Eyes Low hazard for usual industrial handling or commercial handling by trained personnel Skin Low hazard for usual industrial handling or commercial handling by trained personnel Ingestion Expected to be a low ingestion hazard cute Toxicity Data Oral LD-50 (rat) 9000 mg/kg Oral LD-50 (rabbit) 1000 mg/kg Inhalation LC-50 (rat) >4 64 mg/L/6 hour(s) (highest concentration tested) Dermal LD-50 (guinea pig) >20 mL/kg (highest dose tested) Skin irritation (guinea pig) slight Eye irritation (rabbit) slight lefinitions for the Following section(s) LOEL = lowest-observed-eFFect level, 10AEL = no observed-adverse-eFFect level, NOEL = no-observed-eFFect level •ubchronic Toxicity Data Oral study (> 6 weeks, rat) NOEL =25 g/kg/day (highest dose tested) Oral study (> 6 weeks, dog) NOEL = 1 25 g/kg/day (highest dose tested) Oral study (16 weeks, male rat) LOEL = 5 X in diet (increase in weight liver), (reduced body weight gain), NOAEL = 1 0 * in diet Oral study (90 days, Female rat) LOEL = 0 2 X in diet (increase in weight liver), (reduced body weight gain), NOAEL = not established :hronic Toxicity Data Hct 24 1994 14.45H7 EDT FROM: EASTMAN CHEM UT MSG8 B8448734-BBS-1 PAGE BB7 OF BIB MATERIAL SAFETY DATA SHEET D0000079/F/USA uproval Date 10/31/1993 rint Date 10/24/1994 age 5 Oral study (104 weeks, rat) LOEL = 5 X in diet (decrease in growth rate), NOEL = 2 5 X in diet Oral study (104 weeks, dog) NOEL = 2 5 X in diet (highest concentration tested) eproductive Toxicity Data Oral study (mouse) NOEL for maternal/paternal ertility = 2 5 % in diet (highest concentration tested) evelopmental Toxicity Data Oral study (rat) NOEL for embryo/fetotoxicity = 5 X in diet, NOEL for teratogenicity = 5 X in diet (highest concentration tested) Dermal study (mouse) LOEL for maternal toxicity = 500 mg/kg/day (decrease in weight spleen), NOEL for maternal toxicity = not established, NOEL for teratogenicity = 5600 mg/kg/day utagenicity/Genotoxicity Data Salmonella typhimurium assay (Ames test) negative CHO/HGPRT assay negative (+/- activation) Chromosomal aberration assay negative 2 ECOLOGICAL INFORMATION ntroduction This environmental effects summary is written to assist in iddressing emergencies created by an accidental spill which might occur during he shipment of this material, and, in general, it is not meant to address Jischarges to sanitary sewers or publically owned treatment works )ata for this material have been used to estimate its environmental impact It ias the following properties a high biochemical oxygen demand and a potential .o cause oxygen depletion in aqueous systems, a moderate potential to affect some aquatic organisms, a moderate potential to affect the germination and/or 3arly growth of some plants, a low potential to affect the growth of some plant seedlings, a high potential to biodegrade (low persistence) with unacclimated nicroorganisms from activated sludge, a low potential to bioconcentrate •Jhen diluted with a large amount of water, this material released directly or indirectly into the environment is not expected to have a significant impact Uxygen Demand Data COD 1 66 - 2 10 g oxygen/g BOD-5 2 00 g oxygen/g Oct Z4 1994 14.45.48 EDT FROM. EflSTMflN CHEH UT HSGtt 8B448734-B85-1 PftGS 88B OF 818 MATERIAL SAFETY DATA SHEET 00000079/F/USA pproval Date 10/31/1993 rint Date 10/24/1994 age 6 cute Aquatic Effects Data 96-h LC-50 (fathead minnow) 10 - 100 microlitre(s)/I 96-h LC-50 (daphnid) 10 - 100 microlitre{s) /1 48-h LC-50 (golden orfe) 53 - 61 mg/L -Day Plant Germination Effects - No-adverse-effect concentration Ryegrass 10 microlitre(s)/I Radish 10 microlitre(s)/I Lettuce 10 microlitre(s) / 1 -Day Plant Seedling Effects - No-adverse-effect concentration Marigold 100 microlitre(s ) /I Radish 100 micro lit re(s) /1 Corn 100 microlitre(s)/I Lettuce 100 microlitre(s)/I 3 DISPOSAL CONSIDERATIONS iischarge, treatment, or disposal may be subject to national, state, or local aws Incinerate — __«. — _ _, — _ _ «. _ — ___ — _______ — — __ — _ _ _ — _____ — _______ — — _ — — _ — — —_ _ __ — _ _ — _„ — 4 TRANSPORT INFORMATION DOT (USA) Status net quantities less than 454 kg (1000 pounds) are not regulated, the following requirements apply to larger quantities - Class 9, packing group III - Proper Shipping Name and Number Environmentally Hazardous Substances, Liquid, n o s , UN 3082 - DOT Reportable Quantity 1000 Ib (454 kg) - TDG (Canada) Status not regulated - Air - International Civil Aviation Organization (ICAO) - ICAO Status regulated - Class 9, packing group III - Proper Shipping Name and Number Environmentally Hazardous Substances, Liquid, n o s (diethyl phthalate ), UN 3082 - Sea - International Maritime Dangerous Goods (IMDG) - IMDG Status not regulated 15 REGULATORY INFORMATION - This document has been prepared in accordance with the MSDS requirements of Oct 24 1994 14.46.'14 EDT FROM: EASTMAN CHEM UT MSG8 88448734-885-1 PAGE 889 OF 810 MATERIAL SAFETY DATA SHEET 00000079/F/USA Approval Date 10/31/1993 Tint Date 10/E4/1994 'age 7 the OSHA Hazard Communication Standard 29 CFR 1910 1200 OSHA hazardous chemical(s) diethyl phthalate - Material(s) known to the State of California to cause cancer none - Material(s) known to the State of California to cause adverse reproductive effects none - Massachusetts Substance List diethyl phthalate - New Jersey Workplace Hazardous Substance List diethyl phthalate - Pennsylvania Hazardous Substance List diethyl phthalate - This document has been prepared in accordance with the MSDS requirements of the WHMIS Controlled Products Regulation - WHMIS (Canada) Ingredient Disclosure List diethyl phthalate - WHMIS (Canada) Status noncontrolled - Carcinogenicity Classification (components present at 0 12 or more) - International Agency for Research on Cancer (IARC) not listed - American Conference of Governmental Industrial Hygienists (ACGIH) not listed - National Toxicology Program (NTP) not listed - Occupational Safety and Health Administration (OSHA) not listed - Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372 diethyl phthalate - SARA (USA) Sections 311 and 312 hazard classification(s) immediate (acute) health hazard - US Toxic Substances Control Act (TSCA) This product is listed on the TSCA inventory or otherwise complies with TSCA premanufacture notification requirements - Canadian Environmental Protection Act (CEPA) and Domestic Substances List (DSL) This product is listed on the DSL or otherwise complies with CEPA new substance notification requirements - European Inventory of Existing Commercial Chemical Substances (EINECS) This product is listed on EINECS or has been approved in the European Community by hew substance notification EINECS N'jmber 2015506 - Australian Inventory of Chemical Substances (AICS) and National Industrial Chemicals Notification and Assessment Scheme (NICNAS) This product is listed on AICS or otherwise complies with NICNAS - Japanese Handbook of Existing and New Chemical Substances This product is listed in the Handbook or has been approved in Japan by new substance notification Oct 24 1994 14.46.47 EDT FROM: EflSTMftH CHEM UT ttSGtt 88448734-8B5-1 PfiGE BIB OF BIB MATERIAL SAFETY DATA SHEET 00000079/F/USA pproval Date 10/31/1993 nnt Date 10/2il/199H age 8 6 OTHER INFORMATION S/Canadian Label Statements LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL Get medical attention if symptoms occur CAUTION FOR MANUFACTURING, PROCESSING OR REPACKING BY TRAINED PERSONNEL he information contained herein is furnished without warranty of any kind Jsers should consider these data only as a supplement to other information jathered by them and must make independent determinations of suitability and ompleteness of information from all sources to assure proper use and disposal if these materials and the safety and health of employees and customers and the jrotection of the environment EPIBOND 1559 A MATERIAL SAFETY DATA SHEET CI3A-GEIGY CORPORATION FURANE PRODUCTS 5121, SAN FERNANDO ROAD WEST LOS ANGELES, CALIFORNIA 90039 EMERGENCY PHONE NUMBERS: SAFETY /HEALTH: (818) 247-6210 24 HOURS: (800) 888-8372 SECTION I IDENTITY ************i PRODUCT NAME EPIBOND 1559 A CHEMICAL NAME: Filled epoxy resin DATE ISSUED: 08/03/92 HAZARD RATING: TOXICITY' 1 PRODUCT CODE: FPC2181 MSDS CODE: FS1288 FIRE: 1 REACTIVITY: 1 SPECIAL; 4=EXTREME; 3=HIGH; 2=MODERATE; 1=SLIGHT; 0=INSIGNIFICANT; * = SEE SECTION VI *****************^ SECTION II INGREDIENT CHEMICAL IDENTITY OCCUPATIONAL EXPOSURE TLV LIMITS CAS NUMBER FPC OSHA ACGIH Bisphenol A-diglycidylether resin 2-Propenenitrile, polymer with 1,3- butadiene and ethylbenzene Ammonium polyphosphate Dimethyl methyl phosphonate Silane, tnmethoxy{2-(7-oxabicyclo- (4 . 1 . 0) hept-3-yl) ethyl} - 25068-38-6 NE 9003-56-9 NE 68333-79-9 NE 756-79-6 NE 3388-04-3 NE NE NE NE NE NE NE NE NE NE NE These chemicals are not considered to be carcinogenic by NTP, IARC, or OSHA. COMMENTS. NE - NOT ESTABLISHED. SECTION III PHYSICAL PROPERTY INFORMATION APPEARANCE AND ODOR- Blue color soft paste, No odor VISCOSITY. "90,000 cps VAPOR PRESSURE (mm Hg). < 1 i 20° C r*x************************ PAGE EPIBOND 1559 A VAPOR DENSITY (AIR = 1) . > 1 SOLUBILITY IN WATER: Negligible PERCENT VOLATILE (BY WEIGHT): < 1 SPECIFIC GRAVITY (WATER = 1}• 1.20 EVAPORATION RATE (BUTYL ACETATE = 1) : < 1 t***l SECTION IV FIRE AND EXPLOSION HAZARD INFORMATION************ FLASH POINT: 254° C Pensky-Martens Closed Cup EXTINGUISHING MEDIA: CO2/ Dry chemical, Water spray. SPECIAL FIRE FIGHTING PROCEDURES: Wear breathing apparatus (MSHA/NIOSH — approved, pressure demand, self-contained or equivalent.) and full protective gear. UNUSUAL FIRE AND EXPLOSION HAZARDS: Decomposition and combustion products may be toxic. IT***************************** SECTION V REACTIVITY INFORMATION *********** STABILITY: Stable under normal conditions CONDITION TO AVOID: Elevated temperatures HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide. HAZARDOUS POLYMERIZATION. Will not occur INCOMPATIBILITY. Strong oxidizing agents, acids. :******************************** SECTION VI HEALTH HAZARD INFORMATION**************************** PRIMARY ROUTES OF EXPOSURE. Dermal, Inhalation ORAL LD 50: (Rats) 840 - 2400 mg/Kg (component) DERMAL LD 50 2-10 gra/Kg SKIN IRRITATION Irritant EYE IRRITATION Irritant PAGE •J OOSOc? EPIBOND 1559 A SENSITIZATION- Sensitizer OVEREXPOSURE EFFECTS: This products contains materials that are considered to be skin and eye irritants and can cause allergic skin reactions. Some components are considered nuisance dust only. Some materials in this product have had effects on male reproductive organs and fertility in animal studies. Contains dimethylmethylphosphate and epoxycyclohexylethyltnmethoxy silane which has been shown to induce tumors in some animal species. MEDICAL CONDITION AGGRAVATED BY EXPOSURE: Allergy, eczema, or skin conditions. EMERGENCY AND FIRST AID PROCEDURES - EYES: Flush eyes with water for at least 15 minutes. Get medical attention. EMERGENCY AND FIRST AID PROCEDURES - SKIN: Wash with mild soap and water. If irritation occurs, get medical attention. EMERGENCY AND FIRST AID PROCEDURES - INGESTION: If conscious, give large quantities of water. Get medical attention. EMERGENCY AND FIRST AID PROCEDURES - INHALATION: Remove to fresh air. Get medical attention. EMERGENCY AND FIRST AID PROCEDURES - OTHER: Wash contaminated clothing prior to reuse. k*******************************************^ SECTION VII SPILL OR LEAK PROCEDURE INFORMATION ************************************************** STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED-: Clean up all traces of spill. Shovel as much of material as possible into clean, dry containers. On hard surface use absorbent material to pick up remainder; on loose surfaces shovel up contaminated layer. WASTE DISPOSAL METHODS: Incinerate in approved equipment. Incinerate or landfill contaminated diking material in accordance with local, state and federal regulations. b****************************************:l SECTION VIII SPECIAL PROTECTION INFORMATION ***************** VENTILATION TYPE: Normal room ventilation RESPIRATORY PROTECTION: None required if good ventilation is maintained. Wear respirator (MSHA/NIOSH-approved) suitable for concentrations and type of air contaminants encountered. PROTECTIVE GLOVES: Impervious gloves EYE PROTECTION. Safety glasses (ANSI Z-87.1) OTHER PROTECTIVE EQUIPMENT: Protective clothing, safety shower and eyewash facility. PAGE EPIBOND 1559 A SECTION IX STORAGE AND HANDLING INFORMATION HANDLING, SHIPPING AND STORING PRECAUTIONS: Eye and skin irritant. Avoid all skin contact. May cause allergic reaction. Wash exposed area thoroughly with soap and water after handling this material and specially before eating, smoking, or drinking, or using toilet facilities. FOR INDUSTRIAL USE ONLY. STORAGE TEMPERATURE: MAXIMUM 35° C PLEASE READ TECHNICAL DATA SHEET BEFORE HANDLING THE PRODUCT. ***************************** SECTION X TOXICITY INFORMATION*********** IRRITATION: EYES - Moderate SKIN - Slight For Bisphenol A-Diglycidyl ether resin: ORAL LD 50: >10,000 mg/Kg (rats) DEEMAL LD 50- >6,000 mg/Kg (rabbits) c*********************************- SECTION XI MISCELLANEOUS INFORMATION ******************: NOTE TO PHYSICIAN: Allergic dermatitis or respiratory response in susceptible individuals may be delayed. It may appear after weeks or even months of frequent and prolonged contact. DOT/IATA SHIPPING/PACKAGING INFORMATION: DOT PROPER SHIPPING NAME: Not Restricted DOT HAZARD LABEL/CLASS: Not Regulated DOT/UN NUMBER: Not Available PACKAGING GROUP: Not Applicable RCRA STATUS: Not a hazardous vaste under RCRA (40 CFR 261) CERCLA STATUS. Not listed SARA TITLE III - TOXIC CHEMICALS LIST: This product does not contains toxic chemicals subject to the routine annual "Toxic Chemical Release Notification" under Section 313 (40 CFR 372) TOXIC SUBSTANCE CONTROL ACT (TSCA): INVENTORY STATUS Chemical components listed on TSCA inventory. PAGE o OO5OS EPIBOND 1559 A PENNSYLVANIA RIGHT TO KNOW ACT: The following is required composition information. This product contains: (1) Bisphenol A-diglycidylether resin (2) Propenenitrile, polymer with 1,3-butadiene and ethylbenzene (3) Ammonium polyphosphate (4) Dimethyl methyl phosphonate (5) Silane, trimethoxy{2-(7-oxabicyclo(4.1.0)hept-3-yl)ethyl}- CALIFORNIA RIGHT TO KNOW ACT (PROPOSITION 65): The following is required statement. WARNING 11 I This product may contain a chemical which is known to state of California to cause cancer and/or"_reproductivity toxicity._^) CHEMICAL NAME . % BY WEIGHT Epichlorohydrin trace CALIFORNIA SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT RULE 443.1: VOLATILE ORGANIC COMPOUNDS: This product contains 12* mg/liter volatile Organic Compounds. (VOC) * - Based on theoretical calculation ISSUE DATE: 08/03/92 REVISION: 02A SUPERSEDES DATE: 01/12/90 ISSUED BY: RAJESH S. PATEL FOR FURTHJ&i INFORMATION, PLEASE CONTACT: PRODUCT SAFETY DIRECTOR IMPORTANT MESSAGE!!! THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE THEREOF. CIBA-GEIGY CORPORATION ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY THE MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF THE MATERIAL. HAZARD STATEMENT !!! THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH FEDERAL OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200. THIS PRODUCT IS CONSIDERED TO BE A HAZARDOUS CHEMICAL UNDER THAT STANDARD *******: PAGE EPIBOND 1559 B MATERIAL SAFETY DATA SHEE CIBA-GEIGY CORPORATION FURANE PRODUCTS 5121, SAN FERNANDO ROAD WEST LOS ANGELES, CALIFORNIA 90039 T EMERGENCY PHONE NUMBERS: SAFETY/HEALTH: (818) 247-6210 24 HOURS: (800) 888-8372 SECTION I IDENTITY************* PRODUCT NAME: EPIBOND 1559 B CHEMICAL NAME: Mercaptan terminated polymer DATE ISSUED. 08/03/92 PRODUCT CODE: FPC2180 MSDS CODE: JS1288 HAZARD RATING: TOXICITY- 3 FIRE: 1 REACTIVITY: 1 SPECIAL: 4=EXTREME; 3=HIGH; 2=MODERATE; 1=SLIGHT; 0=INSIGNIFICANT; * = SEE SECTION VT SECTION II INGREDIENT CHEMICAL IDENTITY CAS NUMBER OCCUPATIONAL EXPOSURE TLV LIMITS FPC OSHA ACGIH Mercaptan polymer 2,4,6-Tri(dimethylaminomethyl) phenol Ammonium polyphosphate Organophilic clay NOT AVAIL. NE NE NE 90-72-2 5 NE NE 68333-79-9 NE NE NE NOT AVAIL. NE NE NE 5 PPM These chemicals are not considered to be carcinogenic by NTP, IARC, or OSHA. COMMENTS: NE - NOT ESTABLISHED.******************************** SECTION III PHYSICAL PROPERTY INFORMATION********************* APPEARANCE AND ODOR. Dark grey color soft paste, Mercaptan odor VISCOSITY "90,000 cps VAPOR PRESSURE (mm Hg): < 1 @ 20° C VAPOR DENSITY (AIR = 1): > 1 SOLUBILITY IN WATER: Slicht PAGE O05O3 EPIBOND 1559 B PERCENT VOLATILE (BY WEIGHT): Nil SPECIFIC GRAVITY (WATER = 1): 1.30 EVAPORATION RATE (BUTYL ACETATE = 1): < 1 t***i SECTION IV FIRE AND EXPLOSION HAZARD INFORMATION ************ FLASH POINT. >124° C Cleaveland Open Cup EXTINGUISHING MEDIA: CO2, Dry chemical, Foam, Water spray. SPECIAL FIRE FIGHTING PROCEDURES: Wear breathing apparatus (MSHA/NIOSH - approved, pressure demand, self- contained or equivalent.) and full protective gear. UNUSUAL FIRE AND EXPLOSION HAZARD: Decomposition and combustion products may be toxic.it ***************************** SECTION V REACTIVITY INFORMATION ********** STABILITY: Stable under normal conditions CONDITION TO AVOID: Elevated temperatures HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, hydrogen sulfide, oxides of sulfur. HAZARDOUS POLYMERIZATION. Will not occur INCOMPATIBILITY: Strong oxidizing agents, acid_s and bases. SECTION VI HEALTH HAZARD INFORMATION PRIMARY ROUTES OF EXPOSURE. Dermal, Inhalation ORAL LD 50- (Rats) 5000 - 10000 gm/Kg (components) DERMAL LD 50. (Rats) 6000 mg/Kg SKIN IRRITATION. Corrosive. EYE IRRITATION Corrosive. INHALATION LC 50 25 gn/M3/2 hours. PAGE o OO5O3 EPIBOND 1559 B OVEREXPOSURE EFFECTS: This products contains components that can cause skin, eye, and respiratory irritation and prolonged contact may result in allergic skin reactions and are considered nuisance dusts. MEDICAL CONDITION AGGRAVATED BY EXPOSURE: Allergy, eczema, eye or respiratory conditions. EMERGENCY AND FIRST AID PROCEDURES - EYES: Flush eyes with water for at least 15 minutes. Get medical attention. EMERGENCY AND FIRST AID PROCEDURES - SKIN: Wash with mild soap and water. If irritation occurs, get medical attention. EMERGENCY AND FIRST AID PROCEDURES - INGESTION: If conscious, give large quantities of water. Get medical attention. EMERGENCY AND FIRST AID PROCEDURES - INHALATION: Remove to fresh air. Get medical attention. EMERGENCY AND FIRST AID PROCEDURES - OTHER: Wash contaminated clothing prior to reuse. t* ******************************************: SECTION VII SPILL OR LEAK PROCEDURE INFORMATION ************************************************** STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED' Use protective equipment. Clean all traces of spill. Shovel as much of material as possible into dry, clean containers. On hard surface use absorbent material to pick up remainder; on loose surfaces shovel up contaminated layer. Keep spills and cleaning runoffs out of municipal sewers and open bodies of water. WASTE DISPOSAL METHODS: Incinerate in approved equipment in accordance with local, state, and federal regulations. r********************* SECTION VIII SPECIAL PROTECTION INFORMATION***************** VENTILATION TYPE: Mechanical local exhaust ventilation at point of contaminant release. RESPIRATORY PROTECTION: Wear respirator (MSHA/NIOSH-approved) suitable for concentrations and type of air contaminants encountered. PROTECTIVE GLOVES. Impervious gloves EYE PROTECTION: Chemical splash goggles (ANSI Z-87.1) OTHER PROTECTIVE EQUIPMENT. Protective clothing, safety shower and eyewash facility PAGE EPEBOND 1559 B it*****************SECTION IX STORAGE AND HANDLING INFORMATION ******************************************** HANDLING, SHIPPING AND STORING PRECAUTIONS: Store away from excessive heat (e.g., steampipes, radiators), from sources of ignition, and from reactive materials. Do not store near food or feed. Corrosive to copper and brass on long storage. FOR INDUSTRIAL USE ONLY. STORAGE TEMPERATURE: MAXIMUM 35° C PLEASE READ TECHNICAL DATA SHEET BEFORE HANDLING THE PRODUCT. Ir**************************** SECTION X TOXICITY INFORMATION *********** IRRITATION: EYES - Severe SKIN - Severe and Sensitizer For Mercaptan terminated polymer: ORAL LD SO: >2,600 mg/Kg (rats) DERMAL LD 50: >10,200 mg/Kg (rabbit) Ir ********************************** SECTION XI MISCELLANEOUS INFORMATION ******************** NOTE TO PHYSICIAN: Allergic dermatitis or respiratory response in susceptible individuals may be delayed. It may appear after weeks or even months of frequent and prolonged contact. DOT/IATA SHIPPING/PACKAGING INFORMATION: DOT PROPER SHIPPING NAME: Not Restricted DOT HAZARD LABEL/CLASS: Not Regulated DOT/UN NUMBER: Not Available PACKAGING GROUP: Not Applicable RCRA STATUS: Not a hazardous waste under RCRA (40 CFR 261) CERCLA STATUS" Not listed SARA TITLE III - TOXIC CHEMICAL LIST: This product does not contains toxic chemicals subject to the routine annual "Toxic Chemical Release Notification" under Section 313 (40 CFR 372). TOXIC SUBSTANCE CONTROL ACT (TSCA): INVENTORY STATUS. Chemical components listed on TSCA inventory. PAGE ooso3 EPIBOND 1559 B PENNSYLVANIA RIGHT TO KNOW ACT: The following is required composition information. This product contains: (1) Mercaptan polymer (2) 2,4,6-Tri(dimethylaminomethyl) phenol (3) Ammonium polyphosphate (4) Organophilic clay CALIFORNIA SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT RULE 443.1: VOLATILE ORGANIC COMPOUNDS: This product contains 2* mg/liter volatile Organic Compounds. (VOC) * - Based on theoretical calculation ISSUE DATE: 08/03/92 REVISION: 02A SUPERSEDES DATE: 01/12/90 ISSUED BY: RAJESH S. PATEL FOR FURTHER INFORMATION, PLEASE CONTACT' PRODUCT SAFETY DIRECTOR. IMPORTANT MESSAGE!!! THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE THEREOF. CIBA-GEIGY CORPORATION ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY THE MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF THE MATERIAL. HAZARD STATEMENT!!! THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH FEDERAL OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200 THIS PRODUCT IS CONSIDERED TO BE A HAZARDOUS CHEMICAL UNDER THAT STANDARD PAGE LI5T OF CHEMICALS KNOWN TO THE STwTE OF CALIFORNIA TO C'^USE CANCER/ BIRTH DEFECTS/ OR OTHEtt REPRODUCTIVE ClBA-GEIGY PRODUCT ESTIMATED _ : __ CONCENTRA' CONTAINS CALIFORNIA PROPOSITION tS LISTED CHEMICAL DE3C* IN PRODUCT KRALDITE AW i06~8<?""8 OXIRANE/ (CHLOROW1£THYL)- H^RC-ENER HY CIBw-GEl'GY CDRPCRrtTICN PLASTIC5 DIVISION SCVEri SKYLINE DRIVEKHWTHORME/ NEW YORK ic I91fi 34-7-f>600 1J/C9/93 TAYLOR WADS GOLF COMPANY INC 23t71 COSMOS COURT P PCLTIN* Ai9-93i-i99i CA 920C? DEAR CUSTOMER MATERIAL SAFETY DHTA SHEETS (USDS) HRE ROUTIWEL!' SENT TO YOU WITH 'YOUR INITIAL PRODUCT ORDER. THESE MSDSS RELAY HEAL1|4-hAND SAFETY > SAFE HANDLINCs AND REGULMTORY INFORMATION f OR OUR PRODUCTS » DURING THE PttST FEW YEARS i SEVERAL FEDERAL ANO StA'tE RXaifr-TO-KNOU LAWS HHVE BEEN ENACTED* THE STATUS OF OUR PRODUCTS WITH RESPECT TO THESE LAWS IS DETAILED IN SECTION X OF TH£ friSDS* UNDER THE HEADING REGULATORY INFORMATION. THE HSOSS FOR THE FOLLOWING PRODUCTS «RE ENCLOSED WITH THIS LETTER HARDENER HY ?9f WE URGE YOU TO MAt E THE INFORMATION IM TJ-ESE MSDSS AVAILABLE TO YOUR COLLJEHGUES AND CUSTOMERS, AS NECESSARY HMD APPROPRIATE* YOUR CONTINUING BUSINESS IS SINCERELY APPRECZAIED. CORDIALLY* CIBA-GEIGY CORPORATION MIKE MUWSEuL MANAGERt SAFETY HEALTH AND ECOLOGY FORMULATED PRODUCTS ENCLOSURE,*, 01 3f 1*9*0 "'"/ft PLASTICS DIVISION CIBA-GEIGY CORPOftnTIQN SEVEN SKYLINE DRIVE HAWTHORNE* NEN YORK 1C":32 TELEPHONE DEAR CUSTOMER IN NOVEMBER. i?S-i. THE VOTERS OF C*J.IrQBNI^ FP.33EP F*OFQSI- TION £Ej OFFICIALLY CALIFORNIA HE sLTri HMD SnF-TY CODE SEC- TIONS $S2**45 £T SrIQ. THIS L»y REQUIRES THE GOVERNOR OF CwLIFORMIA TO FU3LISH tt LIST OF CHEMICALS 'KNOWN TO THE STATE ro CJAUS: CMNC£R OR REPRODUCTIVE TQXICITY-* » COPY OF THE: LIST Qvl oE OB f AINfc.D FROM FUE CHLIF3PNIA DEP *«lTi'«EMl OF HEttLTH SERVICES* PPOPOS1TIOM 6# R^-BLIFES Thnl H CLEwR AMD REriSOi4ABLE WARNING BE GIVkN TO pPPSONw IN CERTPlN SITUATIONS h|Q LHTEH THAN 12 HONTH5 AFTER :i CHEi^ICnL IS LI51ED* THE STriTE H«S NOT YET PROVIDED GUIDANCE CN HOW TO MEET THE WARNING RESUIR^i-OITS, IN ASSENCE OF THIS GUIDANCE THE FOLLOWING WARNING IS PRO- VIDED DETECTABLE tdlOiJNrs OF 30hS OHEMICsLa KNOWN TO THE ST^T'5: OF CALIFORNIA TO CAUSE C-.NCER/ SIRTH DEFECTS- OR OTHER PEisPO- DUCTIVE HARM MHi' B€ FOUND IN VttRIOUS ChEMICHL PRODUCTS AND TriEIR VAP.DRS« OR RESULT FRCH THEIR USE* ttNY I'NWN PISnS ASSOCIATED WITH CHE USE OF PRODUCTS SOLD BY CIBA-OEIGY CORP* ARE DESCRIBED ON THE PRODUCT'S HHTERlHL SwFETV DHTA SHEET tHSDS)* Pi^M^E *EMO THE ENTIRE MSDS BEFORE USING A PRODUCT AND ALWAYS OBSERVE THE RECOHMENDED PRECAUTIONARY MEASURES TO MINIMIZE EXPOSURE* PENALTIES CwN BE MS3E55ED hGMlNST ANY VIOLATORS t INCLUDING THOSE WHO DO NOT PROVIDE ADEQUATE VtaPNINGS. IT IS IMPORTANT THMT JMRNING ENFQPrt'-iTION BE PuSSED ALONG TO YOUR EMPLOYEES i CUSTOMERS AND OT;-Er\5 WHO MhY USE GUR PRODUCTS* WS W«NT TO ASSUFS l«OU THhT THE »4APJ<4!NG SET FOAFH hBCVE IS THE RESULT OF OUR CuWLlHNCE WITH PROPOSITIOf^l 6F AND DOES NOT REFLECT f«NY NEW SCIENTIFIC EVIDENCE CONCERNING THE LEVEL OF RISK LIl'-'ELi' TQ S* ENCOUNTERED WITH OUP PRODUCTS. ATTACHED IS INFCPHA1ION GIVEN IN COMPLIwNCS WITH PROPOSITION «E RELATIVE TQ V3UR RECENT PURCHASE OF OUR PRODUCTS« SINCEREL MIKE MUNSELL MHNAGERi SAFETY HEwLTH fnND ECOLOGY •i " — ?-•;.. ff.'' M A CTHA-ftETOY C FORMULATED SYSIErfS 'JF.OU'' 491? IMWN AVE EAST LANSING, MJ <517> 351-3900 00 " v DATA 3 H E T T LWDXGENCY i-'HONE <800) N J-3DEMT1TY JWORMATTON IDENTITY <FRAOFNArtE>; FORMER BES I RN A 1 1 ( IN& RP 136 RESIN PROJDOCTfPt EPOXY APHESIVF ^ THIS f«Vl&R'*f WILL NOT BE SOLH FOR USK. IN PRODUCTS * x TOR WHICH PRULONQfcD CONTACT WITH MUCOUS MEMBRANES • OR * >» APRAPED SKXW, OR lJ*«H.ANrAl ION WITHIN THE HUMAN BQfiY» IS * * SPECIF ICALI Y JCMT«iNDtD. BECAUSE OF THE WIDb. RAN6C OF ' » >5 SUCH POTENTIAL "?lr>%, C3 H^-Gfc'IGY CORPORATION IS NOT ABLE * « TO RECOMMEND FHTS MATERIAL. AS SAFE AND EFFECTIVE FOR * * SUCH IMPS P!«D *peu*i«:r NO LIABILITY FOR ANY SUCH USES* * HAZARD STATEMENT i M •»********•>< '*i<'»*»»->*«« »>*•»*»«•>*»»*«->»* * THIS MAI F RIAL SAFETY UATA SHtfel CM8D8) HAS BEEN * PREPARED IN COMPLIANCE Wl^i } "£ FETtERAL OSHA HAZARD w COMMUNIlMl TON ** r^NI'ARH 2V CFR J910»12OO» •X — THIS PROnUCf IS CQNSIDFREP TO PE A HAZARDOUS * CHEMICAL. UNriF_«< TH<*T STANDARD* SECT f 'VI INGRETJTENT8 ____ CHEMICAL NAME: CAPMJN BLACKCOMMON NAME ; CARBON &CAS NUMBER J ARALDI1E AU 336 F.AOE EXPOSURE Limit*. ACGIh ILV t 3,5 'it/MJ ftIR TWA O&HA FTL . Z»rr *<G, 13 AIR TWA CARCJWJFENIGIT?J TfHtS "AlEftliH. T? *G1 CONSiDFRETl TO BE <•* r-^-ciNOcsFM WY N^P, /ARC* OR OSHA*»t ** •» CHEMICAL WinE: 1.1T KJPO*|P. COMMON NAMF *, L\tHjK}N£ CAS NUMBER J OOlZ*'5-O>5-? EXPOSURE1 I ThUST yVCRXH Tl V « \0 *'&/M3 ^(K ?WA < fOTAL HUST> OCHA PEL I 113 MO/rtS AIK TWA 'TOTAL DUST). i% NOT CONSIDERED TO r<E BY H"»H» TARC» OR OSMA, * * «• CHLMXCAL NAME: OK*. VCIOYL. ETHER O^ BI5F1-ICNOL A COMMON NAME ; FF^i/Y t£iN NUMBER i 02GO-40-38-6 RIAL IS NOT CONSXTiEKED TO BE A CAKOIMOGEN BY NTP» IARC, OR OSHA* * * ¥• CHEMICAL NAri£i EJ*£Cw_ORr»<YDRlN, BISPHENOL A CDFOLYMER ADRUCT *Jl^H 'teOF'ENlYL GLYCOL« ADXPTC ACID COPOLYMER COMMON NAMF : POl YF«TCP MOOIFTED CF'OXY RE^IN CAS NUHWIR i 07046^-11-0 JHIS f^ATfc.PIftL IS NOT CONSItiERED TO BF * CARCINOGEN BY NT*", I ARC, OR OSHA* * ** # SECTION 11J -PHYSICAL F«ATA APPFARANCE AND UHGRi X=iLACK FLOWING Klf i €0 LIQLI[D, WITH MILD ODOR FOILING POINT*, NOT DETERMTNE71* EVAPORATION RATg: NOT DETERMINED, PFRCENT VOLATILF*. NEGLIGIBLE. VAPOR DENSITY: NOT OFTERMINED*VAPOR PRESSURE: e ssc »oo\ rthHo SOLUBILITY IN WAFER; NEGLTGIH F PHJNOT DETERMINED*SPECIFIC GRAVITY: I»4 <WATER » A> SECTION TV-FIRE <WD EXPLOSION HA7ARD DATA PLASH POINT; ARALDTTe AW 1?6 > six r . TTMTiS I.1" ^ r-- NGT L^TABLISHf />, F'l E 1.114718 JN AJP-'- NOT CSTABl ISH-IH, EXTINGUISHING MEDIA; CARBON rilOXiriE, D*Y CHfc^TCAL. FIRE FT GHT i NO f •Roc&.rxjKSs- SPF c, i AL : USE SELF-t,Of\' fATNen JPREATHIMG APPAF^TUG. UNUSUAi flRC AND feXPLn^/ON Hi&ZARJiSJ BrCOt'iPO<57 riUN rV«« COHBUS1JON PRUnUClG MAY BC fOXTC* SECTION V-PCACTIVITY HATA STABILITY:STABI..E,CONDITIONS TO AV03DJ FXCCBStVF HCAT FOR e-mOLONGt.D PhRIODS OF STRONG nXIDVZfc"RS, ^C\l«<5 AND BASE&, HAZAFs'DOUS DFCOMPOSH TON f-'RODUCISi COMBUSTION MAY f-Wrf TOXIC fSAT&RTALS, BUCH AS CARBON DIOXIDE, CARPON WILL K'Ot OCCUR. SPG1TON VI-HEALTH HAZARD DATA PRIhARY ROUTES OF E> 1NHALAXLF. VAPORS* I TMIT ^AL U^ J HONF tSTAPLlfJHfcf» ^'Hp TM/S P'KOLiUCT . i?EE THF HAZARDOUS INGRE- SKIN IRRITANT » EYE IKK I TAT TON*IRRITANT*SCNSITTZATTON: POS31BIF £N TrsT RF«U> TS FL,R niBLYcynYL E.THFR OF BTSPHENOL HO AWERtfF FF-t-LCTS ON FhfcKYONIC OK FtTAL '-RATS, RABBITS) 1ur>T KESUL fS FUK fTGLYClDY' ET-Jtr OF K1SFHFNOL AJ AMFS TEST 7 BOTH FOSITIW. ANH NE15ATIVE RESULTS HAHSTER PfjfJF M*PF:Ow CYTD^EiNFTICB < IN VIVO) J NEGAtlVE rtOUBF «P£..^nft-» "CW£? CvIOWtNrT/C& <IN VTVO) : NEGATIVE MicROrtuaeus TEST an vivo\ : NEGATIVE MObSE /iOMJr(A^T ' ETH^L TfcbT : NEGATIVE HLKYLATJOr* Or UNA i POSITIVE HUMAN i-iONONl^' C/ITB-H WBC <TN VIVO) t NEGATIVE HOST MFniftFEU ABSAY : NEGATIVE AFALJiTTL AU !:•< f ftGC CUBCriRDN-i.tr OFfU. fFtP.'*"* ?V"L' Ef : TrST RESULTS POft /«r«L YCIl'YL t™h<» OF BISPHENQL AS W3 OBSFKVrtflLlr *t«-CT <if HIGHEST Lf-.VEL STUDIED <IOOO MG/K8'7iflY FOK 2S DAY'S - «\A1S> OVEREXPOSlJPfc EFFE C TS t SKIN AND FYe. TRRJCTATfON A*D ftl L«lRf3rC SKIN REAC1TONS* OVEREXPOSURE-CHRUWIC t TEST RESULTS FOR f'ltf VCIDYL ETHER OF BISI'HFNOL Al 2-YFAR DERf'iAi. ^TMI'V TH ^.ICCJ "tt TIv'EATMCNT RELATED EFFECTS ?-YEAR SMN PAI^TIMO STUDIED! A> G3HF/BD rtt^E 5 H'J INCREASED 1UMOK INCIDENCE B> Cn^PL/-SBf« MICE: SLIUH1 INCREASE IN EPIDERMAL LOCALIZED CARCINOMAS AT HIGH DOSE C> C3H Mice t NO TUMOR55 KICE RtCETVINl) &KTN «PM.ICATIONS OF HXGLYCIHYL ETHER OF BISPHPNOL A OR E8SCN11MLY TDETNT1CAL K'ESINS FOR TWO YEARS HAVE YXELJIEO VERY LIMITED EVIDENCE OF WEAK CARCINOGEHICITY* THE nnUJGHFD REPORT ON T!ty& STUHY CONCLUDtS THAT THIS RESINPAonJcr "is NOT A ^YSTF.«.IC CAKCINOBEN WHEN APPLIED TO THE SKIN OF CFl MICE" *Wfi THE TUhOR PATA "WAS OF NO BIOLOGICAL IMPORTANCE",* BAStii ON ALL AVA1LAPLL DATA, IARC <INTERNA- TIONAL AGENCY FOR rfPEAFECM ON CANCER) HAS CONCLUDED IN 198B THAT DOT&PA IS NOT C'.^S&JFIED AS A CARCTNO&LN. MEDICAL CQHDXT70NS AC33RAVATEH BY EXPOSURE: SKIN AND FYfe- COKU1 TI'^NS, EMERGFrJCY AND J-JRST AIC' fROCETJURES-EYES J IMMEMATELY FLUSH Cvcg WITH WATER FOR AT LFAST 15 MINUTES* CALL A PHYSICIAN, rMSKGENCY AND FIRST *l»j »ROC^UURES-SKINt WA3H W/TH SOAP ANH UA1ER. REHQVt. CONTAMINATED CLOTHING AND LAUNDER BFFiJKE ftF-«JSfc~, CMERGTNCY AND FIRST 41U ^ROCSDUKhS -INGES)ION: IF CONSCIOUS, C3IV&. M.EN1Y OF WATER TO DRINK* DO ^NOT INDUC? WJHITXW* CALL A PHVSICTAN* TrfEkGENCY AND FIRST *TP tlf=tOCEDURES-lNHALATTON: RTHOVF TO FRFSH ATft* GWE OXYGEN AND/OR ARTIFICIAL F<EBPTRAT\ON, IF istFEIFli. CALL A PHYSICIAN* EMERGENCY AND FIRST -UH PROCEDURES-OTHER * F(EFFKF\AL TO A PhY«*!S:Wl IS F.£t:OMMfcNDFD IF THEKL IS ANY OU~STTON ABOUT THE S?RlUUSNGt>S OT ANY INJURY. {?^l VH-SPTLL OR LKAK PROCEDURES SPILL R£J>1OVE Sr ILl.r»l?F P* fti'S'jr'BING !»%« AbSOf\HENT MATERIAL« UASTF DTSFOSAJ MiLlHOGSt CONSU T OUALTFIFJt L<-«C/»'. fj* COlVORAfE PERSONNEL FOR METHOD THAT WILI CuMP' Y W1T^» I OCAL, PTATE AND TLDERAL HEALTH AND FHVTROMMENTrtL KfG'" A* 10MS. SECTION VIII-b°E'3JAL PROTECTION INFORMATION VENTiLrtTTON: ARAuUXfc AU 3A« •-- - ;.!*• .••>:•• I':,-1 ^*-U L'JL'M- £<*"--<4U«l IN ACCORUANCE WITH AC&TH WEnR TNFFF.ltEftH t r-L'.'V- '- . £Y£ PROTFHTIONt WEAR SPLASH-PROOF f"E*'lrML &' 'Gf~L<=-<3 » RESPIRATORY PRO ! ECT '< (~*> i JSF NIUSH AfPROvei' «'*hlj''^ir, '."M-'OP CAKfRIDGE RESPTRATOR WICM VAF OR/MIS f EXF nBVPf IS i.INELV, r Rfr TAUT !!ON.9 HANltLXNG* SH7FFXNJ.7 ANf STORING PR£CHU! TONSt ^AfiNJHG CAUSED ?fc IN ANI? EYF XKRITATION* MAY CAUS-: -*»f. LERGIC SKIN REACTION. AVOID CONT»C1 WITH £VES» SKIN, AND CLOTHING* AVOiTi PRGL(^»CED OR R«>EATF» CONTACT WITH SKIN* WASH THOROUGH-v *FTT.K HANT<LTNO. HANULING PRECAUTIONS? NUIBANCE DUS1 ttftY i#£ 'sOSL^A^FU WHCN SANUTNG Ok SAWING MATbR/AI , REGULATORY INFORMATION DOT J-RQTER SHIPPINGLIQUID PLASTIC, N.O,I,DOT CLASS: NOT RFGU1 ATtfD*RCRA STATUS: NOT A HAZARfiOUa W*s»F(P «JNW5R WRA (40 O-R 261 >. SARA/TITLF Til - TOXIC CHEMICALS J.ISFJ THIS PROWJCT IS <C« <-ONfAIl«lfe) A TOXIC CHLMICAL FOR ROUTINE ANNUAL "TOXIC CHEWXCAL RELEASE Rfc'PORTTNG" UNDER SFC, 3S3 <4O CFR 37?;, 21 » 2300% ZINC COMPOUND. THIS INFORMATION rfUSl PF. THCLLU'ED IN ALL MSDS'S THAT ARE COPICD ANP OISTRXfilJTFD FOR THIS TSCA INVENTORY CHTMICAL COhPONfNTS LlSFfc'D ON TSCA INVENTORY. PLNNSYLVANTA RIGHf-TO-KNOW ACTt THE FOLLOWING li? REDUX RED COhPOSTT>ON INFORMATION CHEMICAL I4AMB CAR NUMBER COMMON NAME COMMENTS CHEMICAI NAht- CAS HUMPFR COMMENTS CAR9QM BLACK 1333-86-1 CrtPBON SLACK HAZARDOUS SUHSTANCE . *• * »"ITE 5 t *W J RONMEN f AL w AZAPD * ARALUlfE AW 176 PAGC ' X * *Kiinf J PH^/PL , f,/i»-< f-MErHYLETltYLI)iENE>BTS- , POLYM CAS NUMBER T COiMHON NAMb , j£t«iy* «<mEN COMMENTS I NOT- OP P«=>iNSYL VA»«TA HAZARDOUS SUBSTANCE LIST* OOnCAL NAMF I HKX^NtDJOIC '-^CCD, ^OLYMEK WITH <CHLOROMETHYL ;t/yTf\*ir, ?,2-D3MCrHYL-t,:j-PROPANEDIOL AND 4 / « ' -' J -M&.TMYL FTHVLinENF )HIS PHENOL CAS HUMBFR 5 ^4dP-i2-0 COMMENTS I HOT t»l PtNNST1 '.'Ar'Tj* HAZARDOUS SUPSTANCf LIST* issur HATE; oa/iA/d* AFVCSTON: o^c ispueti BY: ptrtR HENIGE FOK F-JkTiJrR IWOMV*1IU*'/ fLE'-SE CONTACT J fROWJCT SAFETY DIR THE CNTORMA1TOM fthB RFCf)WE*iOAT;ONS CONTAINL.H HER£IN ARE BASCO UPON DATA BKLieV=D TO E'F CORRECT, HOWrVLR* NO OUARANTEE" OR WAr%RAN1Y OF ANY KTW. ^X^ReSStT' O6? !*F'LT£r« IS MADF WITH RC&FEC") TO THE INFORMATION COMrAINlTD HEREIN* ARALD) IF AW JL3A MrifERIt,L I ! CIBA-GEIGY i:Q I FORMULATED SYS rE."«S OPOUP I «f917 D*4WN rt'/E 1 EAST LriNSZNG* J-l 'l- I (517* SSl-EVOO I ^ _ F C T Y DATA SHEET 1 i EMERGENCY FHQME NUMBER I i (800) SSQ-B372 \ \ T-JDENTITY ZNFGRfttl ION IDENTITY HARDENER HY FORMER DESIGNATIONSH 9?f HARDENER AMINE EFOXY IMPORTANT **#»**#^*^#)tK***»^^*3t-«*^^##^* # TH£S rtATERIAL WILL NOT BE SOLD FOR US£ IN PRODUCTS # FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBPHNSS OR # ABR«tDEO SKIN/ OR IMPLwNTATION WITHIN THE J-JUM^N BODY* f5 # SPECIFICALLY INfENDED* BECAUSE OF THE WIDE RANGE OF K SUCH POTE.4TIAL USES; CIBA-GEIGY CORFORrtTION IS NOT .ABLE # TO RECOrfM^ND THIS MATERInL AS ShFE AND EFFECTIVE FOR » SUCH U5£5 AND ASSUMES NO LIABILITY FOR «NY SUCH USES. *###$**4*«###*****tt**##*#**## HAZARD STATEiOENT * THIS i^HTEPtli^L SAFETY DATA SHEET (MSDSJ H«S &BEN * PREPARfcB IN COMPLIANCE WITH THE FEDERf4L OSHA HA2ARC« * COMMUNICATION STANDARD 29 CFR 191O*120O. * THIS PRODUCT IS CONSIDERED TO BE A HAZARDOUS * Ch£MZCl4. UNDER THAT STi-iNDARD, ----- ------ # # SECTION IX-H»4ZHRDOUS INGREDIENTS CHEMICAL COMMON N«i'E CAS NU.1BEA i» 3-PPOPANEDIAMINE* NiN-DIMETHYL DZMETHYLAMINOPROPYLAIIINE <X»109-FE1-7 hY EXTINGUISHING M-£DIA CARSON DIOXIDE* DRY O£""»1G4.* FO^M* UATER. FIRE FIGHTING PROCEDURES-SPECIAL USE SELF-CONTMINED BREwTHIftG wPPwR^TUS* UNUSUAL FIFE AND EXPLOSION HAZARDS- DECOMPOSITION <«ND COMBUSTION PRODUCTS rfnY 3E TOXIC* SECTION V-REACTIVITY DATA , STABILITY STABLE, CONDITIONS TO EXCESSIVE HEAT FOP PROLONGED PERIODS CF INCOMPATIBILITY STRONG OXIDISING hOENTSi hCIDSi MET^L~ORG'-.NIi- COHPOUNDS. HAZfWOOUS DECOMPOSITION PRODUCTS I'OHBUSTZON IfeY FORM TOXIC MrtTERZhLSi SUCH MS Cn^BCM DIOXIDE^ CAPBON WONQXEDE, HAZjiRLOUS POl.YM.'-:RIZ^^TIO^i WILL NOT OCOF* SECTION VZ-HCuLTH HwI^RD D1TA u PRIMARY ROUTES OF EXPOSURE KJU44L.J H'ATID PRODUCT Mtt'i PRODUCE INHttLHBLE VttPORS. THRESHOLI« LIrtIT VVLUE NONE ESTA3LZSH-:0 FOR THIS FPODUCF* SEE TIE HAZARDOUS INGRE- DIENTS 5E-7TION* SKIN IRRITATION CORROSIVE, CAUSES BURNS* EYE IRRITATION CORROSIVE* CAUSES BURNS* SENSITIZATION POSSIBI^ IN 5USCEPTIBLE INDZVZDUAL.S. OVEREXPQ5URE-HCUTE O^iNGER CDFP05IVC* C«USES 5* IN AND EYE BURNS* OVEREXPOSURE EFFECTS DANGER CORROSIVE* CAUSES SrIN AND EYE BURNS. C«USE5 ALLERGIC SKIN MND RESPIPHTORY REACTIONS* MEDICAL CONDETIONS AGGRAVATED BY EXPOSURE SKIN AND 6YE CONDITIONS* EMERGENCY ANO FIRST AID PROCEDURES-EYES IMMEDIATELY FLUSH ET.'ES WITH WATER FOR «T LEAST IS MINUTE'S* CALL A PHYSICIAN* EMERGB4Ci' ANO FIRST AID PROCEDURES-SKIN WASH WITH SOAP AND WATER* REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EMERGENCY «NO FIRST AID PRQCEDURE5-INGE5TIGN JF CONSCIOUSj GIVE PLENTY OF W«TER TO DRINK * DO NOT INDUCE VOMITING4 CttLL A PHYSICIAN. EMERGENCY AND FIRST AID PROCEDURES-INHALATION , REMOVE TO FP-ESH AIR* GIVE OXYGEN AND/OR ARTIFICIAL RESPIRATION. Ii- NEeDED. CwLL A PHYSICIAN* HY 59S- 7fT'TiV EMERGENCY *NO FIRST 'iID PPOCESMJPE5-GTHE* REFERRAL fO 3 PHYSTCInN 15 RECOMMENDED IF THERE IS QUESTION '.BOUT THE SERIOUSNESS OF ANY INJURY* .- SECTION VXI-SPILL GR LEHh PROCEDURE'S SPIiJL PROCEDURE'S REMOVE SPLLLMOiE 3Y ABSORBING IW ABSORBENT MATERIAL* AVOID CDNTHCT* WASTE DISPOSAL METHODS «:ONSULT QUALIFIED LCG-iL OP COP-POP-ATE PERSONNEL FOP METHOD THAT WILL COrtPLY WITH LOCAL/ STATE HMD FEDERAL HEALTH AND ENVIRONMENTAL R£GU_»4TICNS. 'sECTIud VIXI-SPECIO. PPOTECTION XNFOPMATIQN VENTILATION GENERAL M-:CF iNIC^L f-.ND LOC-sL EXHwUST IN «CCCBDMNCE WITH J¥:SIH P£coMM£^lCi<H ri DNS * PROTECTIVE GLOVES Ii'TEPJIEwBlE 3LGVES hND FROlECflVE CLOTHING, £*•'£ PROTECTIiDN JfULL FuCE SHIELD* RESPlRftTORY ^POrECTIOW USE Nlbs'H wPPPOVED ORC-ANIC VAPOR CARTRIDGE RESP EPr^TC«R WHEN V-nPCA/JILSr EXP02LIPE IS LIKEuY* .>_ 'SECTION IX-EPECInL PRECAUTIONS _.. HMXS C0t>£ HEwLTH 3 PIPE 2 R^iCTIVITY • HANDLING* SHEPPir^ AND STORING PRECAUTIONS DANGER COMBUSTIBLE. CORROSIVE - CAUSES SKIN AND EYE BURNS4 M«Y CAUSE ALLERGIC SKIN AMP RE5PIRHTORY REACTION* P£EP HWAY FROM HEAT AND FLAME* DO NOT G£T IN EYE!* ON SKIM; ON CLOTHING* AVOID BREATHING V«*POR OR MCST* KEEP CONTAINER CLOSED* USE WITH ADE9UHTE VQilTlLATION* WASH THOROUGHLY wFTER HAILING* HANDLING PRECAUTIONS NUISANCE DUST MuY BE GENERATED WHEN SANDING OR SttWING CURED MATERIHL. SECTION X- REGULATORY INFORttwTION DOT PROPER SHIPPING NAME PQLYALKYL»4MXNJESf N*O.S*j CORROSIVE* CLASS 333 UN 273'4 PG XX KCORROSIVS HMD FLHMM^BLE LIQUID* DOT TECHNICAL SHIPPING NAME(S) CONTAINS HHADENER HY 994- PACE OO5O& * DIMETHYLf«iINOFPCP Y DOT CLASS CORROSIVE l^TE RCPA STATUS D 001 IGNTTH'iUr* SARA/TITLE III - TQXIC C;-»EHICi-i.S LIST- THIS PRODUCT DQ*$ MOT CONTAIN A TOXIC IHErilC-tL ,-OP. RCUTIiME HHNUri. 'TOXi: Q-EhlCwL RELEASE REPOfsTImG' UNDER SEC* 313 CH> CFft 372) * TSCA INVEMTO:iY STATUS CHEMICAL CQf^ONSMTS LISTED ON TSCw IMVIENTOR i'* PENNS'A-VANIA RI3H^^Q-FNOW H»1'T THE FOLLO^IKS IS PESUIRLD COMPOSITION INFORMATION - CHEMICAL WhHS 1 , 3 -PF GFuMEDIwhirtE ; N • N ' -DIMETHYL- CQMWDW NAilE DIMETHYLAMIWOPPOPYLHtllNE CAS NUMBER OOC109--Er-7 COMMENTS h'PZwFDOUS SUBSTANCE ft •* -t CHEHIC'iL NAtt^ i^l-ETHhNEEiIAMINE- N-N'-BIS'l-friMINOETHYL) - COMMON N^ilE TPISIHYLENE TETRAMINE CAS NUMBER ' 0<J0112-;'-f-3 ttMMENTS KPZs-RDOUS SUBSTANCE ¥• « * •:H£MICAL 54<-ih?: ^TTY HCTDSi C18-UN£f4TD. * DIMf.RS; REACTIUW PRODUCTS WI^H POLVETHYLENEPOt-YHMlNES rOMMCN NAME POLYETHYLENE AMIDO AMINES C«S NUJ1BER 068^10-23-1 COI1MET-4T5 wOT ON PENNSYLV^NlH HwZARDCUS SUSST^-NCE LC3T DMTE OS/27/9.3 REVISION OSC ISSUED 3Y M MUN^ELL FOR FLIRTS ER INTQRrfriTIONf FLEwSE CONTACT PRODUCT SAFETY DIR THE ItOFORMATION f-iND ReCOS-JMENDAriONS CONTAINED HEREIN ARE B3SED UPOfJ DATA BoLIEVED TO BE COPAECT* 'HOU!EV£Rj NO GUARANTEE OR WARRANTY OF hNY \ IMP £><PR£SSED OR IMPLIED IS M'-iDE WITH RESPECT TO THE INFORrtriTION CONTAINET* HEREIN* HARC*Er»IER HY 99H- 25-34-1SS3 07 47 P ES MATERIAL SAFETV DATA SHEI-T FQLYMtR DEVELOPMENT LASCF.A TORIES, INC. -12 W. TAFT AVENUE s* $-^£ — ORANGE, CALIFORNIA 92£*5 /"^1" • n*?-<J>°i ISSUE DATE, i11 REVISION DATE:1/15/93 CDDEs F (714) 921-2300 FAX <714) 921-^643 MIKE J4CM&EON V P. OPERATIONS POLYMER DEVELOPMENT LAB PIC, spoke with 12/9" 1. ^F-'ODUCT IDENTIFICATION - "A1 COMPONENT - POLYMERIC ISOCYANATE PRODUCT NAME .......... : poL 729-3M PRODUCT CODE NUMBER. . . : CHEMICAL FAMILY ....... i POLYMERIC ISOCYANATE CHEMICAL NAME ......... » POLYMERIC DIPHENYLMETHANE 4,4 DIISOCYANAT5 SYNONYMS .............. MDI, ISO, "A" COMPONENT CAS NUMBER ............ i SEE BEuOW TSCA STATUS ........... : ON INVENTCPY II. HAZARDOUS INGREDIENTS COMPONENTS « APPROX 7. CURRENT TLV/PEL **«****4«*******#*******««4*#*4«*****************4^ 4,4-DIPHENYLMETHANE DIISOCYANATE CAStt 101-68-3 35-45 .02 PPM PHENYL ISCCYANATE CAS# 103-71-= HIGHER OLIGOMERS OF MDI CA<3# 9016-S7-9 1 TRACE N.E. N.E. «*:NGREDIENTS NOT PRECISELY IDENTIFIED ARE NOT HAZARDOUS** III. PHYSICAL DATA APPEARANCE S VISCOUS LIQUIDCOLOR I LIGHT TO DARK BROWNODOR : SLIGHTLY AROMATIC OR MUSTYMOLECULAR WT N/A MELT POINT/FREEZE POINT.. BOILING POINT VAPOR PRESSURE VAPOR DENSITY <AIR - !>.. SPECIFIC GRAVITY SOLUBILITY IN WATER BELOW 60 F. DECOMPOSES AT &4i F (341 C> AT 25 C « 1 XI0-3 9.6 1.2 REACTS VOC X : 0 OQ6Q3 MATERIAL SAFETY DATA SHEET (CODE F CONT'D; IV. FIRE S< EXPLOSION DATA FLASH POINT- 425 F. (213 C.) CDC FLAMMAfaLE LIMITS IN AIR BY VOLUME - LOWER N.E 'NONVOLATILE FLUID; UPPER- N.E (NONVOLATILE FLUID) EXTINGUISHING MfcDIA: DRY CHEMICAL EXTINGUISHERS SUCH AS MO^QANMONIUM PHOSPHATE, POTASSIUM SULFATE, POTASSIUM CHLORIDE. ADDITIONALLY, CARBC DIOXIDE, HIGH EXPANSION (PRQ7E2NIO CHEMICAL FOAM, WATER SPRAY FOR LAFG- FIRES. SPECIAL FIRE FIGHTING PROCEDURES' IF WATER IS USED, USE LARGE AMOUNTS AS Tr-E REACTION BETWEEN HOT ISOCYANTES AND WATER CAN BE VIGOROUS. USE SELF-CONTAINED BREATHING APPARATUS AND BODY COVERING PROTECTIVE CLOTHING. UNUSUAL FIRE AND EXPLOSION HAZARDS: WATER CONTAMINATION WILL PRODUCE CARSON DIOXIDE. DO NOT RE-SEAL CONTAMINATED CONTAINERS AS PRESSURE BUILDUP MAY RUPTURE THEM. V. HEALTH EFFECTS DATA ANIMAL TOXICITY - ORAL, LDSO<INGEST!ON) : >20B/KB <RATS> DERMAL, LD50 <SKIN CONTACT) . I MS. 8 G/KG (RABBITS) INHALATION, LC5CX4HR.) « APPROX. 370 MS/CUBIC METER (RATS) AQUATIC, LC3CK24 HR. ) : ,'500 MG/L (DAPNEA, LIMNEA INVERTEBRATES AND ZEBRA FISH) EYES : NOT IRRITATING (RABBITS) OECD GUIDELINES SKIN ...i SLIGHT IRRITATION (RABBITS) OECD GUIDELINES AND SENSITIZES IN GUINEA PIGS. OTHER I NO CONCLUSIVE EVIDENCE HAS BEEN DEVELOPED TO INDICATE THAT MDI IS A CARCINOGENIC, TERATCNGENIC, OR THAT IT CAUSES REPRODUCTIVE EFFECTS IN ANIMALS AND HUMANS. HOWEVER, MDI HAS BEEN REPORTED BY NIOSH TO BE MUTAGENIC TO SALMONELLA TYPHIMURIUM BACTERIA. THERE IS NOT FULL AGREEMENT IN THE SCIENTIFIC COMMUNITY AS TO THE SAFETY OF HUMAN CANCER RISKS. HUMAN EFFECTS OF DVEREXPOSURE - INHALATION: MAY CAUSE RESPIRATORY SENSITIZATION IN SUSCEPTIBLE INDIVIDUALS. AT ROOM TEMERATURE, VAPORS ARE MINIMAL DUE TO LOW VAPOR PRESSURE. IF HEATED OR SPRAYED AS AN AEROSOL, EXCESSIVE CONCENTRATIONS ARE ATTAINABLE THAT CCUL BE HAZARDOUS ON SINGLE EXPOSURE. EXCESSIVE EXPOSURE MAY CAUSE IRRITATION OF THE EYE3, UPPER RESPIRATORY TRACT AND LUNGS. EFFECTS MAY BE DELAYED, DECREASED VENTILATORY CAPACITY HAS BEEN ASSSOCIATED WITH EXPOSURE TO SIMIL« ISOCYANATES; IT IS POSSIBLE THAT EXPOSURE TO MDI MAY CAUSE IMPAIRMENT OF LUNG FUNCTION. SKIN: MAY CAUSE ALLERGIC SKIN REACTION IN SUSCEPTIBLE INDIVIDUALS. PROLONGEr OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION. MAY STAIN THE SKIN. OO&O3 MATERIAL SAFETY DATA SHEET <COD£ r CONT'D; INGESTION: THIS IS NOT CONSIDERED A COMMON OCCUPATION ROUTE OF EXPOSURE, AND SINGLE DOSE TOXICITY IS LOW. THRESHOLD LIMIT VALUE (ACBIH) : TLV IS >J< )5 PPM TWA. PREMISSIELE EXPOSURE LIMIT <OSHA> . PEL IS . "12 PPM- VI. EMERGENCE S, FIRST AID PROCEDURES EYE CONTACT. FLUSH WITH CLEAN, LUKE WARM WATER AT LOW PRESSURE FOR AT LEAS" 15 MINUTES, OCCASIONALLY LIFTING E/ELIDS. CONSULT A PHYSICIAN IMMEDIATELY. SKIN CONTACT! REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH WARM SOAPY WATER THOROUGHLY. CONTAMINATED CLOTHING SHOULD BE PROPERLY LAUNDE^E BEFORE REUSING. INHALATION: REMOVE VICTIM FROM AREA OF EXPOSURE TO SAFE AREA. IF NOT BREATHING, GIVE MOUTH TO MOUTH RESUSCITATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CONSULT A PHYSICIAN IMMEDIATELY. INGE3TION: NO ADVERSE EFFECTS ANTICIPATED BY THIS ROUTE OF EXPOSURE INCIDENTAL TO PROPER INDUSTRIAL HANDLING. NOTE TO PHYSICIANt NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT BASED ON JUDGEMENT OF PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT. THE MANIFESTATIONS OF RESPIRATORY SYMPTOMS, INCLUDING PULMONARY EDEMA, RESULTING PROM- ACUTE EXPOSURE, MAY BE DELAYED. MAY CAUSE RESPIRATORY SENSITIZATION. VII. EMPLOYEE PROTECTION RECOMMENDATIONS EYE PROTECTION: LIQUID CHEMICAL GOGGLES OR FULL FACE SHIELD. NO CONTAC" LENSE3 SHOULD BE WORN. SKIN PROTECTIONi CHEMICAL RESISTANT GLOVES SUCH AS NATURAL RUBBER, OF PQLYVINYL ALCOHOL. COVER AS MUCH EXPOSED SKIN AS POSSIBLE WITH APPROPRIATE CLOTHING. IF SKIN CREAMS ARE USED, KEEP THE AREA COVERED SY THE CREAM TO e. MINIMUM. RESPIRATORY PROTECTION : THIS PRODUCT HAS DEMONSTRATED NO OBSERVABLE EFFECTS AT ROOM TEMPERATURE, HOWEVER, ATMOSPHERIC LEVELS SHOULD BE MAINTAINED. IN ADDITION, IN ANY SPRA/ APPLICATION OR SITUATION WHERE AIRBORNE PARTICULATES OR AEROSOL ARE GENERATED, A SUPPLIED AIR SOURCE MUST BE PROVIDED. VENTILATIONS NATURAL OR MECHANICAL. LOCAL EXHAUST WILL KEEP THE TLV BELC. MINIMUM IN MOST CASES. SPILLS OR OTHER EMERGENCIES MAY REQUIRE MORE FORCEF VENTILATION MEANS. OTHERi SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE PROVIDED IN ALL WOR AREAS. ALL EMPOLYEE3 SHOULD BE PROPERLY TRAINED. O 05-34-1SS3 07 43 P 3S OO6O3 MATERIAL SAFETY DATA SHEET (CODE r CONT D> VIII. REACTIVITY DATA STABILITY. STABLE. UNDER RECOMMENDED STORAGE CONDITIONS. POLYMERIZATION: MAY OCCUR WITH INCOMPATIBLE REACTANTS, ESPECIALLY STRONG BASES, WATER OR TEMPERATURES QVEIR 347 F (175 C. ). TEMPERATURES OVER HO F '49 C. > ACCELERATE THE REACTION WITH WATEr. INCOMPATIBILITY (MATERIALS TO AVOID)! WATLR. ACID, BASES, METAL COMPOUNDS AND SURFACE ACTIVE MATERIALS. AVOID WATrR AS IT REACTS TO FORM HEAT, C02 ANI INSOLUBLE UREA. THE COMBINED EFFECT OF THE CO2 AND HEAT CAN PRODUCE ENOUGH PRESSURE TO RUPTURE A CLOSED CONTAINER. SOME REACTIONS ARE VIOLENT IN THE PRESENCE OF THE ABQVED MENTIONED MATERIALS. HAZARDOUS DECOMPOSITION PRODUCTS: I50CYANATE VAPOR AND MIST, CARBON DIOXIDE, CARBON MONOXIDE, NITROGEN OXIDES AND TRACES OF HYDROGEN CYANIDE. IX. SPILL OR LEAK PROCEDURES STEPS TO BE TAkEN IN CASE MATERIAL IS SPILLED OR RELEASED - MINOR SPILLS: CONTAIN THE SPILLCD MATERIAL AND THEN COVER WITH A LOOSE, ABSORBANT MATERIAL SUCH AS OILDRY, VERMICULITE, SAWDUST OR FULLER'S EARTH. SHOVEL WASTE MATERIAL INTO PROPER WASTE CONTAINERS. DO NOT MAKE PRESSURE TISHT. TRANSPORT TO A WELL-VENTILATED AREA AND TREAT WITH A NEUTRALIZING SOLUTION CONSISTING OF A MIXTURE OF WATER AND 3-9'/. CONCENTRATED AMMONIUM HYDROXIDE OR 5-10'/. SODIUM CARBONATE. ADD ABOUT 10 PARTS OF NEUTRALIZES PER PART OF ISGCYANATE WITH MIXING. ALLd TO STAND 48 HOURS LETTING EVOLVED CD2 ESCAPE. MAJOR SPILLS: CALL PDL IMMEDIATELY (714> 921-2300. IF IT IS A TRANSPORTATION SPILL NOTIFY CHEMTREC (3OQ) 424-9300. EVACUATE AND VENTILAT SPILL AREA. DIKE SPILL TO PREVENT ENTRY INTO THE ENVIROMENT. WEAR FULL PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROTECTION DURING CLEAN UP. IF TEMPORARY CONTROL CF ISOCYANATE VAPOR 13 REQUIRED , A BLANKET Or PROTEIN FOAM MAY BE PLACED OVER THE SPILL. LARGE QUANTITIES MAY BE PUMPED INTO CLOSED BUT NOT SEALED CONTAINERS FOR DISPOSAL. CLEAN UP: DECONTAMINATE AREA USING WATER/AMMONIA SOLUTION WITH 1-2V. ADDED DETERGENT, LETTING IT STAND OVER AFFECTED AREA FOR AT LEAST 10 MINUTES. COVER MOPS, BROOMS, ETC USED FOR THIS WITH PLASTIC AND DISPOSE OF PROPERLY (OFTEN bY INCINERATION), WASTE DISPOSAL METHODS: WASTE MATERIAL MAY 3E INCINERATED AT PROPS* FACILITIES OR DISPOSED OF UNDER LOCAL, STATE AND FEDERAL REGULATIONS CONTROLLING ENVIROMENTAL PROTECTION. p 10 OO&Q3 MATERIAL SAFETY DATA SHEET <CDDE F CDNT'D) Y. SPECIAL PRECAUTIONS l« STORAGE DATA STORAGE TEMPERATURE (MIN/MAX): 63 F. (19 C. ) TQ ^IS F. C14 C.> AVERAGE SHELF LIFE: 6 MONTHS FROM DATE OF MFG. SPECIAL SENSITIViTY (HEAT, LIGHT, MOISTURE;: THIS PRODUCT is REACTIVE WITH WATER. CONTAINERS SHOULD BE TIGHTLV SEALED TO PREVENT MOISTURE CONTAMINATION. A NITROGEN BLANKET SHOULD SE USED FQR Bu, j, STORAGE. STORE AT A TEMPERATURE OF 65 F TO 75 F, PROTECT FPOM FREEZING. PRECAUTIONS IN HANDLING AND STORAGE. IF CONTAMINATION OF THE MDI IS SUSPECTED, DO NOT RE-SEAL CONTAINER BECAUSE OF POSSIBLE RUPTURE DUE TO PRESSURE BUILDUP. ALWAYS SLOWLY VENT CONTAIN WHEN OPENING TO RELIEVE ANY PRESSURE BUILDUP, XI. SHIPPING DATA TECHNICAL SHIPPING NAME....: 4,4 - DIPHENYL METHANE DIISOCYANATE DOT HAZARD CLASSIFICATION. . I NMFC 60uOO(POLYMERIC ISQCYANATE'' FREIGHT CLASS (BULK) : NMFC 60000<POLYMER1C ISOCYANATE), CLASS 55 UN NUMBER : UN 2*89 PRODUCT LABEL : "A" COMPONENT - ISOCYANATE PLACARDS RECUIRED l NONE FOR DOT - IATA NEEDS ST. ANDREWS CROSS HMISs F-l, H-3, R-0 FOR FURTHER INFORMATION, CONTACT EZZAT SEIF, VP TECHNICAL. THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT THAT IT IS ACCURATE TO THE BEST KNOWLEDGE OF POLYMER DEVELOPMENT LABORATORIES, INC.. THE DATA ON THESE SHEETS RFLATE ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. POLYMER DEVELOPMENT LABORATORIES, INC. ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THESE DATA. 05-34-1393 07 44 P 32 MATERIAL SAFETY DATA SHEET POLYMER DEVELOPMENT LABORATORIES, INC. 212 W.TAFT AVENUE ORANGE, CALIFORNIA e>2 (714) «21-2300 FAX (714) 921-9643 ISSUE DATE: REVISION DATE*1/15/93 CODE: C I. PRODUCT IDENTIFICATION - "B" COMPONENT PRODUCT NAME : PDL 729-3M PRODUCT CODE NUMBER...! CHEMICAL FAMILY PGLYETHER CHEMICAL NAME : POLYMERIC ALCOHOL SYNONYMS I POLYOL, URETHANE RESIN, "B" COMPONENT CAS NUMBER s N/A - MIXTURE TSCA STATUS I ON INVENTOR* II. HAZARDOUS INGREDIENTS COMPONENTSi APPROX '/. HYDROXYL TERMINATED POLY(OXYALKYLENE) POLYETHER CAS* 9092-00-2 <?6 TERIARY AMINE BEARING COMPOUNDS <2 CURRENT TLV/PEL N.E. N.E. III. PHYSICAL DATA APPEARANCE : VISCOUS LIQUID COLOR I CLEAR TO AMBER ODOR ; SLIGHT AMMONIA MOLECULAR WT t N/A MELT POINT/FREEZE POINT..s <32 F. «O C. > BOILING POINT DECOMPOSES VAPOR PRESSURE i NIL VAPOR DENSITY <AIR « 1)..: M.O SPECIFIC GRAVITY : 1.07 SOLUBILITY IN WATER J SLIGHTLY SOLUBLE VOC '/. : 0 05-O4-1S93 07 45 P 33 MATERIAL SAFETY DATA SHEET (CODE C CONT'D) IV. FIRE ?< EXPLOSION DATA FLASH POINT: 249 F. U20 C. ) PMCC FLAMMABLE LIMITS IN AIR BY VOLUME - LOWER- N E (NONVOLATILE FLUID) UPPER: N.E (NONVOLATILE FLUID) EXTINGUISHING MEDIA- DRY CHEMICAL EXTINGUISHERS SUCH AS MONOAMMONIUf1 PHOSPHATE, POTASSIUM SL'LFATE, POTASSIUM CHLORIDE. ADDITIONALLY, CAPBC DIOXIDE, HIGH EXPANSION (PROTEINIC) CHEMICAL FOAM, WATER SPRAY FOR LARG FIRES. SPECIAL FIRE FIGHTING PROCEDURES- DO NOT DIRECT SOLID WATER STREAM OR FOAM INTO HOT, BURNING POOLS; THIS MAY CAUSE FROTHING AND INCREASE FIR INTENSITY. USE SELF-CONTAINED BREATHING APPARATUS AND BODY COVER !N PROTECTIVE CLOTHINGj BURNING CAN PRODUCE OXIDES OF CARBON AND NITROGEN. UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE V, HEALTH EFFECTS DATA ANIMAL TOXICITY - ORAL, LDSO(INGESTION) : >5000MG/KG <RATS) DERMAL, LD50 (SKIN CONTACT).: >SOOO MG/KG (RABBITS) INHALATION, LC5CK4HR.) J N.E. AQUATIC, LCSO<24 HR. > I N.E. EYES : N.E. SKIN j N.E. HUMAN EFFECTS OF OVEREXPOSURE - INHALATION: MAY CAUSE IRRITATION TO THE THROAT AND RESPIRATORY PASSAGES Bin AT ROOM TEMPERATURE, VAPOR INHALATION IS NOT CONSIDERED HAZARDOUS. SKINl THIS PRODUCT CONTAINS AMINE CATALYST AND WILL CAUSE IRRITATION TO THE SKIN AFTER PROLONGED CONTACT. SOME INDIVIDUALS MAY BE MORE SENSITIVE TO EXPOSURE. INGESTION: THIS IS NOT CONSIDERED A COMMON OCCUPATION ROUTE OF EXPOSURE, ANC NO OBSERVABLE EFFECTS HAVE BEEN DEMONSTRATED. THRESHOLD LIMIT VALUE (ACGIH) I NO TLV HAS BEEN ESTABLISHED FOR THIS PRODUC' AS A SYSTEM. PPEMISSIBLE EXPOSURE LIMIT (DSHA)i SAME AS ABOVE. v 0S-34-1S93 07 45 P 34 MATERIAL SAFETY DATA SHEET (CODE C CONT'D) VI. EMERGENCY J< FIRST AID PROCEDURES EYE CONTACT: FLUOH WITH CLEAN, LUI« E WARM WATER AT LOW PRESSURE FOR AT LEAS' 15 MINUTES, PCCASIONALLY LIFTING E1YELID5. CONSULT A PHYSICIAN IMMEDIATELY SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH WAF"« SOAPY WATER THOROUGHLY. CONTAMINATED CLOTHING SHOULD BE PROPERLY LAUNDE==" BEFCRE REUSING. INHALATION: NOT CONSIDERED HAZARDOUS IN AN INDUSTRIAL SITUATION. INGESTIONi INDUCE VOMITING. NEVER GIVE ANYTHING TO DRINK TO AN UNCONSCIOUS PERSON OR INDUCE VOMITING IN AN UNCONSCIOUS PERSON. NOTE TO PHYSICIAN: BASICALLY, TREATMENT IS SYMPTOMATIC. VII. EMPLOYEE PROTECTION RECOMMENDATIONS EYE PROTECTIONI LIQUID CHEMICAL GOGGLES OR FULL FACE SHIELD. NO CONTACT LENSES SHOULD BE WORN. SKIN PROTECTIONi CHEMICAL RESISTANT GLOVES SUCH AS NATURAL RUBBER, DP PCLYVINYL ALCOHOL. COVER AS MUCH EXPOSED SKIN AS POSSIBLE WITH APPROPRIATE CLOTHING. IF SKIN CREAMS ARE USED, KEEP THE AREA COVERED BY THE CREAM TO A MINIMUM. RESPIRATORY PROTECTION! THIS PRODUCT HAS DEMONSTRATED NO OBSERVABLE EFFECTS AT ROOM TEMPERATURE, HOWEVER, IT IS HIGHLY RECOMMENDED THAT AN Air PURIFYING RESPIRATOR WITH ORGANIC FILTER CARTRIDGES BE WORN. IN ADDITION, I' ANY SPRAY APPLICATION, A SUPPLIED AIR SOURCE MUST BE PROVIDED. VENTILATION: NATURAL OR MECHANICAL. LOCAL EXPAUST WILL KEE» THE TLV BELOW MINIMUM IN MOST CASES. SPILLS OR OTHER EMERGENCIES MAY REQUIRE MORE FORCE-L" VENTILATION MEANS. OTHER: SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE PROVIDED IN ALL WOP1' AREAS. ALL EMPOLYEE3 SHOULD BE PROPERLY TRAINED VIII, REACTIVITY DATA STABILITY: STABLE POLYMERIZATION WILL NOT OCCUR. INCOMPATIBILITY (MATERIALS TO AVOID): AVOID CONTACT WITH ISDCYANATuS AND OTHER SUBSTANCES THAT REACT WITH HYDROXYL GROUPS. HAZARDOUS DECOMPOSITION PRODUCTS: ALIPHATIC FRAGMENTS, CO, NH3, C02. /• to f O.Q ^ MATERIAL SAFETY DATA SHEET (CODE C CONT'D) IX. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL 13 SPILLED OR RELEASED! CONTAIN THE SPILLED MATERIAL rtND THEN COVER WITH ft LOOSE, ABSGRBANT MATERIAL SUCH AS QILDRY, VERMICUL1TE, SAWDUST OR FULLER'S EARTH. SHOVEL WASTE MATERIAL INTO PROPER WASTE CONTAINERS. WASH THE CONTAMINATED AREAS WITH HOT SOAP^ WATER THOROUGHLY. VENTILATE AREA TO REMOVE VAPORS. WASTE DISPOSAL METHODSi WASTE MATERIAL MAY BE INCINERATED OR DISPOSED OF UNDER LOCAL, STATE AND FEDERAL REGULATIONS CONTROLLING fcNVIROMENTAL PROTECTION. X. SPECIAL PRECAUTIONS 5. STORAGE DATA STORAGE TEMPERATURE (MINI/MAX)! &5 F. (19 C. ) TO 75 F. <Z4 C.) AVERAGE SHELF LIFE: 6 MONTHS FROM DATE OF MFG. SPECIAL SENSITIVITY (HEAT LIGHT, MOISTURE)! THIS PRODUCT IS HYGROSCOPIC. CONTAINERS SHOULD BE TIGHTLY SEALED TO PREVENT MOISTURE CONTAMINATION. DO NOT EXPOSE TO HIGH TEMPERATURES FOR ANY LENGTH OF TIME. PRECAUTIONS IN HANDLING AND STORAGE? IF CONTAMINATION WITH ISOCYANATS3 IS SUSPECTED, DO NOT RE-SEAL CONTAINER BECAUSE OF POSSIBLE RUPTURE DUE TO PRESSURE BUILDUP. ALWAYS SLOWLY VENT CONTAINER WHEN OPENING TO RELIEVE ANY PRESSURE BUILDUP. TECHNICAL SHIPPING NAME DOT HAZARD CLASSIFICATION.. FREIGHT CLASS (BULK) FREIGHT CLASS (PACKAGE) PRODUCT LABEL PLACARDS REQUIRED XI. SHIPPING DATA POLYETHER POLYOL BLEND NON-REGULATED POLYPROPYLENE SLYCOL POLYPROPYLENE GLYCOL "B" COMPONENT PQLYOL NONE HMIS: F-l, H-l, R-0 FOR FURTHER INFORMATION, CONTACT EZZAT SEIF, VP TECHNICAL. THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, FXCEPT THAT IT IS ACCURATE TO THE BEST KNOWLEDGE OF POLYMER DEVELOPMENT LABORATORIES, INC.. THE DATA ON THESE SHEETS RELATE ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. POLYMER DEVELOPMENT LABORATORIES, INC. ASSUMES NO LEGAL RESPONSIBILITY FOR USE OR RELIANCE UPON THESE DATA.