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Home My WebLink About2293 COSMOS CT; ; CB010567; Permit04/26/2001 City of Carlsbad 1635 Faraday Av Carlsbad, CA 92008 Commercial/Industrial Permit Permit No Building Inspection Request Line (760) 602-2725 CB010567 Job Address Permit Type Parcel No Valuation Occupancy Group Project Title 04/26/2001 2293 COSMOS CT CBAD Tl Sub Type 2130504500 Lot# $591,660 00 Construction Type Reference # OCEANSIDE GLASSTILE-19,722 SF INDUST 0 IIIN Status Applied Entered By Applicant ROBERT RICHARDSON STEC 2802 STATE ST CARLSBAD CA 92008 760 434-8400 ISSUED 02/08/2001 RMA Plan Approved 04/26/2001Issued Inspect Area Owner AXIOM AIRPORT PARTNERS L P C/0 CHRIS PISARIK 7825 04/26/01 0002 01 3039 CRESTA WAY CGF" LACUNA BEACH CA 92651 02 3755-21 Total Fees $4,51521 Total Payments To Date $760 00 Balance Due $3,755 21 Building Permit Add'l Building Permit Fee Plan Check Add'l Plan Check Fee Plan Check Discount Strong Motion Fee Park Fee LFM Fee Bridge Fee BTD #2 Fee BTD #3 Fee Renewal Fee Add'l Renewal Fee Other Building Fee Pot Water Con Fee Meter Size Add'l Pot Water Con Fee Reel Water Con Fee $2,01868 Meter Size $0 00 Add'l Reel Water Con Fee $1,31214 Meter Fee $0 00 SDCWA Fee $0 00 CFD Payoff Fee $12425 PFF $0 00 PFF (CFD Fund) $0 00 License Tax $0 00 License Tax (CFD Fund) $0 00 Traffic Impact Fee $0 00 Traffic Impact (CFD Fund) $0 00 PLUMBING TOTAL $0 00 ELECTRICAL TOTAL $0 00 MECHANICAL TOTAL $0 00 Master Drainage Fee Sewer Fee $0 00 Redev Parking Fee $0 00 Additional Fees TOTAL PERMIT FEES $000 $000 $000 $000 $000 $000 $12636 $11664 $13468 $12432 $7600 $6000 $9350 $000 $328 64 $000 $000 $4,51521 Inspector/ FINAL APPROVAL Date ni_ ni i i \w v <~xi_ ft- /-Of Clearance NOTICE Please take NOTICE that approval of your project includes the "Imposition" of fees, dedications, reservations, or other exactions hereafter collectively referred to as "fees/exactions" You have 90 days from the date this permit was issued to protest imposition of these fees/exactions If you protest them, you must follow the protest procedures set forth in Government Code Section 66020(a), and file the protest and any other required information with the City Manager for processing in accordance with Carlsbad Municipal Code Section 3 32 030 Failure to timely follow that procedure will bar any subsequent legal action to attack, review, set aside, void, or annul their imposition You are hereby FURTHER NOTIFIED that your right to protest the specified fees/exactions DOES NOT APPLY to water and sewer connection fees and capactiy changes, nor planning, zoning, grading or other similar application processing or service fees in connection with this project NOR DOES IT APPLY to any fees/exactions of which you have previously been given a NOTICE similar to this, or as to which the statute of limitations has previously otherwise expired PERMIT APPLICATION CITY OF CARLSBAD BUILDING DEPARTMENT 1635 Faraday Ave , Carlsbad, CA 92008 PROJECT INFORMATION • FOR OFFICE USE ONL; PLAN CHECK NO EST VAL Plan Ck Deposit Validated By Date DNLY (%»l&%7 ur Address (include Bldg/Suite #)Business Name (at this address) Legal Description Lot No Subdivision Name/Number Unit No Phase No Total tt of units Assessor's Parcel tt Existing Use Proposed Use Description of Work jj .:: fiOr^CtpERSQjJitifJjiffereht from applicant) SO. FT #of Stories tt of Bedrooms 1140 Name ' Address °3'\ ^PJ>LICANT>|rD;;Cbntractor;;; D Agent for Contractor^ D Owner City Agent for Owner, State/Zip Telephone #Fax tt Name 4.'; PROPERTY OWNER Address City State/Zip Telephone tt Name Address City State/Zip Telephone CONTRACT pR^i:COMPANy(NAME» (Sec 7031 5 Business and Professions Code Any City or County which requires a permit to construct, alter, improve, demolish or repair any structure, prior to its issuance, also requires the applicant for such permit to file a signed statement that he is licensed pursuant to the provisions of the Contractor s License Law [Chapter 9 commending with Section 7000 of Division 3 of the Business and Professions Code] or that he is exempt therefrom, and the basis for the alleged exemption Any violation of Section 7031 5 by any applicant for a permit subjects^the applicant to a civil penalty of not more than five hundreddetlars [$500J) Uk — - Name . State License # ^Tlsl ,, — Address'i<3-'\ — -a.1 O 1 License Class [3> City City State/Zip Business License # /vA T ilep'heoe # \'J& Designer Name State License # Address City State/Zip Telephone 16.;. WORKERS' CpiyiPJENSAtipN- ^ ..1,^; ,„:.:„ wJsii|i. , .. ..;... •,.,.. -j'r """„;„„ .^i,...^ ^ •, .: "! Workers' Compensation Declaration I hereby affirm under penalty of perjury one of the following declarations C] I have and will maintain a certificate of consent to self-insure for workers' compensation as provided by Section 3700 of the Labor Code, for the performance of the wwrtTfor which this permit is issued have and will maintain workers compensation, as required by Section 3700 of the Labor Code, for the performance of the work for which this permit is ^tasOed My worker's compensation insurance carrier and policy number are / / O S " OOQO^^fi*) Expiration Date ////O?Insurance Company \Policy No (THIS SECTION NEED NOT BE COMPLETED IF THE PERMIT IS FOR ONE HUNDRED DOLLARS [$100] OR LESS) * O CERTIFICATE OF EXEMPTION I certify that in the performance of the work for which this permit is issued, I shall not employ any person in any manner so as to become subject to the WefCeTs C"hmoe>sation Laws of California WARNING Failure to secure—workers /cprnpinsatian abverage is unlawful, and shall subject an employer to criminal penalties and. civil fines up to one hundred thousand dollars ($100 000) mldd/io/ito iUJ>BjJstA//compensation, damages as provided for in Section 3706 of the Laboypbde^ interest and attorney s fees SIGNATURE Qs XI V\ { /^ ^ '— ' DATE Jl i: OWNER-BUILDER . ... . I hereby affirm that I am exempt from the Contractor s License Law for the following reason n I as owner of the property or my employees with wages as their sole compensation, will do the work and the structure is not intended or offered for sale (Sec 7044, Business and Professions Code The Contractor s License Law does not apply to an owner of property who builds or improves thereon and who does such work himself or through his own employees, provided that such improvements are not intended or offered for sale If, however, the building or improvement is sold within one year of completion, the owner-builder will have the burden of proving that he did not build or improve for the purpose of sale) n li as owner of the property, am exclusively contracting with licensed contractors to construct the project (Sec 7044, Business and Professions Code The Contractor s License Law does not apply to an owner of property who builds or improves thereon and contracts for such projects with contractor(s) licensed pursuant to the Contractor s License Law) n I am exempt under Section Business and Professions Code for this reason 1 I personally plan to provide the major labor and materials for construction of the proposed property improvement fj YES I~|NO 2 I (have / have not) signed an application for a building permit for the proposed work 3 I have contracted with the following person (firm) to provide the proposed construction (include name / address / phone number / contractors license number) 4 I plan to provide portions of the work, but I have hired the following person to coordinate, supervise and provide the major work (include name / address / phone number / contractors license number) ____^_^__^_ 5 I will provide some of the work, but I have contracted (hired) the following persons to provide the work indicated (include name / address / phone number / type of work) PROPERTY OWNER SIGNATURE DATE [COMPLETE THIS,SECT!pNJFOR;/\rp/\Wir£S»£/V7Mt BUILDING PERMITS ONLYi , iiS; , Is the applicant or future building occupant required to submit a business plan acutely hazardous materials registration form or risk management and prevention program under Sections 25505, 25533 or 25534 of the Presley Tanner Hazardous Substance Account Act? O YES l~l NO Is the applicant or future building occupant required to obtain a permit from the air pollution control district or air quality management district7 l~l YES l~l NO Is the facility to be constructed within 1,000 feet of the outer boundary of a school site? l~l YES l~l NO IF ANY OF THE ANSWERS ARE YES A FINAL CERTIFICATE OF OCCUPANCY MAY NOT BE ISSUED UNLESS THE APPLICANT HAS MET OR IS MEETING THE REQUIREMENTS OF THE OFFICE OF EMERGENCY SERVICES AND THE AIR POLLUTION CONTROL DISTRICT I hereby affirm that there is a construction lending agency for the performance of the work for which this permit is issued (Sec 3097(i) Civil Code) LENDER'S NAME _ LENDER S ADDRESS I certify that I have read the application and state that the above information is correct and that the information on the plans is accurate I agree to comply with all City ordinances and State laws relating to building construction I hereby authorize representatives of the CitV of Carlsbad to enter upon the above mentioned property for inspection purposes I ALSO AGREE TO SAVE INDEMNIFY AND KEEP HARMLESS THE CITY OF CARLSBAD AGAINST ALL LIABILITIES JUDGMENTS COSTS AND EXPENSES WHICH MAY IN ANY WAY ACCRUE AGAINST SAID CITY IN CONSEQUENCE OF THE GRANTING OF THIS PERMIT OSHA An OSHA permit is required for excavations over 5 0" deep and demolition or construction of structures over 3 stories in height EXPIRATION Every permit issued by the building Officiatefnder the provisions of this Code shall expire by limitation and become null and void if the building or work authorized by such permit is not com at any time after the work is comme APPLICANT'S SIGNATURE the date of such permit or if the building or work authorized by such permit is suspended or abandoned Section 106 4 4 Uniform Building Code) DATE WHITE File YELLOW Applicant PINK Finance City of Carlsbad Final Building Inspection Dept: Building Engineering Planning CMWD St Lite cEice Plan Check # Date 07/20/2001 Permit # CB010567 Permit Type Tl Project Name OCEANSIDE GLASSTILE-19,722 SF Sub Type INDUS! Address 2293 COSMOS CT Lot 0 Contact Person TIM Phone 7608453003 Sewer Dist CA Water Dist CA Inspected.* /\ . / Bv 7^-^^ Inspected Bv Inspected By 7 Date &4-A.J Inspected Date Inspected Date Inspected 7/ / ^^~~'/f3/0/ Approved ^*"^ Disapproved Approved Disapproved Approved Disapproved Comments City of Carlsbad Bldg Inspection Request For 09/27/2001 Permit# CB010567 Title OCEANSIDE GLASSTILE-19,722 SF Description Inspector Assignment PD Type Tl Sub Type INDUST Job Address 2293 COSMOS CT Suite Lot 0 Location APPLICANT ROBERT RICHARDSON Owner AXIOM AIRPORT PARTNERS L P Remarks Phone 760' Inspector Total Time CD Description 19 Final Structural 29 Final Plumbing 39 Final Electrical 49 Final Mechanical Requested By DON Entered By KAREN Act Comments Associated PCRs PCR01190 PENDING Inspection History Date 07/27/2001 07/20/2001 06/20/2001 06/14/2001 06/12/2001 06/08/2001 06/08/2001 05/31/2001 05/29/2001 05/18/2001 05/11/2001 05/09/2001 05/03/2001 05/03/2001 05/02/2001 05/02/2001 Description 89 Final Combo 89 Final Combo 84 Rough Combo 84 Rough Combo 84 Rough Combo 14 Frame/Steel/Bolting/Welding 66 Grout 17 Interior Lath/Drywall 17 Interior Lath/Drywall 84 Rough Combo 17 Interior Lath/Drywall 17 Interior Lath/Drywall 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 12 Steel/Bond Beam Act CO CO AP AP PA PA AP AP NR PA AP PA AP AP CO CO Insp PD PD RB PD PD PD PD PD PD PD PD PD PD PD TP TP Comments OK TO OCCUPY SEE ATTACHED NOTICE CEILING @ RMS 225 & 226 1ST FLR CEILING AT SAMPLE & MOSAIC CEILING DRYPACK TOOL RM 225,226, BATCH RM NEED ENG DTL @ CONT FTN/CLMN INT I City of Carlsbad Bldg Inspection Request For 07/27/2001 Permit* CB010567 Title OCEANSIDE GLASSTILE-19,722 SF Description Type Tl Sub Type INDUST Job Address 2293 COSMOS CT Suite Lot 0 Location APPLICANT ROBERT RICHARDSON Owner AXIOM AIRPORT PARTNERS L P Remarks Inspector Assignment PD Phone 7608453003 Inspectoi Total Time CD Description 19 Final Structural 29 Final Plumbing 39 Final Electrical 49 Final Mechanical Requested By TIM Entered By CHRISTINE Act Comments To Associated PCRs Date 07/20/2001 06/20/2001 06/14/2001 06/12/2001 06/08/2001 06/08/2001 05/31/2001 05/29/2001 05/18/2001 05/11/2001 05/09/2001 05/03/2001 05/03/2001 05/02/2001 05/02/2001 04/30/2001 Inspection Historv Description 89 Final Combo 84 Rough Combo 84 Rough Combo 84 Rough Combo 14 Frame/Steel/Bolting/Welding, , 66 Grout 17 Interior Lath/Drywall 17 Interior Lath/Drywall 84 Rough Combo 17 Interior Lath/Drywall 17 Interior Lath/Drywall 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 12 Steel/Bond Beam 14 Frame/Steel/Bolting/Weldmg Act CO AP AP PA PA AP AP NR PA AP PA AP AP CO CO AP Insp PD RB PD PD PD PD PD PD PD PD PD PD PD TP TP PD Comments SEE ATTACHED NOTICE CEILING @ RMS 225 & 226 1ST FLR CEILING AT SAMPLE & MOSAIC CEILING DRYPACK TOOL RM 225,226, BATCH RM NEED ENG DTL @ CONT FTN/CLMN INT WALLS Oceanside Qla&stile 3235 Tyler Street Carlsbad, CA 92008 760-434-0051 760-434-0590-fax 7/26/01 City of Carlsbad Building Inspection To Whom it may concern The factory offices #225 and #226 will not be occupied until after installation of the 2nd handj/ail Sean Gi- President r/ City of Carlsbad Bldg Inspection Request For 07/20/2001 Permit# CB010567 Title OCEANSIDE GLASSTILE-19,722 SF Description Inspector Assignment PD Type Tl Sub Type INDUS! Job Address 2293 COSMOS CT/ Suite Lot 0 Location APPLICANT ROBERT RICHARDSON Owner AXIOM AIRPORT PARTNERS L P Remarks Phone 7608453003 Inspect Total Time Requested By TIM Entered By CHRISTINE CD Description 19 Final Structural 29 Final Plumbing 39 Final Electrical 49 Final Mechanical Act Comments Co Associated PCRs Inspection History Date Description 06/20/2001 84 Rough Combo 06/14/2001 84 Rough Combo 06/12/2001 84 Rough Combo 06/08/2001 14 Frame/Steel/Bolting/Welding 06/08/2001 66 Grout 05/31/2001 17 Interior Lath/Drywall 05/29/2001 17 Interior Lath/Drywall 05/18/2001 84 Rough Combo 05/11/2001 17 Interior Lath/Drywall 05/09/2001 17 Interior Lath/Drywall 05/03/2001 11 Ftg/Foundation/Piers 05/03/2001 11 Ftg/Foundation/Piers 05/02/2001 11 Ftg/Foundation/Piers 05/02/2001 12 Steel/Bond Beam 04/30/2001 14 Frame/Steel/Boltmg/Welding 04/30/2001 24 Rough/Topout Act Insp Comments AP RB CEILING @ RMS 225 & 226 AP PD 1ST FLR CEILING PA PD AT SAMPLE & MOSAIC PA PD CEILING AP PD DRYPACK AP PD NR PD PA PD TOOL RM 225,226, BATCH RM AP PD PA PD AP PD AP PD CO TP NEED ENG DTL @ CONT FTN/CLMN INT CO TP AP PD WALLS WC PD CITY'OF CARLSBAD BUILDING DEPARTMENT DATE NOTICE LOCATION PERMIT-NO (760) 602-2700 1635 FARADAY AVENUE TIME T FOR INSPECTION CALL (760) 602-2725 RE-INSPECTION FEE DUE-? I I YES FOR FATHER INFORMATION, CONTACT PHONE BUILDING INSPECTOR CODE ENFORCEMENT OFFICER ® ;:Hd City of Carlsbad Bldg Inspection Request For 06/12/2001 Permit# CB010567 Title OCEANSIDE GLASSTILE-19,722 SF Description Type Tl Sub Type INDUS! Job Address 2293 COSMOS CT Suite Lot 0 Location APPLICANT ROBERT RICHARDSON Owner AXIOM AIRPORT PARTNERS L P Remarks CEILING INSPECTION Total Time Inspector Assignment PD Phone 7608453003 Inspector Requested By TIM Entered By CHRISTINE CD Description Act Comments 14 Frame/Steel/Boltmg/Weldmg VpC k"( £frflA.t?(& < 24 Rough/Topout 34 Rough Electric 44 Rough/Ducts/Dampers Associated PCRs Inspection History Date 06/08/2001 06/08/2001 05/31/2001 05/29/2001 05/18/2001 05/11/2001 05/09/2001 05/03/2001 05/03/2001 05/02/2001 05/02/2001 04/30/2001 04/30/2001 04/30/2001 04/30/2001 Description 14 Frame/Steel/Bolting/Welding 66 Grout 17 Interior Lath/Drywall 17 Interior Lath/Drywall 84 Rough Combo 17 Interior Lath/Drywall 17 Interior Lath/Drywall 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 12 Steel/Bond Beam 14 Frame/Steel/Bolting/Welding 24 Rough/Topout 34 Rough Electric 44 Rough/Ducts/Dampers Act PA AP AP NR PA AP PA AP AP CO CO AP we AP we Insp PD PD PD PD PD PD PD PD PD TP TP PD PD PD PD Comments CEILING DRYPACK TOOL RM 225,226, BATCH RM NEED ENG DTL @ CONT FTN/CLMN INT WALLS WALLS City of Carlsbad Bldg Inspection Request For 05/31/2001 Permit* CB010567 Title OCEANSIDE GLASSTILE-19,722 SF Description Type Tl Sub Type INDUS! Job Address 2293 COSMOS CT Suite Lot 0 Location APPLICANT ROBERT RICHARDSON Owner AXIOM AIRPORT PARTNERS L P Remarks Total Time Inspector Assignment PD Phone 7608453003 Inspect Requested By TIM Entered By CHRISTINE CD Description 17 Interior Lath/Drywall Act Comments Associated PCRs Inspection Historv Date 05/29/2001 05/18/2001 05/11/2001 05/09/2001 05/03/2001 05/03/2001 05/02/2001 05/02/2001 04/30/2001 04/30/2001 04/30/2001 04/30/2001 Description 17 Interior Lath/Drywall 84 Rough Combo 17 Interior Lath/Drywall 17 Interior Lath/Drywall 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 12 Steel/Bond Beam 14 Frame/Steel/Bolting/Welding 24 Rough/Topout 34 Rough Electric 44 Rough/Ducts/Dampers Act NR PA AP PA AP AP CO CO AP we AP we Insp PD PD PD PD PD PD TP TP PD PD PD PD Comments TOOL RM 225,226, BATCH RM NEED ENG DTL @ CONT FTN/CLMN INT WALLS WALLS City of Carlsbad Bldg Inspection Request For 05/29/2001 Permit* CB010567 Title OCEANSIDE GLASSTILE-19,722 SF Description Type Tl Sub Type INDUST Job Address 2293 COSMOS CT Suite Lot 0 Location APPLICANT ROBERT RICHARDSON Owner AXIOM AIRPORT PARTNERS L P Remarks Inspector Assignment PD Phone 7608453003 Inspectoi Total Time CD Description 17 Interior Lath/Drywall Requested By TIM Entered By CHRISTINE Act Comments Associated PCRs Inspection Historv Date 05/18/2001 05/11/2001 05/09/2001 05/03/2001 05/03/2001 05/02/2001 05/02/2001 04/30/2001 04/30/2001 04/30/2001 04/30/2001 Description 84 Rough Combo 17 Interior Lath/Drywall 17 Interior Lath/Drywall 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 1 1 Ftg/Foundation/Piers 12 Steel/Bond Beam 14 Frame/Steel/Boltmg/Weldmg 24 Rough/Topout 34 Rough Electric 44 Rough/Ducts/Dampers Act PA AP PA AP AP CO CO AP we AP we Insp PD PD PD PD PD TP TP PD PD PD PD Comments TOOL RM 225,226, BATCH RM NEED ENG DTL @ CONT FTN/CLMN INT WALLS WALLS .-.if 201'1 ffE 00 <;> '-«! -:„.» c;j Q.I,-.UFL'M 10 3x4 Ul/ 2- Ifcci MAIS T0 EA EXIST 2x-4 v M-t*'^ KlOW ?i I »«r« ^ ! -W :~ t £*•« City of Carlsbad Bldg Inspection Request For 05/03/2001 Permit# CB010567 Title OCEANSIDE GLASSTILE-19,722 SF Description Inspector Assignment PD Type Tl Sub Type INDUST Job Address 2293 COSMOS CT Suite Lot 0 Location APPLICANT ROBERT RICHARDSON Owner AXIOM AIRPORT PARTNERS L P Remarks Phone 7608453002 Inspect Total Time CD Description 11 Ftg/Foundation/Piers Act Comments Requested By TIM Entered By ROBIN Associated PCRs Inspection History Date Description Act Insp Comments 04/30/2001 14 Frame/Steel/Bolting/Welding AP PD WALLS 04/30/2001 24 Rough/Topout WC PD 04/30/2001 34 Rough Electric AP PD WALLS 04/30/2001 44 Rough/Ducts/Dampers WC PD NC : "fley. 03 !53q.M P Ni3- ?r 6 * ss- «.>ft ;l 1 " ,I < " y r rt H 1 8<fTB m C9i JfVi 80I8C 1HI T008--CO/9C 38-'33/5001 THU 39 51 TAX W S4f 3189 DELTA B>OJNEERI>C I - • ' '"\v .v' \ /^ v.X _1_ \ \\ ., \ \ , \ V •% f^^^^^ffiPSB' [ '*; i_j^| j^jj^" 3a \ \ r Ic, n; \ •fti I CARL SCHMIDT REGISTERED SPECIAL INSPECTOR P. O Box 178403 Son Dtego. CA 92177-8403 Phone (619) 865-9252 SPECIAL INSPECTION REPORT PROJECT; Ot^t*,*£,&. £/A*t M - T-.T JOB START: "? ADDRESS, 77^,3 (»*«,&$ £.* JOB STOP' CITY: r.AripW PERMfT # f HolOJ <• 1 PLAN FILE # TYPE OF OBSERVATIONS: MASONRY REINFORCED CONCRETE FIELD WELDING PRESTRESSED CONCRETE SHOP WELDING BOiTlNG REINFORCING STEEL FIREPROORNG. SAMPLES: NUMBER: TYPE Motenafs/Deagn Mix Numbens/PSl, ^JH- ./•* "*'$_ _Q >-_ JpQ inspection Date- . ^ u o •'. REPORT Z/V (•/•'-/ 0,*! ,•/ * 3-f-i. _y .<" "• u .L^-tV . .n // " i-V> eX < U>> •/'•' ." '-f y"7" WORK INSPECTED CONFORfVlS W!TH APPROVED PLANS AND SPECFCATIONS UNLESS OTHERWSE NOTED X, rf l_0ft j 4*^ _ S^P5iot? Project Billing Information. Print Name Certification* Phone' Fax (7C. Signature of Soeclal inspector Carl Schmidt Inspection P O Box 1 78403 San Diego. CA 92177-8403 Phone (619) 855-9252 SPECIAL INSPECTION REPORT PROJECT (}cs^^ i; c/.e <£/***• r/ /-€ JOB START ADDRESS ^, *£, J 3 C^J-^cS C^T. JOB STOP' CITY O^r/s £^c/ PERMIT #: C&&/ &S~ (t>~7 PLAN FILE #• TYPE OF OBSERVATIONS: MASONRY _ REINFORCED CONCRETE _ FIELD WELDING^. EPOXY.X PRESTRESSED CONCRETE _ SHOP WELDING _ BOLTING _ REINFORCING STEEL _ F!REPROOFING SAMPLES NUMBER _ TYPE. Materials/Design Mix Nunnbers/PSI1 S inspection Date' " REPORT F, * /</ ^ ? /{/ / ^ <L : l/Ss t* ^i //> /'^ s & -g ^7^ </ \6ihT-pt~T~ -2>, ct 7" ^6 C/ J" / >g 7^ Je-X/VT^/'^iQ £ *>^ C f-^ T-*- UJl. // -T * ''^c, // x? <^ /^ T^- ? -<-r c/-^ 7" ^ /' / ~ ~, 3 WORK INSPECTED CONFORMS WITH APPROVED PLANS AND SPECIFICATIONS UNLESS OTHERWISE NOTED (_^L^ I JoA/fr-iy^T" £>TC. Project Billing Information1 Print Name Certification^ Fax- ( ) Inspector's Signature Carl Schmidt Inspection P O Box 178403 San Diego. CA 92177-8403 Phone (619) 855-9252 SPECIAL INSPECTION REPORT PROJECT ADDRESS CITY PERMIT # JOB START JOB STOP PLAN FILE #. 30 P#\ TYPE OF OBSERVATIONS: MASONRY REINFORCED CONCRETE FIELD WELDINGj£_ EPOXY_/ PRESTRESSED CONCRETE SHOP WELDING BOLTING REINFORCING STEEL FIREPROOFING SAMPLES NUMBER TYPE' Materials/Design Mix Numbers/PSI XV7 Inspection Date k/S/ol/ ' £71 T REPORT W6LDIMk'.o &] In/< an 4 gf € A lr\*>ldllecl Y~ " LOU fer . $fCUft!£l . 4Wu» ^.leel */\K 3q l!$ sol z-^/ j pppyy Y 7 WORK INSPECTED CONFORMS WITH APPROVED PLANS AND SPECIFICATIONS UNLESS OTHERWISE NOTED Project Billing Information1 Print Name Certification # /?Inspectors Signature Phone. ( Fax. ( ) Carl Schmidt Inspection P O Box 1 78403 San Diego. CA 92 17 7-8403 Phone (6 19) 855-9252 SPECIAL INSPECTION REPORT PROJECT. & <- * q ~~> St c/e G~ /S. J- s / / /£ _ JOB START ADDRESS ^Z^J C<3~r*^ oj- CT: _ JOB STOP. CITY' Gi-r //-/<«; </ PERMIT #. C&O/^~6~7 PLAN FILE #: TYPE OF OBSERVATIONS: MASONRY REINFORCED CONCRETE FIELD WELDING EPOXY_^_ PRESTRESSED CONCRETE SHOP WELDING BOLTING REINFORCING STEEL_ FIREPROOFING SAMPLES. NUMBER. TYPE' Materials/Design Mix Numbers/PSI >ff~ (£/!/""/ ^i't^j^j'^i^ &/&a »rt^ .^CePct */?XT' Inspection Date. -- REPORT s /* 6 . /* f; // & , 5 V J" WORK INSPECTED CONFORMS WITH APPROVED PLANS AND SPECIFICATIONS UNLESS OTHERWISE NOTED C^*c^ / J> <^,^y c/7^ ^ ?^Z~ ProjeJ Billing Information: Print Name Certification # Phone: ( ) Fax' ( ) Inspector's Signature COMPRESSION TEST REPORT KLEINFELDER .A/; (..<!!/;/( '>(.(•: (JU'.')L'J COnjp.f/l1. Report To Carl Schmidt President Carl Schmidt Inspection Services P 0 Box 178403 San Diego, Ca 92177 Material Concrete Supplier Superior Ready Mix Mix No 8355P Spec Strength, psi 3,000 at 28 days File No 51-5783-16 Project Oceanside Glass Tile - T & I 2293 COSMOS CT CARLSBAD PERMIT#CB010567 Date 06/01/01 MIX DATA Cement Factor, sk/cy Max Size Agg , in Admixtures SAMPLE DATA Sampled From New Thickened Slab, 5/F-D 9 Ticket/Load/Truck No 294954/1/355 Sampled By Bill W Date Sampled 05/04/01 Time Date Received 05/05/01 Set No 815 Slump, in Air Temp , F Mix Temp , F Air Content, % Fresh Wt , pcf Measured 40 N/A N/A N/A N/A Specified N/A >40 <90 N/A N/A Specimen (Cyhn) No Identification No Age, days Date Tested Dimensions, in Area, sq in Ultimate Load, Ibs Compressive Str, psi Average Str, psi 9021A 1 - ASTM C 143 2 - ASTM C 1064 3 - ASTM C 231 4 - ASTM C 138 LABORATORY DATA ASTM C-39 902 IB 9021C 7 05/11/01 6x 12 28 27 79,000 2,790 28 06/01/01 6x 12 2827 97,250 3,440 28 06/01/01 6x 12 2827 104,000 3,680 3,560 Remarks CITY OF CARLSBAD MULLEN CONSTR Reviewed by Chnstopher'Raynor f Concrete Lab Manager KLEINFELDER 5015 Shoreham Place, San Diego, CA 921 22 (858) 320-2000 (858) 320-2001 fax t- j H 1 b I r , I i i > . b Iteehnlcs P.O. Box 801889 Temecula, CA 82589 CLIENT Job Project Location: *Grading Permit No; Tract Lot ^? w ft - fa»*fl.) TO _ ft*' Ptfgf V<g>uE-v/r JC-O ^a PI* h . . Earth Technics echims P.O.BOX 891989 (909)699 Temecula, CA 92589 CLIENT Qcssw^te ^i^> Job#J^liii^L_ Date Project Location: wvi £&>MQ<> Q Tract No. Grading Permit No: Lot No. Subject: o'grs °lO.o V>^ Q r . r-» U c. 1 /.> ( r\ A /1/ By:r~n ;/»\I J K.._V.\ FILE • WHITE 5-iti.O PILfc • YELLOW JOB SUPf HIMTtSDENT • PINK EsGig Corporation In fartnersfi-ip With government for 'Suidfmj Safety DATE April 18, 20O1 a APPUgANT JURIS JURISDICTION Carlsbad Q PLAN REVIEWER Q FILE PLAN CHECK NO 01-567 SET III PROJECT ADDRESS 2293 Cosmos Court PROJECT NAME Oceanside Glasstile The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes XI The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified in the attached list are resolved and checked by building department staff The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person The applicant's copy of the check list has been sent to [X] Esgil Corporation staff did not advise the applicant that the plan check has been completed Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Telephone # Date contacted (by ) Fax # Mail Telephone Fax In Person REMARKS By Abe Doliente Enclosures Esgil Corporation D GA D MB D EJ D PC 4/12/01 trnsmtldot 9320 Chesapeake Drive, Suite 208 •» San Diego, California 92123 ^ (858)560-1468 ^ Fax (858) 560-1576 Carlsbad 01-567 III April 18, 2001 THE FOLLOWING OUTSTANDING CORRECTIONS SHALL BE RESOLVED WITH THE BUILDING OFFICIAL 1 Special inspection is required for the installatior^f/Simpson Set anchors as required by ICBO Report No 5279 Please corfjpl^j^f'6 city's special inspection form/ evise the handicap space on sheet AS 1 to show the loading/unloading space to be located on the passenger side of the vehicle , calculations and worksheets to show compliance with current energy Standards Submitted plans will be rechecked after receipt of the completed mechanical plans clearly showing the conditioned area of the tenant improvement Provide the lighting design for the conditioned floor area only. !/ LTG forms were not resubmitted. "*sVe7 Provide automatic shut-off controls for lighting as per Title 24, Part 6, Section 131(d) Referenced sheet (E3.2) not included with resubmittal. he completed and signed LTG-1 form must be imprinted on the plans See comment No.1 above. The provided LTG sheet must be modified to reflect conditioned and/or semi-conditioned floor area only. EsGii Corporation In ^Partnership witfi. government for 'Emitting Safety DATE March 28, 2001 OAEEUgANT ^trJURls3 JURISDICTION Carlsbad a PLAN REVIEWER a FILE PLAN CHECK NO 01-567 SET II PROJECT ADDRESS 2293 Cosmos Court PROJECT NAME Oceanside Glasstile The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes I The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff I | The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck 1X1 The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person The applicant's copy of the check list has been sent to Karnak Architectural/Planning, Inc 2802 State St, Suite C, Carlsbad, CA 92008 Esgil Corporation staff did not advise the applicant that the plan check has been completed XI Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Robert Richardson Telephone # 760/434-8400 Date contacted !>?&-o\ (by £uf] Fax # 760/434-8493 Mail • Telephone Faxw In Person REMARKS By Abe Doliente Enclosures Esgil Corporation D GA IE! MB El EJ D PC 3/19 & 27/01 tmsmtldot 9320 Chesapeake Drive, Suite 208 *• San Diego, California 92123 * (858) 560-1468 4 Fax (858) 560-1576 Carlsbad 01-567 II March 28, 2001 RECHECK PLAN CORRECTION LIST JURISDICTION Carlsbad PROJECT ADDRESS 2293 Cosmos Court DATE PLAN RECEIVED BY ESGIL CORPORATION 3/19 & 27/01 REVIEWED BY Abe Doliente PLAN CHECK NO 01-567 SET II DATE RECHECK COMPLETED March 28, 2001 FOREWORD (PLEASE READ)- This plan review is limited to the technical requirements contained in the Uniform Building Code, Uniform Plumbing Code, Uniform Mechanical Code, National Electrical Code and state laws regulating energy conservation, noise attenuation and disabled access This plan review is based on regulations enforced by the Building Department You may have other corrections based on laws and ordinances enforced by the Planning Department, Engineering Department or other departments The following items listed need clarification, modification or change All items must be satisfied before the plans will be in conformance with the cited codes and regulations Per Sec 106 4 3, 1997 Uniform Building Code, the approval of the plans does not permit the violation of any state, county or city law A Please make all corrections on the original tracings and submit two new sets of prints to Esgil Corp ortothebldg dept of the juris B To facilitate recheckmg, please identify, next to each item, the sheet of the plans upon which each correction on this sheet has been made and return this sheet with the revised plans C The following items have not been resolved from the previous plan reviews The original correction number has been given for your reference In case you did not keep a copy of the prior correction list, we have enclosed those pages containing the outstanding corrections Please contact me if you have any questions regarding these items D Please indicate here if any changes have been made to the plans that are not a result of corrections from this list If there are other changes, please briefly describe them and where they are located on the plans Have changes been made not resulting from this list? QYes UNo Carlsbad 01-567 II March 28, 2001 Please make all corrections on the original tracings, as requested in the correction list Submit three sets of plans for commercial/industrial projects (two sets of plans for residential projects) For expeditious processing, corrected sets can be submitted in one of two ways 1 Deliver all corrected sets of plans and calculations/reports directly to the City of Carlsbad Building Department, 1635 Faraday Ave , Carlsbad, CA 92008, (760) 602-2700 The City will route the plans to EsGil Corporation and the Carlsbad Planning, Engineering and Fire Departments 2 Bring one corrected set of plans and calculations/reports to EsGil Corporation, 9320 Chesapeake Drive, Suite 208, San Diego, CA 92123, (858) 560-1468 Deliver all remaining sets of plans and calculations/reports directly to the City of Carlsbad Building Department for routing to their Planning, Engineering and Fire Departments NOTE Plans that are submitted directly to EsGil Corporation only will not be reviewed by the City Planning, Engineering and Fire Departments until review by EsGil Corporation is complete 1 Plans and calculations shall be signed by the California state licensed engineer or architect where there are structural changes to existing buildings or structural additions Please include the California license number, seal, date of license expiration and date plans are signed Business and Professions Code 4 The tenant space and new and/or existing facilities serving the remodeled area must be accessible to and functional for the physically disabled Title 24 The loading and unloading area of the handicap parking space shall be located on the passenger side of the vehicle. 5 Rooms with more than 10 occupants may have one exit through one adjoining room Revise exits of the manufacturing area to comply Section 1004 2 2 Clearly show the required 2 exits for the manufacturing area. 6 Exits shall not pass through store rooms, or spaces used for similar purposes Section 1004 2 2 Warehouse is considered a store room. 7 Special inspection is required for the installation of Simpson Set anchors as required by ICBO Report No 5279 Please complete the city's special inspection form 9 Please see the following corrections for electrical, plumbing, mechanical and energy The jurisdiction has contracted with Esgil Corporation located at 9320 Chesapeake Drive, Suite 208, San Diego, California 92123, telephone number of 858/560-1468, to perform the plan review for your project If you have any questions regarding these plan review items, please contact Abe Doliente at Esgil Corporation Thank you Carlsbad 01-567 II March 28, 2001 * ELECTRICAL PLAN REVIEW • 1996 NEC « PLAN REVIEWER: MORTEZA BEHESHTI 1 On single line diagram sheet E-1 1 show feeder and conduit size for panels "X1", "X2", "B" and "2A" and transformers "T2" and "T3" NEC 215-5 THE EQUIPMENT GROUND WIRE IS UNDERSIZED FOR PANELS "X1" AND "B". NEC 250-95 8 In all occupancies where the exit system serves 100 or more occupants, provide a minimum of 1 foot-candle of emergency illumination at the floor level and specify a second source of power for the emergency illumination (battery or generator) UBC 1003 2 9 2 & NEC 700-16 THE ONE FOOT-CANDLE OF EMERGENCY EGRESS LIGHTING IS NOT SHOWN IN MANY AREAS. Note. If you have any questions regarding this electrical plan review list please contact Morteza Beheshti at (858) 560-1468 To speed the review process, note on this list (or a copy) where the corrected items have been addressed on the plans PLUMBING, MECHANICAL AND ENERGY CORRECTIONS PLAN REVIEWER: Eric Jensen Revised architectural sheets were submitted after the mechanical plan recheck was performed. The production equipment and materials have been deleted from this permit. As such any of the following corrections dealing with the production equipment or materials may be disregarded. They remain only for informational purposes in helping with the production equipment permit. PLUMBING (1997 UNIFORM PLUMBING CODE) 1 No plumbing is provide in the process area Please include if to be made part of this permit Include the compressed air system piping material on the plumbing material schedule MECHANICAL (1997 UNIFORM MECHANICAL CODE) 2 The mechanical plan check for the non-office area will be performed after the equipment installation is clarified (See above) Sheet MP4 a) Detail completely the method of controlling the exhaust fans EF 1 & 2 exhaust so as not to impact the venting action of the adjacent flues Note If the exhaust airstream crosses the flue termination it may limit the effectiveness of the venting Carlsbad 01-567 II March 28, 2OO1 b) One make up air unit is shown (14,200) for two exhaust fans (14,000 ea X 2 = 28,000 CFM) How does this balance? c) MUA 1 appears to be located too close to flues and exhaust fans Please address 3 How is conditioned air provided to the employee lounge'? 4 Corridors appear to be used on both floors in the office areas Please check with the designer if they are to be rated corridors If rated, revise mechanical design as appropriate (opening protection and air transport) Corridors are shown on the architectural design drawings Please review 5 Clarify on the mechanical plans for the existing mechanical units if smoke detectors are presently installed and, if not, whether they will be installed with this tenant improvement Duct detectors are required for systems exceeding 2, 000 CFM Please review applicability for detectors ENERGY CONSERVATION 6 Provide plans, calculations and worksheets to show compliance with current energy standards Submitted plans will be rechecked after receipt of the completed mechanical plans clearly showing the conditioned area of the tenant improvement Provide the lighting design for the conditioned floor area only 7 Provide automatic shut-off controls for lighting as per Title 24, Part 6, Section 8 The completed and signed LTG-1 form must be imprinted on the plans Note: If you have any questions regarding this Plumbing, Mechanical, and Energy plan review list please contact Eric Jensen at (858) 560-1468 To speed the review process, note on this list (or a copy) where the corrected items have been addressed on the plans EsGii Corporation In Tattnersfiip with government for 'Building Safety DATE February 23, 20O1 OAPEtlQANT JURISDICTION Carlsbad a PLAN REVIEWER a FILE PLAN CHECK NO O1-567 SET I PROJECT ADDRESS 2293 Cosmos Court PROJECT NAME Oceanside Glasstile The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck X] The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person XI The applicant's copy of the check list has been sent to Karnak Architecture/Planning Inc 2802 State St , Suite C, Carlsbad, CA 92008 Esgil Corporation staff did not advise the applicant that the plan check has been completed XI Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Robert Richardson Telephone # 760/434- 8400 Date contacted Z-Zb-oi (by B&~) Fax # - 8493 Mail ix Telephone!/ Fax*^" In Person REMARKS By Abe Doliente Enclosures Esgil Corporation D GA Kl MB Kl EJ D PC 2/12/01 trnsmtldot 9320 Chesapeake Drive, Suite 208 * San Diego, California 92123 ^ (858) 560-1468 ^ Fax (858) 560-1576 \ Carlsbad 01-567 February 23, 20O1 PLAN REVIEW CORRECTION LIST TENANT IMPROVEMENTS PLAN CHECK NO O1-567 OCCUPANCY B/F-2/S-2 TYPE OF CONSTRUCTION III-N ALLOWABLE FLOOR AREA Existing SPRINKLERS'? Yes REMARKS DATE PLANS RECEIVED BY JURISDICTION DATE INITIAL PLAN REVIEW COMPLETED February 23, 2001 JURISDICTION Carlsbad USE Office, manufacturing, warehouse ACTUAL AREA 19,722 SF (T I only) STORIES 1 + M HEIGHT OCCUPANT LOAD 218 (for whole bldg) DATE PLANS RECEIVED BY ESGIL CORPORATION 2/12/01 PLAN REVIEWER Abe Doliente FOREWORD (PLEASE READ): This plan review is limited to the technical requirements contained in the Uniform Building Code, Uniform Plumbing Code, Uniform Mechanical Code, National Electrical Code and state laws regulating energy conservation, noise attenuation and access for the disabled This plan review is based on regulations enforced by the Building Department You may have other corrections based on laws and ordinances enforced by the Planning Department, Engineering Department, Fire Department or other departments Clearance from those departments may be required prior to the issuance of a building permit Code sections cited are based on the 1997 UBC The following items listed need clarification, modification or change All items must be satisfied before the plans will be in conformance with the cited codes and regulations Per Sec 106 4 3, 1997 Uniform Building Code, the approval of the plans does not permit the violation of any state, county or city law To speed up the recheck process, please note on this list (or a copy) where each correction item has been addressed, i.e.. plan sheet number, specification section, etc. Be sure to enclose the marked up list when you submit the revised plans. TENANT IMPROVEMENTS WITHOUT SPECIFIC ENERGY DATA OR POLICY SUPPLEMENTS (1997UBC)tiforw dot Carlsbad 02/23/2001 Please make all corrections on the original tracings, as requested in the correction list Submit three sets of plans for commercial/industrial projects (two sets of plans for residential projects) For expeditious processing, corrected sets can be submitted in one of two ways 1 Deliver all corrected sets of plans and calculations/reports directly to the City of Carlsbad Building Department, 1635 Faraday Ave , Carlsbad, CA 92008, (760) 602-2700 The City will route the plans to EsGil Corporation and the Carlsbad Planning, Engineering and Fire Departments 2 Bring one corrected set of plans and calculations/reports to EsGil Corporation, 9320 Chesapeake Drive, Suite 208, San Diego, CA 92123, (858) 560-1468 Deliver all remaining sets of plans and calculations/reports directly to the City of Carlsbad Building Department for routing to their Planning, Engineering and Fire Departments NOTE Plans that are submitted directly to EsGil Corporation only will not be reviewed by the City Planning, Engineering and Fire Departments until review by EsGil Corporation is complete 1 Plans and calculations shall be signed by the California state licensed engineer or architect where there are structural changes to existing buildings or structural additions Please include the California license number, seal, date of license expiration and date plans are signed Business and Professions Code 2 Provide a note on the plans indicating if any hazardous materials will be stored and/or used within the building which exceed the quantities listed in UBC Tables 3-D and 3-E 3 A complete description of the activities and processes that will occur in this tenant space should be provided A listing of all hazardous materials should be included The materials listing should be stated in a form that would make classification in Tables 3-D and 3-E possible The building official may require a technical report to identify and develop methods of protection from hazardous materials Section 307 1 6 4 The tenant space and new and/or existing facilities serving the remodeled area must be accessible to and functional for the physically disabled See the attached correction sheet Title 24 5 Rooms with more than 10 occupants may have one exit through one adjoining room Revise exits of the manufacturing area to comply Section 1004 2 2 6 Exits shall not pass through store rooms, or spaces used for similar purposes Section 100422 02/23/2001 Carlsbad 02/23/2001 • MISCELLANEOUS 7 Special inspection is required for the installation of Simpson Set anchors as required by ICBO Report No 5279 Please complete the city's special inspection form 8 Complete and recheck the call-outs and cross references to the details 9 Please see the following corrections for electrical, plumbing, mechanical and energy 10 To speed up the review process, note on this list (or a copy) where each correction item has been addressed, i e , plan sheet, note or detail number, calculation page, etc 11 Please indicate here if any changes have been made to the plans that are not a result of corrections from this list If there are other changes, please briefly describe them and where they are located in the plans Have changes been made to the plans not resulting from this correction list9 Please indicate Yes Q No Q The jurisdiction has contracted with Esgil Corporation located at 9320 Chesapeake Drive, Suite 208, San Diego, California 92123, telephone number of 858/560-1468, to perform the plan review for your project If you have any questions regarding these plan review items, please contact Abe Doliente at Esgil Corporation Thank you * ELECTRICAL PLAN REVIEW • 1996 NEC * PLAN REVIEWER. MORTEZA BEHESHTI 1 On single line diagram sheet E-1 1 show feeder and conduit size for panels "X1", "X2", "B" and "2A" and transformers "T2" and "T3" NEC 215-5 2 On single line sheet E-1 1 include panel "2B" shown on sheet E-4 1 3 Show the available fault current (Isc) from the serving utility co and at the equipment where Isc exceeds 10,000 amps 4 Show the ampere interrupting capacity (AIC) ratings of the service and subservice equipment NEC 110-9, 230-65 02/23/2001 Carlsbad 02/23/2001 5 Show or note on the plans the method used to limit fault currents to 10,000 amps on branch circuits Show the fuse letters if used to limit fault current (i e , JJN, AST, LPN) Also note on the plans that circuit breakers used in the subpanels will be listed for series combination with the current limiting mam fuses or circuit breakers 6 Show on the plan the location of the existing service NEC 110-16, 230-2 7 Show the location of panel "B", and transformers "T2" and "T3" NEC 110-16,240- 24,300-21 8 In all occupancies where the exit system serves 100 or more occupants, provide a minimum of 1 foot-candle of emergency illumination at the floor level and specify a second source of power for the emergency illumination (battery or generator) UBC 1003292&NEC700-16 9 If utilizing a series-rated system, note on plans "Overcurrent device enclosures will be identified as series-rated and labeled in accordance with NEC 110-22" and " The overcurrent devices shall be AIC rated per manufacturers labeling of the electrical equipment" Note If you have any questions regarding this electrical plan review list please contact Morteza Beheshti at (858) 560-1468 To speed the review process, note on this list (or a copy) where the corrected items have been addressed on the plans PLUMBING, MECHANICAL AND ENERGY CORRECTIONS PLAN REVIEWER: Eric Jensen 1 The licensed designer must sign each sheet of the plans 2 Provide data on proposed hazardous material to be stored and used UBC, Section 307 and UFC a) Clearly show types of hazardous material is being stored or used Provide a list of the proposed hazardous materials as per the types in UBC, Tables 3-D, and 3-E Provide the material safety data sheets (MSDS) b) Clearly show the amounts of each type of hazardous material to be stored and in use c) Clearly show where in the buildings each type of hazardous material is being stored or used 3 The architectural plans as concerning the installation of the mechanical equipment in the process areas are incomplete No notes are included that are referenced by symbols and architectural details reference do not pertain to the item shown Please review, add the notes where required and correct the details 6 02/23/2001 Carlsbad 02/23/2001 PLUMBING (1997 UNIFORM PLUMBING CODE) 4 Provide gas line plans and calculations, showing pipe lengths and gas demands UPC Section 1217 0 Specify the medium pressure gas pressure on the plans Are there any existing gas uses in the building ? If so show the meter location and gas loads with this tenant improvement 5 No plumbing is provide in the process area Please include if to be made part of this permit MECHANICAL (1997 UNIFORM MECHANICAL CODE) 6 Provide an equipment schedule for all production equipment to be installed under this permit The mechanical floorplan in the production area should include a layout of all equipment, the gas demands of the appropriate equipment, and the flue sizing and routing Presently the architectural does not agree with the mechanical The mechanical sheets themselves even show various layouts (nothing identified) See MP2 and MP7, for example 7 The mechanical plan check for the non-office area will be performed after the equipment installation is clarified (See above) 8 Corridors appear to be used on both floors in the office areas Please check with the designer if they are to be rated corridors If rated, revise mechanical design as appropriate (opening protection and air transport) 9 Include the mechanical design for HP 6, 7, & 8 on the mechanical plans Areas served, ductwork, and registers 10 Include exhaust fans where required for the new restrooms and shower area 11 Clarify on the mechanical plans for the existing mechanical units if smoke detectors are presently installed and, if not, whether they will be installed with this tenant improvement 12 Detail required roof access ladder to roof mounted HVAC equipment UMC, Section 307 5 13 Detail disposal sites of mam condensate drainage from mechanical rooftop units UMC Section 309 ENERGY CONSERVATION 14 Provide plans, calculations and worksheets to show compliance with current energy standards Submitted plans will be rechecked after receipt of the completed mechanical plans clearly showing the conditioned area of the tenant improvement 7 02/23/2001 Carlsbad 02/23/2001 15 On the plans clearly show the wall and roof insulation locations, thickness, and R-values, as per the energy design 16 Provide automatic shut-off controls for lighting as per Title 24, Part 6, Section 131 (d) 17 Show the dayht areas and required daylit area lighting controls for new or relocated lighting in daylit areas Title 24, Part 6, Section 131(c) 18 The completed and signed ENV-1, LTG-1, and MECH-1 forms must be imprinted on the plans Note If you have any questions regarding this Plumbing, Mechanical, and Energy plan review list please contact Eric Jensen at (858) 560-1468 To speed the review process, note on this list (or a copy) where the corrected items have been addressed on the plans DEPARTMENT OF STATE ARCHITECT NON RESIDENTIAL TITLE 24 DISABLED ACCESS REQUIREMENTS The following disabled access items are taken from the 1998 edition of California Building Code, Title 24 Per Section 1011711, all publicly and privately funded public accommodations and commercial facilities shall be accessible to persons with disabilities NOTE All Figures and Tables referenced in this checklist are printed in the California Building Code, Title 24 • REMODELS. ADDITIONS AND REPAIRS 1 When alterations, structural repairs or modifications or additions are made to an existing building, that building, or portion of the building affected, is required to comply with all of the requirements for new buildings, per Section 1134B 2 These requirements apply as follows a) The area of specific alteration, repair or addition must comply as "new" construction b) A primary entrance to the building and the primary path of travel to the altered area, must be shown to comply with all accessibility features c) Existing sanitary facilities that serve the remodeled area must be shown to comply with all accessibility features d) Existing drinking fountains (if any) must be shown to comply with all accessibility features e) Existing public telephones (if any) must be shown to comply with all accessibility features 8 02/23/2001 Carlsbad 02/23/2001 SITE PLAN REQUIREMENTS Show, or note that at every primary public entrance, and at every major function area along, or leading to, an accessible route of travel, there is to be a sign displaying the international symbol of accessibility Signs are required to indicate the direction to accessible building entrances and facilities, per Sections 1117B 5 7 and 1127B3 o DISABLED ACCESS PARKING SPACES Revise site plan to show compliance with the required number of accessible parking spaces for new facilities, (or at existing facilities where a change of occupancy occurs) Per Table 11B-6 the minimum number of spaces is a) 1 for each 25 spaces up to 100 total spaces NOTE- 4 handicap parking spaces are required. Revise site plan to show that accessible spaces comply with Section 1129B 4 1 as follows a) Single spaces shall be 14'0" wide and outlined to provide a 9'0" parking area and a 5'0" loading and unloading area on the passenger side of the vehicle b) When more than one space is provided, in lieu of providing a 14'0" space for each space, two spaces can be provided within a 23'0" area with a 5"0" loading zone between each 9'0" wide space Show or note on the plans that the accessible parking spaces are to be identified by a reflectonzed sign, permanently posted immediately adjacent to and visible from each space, consisting of a) A profile view of a wheelchair with occupant in white on dark blue background b) The sign shall >70 in2 in area c) When in the path of travel, they shall be posted >80" from the bottom of the sign to parking space finished grade d) Signs may also be centered on the wall of the interior end of the parking space >36" from the parking space finished grade, ground or sidewalk e) Spaces complying with Section 1129B 4 2 shall have an additional sign "Van-Accessible" mounted below the symbol of accessibility per Section 1129B5 f) In addition, each accessible space is required to be marked with the international symbol of accessibility 02/23/2001 Carlsbad 02/23/2001 6 Show, or note, that an additional sign shall also be posted in a conspicuous place at each entrance to off street parking facilities, or immediately adjacent to and visible from each stall or space The sign shall be >17" x 22" with lettering not 1" in height Per Section 1129B 5 required wording is as follows "Unauthorized vehicles parked in designated accessible spaces not displaying distinguishing placards or license plates issued for persons with disabilities may be towed away at owner's expense Towed vehicles may be reclaimed at or by telephoning " 10 02/23/2001 Carlsbad 02/23/2001 City of Carlsbad BUILDING DEPARTMENT NOTICE OF REQUIREMENT FOR SPECIAL INSPECTION Do Not Remove From Plans Plan Check No 01-567 Job Address or Legal Description 2293 Cosmos Court Owner Karnak Architecture Address You are hereby notified that in addition to the inspection of construction provided by the Building Department, an approved Registered Special Inspector is required to provide continuous inspection during the performance of the phases of construction indicated on the reverse side of this sheet The Registered Special Inspector shall be approved by the City of Carlsbad Building Department prior to the issuance of the building permit Special Inspectors having a current certification from the City of San Diego, Los Angeles, or ICBO are approved as Special Inspectors for the type of construction for which they are certified The inspections by a Special Inspector do not change the requirements for inspections by personnel of the City of Carlsbad building department The inspections by a Special Inspector are in addition to the inspections normally required by the County Building Code The Special Inspector is not authorized to inspect and approve any work other than that for which he/she is specifically assigned to inspect The Special Inspector is not authorized to accept alternate materials, structural changes, or any requests for plan changes The Special Inspector is required to submit wntten reports to the City of Carlsbad building department of all work that he/she inspected and approved The final inspection approval will not be given until all Special Inspection reports have been received and approved by the City of Carlsbad building department Please submit the names of the inspectors who will perform the special inspections on each of the items indicated on the reverse side of this sheet (over) 11 02/23/2001 FROM' KflRNRK flRCH/PLflN'G INC tai31L LUK,-UKH I J. JIM t-dx PHONE NO 760 434+8493I-SD <x> AJUI Feb 26 2001 10 59flM P12y LD K l^ Carlahad 02/23/2001 SPECIAL INSPECTION PROGRAM ADDRESS OR LEOAU DESCRIPTION 22B3 CoBlDOC CdUrt PLAN CHECK NUMBER: 01-567 OWNER'S NAME: Karnak Architecture I, as the owner, or agent of the owner (contractors may nfit employ the special inspector), certify that I, or the architect/engineer of record, will be responsible for employing the special inspectors) as required by Uniform Building Code (UBC) Section 1701 1 for the construction project located at toe site listed above, UBC Section 109.3.5. Signed I, as the engineer/architect of record, certify that! have prepared the following special inspection program as required by UBC Section 106 3 5 for the construction project located at the site listed above L~ 1, List of work requiring epocial Inspection; Soila Compliance Prior to Foundation Inspection Structural Concrete Over 2500 P8I Prestreesed Concrete Structural Masonry Designer Specified Shield Welding High Strength Bolting Expanslon/Epexy Anchors Sprayed-On Plreprooflng Q Other 2. Name(s) of individuals) or firm(s) responsible for the special Inspections listed above: A. _ B. _ C. 3 Duties of the special Inspectors for the work listed above; A /t B. c. r S39««l msp«ciJns shall check in with tha City and present their credential for approval BflfiLlfi beginnma work on tha job situ 12 02/23/2001 c Carlsbad 01-567 February 23, 2001 VALUATION AND PLAN CHECK FEE JURISDICTION Carlsbad PLAN CHECK NO 01-567 PREPARED BY Abe Doliente DATE February 23, 2001 BUILDING ADDRESS 2293 Cosmos Court BUILDING OCCUPANCY B/F-2/S-2 TYPE OF CONSTRUCTION III-N BUILDING PORTION T 1 Air Conditioning Fire Sprinklers TOTAL VALUE Jurisdiction Code AREA (Sq Ft) 19722 cb Valuation Multiplier By Ordinance 1994 UBC Building Permit Fee T- Reg Mod VALUE ($) 591,660 591,660 $2,294 78' 11994 LJBC Plan Check Fee Type of Review D Repetitive Fee I ;..T.i Complete Review D Other D Hourly fj Structural Only Hour(s) * Esgil Plan Review Fee $1,491 60 $1,19328 Comments Sheet 1 of 1 macvalue doc BUILDING PLANCHECK CHECKLIST DATE <3.//£>Jp / BUILDING ADbRESfe ~S^ 3 PLANCHECK NO CB "7 PROJECT DESCRIPTION ASSESSOR'S PARCEL NUMBER &S0 EST VALUE ENGINEERING DEPARTMENT APPROVAL The item you have submitted for review has been approved The approval is based on plans, information and/or specifications provided in your submittal, therefore any changes to these items after this date, including field modifications, must be reviewed by this office to insure continued conformance with applicable codes Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to build A Right-of-Way permit is required prior to construction of the following improvements DENIAL Please see. the-^attached report of deficiencies marked withjfer Make necessary corrections to plans or specifications for compliance with applicable codes and standards Submit corrected plans and/or specifications to this office for review By By Date Date Date FOR OFFICIAL USE ONLY ENGINEERING AUTHORIZATION TO ISSUE BUILDING PERMIT. Date Dedication Application Dedication Checklist Improvement Application Improvement Checklist Future Improvement Agreement Grading Permit Application Grading Submittal Checklist Right-of-Way Permit Application Right-of-Way Permit Submittal Checklist and Information Sheet Sewer Fee Information Sheet ENGINEERING DEPT CONTACT PERSON Name JOANNE JUCHNIEWICZ City of Carlsbad Address 1635 Faraday Avenue, Carlsbad, CA 92008 Phone (760) 602-2775 CFD INFORMATION Parcel Map No Lots Recordation Carlsbad Tract A-4 H \WORD\DOCSVCHKLST\Building Plancheck Cklsl Form (Cenenc) doc BUILDING PLANCHECK CHECKLIST 1ST 2ND 3rd DISCRETIONARY APPROVAL COMPLIANCE [U D IH 4a Project does not comply with the following Engineering Conditions of approval for Project No D D D 4b Al1 conditions are in compliance Date DEDICATION REQUIREMENTS D EH 5 Dedication for all street Rights-of-Way adjacent to the building site and any storm dram or utility easements on the building site is required for all new buildings and for remodels with a value at or exceeding $15.000. pursuant to Carlsbad Municipal Code Section 18 40 030 Dedication required as follows Dedication required Please have a registered Civil Engineer or Land Surveyor prepare the appropriate legal description together with an 8 1/2B x 11" plat map and submit with a title report All easement documents must be approved and signed by owner(s) prior to issuance of Building Permit Attached please find an application form and submittal checklist for the dedication process Submit the completed application form with the required checklist items and fees to the Engineering Department in person Applications will not be accept by mail or fax Dedication completed by Date IMPROVEMENT REQUIREMENTS 6a All needed public improvements upon and adjacent to the building site must be constructed at time of building construction whenever the value of the construction exceeds $75.000. pursuant to Carlsbad Municipal Code Section 1840040 Public improvements required as follows Attached please find an application form and submittal checklist for the public improvement requirements A registered Civil Engineer must prepare the appropriate improvement plans and submit them together with the requirements on the attached checklist to the Engineering Department through a separate plan check process The completed application form and the requirements on the H \WORD\DOCS\CHKt.S'nBuildino, Planctieck Cklsl Form (RIDDLE HARVEY 7 12 00) doc BUILDING PLANCHECK CHECKLIST I ST 2ND 3rd checklist must be submitted in person Applications by mail or fax are not accepted Improvement plans must be approved, appropriate securities posted and fees paid prior to issuance of building permit Improvement Plans signed by Date D D D 6b Construction of the public improvements may be deferred pursuant to Carlsbad Municipal Code Section 1840 Please submit a recent property title report or current grant deed on the property and processing fee of $280 so we may prepare the necessary Neighborhood Improvement Agreement This agreement must be signed, notarized and approved by the City prior to issuance of a Building permit Neighborhood Improvement Agreement will include the following 6c Enclosed please find your Neighborhood Improvement Agreement Please return agreement signed and notarized to the Engineering Department Neighborhood Improvement Agreement completed by Date D D D 6d No Public Improvements required SPECIAL NOTE Damaged or defective improvements found adjacent to building site must be repaired to the satisfaction of the City Inspector prior to occupancy GRADING PERMIT REQUIREMENTS The conditions that invoke the need for a grading permit are found in Section 11 06 030 of the Municipal Code CD CH CD 7a Inadequate information available on Site Plan to make a determination on grading requirements Include accurate grading quantities (cut, fill import, export) D D D 7b Grading Permit required A separate grading plan prepared by a registered Civil Engineer must be submitted together with the completed application form attached NOTE The Grading Permit must be issued and rough grading approval obtained prior to issuance of a Building Permit Grading Inspector sign off by Date D D 7c Graded Pad Certification required (Note Pad certification may be required even if a grading permit is not required ) H \WORD\DOCS\CHKLS'nBuilding Planctieck Cklst Forai (RIDDLE HARVEY 7 12 00) doc BUILDING PLANCHECK CHECKLIST 1 ST pND 3RD n Q] 7d No Grading Permit required n Q 7e If grading is not required, write "No Grading" on plot plan MISCELLANEOUS PERMITS D D 8 A RIGHT-OF-WAY PERMIT is required to do work in City Right-of-Way and/or private work adjacent to the public Right-of-Way Types of work include, but are not limited to street improvements, tree trimming, driveway construction, tying into public storm dram, sewer and water utilities Right-of-Way permit required for D D 9 INDUSTRIAL WASTE PERMIT If your facility is located in the City of Carlsbad sewer service area, you need to contact the Carlsbad Municipal Water District, located at 5950 El Cammo Real, Carlsbad, CA 92008 District personnel can provide forms and assistance, and will check to see if your business enterprise is on the EWA Exempt List You may telephone (760) 438-2722, extension 7153, for assistance Industnal Waste permit accepted by Date D D D 10 NPDES PERMIT Complies with the City's requirements of the National Pollutant Discharge Elimination System (NPDES) permit The applicant shall provide best management practices to reduce surface pollutants to an acceptable level prior to discharge to sensitive areas Plans for such improvements shall be approved by the City Engineer prior to issuance of grading or building permit, whichever occurs first CH CH CH 11 Q Required fees are attached Q No fees required WATER METER REVIEW D D D 12a Domestic (potable) Use Ensure that the meter proposed by the owner/developer is not oversized Oversized meters are inaccurate during low-flow conditions If it is oversized, for the life of the meter, the City will not accurately bill the owner for the water used • All single family dwelling units received "standard" 1" service with 5/8" service H \WORD\DOCS\CHKLST\Buikling Plancheck CHst Form (Generic) doc 1ST •>ND 3RD D D D 12b BUILDING PLANCHECK CHECKLIST • If owner/developer proposes a size other than the "standard", then owner/developer must provide potable water demand calculations, which include total fixture counts and maximum water demand in gallons per minute (gpm) A typical fixture count and water demand worksheet is attached Once the gpm is provided, check against the "meter sizing schedule" to verify the anticipated meter size for the unit • Maximum service and meter size is a 2" service with a 2" meter • If a developer is proposing a meter greater than 2", suggest the installation of multiple 2" services as needed to provide the anticipated demand (manifolds are considered on case by case basis to limit multiple trenching into the street) Irrigation Use (where recycled water is not available) All irrigation meters must be sized via irrigation calculations (in gpm) prior to approval The developer must provide these calculations Please follow these guidelines 1 If the project is a newer development (newer than 1998), check the recent improvement plans and observe if the new irrigation service is reflected on the improvement sheets If so, at the water meter station, the demand in gpm may be listed there Irrigation services are listed with a circled "I", and potable water is typically a circled "W" The irrigation service should look like STA 1+00 Install 2" service and 5 meter (estimated 100 gpm) If the improvement plans do not list the irrigation meter and the service/meter will be installed via another instrument such as the building plans or grading plans (w/ a right of way permit of course), then the applicant must provide irrigation calculations for estimated worst-case irrigation demand (largest zone with the farthest reach) Typically, Larry Black has already reviewed this if landscape plans have been prepared, but the applicant must provide the calculations to you for your use Once you have received a good example of irrigation calculations, keep a set for your reference In general the calculations will include • Hydraulic grade line • Elevation at point of connection (POC) • Pressure at POC in pounds per square inch (PSI) • Worse case zone (largest, farthest away from valve • Total Sprinkler heads listed (with gpm use per head) • Include a 10% residual pressure at point of connection In general, all major sloped areas of a subdivision/project are to be irrigated via separate irrigation meters (unless the project is only SFD with no HOA) As long as the project is located within the City recycled water H \WORD\DOCS\CHKLST\Buikling Plancheck Cklst Form (Generic) doc 1ST ND oRD2ND 3 BUILDING PLANCHECK CHECKLIST service boundary, the City intends on switching services/meters to a new recycled water line in the future these irrigation D D D 12c Irrigation Use (where recycled water is available) 1 Recycled water meters are sized the same as the irrigation meter above 2 If a project fronts a street with recycled water, then they should be connecting to this line to irrigate slopes within the development For subdivisions, this should have been identified, and implemented on the improvement plans Installing recycled water meters is a benefit for the applicant since they are exempt from paying the San Diego County Water Capacity fees However, if they front a street which the recycled water is there, but is not live (sometimes they are charged with potable water until recycled water is available), then the applicant must pay the San Diego Water Capacity Charge If within three years, the recycled water line is charged with recycled water by CMWD, then the applicant can apply for a refund to the San Diego County Water Authority (SDCWA) for a refund However, let the applicant know that we cannot guarantee the refund, and they must deal with the SDCWA for this 13 Additional Comments: H \WORD\DOCS\CHKLST\Building Plancheck Cklst Form (Generic) doc ENGINEERING DEPARTMENT FEE CALCULATION WORKSHEET Estimate based on unconfirmed information from applicant Calculation based on building plancheck plan submittal Address C-f-Bldg Permit No Prepared by '\ V^ ^ EDU CALCULATIONS Types orUse Types of Use APT CALCULATIONS TypesxxtJJse Types of Use Date 3/3ty£>( Checked byc L List types and square footages^for all uses 3— ^^K S\-«M-^ §W- C^JL&-S )U Sq Ft /Units / Sq Ft /Units List types and square footages for>all uses i_e»^ ^U-suvJ! rz^r- Cls—LQ^) ) v Sq Ft /Units J Sq Ft /Units Date EDU's . / (& EDU's ADT's "7 ADT's FEES REQUIRED WITHIN CFD D YES (no bridge & thoroughfare fee in District #1, reduced Traffic Impact Fee) BfvIO D 1 PARK-IN-LIEU FEE :EE/UNIT PARK AREA & # X NO UNITS = $ TRAFFIC IMPACT FEE ADT's/UNITS BRIDGE AND THOROl ADT's/UNITS X FEE/ADT UNIT/SO FT ET 5 SEWER FEE EDU's . / ( / JGHFARE FEE dENT FEE (DIST X ZONE X #1 FEE/ADT DIST #2 FEE/SO FT /UNIT DIST #3 = $ = $ ) FEE/EDU -i 313.W BENEFIT AREA EDU's D 6 SEWER LATERAL ($2,500) D 7 DRAINAGE FEES PLDA_ ACRES FEE/EDU HIGH =$ /LOW FEE/AC = $ D 8 POTABLE WATER FEES UNITS CODE CONNECTION FEE METER FEE SDCWA FEE IRRIGATION Ward\Docs\Mlsforms\Fee Calculation Worksheet I of 2 Rev 7/14/00 ENGINEERING DEPARTMENT FEE CALCULATION WORKSHEET D 9 RECLAIMED WATER FEES UNITS CODE' CONNECTION FEE METER FEE TOTAL OF ABOVE FEES* $ *NOTE This calculation sheet is NOT a complete list of all fees which may be due Dedications and Improvements may also be required with Building Permits. 2 of 2 Word\Docs\Misforms\Fe6 Calculation Worksheet Rev 7/14/00 IQ D D D n PLANNING DEPARTMENT BUILDING PLAN CHECK REVIEW CHECKLIST Plan Check No CB O\ -S"Lg1 Planner Greg Fisher APN- <a\-?>- osTO-As~ Address Z2PI C T Phone (760) 602-4629 TlType of Project & Use Zoning P-W\ General Plan p\ Net Project Density Facilities Management Zone DU/AC CFD fin/mitl # Circle One _Date of participation.Remaining net dev acres (For non-residential development Type of land used created by this permit ) Legend:7\ Item Complete Environmental Review Required: DATE OF COMPLETION- YES Item Incomplete - Needs your action NO TYPE Compliance with conditions of approval7 If not, state conditions which require action Conditions of Approval. Discretionary Action Required: APPROVAL/RESO NO PROJECT NO YES NO TYPE DATE OTHER RELATED CASES. Compliance with conditions or approval7 If not, state conditions which require action Conditions of Approval [ | | I Coastal Zone Assessment/Compliance Project site located in Coastal Zone? YES CA Coastal Commission Authority' YES NO )d NO If California Coastal Commission Authority Contact them at - 3111 Camino Del Rio North, Suite 200, San Diego CA 92108-1725, (619) 521-8036 Determine status (Coastal Permit Required or Exempt). Coastal Permit Determination Form already completed? If NO, complete Coastal Permit Determination Form now Coastal Permit Determination Log #: YES NO Follow-Up Actions: 1) Stamp Building Plans as "Exempt" or "Coastal Permit Required" (at minimum Floor Plans). 2) Complete Coastal Permit Determination Log as needed H \ADMIN\COUNTER\BldgPlnchkRevChklst I I Inclusionary Housing Fee required: YES _ NO (Effective date of Inclusionary Housing Ordinance - May 21, 1993 ) Data Entry Completed? YES NO (A/P/Ds, Activity Maintenance, enter CB#, toolbar, Screens, Housing Fees, Construct Housing Y/N, Enter Fee, UPDATE1) Site Plan: 1. Provide a fully dimensional site plan drawn to scale Show North arrow, property lines, easements, existing and proposed structures, streets, existing street improvements, right-of-way width, dimensional setbacks and existing topographical lines |_J I I | I 2 Provide legal description of property and assessor's parcel number Zoning: J | 1 Setbacks- Front Interior Side Street Side- Rear. ~J | I I | 2. Accessory structure Front: Interior Side- Street Side Rear- Structure separation I I I I 3 Lot Coverage Required Required Required Required setbacks. Required Required Required Required Required Required Shown Shown Shown Shown Shown Shown Shown Shown Shown Shown D D D 4 He.ght:Required Shown \~~\ \ j | | 5 Parking Spaces Required Guest Spaces Required \[ | Additional Comments Shown Shown TUTS BP THE"SQU\P 1 OK TO ISSUE AND ENTERED APPROVAL INTO COMPUTER H \ADMIN\COUNTER\BldgPlnchkRevChklst Carlsbad Fire Department 010567 1635 Faraday Ave Carlsbad, CA 92008 Plan Review Requirements Category Date of Report 03/29/2001 Fire Prevention (760) 602-4660 Building Plan Reviewed by Name Address Karnak Architecture 2802 State Street Suite C City, State Carlsbad CA 92008 Plan Checker Job Name Oceanside Glasstile Job# 010567 Job Address 2293 Cosmos Court Approved Bldg# CB010567 Ste orBldg No The item you have submitted for review has been approved The approval is based on plans, information and / or specifications provided in your submittal, therefore any changes to these items after this date, including field modifications, must be reviewed by this office to insure continued conformance with applicable codes and standards Please review carefully all comments attached as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements Approved The item you have submitted for review has been approved subject to the Subject to attached conditions The approval is based on plans, information and/or specifications provided in your submittal Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements Please resubmit to this office the necessary plans and / or specifications required to indicate compliance with applicable codes and standards Incomplete The item you have submitted for review is incomplete At this time, this office cannot adequately conduct a review to determine compliance with the applicable codes and / or standards Please review carefully all comments attached Please resubmit the necessary plans and / or specifications to this office for review and approval Review FDJob# 1st 2nd 3rd 010567 FDFile# Other Agency ID Carlsbad Fire Department 010567 1635 Faraday Ave Carlsbad, CA 92008 Plan Review Requirements Category Date of Report 02/28/2001 Fire Prevention (760) 602-4660 Building Plan Reviewed by G Name Address Karnak Architecture 2802 State Street Suite C City, State Carlsbad CA 92008 Plan Checker Job Name Oceanside Glasstile Job# 010567 Job Address 2293 Cosmos Court D Bldg # CB010567 Ste or Bldg No Approved The item you have submitted for review has been approved The approval is based on plans, information and / or specifications provided in your submittal, therefore any changes to these items after this date, including field modifications, must be reviewed by this office to insure continued conformance with applicable codes and standards Please review carefully all comments attached as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements Approved The item you have submitted for review has been approved subject to the Subject to attached conditions The approval is based on plans, information and/or specifications provided in your submittal Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements Please resubmit to this office the necessary plans and / or specifications required to indicate compliance with applicable codes and standards Incomplete The item you have submitted for review is incomplete At this time, this office cannot adequately conduct a review to determine compliance with the applicable codes and / or standards Please review carefully all comments attached Please resubmit the necessary plans and / or specifications to this office for review and approval Review FDJob# 1st 2nd 3rd 010567 FDFile# Other Agency ID Requirements Category Building Plan Requirement Pending 0514 Provide Technical Report To determine the acceptability of technologies, processes, products, facilities, materials and uses attending the design, operation or use of a building or premises subject to the inspection of the department, the Chief is authorized to require the owner or the person in possession or control of the building or premises to provide, without charge to the jurisdiction, a technical opinion and report The opinion and report shall be prepared by a qualified engineer, specialist, laboratory or fire-safety specialty organization acceptable to the Chief and the owner and shall analyze the fire-safety properties of the design, operation or use of the building or premises and the facilities and appurtances situated thereon, to recommend necessary changes Page 1 02/28/01 Karnak Architecture & Planning, Inc. Longton, Architect * Richardson, Planner 2802 State Street, Suite C, Carlsbad, Ca 92008 (760) 434-8400 Fax (760) 434-8493 e-mail karnakarch@aol com Project Oceanside Glasstile Plan Check No 01-567 (City of Carlsbad) Project address 2293 Cosmos Court Plan Check by Abe Dohente Item Response 1 Signed and stamped by each consultant 2 See note 5 on C-l of fixtures and equipment and A6 1 for list of materials normally stored 3 See attached exhibit A6 1 4 The building is fully accessible It has the proper signs, markers, path of travel and door access All doors have low door thresholds per ADA We added a new van accessible space and sign at the rear entry for the required 4th space now required 5 Sample boardroom #119 was changed to exit into warehouse area 6 No exiting will pass through spaces of similar purpose Room 119 will exit into warehouse 7 Special inspection noted on C-l, note 13 and structural plans see attached form 8 Details noted 9 See elect/plumb/mech /energy response list 10 Provided response list 11 Some minor corrections to plan have been made to satisfy this list The equipment will be processed by "shop drawing submittal" and is noted on the cover Cl 0 note #14 The owner clearly understands shop drawings must be plan checked and approve prior to installation and hook up This has been approved by Mike Peterson, City of Carlsbad Responses DSA- Title 24 Disabled Access Requirements 1 The existing facility already has existing 3 handicap spaces with signs, stripping, ramps, and items per code The path of travel has a series of ramps per code to the front door all thresholds meet code 2 Entry sign has been added to AS 1 site plan per code 3 Existing site only has 3 spaces A new van accessible space has been added at the side entrance 4 Sizes noted on plan and new van accessible space at the side elevation 5 Existing spaces have items noted New van accessible space noted with sign 6 Noted on site plan AS 1 and detail on sheet AO 2 March 13, 2001 Karnak Attention: Robert Richardson Subject: Correction Response for Oceanside Glasstile FASHANDI & ASSOCIATES CONSULTING MECHANICAL ENGINEERS 8665 Miralam Dr Suite 210 San Diego, CA 92126 858-547-0090 Fax 858-547-0087 Dear Robert, Fashandi and Associates has reviewed the corrections for the subject project The following items in response to the corrections given to us They are as follows PLUMBING Item Description 4 Please see new gas sizing, isometric drawing, and meter location, sheets MP-1 1, MP-2, and MP-7 5 There is no plumbing for the process area MECHANICAL 6 Please see new schedule provided on sheet MP-7 7 Please see new schedule provided on sheet MP-7 8 Corridors are not to be rated 9 Please see sheets MP-5, MP-6, and MP-7 for mechanical designs 10 Please see sheets MP-1 1 and MP-6 for restroom exhaust fans 11 Existing units do not exceed 2000 CFM, therefore they do not require smoke detectors 12 Roof access ladder is existing, see sheets MP-6 and Mp-7 for location 13 Please see sheet MP-3 for routing of condensate drains ENERGY CONSERVATION 14 Please review revised, submitted energy calculations 15 Please refer to architectural sections indicating the r-value 16 Please see note #10 on sheet E-l 1 17 Please see electrical plans for daylit areas 18 Please see sheet MP-10 for signed ENV-1, LTG-1, and MECH-1 forms ELECTRICAL 1 Please see sheet E-l 1 for feeder and conduit sizes 2 See sheet E-l 1 for location of panel 2B on single line diagram 3 See sheet E-1 1 for the fault current rating 4 See sheet E-l 1 for the AIC rating 5 See sheet E-l 1 for the method used to limit fault current to 10,000 amps 6 See sheet E-2 1 for location of existing service 7 Please see sheet E-2 1 for location of panel B, see sheet E-2 2 for location of transformer T2, and sheet E-2 1 for location of transformer T3 8 Battery backup fixtures Al are shown through out on non-switchable circuits 9 Please see sheet E-l 1 for the note on overcurrent devices and AIC ratings Sincerely, Fashandi and Associates, Inc Micah Ausonio PROCESS DECRIPTION BATCH ROOM All chemical storage is in the batch room Glass cullet (crushed bottle glass), re-cycled waste glass and the chemicals are measured into 55-gallon steel mixing barrels and tumbled Water is added for dust and settling control After mixing the batch is bagged in 40 Ib Bags for charging CASTING AREA The casting area is between the furnaces and the lehr The molten glass is ladled onto a hydraulic press for forming It is transferred to an indtzer for heat- treat and iridizmg From there it is loaded into the lehr for annealing There will be four forming stations with two men operating each station CUTTING & GRINDING Product is unloaded from end of lehr and inspected The pieces are cut and the waste returned to batch room for re-melt Cut mosaic tiles are moved on pallets to mosaic room Cut field tile are ground and crated for transfer to packing and shipping PACKING AND SHIPPING All orders as well as inventory is packed in this area Inventory is boxed and palletized for storage on pallet racks in the storage area UPS and freight are packed and staged for shipment SAMPLE ROOM Tile sample boards are fabricated in the sample room Tile is mounted onto particleboard with thin-set mortar and grouted Sample tile, mortar, grout and completed sample boards are stored in the sample room MOSAIC ROOM Mosaic tile is stored, staged and packed for transfer to packing and shipping MAINTENCE AND FABRICATION All tools and machinery for maintaining and building equipment are in this area All storage of parts inventory and raw materials for new equipment are stored in this area OCEANSIDE GLASSTILE RAW MATERIALS-JAN 2001 LBS Potassium Alumina Florida Sand Soda Ash Borax Sodium Nitrate Nephelene Syenite (feldspar) Zinc Oxide Flourspar Crtf^M1* fuvuor Lime Cfocivrt cMMfMrft Copper Carbonate Cobalt Carbonate Nickel Carbonate Iron Chromate Potassium Dichromate Manganese Dioxide Antimony Oxide Selenium Powder Blue ( bWW #^0 Stannous Chloride Ferric Chloride Sugar Sodium Sulfate / ^m faW) 413670 414000 147000 211000 45000 61070 38250 97480 33000 1470 680 152 520 960 4220 4080 121 0 208 3260 200 2630 3775 4 f/V 1 Iff(ft ftf 1 / (h /ft /A /ft i/v iffifr iff \K ipr I/V gal /A \/ CFI CONSOLIDATED FIREPROTECTION INC. 6108 Avenida Enemas Suite A Carlsbad, CA 92009 (760) 431-9901 Fax (760) 431-9923 cajfomu 641S34 ARIZONA 99198 COLORADO 249 NEVADA 40282 HEW MEXICO 34261 OKLAHOMA 582 UTAH 2»«56-550J WASHINGTON COftSOFI052J7 September 10,2001 Ms Ann Bland, Assistant Fire Marshal Carlsbad Fire Department, Fire Prevention Bureau 1635 Faraday Avenue Carlsbad, California 92008 RE Oceanside Glasstile Technical Report - Supplement Modifications to Control Area(s) Dear Ms Bland The following supplemental data is submitted as a permanent modification to our original technical report for this site This supplemental data is provided on behalf of the owner and is intended to reflect the owner's decision to provide two (2) control areas within the building as opposed to considering the entire building as one control area for the purpose of allowable quantities of hazardous materials This decision is intended to avoid the installation of a secondary containment field All MSDS reports and chemical classifications are provided in our original report The following is a list of the hazardous materials and classification summary for all materials present within each control area detailed on the revised architectural drawings (attached) Control Area #1 Product Pot Alum Flonde Sand F-95 Soda Ash Borax Sodium Nitrate Neph. Sye Total Quantity Stored 2000 Ibs 3000 Ibs 1000 Ibs 2000 Ibs 1000 Ibs 1000 Ibs 10,000 Ibs Quantity in Use - - - - - - _ CFC Classification * 2 2,4 2 2 2,5 2 classification legend: 1. Corrosive 2. Irritant 3. Toxic 4. Carcinogen 5. Oxidizer fen CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile Supplemental (Cont) Page 2 Control Area #2 Product Pot Alum Flonde Sand F-95 Soda Ash Borax Sodium Nitrate Neph Sye Zinc Oxide Flourspar Lime Copper Carbonate Cobalt Carbonate Nickel Carbonate Iron Chromate Chrome Oxide Manganese Dioxide Antimony Selenium Sodium Sulfate Feme Chlonde Stannous Chlonde Total Quantity Stored - - - - - - 300 Ibs 1000 Ibs 500 Ibs 100 Ibs 50 Ibs 10 Ibs 200 Ibs 200 Ibs 200 Ibs 100 Ibs 100 Ibs 300 Ibs 40 Ibs 100 Ibs 3,200 Ibs Quantity in Use 500 500 500 500 500 500 50 Ibs 500 Ibs 100 Ibs 10 Ibs 10 Ibs 5 Ibs1 100 Ibs 100 Ibs 100 Ibs 50 Ibs 5 Ibs 50 Ibs 5 Ibs 100 Ibs 4,185 Ibs CFC Classification * 2 2,4 2 2 2,5 2 2,3 2,4 2 2,3 2 1,2 2 2 2 2, 4, 5 1, 1, 3 2 1, 2 2 classification legend: 1. Corrosive 2. Irritant 3. Toxic 4. Carcinogen 5. Oxidizer CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile Supplemental (Cont) PageS Conclusion: As noted above, this change in the storage plan reflects the owner's objective of avoiding having to provide secondary containment within the batch room by separating raw materials into two separate control areas and by arranging for "Just in Time" delivery of critical inventory, which exceeded the allowable limits of hazards for this occupancy use Based upon our review of the revised storage arrangements and use of hazardous materials, it is our opinion that this owner will be m compliance with all required code sections All other provisions and requirements of our base report remain in effect If you have any comments or questions regarding this report or the proposed use of this facility, please do not hesitate to contact the undersigned or the owner directly Respecjfiilly submitted, Robert G Caputo President Attachment Hazardous Materialsi r SAN DIEGO REGIONAL HAZARDOUS MATERIALS QUESTIONNAIRE Management Division eevirr »r i«i DIIIO Business Name Contact Person Telephone Mailing Address City -U' State CA Zip Plan File* Site Address City State Zip Plan File* PART I FIRE DEPARTMENT • HAZARDOUS MATERIALS MANAGEMENT DIVISION OCCUPANCY CLASSIFICATION Indicate by circling the item, whether your business will use, process, or store any of the following hazardous materials circled, applicant must contact the Fire Protection Agency with jurisdiction pnor to plan submrttal If any or the items are 1 Explosive or Blasting Agents 4 Rammable Solids 7 Pyrophoncs 10 Cryogenics 13 Corrosives 2 Compressed Gases 5 Organic Peroxides 8 Unstable Reactives 11 Highly Toxic or Toxic Materials 14 Other Health Hazards 3 Flammable or Combustible Liquids 6 Oxidizers 9 Water Reactives 1 2 Radioactives PART II COUNTY OF SAN DIEGO HEALTH DEPARTMENT - HAZARDOUS MATERIALS MANAGEMENT DIVISION CONTINGENCY PLAN REVIEW If the answer to any of the questions is yes, applicant must contact the County of San Diego Hazardous Materials Management Division, 1255 Imperial Avenue, 3rd Floor, San Diego, CA 92186-5261 Telephone (619) 338-2222 pnor to the issuance of a building permit FEES MAY BE REQUIRED Yes No 1 | — | ^^* Is your business listed on the reverse side of this form?2 1 — 1 feq Will your business dispose of Hazardous Substances or Medical Waste in any amount? 3 1 — 1 jsP! Will your business store or handle Hazardous Substances in quantities equal to or greater than 55 gallons, * ~* 500 pounds, 200 cubic feet or carcinogens/reproductive toxins in any quantity? 4 | — 1 S?1 Will your business use an existing or install an underground storage tank? 5 l~~l pST Will your business store or handle Acutely Hazardous Materials? OFFICE USE ONLY | | RMPP Exempt / Date Initials [~| RMPP Required / Date Initials |~j RMPP Completed / Date Initials PART III SAN DIEGO COUNTY AIR POLLUTION CONTROL DISTRICT If the answer to any of the questions is yes, applicant must contact the Air Pollution Control Distnct, 9150 Chesapeake Drive, San Diego, CA 92123 Telephone (619) 694-3307 prior to the issuance of a building permit YES NO 1 | l*P5gTWill the intended occupant install or use any of the equipment listed on the bating of Air Pollution Control Distnct Permit Categories, on the ' reverse side of this form? 2 |—| K£T (ANSWER ONLY IF QUESTION 1 IS YES ) Will the subject facility be located within 1 ,OOO feet of the outer boundary of a school (K. through ' ^ 12) as listed in the current Directory of School and Community Collage Distncts, published by the San Diego County Office of Education and the current California Pnvate School Directory, compiled in accordance with provisions of Education Code Section 33190? Briefly describe nat\jtS^T^f!S^nSn3S3^us!nSS»TcSw^r Name of Owner or Authonzed Agent* Signature of Owner or/rythonzed A| and correct Do not write below this* line 2 iiTiir penalty of perjury that to the bast of my knowledge and belief the responses made herein are true Date £~6~<M FIRE DEPARTMENT OCCUPANCY CLASSIFICATION BY Date EXEMPT FROM PERMIT REQUIREMENTS COUNTY-HMMD APCD APPROVED FOR BUILDING PERMIT BUT NOT OCCUPANCY COUNTY-HMMD APCD APPROVED FOR OCCUPANCY COUNTY-HMMD APCD Environment*] Health Service* DHS HM-9171 (6/92) County of San Dicf o Department of Health Service* /: * Part II and Part III of this questionnaire may be handled at one single location : Regional Permit Assistance Center San Diego City Operations Building, 1222 First Avenue, Fourth Floor, San Diego, Ca 92101 RPAC is staffed from 8:00 am to 5:00 pm Monday through Friday PHONE:(619)-236-5938 FAX: 236-7200 Appointments suggested, Walk-ins also welcome Job: Date: 21008 02/2001 Calcsby: C. Sun Sheet 1 of 10 Structural Calculations OCEANSIDE GLASSTILE TENANT IMPROVEMENT O DELTA ENGINEERING Consulting Structural Engineers 135 Liverpool Dr Suite D Cardiff, CA 92007 Tele (760)942-8649 Fax (760)942-6189 7 ELTA NGINEERING .TING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff, CA92007Tele (760)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By C Sun Date 01/2001 Sht No2_ Of Subject Job No 21008 LOADING: ROOF BUILT-UP ROOFING 5 0 PSF !/2" PLYWOOD 2 0 PSF 2x4 @ 24" O C 2 5 PSF INSULATION 1 0 PSF SUSPENDED CEILING 2 5 PSF MECHANICAL & MISC 1 0 PSF DL= 14.0 PSF CONSTRUCTION LOAD = 20.0 PSF FLOOR FLOORING 2 0 PSF 3/4" PLYWOOD 2 5 PSF 2x12 @ 16" O C 4 0 PSF INSULATION 1 0 PSF !/2" GYPBOARD 2 5 PSF MECHANICAL & MISC 1 0 PSF DL= 13.0 PSF LL = 50.0 PSF EXTERIOR WALL 10" CONCRETE TILTUP PANEL 125.0 PSF INTERIOR WALL WOOD STUDS WALL 8.0 PSF SEISMIC ZONE 4 WIND EXPOSURE "C" SPEED 70 MPH ELTA NGINEERING ILTING STRUCTURAL ENGINEERS 135 Liverpool Or Suite DCardiff CA92007Tele (760)942-8649 Fax (760)942-6189 Project Oceanside Glasstile Remodel By CSUN Date 02/2001 Sht No 3 Of Subject Job No Jo f V- ,4- T 1 1 J 1 i 1 > 1 "" y -1 /A - 43i Q Woodworks® Sizer SOFTWARE FOR WOOD DESIGN <; ^4- stair joist-1 Woodworks® Sizer 97d Feb 1,2001 135108 COMPANY PROJECT DESIGN CHECK NDS-1997 Joist DESIGN DATA material Lumber-soft @ 16 0 [in] spacing lateral support Top= Full Bottom= ©Supports total length 11 50 [ft] repetitive factor applied where permitted(refer to online help) Load Combinations BOCA-NBC INPUT LOADS (force=lbs, pressure=psf, udl=plf, location=ft) »Self-weight of members has NOT been included« Load Type Distribution Magnitude Location Pattern Start End Start End Load 1 Dead Full Area 7 (16 0)* No 2 Live Full Area 50 (16 0)* No *Tributary Width (in) MAXIMUM REACTIONS and BEARING LENGTHS (force=lbs, length=in) 11 5 ft Dead 50 50 Live 383 383 Total 433 433 B Length 10 10 #####ft#tt## DESIGN SECTION D Fir-L, No 1, 2x8 This section PASSES the design code check «########################tt#S###(f#ft######## SECTION vs DESIGN CODE (stress=psi, deflection=in) Criterion Analysis Value Design Value Analysis/Design Shear fv @d = 53 Fv1 = 95 fv/Fv1 = 0 56 Bending(+) fb = 1137 Fb' = 1380 fb/Fb1 = 0 82 Live Defl'n 0 32 = L/425 0 38 = L/360 0 85 Total Defl'n 0 39 = L/356 0 58 = L/240 0 67 FACTORS F CD CM Ct CL CF CV Cfu Cr LC# Fb'+ = 1000 1 00 1 00 1 00 1 000 1 20 1 000 1 00 1 15 2 Fv1 = 95 1 00 1 00 1 00 (CH = 1 000) 2 Fcp' = 625 1 00 1 00 E1 = 17 million 1 00 1 00 2 ADDITIONAL DATA Bending(+) LC# 2 = D+L, M = 1245 Ibs-ft Shear LC8 2 = D+L, V = 433, V@d = 388 Ibs Deflection LC# 2 = D+L Total Deflection = 1 50(Defln_dead) + Defln_Live (D=dead L=live S=snow W=wind I=impact C=construction) (All LC's are listed in the Analysis output) DESIGN NOTES 1 Please verify that the default deflection limits are appropriate for your application 2 Sawn lumber bending members shall be laterally supported according to the provisions of NDS Clause 441 ELTANGINEERING ILTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff, CA92007Tele $60)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By C SUN Date 02/2001 Sht No 5~Of Subject Job No io'x/o' UJ =r /o' n JL, ^JELTA^ ENGINEERING CONSULTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff! CA 92007 Tele (760)942-S649Fax (760)942-6189 Project Oceanside Glassfcle Remodel By C SUN Date 02/2001 Sht NoC? Of Subject Job No io'*io'T- •= a^ I 15 Of T>(E - 0 5' ELTA NGINEERING ILTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite D Cardiff, CX92007 Tele (760)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel-, By CSUN Date 02/2001 Sht No / Of Subject Job No L- r, C 4- ELTANGINEERING .TING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff, CA92007Tele $60)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By CSUN Date 02/2001 Sht.NoC? Of Subject Job No H-<i' 4^ i""2-0 24 ' |L I .. . K<Q r /2.• !LL £.r'- ELTA NGINEERING TING STRUCTURAL ENGINEERS 135 Liveroool Dr Suite DCarfiff;CA92007Tele (760)942-8649Fax (760)942-6189 Project OceansideGlasstileRemodel_^ By CSUN Date 02/2001 Sht No^ Of Subject Job No 4/31 02- - o = 5' CO - L- 4*-j—- & **Vc Woodworks® Sizer SOFTWARE FOR WOOD DESIGN 2x4 brace at curtain wall Woodworks® Sizer 97d Feb 2, 2001 10 56 58 COMPANY PROJECT DESIGN CHECK NDS-1997 Wall DESIGN DATA type pinned base, Loadface = width(b) material Lumber Stud @ 48 0 [in] spacing Ke X Lb 1 00 X 6 20= 6 20 [ft] Ke x Ld 1 00 x 6 20= 6 20 [ft] total length 6 20 [ft] Load Combinations BOCA-NBC INPUT LOADS (force=lbs, pressure=psf, udl=plf, location=ft) »Self-weight of members has NOT been included« Load Type Distribution Magnitude Start End Location Start End Pattern Load Dead Axial 201 (Eccentricity = 00 in) DESIGN SECTION D Fir-L, No 2, 2x4 This section PASSES the design code check SECTION vs DESIGN CODE (stress=psi, deflection=in) Criterion Analysis Value Design Value Analysis/Design us. Axial fc = 38 Axial Bearing fg = 38 Fc1 = 189 Fg' = 1818 fc/Fc1 = 0 20 fg/Fg' = 0 02 FACTORS F CD CM Ct CL CF CV Cfu Cr LCft Fc1 = E' = Fg' = 1350 1 6 2020 . 0 90 million 0 90 1 1 00 00 1I1 00 00 00 1 15 (Cp = 0 136)1 01 ADDITIONAL DATA Axial LC# 1 = D only, P = 201 Ibs (D=dead L=live S=snow W=wind I = itnpact C=construction) (All LC's are listed in the Analysis output) DESIGN NOTES 1 Please verify that the default deflection limits are appropriate for your application Job: 21008 Date: 03/2OO1 Calcsby: C. Sun Sheet 1 of 29 Structural Calculations OCEANSIDE GLASSTILE TENANT IMPROVEMENT DELTA ENGINEERING Consulting Structural Engineers 135 Liverpool Dr Suite D Cardiff, CA 92007 Tele (760)942-8649 Fax (760)942-6189 ELTAENGINEERING CONSULTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardifQCA 92007Tele (760)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By CSun Date 01/2001 Sht No 2- Of Subject Job No 21008 LOADING: ROOF BUILT-UP ROOFING 3 5 PSF V" PLYWOOD 1 55 PSF 2x4 @ 24" O C 1 2 PSF INSULATION 1 0 PSF SUSPENDED CEILING 2 5 PSF MECHANICAL & MISC 1 0 PSF DL= 11.0 PSF CONSTRUCTION LOAD = 20.0 PSF FLOOR FLOORING 2 0 PSF 3/4" PLYWOOD 2 5 PSF 2x12 @ 16" OC 40 PSF INSULATION 1 0 PSF V" GYPBOARD 2 5 PSF MECHANICAL & MISC 1 0 PSF DL= 13.0 PSF LL = 50.0 PSF EXTERIOR WALL 10" CONCRETE TILTUP PANEL 125.0 PSF INTERIOR WALL WOOD STUDS WALL 8.0 PSF SEISMIC ZONE 4 WIND EXPOSURE "C" SPEED 70 MPH Woodworks® Sizer SOFTWARE FOR WOOD DESIGN 3 roof beam under mech wbc Woodworks® Sizer 97d Mar 9, 2001 09 47 22 COMPANY DELTA ENGINEERING 135-D LIVERPOOL DR CARDIFF BY THE SEA, CA 92007 TEL (760)942-8649 PROJECT OCEANSIDE GLASS TILE REMODEL BY C SUN DATE 03/2001 SHT- JOB No DESIGN CHECK - NDS-1997 ROOfJoist DESIGN DATA material Lumber-soft 9 24 0 [in] spacing lateral support Top= Full Bottom= ®Supports total length 8 00 [ft] Load Combinations ICBO-UBC INPUT LOADS (force-lbs, pressure=psf, udl=plf, location=ft) »Self-weight of members has NOT been included« \ l i t L \ \ [ Load Type Distribution Magnitude Start End 1 Dead Full Area 14 2 Live Full Area 20 3 Dead Full UDL 121 •Tributary Width (in) Location Start End Pattern Load (24 0)* No (24 0)* No No MAXIMUM REACTIONS and BEARING LENGTHS (force=lbs, length-in) s = = === = ss:sss = = = = s:sss = = = = = = = = = = = sss^s = s = :;:r:ss±s: = :;rr = = = sss== = = = = = = = = : 8 0 ft Dead Live Total B Length 596 160 756 1 0 596 160 756 1 0 DESIGN SECTION D Fir-L, No 2, 4x8 This section PASSES the design code check SECTION vs DESIGN CODE <stress=psi, deflection=»m) Criterion Analysis Value Design Value I Analysis/Design Shear Bending(+) Live Def1'n Total Defl'n FACTORS F f v ®d = 38 fb = 592 0 02 = <L/999 0 14 = L/703 Fv1 = 95 Fb1 = 1170 0 40 = L/240 0 53 = L/180 fv/Fv1 = fb/Fb1 = 0 40 0 51 0 05 0 26 CD CM Ct CL CF CV Cfu Cr LC# Fb' Fv' Fcp E' + = 3 I 3 900 95 625 1 6 1 1 00 00 million 1 1 1 1 00 00 00 00 1111 00 1 000 00 00 00 1 30 1 000 (CH = 1 00 1 000) 1 00 2 2 - 2 ADDITIONAL DATA Bending(+) LC# 2 = D+L, M = 1512 Ibs-ft Shear LC# 2 = D+L, V = 756, V@d = 642 Ibs Deflection LCtt 2 = D+L Total Deflection = 1 50(Defln_dead) + Defln_Live (D=dead L=live S=snow H=wind I=impact C=construction) (All LC's are listed in the Analysis output) DESIGN NOTES 1 Please verify that the default deflection limits are appropriate for your application 2 Sawn lumber bending members shall be laterally supported according to the provisions of NDS Clause 441 l I. i 1 1 L T 1 1 t> P. 13 (/ft- Woodworks® Sizer SOFTWARE FOR WOOD DESIGN 14 CHECK EXIST GLULAM BEAM FOR NEW ROOF Woodworks® Sizer 97d Mar 9, 2001 11 40.36 COMPANY DELTA ENGINEERING 135-D LIVERPOOL DR CARDIFF BY THE SEA, CA 92007 (760)942-8649 PROJECT OCEANS IDE GLASS TILE REMODEL BY C SUN DATE 03/2001 SHT- JOB No Beam DESIGN DATA DESIGN CHECK - NDS-1997 material Glulara Simple lateral support Top= Full total length 47 50 [ft] Load Combinations ICBO-UBC Bottom= ©Supports I .1 .1 I J. INPUT LOADS (force=lbs, pressure=psf, udl=plf, location=ft) »Self-weight automatically included« Load Type Distribution Magnitude Start End 1 Dead Full Area 10 2 Constr Full Area 16 3 Dead Point 610 *Tributary Width (ft) Location Start End Pattern (8 00)* No (8 00)* No 45 00 No 4 I **• •4- 5 ' MAXIMUM REACTIONS and BEARING LENGTHS (force=lbs, length=m) 47 S ft Dead Live Total B Length A 2313 3040 5353 3 3 A 2859 3040 5899 3 6 fJD TAf/ = \0 m##*mm#m#####m####mmm#m#m#*####ftmM##m#^##tf###### DESIGN SECTION VG West DF, 24F-V4, 2 5x27 016 033 plf #### WARNING this CUSTOM SIZE is not in the database Refer to online help #### WARNING your custom section may be too thin to use the properties of this TIMBER database Use a database containing LUMBER sizes instead #### WARNING This section violates the following design criteria #### Deflection k , ^~) e' vA " TY- ^ *• V TV-"HJ SECTION vs DESIGN CODE (stress=psi, deflection=in) Criterion Shear Bending (+) Live Def 1 ' n Total Defl'n Analysis Value f v ed = 113 fb = 2526 1 99 = L/286 4 30 = L/132 Design Value Fv1 = 237 Fb1 = 2739 1 58 = L/360 2 38 = L/240 Analysis/Design fv/Fv1 = 0 48 fb/Fb' = 0 92 1 25 1 81 FACTORS F CD CM Ct CL CF CV Cfu Cr LC# Fb' Fv' Fcp E' •f i _ = = = 2400 190 650 1 8 1 25 1 25 million 1 1 1 1 00 00 00 00 1 11 1 00 1 000 1 00 0 913 1 00 1 00 00 00 00 2 2 - 2 f, _!-— ~6(o IK. ADDITIONAL DATA Bending(+) LC# 2 Shear LC# 2 Deflection LC# 2 Total Deflection = (D=dead L=live M V 63949 Ibs-ft 5518, v®d = 5086 Ibs = D+C, = D+C, = D+C 1 50(Defln_dead) + Defln_Live S=snow W=wind I=impact C=construction) £*'*[ i\<-v7" 6u^H IS At?£-d (All LC's are listed in the Analysis output) DESIGN NOTES 1 Please verify that the default deflection limits are appropriate for your application 2 GLULAM The loading coefficient KL used in the calculation of Cv is assumed to be unity for all cases This is conservative except where point loads occur at 1/3 points of a span (NDS Table 532) 3 GLULAM bxd = actual breadth x actual depth 4 Glulam Beams shall be laterally supported according to the provisions of NDS Clause 333 5 GLULAM bearing length based on smaller of Fcp(tension), Fcp(comp'n) 1 0%*A HAS -2. £AH«£'<- Woodworks® Sizer SOFTWARE FOR WOOD DESIGN 5" CHECK EXIST wbc Woodworks® Sizer 97d Mar 9,2001 110048 COMPANY DELTA ENGINEERING 133-D LIVERPOOL DR CARDIFF BY THE SEA, CA 92007 TEL (760)9428649 PROJECT OCEANS IDE GLASS TILE REMODEL BY C SUN DATE 03/2001 SHT- JOB No DESIGN CHECK NDS-1997 Beam DESIGN DATA material Glulam Simple lateral support Top= Full Bottom= ^Supports total length 28 00 [ft] (/\J Load Combinations ICBO-UBC I —. . . . . , =========================================================================== I 1, 1 i 1 II INPUT LOADS (force=lbs, pressure=psf, udl=plf, location=ft) V »Self-weight automatically included« . r\ Load Type Distribution Magnitude Location Pattern | Start End Start End Load 1 Dead Full Area 14 (45 00)* No \ 2 Constr Full Area 12 (45 00)* No ' *Tributary Width (ft) MAXIMUM REACTIONS and BEARING LENGTHS (force=lbs, lengthen) . =========================================================================== (^ &- 28 0 ft A A Dead 9325 9325 Live 7560 7560 Total 16885 16885 B Length 38 38 ########* DESIGN SECTION VG West DF, 24F-V4, 6 75x22 5 036 074 plf #### WARNING This section violates the following design criteria #### Deflection tt##tt###»###########)t(t#########tttttt##(»tt###tt#)t####«##jttt#(t#tt)t#####)t#)f# SECTION vs DESIGN CODE (stress=psi, deflection=in) Criterion I Analysis Value Design Value Analysis/Design Shear fv ed = 144 Fv' = 237 fv/Fv1 = 0 61 Bending(+) fb = 2490 Fb' = 2663 fb/Fb1 = 0 94 Live Defl'n 0 65 = L/518 0 93 = L/360 0 69 Total Defl'n 1 85 = L/182 1 40 = L/240 1 32 Fb'+= 2400 1 25 1 00 1 00 1 000 1 00 0 888 1 00 1 00 2 Fv1 • 190 1 25 1 00 1 00 2 Fcp'= 650 1 00 1 00 E' = 18 million 1 00 1 00 2===== £XI*TADDITIONAL DATA I =========================================================================== \ Bendmg(+) LC# 2 = D+C, M =118195 Ibs-ftShear LC# 2 = D+C, V =16885, V®d =14623 Ibs Deflection LC# 2 = D+C Total Deflection = 1 50(Defln_dead) + Defln_Live (D=dead L=live S=snow W=wind I=impact C=construction) (All LC's are listed in the Analysis output) DESIGN NOTES 1 Please verify that the default deflection limits are appropriate for your application 2 GLULAM The loading coefficient KL used in the calculation of Cv is assumed to be unity for all cases This is conservative except where point loads occur at 1/3 points of a span (NDS Table 532) 3 GLULAM bxd = actual breadth x actual depth 4 Glulam Beams shall be laterally supported according to the provisions of NDS Clause 333 5 GLULAM bearing length based on smaller of Fcp(tension), Fcp(comp'n) er ff \K&*\ (5 Woodworks® Sizer SOFTWARE FOR WOOD DESIGN CHECK EXIST wbc Woodworks® Sizer 97d Mar 9, 2001 12 01 42 COMPANY DELTA ENGINEERING 135-D LIVERPOOL DR CARDIFF BY THE SEA, CA 92007 (760)942-8649 PROJECT OCEANSIDE GLASS TILE REMODEL BY C SUN DATE 03/2001 SHT- JOB No DESIGN CHECK NDS-1997 Beam DESIGN DATA material Glulam Reverse _______._—, f lateral support Top= Full Bottom= ^Supports I I1TTT 1 L total length 57 00 [ft] ' ' • r * ' "*' ''' Load Combinations ICBO-UBC INPUT LOADS (force=lbs, pressure=psf, udl=plf, location=ft) »Self-weight automatically included« Load Type Distribution Magnitude Location Pattern 1 Start End Start End Load ^ _4_7' 1 Dead Full Area 14 (45 00)* No * 2 Constr Full Area 12 (45 00)* Yes 3 Dead Point 9325 57 00 No 4 Dead Point 1213 40 00 No 5 Constr Point 7560 57 00 Yes •Tributary Width (ft) MAXIMUM REACTIONS and BEARING LENGTHS (force=lbs, length=in) 47 0 10 0 ft = = i*i ^ \-i. Dead 13572 36028 Live 12690 27833 p .-.1-3 i ft Total 26262 63861 I I PC ~ ' * ' * l-S> B Length 60 14 6 ~ »iiiiiii#iiiiiiiiii#i###iii##ii########## DESIGN SECTION VG West DF, 24F-V8, 6 75x34 5 055 313 plf #### WARNING Member length exceeds typical stock length of 41 0 [ft] #### WARNING This section violates the following design criteria #### Bending Deflection »#*fttt#ft#; SECTION vs DESIGN CODE (stress=psi, deflection=in) Criterion I Analysis Value I Design Value I Analysis/Design Shear fv ®d = 194 Fv1 = 237 fv/Fv' = 0 82 "l^ I BtfTA^."* Bending(+) fb = 2522 Fb1 = 2447 fb/Fb1 = 1 03 l Bending(-) fb = 2062 Fb' = 2582 fb/Fb' = 0 80 Live Defl'n 0 97 = L/123 0 67 = L/180 1 46 Total Defl'n 1 39 = L/86 1 00 = L/120 1 39 (a cantilever span governs deflection)=========================================================================== KP/LM i^ ?'/ FACTORS F CD CM Ct CL CF CV Cfu Cr LC# OevV A I •» ' /• Fb'+= 2400 1 25 1 00 1 00 1 000 1 00 0 816 1 00 1 00 3 Fb'-= 2400 1 25 1 00 1 00 0 906 1 00 0 861 1 00 1 00 4 Fv' = 190 1 25 1 00 1 00 2 Fcp'= 650 1 00 1 00 E' = 18 million 1 00 1 00 3 ADDITIONAL DATA Bendmg(+) LC# 3 = D+C (pattern C_) , M =281473 Ibs-ft Bendmg(-) LC# 4 = D+C (pattern _C), M =230115 Ibs-ft Shear LC# 2 = D+C, V =33364, Ved =30159 Ibs Deflection LC# 3 = D+C (pattern C_) Total Deflection = 1 50(Defln_dead) + Defln_Live (D=dead L=live S=snow W=wind I=impact C=construction) (All LC's are listed in the Analysis output) (Load Pattern s=S/2, X=L+S or L+C, _=no pattern load in this span) DESIGN NOTES 1 Please verify that the default deflection limits are appropriate for your application 2 GLULAM The loading coefficient KL used in the calculation of Cv is assumed to be unity for all cases This is conservative except where point loads occur at 1/3 points of a span (NDS Table 532) 3 Grades with equal bending capacity in the top and bottom edges of the beam cross-section are recommended for continuous beams on: )cr ELTAS. ENGINEERING CONSULTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff, CA92007Tele (760)942-8649 Fax (760)942-6189 Project Oceanside Glassfale Remodel By C SUN Date 03/2001 Sht No "7 Of Subject . . Job No 21008 I-16' /r 2^4/0 're sr ELTANGINEERING -TING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite D Cardiff CA 92007Tele (760)942-8649Fax (760)942-6189 Project Oceanside Glasstale Remodel By CSUN Date 02/2001 Sht No Subject Job No Of ( < . 1 J J 1 . rx 1 y i 1 1 • 0\<- I I I 1 1 Itt- Woodworks® Sizer SOFTWARE FOR WOOD DESIGN stair joist-1 Woodworks® Sizer 97d Feb 1,2001 1351 08 COMPANY PROJECT DESIGN CHECK NDS-1997 Joist DESIGN DATA material Lumber-soft ® 16 0 [in] spacing lateral support Top= Full Bottom= eSupports total length 11 50 [ft] repetitive factor applied where permitted(refer to online help) Load Combinations BOCA-NBC INPUT LOADS (force=lbs, pres9ure=psf, udl=plf, location=ft) »Self-weight of members has NOT been included« Load Type Distribution Magnitude Location Pattern Start End Start End Load 1 Dead Pull Area 7 (16 0)* No 2 Live Full Area 50 (16 0)* No "Tributary Width (in) MAXIMUM REACTIONS and BEARING LENGTHS (force=lbs, lengthen) 11 5 ft A A Dead SO 50 Live 383 383 Total 433 433 B Length 10 10 n**W**M DESIGN SECTION D Fir-L, No 1, 2x8 This section PASSES the design code check ##mm###mm*mm##****M##m#m# SECTION vs DESIGN CODE (stress-psi, deflection=in) Criterion Analysis Value I Design Value I Analysis/Design Shear fv ad = 53 Fv1 = 95 fv/Fv1 = 0 56 Bending(+) fb = 1137 Fb1 = 1380 fb/Fb' = 0 82 Live Defl'n 0 32 = L/425 0 38 - L/360 0 85 Total Defl'n 0 39 = L/356 0 58 » L/240 0 67 FACTORS F CD CM Ct CL CF CV Cfu Cr LC# Fb'+= 1000 1 00 1 00 1 00 1 000 1 20 1 000 1 00 1 15 2 Fv' = 95 1 00 1 00 1 00 (CH = 1 000) 2 Fcp'= 625 1 00 1 00 E' = 17 million 1 00 1 00 2 ADDITIONAL DATA Bending(+) LC# 2 = D+L, M = 1245 Ibs-ft Shear LC# 2 = D+L, V = 433, V®d = 388 Ibs Deflection LC# 2 = D+L Total Deflection = 1 50(Defln_dead) + Defln_Live (D=dead L=live S=snow W=wind I=impact C=construction) (All LC's are listed in the Analysis output) DESIGN NOTES 1 Please verify that the default deflection limits are appropriate for your application 2 Sawn lumber bending members shall be laterally supported according to the provisions of NDS Clause 441 ELTANGINEERINGILTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff CA92007Tele (760)942-8649Fax (760)942-6189 Project Oceanside Glassfale Remodel By C SUN Date 02/2001 Sht No IO Of Subject Job No TVf£ /OX/Q'**/ X-N -* ELTANGINEERING .TING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff CA92007Tele (760)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By CSUN Date 02/2001 Sht No U Of Subject Job No jo ,5 Af f 25' — = 7?7a LB. ELTA_L ENGINEERINGCONSULTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff CA92007Tele (760)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By CSUN Date 02/2001 Sht No 12-Of Subject Job No T$- A" To 4- /4-V ELTA NGINEERINGTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff CA92007Tele 060)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By CSUN Date 02/2001 Sht No^ Of Subject Job No x/2.!El ^ a ELTA_w ENGINEERING CONSULTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff CA92007Tele f?60)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By C SUN Date 02/2001 Sht No) L\ Of Subject Job No 4/31 5 (5 CO - L 14 a. Woodworks® Sizer SOFTWARE FOR WOOD DESIGN 2x4 brace at curtain wall Woodworks® Sizer 97d Feb 2, 2001 10 58.58 COMPANY PROJECT Wall DESIGN DATA type material Ke x Lb Ke x Ld total length DESIGN CHECK - NDS-I997 pinned base, Loadface = width(b) Lumber Stud ® 48 0 [in] spacing 1 00 x 6 20= 6 20 [ft] 1 00 X 6 20= 6 20 [ft] 6 20 [ft] Load Combinations BOCA-NBC INPUT LOADS (force=lbs, pressure=psf, udl=plf, location=ft) »Self-weight of members has NOT been included« Load Type Distribution Magnitude Start End Location Start End Pattern Load Dead Axial 201 (Eccentricity = 00 in) DESIGN SECTION D Fir-L, No 2, 2x4 This section PASSES the design code check SECTION vs DESIGN CODE (stress=psi, deflection=in) Criterion Analysis Value I Design Value Analysis/Design JT Axial Axial Bearing fc 38 38 Fc' Fg' 189 1818 fc/Fc' fg/Fg' 0 20 0 02 L- FACTORS F CD CM Ct FC1 E> Fg' 1350 0 90 1 6 million 2020 0 90 00 1 00 00 1 00 1 00 CL CF CV Cfu 1 15 (Cp = 0 136) Cr LCtt ADDITIONAL DATA Axial LC# 1 = D only, P = 201 Ibs (D=dead L=live S=snow W=wind I=impact C=construction) (All LC's are listed in the Analysis output) DESIGN NOTES 1 Please verify that the default deflection limits are appropriate for your application / ^5^5 pNGINEERING CONSULTING STRUCTURAL ENGINEERS1 35 Liverpool or suite D Cardiff CA 92007 Tele (760)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel n~ ,~~n, „, ^ IL^ ,-wBy C SUN Date 03/2001 Sht Nol*9 Of o u * T u XT omrkoSubject Job No 21008 W - ^ 3 \ W P - 3333 V. A-f ELTA NGINEERING TING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff CA 92007 Tele 060)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By C SUN Date 03/2001 Sht No ' "7 Of Subject . Job No 21008 1 tfr 2, ELTA $L ENGINEERING CONSULTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiiT. CA 92007Tele 060)942-8649Fax (760)942-6189 Project Oceanside Glasstile Remodel By CSUN Date 03/2001 Sht No!*?? Of Subject Job No 21008 V- * r- — °- 02$-^ Entxtaamc Title : ObEANSIDE GLASSTILE REMODEL Job # 21008 Dsgnr 0SUN Date- 925AM, 9 MAR 01 Description Scope • 13-Juv1M8 Win32 Steel Column Page 1 \\chang\c\enef\fites\ocensideglasstile\steel Description DESIGN OF STEEL COLUMN FOR NEW PIPING General Information Calculations are designed to AISC 9th Edition ASD and 1997 UBC Requirements | Steel Section P4STD Column Height 11000ft End Fixity Fix-Free Live & Short Term Loads Combined Fy Duration Factor Elastic Modulus X-X Unbraced Y-Y Unbraced 36 00 ksi 1330 29,000 00 ksi 11000ft 11000ft X-X Sktesway Y-Y Sidesway Kxx Kyy Sway Allowed Sway Allowed 2100 2100 Loads ____J Axial Load... Dead Load Live Load Short Term Load Point lateral Loads Along Y-Y (strong axis moments) Along X-X (y moments) 078k k k Ecc for X-X Axis Moments Ecc for Y-Y Axis Moments in in _BL__ST_ 0400k k Height 11000ft ft Summary Column Design OK Section P4STD, Height = 11 00ft, Axial Loads DL = Unbraced Lengths X-X= 1100ft, Y-Y= 1100ft Combined Stress Ratios Dead AISC Formula H1 -1 AISC Formula H1 - 2 AISC Formula H1 - 3 0 0555 0 78, LL = 0 00, ST = 0 00k, Ecc = 0 000m Live 00555 PL + ST + (LL if Chosen) 05617 XX Axis : Fa calc'd per 1 5-2, K*L7r > Cc YY Axis • Fa calc'd per 1 5-2. K*L/r > Cc Stresses Allowable & Actual Stresses Fa Allowable fa Actual Fb'xx Allow [F31] fb xx Actual Fbyy Allow [F31] fb yy Actual Dead Live DL 443ksi OOOksi 0 25 ksi 0 00 ksi 23 76 ksi 0 00 ksi 0 00 ksi 0 00 ksi 23 76 ksi 0 00 ksi 0 00 ksi 0 00 ksi + LL DL + Short 443 ksi 025 ksi 23 76 ksi 000 ksi 23 76 ksi 000 ksi 590 ksi 025 ksi 31 60 ksi 1643 ksi 31 60 ksi 000 ksi I Analysis Values | Pex DL+LL F'ey DL+LL F'ex DL+LL+ST Fey DL+LL+ST Max X-X Axis Deflection 4,432 psi Cm X DL+LL 0 85 4,432 psi Cm y DL+LL 0 85 i 5,895 psi Cm x DL+LL+ST i 0 85 1 5,895 psi Cm y DL+LL+ST 0 85 -1463m at 11000ft Max Y-Y Axis Deflection Cbx DL+LL Cby DL+LL Cbx DL+LL+ST Cby DL+LL+ST 0000 in at 175 175 100 175 0000ft Title OCEANSIDE GLASSTILE REMODEL Job #21008 Dsgnr C SUN Date 925AM, 9 MAR 01 Description Scope R«v- 510002 Uwr KWMM03111 Ver 5 1 2. lJ.Jun-1889 Win32(c) 1813-98 ENERCALC Steel Column Page 2 \\chano\c\enei\files\ocansidealasstile\steel Description DESIGN OF STEEL COLUMN FOR NEW PIPING Section Properties P4STD Diamet Thickness 4 50 m 0237m Weight Area 1077#/tt 317m2 l-xx l-yy S-xx S-yy r-xx r-yy 723 in4 723in4 3213m3 3213in3 1510m 1510m Sketch & Diagram Axial DL = 078k Axal LL = Ok AxM ST = Ok —O —o Dun Enamaaa Title OCEANSIDE GLASSTILE REMODEL Job #21008 Dsgnr C SUN Date 1 55PM, 9 MAR 01 Description Scope 2-1 Rev- 510302 User KW 0603118 Ver 5 1 3 22 Jun 1999 Win32(c) 1983 99 ENEROM.C Pole Embedment in Soil Page 1 c \ener\files\ocenside elasstile\steel column Description FOOTING FOR THE STEEL COLUMN General Information AIIOW passive Max Passive Load duration factor Pole is Rectangular Width Restrained @ Surface loU 00 pet 1,500 00 Psf 1330 36 000 in Applied Loads Point Load distance from base Distributed Load distance to top distance to bottom 286 00 Ibs 11000ft 000#/ft 0000ft 0000ft | summary | Moments @ Surface Point load Distributed load With Surface Restraint Req'd Depth Pressure @ Base Actual Allowable Surface Restraint Force 3,14600 ft-# Total Moment 0 00 Total Lateral 2512ft 501 07 psf 501 07 psf 1,748 33 Ibs 3,146 00 ft-# 286 00 Ibs ELTANGINEERING .TING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff CA 92007Tele Q60)942-S649Fax 17601" Project By. Subject Date £U*ri'b;('*- Sht No^Z Of Job No n - /«>.//< = z, S^k! *£ NrJTNRRPTNa CONSULTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite D Cardiff CA 92007Tele. (760)942-8649Fix: (760/942-6189 LftTeltL WfttY«$ tjtl^MlC-^- -. . o tt^t. Project (x By Subject :.,-/ rry* ^ ^^K\<IC^ uiogg^id. Date ^Ol. Sht No"Z3 Of Job No • i ? V Ce 1 o I./3 I c A3 A* I f CONSULTING STRUCTURAL ENlilNthRS 135 Liverpool Dr. Suite D Cardiff CA. 92007 Tele (760)942-S649Fix (760)942-6189 " 4HW 62\^— ^x© sX© 3' (' {' Lift ) X X ' '® <§ ^?X^ © px© ,•,;«•,, '\ > X X /.. € I*I ' ^x 1 X X ' r By. Date ^ Subject <3> © ^ v^L X X e c . ,r 1 S) X ,• ^ ^ ^fj 2/0 / Sht No^-T. Of . . Job No ® (J 1 5' >I T 24' ® ?) •V Z c*l* L_ .«?£ ~™n "i r ,y ,t? e_ \J * 0 -. (T). (7 ^ELTA5.. ENGINEERING CONSULTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite DCardiff CA 92007Tele. 060)942-8649Fax C760)942-6189 ProjectOd£} By Date Subject 'i sht: Job No (A) ( -p f-r-< /f 5. RNGINEERING CONSULTING STRUCTURAL ENGINEERS 135 Liverpool Dr Suite D CardifTCA92007Tele (760)942-S649Fax (760)942-^189 By Date °JO I Subject Job No Of 4 = ^ ' CTF- ^ A , /* / 7 CLTAENGINCCRING CONSULTING STRUCTURAI 1 3S 1 iM.rpool Or Since OC ir.l.ff C\')2007I C.IL (/GO)1; I? SGI')i iv (i<->oym GISQ Shi lob I v/ 2 - o = ? 2- P ^[ YV\ . n , 00 - * - -7 CLTAENGINCCRING I 3S I mrpool Or Suilc IIr Tr.i.rr o 02007 IC.IL (/60)Ji2 SO")i iv (;f,ov'i21" " op , V Y P = 1 if 4.8 T=1 ' j ' Of ^ENCINCCRING CONSULTING STnucruRAi 135 I n(.rpool Or Smic Ot'iriliff C/\ 02007Ilk (760WI2 S6-!1;1? GIRO I IOICC I ny SMI lob A--/. o\< CONSOLIDATED FIREPROTECTION INC. 6108 Avenida Encinas Suite A Carlsbad, CA 92009 (760) 431-9901 Fax (760) 431-9923 PJ CALIFORNIA 641134 ARIZONA 9919S COLORADO 249 NEVADA 40282 NEW MEXICO 34261 OKLAHOMA 512 UTAH 2936S6 5501 WASHINGTON COHSOFH52J7 Technical Opinion & Report Prepared for: Glasstile 2293 Cosmos Ct. Carlsbad, CA 92009 For Submittal to: Carlsbad Fire Department Fire Prevention Bureau 1635 Faraday Avenue Carlsbad, California 92008 CITY OF CARLSBAD FIRE DEPARTMENT APPROVED Subject to field inspection and required tests, notations hereon, conditions in correspondence and conformance with applicable regulations The stamping of these plans shall not be held to permit or approve the violation of any law BY I I I I I I I CFI CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 2 Building Construction, Occupancy Classification and Fire Protection: Ed N Fully SprinkleredBuilding Type of Construction Building Area Analysis 1st Floor 2nd Floor Total Building Area Offices - Manufacturing - Warehouse- Total- Occupancy Classification Offices Glass Products Manufacturing Glass Products Storage Ceiling Height Ceiling Level Sprinkler Density 41,341 sqft. 5.931 soft 47,272 sqft. 11,267 sqft 11,129 sqft 24,875 sqft 47,272 sqft. B F-2 S-2 27 ft. max. 45 gpm/3000 sqft General Overview: Oceanside Glasstile manufactures and distributes glass, mosaic and ceramic tile for use in kitchens, bathrooms, etc The tiles are manufactured using re-cycled bottle glass, with chemical additives for color The mixture is fired in one of three gas-fired furnaces and baked in a self-contained kiln described below All items used, stored and distributed (recycled bottle glass, sand, misc. powder additives for color and related mastics and mortars) are used in the manufacture or installation of glass tiles Prndnct packaging includes a two-part figrrid Spray fopm fa place filler Manufacturing Processes & Machinery: All raw materials used in glass tile making are powdered chemicals or silica sand stored and mixed in the BatcitRaom. Storage is in 50 Ifr and 100 Ib bags in pallet quantities. The open storage is in plastic drums (500 Ib quantities) or 12" x 18" x 24" plastic tubs (5 Ib- 100 Ib quantities). All open use containers have lids , The chemicals are measured in 250 Ib - 300 Ib quantities into steel mixing drums with one quart water (for dust control) and tumbled on side, on rollers. The mixed batches are transferred into paper bags (40 Ib capacity) for charging. All mixing and bagging takes place in the Batch Room. The closed bags of batch are transported to the furnaces in pallet quantities for charging. The batch is charged, bag and all, into one of the furnaces to melt the glass, dust in the furnace area. I I I I I I i . JCFI • CONSOLIDATEDm FIREPROTECTfON Oceanstde Glasstile (Cont) Page 3 The melted glass is dumped into pattern forms then loaded into the kiln by hand. The tiles exit the kiln in a copied state where workers score the tiles and break them into individual tiles, boxed and stored for distribution. The batch mixing workers are issued proper protective gear and trained to handle and dispose of hazardous materials, which are collected; in a polyethylene lined gaylord pallet container and picked up by a licensed disposal company Btast furnaces: 3 gas-fired 3,000 Ib units constructed of brick and mortar operating at 2,450 degrees F, used to fire glass tiles. Units are provided with automatic gas shut-off valves, which operate within 1/10* of one second following any loss of electrical power Each blast furnace is provided with a fixed exhaust stack, vented through the roof to the atmosphere Exhaust gases measured at 400 degrees F at stack discharge, 600 degrees F within the stack, (See attached rerx>rt on emissions testing by Horizon Air Measurement Services, Hoc, dated 2/7/01) Kiln: the self-contained annealing tehr kiln is manufactured by E W Bowman Corp The process requires heating and cooling the product within the confines of the oven This unit does not require an exhaust Special Notes: 1 Oceanside Glasstile has received a Certificate of Exemption from the San Diego County Air Pollution Control District #975087 (attached) for then- current location, which is transferable to the new location. < 2 Oceanside Glasstile has a San Diego Regional Hazardous Materials Permit #H39080 (attached) which is also transferable to the new site Hazardous Materials: Allowable Exempt Amounts: Aggregate quantities of materials for storage are identified in the following Hazardous Materials Inventory Statement and the Comparative Summary of Hazardous Materials to Exempt Amounts per the Building Code Tables 3-D and 3-E and Fire Code Table 8802.3-A (attached). For the purpose of this report, the entire building shall be considered as one control area. I CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 4 Hazardous Materials Inventory Statement (HMIS) per Area Sample Room Product Tile Mate Thin Set Mortar Hydroment Flex-a-Lastic Flexible Mortar Additive 33SC Silicone Sealant, Clear Shur-StkC-11 Water Based Glue -Wall Covering Adhesive Form Powder jn 50 Ib • bags Liquid : Paste Clear Translucent Paste Quantity Stored or Used 500 Ibs 55 gal 24 tubes 200 gal m 2 qt containers Quantity Allowed per Control Area CFC Table 79Q2.5-A N/A N/A N/A N/A CFC Classification or Comments- Irritant (Portland cement) Dust No specific Fire Hazard Imtant Dust No specific Fire Hazard . Imtant Dust - No Specific Fire Hazard Local Exhaust or General Ventilation Recommended Non-Flammable Normal ventilation is adequate, no respiratory protection required rCFI CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) PageS Packing & Shipping Area Product fagtgfill Component A (two-part Soam-va place na>A aping imlraiais) T InstafiE, Component B & fastafffl Stow Rise Component B Hhkfrr/TtMhingu^ir SrJwnt Farm Liquid Clear, Straw Colored Ljqmd Clear liquid Quantity Stored or Used 210 gal 210 gal 10 gal f\ s*t\gmuufty Atteuedpcr Control Area CFC N.L N.L. NL CFCGasstfica&mand Commatte brilanl to ski0 and itspiiatoty system Water reactive if hot Other Health Hazards HI- B Combustible Tjqinj CFIariiP<mrt=390d^.F) User must wear itibber ^oves, safi^ygoggtesaudtcspiratorif VEotibboo is not adequate. Irritant jn-BCombqstarfcLkiuid (Flasb.Poufl=390deg.F) Other Health Hazards Contain all spills uTsaiit ffl- B Cooafaustible Liquid (Flash Ptso»t= 232 deg.F) Use eye protectwo, rubber gloves & ventilation i^ea in use PerUFC Table 7902.5-A (note 5), Class HI-B Liquids are not limited (NL) within spnnklered buildings Note: the Instafill fill system is a ck>se4 setf-conlained unit, which dispenses a two- part expansive foam packing material into polyethylene bags for a form fittmgpaeking material The unit is provided and serviced by an outside vendor Storage of Parts A & B are in 55 gallon drums, stored in the warehouse on special plastic tub style pallets provided by the manufacturer to contain any possible spills. . JCFI • CONSOLIDATEDm FIREPROTECTION , INC. o •8 so 1 I I 0 § a I £a 1 1 1 ? 8 •a; u '1 2 i 8,0- l s oI/I J J! CONSOLIDATED FIREPROTECTION INC. i <D O -8 I I I a'•fl 8 •a, li 1 8 I. :4 4^ I 1 s •a: cs I 8 s 1JSsi. •a, 1ll §•• o 8 • f" -„_ I I I I I i i i i i i i i i i CFI CONSOLIDATED FIREPROTECTION INC. 1 •8 00 PH ClSi uctAcacl§ u £ g skin, eyes and soft tissue. Wash hands oftedochemicash stationIl9 I I 75 i tetacWear approved NIOSH dust filter mask,Avoid inhalation of dust and fume, avoidt wwaeyenutes5shtation. Washical attention.seecontact with eyecontact with skin, use shogested or swallowedlean up with clean shovelspportIfIfIf iRe CFI CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Conf) Page 9 Allowable Exempt amounts: Aggregate quantities 'of materials for use are identified by hazard class in the following Summary of Hazardous Materials to Exempt Amounts per the Building and Fire Code Tables 3-D, 8001.15-C and BOOLl^D. Exempt Amounts of Hazardous Materials in Use in a Control Area: CT'f OasjjHicjrtion Cooosivss Irritants Sensitiaas Other Health IXQZ2BuS Toxics Carcinogens Oxidizes 1 Amount in Open Use 15 Ibs 5gal 4,000 Ibs 350 gal 0 3,5008*3 300 sal 125 Ibs (1.0 B»>* 1,1 10 Ibs 505 Ibs AHowabfe open use perCBC&CFC 2,000 Ibs 100 gal 10,000 Ibs " SOOgal 10,000 Has 10,000 Ibs 500 gal 250 Ibs (23 Ibs)* 5,000 Ibs 1000 Ibs AlBODBDEtlD Storage 150 Ibs 25 gal 92,950 Ibs 455 gal 0 54,150 Ibs 445gal 800 Ibs {21 Ibs)* 20,000 Ibs 4,000 OK Allowable Stored perCBC&CFC 10,000 Ibs SOOgal NL UOOOgal N.L. N.L 1,000 gal , 1,000 Ibs (500 fts)* 20,000 Ibs 4,000 B>s * Per UFC Table 8001 ]r5-D for gallons of hquids, divide the amount m Ibs by 10 calculations reflect the weight of liquids stored or used under Toxic category Exempt quantities have been increased as allowed for sprinMered buildings Hazardous Materials Handling and Use: All chemicals are stored and used in accordance with the respective manufacturer's written recommendations and procedures. Employees exposed to dust and flames shall be provided with protective clothing, protective rubber gloves, protective eyewear and appropriate dust masks and/or respirators. Showers and eye wash units shall be located within the Batch Room for use in emergency exposure cases. Protective paper over-suites are provided for workers within the Batch Room. Soiled suits are deposited in the Hazardous Waste disposal bin after each shift CFI CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cent) Page 10 Secondary Containment: Per CFC, Article 80, section 8003 1 3 3 - Secondary containment is required per Table 8003 1-A (attached) for the Toxics and Oxidjzers plus the volume of sprinkler system water for 20 minutes. This will be accomplished with an JTdyfce orierm constructed of water tight materials within the Batch Room. The floor will be epoxy coated and sealed with an 8" tile cove base Volume of chemicals (toxics & oxidizers) = 4,100 Ibs powder + 21 gal Jiquid Volume of fire sprinkler discharge = 45 gpm x 2,244 sqft = 1.010 gpm x 20nffliutes = 20,200 gallons Storage of Materials: Finished goods and packaging materials will be stored within the building's warehouse in storage racks to 20 ft. with 8 ft aisles Storage Array: Aisles Height of Storage - Type of Racks Commodity Class Ceiling Height >8ft 20 ft,max. Single and Double Row I 27ft Fire Protection: Per NFPA13,1999 edition, Figure 7-4221 (a) (attached) the prescribed density for non-encapsulated Class I commodities stored in racks to 20 ft with 286 degJ sprinklers and 8 ft aisles is 0.26 gpm/3,000 sq.ft. The existing fire sprinkler system was installed by Action Fire Systems, Fullerton, CA and is designed for 0 45gpm per sqft over the most demanding 3,,000 sqft of floor area Steel columns located within the storage racks are required to be protected in accordance with NFPA 13, Section 7-9.8 (attached). The tenant shall be required to add column sprinkler protection with sidewall sprinklers located 15 ft above the floor where steel columns are located with the rack-storage area General Fire Protection, and Life Safety Requirements: The rack storage area will be in accordance with CFC Article 81, Section 8102 including the following • Automatic Fire Extinguishing Systran • Buflding Access • Smoke and Heat Removal • Small Hose Valves and Stations I I CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 11 Smoke and Heat Removal/Curtain Boards Pursuant to Carlsbad Fire Department Policy and based on full scale fire testing performed by Factory Mutual Laboratories, we request permission tp omit draft curtain boards in this warehouse facility Small Hose Connections: Small hose connections are required per section 7-4. 1 .6. Per Carlsbad JFire Department Policy, it is requested that the hose, nozzle and rack requirements be waived. It is not recommended that employees attempt to fight a fire with 1 % inch hose lines in high pile stock areas The request to omit fire nose is based on the following points: * The fibre department carries hose packets and generally do not use building equipment * Employees are generally instructed not to use this equipment and to evacuate the building in case of fire * Maintenance of this equipment is difficult and therefore the integrity of the hose cannot be counted on. * This building is fully protected with a fire sprmjder system with a design density greater than, the minimum required for the use * Fire tat iHigi rushers are provided for mcnnent fires. - General Safety Practices J No smoking will be permitted in the building S AH employees wiU receive special training on the use «f portable fire extinguishers of the type to be provided in this building. An evacuation plan will be in place. S Exit doors will be maintained unobstructed and will be opened weekly to ensure their operation S Employees will be trained to handle small.spills and cleanup of hazardous materials used or stored within the facility. The Fire Department shall be notified of any and all hazmat spills and/or fires contained and cleaned up by employees S The following signage will be posted immediately outside and within the Batch Room, in English and Spanish languages: • All batch room workers must wear protective clothing, changed daily; dispose of suits in hazardous waste container daily. • Wear approved NIOSH dust filter mask, gloves and chemical protec4»£ eyewear. • ' Avoid inhalation of dust and fume. Avoid contact with skin, eyes and soft tissue. Wash hands often. • If contact with eyes, wash for IS minutes @ eyewash station. • If contact wtthsfcia, use shower station. Wash thoroughly with soap. • If ingested or swallowed, seek medical attention. • Report all spills. Clean up with clean shovel, wash with water, contain ait water and spilled chemicals, do not. sweep I I i i CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 12 Hydrates/Access Hydrants and fire department access roadways will continue to be maintained unobstructed and accessible to emergency response crews Exiting/Egress: The basic layout of the building is in conformance with the 1997 CBC. The travel distance from any point in the building to an exit does not exceed 250 feet All exit doors are ait least three feet wide and proper exit signs over each door will be provided fife extinguishers: ' , Minimum. 2A10BC rated fire extinguishers shall be provided for every 50 feet of travel distance. Conclusion/Recommendations: Our opinion is based solely upon our review of the proposed storage arrangements and hazardous materials storage or use as disclosed to me writer. Per the UfC, it is the Owner's responsablSty to determine material quantities mthin the buiMSng and report them to the Authority Having Jurisdiction. Any deviation from the descriptions provided or additional chemicals or flammables not disclosed will render tins report invalid Based upon me information provided and me recommendations contained in tins report, it is our opinion that Oceanside GlasstUe will be in full compliance with the requirements of the CBC and CFC 1997 editions If you have any comments or questions regarding this report or the. proposed use of this facility, please do not hesitate to contact the undersigned or the owner directly. Respectfully submitted, Robert President Attachments . OCEANSIDE GLASSTILE-2293 COSMOS CT PROJECT PROJECT DESCRIPTION Oceanside Glasstile proposes to install process machinery necessary for the manufacture of glass tile The installation consists of: 1. Two 3000 Ib capacity glass melting furnaces 2 Four induing machines with two exhaust blowers 3. One E W Bowman glass annealing lehr (kiln) 4. Three roof mounted air-circulating blowers One incoming fresh air and two exhaust blowers. The Bowman annealing kiln will be installed and test run by the manufacturer. The furnaces and iridizing machines are built by Oceanside Glasstile The furnaces are built on site with rated flame safety components and the iridizers are of proprietary design, also with complete flame safety components. Included is a cover letter from Industrial Furnace outlining their proposal to field certify the glass machinery and related venting The roof-mounted blowers will be inspected by the City Industrial Furnace OFMLNSAHD FURNACES 2081 S HELL MAM AVE, UNIT A ONTARIO, CA 91761 (909) 947-2449 January 25, 2001 City of Carlsbad Carlsbad, CA Attention1 Building and Safety Inspector Reference* Occanside Glasslile gas fired equipment Industrial Furnace has been commissioned by Oceausidc Glasstile to do a retro-fit inspection and overview of their gas fired equipment the wish to move from their current location to their new location inside the city limits of Carlsbad. The current equipment was inspected by us upon the original installation at the present location in Carlsbad. There will be a new pieces of equipment at the new facility along with the existing equipment All equipment will be inspected for NhPA 86 guidelines on fuel fired equipment The electrical will be inspected using NEC guidelines The preliminary report of the new equipment wtfl follow shortly and will detail the correct equipment configuration and supported by ISI'PA , UL, or AGA documentation or issue numbers We hope this will be a satisfactory procedure to allow Oceansidc Glasstile to move forward and obtain the necessary permits from the City of Carlsbad Regards, Craige Sriaw Industrial Furnace cc Occanside Glasstile I I I I i Industrial Furnace MAHUFA CTURERS OF KILNS AHD FURHA CES 2O81 S HELLMAM AVE, UNIT A OHTARIO. CA 91761 (714) 947 2449 ceanside City Building and Safety ceanside, CA ttention: Building and Safety Inspector • Industrial Furnace has been commissioned by Oceanside Glasstile to do anInspection and overview of their gas fired glass melting furnace located t 614 S. Cleveland St., Oceanside, CA. We are therefor submitting our report to you with a copy to Don Petty, of Oceanside Glasstile, to assist tim in obtaining permits from the City of Oceanside for the above entioned furnace. • The furnace incorporates a single Eclipse, Model No. 54 NM, burner with a J ximum input of 360,000 BTUH. The burner is equipped with a pilot burner r main flame ignition. The pilot fuel regulator is cross connected to the combustion air supply to maintain proper fuel/air in the event of ^imbustion air fluctuations. Furnace is outside of the building and .no •Loser than 60 inches to a combustible material. Flame supervision and ^as safety system is in accordance with NFPA 86, Ovens and Furnaces. The equipment is as follows: I I i I i i i COMBUSTION SAFEGUARDS 1.1 Flame Safety System: Protection Controls Form 6642 single burner Protectofler. FM and IRI approved and UL recognized. 30 second prepurge with a 15 second ignition trial. 1.2 Flame Sensing; 1.3 Ignition: Protection Controls PC-II Ultra- violet scanner to monitor the intersection of the pilot and main flame per NFPA 4-7.4.1, exception 1. Scanner is FM approved and UL listed Spark ignited by a Dongan UL inter- changeable ignition transformer. Issue Number C-6488. Industrial Furnace MANUFACTURERS OF KILNS AND FURNACES 3.0 FURNACE CONSTRUCTION 3.1 Frame:The frame follows traditional furnace design techniques. Extremely rigid to to support the weight of the refractories and the product being processed, yet flexible enough to allow for the expansion of the refractories. 3.2 Refractories 3.3 Flue: 3.4 Vent: 3.5 Damp er: 3.6 Auxiliary Equipment; The furnace lining is constructed of commercial firebrick, insulating fire- brick, castables, as well as ceramic fiber insulation. Calculated cold face temperatures with 2350 F. internal temperatures are attached. Attached heat shields will reduce the external temperature even more., At 360,000 BTUH input, required flue area is 36 square inches. (1 sq. in. per 10,000 BTU input). Adequate area is provided with 64 square inches on this furnace. Vent pipe is completely exposed and does not penetrate combustable material nor is it close to any combustable material. Vent pipe is secured firmly to furnace and building structure. NFPA 2-2.4.1 and 2-2.4.2. Flue damper is pinned so that it may not be closed beyond minimum area for proper and safe ventilation. (36 sq. in.) NFPA 2-2.4.9 Associated safety and control equip- ment is mounted near the furnace and under a roofed area for protection from the elements. Equipment mounted near the furnace is protected from heat by means of a sheet metal heat shield. Adequate area is provided to allow service to such equipment. NFPA 2-2.5.1 and 2-2.5.2. C, O C. J< #: wJ 1 «... 1- i Ji •», ., .11 l"« li IJ IL_ *•*« 1" X HI Hi ii-" iN' 1 1 0 1 .3 C T tJ JL> Z VA j> i: v 3. T.J; i. n j II-P " or »"» «.: i )• E-. i < i«i cs i T i H c., . 37 E- AD . ii'-I!: ih. rt I LOW AiiAL *i 51G/ PC VCI' CQIIDITIQHS : ROOF ATMOSPHERE ». 5'fAHDAPL APIblENT TCPIF: LH i£HlSS1Vir. J @.?5 -'tL-JCHi ' 3 FI'S I I i i I I i i i i I i l!r PlL Ili-nlljr Ai,i LH-L-.K ^.SQ IN KAOLlTE ISrtH b'AffCGCK * WILCOX Hf" ?J50 F 4.00 IN KUL BLKT Bin ni- BABCOCK & UILCOX 1F1 1705 F COLD f-ACE 223 F. HEAi LU33 38a ETLi/SF/HF,. HEAT STORAGE 16010 BTU/oF «JB C O C K -»i W JL L_ «... i, j x , X 8 ^ £> U II _ u-'-l.1 X Ml O S"'» < O D U t, 1 ii II> 1. V JL> JL V 1 t-J i. il * -i! Oil-" J'J c: 1> LR a»IIO"ll "I JLI-KJ- bl.il. '-idTl FuOW AIIAI.VGIS/1'C Vtl'SIGN 0 FPb CONDITIONS : WALL. AHBIEHT TE.MFS S>® NANL IN B&W SPi I-C 2.50IN K-26 Li II K BADCOCK S U1LCOX BABCOCK * W1LCOX Hi: 2J50 h in 18^4 F COLD FACL HEAT LOSS HEAT SrOKACE •403 f-. 1122 B1U/SF/HK. 52J3 DIU/SF 2— 26— O1 , I l^U C-U S 34AM 85S 65O , UU'0<J 1111 Ill CONTROL NO.189845 COUNTY OP SAN DIEGO, AIR POLLUTION CONTROL DISTRICT 9150 CHESAPEAKE DRIVE, SAN DIEGO, CA 92123-1036 (858)650-4700 FAX(8S8)650-4659 CERTIFICATE OF EXEMPTION CERTIFICATE975087 EXPIRES EXEMPT THE FOLLOWING IS HEREBY GRANTED AM EXEMPTION PROM PERMIT REQUIREMENTS PURSUANT TO RULB 11 (d) (19) (XVIII} FOR THE ARTICLE .MACHINE, EQUIPMENT OR CONTRIVANCE DESCRIBED B^'OW. THIS CERTIFICATE IS NOT TRANSFERABLE TO A NEW OWNER NOR IS IT VALID FOR OPERATION OF THE EQUIPMENT'>\T ANOTHER LOCATION, EXCEPT AS SPECIFIED. THIS CERTIFICATE OF EXEMPTION OR A COPY MUST BE POSTED ON OR WITHIN 2S FEET OF THE EXEMPT EQUIPMENT/PROCESS OR BE READILY AVAILABLE ON THE OPERATING PREMISES OCEANSIDE GLASSTILE CO VP PETTEY DON 3235 TYLER ST CARLSBAD CA 92008-0000 EQUTPMBMT ADDRESS OCEANSIDE GLASSTILE CO 3235 TYLER ST CARLSBAD, CA 92008-0000 I I I I I I I I I I BQTJIPMEOT BBSCRIPTION DECORATIVE AND ORNAMENTAL GLASS TILE MANUFACTURING OPERATION USING THREE GLASS MELTING FURNACES AND ONE ANNEALING OVEN. Sector*.15 ID#.07267A PO#-975087 BEC#:10614 Fee Schedules- COSOl EVERY PERSON WHO OWNS OR OPERATES THIS EQUIPMENT IS REQUIRED TO COMPLY WITH THE CONDITIONS LISTED BELOW AND ALL APPLICABLE REQUIREMENTS AND DISTRICT RULES, INCLUDING BUT NOT LIMITED TO RULES 2, 10, 11, 40, 50, 51, 67.17. TO OPgRKCB I» COMPLIAHCB 13 A MISDEMEANOR 3UBJHCT TO CIVIL ASP OtlMIKM. THE EQUIPMENT SHALL BE OPERATED ACCORDING TO THE MANUFACTURER'S INSTRUC- TIONS/RECOMMENDATIONS AND AS DESCRIBED IN THE CERTIFICATE OF EXEMPTION APPLICATION SUBMITTED TO THE DISTRICT THIS CERTIFICATE OF EXEMPTION SHALL ONLY APPLY TO THE EQUIPMENT DESCRIBED ABOVE. THE DISTRICT RESERVES TBS RIGHT TO CHANGE THE EXEMPTION STATUS OF THE ABOVE EQUIPMENT/PROCESS AT ANY TIME. THE FACILITY WILL BE NOTIFIED AT LEAST 30 DAYS IN ADVANCE OF ANY CHANGES WHICH MAY AFFECT THE EXEMPTION STATUS OF THE ABOVE EQUIPMENT/PROCESS. ' ' THIS CERTIFICATE OF EXEMPTION MUST BE MAINTAINED WITH THE EXEMPT EQUIP- MENT/PROCESS OR BE READILY AVAILABLE AT ALL TIMES. THIS AIR POLLUTION CONTROL DISTRICT CERTIFICATE OF EXEMPTION DOES NOT RELIEVE THE HOLDER FROM OBTAINING PERMITS OR AUTHORIZATION REQUIRED BY OTHER GOVERNMENTAL AGENCIES OR FROM COMPLYING WITH APPLICABLE DISTRICT RULES AND REGULATIONS, STATE AND FEDERAL LAW. Hazardous Material. • SAN DIEGO REGIONAL . -.,-,'%»''• J.'J ' < Ilanagement Division ctssTr tr ««• in*« Business Name "Contact Person Telephone Mailing Address City State ip Plan File* ST. Sit« Address City State Zip cry. o*yijs£ftO 0s Plan File* I I ART I PtRE DEPARTMENT - HAZARDOUS MATERIALS MANAGEMENT DIVISION: OCCUPANCY CLASSIFICATION dicatu by circling the item. whether your business will use. precast, or store any of tha following hazardous matanals If any of tha items are irclad, applicant must contact tha Fira Protaetion Agency with (unadiction prior to plan •ubrmttal. Explosive 6r Blasting Agents 4. Flammable Solids Compressed Geses 5. Organic Peroxides t Flammable or Combustible Liquids 6. Oxidizers 7. Pyrophorics 10. Cryogenics 8. Unstable Reectives 11. Highly Toxic or Toxic Materials 9. Water Reactlves 12. Radioactives 13. Corrosive* 14 Other Health Hazards Ime I i IART n COUNTY OF SAN DIEGO HEALTH DEPARTMENT • HAZARDOUS MATERIALS MANAGEMENT DIVISION: loNTINGENCY PLAN REVIEW. tha answer to any of the question* ie yes, applicant must contact the County of Sen Diego Hazardous Matanals Management ivision, 1255 Imperial Avenue, 3rd Floor. San Diego, CA 92186-5261. Telephone (619) 338-2222 pnor to the issuance of a tiding permit. ES MAY BE REQUIRED Yes No Is your buslneee listed on tha reverse side of this form? ', £P, Will your business dispose of Hazardous Substances or Medical Waste in any amount? '.„ ", Will your business store or 'handle Hazardous Substances in quantities equal to or greater than 55 j SOO pounds, 20O cubic feat or carcinogens/reproductive toxins in any quantity? Will your business use an existing or install an underground storage tank? Will your business store or handle Acutely Hazardous Materials? ; llons, fS -,ts .--, - OFFICE USE ONLY [""] RMPP Exempt Date Initials RMPP Required Dete Initials f] RMPP Completec Date Initials ( 'ART III- SAN DIEGO COUNTY AIR POLLUTION CONTROL DISTRICT ? 1 ~'_ O . C ' tha answer to any of tha questions la yes, applicant must contact the Air Pollution Control District, 9150 Chesapeake Dnve, San Diego, CA 92123 elephon* (619) 694*3307 pnor to tha issuanca of • building permit. YES NO f—"1 r~1 Will the intended occupant Install or use any of tha equipment listed on the Listing of Air Pollution Control District Permit Categories, on th« reverse aide of this form? p—I r~l (ANSWER ONLY IF QUESTION 1 IS YES.) Will the subject facility be located Within 1,000 feet of the outer boundary of a school (K through 12) as listed in tha current Directory of School and Community College Distncts, published by the San Diego County Office of Education anc the current California Private School Directory, compiled In accordance with provisions of Education Code Section 3319O? iney business activity: JL llame of Owner or Authonzed Agent: »l I I iignatura of Owner or Authorized Agent: I declare under penalty of perjury that to the best of my knowledge end belief the responaea made herein are tru nd correct. . Date- o not write below this line IRE DEPARTMENT OCCUPANCY CLASSIFICATION:. Y. ironmenul Hettth Sennet HS HM-9171 (6V92) INL.I ll_ll I lUUOJTOU 01 fO f . JL I I Fax To: Don Pettey Of: Oceanside Glass Tile Fax: (760) 434-0590 Phone: ((760) 434-0051 x!06 Pages: 11, including this cover sheet. Date: February 7,2001 Don t* Please find attatched draft results of emissions testing conducted at yor facility on January 14,2001. I have sent a copy to Bill Powers These results are subject to a final review before becoming final. Please call me at (805) 498-8781 if you have any questons Robert Carrier From the desk of Horizon Air Measurement Services, Incorporated 996 Lawrence Dive Suite 108 Newbury Park, California 93021 (805) 498-8781 Pax (805)498-8781 IN JL £. U I I IIJ.IN I 11_ I I %J u IX l_ | TABLE 1 Stack Gas Characteristics and Emission Rates Furnace #2 Oceanside Glass Run Number Date Run Start Time Run End Time Stack Gas Characteristics Stack Temperature Moisture Fixed Gases, CO2 02 N2 Stack Velocity Volumetric Flowrate Volumetric Flowrate IsohneUc Ratio Total Farticulare Emissions Concentration PmlO Emission Rate Hydrogen Chloride Emissions Concentration Emission Rate Hydrogen Flouride Emissions Concentration Emission Rate ****** ****** ****** ****** F % % % % afpin dscfm acfm % gr/dscf g/dscf Ib/hr mg/dscf Ib/hr mg/dscf Ib/hr 1 01/14/01 1110 1213 268 17 00 209 79 1 803 2809 3878 94 00139 QUQQ93.& 0335 < 0000002 < < 0 000001 < 5378 1998 2 01/14/01 1340 1440 282 26 00 209 791 739 2512 3566 96 00136 0.000918 0293 0000002 0000001 6899 2293 3 01/14/01 1730 1830 295 35 00 209 791 711 2353 3432 96 00136 QJQQQ882 0275 < 0 000003 < 0000001 5.333 1.660 Average 282 26 00 209 79 1 751 255R 3625 96 00137 CLQOQ912 0301 < 0000002 < 0000001 5870 1984 Horizon Air Measurement Services, Inc MS 421EMITBL.-F2 TABLE 2 Stack Gas Characteristics and Emission Rates Furnace #3 Oceanside Glass Run Number Date Run Start Time Run End Tune Stack Gas Characteristics Stack Temperature Moisture Fixed Gases, CO2 02 N2 Stack Velocity Volumetric Flowrate Volumetric Flowrate Isokinebc Ratio Total Particulate Emissions Concentration PmlO Emission Rate Hydrogen Chloride Emissions Concentration Emission Rate Hydrogen Flouride Emissions Concentration Emission Rate ****** ****** ****** ****** F % % % % afpm dsofin acfrn % gr/dsct g/dscf Ib/hr mg/dscf ib/hr mg/dscf Ib/hr 1 01/14/01 1115 1221 285 19 00 209 791 737 2513 3556 99 000073 Q.QOQQ49 0016 < 0000002 < < 0000001 < 07179 02386 2 01/14/01 1255 1430 291 21 00 209 791 735 2482 3546 100 0 00923 Q-QQQ623 0 196 0 000002 000000 1 I 111 03648 3 01/14/01 1715 1820 288 33 00 209 791 688 2304 3321 105 00142 QJJQQ922 0281 < 0 000002 < 0000001 04579 0 1395 Average 288 24 00 209 791 720 2433 3474 101 00081 0 000531 0164 < 0000002 < 0000001 07624 02477 Horizon Air Measurement Services, Inc M5_421EMim-r3 TABLE 3 Stack Gas Charactenstics-Particulate Emissions Furnace #4 Oceanside Glass *%*•*Is* * Run Number Date Run Start Time Run End Time Stack Gas Characteristics Stack Temperature Moisture Fixed Gases, CO2 O2 N2 Stack Velocity Volumetric Flowrate Volumetric Flowraie Isohnefcc Ratio Total Particulate Emissions Concentration Concentration PmlO Emission Rate Hydrogen Chloride Emissions Concentration Emission Rate Hydrogen Flouride Emissions Concentration Emission Rate ****** ****** ****** ****** F % % % % afpin dscfin acfrn % gr/dscf g/dscf Ib/hr mg/dscf Ib/hr mg/dscf Jb/hr 1 01/14/01 1100 1208 296 15 00 209 791 659 2224 3183 99 00246 oomee 0468 < 0 000003 < < 0000001 < 1013 2981 2 01/14/01 1255 1400 293 3 1 00 209 791 678 2260 3273 99 00261 &W176 0505 0 000003 0000001 8217 2456 3 01/14/01 1645 1755 282 32 00 209 791 658 2222 3178 101 00293 0 9CH 90 0557 < 0 G00003 < 0000001 7402 2175 Average 290 26 00 209 791 665 2235 1211 100 00266 00&177 0510 < 0000003 < 0000001 8584 2537 Hot'ran Air Measurement Service*, Inc M5 421EMITBL-F4 I TABLE 4 Stack Gas Charactenstics-Particulate Emissions Ambient- Roof Vent Oceanside Glass Run Number Date Run Start Time Run End Tune Stack Gas Characteristics Moisture Fixed Gases, CO2 O2 N2 ****** ****** ****** ****** 1 01/14/01 1154 1259 10 2 01/14/01 1332 1432 13 3 01/14/01 1630 1730 15 Average 13 00 209 791 00 209 791 00 209 791 00 209 791 Hydrogen Chloride Emissions Concentration Hydrogen Flouride Emissions Concentration mg/dscf < 0000002 < 0000002 < 0000002 < 0000002 mg/dbcf 01362 01412 00920 01231 Horizon Air Measuremont Servkes, Inc.MS.421EMITBL AM I IU IX A C. w I I I I J, IS 41 ± /o L** a, SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL AVG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H DGMCALIB FACTOR [Y] WATER COLLECTED CO2 02 CO CH4 N2 STACK AREA STATIC PRESSURE PITOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULAR WT DRY EXCESS AIR MOLECULAR WT WET STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOWRATE, DRY STD VOLUMETRIC FLOWRATE, ACTUAL ISOKINETIC RATIO STD TEMP ****** ****** ••""" ****** Degrees F Inches H20 Inches Inches HG Minutes Cubic Feet Degrees F Inches H20 ****** Millihters Percent Percent Percent Percent Percent Square Inches Inches WG ****** DSCF SCF Percent ****** Ib/lb Male Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 68 1 1/14/01 1110 1213 268 02039 0495 3040 60 43499 67 168 09900 16 00 209 791 6951 -001 084 4400 08 17 098 2834 118750 2865 3040 803 2809 3878 94 Furnace 2 2 1/14/01 1340 1440 282 : 01855 0495 ; 3040 60 39963 70 ! 138 09900 23 i 00 209 I 791 6951 , 001 084 4021 , 11 26 097 2884 118750 2855 3040 739 2512 3566 ; 96 CALCULATIONS EOS GRAIN LOADING AND EMISSION RATES TOTAL PARTICULATE PARTICULATE CONCENTRATION PARTICULATE EMISSION RATE HYDROGEN CHLORIDE HYDROGEN CHLORIDE CONCENTRATION HYDROGEN CHLORIDE EMISSION RATE HYDROGEN FLOURIDE HYDROGEN FLOURIDE CONCENTRATION HYDROGEN FLOURIDE EMISSION RATE mg gr/dscf Ib/hr mg mg/dscf Ib/hr mg mg/dscf Ib/hr 397 00139 Q335 < 00001 < < 0000002 < < 0000001 < 2366 5378 1998 355 00136 ' 0293 00001 < 0000002 < 0000001 < 2774 6899 I 2293 : 3 1/14/01 1730 1830 295 01766 0495 3040 60 37315 68 125 09900 29 00 209 791 6951 -001 084 3767 14 35 096 2884 118750 2846 3040 711 2353 3432 96 333 00136 0275 00001 0 000003 0 000001 2009 5333 1660 Horizon Air Measurement Services, Inc M5.421EMITBt.-FZ IV j. e. u i i lUU^jJTOU O J. f o SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL MG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H DGMCALia FACTOR [Y] WATER COLLECTED CO 2 02 CO CH4 N2 STACK AREA STATIC PRESSURE PITOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULAR WT DRY EXCESS AIR MOLECULAR WT WET STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOWRATE, DRY STD VOLUMETRIC FLOWRATE, ACTUAL ISOKINETIC RATIO STD TEMP ****** ****** ****** ****** Degrees F Inches H20 Inches Inches HG Minutes Cubic Feet Degrees F Inches H20 ****** Milliliters Percent Percent Percent Percent Percent Square Inches Inches WG ****** DSCF SCF Percent ****** Ib/lb Mole Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 68 1 1/14/01 ins 1221 285 01848 0501 3040 60 41238 67 137 10034 17 00 209 791 6951 002 084 4225 08 19 098 28 84 118750 2863 3040 737 2513 3556 99 Furnace3 2 1/14/01 1255 1430 291 01835 0501 3040 60 41613 72 122 10034 19 00 209 791 6951 -003 084 4221 09 21 098 2884 118750 2861 3040 735 2482 3546 100 CALCULATIONS FOR GRAIN LQADJNG AND EMISSION RATES TOTAL PARTICULATE PARTICULAR CONCENTRATION PARTICULATE EMISSION RATE HYDROGEN CHLORIDE HYDROGEN CHLORIDE CONCENTRATION HYDROGEN CHLORIDE EMISSION RATE HYDROGEN FLOURIDE HYDROGEN FLOURIDL CONCENTRATION HYDROGEN FLOURIDE EMISSION RATE mg gr/dscf Ib/hr mg mg/dscf Ib/hr mg mg/dscf Ib/hr 20 0 00073 0016 < 00001 < < 0000002 < •= 0000001 < 3033 07179 02386 253 0 00923 0196 00001 < 0000002 < 0000001 < 4691 11115 03648 3 1/14/01 17-15 1820 288 01718 0501 3040 60 40322 69 1 06 10034 30 00 209 791 6951 -002 084 4114 14 33 097 2884 118750 2848 3040 688 2304 3321 105 380 0014? 0281 00001 0 000002 0 000001 1883 04579 01395 Horizon Ah Mwiucement Services, Inc IN X C. «J I I I I J. IX I 1L_ | | o U IV l SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL AYG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H DGMCALIB FACTOR [Y] WAFER COLLECTED CO 2 02 CO CH4 N2 STACK AREA STATIC PRESSURE PITOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULAR WT DRY EXCESS AIR MOLECULAR WT WET STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOWRATE, DRY STD VOLUMETRIC FLOWRATE, ACTUAL ISOKINETIC RATIO STO TEMP ****** ****** ****** H«»«-H' Degrees F Inches H20 Inches Inches HG Minute; Cubic Feet Degrees F Inches H20 ****** Milfihters Percent Percent Percent Percent Percent Square Inches Inches WG ****** DSCF SCF Percent ****** Ib/lb Mole Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 68 1 1/14/01 1115 1221 285 01848 0501 3040 60 41238 67 137 10034 17 00 209 791 6951 -002 084 4225 08 19 098 2884 118750 2863 3040 737 2513 3556 99 Furnace 3 2 1/14/01 1255 1430 291 01835 0501 3040 60 41613 72 122 10034 19 00 209 791 6951 -003 084 4221 09 21 098 2884 -118750 2861 3040 735 2482 3546 100 CALCULATIONS. FQP- GRAIN LOADING AND EMISSION RATES TOTAL PARTICULATE PARTICULAR CONCENTRATION PARTICULATE EMISSION RATE HYDROGEN CHLORIDE HYDROGEN CHLORIDE CONCENTRATION HYDROGEN CHLORIDE EMISSION RATE HYDROGEN FLOURIDE HYDROGEN Fi OURIDE CONCENTRATION HYDROGEN FLOURIDE EMISSION RATE mg gr/dscf Ib/hr mg mg/dscf Ib/hr mg mg/dscf Ib/hr 20 0 00073 0016 < 00001 < < 0000002 < < oooooai < 3033 07179 02386 253 0 00923 0196 00001 < 0000002 < 0000001 < 4691 11115 03648 3 1/14/01 1715 1820 288 01718 0501 3040 60 40322 69 1 06 10034 30 00 209 791 6951 -002 084 4114 14 33 097 2884 118750 2348 3040 688 2304 3321 105 380 00142 0281 00001 0 000002 0 000001 1883 04579 01395 Horizon Air Measurement Services, Itic M5_421E»IITBL-F3 I IJL IS I I L. I I %J U IN L. I 11_ I I I I I I I I I I I I I I I I I I I I SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL AVG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H DGMCALIB FACTOR [Y] WATER COLLECTED CO 2 02 CO CH4 N2 STACK AREA STATIC PRESSURE PITOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULAR WT DRY EXCESS AIR MOLECULAR WT WET STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOWRATE, DRY STD VOLUMETRIC FLOWRATE, ACTUAL ISOKINETIC RATIO STD TEMP 68 CALCULATIONS FOR GRAIN LOADING AND EMISSION RATES TOTAL PARTICULATE mg PARTICULATE CONCENTRATION gr/dscf PARTICULATE EMISSION RATE Ib/hr HYDROGEN CHLORIDE mg HYDROGEN CHLORIDE CONCENTRATION mg/dscf HYDROGEN CHLORIDE EMISSION RATE Ib/hr HYDROGEN FLOURIDE mg HYDROGEN FLOURIDE CONCENTRATION mg/dscf HYDROGEN FLOURIDE EMISSION RATE Ib/hr Furnace 4 ************ ****** ****** Degrees F Inches H20 Inches Inches HG Minutes Cubic Feet Degrees F Inches H20 ****** Milliliters Percent Percent Percent Percent Percent Square Inches Inches WG ****** DSCF SCF Percent ****** Ib/lb Mole Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 1 1/14/01 1100 1208 296 01643 0491 3040 60 34960 62 108 10001 12 00 209 791 6951 -001 084 3605 06 15 098 2884 -118750 2867 3040 659 2224 3183 99 2 1/14/01 1255 1400 293 01688 0491 3040 60 36068 69 114 10001 25 00 209 791 6951 -001 084 3672 12 31 097 2884 118750 2850 3040 678 2260 3273 99 3 1/14/01 1645 1755 282 01650 0491 3040 60 35505 63 109 10001 26 00 209 791 6951 001 084 3653 12 32 097 2884 118750 2848 3040 658 2222 3178 101 575 00246 0468 < 00001 < < 0000003 <; < 0000001 < 3652 1013 622 00261 0505 00001 < 0000003 < 0000001 < 3017 8217 2456 694 00293 0557 00001 0 000003 0 000001 2704 7402 2175 Horizon Air Measurement Services, Inc M5.421EMITBL-Ffl iow«jj-rwu ^p j. r *j P <** SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL AVG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H DGMCALI8 FACTOR [Y] WATER COLLECTED CO 2 02 CO CH4 N2 STACK AREA STATIC PRESSURE PITOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULAR WT DRY EXCESS AIR MOLECULAR WT WET STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOWRATE, DRY STD VOLUMETRIC FLOWRATE, ACTUAL ISOKINETIC RATIO STD TEMP Ambient Air- Roof Vent «"""«» ****** '"""' ****** Degrees F Inches H20 Inches Inches HG Minutes Cubic Feet Degrees F Inches H20 ****** Mifhliters Percent Percent Percent Percent Percent Square Inches Inches WG ••"«« DSCF SCF Percent ****** Ib/lb Mole Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 68 1 1/14/01 1154 1259 NA NA NA 3040 60 63988 72 300 09973 14 00 209 791 NA NA NA 6479 07 1 0 099 2884 118750 2873 3040 NA NA NA NA 2 1/14/01 ; 1332 1432 NA NA NA 3040 : 60 59326 72 ' 300 09973 17 : 00 209 791 NA ; NA NA 6008 08 13 099 2884 ; -118750 2869 3040 NA NA NA NA 3 1/14/01 1630 1730 NA NA NA 3040 60 59174 69 300 09973 19 00 209 791 NA NA NA 6028 09 15 099 2884 -118750 2868 3040 NA NA NA NA CALCUlATIfltJS FOR GRAIN LOADING AND EMISSION RATES HYDROGEN CHLORIDE HYDROGEN CHLORIDE CONCENTRATION HYDROGEN FLOURIDF HYDROGEN FLOURIDE CONCENTRATION mg mg/dscf mg mg/dscf * 00001 < < 0000002 < a 826 01362 00001 < 0000002 < 8486 01412 00001 0 000002 5545 00920 Horizon Air Measurement Services, Inc M5_421EMrrBL-AM ML.lfOUIXL.IIL.ll I I I I I FACILITY: 0e&H&to>& «EM-*c.S JOB NO : ?3t,-I Tstd = gg" »F Pstd = 29.92 u>./Hg STACK GAS MOISTUHE CALCULATION SOURCE: FcnzKWCg" *fe^L, TESTDAT HUN*: / _ I Volume of nraple at standard conditions, dry basis v ^Vmstd = 29 92 (Tm + 460) ,«7<JWhere, Vm — dry gas meter volume, fV* ' Y <• DOM calibration factor £ to Pin = average AH, in HjO * A I Volume of water vapor in sample at standard conditions Vwstd - 004715 x Vw Where, Vw - water volume, mlIFractional atoisture content of stack gas (460 + £&* Tsd) (Y) (Vrri) (Pb — - *"* Pb = borometnc pre«sure, in Kg •*• 3 O. */ ^ Tm - tempemhUQ of meter, *F ,. 6 ^-i = ^-ly*"//•/O scf 1 Tstd = e^& "F • Pstd = 29.92 in./Hg • STACK VOLUME FLOW RATE CALCULATION SUMMARY _ FACILITY. ,t?d&k*\ **£>& & C*-JS JOB NO.- ?> * 1 • SOURCE n^oWkoe* *£, TEST DATE: a»t RUN*' / Dry molecular weight of stack gas Afwf=0.44 (%CO,)+032 (%O,)+0.28 (%W,+%C0)^ i' 2. _*' y ^ 'e,&& ?-*'*i *pr-r Molecular weight of stack gas, wet basis M / \ f i^\ i n si l^\ * = (MW/ * Mrf> + l8 (I -Af^ •Pfc- 3, _ 100 - JAM** /-^Si^H« ^ ^^^ iJ =rrnere, m.^ - — — *. u/-"7^ x f ( lUU Pitot tube coefident C (calibration curve) Standard = 0.99 S-Type = 0 84 Average velocity head of stack gas, inches H^O (A/A/O avg ~\1 ^** 1 O ; Average absolute stack gas temperature (r> avg. = °F + 460 =! N J^ ^^ • Absolute stack gas pressure C~ &• e^> ^J P, = PB + (ftfa^/lSe) **>O.W + ~~^£ (Pstal = todies ftffi Where PB = barometric pressure Stack gas velocity CK) crvr ("5130^ C x i/A? 4vz x /T" OVP x ( ^ )iri \r ft "VK V.-"-'vV '"p A V-" "'a \f s o p A>f ' "j X ^*wr^-Ts-^ v i //./v *Stack gas volume flow rate i ^ -£— J Ir J / ' ^ ' Q ^ V A (A =H.&2.*z,\ft2)*^n ft * J * ****' •T'J •> ' Stack gas volume flow rate, dry basis (460 * r J x ^ x Mrf x F, (^ a*; I ~°f •^/V/^ I •« g 1 ^^.^"S^, Ib/lb-mole I ^-^^5^5» Ib/lb-mole • I &&~f | • f\ ~3 -— ^ *5t^X-e?^*? |•1 "^i-S-S -R 1 30.Y00 mHE 1" W 1 ^(gS. S^ ft/mm | ^i ^^s« j—k IB"5^'^T. «9 acfm 1 •aa^^ 1 clscfm I • 1 CALCULATION DATA SHEET ^- C Horizon Air Measurement Services, Inc 13-92 INSTALLATION OF SPRINKLER SYSTEMS Table 7-4.2.1.5 Single- or Double-Row Racks — Storage Height Up to and Including 25 ft (7 6 m) Without Solid Shelves Height •""3 Over 12 ft (3 7 m), up to and including 20ft (6 1m) Over 20 ft (6 1 m), up to and including 22 ft (6 7m) Commodity Class — ^ > I II HI rv i ii m rv £ncap- sulate< No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes Aisles ft *8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 4 8 m *i 2 1^ 24 12 24 12 24 12 24 12 24 12 24 12 24 12 24 12 24 12 24 12 24 12 24 12 24 12 24 12 24 Sprinklers Mandatory In-Racks No No No No No 1 level No 1 level No 1 level No 1 level No 1 level No 1 level Ceiling Sprinkler Water Demand With fa-Rack Sprinklers Figure 7-42211(a) 7-42211(e) 7-42211(b) 7-42211(e) 7-42211(c) 7-42211(f) 7-42211(d) 7-42 21 l(g) 7-42211(a) 7-42211(e) 7-42211(b) 7-4 2 2 1 1 (el 7-4 2 2 1 1 (e.) 7-4 2 2 1 1 1 f> 7-42 21 Hil\ 7-4 2211 (o\I-* 4411. (g) Curves CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB CandD AandB Apply Figure 7-4.2.2.1.3 j^^>"~ r Yes No Without fa-Rack Sprinklers Figure 7-42211(a) 7-42211(e) 7-42211(b) 7-42211(e) 7-42211(c) 7-42211(d) 7-42211(a) 7-4 2211 (\*\ 7-4221 1 Ccl 7-4 221 Hdl Curves FandH EandG GandH EandF GandH EandF GandH EandF GandH EandF — GandH EandF FandH EandG — GandH EandF GandH EandF GandH EandF Apply Figure 7-4.2.2.1.3 Yes Yes Yes Yes Yes Yes Yes — Yes Yes Yes I 1999 Edition DESIGN APPROACHES 13-95 Figure 7-4.2 2 1 1 (a) Sprinkler system design curves — 20-ft (6 1-m) high rack storage — Class I nonencapsulated commodities—conventional pallets. 41 Ceiling sprinkler density (mm/mm) 81 102 122 143 163 Curve Legend Curve Legend 183 6000 5000 4000 3000 2000 1000 557 Single point— design only; ~ ~_ 93 015 02 025 03 035 04 Ceiling sprinkler density (gpm/ft2) 045 A — Slngle-or double-row racks with 8-ft (2 44-m) aisles with 286°F (141°C) celling sprinklers and 165'F(74°C) in-rack sprinklers B—Single-or double-row racks with 8-ft (2 44-m) : aisles with 165°F(74«C) ceiling sprinklers and 165^(74-0) In-rack sprinklers C— Single-or double-row racks with 4-tt (1 22-m) aisles or multiple-row racks with ' 286"F(141 °C) ceiling , sprinklers and 165°F (74°C) in-rack sprinklers D—Single-or double-row racks with 4-ft (1 22-m) aisles or multiple-row racks with i 165"F(74°C) ceiling sprinklers and 165°F (74»C) In-rack sprinklers E— Single-or double-row racks with 8-ft (2 44-m) aisles and 286°F (141°C) celling spnnklers F— Slngle-or double-row racks with 8-1t (2 44-m) aisles and 165°F(748C) ceiling sprinklers G — Slngle-or double-row racks with 4-ft (1 22-m) aisles and 286"F(141 «C) celling sprinklers H—Single-or double-row racks with 4-ft (1 22-m) aisles and 16S'F (748C) ceiling sprinklers /— Multiple-row racks with 8-ft (2 44-m) or wider aisles and 286'F (141 °C) ceiling sprinklers J— Multiple-row racks with 8-ft (2 44-m) or wider aisles and 16S«F(74'C) celling sprinklers figure 7-4.2.2 1 l(b) Sprinkler system design curves—20-ft (6 1-m) high rack storage — Class U nonencapsulated commodities—conventional pallets 6000- 5000- 4000- 3000- 2000- Ceiling sprinkler density (mm/mm) 81 102 122 143 163I I BC\ D E FG\ H Curve Legend Curve Legend 183 20 4 tooo 010 015 020 025 030 035 040 Ceiling sprinkler density (gpm/ft2) 045 050 A — Single-or double-row racks with 8-ft (2 44-m) aisles wrth286°F(141°C) ceiling sprinklers and 165°F(74°C) In-rack spnnklers B—Slngle-or double-row racks with 8-ft (2 44-m) ' aisles with 165°F(74°C) ' ceiling sprinklers i and165°F(74°C) : in-rack sprinklers C—Single-or double-row racks, with 4-ft (1.22-m) aisles or multiple-row racks with ' 286°F(141 -C) celling : sprinklers and 1650F(74°C) In-rack sprinklers , 0— Single-or double-row racks with 4-ft (1 22-m) aisles or multiple-row racks with 165°F(74°C) ceiling i sprinklers and IBS'F (74-C), In-rack sprinklers E— Slngle-or double-row racks with 8-ft (2 44-m) aisles and 286°F(141 °C) celling sprinklers F— Single-or double-row racks with 8-ft (2 44-m) aisles and leS'FCWC) ceiling sprinklers G—Single-or double-row racks with 4-ft (1 22-m) aisles and 286'F(141°C) ceiling sprinklers H— Single-or double-row racks with 4-ft (1 22-m) aisles and 16S«F(74aC) ceiling sprinklers /— Multiple-row racks with 8-ft (2 44-m) or wider aisles and 286°F(141 «C) ceiling sprinklers J— Multiple-row racks with 8-ft (2 44-m) or wider aisles and 165°F(74°C) ceiling sprinklers 7-4 2.1.6.2 For encapsulated or nonencapsulated storage in multiple-row racks deeper than 16 ft (4 9 m) or with aisles less than 8 ft (2 4 m) wide, in-rack spnnklers shall be installed in accordance with Table 7-42162 7-4.2.1.6.3* Maximum horizontal spacing of in-rack spnn- klers on branch lines, in multiple-row racks with encapsulated or nonencapsulated storage up to and including 25 ft (7 6 m) in height, shall not exceed 12 ft (3 7 m) for Class I, II, or III commodities and 8 ft (2 4 m) for Class IV commodities, with area limitations of 100 ft2 (9 3 m*) per spnnkler for Class I, II, or III commodities and 80 ft8 (7 4 m8) per spnnkler for Class IV commodities The rack plan view shall be considered in determining the area covered by each spnnkler The aisles shall not be included in area calculations 7-4.2.1.6 4 A minimum of 6 in (152 4 mm) shall be main- tained between the in-rack spnnkler deflector and the top of a tier of storage 7-4.2.2f Ceiling Spnnkler Discharge Criteria—Area Density Method. 7-4.2.2.1 General. 7-4.2.2.1.1 *f Ceding Sprinkler Water Demand. Ceiling spnnkler water demand shall bd determined in accordance with 7-4222 for single- and double-row racks or 7-4 2 3 for multiple-row racks The design curves in Figures 7-4 2 2 11 (a) through (g) shall apply to nominal 20 ft (61 m) height of storage 1999 Edition i i I I I i i i i I I I i i i I i I I DESIGN APPROACHES 13-131 Table 7-9.5.1.2 Type of Storage* Single-row rack storage, double-row rack storage, multiple-row rack storage ESFR Protection of Rack Storage without Solid Shelves Maximum Height of Storage Commodity ft m 1 Cartoned unexpanded 25 76 plastic 2 Cartoned expanded plastic 3 Exposed unexpanded plastic 4 Classes I, n, in, and IV commodities, encapsu- lated or unencapsulated 5 Idle wood and plastic pallets 1 Cartoned or exposed 35 10 7 unexpandedplasuc 2 Classes I, n, m, and IV Maximum Ceiling/ Roof Sprinkler Height of Design Hose Stream Building , Pressure In-Rack DemandNominal Sprinkler Duration ft m K-factor psi bar Requirements gpm L/min (hours) 30 91 14 50 34 No 250 946 1 40 122 14 75 52 No 250 946 1 commodities, encapsu- lated or unencapsulated 3 Idle wood and plastic pallets 1 Cartoned or exposed unexpanded plastic 2 Classes I, if IB, and IV commodities, encapsu- lated or unencapsulated 1 Cartoned unexpanded plastic 2 Classes I, n, in, and IV commodities, encapsu- lated or unencapsulated 35 40 20 25 30 35 40 107 122 61 76 91 107 122 45 45 25 30 35 40 45 137 137 76 91 107 122 137 14 14 112 252 252 252 252 90 90 50 20 30 40 50 62 62 34 14 21 28 34 No Yes No No No No No 250 250 250 250 250 250 250 946 946 946 946 946 946 946 1 1 1 1 1 1 1 *No open-top containers 7-9.5.2.4 ESFR sprinklers shall be limited to wet pipe systems 7-9.5.2.5 Early suppression fast-response (ESFR) sprinklers shall be used only in buildings equal to, or less than, the height of the building for which they have been listed 7-9.6 Exposure Protection 7-9.6.1* Piping shall be hydraulically calculated in accordance with Section 8-4 to furnish a minimum of 7 psi (0 5 bar) at any sprinkler with all sprinklers facing the exposure operating 7-9.6.2 Where the water supply feeds other fire protection sys- tems, it shall be capable of furnishing total demand for such systems as well as the exposure system demand 7-9.7 Water Curtains. Sprinklers in a water curtain such as described in 5-13 4 shall be hydraulically designed to provide a discharge of 3 gpm per lineal foot (37 L/rmn per lineal meter) of water curtain, with no sprinklers discharging less than 15 gpm (56 8 L/min) For water curtains employing automatic sprinklers, the number of sprinklers calculated in this water curtain shall be the number m the length corre- sponding to the length parallel to the branch lines in the area determined by 8-4 41 (a) If a single fire can be expected to operate sprinklers within the water curtain and within the design area of a hydraulically calculated system, the water sup- ply to the water curtain shall be added to the water demand of the hydraulic calculations and shall be balanced to the calcu- lated area demand Hydraulic design calculations shall include a design area selected to include ceiling sprinklers adjacent to the water curtain (See 5-13 4 ) 7-9.8 Fire Protection of Steel Columns. 7-9.8.1f"Columns within Storage Racks of Class I through Class IV and Plastic Commodities. Where sprinkler protec- tion of building columns within the rack structure or vertical rack members supporting the building are required in heu of fireproofing, sprinkler protection in accordance with one of the following shall be provided (1) Sidewall sprinklers at the 15-ft (4 6-m) elevation, pointed toward one side of the steel column (2) Provision of ceiling sprinkler density for a minimum of 2000 ft* (186 m2) with 165°F (74°C) or 286°F (141°C) rated sprinklers as shown in Table 7-981 for storage heights above 15 ft (4 6 m), up to and including 20 ft (61 m) (3) Provision of large drop or ESFR ceding sprinkler protec- tion in accordance with 7-9 4 and 7-9 5, respectively 1999 Edition 13-136 INSTALLATION OF SPRINKLER SYSTEMS Table 7-10.23 6 1 Sprinkler Protection for Class 3 Oxidizers Storage Height Density Area of Application *7Jt«: l» - Storage Palletized Bulk Rack ft 5 10 10 m 15 3 3 gpm/ft2 035 065 035 / •TTlTyi / Till^i 143 265 143 ft2 5000 5000 5000 m* 465 4651 465ii In-Rack Sprinklers — . 1 level at midpoint of rack (430. Table 541) 7-10.23.2 Only wet pipe sprinkler systems shall be employed for protection of buildings or areas containing Class 2 or Class 3 oxidizers (430-2-113) 7-10.23.3 Sprinkler System Water Supplies. 7-10.23.3.1 Water supplies shall be adequate for the protection of the oxidizer storage by hose streams and automatic sprin- klers The water system shall be capable of providing not less than 750 gpm (2840 L/min) where protection is by means of hose streams, or 500 gpm (1890 L/min) for hose streams in excess of the automatic sprinkler water demand (430:2-11 41) 7-10 23.3.2 Duration of the water supply shall be a minimum of 2 hours (430:2-1142) 7-10.23.4 Class 1 Oxidizers. Class I oxidizers in noncombus- bble or combustible containers (paper bags or noncombusa- ble containers with removable combustible liners) shall be designated as a Class 1 commodity; as a Class 2 commodity where contained in fiber packs or noncombusdble containers in combustible packaging, and as a Class 3 commodity where contained in plastic containers (430:3-3 2) 7-10.23.5 Class 2 Oxidizers. 7-10.23 5.1* Sprinkler protection for Class 2 oxidizers shall be designed in accordance with Table 7-10 23 5 1 (430:4-4 1) 7-10.23.5.2 Storage Protection with In-Rack Sprinklers. In- rack sprinklers shall be designed to provide 30 psi (2 1 bar) on the hydraulically most remote six sprinklers on each level (430-4-44,4-441) 7-10.23.6 Class 3 Oxidizers. 7-10 23.6.1* Sprinkler protection for Class 3 oxidizers shall be designed m accordance with Table 7-10 23 6 1 (430:5-41) 7-10.23.6.2 Storage Protection with In-Rack Sprinklers. In- rack sprinklers shall be designed to provide 30 psi (2 1 bar) on the hydraulically most remote six sprinklers on each level (430:5-44,5-441) 7-10.23 7 Class 4 Oxidizers. Sprinkler protection for Class 4 oxidizers shall be installed on a deluge sprinkler system to pro- vide water density of 0 35 gpm (14 3 mm/min) over the enure storage area (430. 64 1) 7-10.24 Storage of Organic Peroxide Formulations. 7-10.24.1 SeeNFPA432, Code for the Storage of Organic Peroxide Formulations, for applicable terms not defined in Chapter 1 7-10 24.2 Where [automatic sprinkler systems are required per NFPA 432, Code for the Storage of Organic Peroxide Formula- tions, they] shall provide the following discharge densities Class I [organic peroxides] — 0 5 gpm/ft2 (20 4 mm/mm) Class II [organic peroxides] — 04 gpm/ft2 (16 3 mm/mm) Class HI [organic peroxides] —jO 3 gpm/ft (12 2 mm/nun) Class IV [organic peroxides] — 0 25 gpm/ft? (102 mm/mm) (432-2-82) ! 7-10.24.2.1 The system shall be, designed to provide the required density over a 3000-ft2 (279-m2) area for areas pro- tected by a wet pipe sprinkler system or 3900 ft2 (363 m2) for areas protected by a dry pipe sprmkler system The entire area of any building of less than 3000 fl? (279 m2) shall be used as the area of application (432:2-8211) 7-10.243 Sprinkler System Water Supply Water supplies for automatic sprinkler systems, fire hydrants, and so forth, shall be capable of supplying the anticipated demand for at least 90 minutes (432:2-83) I 7-10.24.4 Where automatic sprinkler systems are required for Class I organic peroxide formulations m quantities exceeding 2000 Ib (908 kg) in detached storage, per NFPA 432, Code for the Storage of Organic Peroxide Formufottons, automatic sprinkler protection shall be of the deluge type (432- 5-5 2) 7-10.25 Organic Peroxide Formulations 7-10.25.1 See NFPA 432, Code for the^ Storage of Organic Peroxide Formulations, for applicable terms nqt defined in Chapter 1 7-10.25 2 Automatic sprinkler systems for the protection of storage of organic peroxide formulations shall provide the fol- lowing discharge densities ] Class 1 — 05 gpm/ft2 (20 4 mm/pun) Class II — 0 4 gpm/ft2 (16 3 mm/mm) Class IH — 0 3 gpm/ft2 (12 2 mmj/min) Class IV — 0 25 gpm/ft2 (102 mm/mm) 7-10.25.3 The system shall be designed to provide the required density over a 3000 ft2 (280J m2) area for areas pro- tected by a wet pipe sprinkler system or 3900 ft2 (360 m2) for areas protected by a dry pipe sprinkle t system The enure area of any building of less than 3000 ft2 (280 m2) shall be used as the area of application < 7-10.26 Light Water Nuclear Power P}ants. 7-10.26.1 See NFPA 803, Standard fot Fire Protection for Light Water Nuclear Power Plants, for applicable terms not defined in Chapter 1 i 7-10 26.2* The yard mains shall be loojped and shall be of suf- ficient size to meet the flow requiremejnts specified in Section 7-10 26 3 of NFPA 13 (803:11-2) fi 1999 Edition . 1998 CALIFORNIA BUILDING CODE TABLE 3-B TABLE 3-C TABLE 3-B—REQUIRED SEPARATION IN BUILDINGS OF MIXED OCCUPANCY1 (HOURS) A-1 A-2 A-21 A-3 A-4 B E F-1 F-Z H-1 H-2 H-3 H-4,5 £-6,7 I M R-1 R-3 S-1 S-2 S-3 S-4 S-5 A-1 A-2 N A-21 N N A-3 N N N A-4 N N N N B 3 1 1 N 1 E N N N N N 1 F-1 3 1 1 N 1 N* 1 F-2 3 1 1 N 1 N 1 1 H-2 4 4 4 4 2 4 2 2 H-3 4 4 4 4 1 4 1 1 H-4,5 4 4 4 4 1 4 1 1 H-6,7* 4 4 4 3 1 3 1 1 H-8 3 2 2 1 1 2 1 1 \ 3 3 3 2 3 2 1 3 2 M 3 1 1 N 1 N 1 N5 1 R-1 1 1 1 1 1 1 1 1 1 R-3 1 S-1 3 1 1 N 1 N 1 N N S-2 3 1 1 N 1 N 1" N N S-3 4 3 3 3 3 1 3 1 1 S-5 3 1 1 1 1 1 1 1 1 U-13 -1 1 1 1 1 1 1 1 1 NOT PERMITTED IN MIXED OCCUPANCIES SEE SECTION 307 2 8 1 1 1 2 1 1 2 I 1 1 2 1 4 4 I 1 I 4 4 4 4 2 1 1 1 2 4 3 3 4 1 1 4 3 3 4 1 1 N 2 1 1 1 2 1« 3 1 2 1 1 1 2 1* 1 1 1 2 1 1 1 4 1 3 1 1 1 2 1 1 1 3 1 1 1 1 1 1 1 1 1 3 1 1 1 1 1 N 1 OPEN PARKING GARAGES ARE EXCLUDED EXCEPT AS PROVIDED IN SECTION 3112 .1 1 N N—No requirements for fire resistance 'For detailed requirements and exceptions, see Section 302 42For special provisions on highly toxic materials, see the Fire Code3For agricultural buildings, see also Appendix Chapter 34See Section 309 2 2 for exception.5For Group F, Division 1 woodworking establishments with more than 2,500 square feet (232 3 m2), the occupancy separation shall be one hour TABLE 3-C—REQUIRED SEPARATION OF SPECIFIC-USE AREAS IN GROUP I, DIVISION 1 1 HOSPITAL AND NURSING HOMES DESCRIPTION 1 2 3 4 5 6 7 8 9 10 11 12 Employee locker rooms Gift/retail shops Handicraft shops Kitchens Laboratories that employ hazardous materials in quantities less thanthat which would cause classification as a Group H Occupancy Laundries greater than 100 square feet (9 3 m2)1 Paint shops employing hazardous substances and matenals inquantities less than that which would cause classification as a Group H Occupancy Physical plant maintenance shop Soiled linen room1 Storage rooms 100 square feet (9 3 m2) or less in area itonngcombustible material Storage rooms more than 100 square feet (9 3 m2) storing combustiblematerial Trash-collection rooms1 OCCUPANCY SEPARATION None None None None One hour One hour One hour One hour One hour None One hour One hour 'For rubbish and linen chute termination rooms, see Section 711 5 1-403 TABLE 3-D 1998 CALIFORNIA BUILDING CODE F TABLE 3-D— EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A PHYSICA i MAXIMUM QUANTITIES PER CONTROL AREA'When two units are given, values within parentheses are In cubic feet (cu. ft ) or pound F CONDITION i Malarial F 1 1 CombustibleF liquid4 3 6,7,8,9 F 1 2 Combustible fiber£ (loose) F (baled) : 1 3 Cryogenic, flammable• or oxidizing ; 2 1 Explosives ' 3 1 Flammable solid ; 3 2 Flammable gas; (gaseous) [ (liquefied) 1 3 3 Flammable1 liquid4'5'6'7 8'9 : ! Combination I-A, : I-B.I-C13 I 4 1 Organic peroxide, I unclassified [ detonatable ! 42 Organic peroxide r r i 4 3 Oxidizer| F 1 4 4 Oxidizer— gas • (gaseous)"10 ; (liquefied)6-10 ; 5 1 Pyrophonc ! 6 1 Unstable (reactive) ; p: 1 7 1 Water reactive : : Classn m-A m-B I-A I-B I-C I n ni IV V 4 316 2 1 4 3 2 1 3 2 1 STORAGE2 Solid Lbs 3(Cu Ft) x 04536 for kox 08283 lorn? NA NA NA (100)(1,000) NA I10-13 1256,10 NANA NA NA NA. NA 110,12 56,10 506'1° 1256.1° 5006'10 NL 1 10,12 10610 25Q6.10 4,00061° NA NA 410,12 110,12 56,10 506.10 NL 56,10 SO6-10 125 io,U Qal?ons> x3765forLx 04536 for kg 1201° 33010 13.20010 u NANA. 45 (1)10,13 NA N5A10 30io fl>i° 90io 12010 (1)10-12 (5)6.10 (50)6'1° (125)6-10 (500)6'10 NL (1)10.12 (10)6.io (250)6 10 (4,000)6.10 NA15 (4)10,12 (1)1012 (5)6.10 (50)6.10 N.L (5)6,10 (50)6,io (125)10'11 ; NA — Not applicable NL — Not limited, i 'Control areas shall be separated from each other by not less than a• used for retail or wholesale sales shall not exceed two Thenumtx: 2The aggregate quantity in use and storage shall not exceed the quai F 3The aggregate quantity of nonflammable solid and nonflammable orI cies used for retail sales may exceed the exempt amounts when st; ^The quantities of alcoholic beverages in retail sales uses are unlimii The quantities of medicines, foodstuffs and cosmetics containing • solutions not being flammable in retail sales or storage occupancii 5For aerosols, see the Fire Code: Quantities may be increased 100 percent in spnnklered buildings ^! 7For storage and use of flammable and combustible liquids in Groups F through 307 1 5, 308 8, 309 8, 310 12, 311 8 and 312 4F 8Fot wholesale and retail sales use, also see the Fire Code• 'Spray application of any quantity of flammable or combustible liqi ; 10Quantities may be increased 100 percent when stored in approved1 Footnote 6 also applies, the increase for both footnotes may be ap• ilThe quantities permitted™ a spnnklered building are not limited.1 12Permitted in spnnklered buildings only None is allowed in unspn: 13One pound of black sporting powder and 20 pounds (9 kg) of smc: 14See definitions of Divisions 2 and 3 in Section 307 1 1-404 OaaCu Ft x 00263 for of NA NA. NA NANA NA NA NA 7506,10 NA NA NA NA. NA NA NA NA NA NA NA NA. NA. NA NA 1,500NA. 5Q10.12 1010,12 506-10 2506,10 7506 10 NA NA. NA one-hour fire-rex of control areitity listed for stnoncombusnblech areas are in ted provided thenot more than 5es are unlimitee Vhen Footnote A,B,E,F,H,I, lids shall be con storage cabinetplied. nklered buildinkeless powder i USE2— CLOSED SYSTEMS Solid Lbs. (Cu Ft) x 0 4536 for tox 00263 for n? NA NA. NA (100) (1.000) NA V412 14 NA. NA NA NA. NA NA I/4,2 I6 506 1256 500s Ni V4i2 26 2506 4,000s NA NA I12 V412 I6 50s Ni 5« 506 12511 Liquid Gallons(Lbs) x 3 715 lor Lx 04536 forko 120 330 13,200" NANA 45 (l/4)12 NA NA156.1° 30 60 90 120 (W2 (1)6 (SO)6 (125)6 (SOO)6 NX (V4)12 (2)6 (250)6 (4,000)6 NA15 (I)12 (V4)i2 (1)6 (50)6 NX (5)6 (SO)6 (125)" GasCu Ft .HAZARD »(lbs) x 00213 for |n» NA NA. NA NANA. NA NA NA 7506 10NA NA NA NA NA. NA NA. NA NA N A. NA j NA. ! NA. NA NA ! 1,500NA 1Q10.12 210.12 1Q6.10 25Q6 10 N.L ; NA NA NA sisttve occupancy separation The number oas in buildings with other uses shall not exciorageliquid hazardous materials within a single cc:omphance with the Fire Codei liquids are packaged in individual contains 0 percent of volume of water-misctble liquiwhen packaged in individual containers no 10 also applies, the increase for both footno M, R, S and U Occupancies, see Sections 30 ducted as set forth in the Fire Codes, gas cabinets or exhausted enclosures as s !sire permitted in spnnklered or unspnnklerec USE2— OPEN SYSTEMS Solid Lbs(Cu. Ft) x 0 4536 lor tox 0 0263 for li? NA NA NA (20) (200) NA V412 14 NA NA NA NA NA NA V4'2 I6 106 256 1006 N.L V4l2 26 506 1,000s NA.NA 0 l/4i2 1s 10s NL I6 10s 25U Liquid Gallons(Uw) x3765forLx 04536 for Kg 30 80 3,300n NANA 10 (V4)i2 NA. NA NA 10 15 20 30 (l/4)I2 (I)6 (10)6 (25)6 (100)6 NL (V4)l2 (2)6 (50)6 (1,000)6 NANA 0 (*/4)12 (I)6 (10)6 NL (I)6 (lO)6 (25)" " control areas within a buildingedfour See Section 204 Urol area of Group M Occupan- •s not exceeding 4 literss and with the remainder of theexceeding 4 liters es may be applied 3 8, 304 8, 305 8, 306 8, 307 1 3 ecified in the Fire Code When buildings I I I I I I I I I I I I I I I I I I I 1998 CALIFORNIA BUILDING CODE TABLE 3-D TABLE 3-D 1 FOOTNOTES TO TABLE 3-D—(Continued) 15Contaimng not more than the exempt amounts of Class I-A., Class I-B or Class I-C flammable liquids16A maximum quantity of 200 pounds (90 7 kg) of solid or 20 gallons (75 7 L) of liquid Class 3 oxidizers may be permitted when such materials are necessary for maintenance purposes or operation of equipment as set forth in the Fire Code TABLE 3-D. 1 [For SFMJ—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS, LIQUIDS AND CHEMICALS PRESENTING A PHYSICAL HAZARD BASIC QUANTITIES PER LABORATORY SUITED When two units an given, values within parentheses are In cubic feet (Cu Ft.) or pounds (Lhs ) CONDITION MATERIAL 1 1 Combustible liquid 1 2 Combustible dust IbsMOOO cu.fi. I 3 Combustible fiber (hose) (baled) 1 4 Cryogenic, flammable or enduing 2 1 Explosives 3 1 flammable solid 3 2 Flammable gas (gaseous) (liquefied) 3 3 Flammable liquid Combination I-A. l-B. I-C 4 1 Organic peroxide, unclassified detonatdble 4 2 Organic peroxide 430xuu&r 4 4 Oxiida.tr— Gas (gaseous) (liquefied) 5 1 Pyrophonc 6 1 Unstable (reactive) 71 Water (reactive) CLASS II III-A III-B I-A I-B I-C rIImIV V 4 3 21 4 3 21 32 1 STORAGE Solid Lbt.(CUR; — — — 1 (100) (1.000) V1252 _ — — — —i2 52 502 1252 500 NL 12 ID2 2502 LOGO1 — 4* 1*52 SO2 1252 &12S2 LiquidOallont(Lta.) 1202 3302 13.2002 — — 45 <D2 — 7s2 30* 602 902 12Q2 (I)2 (5)2 (SO)2 (125)2 (500) NL. (I)2 (lO)2 (250)2 (l.OOO)2 is2 (4)2 (I)2 (5)2 (SO)2 (125)2 ISP(SO)2 (125)2 OmCu Ft — — — — — — — 7502 — — — —— — — 1.5002 SO2 102 SO2 2502 7502 — USE— CLOSED SYSTEMS Solid Uu.(CuFt) — — — I (100) (1,000) — v. 2$ ~ — — — —'/4 (1)50 125 500 NL J2 2501,000 — 1 "i50 125 550 125 LiquidQtllont (Uu) 120 330 13,200 _ ~ 45 (ty) — ~52 30 60 90 120 C/4) (1)(50) (125) (500)NL. (l/4)(2)(250) (1,000) is2 W C/4) (1)(50) (125) (5)(50) (125)2 OnCuFt — — — i — — — 7502 — — — — — — — 1.5002 102 22 lO2 250.2 7502 ~_ USE— OPEN SYSTEMS Solid Lb*(CuFt) — — — 1 (20) (200) — v. 25 — — — — —'4 11025 70? NL. >/4 50 200 — 0 1/411025 ; 10 25 LiquidQtllon* (Lt».) 30 80 3,300 __ ~ 10 (l/4) — ~ 10 15 20 30 (1M I (10)(25) (100) tfj- (l/4)(2)(50) (200) — 0 (*/4)(1)(10)(25) (1)(10) (25) Q*3Cu Ft — — — = — — — = — — — — — — — — 0 00 00 -_ "NL—Not limited. *A laboratory suite is a space up to 10,000 square feet (929 m2) bounded by not less than a one-hour fire-resistive occupancy separation within which the exempt amounts of hazardous materials may be stored, dispensed, handled or used. Up through the third floor and down through the first basement floor, the quantity in this table shall apply Fourth, fifth and sixth floors and the second and third basement floor level quantity shall be reduced to 75 percent of this table The seventh through 10th floor and below the third basement floor level quantity shall be reduced to 50 percent of this table ^Quantities may be increased 100 percent when stored in approved exhausted gas cabinets, exhausted enclosures or fume hoods 1-40.5 TABLE 3-E 1998 CALIFORNIA BUILDING CODE TABLE 3-E—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A HEALTH HAZARD MAXIMUM QUANTITIES PER CONTROL AREA1'2 When two units are given, values within parentheses are In pounds (Iba) MATERIAL 1 Corrosives10 2 Highly toxics7 3 Imtants9 4 Sensittzers' 5 Other health hazards9 6 Toxics7 STORAGE1 Solid Lb* «*• x 04536 for kg 5,000 10 Nl NL Ni 500 J&ttM(UM) x 3 785 lor Lx 0.4536 for kg 500 (10) N.L. NL N.L (500) GasCu.Pl.1 X 0028 form3 810s 20s 810«.» 8106-11 810«» 8106 USE3— CLOSED SYSTEMS SolidLb».<.» x 04538 for kg 5,000 10 N.L NL NL 500 oi&(Lbs.) x 3 785 for Lx 0 4536 for kg 500 (10) ; NL N.L NL (500) Ga*Cu Ft» x 0028 form9 810s 20» 810«." 810W 8lO«.u 8108 USE3— OPEN SYSTEMS SolidLbs.4'* x 04538for*g 1,000 3 5.00011 5.00011 5.00011 125 Gallons49 (Lot) x 3 785 for Lx 04536 for kg 100 (3) 50011 50011 500" (125) N.L = Not limited 'Control areas shall be separated from each other by not less than a one-hour fire-resistive occupancy separation. The number iff control areas within a building used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four See Section 2042The quantities of medicines, foodstuffs and cosmetics, containing not more than 50 percent by volume of water-miscible liquids and with the remainder of the solutions not being flammable, m retail sales uses are unlimited when packaged in individual containers not exceeding 4 liters3The aggregate quantity in use and storage shall not exceed the quantity listed for storage :4The aggregate quantity of nonflammable solid and nonflammable or noncombusable liquid health hazard materials within a single control area of Group M Occu- pancies used for retail sales may exceed the exempt amounts when such areas are in compliance with the Fire Code 'Quantities may be increased 100 percent in spnnklered buildmgs When Footnote 6 also applies, the increase for both footnotes may be applied "Quantities may be increased 100 percent when stored in approved storage cabinets, gas cabinets or exhausted enclosures as specified m the Fire Code When Foot- note 5 also applies, the increase for both footnotes may be applied. :7For special provisions, see the Fire Code Permitted only when stored in approved exhausted gas cabinets, exhausted enclosures or fume hoods 'Irritants, sensitizers and other health hazards do not include commonly used building materials and consumer products that arp not otherwise regulated by this code :IOFor stationary lead-acid battery systems, see the Fire Code '11The quantities allowed in a spnnklered building are not limited when exhaust ventilation is provided in accordance with the jire Code See Table 8001 15-B, Footnote 12 ' I I I I I I I I I I I I I I 1-406 TABLE 7902.5-B 1997 UNIFORM FIRE CODE TABLE 7902 3-A—OUTDOOR LIQUID STORAGE IN CONTAINERS AND PORTABLE TANKS (See Sections 7902 3 3.1 and 7902 3.3.2) CLASS OFLIQUID I-A I-B I-Cnm CONTAINER STORAGE— MAXIMUMPER PILE Quantity1.2 (gallons) x 3.785 for L 1,100 2,200 4,400 8,800 22,000 Height C««t) x 304 8 for mm 10 12 12 12 18 PORTABLE TANKSTORAGE— MAXIMUM PER PILE Quantity1.2 (gallon*) x 3 785 for L 2,200 4,400 8,800 17,600 44,000 Height <f«t) MINIMUM DISTANCEBETWEEN PILES ORRACKS (feet) MINIMUM DISTANCETO PROPERTY LINEOF PROPERTY THATCAN BE BUILTUPON3'4 (leef) MINIMUM DISTANCE TO STREET, ALLEY ORA PUBLIC WAY* (feet) x 304.8 for mm 7 14 14 14 14 5 5 5 5 5 50 50 50 25 10 10 10 10 5 5 JFor mixed class storage, see Section 7902 331 2For storage in racks, the quantity limits per pile do not apply, but the rack arrangement shall be limited to a maximum of 50 feet (15 240 mm) in length and two tows or 9 feet (30 480 mm) m depth 3If protection by a public fire department or pnvate fire brigade capable of providing cooling water streams is not available, the distance shall be doubled4When the total quantity stored does not exceed 50 percent of the ma-tinnim allowed per pile, the distances are allowed to be reduced 50 percent, but not less than 3 feet (914 4 mm) TABLE 7902 5-A—EXEMPT AMOUNTS OF FLAMMABLE AND COMBUSTIBLE LIQUIDS- MAXIMUM QUANTITIES STORED PER CONTROL AREA1'2-3 (See Section 7902 5 7) TYPE OF LIQUID Flammable Class I-A Class I-B Class I-C Combination I-A, I-B, I-C Combustible Class n Class ffl-A Class m-B EXEMPT AMOUNT (gallons) x 3.785 for L 30 60 90 120* 120 330 13,200s ^Control areas shall be separated from each other by not less than a one-hour fire-resistive occupancy separation The number of control areas within a building used for retail or wholesale sales shall not exceed two Tne number of control areas in buddings with other uses shall not exceed four See Sections 204 and 800110 2 ^Quantities are allowed to be increased 100 percent when stored in approved storage cabinets When Footnote 3 applies, the increase for each footnote is allowed ^Quantities are allowed to be increased 100 percent in buildings equipped with an approved automatic sprinkler system When Footnote 2 applies, the increase for each footnote is allowed ^Combinations shall not contain more than the exempt amounts of any individual class Quantities permitted in a budding equipped with an approved automatic sprinkler system are not limited. I i i i i1 i i i TABLE 7902.5-B—EXEMPT AMOUNTS OF FLAMMABLE AND COMBUSTIBLE LIQUIDS IN WHOLESALE AND RETAIL SALES USES- MAXIMUM QUANTITIES STORED PER CONTROL AREA1 (See Section 7902 5.71) TYPE OF UOUID Flammable Class I-A Flammable and combustible Combination Class I-B, I-C,n and ffl-A Combustible Class m-B EXEMPT AMOUNTS (gallon*) * 3.785 tar L Sprlnklereo? per Footnote Denertle* 60 7,5003 Unlimited Sprlnklered per Table* 7902.5-Fthrough 7902.S-K 60 15,000s Unlimited UiMprinWered 30 1,600 13,200 ^ntrol areas shall be separated from each other by not less than a one-hour fire-resistive occupancy separation The number of control areas within a building used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four See Sections 204 and 800110 2 2To be considered as sprmklered, buildings shall be protected with approved automatic sprinkler systems with designs providing minimum densities as follows For uncartoned commodities on shelves 6 feet (1829 mm) or less m height where the ceiling height does cot exceed 18 feet (5486 mm), quantities are those per- mitted with a minimum sprinkler design density of Ordinary Hazard Group 2 For cartoned, palletized or racked commodities where storage is 4 feet 6 inches (1372 mm) or less in height and where the ceiling height does not exceed 18 feet (5486 mm), quantities are those permitted with a minimum sprinkler design density of 0 21 gpm per square foot [8 56 L/(min»m2)] over the most remote 1,500-square-foot (139 m2) area 3When wholesale and retail sales or storage areas exceed 50,000 square feet (4645 m2) in area, exempt amounts are allowed to be increased by 2 percent for each 1,000 square feet (92.9 m2) of area in excess of 50,000 square feet (4645 m2), up to a maximum of 100 percent of the table amounts A control area separation is not required. The cumulative amounts, including amounts attained by having an additional control area, shall not exceed 30,000 gallons (113 562 L) 1-184 1997 UNIFORM FIRE CODE be free from residual material and vapor as defined by DOT, the Resource Conservation and Recovery Act (RCRA) or other regu- lating authority or maintained as specified for the storage of the hazardous material 8001.4.7 Maintenance. 8001.4.7.1 General. Equipment, machinery and required detec- tion and alarm systems associated with hazardous materials shall be maintained in an operable condition Defective containers, cyl- inders and tanks shall be removed from service, repaired or dis- posed of in an approved manner Defective equipment or machinery shall be removed from service and repaired or replaced Required detection and alarm systems shall be replaced or repaired where defective See also Section 80014 4 8001.4.7.2 Tanks out-of-service for 90 days. Stationary tanks not used for a period of 90 days shall be properly safeguarded or removed in an approved manner Such tanks shall have the fill hne, gauge opening and pump connection secured against tamper- ing Vent lines shall be properly maintained Tanks which are to be placed back in service shall be tested in an approved manner 8001.4.7J Defective containers and tanks. Defective contain- ers and tanks shall be removed from service, repaired or disposed of in an approved manner 8001.4.8 Liquid-level limit control. Atmospheric tanks which have a capacity greater than 500 gallons (1893 L) containing haz- ardous material liquids shall be equipped with a liquid-level limit control to prevent overfilling of the tank. EXCEPTION Tanks monitored by a system which limits net con- tents by weight 8001.4.9 Seismic protection. Machinery and equipment utiliz- ing hazardous materials shall be seisrrucally anchored in accord- ance with the Building Code 8001.5 Release of Hazardous Materials. 8001.5.1 General. Hazardous materials shall not be released into a sewer, storm drain, ditch, drainage canal, lake, nver or tidal waterway, or upon the ground, sidewalk, street, highway or into the atmosphere EXCEPTION- Materials released in accordance with federal, state or local governing regulations or permits of the jurisdictions! Air Quality Management Board with a National Pollutant Discharge Elim- ination System Permit, with waste discharge requirements established by the jurisdictions! Water Quality Control Board 01 with local sewer pretteatment requirements for publicly owned treatment works 8001.5.2 Unauthorized discharges. 8001.5.2.1 Records. Accurate records shall be kept of the unau- thorized discharge of hazardous materials by the permittee 8001.5.2.2 Notification. The chief shall be notified immediate- ly when an unauthorized discharge becomes reportable under state, federal or local regulations 8001.5.2.3 Preparation. Provisions shall be made for control- ling and mitigating unauthorized discharges 8001.5.2.4 Control. When an unauthorized discharge due to pri- mary container failure is discovered, the involved primary con- tainer shall be repaired or removed from service 8001.5.2.5 Responsibility for cleanup. The person, firm or cor- poration responsible for an unauthorized discharge shall institute and complete all actions necessary to remedy the effects of such unauthorized discharge, whether sudden or gradual, at no cost to 80Q14680019 the jurisdiction When deemed necessary by the chief, cleanup may be initiated by the fire department or by an authorized indi- vidual or firm Costs associated with such cleanup shall be borne by the owner, operator or other person responsible for the unau- thorized discharge 8001.6 Matenal Safety Data Sheets. Material safety data sheets (MSDS) shall be readily available on the premises for haz- ardous materials regulated by Article 80 See also Sec- tion 8001 3 2 8001.7 Identification Signs. Visible hazard identification signs as specified in UFC Standard 79-3 shall be placed on stationary aboveground tanks and at entrances to locations where hazardous materials are stored, dispensed, used or handled in quantities requiring a permit Signs shall be provided at specific entrances and locations designated by the chief EXCEPTION The chief may waive this requirement in special cases when consistent with safety if the owner or operator has submitted a hazardous materials management plan and hazardous materials inventory statement See Appendix n-E and Sections 8001 3 2 and 80013 3 Individual containers, cartons or packages shall be conspicu- ously marked or labeled in accordance with nationally recognized standards Rooms or cabinets containing compressed gases shall be con- spicuously labeled COMPRESSED GAS Signs shall not be obscured or removed Signs shall be in English as a primary language or in symbols allowed by this code Signs shall be durable The size, color and lettering shall be in accordance with nation- ally recognized standards 8001.8 Signs. In addition to the hazard identification signs re- quired by Section 80017, additional hazard identification and warning signs shall be provided as follows 1 Stationary containers and tanks shall be placarded with haz- ard identification signs as specified in UFC Standard 79-3 for the specific material contained 2 Signs prohibiting smoking shall be provided in the following situations 2 1 In rooms or areas where hazardous materials are stored or dispensed or used in open systems in amounts requiring a permit in accordance with Section 8001 3 1 2 2 Within 25 feet (7620 mm) of outdoor storage, dispens- ing or open-use areas Signs shall not be obscured or removed Signs shall be in Eng- lish as a primary language or in symbols allowed by this code Signs shall be durable The size, color and lettering shall be in ac- cordance with nationally recognized standards 8001.9 Sources of Ignition. Smoking shall be prohibited in the following locations 1 Within 25 feet (7620 mm) of outdoor storage or dispensing areas 2 In rooms or areas where hazardous materials are stored or dis- pensed or used in open systems in amounts requiring a permit in accordance with Section 8001 3.1 Open flames and high-temperature devices shall not be used m a manner which creates a hazardous condition EXCEPTION: Energy-consuming equipment listed for use with the hazardous materials stored or used 1-203 I I I I II I I 'I I I 8001 11.5 1997 UNIFORM FIRE CODE I 8001.10 Construction Requirements. 800110.1 General. Buildings, or portions thereof, in which hazardous materials are stored, handled or used shall be con- structed in accordance with the Building Code 8001.10.2 Control areas. 8001.10.2.1 Construction requirements. Control areas shall be separated from each other by not less than a one-hour fire-resis- tive occupancy separation 8001.10.2.2 Number. The number of control areas in buildings or portions of buildings used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four 8001.103 Gas rooms. 8001.103.1 General. When a gas room is used to increase com- pressed gas exempt amounts or when the location of compressed gases in a gas room is required or allowed by Section 8003 or 8004, the gas room shall be in accordance with Section 8001 10 3 8001.10.3.2 Construction Gas rooms shall be separated from the remainder of the building by not less than a one-hour fire-resis- tive occupancy separation For highly toxic and toxic compressed gases used in conjunction with or serving a Group H, Division 6 Occupancy, also see the Building Code 8001.103.3 Ventilation system. The ventilation system for gas rooms shall be designed to operate at a negative pressure in rela- tion to the surrounding area. For toxic and highly toxic gases, the requirements set forth in Section 8003 3134 shall also be met. 8001.10.4 Exhausted enclosures. 8001.10.4.1 General. When an exhausted enclosure is used to increase exempt amounts or when the location of hazardous mate- rials in exhausted enclosures is either required or allowed by Sec- tion 8003 or 8004, the exhausted enclosure shall be in accordance with Section 8001 10.4 8001.10.4.2 Construction. Exhausted enclosures shall be non- combustible 8001.10.43 Ventilation. The ventilation system for exhausted enclosures shall be designed to operate at a negative pressure in relation to the surrounding area. For toxic and highly toxic gases, the requirements set forth in Section 8003 3133 shall also be met. 8001.10.5 Gas cabinets. 8001.10.5.1 General. When a gas cabinet is used to increase ex- empt amounts or when the location of compressed gases in gas cabinets is either required or allowed by Section 8003 or 8004, the gas cabinet shall be in accordance with Section 8001 10 5 8001.10.5.2 Construction. Gas cabinets shall be constructed in accordance with the following 1 Constructed of not less than 0 097-inch (2 46 mm) (12 gage) steel 2 Be provided with self-closing limited access ports or non- combustible windows to give access to equipment controls 3 Be provided with self-closing doors 8001.10.53 Ventilation. The ventilation system for gas cabi- nets shall be designed to operate at a negative pressure in relation to the surrounding area. For toxic and highly toxic gases, the re- quirements set forth in Section 8003 3132 shall also be met 1-204 8001.10.6 Hazardous materials storage cabinets. 8001.10.6.1 General. When storage cabinets are used to in- crease exempt amounts or to comply with Article 80, such cabi- nets shall be in accordance with Section 8001 10 6 8001.106.2 Construction. Cabinets shall be constructed of metal The interior of cabinets shall be treated, coated or con- structed of materials that are nonreactive with the hazardous mate- rial stored. Such treatment, coating or construction shall include the entire interior of the cabinet. Cabinets shall either be listed as suitable for the intended storage or constructed in accordance with the following 1 Cabinets shall be of steel having a thickness of not less than 0 044 inch (1 12 mm) (18 gage) The cabinet, including the door, shall be double walled with 1 V2-mch (38 1 mm) airspace between the walls Joints shall be riveted or welded and shall be tightfitting Doors shall be well fitted, self-closing and equipped with a self- latching device, and 2 The bottoms of cabinets utilized for the storage of liquids shall be liquid tight to a minimum height of 2 niches (50 8 mm) For requirements regarding electrical equipment and devices within cabinets used for the storage of hazardous gases or liquids, see the Electrical Code 8001.11 General Safety Precautions. 8001.111 Personnel training and written procedures. 8001.11.1.1 General. Persons responsible for the operation of areas in which hazardous materials are stored, dispensed, handled or used shall be familiar with the chemical nature of the materials and the appropriate mitigating actions necessary in the event of fire, leak or spill 8001.11.1.2 Fire department liaison. Responsible persons shall be designated and trained to be liaison personnel for the fire department These persons shall aid the fire department in pre- planning emergency responses and identification of the locations where hazardous materials are located and shall have access to material safety data sheets and be knowledgeable in the site emer- gency response procedures 8001.11.2 Security. The storage, dispensing, use and handling areas shall be secured against unauthorized entry and safeguarded with such protective facilities as public safety requires 8001.11.3 Protection from vehicles. Guard posts or other ap- proved means shall be provided to protect storage tanks and con- nected piping, valves and fittings, dispensing areas, and use areas subject to vehicular damage When guard posts are installed, the posts shall be 1 Constructed of steel not less than 4 niches (1016 mm) in di- ameter and concrete filled, 2 Spaced not more than 4 feet (1219 mm) between posts on center, 3 Set not less than 3 feet (914 mm) deep in a concrete footing of not less than a 15-inch (381 mm) diameter, 4 Set with the top of the posts not less than 3 feet (914 mm) above ground, and 5 Located not less than 5 feet (1524 mm) from the tank. 8001.114 Electrical wiring and equipment Electrical wiring and equipment shall be installed in accordance with the Electrical Code 8001.11.5 Static accumulation. When processes or conditions exist where a flammable mixture could be ignited by static elec- 1997 UNIFORM RRE CODE 8001.16.23 LJqueGed flammable gases and flammable gases in solution. Containers of liquefied flammable gases and flam- mable gases in solution shall be positioned in accordance with Section 8004113 8001.163 Oxidizing gases. 8001.163.1 Emergency shutoff. Compressed gas systems con- veying oxidizing gases shall be provided with emergency shutoff capability in accordance with Section 8004 112 8001.163.2 Ignition source control. Ignition sources in areas containing oxidizing gases shall be controlled in accordance with Section 80019 8001.16.4 Pyrophoric gases. 8001.16.4.1 Emergency shutoff. Compressed gas systems con- veying pyrophonc gases shall be provided with emergency shut- off capability m accordance with Section 8004 112 SECTION 8002 — CLASSIFICATION BY HAZARD 8002.1 General. Hazardous materials shall be classified according to hazard categories The categories include materials regulated by Article 80 and materials regulated elsewhere in this code 8002.2 Hazard Categories. 8002.2.1 Physical hazards. The materials categories listed in this section are classified as physical hazards A material with a primary classification as a physical hazard can also present a health hazard 1 Explosives and blasting agents, regulated elsewhere in this code 2 Compressed gases, regulated in Article 80 and elsewhere in this code, as follows 21 Air, 8001.16.2 3 80023 22 Flammable, 23 Inert, 24 Oxidizing, ' 25 Pyrophonc, 2 6 Simple asphyxiant, j 2 7 Unstable (reactive), and 2 8 Health hazards identified in Section 8002 2 2 3 Flammable and combustible liquids regulated elsewhere in this code 4 Flammable solids I 5 Organic peroxides 6 Oxidizer solids and liquids 7 Pyrophonc solids and liquids 8 Unstable (reactive) sokdsj and liquids 9 Water-reactive solids and liquids 10 Cryogenic fluids, regulated elsewhere in this code 8002.2.2 Health hazards. The materials categones listed in this section are classified as health hazards A matenal with a primary classification as a health hazard cjan also present a physical hazard 1 Highly toxic and toxic materials, including highly toxic and toxic compressed gases 2 Radioactive materials • 3 Corrosives 4 Carcinogens, irritants, sensittzers and other health hazards 80023 Descriptions and Examples. For descriptions and ex- amples of materials included in hazard categones, see Appendix VI-A, except that refrigerants regulated under Article 63 shall be classified in accordance with Table A-VI-F-1 if the refrigerant used is included in Table A-VI-F.-1 I I I I I I I I I I I 1-209 IMBLfcUUUT 15-A 1997 UNIFORM FIRE CODE TABLE 8001 15-A— EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A PHYSICAL HAZARD MAXIMUM QUANTITIES PER CONTROL AREA1 When two units are given, values within parentheses are In cubic feet (cu. ft) or pounds (Ibs.) (Apply table as specified In Section 8001.15.) CONDITION Material 1 1 Combustible hquid4-5.6-7.8'9 12 Combustible fiber17 rtoose) (baled) 1 3 Cryogenic, flammable or OXlulZHlt 2 1 Explosives12-17 3 1 Flammable solid17 3.2 Flammable gas17 (gaseous) (liquefied) 3 3 Flammable liquid4-5-6-7'8-9 Combination I-A, I-B,1-0*^6,7,8,9,15^ 4 1 Organic peroxide,unclassified detonatable 4 2 Organic peroxide 4 3 Oxidizer 4 4 Oxidizer— gas (gaseous)6-1"-17 (liquefied)*-1"-17 5 1 Pyrophonc17 6 1 Unstable (reactive)17 7 1 Water reactive Clan — — — — — — — — I n m rv V 4 3u, 2 1 — — 4 3 2 1 3 2 1 STORAGE* Solid Lin 3 (cubic (nt) x 04536 for kox 00283 for n? — (100) (1,000) NA 110,13 125S,10 NA NA — 110.12 56,10 SO*.™ 1256,10 5006-1" NL 110,12 10«.lO 2506,10 4,0006'1° NA N.A 410,12 110,12 56,10 506-10 NL 56,10 50«'10 12510,11 Liquid Qolloni*(pounds) x 3 785 tar Lx 04536 tor k0 — NA NA 45 (1)10,13 NA NA156,10 — (1)10,12 (5)6-1" (50)6.10 (125)«-1° (500)6-1° N.L (1)10,12 (10)«,!0 (250)<-1° (4,000)S.10 NA 15 (4)10,12 (I)10'12 (5)6'10 (SO)6-1" NL. (5)6,10 (50)6.10 (125)10,11 OilCubic Foot x 00283 for m' — NA NA NA NA NA 7506,10 NA — NA NA NA NA NA NA NA NA NA NA 1,500 NA 5010,12 1010-12 SO6-10 7506,10 NLA1" NA NA NA USE*-CLOSED SYSTEMS Solid Lot(cobiotaot) x 04536 for kox 00283 lorn? — (100) (1,000) NA VA 14 NA NA — 1/412 I6 506 1256 5006 NL V412 2« 2506 4,000s NA NA 112 V412 I6 SO6 NL 56 506 12511 Liquid Golloiu(pound.) x 3 785 tor L x 04538 tor kg — NA NA 45 (VO NA "iswo — (V4)12 (i)6 (50)« (125)« (500)6 NL. (V4)12 (2)« (250)« (4.000)6 NA15 (I)12 (V4)12 (I)6 (SO)6 NL (5)6 (SO)6 (125)11 GuCubic Foot x 00283 (or or* — NA NA NA NA NA 7506,10 NA — NA NA NA NA' NA NA NA NA NA NA 1,500NA 1010-12 210,12 lO6-1" 7506,10 NL NA NA NA DSP— OPEN SYSTEMS Solid Lbo(cubic fool) x 04536 for ku x 00283 for n? — (20) (200) NA J/4 14 NA NA — l/412 1« 106 256 100« N.L V412 26 506 1,000« NANA 0 1/412 I6 106 N.L I6 106 2511 Liquid Gollono (pounds) x 3 785 for Lx 04536 tor kg — NANA. 10 (V4) NA NA NA — (V4)12 (I)6 (10)6 (25)« (100)6 NL (V4)12 (2)6 (SO)6 (l.OOO)6 NA NA 0 (V4)1Z (I)6 (10)6 NL (I)6 (10)6 (25)" NA—Not applicable NX.—Not limited ^Control areas shall be separated from each other by not less than a one-hour fire-resistive occupancy separation. The number of control areas within a building used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four See Sections 204 and 800110 2 ^The aggregate quantity in use and storage shall not exceed the quantity listed for storage Quantities shall not exceed limits set forth in Section 800115 2 3The aggregate quantity of nonflammable solid and nonflammable or noncombustible kqmd hazardous materials within a single control area of Group M Occupan- cies used for retail sales may exceed the exempt amounts when such areas are in compliance with Section 800114 4For flammable and combustible liquids, see Article 79 See also Section 800111, Exception 2 5For aerosols, see Article 88 6Quannties may be increased 100 percent in sprmklered buildings When Footnote 10 also applies, the increase for both footnotes may be applied 7For storage and use of flammable and combustible liquids in Groups A, B, E, F, H, I, M, R, S and U Occupancies, see also UBC Sections 303 8,304 8,305 8,306 8,30713-30715, 308 8,309 8,310 12,3118 and 312 4 8For wholesale and retail sales use, see Section 7902 5 10 2 'Spray application of any quantity of flammable or combustible liquids shall be conducted as set forth in Article 45 10Quanbaes may be increased 100 percent when stored in approved storage cabinets, gas cabinets or exhausted enclosures as specified in Sections 8001 3 2, 8003 313 2 and 8003 3133 When Footnote 6 also applies, the increase for both footnotes may be applied l^The quantities permitted in a sprmklered building are not limited 12Penmtted in sprmklered buildings only None is allowed in unspnnklered buildings 13One pound ( 454 kg) of black sporting powder and 20 pounds (9 kg) of smokeless powder are permitted in sprmklered or unspnnklered buildings 14See definitions of Group H, Divisions 2 and 3 Occupancies in Section 216 15See Article 79 16A maximum quantity of 200 pounds (90 7 kg) of solid or 20 gallons (75 7 L) of liquid Class 3 oxidizers is allowed when such materials are necessary for mainte- nance purposes, operation or sanitation of equipment Storage containers and the manner of storage shall be approved i7For any amount, see Articles 28,30, 45,46,48,50,74,75,76,77 and 78 as applicable for the hazard category 1-210 199S CALIFORNIA FIRE CODE TABLE 800115-B TABLE BOOt,15-B—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A HEALTH HAZARD MAXIMUM QUANTITIES PER CONTROL AREA1-2 When two units are given, values within parentheses are In pounds (ibs > (Apply table as specified in Section 8001 15) MATERIAL 1 Carcinogens7 8 2 Corrosives 3 Highly toxics11 4 Irritants7 5 Radloacavesn Alpha emitters Beta emitters Gamma emitters 6 Sensmzers7 7 Other health 8 Toxics1 1 STORAGE1 Solid Pounds**8 x 0.4536 for kg 10,000.9 5,000 to NL 2mCi (74MB<j) 200 Ci (7.4 X 106 MBq) 14 Ci (52 x 1QS MBq) NX NX , 500 Qdb»&*(pounds) x 3.785 tori,x 04536 forte 1,000s 500 UO) N.L. 2mCi (74 MBq) 2000 (7 4 x 10s MBq) 14 Ci (52 x 10s MBq) NX NX, (500) GasCubic Pw»5 x 0028 form3 aio6* 810s 2012 810fi'9 02mCis (74MBq) 20 Ci* (7 4 X 10? MBq) 14Ci6 (52 X 104 MBq) 810s9 810«^ 8106 USE1— CLOSED SYSTEMS Solid Pounds5 x 04536 lor kg 10,000s 5,000 10 NL 2mCi (74 MBq) 200 Ci (7 4 x 106 MBq) 14 Ci (52 x 105 MBq) NX NX 500 Liquid Gallons*(pounds) x 3 785 for Lx 0.4536 for kg UOOO9 500 (10) NL 2mCi (74 MBq) 200 Ci (7 4 x 10s MBq) 14 Ci(52 x 10s MBq) NX NX (500) Gas „Cubic Past* x 0 028 tar m* 810s-9 S106 20" 8I06-9 02md ' (7 4 MBq) 20 Ci (74 x 10s MBq) 14Ci(52x10* MBq) 810«-9 810«.9 810" USE3— OPEN SYSTEMS Solid Pounds x 0 4536 for kg 5,00010 1,000s 3s 5,000s ImO (37 MBq) 100 Ci (3 7 x 1Q«MBq) Old (3700 MBq) 5,000s 5,000s 125^ Liquid Gallons(pounds) X 3 785 for Lx 04536 for kg 50010 100s (3)5 500s ImCi (37 MBq) 100 Ci (3 7 x 106 MBq) OlCi(3700 MBq) 500s 500s (125)5 I I I I I N L = Mot Limited 'Control areas shall be-separated from each other by not less than a one-hour fire-resistive occupancy separation The number of control areas within a building usedfor retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four See Sections 204 and 8001102 2See Section 8061 1 1, Exception 23The aggregate quantity in use and storage shall not exceed the quantity listed for storage Quantities shall not exceed limits set forth in Sections 8001 15 2and 8001 15.3. 4The aggregate quantity of nonflammable sohd and nonflammable or noncombusnble liquid health hazard materials within a single control area of Croup M Occu-pancies used for retail sales may exceed the exempt amounts when such areas are in compliance with Section 8001 14 5Quannnes may be increased 100 percent in spnnklered buildings 'When Footnote 6 also applies, the increase for both footnotes may be applied ^Quantities may be increased 100 percent when stored m approved storage cabinets, gas cabinets or exhausted enclosures as specified in Sections 8001 3 2, 8003 3 13 2 and 8003 3133 When Footnote 5 also applies, the increase for both footnotes may be applied7Carctnogens, irritants, sensitizers and other health hazards do not include commonly used building materials and consumer products which are not otherwise regu- lated, by this coder *See also applicable federal and state OSHA guidelines *The quantities allowed in a spnnklered building ace not limited when exhaust ventilation in accordance with Sections 8003 1 4, 8004 111, 8004 2.2 2 and8004.2.3 3, as applicable to the material condition, is provided 10The'quantities allowed in a spnnklered building are not limited when exhaust ventilation in accordance with Sections 8003 1 4. 8004.1 11, 8004 2 2 2 and8004.2 3 3 and spilfcontrot and secondary containment in accordance with Sections 8003 1 3,8004 14,8004 225 and 8004 2 3 6, as applicable to the material condition, is provided1'For special provisioiis. see Sections 8003.3,, 8003 12,80045 3 7 and 8004 3 6 12Pentntted only when located in approved gas cabinets, exhausted enclosures or gas rooms See Sections 8003 3132,8003 3 1 3 3 and 8003 3134 1 ^Licensed, sealed sources for instruments, calibration devices and equipment are exempt Licensing requirements and determination of whether a source is sealed01 ntmsealed shall be as set forth in Nuclear Regulatory Commission regulations Individual containers shall not exceed a quantity of 2 mCi (7 4 x 107 becquerels) for alpha emitters, 200 Ci (7 4 x 1Q12 becquetels) for beta emitters and 0 Id (3 7 x 109 becquerels) for gamma emitters Ci = curies, mG = nullicnries 1-211 TABLE 8001 15-C TABLE 8001 15-D 1998 CALIFORNIA FIRE CODE TABLE 8001.15-C—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A PHYSICAL HAZARD—MAXIMUM QUANTITIES ALLOWED IN AN OUTDOOR CONTROL AREA1- *• 3 CONOITIOH Material Flammable gas GaseousLiquefied Flammable solid Organic peroxide Organic peroxide Oxidizer Oxidizer gas GaseousLiquefied Pyrophonc Unstable(reactive) Water reactive Class UnclassifiedDetonable I II IIIIVV 4 32 1 4 32 1 32 1 STORAGE SolidPounds x 04536 lor kg NA NA 125 1 5 50 125 500 N.L J 10 250 4,000 NA NA 4 1 5 50 NJ. 5 50 125 liquid Gallons(pouadsl X 3 785 forLx 04536 for kg NA. 15 NA (i) (5)(50) (125) (500) NL (1)(10)(250) (4,000) NA 15 4 (I)(5) (50) N.L (5) (50) (125) GasCu FLItHTP X 00283torn* 750 NA. NA NA NA NA 1,500NA 50 1050 250 750 NA.NA NA US— CLOSED SYSTEM SolidPoundt X 04536 to* NANA 25 1/4 1SO125 500NL 2504,000 NANA 1 I4 SON.L 550 125 UqilU GtllMI x 3.789 forLx04Ui«orkg N A15 NA C/4) (1)(50) (125) (500) NL (2)(250) (4,000) NA 15 (1) (I4)(50) NL (5)(50) (125) GasCo Ftat (HP x 00283 tor m» 750 NA NA NA NANA NANANA NA NANANA 1,500NA 10 2 10250 N.L NA.NA NA, USE— OPEN SYSTEM Solid Ponads X 04531 tor kg NA NA 25 1/4 1 10 25100NL 2 50 1,000 NANA 0 1 10 N.L 1 10 25 Liquid Gallon* x 371$ forLX 04538 lor kg < NA NA NA C/4) (1)(10)(25)ClOO).NL C/4)(2)(50) (1,000) NANA 0 C/4) 10 NL (25) N A —Not applicable N.L —No limit 'For gallons of liquids, divide the amount in pounds by 102The aggregate quantities in storage and use shall not exceed the quantity listed for storage 3The aggregate quantity of nonflammable solid and nonflammable or noncombnstible liquid hazardous materials allowed in outdoor storage per single propertyunder the same ownership or control used for retail or wholesale sales is allowed to exceed the exempt amounts when such storage is in accordance with Sec-tion 8001 14 TABLE 8001 15-D-MATERIALS PRESENTING A HEALTH HAZARD- MAXIMUM QUANTITIES ALLOWED IN AN OUTDOOR CONTROL AREA'A3 MATERIAL Carcinogens Corrosives Highly toxics Irritants Other health hazards Radioactive367 Alpha emitters Beta emitterss Gamma emitters Sensiuzers Toxics STORAGE Solid Pound! x 04536 for kg 10,000 5,000 1 10,000 10,000 2mCi(74MBa) 200mQ(74 x 10* MBa) 14O(52 x10s MBa} 10,000 500 Liquid Qilloiu(pounds) x37»lorlX 0,4536 tor kg 1,000 500 0) 1,000 1,000 2mCi(74MBa) 200mCi(74 x 10«MBa) 14Ci(5.2 x 105 MBa) 1,000 (500) Gasta RalNTP xO 0213 (or •* 810 810 20* 810 810 2mCi(74MBa) 200mCi(74x 10* MBa) 14Ci(52 x 10s MBa) 810 810 UK-CLOSED SYSTEM Solid POOH* x0.4S36lorkg 10,000 5,000 1 10,000 10,000 0 0 0 10,000 500 Uqufd Gallon x 3785 forLX 0.4531 (or kg 1,000 500 (1) 1,000 1,000 0 0 0 1,000 50 GatCu R atNTP x 00283 (or m* 810 810 204 810 810 0 0 0 810 810 USE— OPEN SYSTEM SoNdPomds x 04536 for kg 5,000 1,000 L_ J/* 5,000 5,000 0 0 0 5,000 25 T-Uold Gallons (•Ml*) x37«5(ofLX 04536 tor kg 500 100 C/4) 500 500 0 0 0 500 (25) 'For gallons of liquids, divide the amount in pounds by 102The aggregate quantities in storage and use shall not exceed the quantity listed for storage 3The aggregate quantity of nonflammable solid and nonflammable or noncpmbusable liquid hazardous materials allowed in outdoor storage per single propertyunder the same ownership or control used for retail or wholesale sales is allowed to exceed the exempt amounts when such storage is in accordance with Sec- tion 8001 14 ••Permitted only when used in approved exhausted gas cabinets, exhausted enclosures or fume hoods 5For licensed nonsealed sources, the maximum quantity allowed and the maximum quantity per container m outdoor storage per single property under the same ownership or control are as follows alpha emitters, 2 millicunes (7 4 x 107 becquerels), beta emitters, 200 cones (7 4 x 10" becquerels), for gamma emitters, the maximum quantity allowed is 14 cunes (5 2 x 105 MBa) and the maximum quantity allowed per container is 0 1 cune (3 7 x 109 becquerels) ^Licensed, sealed sources in instruments, calibration devices and equipment are exempted7 mCi—miLucunesCi—cunes 1-212 1993 CALIFOfiNIA FIRE CODE . '• •. jBOOS8003,1.3,4 SECTION 8003- 80031 GeneraL •STORAGE 8003.1.1 Applicability. Storage of hazardous matenals where the aggregate quantity is in excess of the exempt amounts set forth m Section 8001 15 shaH be in accordance with Sections'gQOl andSOO? " Storage of hazardous matenals where the aggregate quantity does not exceed the exempt amounts set forth in Section 8001,15 shall be in accordance with Section 8001 For display and storage hr retail and wholesale sales occupan- cies, see Section 80G114 8003.1.2 Signs. Signs prohibiting smoking shall be provided in storage areas and within 25 feet (7620 mm) of outdoor storage areas, 8003.13 Spill control and secondary containment for hazard- ous materials, liquids and solids. 8003.1.3.1 Applicability. Rooms, buildings or areas used., for the storage of liquid or solid hazardous matenals shall be provided with spill control and secondary containment in accordance with Section 8003 1 3. EXCEPTK>N;Outdoor storage of containers on approved contain- ment pallets In accordance fcuh Section 8003 13A. 80031.3.2 Spill control for hazardous materials liquids. Rooms, buildings or areas used for tfie storage of hazardous mate- rials liquids in individual vessels having ^ capacity of more than 55 gallons C2Q8 2 B) or when the aggregate capacity of multiple vessels exceeds 1,000 gallons (37.851) shall be provided with spill control to prevent the flow q£ hquids to .adjoining areas Floors-m indoor locations and similar surfaces in outdoor loca- tions shall be constructed to contain a spill from the largest single vessel by one of the following methods- . .., .,, I Liquid-ught sloped or recessed floors m indoor location^ or similar areas in outdoor locations, ' 2. Liquid-tight floors in indoor locations or similar areas in out- door locations providedrwlfh Squid-tight raised or recessed alls or dikes, or 3. Sumps and collection systems. -• Except for surfacing, the floors, sills, dikes, sumps and collec- tion, systems shall be constructed of noneombustibk material, jand the kquid-tight seal sKafi be compatible with the material stored- When liquid-tight siHi or dikes are provided, they areaot required it perimeter openings which are provided with air open-grate trench across the opening that connects to an approved coEeetion system: !- " §003.1 J3 Secondary containment for hazardous niatexials b'qoida and solids. When required^ by Table 8003 "I-A, buildings, rooms or areas used for the storage of hazardous materials liquids or solids shall be provided sylth secondary cojataiatnent in accord- ance *ith mis section when the. capacity of an individual vessel or the aggregate capacity of multiple vessels exceeds tie following1 ;Capacity.ri3f ari'u«r!vidiial vessel B*ceeds-55 gat- Ions.(2e8.2 L) of the aggregate capacity; of multi- ple vessels exceeds LOGO gallons (37S5 L}. ., Capacity of ao .individual vessel exceeds 530 ponnds> ^248,8 kg) ot the aggregate capacity of multiple vessels exceeds 10,000 pounds (4524 8 kg)-" The building, room or area shall contain or drain the hazardous materials and fire-protection water through the use of one of the following methods , ; .. 1 Liquid-tight sloped or recessed floors m indoor locations, or similar areas in outdoor locations, 2 Liquid-tight floors in indoor locations or similar areas m put- door locationsprovided with liquid-tight raised or recessed sills or dikes, ' . - \ 3 Sumps and collection systems, or 4 Drainage systems leading io an approved location. Incompatible materials shall be separated from each other in the secondary containment system • •; Secondary containment for-indoor storage areas shall be designed to contain a spill from the largest vessel plus the design flow volume of fire-protection water calculated to discharge from the fire-extinguishing system over .the mnjtmum required system design area or area' of the room or area, in whichjthe storage is located, whichever is smaller, for a period of 20 minutes, ' Secondary containment for outdoor storage areas shall be designed to contain a spill from the largest individual vessel. If the area is apea to rainfall, secondary Containment shall be designed to include the volume, of a 24-hour rainfall as determined by a 25-year storm and provisions shall be made to drain accumula- tions of ground wafer and jain water . (., -- , " .- A monitoring method shall be provided to detect hazardous materials m the secondary containment system The monitoring method is allowed to be visual mspeetion of Jhepiunaryxjr secon- dary containment, or ojher approved rneans. Where secondary containment is subject to the intrusion of water, a ntonitonng method for detecting water shall be provided; Wben monitoring devices are provided, they shall be connected tix distinct visual or audible alarms ;•• '• " " - Drainage systems shall be ui accordance with the Plumbing Code and the following: " " •, , ,-.-, 1 The slope of floors m indoor locations or similar areas in out- door locations to drams shall not b> less that* 1 percent, .. 2 Drams from indoor 'storageareas'shaft bei sized to carry the volume of the fire-protection water as determined tfy the design density discharged from the automatic fire-extinguismng system over the minimum required systein desigfi area or. area of trie-room or area in which the storage is located, whichever is smaller, 3 Drains from outdoor Storage areas shall be sized to carry the volume of the fire flfcw and Che'volume of a 24-hout"ramfaB'as determined by a 2^-year-.sU>rm, - ^ ,-, ' \ .„ 4. Matenals of coHStruction for drainage systems shall be Com- patible w*th the materials stored, , . yl" . - " ' • 5: Incompatible materials shall be separated from, each other in the drainage system, apd '-:* !"\ ': ' " ~' ,**'• as a subsfitote for Solids. 6 Drains shall tenrrifiate m an approVBd location .away from buildings, valves, rneans. of 'egress. Sis access roadways, adjoin- ing property and storm-drains '" .u "' 8QQ3.1.3K4 Containment pall spill conjroljnjlsecpadary c accordance wifli the exe^jtwo jft-§ejctionI8CiC!3,i,iY,<!on«airanent pallets shall conrofy swSb me fcljowjag; ; ! . , 1 A liquid-tight Surnp accessible for visual inspection Shall be provided, ' ' x .; ' 2 The sump shall be designed to contanvnof fos than 66 gallons (249 » L), • - = _ , ,-• - :. 1997 UNIFORM FIRE CODE 80031.15 TABLE 8003.1 -A 8003.1.15 Required detached storage. Group H Occupancies containing quantities of hazardous materials in excess of those set forth in Table 8003 1-B shall be in buildings used for no other pur- pose, shall not exceed one story in height and shall be without basements, crawl spaces or other under-floor spaces TABLE 8003 1-A—REQUIRED SECONDARY CONTAINMENT—HAZARDOUS MATERIALS SOUDS AND LIQUIDS STORAGE MATERIAL INDOOR STORAGE Solids Liquid* OUTDOOR STORAGE Solid* Liquid* 1. Physical Hazard Materials Combustible dusts Combustible liquids Class n Class m- A Class m-B Cryogenic kquids Explosives Flammable liquids Class I-A Class I-B Class I-C Flammable solids Organic peroxides Ondizers Class UD Class I Class n Class m Class IV Class V Class 4 Class 3 Class 2 Class 1 Pyrophoncs Unstable (reactives) Water reactives Class 4 Class 3 Class! Class 1 Class 3 Class 2 Class 1 MR NA NA NA NA NA See Article 79 See Article 79 See Article 79 See Article 75 See Article 77 NA NA NA NR R R R R R NR R R R R NR R R R NR R R NR See Article 79 See Article 79 See Article 79 NA R R R R R NR R R R R R R R R NR R R NR NR NA NA NA NA NA See Article 79 See Article 79 See Article 79 See Article 75 See Article 77 NA NA NA NR NR NR NR NR NR NR NR NR NR NR NR R R R R R R R See Article 79 See Article 79 See Article 79 NA NR NR NR NR NR NR NR NR NR NR R R R R R R R R 2. Health Hazard Materials Carcinogens Corrosives Highly toxics Irritants Other health hazards Radioactrves Sensibzers Toxics NR NR R NR NR R NR R NR R R NR NR R NR R NR NR R NR NR R NR R R R R R R R R R NA = Not Applicable NR = Not Required R = Required UD - Unclassified Detonatable 1-215 TILE-MATE Dual Purpose Thin-Set Mortars PRODUCT DESCRIPTION TILE-MATE Thin-Set Mortars are composed of select, proprietary chemicals, carefully graded aggregates *"<*Portland cement. TILE-MATE Thin-Set Mortars are pre*btended and ready to use. TILE-MATE Mortars are recommended for setting ceramic tile and dimensional stone over brick, cement plaster, concrete, concrete block and piass mesh mortar units. When used In conjunction with HYDRQMENT Multi-Purpose Acrylic Latex Additive, TILE-MATE Mortars can be used for setting tile over structurally sound, exterior grade plywood and for setting glass block. All TILE-MATE Thin-Set Mortars are suitable for use on horizontal and vertical surfaces. Product selection should be based on the absorptive characteristics of the tile being installed Ail TILE-MATEThirvSet Mortars can be used for both Interior and exterior applications. TILE-MATE 710/780/70713 This product la the premium TILE-MATE Thin-Setting System. TILE-MATE 710 and 760 are specially designed for setting absorptive, semi-vitreous and vitreous tiles, marble and dimensional stone, while giving maximum work-ability/troweling characteristics. 710-whtte, 700-grey, 70713-whlte (West Coast) TILE-MATE HOT WEATHER FORMULA Specially formulated, TILE-MATE Hot Weather Formula l» designed lor setting ail semi-vitreous and vitreous tile,marble, dimensional stone, slate and absorptive tile when job site conditions require extended open time at highertemperatures,Color: white TILE-MATE 972 MP This dual purpose thin-set mortar is designed for setting quarry tile, pavers, ceramic mosaics, slate, stone andall vitreous, and semi-vitreous tile.Coior gray TILE-MATE 971 (Floors Only) TILE-MATE 971 is a high grade thin-set designed to set quarry tile, pavers, ceramic mosaics and all vitreous, and eeml-vllreous tile. Color: gray TYPICAL PHYSICAL PROPERTIES Ail TILE-MATE Mortars meet or exceed ANSI A 116.1-1985. All TILE-MATE Mortars meet or exceed ANSI A 118.4-1985 for latex-Portland cement mortar when used with HYOROMENT Multi-Purpoae Acrylic Latex Mortar Admixture and Grout Additive. Boston Street, Middtaton. MA 01949 (800} 7-BOSTIK . (909) 7770100 . Technical SSr/ic8» (800) 523^530 CLEVELAND. OH • U3NGB&«CH,CA • CONYERS.QA • DALUS, TX • Easy mixing jh 'High Compresslve strengths High Tensile strengths Excellent Initial grab PRODUCT FEATURES AND BENEFITS * Non shrinking * Excellent Workability * Select aggregate Gradation IMPORTANT For all back-mounted tile*, be certain that sufficient TILE-MATE is used to bond each Individual tile. COVERAGE For ail TILE-MATE Thin-Set Mortars up to 1,3 square feet per pound at 3/32* to 1/8" bed thickness PACKAGING Moisture-proof three-ply SO pound sacks. DIRECTIONS FOR USE Mixing; Add 5 to 6 quarts of Hydroment Multi-Purpose Latex Additive or cool, clean drinkable water ONLY to 50 pounds o? TILE-MATE Thin-Set Mortars; and mix to a stiff, trowelable consistency. Use only slow speed bucket mixers or mortar boxes for mixing, do not use high speed drills (greater than 200 rprrfs). High speed mixing entraps alt* and decreases the ultimate atrengthsof the mortar. Allow the mixture to slake lor 15 minutes and remix before applying. TILE-MATE Thin-Set Mortars should be remixed occasionally during use, The pot life of TILE-MATE Thin-Set Mortars Is approximately 2 to 3 hours depending upon temperature and humidity. Requirements For Plywood SuMtoorc (Interior U*e Only): Maximum Joist spacing shall be 16" on center with a maximum deflection of I/360 of the span Plywood type shall be underlayment with exterior glue or exterior type C-C plugged (exterior underlayment or better), if the existing floor Is less than 1" thick, glue and nail 1/2" plywood to the floor. Glue and nail using 5d or 6d cement ooated or screw shank nails on 8" center along with panel edges and amaximum 8" on center each way throughout the panel. Allow 1/4" gap between underlayment sheet edgee and ail areas where they abut walls, drains, posts, eta These areas shall be filled with TILE-MATE Thin-Set Mortars when the tiles ana installed Dean and rough sand the plywood. Due to the limitations of plywood e« « auosfrafe material, TILE-MATE Thin-Set Mortars i» not intended for use on plywood in exterior/ wet applications or on plywood in heavy traffic areas. Substrate deflection Is greater than 1/360 but less than 1/240 (up to 1* per 20 ft. apan). TILE-MATE Thin-Set Mortars must be mixed with 6-7 quarts of Flex-a-Lastio Mortar Admixture per SO pounds of mortar. Caution: Flex-a-Lastlc Is not recommended for use with TILE-MATE 972 MR Application: All surfaces to receive tile must be clean and free of dust, grease, oil, curi ng compounds and any foreign material. Apply a thin coat of TILE-MATE Thin-Set Mortars with the flat edge of the trowel to achieve * good mechanicalbond Then apply the mortar with the appropriate sized notch trowel (See Illustration Below) Recomb the mortarwith a notched trowel if any evidence of skinning or setting is evident, Apply TILE-MATE Thin-set Mortara to anarea no greater than can be tiled in 30-46 minutes. Always test the bond of backmounted sheets of tile to insure adhesion of the full sheet. Suggested Notched Trow*J* For Maximum Performance aiS'x5/32'Wxl/4' inn 1/2" x 1/2" ceramic mosaics mounted oanunlo* 4*x4*44*x8* 8*x6* 4.8*x8* 8*xfl"*1« cenmtos & p*v»m quarry tile lugged back & Mexican paver tile Tiling: Tiie should be applied with a twisting motion Into a fresh bed of TILE-MATE Thin-Set Mortars. Alwaye beat the tile In with a beat ing block as soon as possible to Insure maximum contact and bond. A finished mortar bed thick- ness 3/32" to 1/6" thick after "beat Irf is required. Curing: All traffic should be kept off the installation for 72 hours. Grouting: Grouting may begin using Hydroment Joint Filler/ Ceramic Tile Grout, Hydroment 1900, or U-Poxy AAR II, only aftera firm set has taken place. Set times will vary depending upon the mortar selected for use, ambient, slab and material temperatures. Follow normal grouting clean-up procedures. When U-Poxy AAR II is ueed for grouting, the installation must be protected tor 48 hours before grouting com- m«no«*< Irt in*te>ll«tf*n» wh«rw •vWtret* <f«fl«*tion !• greaterth«n 1/490 bv* )«*« than I/24O, i»n«Mlurt*rt Mudnsmant Multi-Purpose Acrylic must be ueed to mix Hydroment Joint Filler/Ceramic Tile Grout. Marble installations with grout joints 1/16* or less may be grouted wHh Hydroment Dry Tiie Grout Cleaning: Clean excess mortar as work progresses. Do not allow to dry on surface of tila TM IQ HYDROMENT® FLEX-A-LASTIC™ FLEXIBLE MORTAR ADMIXTURE PRODUCT DESCRIPTIONHydromenr Flex-A-Lastic™ Mortar Admixture is a new generation acrylic polymer emulsion designed to Incorporate flexibility and superior adhesive perfcrmanca into Tile-Mate Thin Set Mortars. When used to mix Tile-Mate* 710/ 713,760, or§71 Thin Set Mortars, Hydroment Fiex-A-Lastic provides the following performance benefits • Outstanding Flexural and Tensile Strengths • Outstanding Shear Bond Strengths • Tenacious Grab • Bonding Capabilities to "difficult substrates" such as vinyl composition ttie, vinyl flooring, asphalt- based cutback adhesive residue and exterior grade plywood • Outstanding Freeze/Thaw Resistance • Self CurlnglNon Reemulstfying • Can be used to set ceramic tile, synthetic marble and stone in installations subject to deflection of up to 1/240• Can be used to Insiall heavy/large ceramic tile (such as 12* x 12" x3/8") marble and stone vertically. PRODUCT USES Hydroment Flex-A-Lastic when used to mix Tile-Mate 710/713,760, or 971 is designed to set all types of ceramic We, marble and dimensional atone indoors and outdoors; for both vertical and horizontal installations. RECOMMENDED SUBSTRATES: Flex4-Las1ic modified Thin Sets are designed for use over • Concrete • Exterior Grade Rywood • Asphalt Based Cutback Adhesive Residue • Cementitious Backer Units • Hydroment* Ultra-Set™ • Existing Ceramic Tile • Existing Vinyl Composition Tile/Vinyl Flooring « Existing Brick • Gypsum Plaster (when coated with Hydroment Ultra-Set) • Gypsum Board (when coaled with Hydroment Ultra-Set) • Formica and other Laminated Surfaces STANDARDS Hydroment Flex-A-Lastic meets or exceeds ANS1118.4 when mixed with Tile-Mate 710/713,760, or 971 Thin Set Mortar Typical Physical Properties wHh Tito-Mate 710/713, 760, w 971 Thin Sets Open Time 70'FAdjustability 70'F Coverage Flexural Strength Tensile Strength Shear Strength Ceramic Mosaic Tile Quarry to Wood 90-120 minutes60-80 minutes 70-80 sq. ft. at 1/8" bed thickness 14 days 635 psl 14 days 400 psl 28 days 350 psi Shear Strength (psi)7 day 2»<tev 350 482 .. 170 190 Packaging; 2,5, and 56 galton containers I O 1 Boston StPMt. MWcflfton, KM 01949 (BOO) 7-80ST1K - (SOB) 777-0100 • Technical Services (SOO) 523-6530 MOWS'BWP o SUBSTRATE PREPARATION Ail surfaces to receive tile must be clean and free of dust, Qr«as«, oil, curing compounds, vinyl floor waxes and any other foreign material. All substrates must be properly anchored, structurally soundand free from deflection in excess of 1/240, Plywood floors must be exterior grade. Maximum joist spacing shall be 16" on center with a maximum deflection of I/240 of the span. Plywood shall be underiayment type C-C plugged (exterior underlayment or belter), if the existing floor is lew than 1" thick, gJueand nail 1/2* plywood to the floor. Glue and nail using 5d or 6d cement coated or screw-shank nails 8" on center along panel edges and a maximum 6" on center each way throughout the panel Allow 1/4* gap between underlayment srvsei edges and all areas where they abut waits, drains, posts, etc. These areas are to be filled with Hydroment Flex-A-Laaticmodified Thin Set Mortar. Clean and rough sand the plywood. NOTE: Due to the limitations of plywood as a substrate material, this product is not Intended for use on plywood in exterior/wet applications or on plywood in heavy traffic areas. Caution: Due to the relatively low compresslve strength and over-all softness of quarried marble, natural marble should never be installed over substrates with deflection In excess of 1/360. MIXING Ado 6-7 quarts of Flex-A-Lastic Mortar Admixture per 50 pounds of Tile-Mate Thin Set Mortar and mix to scraamy consistency, use only slow speed rmxers or mortar boxes tor mixing; do not use high speed drills (greaterthan 200 RPM's). Allow the mlxturetoslake for 10-15 mmules and remix Do not add water or any other liquids before, during or after the Initial mixing APPLICATION Apply a thin coat of Thin Set Mortar with the flat edge of the trowel to achieve a good mechanical bond to the substrate, than comb the mortar with the appropriate sized notched trowel as indicated below Recomb the mortar II any evidence of skinning is present. Temperatures and humidity will effect open time, therefore, both Fiex-A-Lastte and Tile-Male should be kept in a cool, shaded area to control the products setting characteristics. Hot ambient and material temperatures (greater than 85'F) wrll acceler- ate the set of Ftex-A-Lastlc modified Thin Set Mortars, Cooler ambient and material temperatures (less than 65* F) will retard the set time. It te advisable to spread no more Thin Set Mortar than can be tiledwithin 30-40 minutes. OVER EXISTING VINYL FLOORING Hydroment Ftex-A-Lastic modified Tile-Mate Thin Set Mortar can be used to set tile over existing vinyl flooring, provided It is well bonded to the substrate. Any loose pieces of vinyl tile, flooring or cutback adhesive should be removed prior to the application of Flex-A-Laatlc; again making suns the exposedsubstrate Is suitable for application. Follow mixing Instructions listed above. Caution; Do not sand or abrade vinyl asbestos tfte prior to applying Flex-A-Lastic modified Tile-Mate Thin Set Mortar. The use of Flex-A-lastic is not recommended over cushion backed sheet vinyl flooring. OVER HYDROMENT ULTRA-SET* Refer to Ultra-Set installation Instructions and apply Ultra-Sat as directed. Application of Flex-A-Last ic modified thin set mortar over Ultra-Set must commence within 72 hours of Ultra-Set curing. GROUTING Grouting may begin using Hydroment Joint FWar/Ceramic Tile Grout Hydroment 1800, or U-Poxy AARII, only after a firm set haa taken place. Set times wilt vary depending upon the mortar selected for use; ambient, slab and material temperatures. Follow normal grouting clean-up procedures When U-Poxy AAR H is used for grouting,allow the FleXiA-Lastic modified mortar to cure for 48 hours before grouting commences. In InstaHatkms where substrata deflection (s greater than I/360 but (ess than I/24Q, undiluted Hydroment Multi-purpose Acrylic must be used to mix Hydroment Joint Filler/ Ceramic Tile Grout. Marble installations with grout Joints in&" or less may be grouted with HydromentDry Tile Grout. CLEAN UP Clean-up should begin as soon as possible due to the superior adhesive capabilities of Flex-A-Lastic modified Thin Sets. Partially cured materiel may be removed from toots using Hydroment Remove and a scrubbing pad Fully cured material Is extremely difficult to remove. Suggested Notched Trowels For Maximum Performance ceramic mosaics mounted mosaics Avg, 73-85 Sq, ft. 4" X 4" & 4" X S" ceramics & pavers Avg. 70-80 sq.ft. 1/4 1/3" X t/3* 8' xe'46'xa"quarry ttla Awg. 50-60 sq ft. 8" X 8* & 12" X 12* luggad back & Maxloan p«ver tile Av0,35-40 *q. ft. 2503 E VERNON AVE LOS ANGELES, CA 90058 (213; 5881281 EMERGENCY PHONE NUMBER (24 HRS) US,- CHEMTREC (800) 424-9900 OR (703) 527-38$ CANADA • CANUTEC (613)995-666$ DATS PREPARED MSOS NUMBER 3/2S/95 3380/95 33SCSIUCOME SEALANT, CLEAR CHEMICAL PRODUCT IDENTIFICATION GENERIC OESCfHnQR. SIICONE ELASTOMER PHYSICAL TOW PASTE COLOR. CLEM ODOR ACETIC ACID OOOfl NPPA PROFILE' HEALTH I FIAWMABIUTY t, REACTIVITY C NOTE- «FRA » NATIONAL FIFE PROTECTION ASSOQATON OSHA HAZARDOUS INGREDIENTS CAS NUMBER OQfcSWS 007831Sffl 2 11 COMPONENT METHYLTfliACeTOmiLANE SILtCA. AMORPHOUS ETHYLTPJAC£7CXYSILANE EXPOSURE UNITSsee ACETIC AGIO COMMENTS.OBSBWE PARTCULxres UMTS. OSHA PELM-.A ••waf. « <v*w*>w,«. nwvn I4.V inn IU SEE ACETIC ACID COMMENTS i ntlftt fi mnftfl COMMENTS JEL TWA 10 wr. AND ACSIH nv m* 10 ppn STSI is mm EFFECTS OF OVEREXPOSURE ACUTE EFFECTS: MS; DffiECT CONTACT IRRITATES MODERATELY JW7H REDNESS AMD SWELLINGWIN A iiNfii P snnRT Fvprvtueg JLEBS THAN s< iwwnc) MW mnmrc ncrwrco moLCNCies COHTAIT (« I IhNAUTION- VAPOR OVEREXPOSURE MAY IRRffATE EVES, NOSE AND THROAT OMU SMALL AMOUNTS TRANSFERRED TO THE MOUTH 3V FINGERS OUR NG ! USE. ETC., SHOULD NOT INJURE SWAUOWINS LARGE AMOUNTS MAV CAUSE OfaESUVE DISCOMFORT REPEATED EXPOSURE EFFECTS'SKIN: NONE KNOWN INHALATION. NONE KNOWN ORAL ISCNE KNOWN SPECIAL HAZARDS. THIS MATERIAL CONTAINS THE FOLLOWING COUPONEHTS WITH THE SPECIAL HAZARDS USTTHJ BELOW CARCINOGENS. NONE KNOWN; T5BATOCEKS- NONE KNOWN. MUTAOENS, HONE KNOWN, M»HOOUCT1VS TOXWS MCAE KNOWN SUSmZEffS. NOME KNOWN THE ABOVE LISTED POTENTIAL EFFECTS Of QVEREXPOSJRE ABE BASED ON ACTUAL DATA. RESULTS OF STUDIES PERFORMED UPON SIMILAR COMPOSITIONS COMPONENT DATA ANOOB EXPEFIT REVIEW Of TH£ PjHOOUCT j FIRST AID MEASURES EYES MUEDIATEiy RUSH WITH WATER FOR tS lANOTES. SET MEDICAL ATtKTIOM. SKH REMOVE FROM SKIN AND WASH THOrlOUGRY MTH SOAP ANC WATER OR WATERLESS CLSAN5FR GET MEDCAL jITTENIOM lc IRRITATION OF OTHER ILL EFFECTS DEWB.OP OR PERSIST INHALATION. REMOVE TO FRESH AIR OPAL MO FfflST AIQ SHOULD E£ NEEDED COMMENTS! T1EAT ACCOJDMC 7Q.P6HbOI3 COMOTON AND SPECIFICS OF EXPOSURE. FiRE FIGHTING MEASURE? FLASH coir nausea ew» »or APHJCMLE-SOLID.AUWIBMtlOH TtWflWTUWt NOT DETEPMINEO UMTS IN AIR, NOT OSTEPMINSD BnWGlBSHHW MH«fc CXRBOK OIC'XIDE (CO,) WATER WATEBF03 (W SfBAY) OPV CHEMICAL fOAM, UN9UTTABU !JmnaUlS«« MCOM FIRE FISHTma PROCEDURES! SELF CONTAINED 3REATH)M3 APMRATUS AND PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING OftVOCALS. IF URGE AMOUNT 1$ WVCiVED EVACUATE AREA. UNUSUAL F1M HAZARDS. NONE HAZARDOUS DECOttPOSmON PBOOUCTS, THERMAL BREAKDOWN OF THIS PRODUCT DURING FIRE OB VERY HIGH HEAT CONDITIONS MAv EVOLVE THE FOLLOWING HAZARDOUS DECOMPOSITION PRODUCTS. SILICON DIOXIDE, CARBON OM08S AND TPACE Of WCOMPLETa1* BURNED CARBON COMPOUNDS FORMALDEHYDE. J I i I ACCIDENfAL RELEASE MEASURE: CONTAINMtHTCUAIWP- DISPOSAL OF COLLECTEO PRODUCT, ncSiCUES, AND CUAKUP MATERIALS MAY BE QOVERNMENTALLY FEGULATtD. QB&WE ALL APRICHB-E LOCAu, SW t, AND FEDERAL AASTE MANAQEMENT BEGULATiCNS. SCFWC UP AND CONTAIN FOR SALVAGE OR DISPOSAL OBSERVE ALL PER 90NAL PfOTECTIOh EOUIPUENT flECCMUENOATIONS DESCfflBEO N SECTIONS S AND (L LQfiAi, gj^p ^H FFDFBAI RePnRT!Nn flFniliR^MRiirS UtY U a-ii.ua un MtxtMtb Uf Iris MATERIAL INTO THE ENVIRONMENT SEE APRXABLE SEfiULATORY COMHJAMCE INFORMATION 1*4 SECTON IS KOTE SEE SECTION 6 RW PERSONAL PROTECTIVE EQUIPMENT FOR 9H-S HANDLING AND STORAGE hANDUWO- NO SPECIAL PPECAUTIONS I STOBAQE KE£i» CONTAWEft ClOSF.0 AND STORE AWAY FHOM WATER QB MOISTURE. PRODUCT: 33SC SILICONE SEALANT, CLEAR EXPOSURE CONTROLS/PERSONAL PROTECTION GENERAL VENTILATION: RECOMMENDEDENtiMUMiO CONTROLS LOCAL EXHAUST- RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT FOR ROUTINE HANDLING EVES USE PROPER PROTECTION SAFETY GLASSES AS A MNMUM SKM' WASHING AT MEALTIME AND END OF SHIFT IS AOEOIttg »UTA«J GLOWS: NO SPECIAL PROTECTION NEEDED NHALATtON: USE RESPIRATORY PROTECTION UNLESS ADEQUATE LOCAL EXHAUST VENTiLATION 1$ PROVIDED OR AIR SAMPLING DATA SHOW EXPOSURES ARE WITHIN RECOMMENDED EXPOSURE GUIDELINES INDUSTRIAL HYGIENE PERSONNEL CAN ASSIST W JUDQMB THE ADEQUACY OF EXISTING CNQMEERING CONTROLS. SUITABLE KEPIRMOD ORGANIC VAPOR TYPE PERSONAL PROTECTIVE EQUIPMEWT FOR SPILLS. EYE4. USE PROPER PROTECTION,- SAFETY QUSSES AS A MIMWUM SKM WASHIN3 AT MEALTIME AMD END OF SHIFT IS ADEOUAT WHALATOM/SUTABLJ RESPIRATOR- USE RESPIRATORY PROTECTION UNLESS AD60UATE LOCAL EXHAUST VENTILATION IS PRO- VIDED OP. AIR SAMPLING DATA SNOW EXPOSURES ABE WITHN RECOMMENDED EXPOSURE GUIDELINES INDUSTRIAL HYQIENE PERSOWEL CAN ASSIST X JUDGING THE ADEQUACY OF EXISTING ENOHHEERINQ CONTROLS. PMCAUTIOMARY MEASURES AVOID EVE CONTACT AVOO MEflWNO VAPOR KEEP CON- TAINER CLOSED. USE REASONABLE CARE. COMMENT* PRODUCT EVOLVES ACETIC AGIO (HOAe) WHEN EXPOSED TO AKTER OR HUMID AIR PROVIDE VENTI- LATION DUPING USe TO CONTROL HOAe WITHIN EXPOSURE SUBBJNES (SEE SECTOK 2) OB US6 RESPIRATORY PROTECTION MOTiS' THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HAK5UN3 USE XT ELEVATED TEMPEHAf UHE, OR AEHOSOUSP1WV APPLICATIONS. MAY REQUIRE ADDED PRECAUTIONS. IX PHYSICAL AND CHFMICAL PROPERTIES PHYSCALFBTOfc BASTESPECIFIC (MAvmr • »c KM BOUNG POINT. NOT APPLICABLE SQLUBIUTVN WATER NONE COUMt COLORLESS OOOfl, ACETC ACC ODOR V18COSITY. MOT APPLICABLE FUEEZWO/MeLTWCI POHT NOT OETERMWEO V«K» PRESSURE • MC- NOT APPLICABLE VAPOR DENOTT NOT APPLICABLE pH. NOT APPUCABLE VOLATU COffTENT- NOT APPLICABLE AOTE TW A60VE FORMATION IS »K^ MTSVDB) FOR USE IN PflERM .'ABILITY AND REACTIVITY HAZARDOUS WLYMilBZATION: HAZAROOCS POtnteUDBBtOHWHU NOT OCCUR. CONOmOHS TO KOD NONE MATHUAL» TO MOIO, OX!Oa«0 MATtBIAL CAN CAUSE A REACTiON COBHEHTS WTER,, MOISTURE, OR HIMID Alfl CAN CAUSE HAZARDOUS VAPORS TO FORM AS OE3Cffi96O IN SECTION 2. 5OXICOLOGICAL INFORMATION I OPTBMALSKTIO*"- OOMPLETE WPOWMMJJN NOTVEt AVAtUBLE DISPOSAL INFCHMATION RCRA HAZAfO CUM HOCn Stt) WHEN A DECISION 1$ MADE TO DISCARD THIS MATERIAL AS RECEIVED, IS IT CLASSIFIED AS A HAZARDOUS WASTE? NO ra»E«AHWWOW» WASTE CODS- W CHARACTERISTIC WASTE. ISNTlABLe-NA COMOSWE NA WACTWE- HA TOP NA S1WE OH LOCAL LAUVS MAV IMPOSE ADDITIONAL H6GULATORY BEOUIBaeHTS REQAROINa DISPOSAL RAN3PORT INFORMATION DOT IHnMWMIDN (MCnt TRttl) I HAZARD CUSS NOT APPUCABLE ! HOT APPLICABLE iKKAPPUCABLE HAZAWTMlMteM. «*Mfc NOT APPUCA0LE PACMMaaROBP-WTAPPUCABie Msoe coMPiy wimwe OSHAMAWIBCONTENTS Of TJCA STATUS- ALL CHEM'CAL SUBSTANCES FOUND N THIS PRODUCT COMPU1 WITH THE TOXIC SUBSTANCES CONTROL ACT INVENTORY REPORTING REQUfiEMENTS. mSMMITUH CHEMICAL U8TINOS. SB«X«M«fiXT«MeU HAZARDOUS SUBSTIWCE3. NONE 8ECTIOH HWCSROAHAMROOUSIUMWiCEft NONE SECTION Jit MZMO CLASS ACUTE. XES CHRONIC (C FIBS (fi PPESSUSE. {JQ REACTIVE (ffi SeCTKXI 313 TOMC CNEMCAL9' NONE PRESENT OB N0« PRESENT W flBaULAT£0 aUAMTireS SUPPUNCNTAL SWE COKPUANCE INFORMATION CALIFORNIA WABMNO: THIS PROOUCT CONTAINS THE FOLLOWING! CHEMCALCS) USTED SY THE STATE OP CAUFOPNIA UNDER THE SAFE DRNQNG WATER AND TO CAUSE CANCER NONE KNOVm WMNMC THIS PRODUCT CONTAINS THE FOUOWMG CHEMCAL® USTED 8Y THE SWE OR CALKWNIA UNDER THE, SAPE DRMKINO IMIER AND CAS NUMBER 370131878 OOUS3M3 WTS (3 2 I COMPONENT DIMETHYL SlLOXANs, HYDBOXY-TEFWINATEO METHYLTRtACETOXYSILANE OC7S318B TO CAUSE BIRTH DEFECTS OR OTHER ftEPflDOUCTIYt HARM WD,* KNOWN COMPONENT SILICA CAS NUMBER CASMUMBER MTT% 11 007431869 11 SILICA AMORPHOUS FUMED: I16S5 WT% COMPONENT 63 DIMETHYL SUKANE 11 SILICA. AMORPHOUS \\ARHAN J Y INFORMATION T«S»fCn*TO«ISOFf«EOMaOOOF*TOAB TYPICAL VMOfflSANOWTAS A H£PIHBYIW3£Tr«fffiCC*«EWlEDINCLSTlMLHYO®ffi AND SAfE HANDLING 1^^ EACH USSR SHOULD REVCW 7HESS RECOMMENOffilONS IN THE SPSORC COHTEXT OP Trffi INT6NDEO USE AND 36TERWE VHHETHER THEY ARE APPROPRIATE j " " AV0342*-C REV a/96 •MATERIAL SAFETY DATA SHEET THE GIBSON-HOMANS COMPANY 8701.1 PAGE 1 ABBREVIATIONS NA = NOT APPLICABLE H5ALIS " 2ND = NOT DETERMINED FLAMMABILITY = 0NE = NOT ESTABLISHED REACTIVITY - 0PERSONAL PROTECTION - + SECTION I-MATERIAL IDENTIFICATION AND USE + SEE SECTION VIII MATERiAL'NAME/IDENTIFIERr'sHUR-STIK C-ll ULTRA-CLEAR ADHMANUFACTURERS NAME AND ADDRESS. GIBSON-ROMANS COMPANY1755 ENTERPRISE PARKWAY TWINSBURG, OHIO 44087 EMERGENCY TELEPHONE NO.: (DAY) 330/425-3255 (24 HOUR) 440/843-2982DATE PREPARED: JANUARY 20, 1988 REVISED: DECEMBER 6, 1994 CHEMICAL FAMILY: MIXTURE CHEMICAL FORMULA/MOLECULAR WT: NATRADE NAME AND SYNONYMS: NAMATERIAL USE: WALLCOVERING ADHESIVE SECTION II-HAZARDOUS INGREDIENTS CHEMicAL~NAME OSHA-PEL ACGIH-TLV LD50/LC50 % WT NA ... - CAS #- - - -CARCINOGEN: -Sara Title III, Sect 313 reportable- - i i i I I I SECTION III-PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT: 212 DEG. F. VAPOR PRESSURE (MM) : 25 DEG C 18 MMVAPOR DENSITY(AIR-1): >1SPECIFIC GRAVITY/DENSITY(G/ML): 1 0-1 05 MELTING/FREEZING POINT: NAEVAPORATION RATE(BUAC=1): <1 SOLUBILITY IN WATER. MISCIBLE%VOLATILE BY VOLUME: 85-95 PH: 7.0-9.0COEFFICIENT OF WATER/OIL DISTRIBUTION: ND ODOR THRESHOLD (PPM): NDAPPEARANCE, PHYSICAL STATE AND ODOR: CLEAR, TRANSLUCENT PASTE SECTION IV-FIRE AND EXPLOSION DATA FLASH POINT: >200 DEG. F - WATER BASED UPPER EXPLOSION LIMIT: NA AUTO IGNITION TEMPERATURE: NA LOWER EXPLOSION LIMIT: NASENSITIVITY TO CHEMICAL IMPACT: NA RATE OF BURNING NAEXPLOSIVE POWER: NA SENSITIVITY TO STATIC DISCHARGE NAEXTINGUISHING MEDIA: NA SPECIAL FIRE FIGHTING PROCEDURES: NA UNUSUAL FIRE AND EXPLOSION HAZARDS- PRODUCT WILL NOT BURN AS SUPPLIED DRIEDFILM MAY BURN IF SUBJECT TO SOURCE OF IGNITION.FLAMMABILITY• NO UNDER WHAT CONDITIONS: NA ess ssMViE8 = s •Ma> = =ss3R3s:s:==:s sss — — = ssss—— ass —scsssjsssssajssssssr *ss = = = «s»=:s = s*fcm«»*»«*»«««H SECTION V-REACTIVITY DATA STABiLITY-MATERIAL " IS " " STABLECONDITIONS TO AVOID- NA INCOMPATIBILITY (MATERIALS TO AVOID): STRONG OXIDIZERSHAZARDOUS DECOMPOSITION/COMBUSTION PRODUCTS: BURNING OF DRIED FILM MAY RE-LEASE OXIDES OF CARBON AND NITROGEN.HAZARDOUS POLYMERIZATION: WILL NOT OCCURCONDITIONS TO AVOID: NA SECTION VI-HEALTH HAZARD DATA PRiMARY~ROUTES OF ENTRY-TsKIN - INGESTIONEFFECTS OF OVEREXPOSURE, CHRONIC- NONE KNOWN ^^l^gOSgRS^ACUTK^SK^^Y^^S^^^^TION. ^.. «„ MATERIAL SAFETY DATA SHEET THE GIBSON-HOMANS COMPANY 8701.1 PAGE 2 EMERGENCY AND FIRST AID PROCEDURES- SKIN- WASH WITH SOAP AND WATER. EYES- FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. INGESTION: SEEK MEDICAL ATTENTION.MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE- PRE-EXISTING SKIN DISORDERS CARCINOGENICITY: NOLD50 OF PRODUCT: ND LC50 OF PRODUCT. NDIRRITANT?: NO SENSITIZE*? • NOSYNERGISTIC MATERIALS. NAREPRODUCTIVE EFFECTS: NO TERATOGENIC- NO MUTAGENIC: NO SECTION VII-PREVENTIVE MEASURES, SAFE HANDLING AND USE LEAK AMD SPILL PROCEDURES- SCOOP UP AND RETURN TO CONTAINERWASTE DISPOSAL METHOD: DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS.PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN COOL, DRY AREA. PROTECT FROM FREEZING OTHER: KEEP OUT OF THE REACH OF CHILDREN! SECTION VIII-CONTROL MEASURES/PROTECTION INFORMATION VENTILATION:"NORMAL VENTILATION ADEQUATE.RESPIRATORY PROTECTION: NOT NECESSARY.PROTECTIVE GLOVES: NOT NORMALLY REQUIREDEYE PROTECTION: NAOTHER PROTECTIVE EQUIPMENT: NAWORK/HYGENIC PRACTICES: REMOVE CONTAMINATED CLOTHING, LAUNDER BEFORE REUSE. SECTION IX-REGULATORY INFORMATION EXPORTABLE QUANTITY (MIN. UNDER ANY ACT) 9,900 LBS.RCRA HAZARDOUS WASTE NO: (FED) NONE SHIPPING NAME: ADHESIVES, NOI NORTH AMERICAN EMERGENCY RESPONSE GUIDE NUMBER- NA DOT CLASSIFICATION. NOT REGULATEDIDENTIFICATION NO: NMFC ITEM NO. 04620 SUB. 5 NMFC CLASS 060VOLATILE ORGANIC COMPOUNDS(VOC): 10 G/L MAX. IMDG CLASSIFICATION: NOT REGULATED THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOTWARRANTED TO BE, WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS AREADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,APPLICABLE AND SUITABLE TO THEIR CIRCUMSTANCES MATERIAL SAFETY DATA SHEET I Air Corporation oduet* Wvteion rrTnpK.,Daiibury CT 06810, (203)791 3500 FILMS Page 1 of5 Issued 4/98 fCY NUMBERS: I Air Corporation: (203) 791-3500 For emergency and general information 8:30am-5:00pm, (Eastern Time), Monday-Friday CHEMTREC- (800) 424-9300 For Chemical Emergency - spill, leak, fire, exposure or accident 24 hours tName- [Name: flame- I Family: 1 Formula: INSTAMATE*, ANTI-STATIC INSTAMATE*, INSTAPACKER™» ANTI-STATIC INSTAPACKER™, SPEEDYPACKER™, ANTI-STATIC SPEEDYPACKER™, DURAMATE™ and PTYA FILM Polyolefins, Proprietary Polyolefins Polyolefins, Anti-static agent, Color concentrates N.A CAS No Wt.% OSHA-PEL ACGIH-TLV THIS MATERIAL IS NOT CONSIDERED HAZARDOUS UNDER 29 CFR 1910.1200 fMERGENCY OVER VTKW s: Film additives may cause slight skin irritation. No immediate hazard. Pink, Silver or other color. tthe entire MSDS for a more thorough evaluation of the hazards m Not a likely route of exposure t: Wash exposed skin with soap and water. t: Flush eyes with water for at least 10 minutes Obtain medical attention if problem persists. . Not a likely route of exposure. Consult a physician i: Symptomatic and supportive care as needed N E - NOT ESTABLISHED N A • NOT APPLICABLE A I • ACTIVE INGREDIENT id or implied, except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet *••lift) Seated Mr Corporation Engineered Products Division 10 Old Sherman Triple, Danbury CT 06810 (203)791-3500 FILMS Page 2 of5 Issued 4/98 I I Flash Point Approximately 600° F (315° C) Flammable limits (lower): Not applicable Flammable limits (upper). Not applicable. Extinguishing Media Carbon dioxide (CQj), chemical foam, dry chemical, water spray. Fire and Explosion Hazards: None known. Special Fire Fighting Procedures: Firefighters should be equipped with self-contained breathing apparatus in enclosed areas. NFPA Hazard Code-Health: 1 Flammability- 1 Reactivity 0 Special Hazard: None I i I I I 1 Not applicable due to material form Storage Temperature: Min. 20° F (-7° C) Max 120° F (49° C) Average Shelf Life- Not applicable JSf^jf^ Special Sensitivity. None Precautions to be Taken in Handling and Storage. Not applicable Exposure Limits' HMIS Hazard Code- OSHA-PEL: NE ACGIH-TLV. N.E. Health Flammabihty Reactivity PPE 1 1 0 B (Personal Protective Equipment) Respiratory Protection None required in normal use. Eve Protection Avoid indirect contact with hands X. N E <= NOT ESTABLISHED N A • NOT APPLICABLE A I = ACTIVE INGREDIENT This information Is furnishprt withnuf , Sealed Air Corporation \ Engliwand Products Division 1 10 OM Sherman Tnpk., Oanfaury, CT 06810 (203) 791 3500 FILMS Page 3 of5 Issued 4/98 • Protective Clothing: None normally required. If special sensitivity exists, use protective gloves. ± Ventilation: Good general ventilation during normal use. Other: Eye wash station. Wash hands before eating or handling food. Form. Plastic Film Color Pink, Silver or other Odor: None Vapor Density (Air = IV N.A Molecular Weight: N.E. Melting Point. 115- 140° C (240-285° F) Boiling Point: N.A. Vapor Pressure: Nil Specific Gravity: 0.92 - 0.98 Bulk Density- NA. Solubility in Water: Insoluble % Volatile bv Volume: Nil i i I i i i i Stability. Stable Polymerization Will not occur Conditions to Avoid: None. Incompatible Materials: None s: By fire or extreme heat, oxides of carbon, oxides of nitrogen Toxicitv Data LDJO, Oral: N.E LDso, Dermal: NE LCjo, Inhalation. N.E. Primary Routefsl of Exposure- Skin contact. Inhalation: Unlikely due to material form. Skin Contact' Some people may experience skin sensitivity or minor irritation due to film additives. Eve Contact: Film additives can cause irritation of the mucous membranes. r N E * NOT ESTABLISHED N A = NOT APPLICABLE A I » ACTIVE INGREDIENT This information Is furnished without wa Air Corporation Ei „ .••red Products Division 10 Old Sherman Tnpk.Danbury CT 06810, (203)791-3500 FILMS Page 4 of5 Issued 4/98 I 1 Ingestion Unlikely due to material form. Chronic Effects- No applicable data Carcinogenicitv: Tlie ingredients of this product (>0.1%) are not classified as carcinogenic by ACGIH or IARC, not regulated as carcinogens by OSHA, and not listed as carcinogens by NTT. ]Vlutagenicitv No applicable data. Reproductive Effects. No applicable data Teratogenicitv and Fetotoxicity No applicable data. No applicable data for this section. Dispose of in accordance with existing federal, state and local environmental control regulations. This material is not a hazardous waste under RCRA 40 CFR 261 when disposed of in its purchased form. DOT Not regulated. IMP Not regulated IATA/ICAO Class- Not regulated. Reportable Quantity (ROV Not applicable. QSHA Status- This product is NOT considered hazardous under the Federal OSHA Hazard Communication Standard 29 CFR 1910 1200. TSCA Status All ingredients listed or are not required to be listed N E - NOT ESTABLISHED N A <• NOT APPLICABLE A I * ACTIVE INGREDIENT nformation Is furnished without warranty expressed or implied, except that it Is accurate to the best knowledge of Sealed Air Corporation The data on this sheets onlv to the soecific material deiinnatod hnrnin Sealed Air Corooratinn assumes no leaal resoonsibilitv for use or reliance uoon these data Sealed Air Corporal km ets Division 10 Old Sherman Tnpk. Danbury.CT 06810, (203)791-3500 FILMS Page 5 of 5 Issued 4/98 SARA 302 Extremely Hazardous Substances; None SARA 311/312 Hazard Type: Not applicable SARA 313 Listed Ingredients: None RCRA Status: Discarded product is not a hazardous waste under RCRA, 40 CFR 261, when disposed of in its purchased form. No applicable information for this section. Section(s) Revised: Format changes I Printed on recycled paper (50% secondary material, minimum 10% post consumer) using vegetable based inks M-23 Rev 4/98 N E • NOT ESTABLISHED N A • NOT APPLICABLE A I • ACTIVE INGREDIENT This information Is furnished without warranty exoressed or imolied axrwrt mat it m arriirata »n *K» K..I knnwi~4«» ~«e~.i-- AI. /• «i— —- •• MATERIAL SAFETY DATA SHEET Sealed Air Corporation id Product* DM*lonEngfe 100WShermanTn(*., Danbury. CT06810, (203)791 3500 FILL-A Page 1 of 6 Issued 4/98 EMERGENCY NUMBERS: Sealed Air Corporation: (203)791-3500 For emergency and general information 8:30am-5:00pnv (Eastern Time), Monday-Friday CHEMTREC: (800)424-9300 For Chemical Emergency - spill, teak, fire, exposure or accident 24 hours Product Name: Chemical Name- Trade Name: Chemical Family: Chemical Formula: INSTAFDLL* COMPONENT "A" Polymethylene Potyphenylisocyanate Polymeric MDI Aromatic Isocyanates NA. Ingredients: Polymeric Diphenylmethane Diisocyanate ("polymeric" MDI) Contains 4,4'-Diphenylmethane diisocyanate x (M'-MDI; CAS 101-68-8;* 55%) Other MDI isomers and oligomers CAS No 9016-87-9 Wt.% 100 OSHA-PEL N.E. 002ppm (Ceiling) ACGffl-TLV N,E. 0.005 ppm (TWA) N.E.NE EMERGENCY OVERVIEW Health Hazards- Irritating to eyes, respiratory system and skin. Inhalation at levels above the occupational exposure limit could cause respiratory sensitization. The onset of the respiratory symptoms may be delayed for several hours after exposure. A hyper-reactive response to even minimal concentrations of MDI may develop in sensitized persons. Sensitized persons should not be exposed to any mixture containing unreacted MDI. Physical Hazards- Reacts slowly with water to produce carbon dioxide that may rupture closed containers. This reaction accelerates at higher temperatures. Appearance Dark brown liquid Odor Slightly aromatic (musty) Note: Read the entire MSDS for a more thorough evaluation of the hazards. N E - NOT ESTABLISHED N A = NOT APPLICABLE A I - ACTIVE INGREDIENT This information Is furnished without warranty, expressed or implied except that it is accurate to the best knowledge of Seated Air Corporation The data on this sheet Seated Air Corporation Englnssrsd Products Division 10 Old Sherman Tnpk. Danbury, CT 06810, (203)791-3500 FILL-A Page 2 of6 Issued 4/98 o Inhalation: Remove from further exposure and obtain medical attention. Treatment is symptomatic for primary irritation or difficulty in breathing If breathing is labored, oxygen should be administered by qualified personnel. Apply artificial respiration if breathing has ceased or shows signs of failing. Asthmatic-like symptoms, if manifested, may develop immediately, or be delayed for up to several hours. Skin Contact: Wash affected area thoroughly with soap and water. Launder contaminated clothing thoroughly before reuse. If irritation, redness, or a burning sensation develops and persists, obtain medical advice. Eye Contact. Flush with copious amounts of water for at least 15 minutes, holding lids open with fingers. If irritation persists, repeat flushing. Refer individual to a physician for immediate follow-up. Ineestion: DO NOT INDUCE VOMITING. Provided the patient is conscious, wash out mouth with water then give 1 or 2 glasses of water to drink. Refer person to medical personnel for immediate attention. Note to Physicians: Symptomatic and supportive therapy as needed. Following severe exposure medical follow- up should be monitored for 48 hours. Pulmonary disorders may be aggravated by overexposure. FlashPoint: 390° F (199° C) [Pensky-Martens Closed Cup] Flammable Limits flower)' Not available Flammable Limits (upper)' Not available O Extinguishing Media- Carbon dioxide (C0z)> dry chemical, or chemical foam. If water is used, large quantities are required Contain run-off water with temporary barriers. Fire and Explosion Hazards: Containers may burst under intense heat. Avoid water contamination in closed containers, carbon dioxide is evolved which can cause pressure build-up. Caution: Reaction between water and hot isocyanate can be vigorous. Special Fire Fighting Procedures. Firefighters must wear self-contained breathing apparatus to protect against toxic and irritating vapors; full protective clothing should also be worn. NFPA Hazard Code-Health 2 Flammability 1 Reactivity: 1 Special Hazard None I I I Evacuate area surrounding the spill and prevent further leakage, spillage or entry into drains Eye and skin protection should be worn during spill cleanup and ventilation maintained. If the potential for airborne concentrations of MDI above the PEL exists, then respiratory protection should be worn.U N E - NOT ESTABLISHED N A ' NOT APPLICABLE AI - ACTIVE INGREDIENT 1 Seated Air Corporation Vd Product* Division * flSrhian tnpk., Danbury, CT 06810 (203) 791 350010 Old S FILL-A Page 3 of6 Issued 4/98 Contain and cover spill with loose absorbent (earth, sand, sawdust or other absorbent material), or absorbent pillows, pads or socks Collect absorbed material in open containers or plastic bags, and treat with deactivating solution (90% water, 8% concentrated ammonia, 2% detergent). Allow to stand uncovered for 48-72 hours to permit carbon dioxide to escape and solidification to occur. Wash spill area with deactivating solution and let stand for 15 minutes or longer. Dispose of spilled material properly. Storage Temperature Min. 50° F (10° C) Max. 100° F (38° C) Average Shelf Life: 6 months Special Sensitivity: Reacts with moisture to produce carbon dioxide gas. Precautions to be Taken in Handling and Storage: Do not store product containers uncovered outdoors. Do not reseal containers unless it is certain that no moisture contamination has occurred. Do not breathe vapors or allow skin contact. • ExDOsure Limits* HMIS Hazard Code: OSHA-PEL: 4,4'-Diphenylmethane dusocyanate; ACGffl-TLV: 4,4'-Diphenylmethane diisocyanate; Ceiling = 0.02 ppm TWA = 0.005 ppm Health Flammability Reactivity PPE 3 1 1 B (Personal Protective Equipment) Respiratory Protection: Due to the low vapor pressure of this material, the PEL is not likely to be exceeded under normal conditions. If the material is heated or spilled in a confined area, respiratory protection should be worn. Because of their short life and lack of breakthrough indicators, cartridge type respirator* equipped for organic vapors are generally not recommended for use with isocyanates. They can be used for short-term emergency situations at concentrations below the PEL where the presence of adequate breathing oxygen can be assured. Where concentrations exceed me PEL, air supplied respirators must be used. ; Eye Protection: Goggles or safety glasses with side shields Protective Clothing: Chemical resistant butyl rubber, nitnle rubber, neoprene, or other suitable protective gloves Ventilation: Use local exhaust ventilation if necessary to maintain levels below the PEL. For guidance on engineering controls refer to the ACGIH publication "Industrial Ventilation " • Other' Eyewash station, safety shower and deactivating solution should be available. Refer to the "Recommendations for the Safe Use and Handling of Instapak* Foam-in-Place Chemicals" bulletin before handling Instapak* chemicals. N E • NOT ESTABLISHED N A - NOT APPLICABLE A I • ACTIVE INGREDIENT led Air Corporation I Products DIvMon ) Old Sherman Tnpk., Danbury CT 06810 (203) 791 3500 FILL-A Page 4 of6 Issued 4/98 Liquid Color- Dark brown Slightly aromatic (musty) Density (Air = 1): 85 Molecular Weight: Approx. 350 jfeltine Point: N.E. ! 25° C (for Polymeric MDI) RnilinpPAinf 406° F (208° C) Vapor Pressure: < 10~5 mm Hg (Z Specific Gravity: 1.24 @ 25° C Bulk Density: 10.3 Ibs/gal % Volatile bv Volume. Nil Solubility in Water: Not soluble Reacts slowly with water to liberate COz gas. ^ability: Stable under normal conditions. Avoid temperatures above 110° F (43° C) or below 40° F (4° C) •vmerization: May occur at elevated temperatures in the presence of moisture, alkalies, tertiary amines and flStal compounds. Avoid: Contact with moisture and other materials that contain active hydrogen. le Materials: Water, amines, strong bases and alcohols. The reaction with water is slow at )peratures less than 120°F (49°C) but is accelerated at higher temperatures. Highly unlikely under normal industrial use. Exposure to fire or extreme : may generate oxides of carbon, oxides of nitrogen, and traces of hydrogen cyanide. ivmeric MDI:el ••112 LDJO, Oral: LD , Dermal. LC}Q, Inhalation: >15,800 mg/kg (rat) >5000 mg/kg (rabbit) 370 - 490 mg/m3/4 hours (rat) for an aerosol of polymeric MDI jary Routefs) of Exposure' Skin contact from liquid. Inhalation. However, due to the low vapor pressure, •verexposure is not expected under normal conditions unless material is heated or used in a poorly ventilated This product is a respiratory irritant and potential respiratory sensitizer. Inhalation of vapor or )1 at levels above the occupational exposure limit can cause respiratory sensitization. Symptoms may hide irritation to the eyes, nose, throat, and lungs, possibly combined with dryness of the throat, tightness of nest and difficulty in breathing. The onset of respiratory symptoms may be delayed for several hours after ^posure. A hyper-reactive response to even minimal concentrations of MDI may develop in sensitized persons, sitized persons should be removed from any further exposure. Persons with asthma-type conditions or other lie respiratory diseases should be excluded from working with MDI In a single evaluation of 5 men ccupationalty exposed to MDI and hydrocarbon solvent vapors under conditions where adequate ventilation or mpr safety precautions were not used, neuropsychologic findings were attributed to MDI. kin Contact' May cause irritation or rash. Can cause skin discoloration Repeated and/or prolonged contact ^ result in skin sensitization. There is limited evidence from laboratory tests mat skin contact may play a role Respiratory sensitization. This data reinforces the need to prevent direct skin contact and the importance of rotective gloves. • N E * NOT ESTABLISHED N A. > NOT APPLICABLE AI » ACTIVE INGREDIENT irmation Is furnished without warranty expressed or imolied exceot that It Is accurate to the best knowledae of Sealed Air Corooration ThA ri*t» nn thin xhMt D U Sealed Air Corporation EnoirMwvd Products Division 10 ad Sherman Tnpk, Danbury, CT 06810, (203) 791 3500 FILL-A Page 5 of6 Issued 4/98 -* I I I I Eve Contact: Liquid can cause eye irritation, tearing, reddening and swelling Permanent corneal injury is unlikely Exposure to MDI vapors in excess of 0.02 ppm may cause irritation Ingestion Ingestion is unlikely Based on the acute oral LD50, this product is considered practically non-toxic by ingestion Ingestion can cause irritation and corrosive action in the mouth, stomach and digestive tract. Chronic Effects: A study was conducted where groups of rats were exposed for 6 hours/day, 5 days/week for a lifetime to atmospheres of respirable polymeric MDI aerosol either at concentrations of 0,0.2,1, or 6 ing/m3 (which corresponds to MDI levels equal to the OSHA-PEL, 5 times the OSHA-PEL add 30 times the OSHA- PEL). No adverse effects were observed at 0.2 mg/m3 concentrations. At the 1 mg/m3 Concentration, minimal nasal and lung irritant effects were seen Only at the top concentration (6 mg/m1) was there an increased incidence of benign tumor of the lung (adenoma) and one malignant tumor (adenocarcipoma). Overall, the tumor incidence, both benign and malignant, and the number of animals with tumors were not different. The increased incidence of lung tumors is associated with prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung. In the absence of prolonged exposure to high concentrations leading to chronic irritation and lung damage, it is highly unlikely that tumor formation will occur Carcinogemcitv: The ingredients of this product (>0.1%) are not classified as carcinogenic by ACGIH or IARC, not regulated as carcinogens by OSHA and not listed as carcinogens by NIP. Mutagemcity- There is no substantial evidence of mutagenic potential. ' Reproductive Effects No adverse reproductive effects are anticipated . Teratogenicity and Fetotoxicity: No birth defects were seen in two independent animal (rat) studies. Fetotoxicity was observed at doses that were extremely toxic (including lethal) to the mother. The dose that produced this effect (1.2 ppm) is 60 times higher than the OSHA-PEL Fetotoxicity was not observed! at doses that were not maternally toxic. The doses used in these studies were maximal, respirable concentrations well in excess of the defined occupational exposure limits. Environmental Fate and Distribution: It is unlikely that significant environmental exposure in the air or water will arise, based on consideration of the production and use of the substance. Persistence and Degradation: Immiscible with water, but will react with water to produce carbon dioxide, and inert and non-biodegradable solids. Aquatic Toxicitv LC50: ECso (24 hour)- EC50: >1000 mg/1 (Zebra fish) At the highest level of 1000 mg/1, there were no deaths. >1000 mg/1 (Daphnea magna) I >100mg/l(E.Coli) ' Incinerate or dispose of in accordance with existing federal, state and local environmental control regulations. This material is not a hazardous waste under RCRA 40 CFR 261 when disposed of in its purchased form. Small quantities should be treated with deactivation solution outlined in Section 6. Refer to the "Recommendations for the Safe Use and Handling of Instapak* Foam-in-Place Chemicals" bulletin for additional information concerning disposal of wastes and empty containers Chemical waste, regardless of quantity, should never be poured into drains, sewers or waterways. N E - NOT ESTABLISHED N A • NOT APPLICABLE A I - ACTIVE INGREDIENT I .. I i Seated Air Corporation Enghmrad Product* Division 10 Old Sherman Tnpk., Danbuty CT 06810, (203)791-3500 FILL-A Page 6 Of6 Issued 4/98 DOT; Cootainers less than 5,000 pounds are not regulated. IMP: Not regulated IATA/ICAO Class: Not regulated. Reportable Quantity fROV 5,000 Ibs for Methylene diphenyl diisocyanate (MDI), CAS #101-68-8 (* 55% of product). I OSHA Status: This product is considered hazardous under the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All ingredients are listed or are not required to be listed SARA 302 Extremely Hazardous Substances: None SARA 311/312 Hazard Categories: Immediate (acute) Health Hazard Delayed (chronic) Health Hazard SARA 313 Listed Ingredients* This product contains the following chemicals subject to the reporting requirements. 100% Diisocyanate compounds (Category Code N120). RCRA Status; Discarded product is not a hazardous waste under RCRA, 40 CFR 261, when disposed of in its purchased form. O The following states have regulations that apply to the use of this product MA Massachusetts Hazardous Substance List NJ New Jersey Hazardous Substance List PA Pennsylvania Hazardous Substance List The appropriate state agency should be contacted for further details on regulatory requirements for the substances shown below. Ingredient Methylene bisphenyl isocyanate (MDI) (Benzene, l,r-methylenebis[4-]isocyanato-) CAS No. 101-68-8 Wt % 55 Section(s) Revised. Section 15-Regulatory Information Printed QD.recycled paper (50% secondary material, minimum 10% post consumer) using vegetable based inks M-18 Rev 4/98 N E - NOT ESTABLISHED N A • NOT APPLICABLE A I - ACTIVE INGREDIENT This information Is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet MATERIAL SAFETY DATA SHEET Sealed Air Corporation Engineered Product* Division I 10 Old Stwrnan Tnpk, Danbury CT 06810 (203)791-3500 HS Page 1 of5 Issued 4/98 EMERGENCY NUMBERS: ! Sealed Air Corporation. (203) 791-3500 For emergency and general information \ 8:30am-5.00pm, (Eastern Time), Monday-Friday CHEMTREC (800)424-9300 For Chemical Emergency-spill, leak, ftre,\exposwe or accident 24 hours Product Name: Chemical Name. Trade Name: Chemical Family. Chemical Formula: HOLSTERflNSTAPAKER® SOLVENT Tripropylene Glycol Methyl Ether NA. Glycol Ethers Hazardous Ingredient CAS No Tripropylene Glycol Methyl Ether 025498-49-1 > 99 OSHA-PEL N.E. ACGIH-TLV NE. EMERGENCY OVERVIEW Health Hazards* Irritating to eyes and skin. Physical Hazards. No immediate hazard Appearance Clear Odor- Mild ether-like Note: Read the entire MSDS for a more thorough evaluation of the hazards. Remove from further exposure and obtain medical attention. Administer oxygen if necessary. Skin Contact' Wash area thoroughly with soap and water Launder contaminated clothing before reuse Eye Contact Flush with copious amounts of water for at least 15 minutes, holding lids opeiji with fingers Consult an eye physician if blinking, redness or tears persist. Ingesfton: If large quantity is swallowed, induce vomiting and obtain medical attention ; Note to Physicians Symptomatic and supportive care as needed. Kidney, urethra or bladder! disease may be aggravated by repeated, prolonged, gross overexposure. N E - NOT ESTABLISHED N A « NOT APPLICABLE A I = ACTIVE MMGRCQIENT This information Is furnished without warranty expressed or implied, except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet relates only to the specific material designated herein Sealed Air Corporation assumes no legal responsibility for use or reliance upon these data Seated Air Corporation Engineered Product* DiVI»lon 10 Old Sherman Tnpk., Danbury, CT 06810, (203) 791 3500 HS Page 2 of5 Issued 4/98 Flash Point: 232°F (111° C) [Setaflash] Flanynahle limits flower): Not applicable. Flammable limits (upper): Not applicable Extinguishing Media: Carbon dioxide (CO2), chemical foam, dry chemical, water spray. Fire and Explosion Hazards* None known. Special Fire Fighting Procedures: Firefighters must wear self-contained breathing apparatus and full protective clothing. NFPA Hazard Code-Health. 0 Flammability. 1 Reactivity: 0 Special Hazard None Evacuate area surrounding the spill and prevent further leakage, spillage or entry into drains. Eye and skin protection should be worn during spill cleanup and ventilation maintained. Contain and cover spill with loose absorbent (earth, sand, sawdust or other absorbent material) or absorbent pillows, pads or socks Collect absorbed material in open containers or plastic bags. Dispose of spilled material properly. O Storage Temperature: Mm. 20° F (-7° C) Max. 120° F (49° C) Average Shelf Life. 2 years. Special Sensitivity: None Precautions to be Taken in Handling and Storage' Avoid breathing vapor if generated. Exposure Limits: OSHA-PEL: N.E. ACGIH-TLV N E. HMIS Hazard Code ^I • • Health Flammability Reactivity PPE 1 1 0 B (Personal Protective Equipment) N E ' NOT ESTABLISHED N A - NOT APPLICABLE A I ' ACTIVE INGREDIENT Seated Air Corporation Engineered Product* Division f V 10 OW StwnnanTnpk., Oanbury.CT 06810, (203)791-3500 V—A HS Page 3 of5 Issued 4/98 Respiratory Protection. The use of respiratory protection should not be needed under nomjal use and handling conditions. If protection is chosen, an air-purifying respirator, equipped with organic vapor cartridges, is appropriate Eve Protection. Safety glasses with side shields or goggles. Protective Clothing Chemical resistant butyl rubber, nitrite rubber, neoprene, or other suitable protective gloves Ventilation- Good general ventilation. For guidance on engineering controls refer to the ACGIH publication "Industrial Ventilation." Other' Eyewash station should be available. Refer to the "Recommendations for the Safe Use and Handling of Instapak Foam-in-Place Chemicals" bulletin before handling Instapak* chemicals. Form' Liquid Color Clear Odor- Mild Glycol Ether Vapor Density (Air = IV 7.15 Molecular Weight: 206 Melting Point -100° F (-73° C) VOC Content- 965 g/1 or 8.03 Ugal. as per Rule 443 1 of California SCAQMD Boiling Point: 468° F (242° C) Vapor Pressure: 0.02 mm Hg @ 25° C Specific Gravity: 0.96 @ 25° JC Bulk Density: 8.1 Ibs/gal ! Solubility in Water: Complete Evaporation Rate (BuAc = 100): <1 Stability Stable. Polymerization. Will not occur. Conditions to Avoid' None Incompatible Materials: Strong oxidizers. Hazardous Decomposition Products: Oxides of carbon. Toxicitv Data* LD50, Oral LD50, Dermal. LC5o, Inhalation 3200 rag/kg (Rats) > 20,000 mg/kg (Rabbits) NE. N E " NOT ESTABLISHED N A • NOT APPLICABLE A I = ACTIVE INGREDIENT [ leafed Atr Corporation jim*rad Product* Division 10 Old Sherman Tnpk, Oanbury, CT 06810, (203) 791 3500 HS Page 4 of 5 Issued 4/98 I i I I i I i Primary Routefs) of Exposure: Skin absorption. Inhalation: Gross overexposure may result in anesthetic or narcotic effect Skin Contact: Not considered an irritant. Repeated or prolonged exposure may cause mild irritation and/or absorption of potentially toxic amounts. In rabbits, toxicity by single dose is low; by repeated doses, moderate. Eye Contact: May cause temporary eye irritation. Corneal injury is unlikely. Ineestion: Toxicity is low, however, ingestion of large amounts could cause injury. Systemic: Central nervous system depression at high levels. Rat studies suggest the kidney may be the target organ with overexposure. Birth defects are unlikely. Even exposures having an adverse effect on the mother should have no effect on the fetus. Results of in vitro ("test tube") mutagenicity tests have been negative Carcinogenicitv. The ingredients of tins product (>0.1%) are not classified as carcinogenic by ACGEH or IARC, not regulated as carcinogens by OSHA and not listed as carcinogens by NTP. Mutagenicity: No applicable data. Reproductive Effects: No applicable data. Teratoeenicitv and Fetotoxicitv No applicable data. iNo applicable data for this section. I i Incinerate or dispose of in accordance with existing federal, state and local environmental control regulations. This material is not a hazardous waste under RCRA 40 CFR 261 when disposed of in its purchased form. Also see "Recommendations for the Safe Use and Handling of Instapak* Foam-in-Place Chemicals" bulletin for additional information concerning disposal of wastes and empty containers Chemical waste, regardless of quantity, should never be poured into drains, sewers or waterways DOT. Not regulated. • IMP- Not regulated. IATA/ICAO Class- Not regulated • Reportable Quantity (ROV Not applicable • N E • NOT ESTABLISHED N A • NOT APPLICABLE A I = ACTIVE INGREDIENT This information Is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet. - ~ — .... .. ... _„„ „„ I,,-,i •...nnnoihilitu Inr 11*11 nr ntllnncA uoon these data J J I8J Sealed Air Corporation Engineered Products Dlvtaten 10 OW Sherman Tnpk. Danbury CT 06810, (203)791 3500 HS Page 5 of5 Issued 4/98 OSHA Status: This product is considered hazardous under the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status- All ingredients are listed or are not required to be listed. SARA 302 Extremely Hazardous Substances: None. SARA 311/312 Hazard Categories: Immediate (acute) Health Hazard SARA 313 Listed Ineredientfs). None RCRA Status: Discarded product is not a hazardous waste under RCRA, 40 CFR 261, {when disposed of in its purchased form. No applicable information for this section. Section(s) Revised. Format changes I I Printed on recycled paper (50% secondary material, minimum 10% post consumer) using vegetable based M-5 Rev 4/98 N E = NOT ESTABLISHED N A « NOT APPLICABLE A I « ACTIVE INQREDIENT This information Is furnished without warranty, expressed or implied except that it is accurate to the best knowledge of Sealed f\\r Corporation The data on this sheetrelates only to the specific material designated herein Sealed Air Corporation assumes no legal responsibility for use or reliance upon these data I Air :eup MATERIAL SAFETY DATA SHEET L v Seated Air Corporation * EntftoMrwi Products OlvMdn ' ^ 0 Old Sherman Tnpk., Panbury, CT 06810. (203)791 3500 FILL-B Page 1 of5 Issued 4/98 EMERGENCY NUMBERS: .i Sealed Air Corporation: (203)791-3500 For emergency and general information 8:30am-5 00pm, (Eastern Time), Monday-Friday CHEMTREC: (800) 424-9300 For Chemical Emergency - spill, leak, fire, exposure or accident 24 hours Product Name: Chemical Name: Trade Name: Chemical Family: Chemical Formula: Hazardous Ingredient Amine Catalyst INSTAFILL® COMPONENT "B" and INSTAFILL® SLOW RISE COMPONENT "B" Polyurethane Foam Resin Polyol NA. N.A. CAS No Proprietary Wt 2-4 OSHA-PEL N.E. ACGIH-TLV N.E. " I EMERGENCY OVERVIEW f| Health Hazards- Imtating to eyes and skin. Inhalation may result in irritation. Physical Hazards. No immediate hazard. • Appearance. Clear, Straw Odor Slight amine INote: Read the entire MSDS for a more thorough evaluation of the hazards I I Inhalation: Remove from further exposure and obtain medical attention Administer oxygen if necessary Skin Contact' Wash area thoroughly with soap and water Launder contaminated clothing before reuse. Eve Contact. Flush with copious amounts of water for at least IS minutes, holding hds open with fingers. Ingestion. Drink water" to dilute and obtain medical attention Note to Physicians' Symptomatic and supportive care as needed fms N E = NOT ESTABLISHED N A • NOT APPLICABLE A I > ACTIVE INGREDIENT information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet Seated Air Corporation Engineered Product* Division 10 Old Sherman Tnpk.,Danbuiy,CT 06810, (203)791-3500 FILiL-B If age 2 of S Issued 4/98 Flash Point: Product as supplied does not have a flash point. [Pensky-Martens Closed Cup] Flammable limits (lower): Not applicable. FlfflmmaMc limits (upper): Not applicable. Extinguishing Media: Carbon dioxide (CO2), chemical foam, dry chemical, water spray. i Fire and Explosion Hararda; Containers may burst under intense heat. ' Special Fire Fighting Procedures: Firefighters must wear self-contained breathing apparatus to protect against toxic and irritating vapors; full protective clothing should also be worn. NFPA Hazard Code. Health: 2 Flammability 1 Reactivity: 0 Special Hazard: None Evacuate area surrounding the spill and prevent further leakage, spillage or entry into drains, protection should be worn during spill cleanup and ventilation maintained. Contain and cover absorbent (earth, sand, sawdust or other absorbent material) or absorbent pillows, pads or solcks, absorbed material in open containers or plastic bags. Dispose of spilled material properly. Eye and skin spill with loose i. Collect Storage Temperature: Mm. 35° F (2° C) Max. 110° F (43° C) Average Shelf Life: 12 months Special Sensitivity None Precautions to be Taken in Handling and Storage: None Exposure Limits- OSHA-PEL. N.E. ACGIH-TLV: N.E. HMIS Hazard Code Health Flammability Reactivity PPE 2 0 0 B (Personal Protective Equipment) N E. « NOT ESTABLISHED N A « NOT APPLICABLE A I =• ACTIVE INGREDIENT This information Is furnished without warranty expressed or implied, except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet §••• ::: Sealed Air Cor fton iKvtrton \100WShermanTnpk.,Danbury,CT06810, (203)791-3500 FUL-B Page 3 of5 Issued 4/98 i i I i i Respiratory Protection: The use of respiratory protection should not be needed under normal use and handling conditions. If protection is chosen, an air-purifying respirator, equipped with organic vapor cartridges, is appropriate. Eye Protection: Safety glasses with side shields or goggles. Protective Clothing: Chemical resistant butyl rubber, nitrite rubber, neoprene, or other suitable protective gloves. Ventilation: Good general ventilation. For guidance on engineering controls refer to the ACGIH publication 'Industrial Ventilation." Other Eyewash station and safety shower should be available. Refer to the "Recommendations for the Safe Use and Handling of Instapak* Foam-in-Place Chemicals" bulletin before handling Instapak* chemicals. i i Form Liquid Color Clear, Straw : Slight Anune apor Density (Air = 1): > 1 Molecular Weight: N.A. Melting Point: -20° F (-29° C) Boiling Point. >201°F (94°C) Vapor Pressure: N. E. (low) Specific Gravity: 103@25°C Bulk Density: 8.6 Ibs/gal Solubility in Water Soluble % Volatile bv Volume: Nil i i Stability: Stable Polymerization: Will not occur. Conditions to Avoid- None. •Incompatible Materials: Isocyanates; avoid contact unless mixed at proper ratio. Hazardous Decomposition Products: By fire or extreme heat, oxides of carbon and nitrogen. I I LDjo,Oral LD50, Dermal. Inhalation- NE. N.E N.E ki N E > NOT ESTABLISHED N A ' NOT APPLICABLE AI « ACTIVE INGREDIENT formation Is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet - - ly to the specific material designated herein Sealed Air Corporation assumes no legal responsibility for use or reliance upon these data I Jed Air Corporation Engineered Product* Division 10 OW Sherman Tnpk.. Danbury, CT068tO. (203)791-3500 FILL-B Page- Issued 4/98 of 5 Primary RoutdV) of Exposure: Skin contact from liquid. Inhalation However, overexposure is not expected under normal conditions Inhalation: Vapors may be irritating if hot. Skin Contact: Repeated contact may be irritating. Eve Contact: Can cause eye irritation. Permanent corneal injury is unlikely. Ineestion: Ingestion is unlikely. Large quantities could cause irritation of mouth and stomach. Chronic Effects No applicable data. ' Carcinogenicitv The ingredients of this product (X).l%) are not classified as carcinogenic by ApGIH or IARC, not regulated as carcinogens by OSKLA, and not listed as carcinogens by NTP. Mutaeenicity: No applicable data. Reproductive Effects: No apphcable data . jratogenicitv and Fetotoxicitv: No applicable data. No applicable data for this section. Incinerate or dispose of in accordance with existing federal, state and local environmental control regulations. This material is not a hazardous waste under RCRA 40 CFR 261 when discarded in its purchased form. Also see "Recommendations for the Safe Use and P<mHlmg of Instapak* Foam-in-Place Chemicals" bulletin for additional information concerning disposal of wastes and empty containers. Chemical waste, regardless of quantity, should never be poured into drains, sewers or waterways. DOT Not regulated. IMP. Not regulated. IATA/ICAO Class- Not regulated ^portable Quantity (RCO: Not applicable. N E =• NOT ESTABLISHED N A » NOT APPLICABLE A I « ACTIVE INGREDIENT t that it i« arriirftta tn the best knowledae of Sealed Air Corporation The data on this sheet Seated Air Corporal ton Engineered Products DIvMon 10 Old Shaman Tnpk, Danbury CT 06810 (203) 791-3500 FILL-B Page 5 of5 Issued 4/98 OSHA Status: This product is considered hazardous under the Federal OSHA Hazard Communication Standard 29 CFR1910.1200 TSCA Status- All ingredients are listed or are not required to be listed. SARA 302 Extremely Hazardous Substances- None. SARA 311/312 Hazard Categories. Immediate (acute) Health Hazard. SARA 313 Listed IngredientCs): None. RCRA Status: Discarded product is not a hazardous waste under RCRA, 40 CFR 261, when disposed of in its purchased form. No applicable information for this section. Section(s) Revised: Section 1- Chemical Product and Company Identification Printed on recycled paper (50% secondary material, minimum 10% post consumer) using vegetable based inks. M-l 9 Rev 4/98 N E • NOT ESTABLISHED N A • NOT APPLICABLE A I * ACTIVE INGREDIENT This information Is furnished without warranty expressed or implied, except that it a accurate to the best knowledge of Sealed Air Corporation The data on this sheet ilates only to the specific material designated herein Sealed Air Corporation assumes no legal responsibility for use or reliance upon these rlat« CQfiSLT CSEBQN2LTE USDS Number: C4917 Effective Date: 11/17/99 1. Product Identification Synonyms: Cobaltous carbonate; carbonic acid, cobalt salt CAS No,: 513-79-1 Molecular Weight: 118.94 Chemical Formula: CoCOS Product Codes: 1666 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Cobalt Carbonate 513-79-1 90 - 100% Yes 3. Hazards Identification Emergency Overview WARNING! HARMFUL IF SHALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. CHRONIC EXPOSURE MAY AFFECT THYROID, LUNGS, HEART, AND KIDNEYS. J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 2 - Moderate Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: Causes irritation to the respiratory tract, symptoms may include coughing/ shortness of breath, and nausea. Respiratory hypersensitivity, asthma may appear. Inhalation of cobalt dust and fumes is associated with an increased incidence of lung disease. Ingestion: Causes abdominal pain, nausea, vomiting, flushing of the fa'ce and ears/ mild hypotension, rash, and ringing in the ears. May have cumulative toxic action where elimination cannot keep pace with absorption. Large amounts depress erythrocyte production. Skin Contact: | May cause dermatitis. Causes irritation to skin. Symptoms include redness, itching, and pain. j Eye Contact: Causes irritation, redness, and pain. i Chronic Exposure: • Repeated oral administration may produce goiter and reduced thyroid activity. Prolonged or repeated skin exposure may c$use dermatitis. Chronic exposure associated with kidney, heart and lung damage. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more I susceptible to the effects of the substance. Persons with allergies or sensitivity to cobalt may also be more susceptible to the effects of the substance. l 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medjical attention. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. ! Skin Contact: Wipe off excess material from skin then immediately flush skjln with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Hash clothing before reuse. Thoroughly clean shoes before reuse. ! Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Contact with strong oxidizers may cause fire. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approTred self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive TM*ASSt1T*A TTIoHia -pressure mode 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Hash hands before eating and do not eat, drink, or smoke in workplace. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues {dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: For Cobalt Compound: -OSH& Permissible Exposure Iiimit (PEL): 0.1 mg/m3 (TWA) Cobalt metal dust and fume as Co -ACGIH Threshold Limit Value (TLV) : inorganic cobalt compounds: 0.02 mg/m3 (TWA) as Co, A3: Animal carcinogen. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face high efficiency dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece high efficiency dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator, j WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: j Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. f - 9. Physical and Chemical Properties Appearance: Red crystalline powder. | Odor: No information found. Solubility: I Negligible. Specific Gravity: 4.13 pfl: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: No information found* Melting Point: No information found. Vapor Density (Air=l): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=l): No information found. 10. stability and Reactivity Stability: Stable under ordinary conditions of use and storage. May air-oxidize. Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, phosphoious oxides and benzoic acid. Hazardous Polymerization: j Will not occur. Incompatibilities: Strong oxidizers, tert-butyl hydroperoxide. I Conditions to Avoid: Air, incompatibles. ! 11. Toxicological Information Oral Rat LD50: 640 mg/kg. Investigated as a tumorigen. \Cancer Lists\ NTP Carcinogen Ingredient Known Anticipated IARC Category Cobalt Carbonate (513-79-1) No No 2B _««w-h_w_««« — «_ — •- — ^ —— —•_ — — «•— — »—•«•• — MV_~ — «_ ~^M W__^w«^»w _- — r • i •• i .....•-. -_i if- - ^ J-i •t 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information \Chemical Inventory Status - Part 1\ Ingredient TSCA EC Japan Australia Cobalt Carbonate (513-79-1) Yes Yes Yes Yes \Chemical Inventory Status - Part 2\ —Canada— Ingredient Korea DSL HDSL Phil. Cobalt Carbonate (513-79-1) Yes Yes No No \Federal, State & International Regulations - Part 1\ -SARA 302- SARA 313 Ingredient RQ TPQ List Chemical Catg. Cobalt Carbonate (513-79-1} No No Yes No \Federal, State & International Regulations - Part 2\-: -RCRA- I -TSCA- Ingredient CERC1A 261.33 ; 8(d) Cobalt Carbonate (513-79-1)No No No Chemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure:: No Reactivity: No (Pure / Solid) Australian Hazchem Code: No information found. '; Poison Schedule: No information found. WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations {CPR) and the MSDS contains all of the information required by the CPR. : 16. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Label Hazard Warning: WARNINGS HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT, MAY CAUSE ALLERGIC SKIN OEJ. RESPIRATORY REACTION. CHRONIC EXPOSURE MAY AFFECT THYROID, IkUNGS, HEART, AND KIDNEYS. : Label Precautions: Avoid breathing dust. Keep container closed. ; Use with adequate ventilation. ; Wash thoroughly after handling. i Avoid contact with eyes/ skin and clothing. : Label First Aid: • If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled/ remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case] of contact, immediately flush eyes or skin with plenty of water! for at least 15 minutes. Remove contaminated clothing and shoes.! Wash clothing before reuse. In all cases, get medical attention. Product Use: Laboratory Reagent. Revision Information: No changes. Disclaimer: **************** *•****-*•*•**-***** Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its ; comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. **************** Prepared by: Strategic Services Division Phone Number: (314) 539-1600 (U.S.A.) MATERIAL SAFETY DATA SHEET Hazardous according to criteria of Worksafe Australia Date of issue : Oct 1997 1. IDENTIFICATION General Product Name • FLUORSPAR POWDER Other Names: FLUORITE; METSPAR; CALCIUM FLUOfUDE UN No -N/A Dangerous Goods Class: None Allocated Subsidiary Risk • None Allocated Hazchem Code: N/A Pack Group: 0 EPG: N/A Poisons Schedule N/A Uses Principal source of fluorine and its compounds by way of hydrogen fluoride, flux in open hearth steel fymaces and in meta! smefljng, in ceramics, for synthetic cryolite, tn carbon electrodes, emery wheels, electric are welders, dentnfices, phosphors, paint pigment, catalyst tn wood preservatives, optical equipment. 1.1 Physical Description / Properties Appearance ' Light grey to brownish fine powder Formula: CaF2 Baling Point • N/A deg C Melting Point: >1350 deg C Vapour Pressure N/A Specific Gravity :ai8 (water =1) Flash Point: Test Unknown >300 pH:N/AO certain cements, Solubility in water: 0 016 g/l (25 deg C) Flamrnabiltty Limits (as percentage volume in all) Lower Explosion Limit: N/A Upper Explosion Limit: N/A 1.2 Other Properties No data available 1.3 Ingredients Chemical Entity CALCIUM FLUORIDE SILICA (AMORPHOUS) (CRYSTALLINE) CAS No. [7789-75^1 [7631-86-9J [14808-6G-7J Proportions (%) >97 <1.5 2. HEALTH HAZARD INFORMATION I I ( II i i I i i 2.1 Heatth Effects -Acute Swallowed Unlikely to cause significant effects. Eye Physical nature of powder may cause mechanical irritation. Skin Unfikeiy to cause irritant effects. Inhaled Acute exposure to dust may cause irritation to respiratory tract, 2JZ Health Effects-Chronic Fluorspar may contain up to 1 5% silica (amorphous or crystalline) as an Impurity. Chronic inhalation exposure to crystalline silica may result in serious adverse health effects particularly if the silica is of respirabte size (approximately < 7 micron aerodynamic diameter). Crystaffine sffica has been shown to induce king cancer in laboratory animate and there is Smiled evidence ftat ft may cause fang cancer in humans. The international Agency foReseanft on CarKCTfiARC) has classified crystalline silica as a probable human carcinogen (2A). 2.3 First AM Swallowed If swallowed, give a glass of water, jf feefing unwell contact a doctor cr prisons nfbnnation centre. Eye If in eyes wash with water for at (east 15 minutes If irritation persists see a doctor ; ! Skin Wash affected areas thoroughly with water inhaled If discomfort or irritation occurs remove to fresh air. first AW Facilities \ Ensure an eye bath and safety shower are available and ready for use. : 2.5 Advice to Doctor Treat symptomatcally based on judgement of doctor and individual reactions of patient. 2.6 Toxfctty Data Oral LD50 = 4250 mg/kg (Rat) Dermal LD50 = not available Inhalation LC50 ~ not available j 3. PRECAUTIONS FOR USE 3.1 Exposure Standards , The following exposure limits have been established by Worksafe Australia • Inorganic fluorides (as F) TWA • 2 5 mg/m3 Crystalline silica TWA 0.1 or 0 2 mg/m3 ; 3.2 Engineering Controls ' The generation of dusts should be avoided Where possible, dampen material, tf dust generation Is unavoidable, local exhaust ventilation should be used to achieve concentrations below TWA. : 3.3 Personal Protection ; A Class P1 paniculate filter respirator should be used where dusts may be formed, in accordance wfthjAustralfan and New Zealand Standard AS/NZS 1716,1994. Eye goggles should be worn as a general precaution if dust is ijkeiy to be formed Wash hands and face thoroughly after handling and before work breaks, eating, drinking, smoking and using jtoffet facffities. 3.4 Flammabilfrty Not flammable j i SAFE HANDLING INFORMATION i I 4.1 Storage / transport \ The product is not a dangerous good. No special storage or transport operations are required. 4.2 Packaging / Labelling I I I i i i I I I UN No. N/A Class None Allocated Sub Risk None AHocated Hazchem Code N/A Pack Group 0 EPGNo N/A Shipping Name FLUORSPAR POWDER Hazard Risk Phrases R48-FLUORS Danger of serious damage to health by prolonged inhalation exposure. R49 May cause cancer by inhalation. Safety Phrases S22 Do not breathe dust 853 Avoid exposure - obtain special instructions before use 4.3 Spills and Disposal te Clean-up personnel should wear full protective clothing including breathing protection. Avoid generation of dust Use an industrial vacuum cleaner to pick up material and transfer to suitable containers for reuse or disposal. • Disposal Dispose of in accordance with all Local, State and Federal regulations at an approved waste disposal facility. I 4.4 FIRE AND EXPLOSION HAZARD • Fire / Explosion Fluorine gas may be released on decomposition. Extinguishing MediaI , Fire-fighters should wear luB protecfive equipment including breathing apparatus. Mterial is not flammable. Use equipment/media • appropriate to surrounding materials and fire conditions. I I 5 OTHER INFORMATION Other Information No data avaflabte 5.1 Contact Points Organisation Redox Chemicals Pty Ltd Poisons iiiforntaaon ueoire Location WethenH Park NSW Ift/j- _.|_.- _• twestmead Tel^Jhone 02-97256155 131129 1800-251525 Ask For Technical CJfficer day fSarch 22, 2001 Page 1 30] I Chloride Solution IS Number F1080 Effective Date 02/21/00 i i Product Identification Synonyms Iron (III) Chloride Solution CAS No 7705-08-0 Molecular Weight Not applicable to mixtures Chemical Formula FeCIS in H20 product Codes 5251 Mcomposition/Information on Ingredients Ingredient CAS No Percent Hazardous I: rnc Chloride 7705-08-0 35 - 45% Yes ter 7732-18-5 55 - 65% No I I I I I I I I I I zards Identification Emergency Overview DANGER' CORROSIVE CAUSES BURNS TO ANY AREA OF CONTACT HARMFUL IF SWALLOWED OR INHALED AFFECTS THE LIVER J T Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating 2 - Moderate Flammability Rating 0 - None Reactivity Rating 2 - Moderate Contact Rating 3 - Severe (Corrosive) Lab Protective Equip GOGGLES & SHIELD, LAB COAT & APRON, VENT HOOD, PROPER GLOVES Storage Color Code White (Corrosive) Potential Health Effects Inhalation Extremely destructive to tissues of the mucous membranes and upper respiratory tract Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting Ingestion Corrosive Swallowing can cause severe burns of the mouth, throat, and stomach Can cause sore throat, vomiting, diarrhea Low systemic toxicity in small quantities but larger doses may cause systemic effects Pink urine discoloration is a strong indicator of iron poisoning Liver damage, coma and death may follow, sometimes delayed as long as three days Skin Contact. Corrosive Symptoms of redness, pain, and severe burn can occur Eye Contact Corrosive Contact can cause blurred vision, redness, pain and severe tissue burns Chronic Exposure Repeated ingestion may cause liver damage Prolonged exposure of the eyes may cause discoloration Aggravation of Pre-existing Conditions No information found irst Aid Measures Inhalation Remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen Get medical attention immediately Ingestion If swallowed, DO NOT INDUCE VOMITING Give large quantities of water Never give anything by mouth to an unconscious person Get medical attention immediately Skin Contact fll8jtfmac%20%A5%2Mon/DesMop%20Fo!der/MSDS/Fwilc%20ChlOfld8%20Soiut!on I I lureday, toarch 22, 2001 Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Get medical attention immediately Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally Get medical attention immediately Page I 5 Fire Fighting Measures Fire Not considered to be a fire hazard Irritating hydrogen chloride fumes may form in fire Explosion Not considered to be an explosion hazard Fire Extinguishing Media Water, dry chemical, foam or carbon dioxide Do not allow water runoff to enter sewers or waterways Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode 5 Accidental Release Measures Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8 Isolate hazard area Keep unnecessary and unprotected personnel from entering Contain and recover liquid when possible Collect liquid in an appropriate container or absorb with an inert material (e g , vermiculite, dry sand, earth), and place in a chemical waste container Do not use combustible materials, such as saw dust Do not flush to sewer1 US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable guantities The toll free number for the US Coast Guard National Response Center is (800) 424-8802 Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area Protect against physical damage Isolate from incompatible substances Containers of this material are hazardous when empty since they retain product residues, observe all warnings for the product Exposure Controls/Personal Protection Airborne Exposure Limits -ACGIH Threshold Limit Value (TLV) 1 mg/m3 (TWA) soluble iron salt as Fe Ventilation System A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended practices, most recent edition, for details personal Respirators (NIOSH Approved) If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator WARNING Air purifying respirators do not protect workers in oxygen-deficient atmospheres Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact Eye Protection Use chemical safety goggles and/or a full face shield where splashing is possible Maintain eye wash fountain and quick-drench facilities in work area Physical and Chemical Properties flley//mac%20%A5%20don/Desktop%20Folder/MSDS/Ferrlc%20Chlorld8%20Solutlon mrsday, &arch 22, 2001 Page 3 I I I I I I i I Appearance Orange to brown liquid Odor Acid odor Solubility Complete (100%) Specific Gravity 1 40 PH No information found % Volatiles by volume @ 21C (70F) 55-65 Boiling Point 230C (446F) Melting Point No information found Vapor Density (Air=l) No information found Vapor Pressure (mm Hg) No information found Evaporation Rate (BuAc=l) No information found Stability and Reactivity Stability Stable under ordinary conditions of use and storage Hazardous Decomposition Products May produce hydrogen chloride Hazardous Polymerization This substance does not polymerize Incompatibilities Metals, allyl chloride, sodium, potassium Conditions to Avoid Incompatibles I I i i IToxicological Information Oral rat LD50 450 mg/kg (anhydrous), investigated as a mutagen, reproductive effector --\Cancer Lists\ NTP Carcinogen jngredient Known Anticipated IARC Category xric Chloride (7705-08-0) No No None ter (7732-18-5) No No None Ecological Information Environmental Fate No information found Environmental Toxicity No information found. i i I isposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements Processing, use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal, state and local requirements I'ransport Information Not regulated Regulatory Information r \Chemical Inventory Status - Part 1\ edient TSCA EC Japan Australia flle///mac%20%AS%20don/DesMop%20Folder/MSDS/F8rrlc%20Chlorlde%20Solutlon hursday March 22. 2001 Ferric Chloride (7705-08-0) Water (7732-18-5) \Chemical Inventory Status - Part 2\- Ingredient Yes Yes Yes Yes Yes Yes Yes Yes --Canada-- Korea DSL NDSL Phil Ferric Chloride (7705-08-0) Water (7732-18-5) Yes Yes Yes Yes No No Yes Yes \Federal, State & International Regulations - Part 1\ -SARA 302- SARA 313 Ingredient RQ TPQ List Chemical Catg Ferric Chloride (7705-08-0) Water (7732-18-5) No No No No No No No No Ingredient CERCLA Ferric Chloride (7705-08-0) 1000 Water (7732-18-5) No -RCRA- 261 33 No No -TSCA- 8(d) No No Chemical Weapons Convention No TSCA 12(b) No CDTA No SARA 311/312 Acute Yes Chronic Yes Fire No Pressure No Reactivity No (Mixture / Liquid) Australian Hazchem Code No information found Poison Schedule No information found WHMIS This USDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR Page I 16 Other Information NFPA Ratings Health 3 Flammability 0 Reactivity 0 Label Hazard Warning DANGER' CORROSIVE CAUSES BURNS TO ANY AREA OF CONTACT HARMFUL IF SWALLOWED OR INHALED AFFECTS THE LIVER Label Precautions Do not get in eyes, on skin, or on clothing Do not breathe mist Keep container closed Use only with adequate ventilation Wash thoroughly after handling Label First Aid In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Wash clothing before reuse If inhaled, remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen If swallowed, DO NOT INDUCE VOMITING Give large quantities of water Never give anything by mouth to an unconscious person In all cases get medical attention immediately Product Use Laboratory Reagent Revision Information MSDS Section(s) changed since last revision of document include 1, 3, 4, 5, 6, 7, 8, 9, 10, 11, 13, 16 Disclaimer Mallinckrodt Baker, Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER, INC MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDINGLY, MALLINCKRODT BAKER, INC WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION Prepared by Strategic Services Division Phone Number (314) 539-1600 (USA) fll9///mac%20%A5%20don/D9Sktop%20Folder/MSDS/Ferrlc%20Chlorlde%20Solutlon lursday, March 22 2001 Nlckelous Carbonate Page 1 Nickelous Carbonate ifeiDS Number N2970 --- Effective Date 04/15/99 I I Product Identification Synonyms. Nickel (II) Carbonate, Carbonic Acid, Nickel Salt, CI 77779 CAS No.: 3333-67-3 Molecular Weight. 118 70 Chemical Formula: NiCOS Product Codes: 2764 I Composition/Information on Ingredients •ngredient CAS No Percent Hazardous Nickel Carbonate 3333-67-3 99 - 100% Yes I \JHazards Identification Emergency OverviewI I I I i i i i I WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE NASAL OR LUNG DAMAGE. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. CANCER HAZARD. CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure. J T. Baker SAF-T-DATA**™) Ratings (Provided here for your convenience) Health Rating 3 - Severe (Cancer Causing) Hammabihty Rating 0-None Reactivity Rating 0-None Contact Rating 3 - Severe (Life) Lab Protective Equip GOGGLES, LAB COAT, VENT HOOD, PROPER GLOVES Storage Color Code Blue (Health) Potential Health Effects Inhalation: Can cause headaches, dizziness, and difficult breathing Finer dust participates may irritate the respiratory tract. Symptoms may include coughing, sore throat, and shortness of breath Inhalation of nickel and nickel compounds is associated with nasal and lung damage and cancer Ingestion: May cause irritation to the gastrointestinal tract Large oral dose may cause nausea, vomiting, abdominal pain and diarrhea. Skin Contact. Causes irritation, redness, pain May cause allergic dermatitis Nickel is a contact allergen and sensiuzer Eye Contact: Causes irritation, redness, and pain Chronic Exposure: Prolonged exposure to excessive concentrations of dust may cause chronic pulmonary disorders Nickel and certain nickel compounds are considered carcinogenic and noted for producing nasal and lung cancer Aggravation of Pre-existing Conditions: Skin contact with some nickel compounds in sensitive individuals may cause dermatitis (nickel itch) I I First Aid Measures Inhalation: Remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen Get medical attention Ingestion: Induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person. Get medical attention. flle///mac%20%AS%20don/Desktop%20Folder/MSOS/Nickelous%20Carbonate hursday. March 22, 2001 Nickelous Carbonate Skin Contact: Immediately flush skin with plenty of soap and water Remove contaminated clothing and shoes Get medical atten ion Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact. Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally Gejt medical attention immediately Page I 5. Fire Fighting Measures Fire: Not considered to be a fire hazard j Explosion. j Not considered to be an explosion hazard : Fire Extinguishing Media: [ Use any means suitable for extinguishing surrounding fire : Special Information' ! In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode Toxic gases and vapors such as nickel carbonyl may be released in a fire involving nickel 6. Accidental Release Measures \ Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8 Spills Sweep up and containerize for reclamation or disposal Vacuuming or wet sweeping may be used to avoid dust dispersal j 7. Handling and Storage Keep m a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage Wear specia 1 protective equipment (Sec 8) for maintenance break-in or where exposures may exceed established exposure levels Wash hands, face, fo rearms and neck when exiting restricted areas Shower, dispose of outer clothing, change to clean garments at the end of the day Avoid cro ;s-contamination of street clothes Wash hands before eating and do not eat, dnnk, or smoke in workplace Containers of this material may be i lazardous when empty since they retain product residues (dust, solids), observe all warnings and precautions listed for the product j Exposure Controls/Personal Protection Airborne Exposure Limits: For Nickel, Metal and Insoluble Compounds, as Ni - OSHA Permissible Exposure Limits (PEL) - 1 mg/m3 (TWA) For Nicket Elemental / Metal - ACGIH Threshold Limit Value (TLV) - 1 5 mg/m3 (TWA), A5 - Not suspected as a human carcinogen For Nickel, Insoluble Compounds, as Ni- ACGIH Threshold Limit Value (TLV) - 0 2 mg/m3 (TWA), Al - Confirmed human carcinogenVentilation System-A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dis; ersion of it into thegeneral work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit c r the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest A full-face p ece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regul itory agency, or respirator supplier, whichever is lowest For emergencies or instances where the exposure levels are not known, use a full-facep ece positive-pressure, air-supplied respirator WARNING Air-purifying respirators do not protect workers in oxygen-deficient attnospher M Skin Protection. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection. ! Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible Maintain eye- wash fountain and quick-drench faculties in work area ; '. Physical and Chemical Properties Appearance: Light green powder Odor: Odorless Solubility. f!le///mac%20%A5%20don/Desktop%20Folder/MSDS/Nickelous%20Carbonate ursday I I I March 22 2001 Nlckelous Carbonate Page 3 Negligible Specific Gravity No information found pH: No information found % Volatilcs by volume @ 21C (70F): 0 Boiling Point: No information found Melting Point: Decomposes before reaching melting point Vapor Density (Air=l)- Not applicable Vapor Pressure (mm Hg): Not applicable Evaporation Rate (BuAc=l): No information found ILO. Stability and Reactivity I I i Stability: Stable under ordinary conditions of use and storage Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition Toxic gases and vapors such as nickel carbonyl may be released. Hazardous Polymerization: Will not occur Incompatibilities: For Nickel Aluminum, aluminum trichloride, ethylene, p-dioxan, hydrogen, methanol, non-metals, oxidants, sulfur compounds Slowly attacked by dilute hydrochloric or sulfunc acid, readily attacked by mtnc acid. Not attacked by fused alkali hydroxides Conditions to Avoid: Incompatibles I I lexicological Information No LD50/LC50 information found relating to normal routes of occupational exposure Investigated as a tumongen and mutagen \Canoer Lists\ I NTP Carcinogen gredient Known Anticipated IARC Category ckel Carbonate (3333-67-3) No Yes 1 I i Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. I"Disposal Considerations ^^ Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility Processing, use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal, state and local requirements ITransport Information Not regulated egulatory Information -\Chemical inventory Status - Part 1\ Ingredient TSCA EC Japan Australia I ;kel Carbonate (3333-67-3) Yes Yes Yes Yes file///mac%20%A5%20don/D9sktop%20Folder/MSDS/Nickelous%20Cart)onat8 luraday, Mar&i 22, 2001 Nlckekxjs Carbonate \Chemical Inventory Status - Part 2\ —Canada— Ingredient Korea DSL NDSL Phil Nickel Carbonate (3333-67-3) Yes Yes No Yes \Federal, State & International Regulations - Part 1\ -SARA 302- SARA 313 Ingredient RQ TPQ List Chemical Catg Nickel Carbonate (3333-6-7-3) No No No Nickel compo \Federal, State & International Regulations - Part 2\ -RCRA- -TSCA- Ingredient CERCLA 261 33 8(d) Nickel Carbonate (3333-67-3) No No No ' :hemical Weapons Convention No TSCA 12(b) No CDTA- No 3ARA 311/312 Acute Yes Chronic Yes Fire No Pressure No Reactivity No (Pure / Solid) I WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER Australian Hazchem Code: No information found Poison Schedule: No information found j WHME: ! This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR I 16. Other Information NFPA Ratings: Health. 2 Flammability 0 Reactivity 0 ' Label Hazard Warning: WARNING' HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT MAY CAUSE NASAL OR LUNG DAMAGE MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION CANCER HAZARD CAN CAUSE CANCER Risk of cancer depends on duration and level of exposure Label Precautions: Wash thoroughly after handling Do not breathe dust. Keep container closed Use only with adequate ventilation. Do not get in eyes, on skin, or on clothing Label First Aid- If swallowed, induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen. In case of skin contact, immediately flush skin with plenty of soap and water Remove contaminated clothing and shoes Wash clothing before reuse In qase of eye contact, immediately flush eyes with plenty of water for at least IS minutes In all cases, get medical attention. Product Use: : Laboratory Reagent I Revision Information: MSDS Secbon(s) changed since last revision of document include 8 . Disclaimer: I Mallinckrodt Baker, Inc. provides the information contained herein hi good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exei •cise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC.MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. | Prepared by: Strategic Services Division Phone Number (314) 539-1600 (U S A.) Hle.///mac%20%A5%20don/Desktop%20Folder/MSDS/Nlckelous%20Carbonate I I i i i i I i i i i I i i i i i i I Chromium Oxide MSDS Number: C4356 Effective Date: 03/01/00 1. Product Identification Synonyms: Chromium (III) Oxide; Chromic Oxide; Chrome Oxide Green CAS No.: 1308-38-9 Molecular Weight: 151.99 Chemical Formula: Cr203 Product Codes: 1616, 1617 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Chromium (III) Oxide 1308-38-9 90 - 100% Yes 3. Hazards Identification Emergency Overview: WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating: 2 - Moderate Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Blue (Health) Potential Health Effects: Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Ingestion: Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. Skin contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: Prolonged or repeated skin contact may produce severe irritation or dermatitis. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for an least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. €. Accidental Release Measures Protect against physical damage. Do not store on wooden floors.Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for ;he product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: I IJ- I 5. Fire Fighting Measures j Fire: Not considered to be a fire hazard. • Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protectivje clothing and NIOSH-approved self-contained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode.I I I Ventilate area of leak or spill. Wear appropriate personal protective | equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal ^ in a method that does not generate dust. Do not sweep. Damp mop jany residue. • 7. Hand! ing and Storage • Keep in a tightly closed container, stored in a cool, dry, ventilated area. I I I- OSHA Permissible Exposure Limit (PEL): for Cr(III) compounds = 0.5mg/m3 (TWA) -ACGIH Threshold Limit Value (TLV): for Cr(III) compounds = 0.5 mg/m3 (TWA), I A4 - Not classifiable as a human carcinogen. * Ventilation System: I A system of local and/or general exhaust is recommended to keep Employee | exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the Contaminant at its source, preventing dispersion of it into the general work)area. Please refer to the ACGIH document/ Industrial Ventilation/ A Manual of Recommended Practices, most recent edition, for details. j I I I I I I I I i I Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive- pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Light to dark green Crystalline solid. Odor: Odorless. Solubility: Negligible {< 0.1%) Specific Gravity: 5.10 pH: No information found. % Volatiles by volume S 21C (70F): 0 Boiling Point: 4000C (7232F) Melting Point: 2435C (4415F) Vapor Density (Air=l): Not applicable. Vapor Pressure (mm Hg): Not applicable. Evaporation Rate (BuAc=l): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: No information found. Hazardous Polymerization: Will not occur. Incompatibilities: Lithium, glycerol. Conditions to Avoid: Dusting. 11. Toxicological Information Investigated as a tumorigen, mutagen. \Cancer Lists\ NTP Carcinogen— Ingredient Known Anticipated IARC Category Chromium (III) Oxide (1308-38-9) No No 3 12. Ecological Information Environmental Fate: When released into the soil, this material is not expected to biodegrade. This material is not expected to significantly bioaccumulate. Environmental Toxicity: No information found. 13. Disposal Considerations I I leantly _ I Whatever cannot be saved for recovery or recycling should be managed in an • appropriate and approved waste disposal facility. Processing, us]e or • contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal (regulations.and local disposal regulations may dirrer from federal disposal regulations. • Dispose of container and unused contents in accordance with federal, state I I t— I I and local requirements. . w. I 14. Transport Information Not regulated. 15. Regulatory Information \Chemical Inventory Status - Part 1\- NDBL Phil. Ingredient TSCA EC Japan Australia _ Chromium (III) Oxide (1308-38-9) Yes Yes Yes j Yes • \Chemical Inventory Status - Part 2\—Canada- Ingredient Korea DSL — — _-.____..M_..V._ —— ___....._ _.».».•._ — — — -» — -. — — —. —— -._«^ — _™ „_«.._ *_.« «_L._ __-__-*. Chromium (III) Oxide (1308-38-9) Yes Yes No| Yes • Federal, State & International Regulations - Part 1\SARA 302—SARA 313 Ingredient RQ TPQ List Chemical Catg. • Chromium (III) Oxide (1308-38-9) No No No Chromium com Federal, State & International Regulations - Part 2\ —j I I-RCRA--TSCA- Ingredient CERCLA 261.33 8 (d) Chromium (III) Oxide (1308-38-9) No No 'NO • Chemical Weapons Convention: No TSCA 12(b): No CDTA: No m SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure Reactivity: No (Pure / Solid) I I Australian Hazchem Code: No information found. Poison Schedule: No information found. WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPU) and the MSDS contains all of the information required by the CPR.__ ___„____.. -^ ._ __—_ _.___..____. __ 16. Other Information Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Label Precautions: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Label First Aid: If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention. Product Use: Laboratory Reagent. Revision Information: No changes. Disclaimer: Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent 3udgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, IMC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. Prepared by: Strategic Services Division Phone Number: (314) 539-1600 (U.S.A.) 0 Health ,« 0 F 1 dirvrfabi 1 i ty 0 Reactiv/ty FOOTE MINERAL COMPAHY DATE 1/19/82 MATERIAL SAFETY SHEET SECTION 1 MANUFACTURER'S NAME . EMERGENCY TELEPHONE NOFoote Mineral Company 215/363-6500 ADDRESS (Number, Street. Cliy. Sutc. inn ZIP code) ' "I"Route 100 Exton, PA 193^1 CHEMICAL NAME AND SYNONYMS TRADE NAME AND SY Chromite Chromite AF and SONYMS Chromite SG CHEMICAL FAMILY FORMULA r _ r. C«ftMineral Cr70,-FeO. - SECTION II HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES. tV SOLVENTS PIGMENTS , - - •„ f CATALYST T ' - i '• -< VEHICLE SOLVENTS ADDITIVES OTHERS V .... ... x • - TLV(Units) •V ALLOYS AND METALLIC COAT BASE METAL . ALLOYS ' %,,_ y , METALLIC COATINGS ... , FILLER METAL PLUS COATING OR CORE FLUX OTHERS T^ J HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES Chromite Is not a serious hazard . C^O^ ' FeO INGS _ % X ^21) TLV (Units) TLV fUn"?' SECTION III PHYSICAL DATA 8OILIMG POINT (°F.) • VAPOR PRESSURE (mm Hj ) VAPOR DENSITY (AIR-1) SOLUBILITY IN WATER NA NA NA Nf>nl ?nihU SPECIFIC GRAVITV (H2O"1) PERCENT VOLATILE BY VOLUME (S) EVAPORATION RATE 1 -1) APPEARANCE AND ODOR „ . ' _ . .Brown oowder. Odorless. ll.lt NA NA SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method UMd) NA FLAMMABLE LIMITS L«l LUI EXTINGUISHING MEDIA NA ' SPECIAL FIRE FIGHTING PROCEDURES Nonf 1 ammahl UNUSUAL FIRE AND EXPLOSION HAZARDS none SECTION V HEALTH HAZARD DATA THRESHOLD LIMIT VALUE NA EFFECTS OF OVEREXPpSURE . .No known hazard except as a nuisance dust. Suspected but indefinite j:a re inoqen ic. EMERGENCY AND FIRST AID PROCEDURES SECTION VI REACTIVITY DATA STABILITY UNSTABLE STABLE CONDITIONS TO AVOID INCOMPATABILITY (Materials to avoid) HAZARDOUS DECOMPOSITION PRODUCTS .-, . HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID STEPS TO BE TAKEN IN CASE SECTION VH SPILL OR LEAK MATERIAL IS RELEASED OR SPILLED PROCEDURES Sweep up and return to container. * WASTE DISPOSAL METHOD Landfill , with in all pollution regulations — " SECTION Vm SPECIAL PROTECTION INFORMATION RES PI RATORY PROTECTION (Specify typ«) Hprhaniral VENTILATION LOCAL EXHAUST 'MECHANICAL (General) SPECIAL OTHER PROTECTIVE GLOVES EYE PROTECTIONgoggles for dust protection OTHER PROTECTIVE EQUIPMENT SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANOLINQ AND STORING Norma1 OTHER PRECAUTIONS c QC-2(2){U-71)by »SDS - MANGANESE DIOXIDE 1 - PRODUCT IDENTIFICATION PRODUCT NAME: MANGANESE DIOXIDE FORMULA: MN02 FORMULA WT: 86.94 CAS NO. : 1313-13-9 NIOSH/RTECS NO-: OP0350000 ; COMMON SYNONYMS: BLACK MANGANESE OXIDE; CEMENT BLACK; MANGANESJE (IV) OXIDE PRODUCT CODES: Z134,2526,8392,5308,2527,5298 I EFFECTIVE: 09/08/86 i REVISION #02 ! PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 1 SLIGHT FLAMMABILITY - 0 NONE : REACTIVITY - 1 SLIGHT ; CONTACT - 1 SLIGHT ; HAZARD RATINGS ARE 0 TO 4 {0 = NO HAZARD; 4 = EXTREME HAZARD) . \ LABORATORY PROTECTIVE EQUIPMENT ' SAFETY GLASSES; LAB COAT ; PRECAUTIONARY LABEL STATEMENTS ; WARNING : CAUSES IRRITATION : HARMFUL IF INHALED : DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING. WASH THOROUGHLY AFTER HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER. i SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE) ; 2 - HAZARDOUS COMPONENTS i COMPONENT % ; CAS NO. MANGANESE DIOXIDE 90-100 1J313-13-9 3 - PHYSICAL DATA BOILING POINT: N/A VAPOR PRESSURE (MM EG): N/A MELTING POINT: 535 C C 995 F) VAPOR DENSITY(AIR=1); N/A SPECIFIC GRAVITY: 5-02 EVAPORATION RATE: : N/A (H20=l) (BUTYL ACETATE=1) SOLUBILITY(H20): NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME: N/A APPEARANCE & ODOR: ODORLESS BLACK CRYSTALLINE POWDER. 4 - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP N/A FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A % FIRE EXTINGUISHING MEDIA USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED (POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE. MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE & EXPLOSION HAZARDS STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. 5 - HEALTH HAZARD DATA TLV LISTED DENOTES CEILING LIMIT. THRESHOLD LIMIT VALUE (TLV/TWA) : 5 MG/M3 { PPM) CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO EFFECTS OF QVEREXPOSURE DUST MAY IRRITATE SKIN OR EYES.INHALATION OF EXCESSIVE AMOUNTS OF DUST MAY CAUSE NAUSEA, WEAKNESS, CHILLS, AND LOSS OF APPETITE. INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. PROLONGED INHALATION OF MANGANESE IN THE FORM OF ITS INORGANIC COMPOUNDS MAY CAUSE MANGANISM. TARGET ORGANS RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM, BLOOD, KIDNEYS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INGESTION, INHALATION EMERGENCY AND FIRST AID PROCEDURES INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED PERSON TO FRESH AIR. GET MEDICAL ATTENTION.! EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LfAST 15 MINUTES. GET MEDICAL ATTENTION. ! SKIN CONTACT: IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES. j 6 - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, FUVME, OTHER SOURCES OF IGNITION \ INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG ACIDS, ! STRONG REDUCING AGENTS, NITRATES, ; COMBUSTIBLE MATERIALS, HYDROGEN PEROXIDE/i AZIDES, CHLORINE, CHLORATES, CHLORINE TRIFLUORIDEJ 7 - SPILL AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SUITABLE PROTECTIVE CLOTHING. KEEP COMBUSTIBLES (HOOD, PAJPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. ; DISPOSAL PROCEDURE : DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. ' 8 - PROTECTIVE EQUIPMENT j i VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATIONiTO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES, UNIFORM, APRON, PROPER GIJOVES ARE RECOMMENDED. 9 - STORAGE AND HANDLING PRECAUTIONS SAF-T-DATA(TM) STORAGE COLOR CODE: ORANGE (GENERAL STORAGE) i SPECIAL PRECAUTIONS ; KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLEFLAMMABI AND COMBUSTIBLE MATERIALS. 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION DOMESTIC (D.O.T.) PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED) INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME CHEMICALS, N.O.S. (NON-REGULATED) Q'MAX MATERIAL SAFETY DATA SHEET Section I: IDENTIFICATION OF PRODUCT Product Name: Product Use: Chemical Family: WHMIS CLASSIFICATION: WORK PLACE HAZARD: TDG CLASSIFICATION: PACKAGE GROUP: PIN: Section II: HAZARDOUS INGREDIENTS Ingredient LC(50) Calcium Oxide [Q'Max Header] [Image] QUICKLIME (Pebble, Crushed, Pulverized) Various Calcium Oxide Cas No. 1305-78-8 Eye and Skin Irritant Not Applicable Not Applicable Not Applicable Percent 95.1 CAS Number 1305-78-8 LD(50) N/AV N/AV Section III: TOXICOLOGICAL PROPERTIES Route of [Image] SKIN [Image]EYE CONTACT [Image]INHALATION INGESTION | Entry: SKIN CONTACT: soft, [Image] contact. The contact. contact. EYE CONTACT: solutions may destruction; can conjunctivitis. INHALATION: coughing, headache, may result pulmonary edema. penetration are common.INGESTION: Physician Exposure Limits: Irritancy of Product: Skin, Exposed Can penetrate the skin slowly, producing necrotic, deeply penetrating areas on extent of damage depends on duration of A chronic dermatitis may follow repeated Direct contact with the solid or aqueous cause conjunctival edema and corneal lead to and may cause blindness. Prolonged contact may cause Low concentrations may causef sore throat, | choking, dyspnea, and variable symptoms of dizziness, and weakness. Intjense exposures in tightness in the chest and delayed The solubility of substance allows further that may continue for several days. Bronchial irritation with chronic cough iCorrosive. If ingested, consult a immediately. j 5 mg/m? Lime ' Respiratory System Nasal Passages, Eyes, Section IV: FIRST AID MEASURES SKIN CONTACT: large amounts of Lime dust. Acid solution, EYE CONTACT: then vinegar Keep bandaged INHALATION: artificial INGESTION: water. Do not attention. Section V: PHYSICAL DATA APPEARANCE AND ODOUR: Odourless SPECIFIC GRAVITY: BOILING POINT (°C) : MELTING POINT (°C>: SOLUBILITY IN WATER: pH @ 1.0%: PERCENT VOLATILE BY VOLUME: EVAPORATION RATE: VAPOUR PRESSURES (mm Hg) : VAPOUR DENSITY (Air=l): Section VI: FIRE AND EXPLOSION DATA FLASH POINT: AUTOIGNITION TEMPERATURE: FLAMMABLE LIMITS: EXTINGUISHING MEDIA: which is SPECIAL FIRE FIGHTING PROCEDURES: UNUSUAL FIRE AND EXPLOSION PROCEDURES: Section VII: REACTIVITY DATA STABILITY [Image] INCOMPATIBILITY (conditions to and many avoid): swell and burst Oxide/ exposed to air, Cuts or Scrapes. Flush affected eye "immediately" with water. Do not rub eyes if irritated by Following eye wash with water, use Boric then get medical attention. Wash thoroughly with soap and warm water, to remove all Lime. Apply burn ointment. during healing to prevent infection. Remove to fresh air. If not breathing give respiration and call a doctor. Give three to four glasses of milk or induce vomiting. Get immediate medical Greyish white solid, various sizes - (H20=l) 3.2 - 3.4 2850 C 5162 F Not Applicable Insoluble 12 - Strong Alkaline Not Applicable butylacetate=l) NM/AP 20C (68F) Not Available None Applicable Not Applicable Not Applicable Non flammable, use extinguishing media appropriate for surrounding fire. None None Stable [Image] Unstable Boric Oxide, Acids, Fluorine, water, steam organic materials. Calcium. Oxide will generate heat when moistened and could containers. Fluorine will attack Calcium evolving much heat and some light. When it will react with moisture and Carbon Dioxide in the HAZARDOUS DECOMPOSITION PRODUCTS: HAZARDOUS POLYMERIZATION: [Image] Section VIII: PREVENTIVE MEASURE SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: excessive dust VENTILATION: airborne levels PROTECTIVE GLOVES: material getting [Imaged May Occur air. None Will not occur Approved filter mask should be worn if is created. Local exhaust as necessary to maintain within prescribed limits. : Gauntlet type work gloves to prevent inside. Tight fitting goggles should be worn. Should be worn to prevent LJime from EYE PROTECTION: CLOTHING: contacting skin. OTHER PROTECTIVE EQUIPMENT (specify): Long sleeved shirt with collar buttoned, trousers with | legs down over boot tops, PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING i Avoid creating dust. Keep containers closed to avoid breathing dust and eye contact. Keep product dry. Store in coo, "DRY", well-ventilated area out of direct contact with weather, I STEPS TO BE TAKEN IN CASE THE MATERIAL IS SPILLED OR RELEASED Ventilate area of spill. Keep spilled material away from Organic katerial and Water. I Carefully pick up solid material and collect in metal containers with covers for disposal. WASTE DISPOSAL METHOD Trace amounts of residue can be flushed into the drain, using plenty of water. Large amounts j may require neutralization by Acid. Check local regulations. Alternately, waste lime can be used for neutralizing plant acid wastes. | Section IX: PREPARATION The information contained herein is given in good faith, but no warranty, expressed or j implied/ is made. DATE ISSUED: July 1, 1995 BY: Calgary Division Office DATE UPDATED: October 1, 1999 [Image] . Return to MSDS Menu [Image] Return to Main Menu ! [Image] i site design and construction by : Cobra Internet [Design 2000 SELENIUM DIOXIDE MSDS Number: S1130 Effective Date: 11/17/99 1. Product Identification Synonyms: Selenium oxide; selenious anhydride CAS No.: 7446-08-4 Molecular Weight: 110.96 Chemical Formula: SeO2 Product Codes: U995 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Selenium Dioxide /Se02/ 7446-08-4 90 - 100% Yes 3. Hazards Identification Emergency Overview DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. HIGHLY TOXIC BY INHALATION OF BUST OR VAPOR. CONTACT CAUSES INTENSE LOCAL IRRITATION OF SKIN AND EYES. TARGET ORGANS: SKIN, EYES, KIDNEY, LIVER, GASTROINTESTINAL TRACT, LUNGS. MAY CAUSE ALLERGIC SKIN REACTION. J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating: 3 - Severe (Life) Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 3 - Severe (Life) Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Blue (Health) Potential Health Effects Acute toxicity of soluble selenium compounds is high. A general tissue poison like arsenic, presumably attacking sulfhydryl enzymes. Inhalation: Highly toxic via inhalation. May cause severe breathing problems that may not appear for several hours after exposure. Irritates the -upper respiratory tract. May cause headache, fever, chills. Ingestion: Toxic. May be fatal if swallowed. May cause severe stomach problems.. Skin Contact: May cause skin burns. May be absorbed through the skin in tt>xic quantities. May cause skin rash. Prolonged contact may causb skin sensitization. Eye Contact: Causes eye irritation. May cause "Rose eye", eyelids in which they become puffy. • Chronic Exposures j Chronic exposure may cause paleness, coated tongue, stomach I disorders, nervousness, metallic taste and garlic breath. | Aggravation of Pre-existing Conditions: j Person with a history of asthma, allergies, or known sensitazation to selenium, or with a history of other chronic respiratory| disease, gastrointestinal disturbances, disorders of the liver or kidneys, or recurrent dermatitis would be expected to be at j increased risk from exposure. '• an allergy of the 4. First Aid Measures ' Inhalation: Remove to fresh air. If not breathing, give artificial ; respiration. If breathing is difficult, give oxygen. Get medical attention immediately. | Ingestion: j Induce vomiting immediately as directed by medical personnel]. Never give anything by mouth to an unconscious person. Get Medical attention immediately. ' Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Protect from moisture. Wear special protective equipment {Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels. Wash hands, face, forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink, or smoke in workplace. Containers of this material may be hazardous when empty since they retain product residues {dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): 200 ug (Se)/m3(THA) -ACGIH Threshold Limit Value (TLV): 200 ug(Se)/m3{TWA) Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators {NIOSH Approved): If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure leveJLs are ednot known, use a full-facepiece positive-pressure, air-suppl respirator. WARNING: Mr purifying respirators do not protect workers in oxygen-deficient atmospheres. '• Skin Protection: ; Wear impervious protective clothing, including boots, gloves^ lab coat/ apron or coveralls/ as appropriate, to prevent skin contact. Eye Protection: ; Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. | 9. Physical and Chemical Properties Appearance: White crystalline powder. Odor: Vapor has a pungent sour smell. Solubility: 28% in water @ 20C (68F). Specific Gravity: 3.95 pH: No information found. % Volatlles by volume 9 21C {70F} 0 Boiling Point: Not applicable. Melting Point: 340C (644F) Vapor Density (Air=l): No information found. Vapor Pressure (mm Eg}: 1 8 157C (315F) Evaporation Rate (BuAc=l): No information found. 10. Stability and Reactivity : Stability: : Stable under ordinary conditions of use and storage. | Hazardous Decomposition Products: I Toxic metal fumes may form when heated to decomposition. j Hazardous Polymerization: ! Will not occur. ; Incompatibilities: : Organic materials, phosphorous trichloride, strong acids, amjnonia. ! I Conditions to Avoid: Moisture and incorapatibles. ; 11. Toxicological information Oral rat LD50: 68.1 mg/kg. Investigated as a mutagen, reproductive effector. \Cancer ListsN NTP Carcinogen Ingredient Known Anticipated IARC Category Selenium Dioxide /Se02/ (7446-08-4) No No None 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal/ state and local requirements. 14. Transport Information Domestic (Land, D.O-T.) Proper Shipping Name: SELENIUM COMPOUND, N.O.S. (SELENIUM DIOXIDE) Hazard Class: 6.1 DN/NA: DN3283 Packing Group: I Information reported for product/size: 100G International (Water, I.M.O.) Proper Shipping Name: SELENIUM COMPOUND, N.O.S. (SELENIUM DIOXIDE) Hazard Class: 6.1 UN/NA: UN3283 Packing Group: I Information reported for product/size: 100G International (Air, I.C.A.O.) Proper Shipping Name: SELENIUM COMPOUND, N.O.S. (SELENIUM DIOXIDE) Hazard Class: 6.1 ON/NA: UN3283 Packing Group: III ' Information reported for product/size: 100G 15. Regulatory Information \Chemical Inventory Status - Part 1\ 1- Ingredient TSCA EC Jap^n Australia Selenium Dioxide /SeO2/ (7446-08-4) Yes Yes Yes Yes! j \Chemical Inventory Status - Part 2\ j- • —Canad^— Ingredient Korea DSL NIpSL Phil. Selenium Dioxide /SeO2/ (7446-08-4) Yes Yes No Yes \Federal, State & International Regulations - Part 1\—— —- -SARA 302- SARA 313 Ingredient RQ TPQ List Chemical Catg,— ___— __ — ___—_™_ ___ _____ —._— _j.____ ___ Selenium Dioxide /Se02/ (7446-08-4) No No No Selenium cmp \Federal, State & International Regulations - Part 2\—? -RCRA- I-TSCA- Ingredient CERCLA 261.33 l 8 (d) _.__.__ _-«, — — „_ — — _ —^.-fc — — -.— __ — — — _ ..— — — — *.____.__ __ *_«.*. .__ — _— ' .ta_« — — Selenium Dioxide /SeO2/ (7446-08-4) 10 No No Chemical Weapons Convention: No TSCA 12(b): No CDTA: ; SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: tfo Reactivity: No (Pure / Solid) i i Australian Hazchem Code: No information found. i Poison Schedule: No information found. I WHMIS: j This MSDS has been prepared according to the hazard criteria I of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. ! 16. Other Information ' NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 0 ! Label Hazard Warning: ; DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. HIGHLY TOXIC BY INHALATION OF DUST OR VAPOR. CONTACT CAUSES INTENSE LOCAL IRRITATION OF SKIN AND EYES. TARGET ORGANS: SKJN, EYES, KIDNEY, LIVER, GASTROINTESTINAL TRACT, LUNGS. MAY GAUSS ALLERGIC SKIN REACTION. Label Precautions. Do not breathe dust or vapor. Do not get in eyes, on skin, or on clothing. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Label First Aid: If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In all cases get medical attention Immediately. Product Use: Laboratory Reagent. Revision Information: No changes. Disclaimer: ***************** Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. *•**•*•**•*•*•**•****** Prepared by: Strategic Services Division Phone Number: (314) 539-1600 (U.S.A.) March 22 2001 i Page [Image] j ANTIMONY TRIOXIDE USDS Number A7236 --- Effective Date 08/02/00 Product Identification Synonyms Antimony oxide, antimony peroxide CAS Mo 1309-64-4 Molecular Weight 291 50 Chemical Formula Sb203 Product Codes J T Baker 0886, 0887, 5305 Mallinckrodt 0216 2 Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Antimony Trioxide 1309-64-4 99 - 100% Yes 3 Hazards Identification Emergency Overview WARNING1 HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN, EYES, RESPIRATORY AND GASTROINTESTINAL TRACTS AFFECTS THE CARDIOVASCULAR SYSTEM J T Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating 3 - Severe (Life) Flammability Rating 0 - None Reactivity Rating 0 - None Contact Rating 2 - Moderate Lab Protective Equip GOGGLES, LAB COAT, VENT HOOD, PROPER GLOVES Storage Color Code Blue (Health) Potential Health Effects Inhalation Causes irritation to the respiratory tract Symptoms can include sore throat, cough Ingestion Ingestion causes irritation to the mouth, nose and stomach Other symptoms include salivation, cough, metallic taste, nausea, vomiting, bloody diarrhea, dizziness, irritability, and muscular pains May cause heart to beat irregularly or stop Skin Contact Causes irritation to skin Symptoms include redness, itching, and pain Eye Contact Causes irritation, redness, and pain Chronic Exposure Prolonged or repeated exposure may damage the liver and the heart muscle Prolonged skin contact may cause irritation, dermatitis, itching, and pimple eruptions There is an association between antimony trioxide production and an increased incidence of lung cancer Aggravation of Pre-existing Conditions Persons with pre-existing skin disorders, impaired respiratory function, or heart disorders (or disease) may be more susceptible to the effects of the substance First Aid Measures Inhalation Remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen Call a physician Ingestion Induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person flley//mao%20%AS%20don/D9Sktop%20Folder/MSDS/ANTIMONY%20TRIOXIDE I xjrsday, March 22 2001 Page 2i i 1 i Skin Contact Immediately flush skin with plenty of soap and water for at least 15 minutes Remove contaminated clothing and shoes Get medical attention Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally Get medical attention immediately Note to Physician A urine test can be used to confirm exposure to antimony trioxide 1 mg / ml is indicative of potentially harmful exposure Chelators such as BAL and unithiol have been used in some countries 5 Fire Fighting Measures i i i Fire Non-combustible, but powdered antimony trioxide may ignite and burn when heated in air Explosion Not considered to be an explosion hazard Trivalent antimony compounds tend to form explosive mixtures with perchloric acid Fire Extinguishing Media Use any means suitable for extinguishing surrounding fire Special Information In the event of a fire, wear full protective clothing and NIQSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode rcidental Release Measures Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8 Spills Sweep up and containerize for reclamation or disposal Vacuuming or wet sweeping may be used to avoid dust dispersal US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities The toll free number for the US Coast Guard National Response Center is (800) 424-8802 i Hi I I Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area Protect against physical damage Isolate from incompatible substances Containers of this material may be hazardous when empty since they retain product residues (dust, solids), observe all warnings and precautions listed for the product . Exposure Controls/Personal ProtectionIAirborne Exposure Limits -OSHA Permissible Exposure Limit (PEL) 0 5 mg (Sb) m3 (TWA) ; -ACGIH Threshold Limit Value (TLV)1 0 5 mg (Sb)/m3 (TWA) for handling and use, A2 suspected human carcinogen for production Ventilation System A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local • exhaust ventilation is generally preferred because it can control • the emissions of the contaminant at its source, preventing ™ dispersion of it into the general work area Please refer to the ACGIH document. Industrial Ventilation, A Manual of Recommended ^ Practices, most recent edition, for details H Personal Respirators (NIOSH Approved) • If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the _ appropriate regulatory agency or respirator supplier, whichever is • lowest For emergencies or instances where the exposure levels are • not known, use a full-facepiece positive-pressure, air-supplied respirator WARNING Air purifying respirators do not protect workers in oxygen-deficient atmospheres ISkin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact I Eye Protection Use chemical safety goggles Maintain eye wash fountain and flleJ//mac%20%A5%20<fon/Desttop%20Folder/MSDS/ANTIMONY%20TRIOXIDE hureday March 22, 2001 j Page quick-drench facilities in work area ]I 9 Physical and Chemical Properties Appearance White polymorphic crystals Odor Odorless Solubility Insoluble in water @ 25C (77F),Slightly soluble in water @ 100C (212F) Density 5 2 pH Wo information found % Volatiles by volume @ 21C (70F) 0 Boiling Point 1425C (2597F) Melting Point 655C (1211F) Vapor Density (Air=l) No information found Vapor Pressure (mm Hg) 1 8 574C (1065F) Evaporation Rate (BuAc=l) No information found LO Stability and Reactivity Stability Stable under ordinary conditions of use and storage Hazardous Decomposition Products Toxic metal fumes may form when heated to decomposition Hazardous Polymerization Hill not occur Incompatibilities Bromine trifluoride, strong acids, strong bases, reducing agents, perchloric acid, and chlorinated rubber Reduction with hydrogen or if used near acids it may form a deadly gas (stibine) Conditions to Avoid Dusting and incompatibles 1 Toxicological Information Oral rat LD50 > 20 g/kg, investigated as a mutagen, tumorigen, reproductive effector \Cancer ListsN NTP Carcinogen Ingredient Known Anticipated IARC Category Antimony Trioxide (1309-64-4) No No 2B 2 Ecological Information Environmental Fate When released into the soil, this material is not expected to leach into groundwater When released into the soil, this material is not expected to evaporate significantly When released into water, this material is not expected to evaporate significantly Environmental Toxicity The LC50/96-hour values for fish are over 100 mg/1 I Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility Processing, use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal, state and local requirements Transport Information Domestic (Land, DOT) flleV//mac%20%A5%20don/Desktop%20Folder/MSDS/ANTIMONY%20TRIOXIDE 'day March 22 2001i i i i i i I i Proper Shipping Name ANTIMONY COMPOUND, INORGANIC, SOLID, N 0 S (ANTIMONY TRIOXIDE) Hazard Class 6 1 UN/NA UN1549 Packing Group III Information reported for product/size 250LB International {Water, I M O ) Proper Shipping Name ANTIMONY COMPOUND, INORGANIC, SOLID, N O S (ANTIMONY TRIOXIDE) Hazard Class 6 1 UN/NA UN1549 Packing Group III Information reported for product/size 250LB International (Air, I C A 0 ) Proper Shipping Name ANTIMONY COMPOUND, INORGANIC, SOLID, N 0 S (ANTIMONY TRIOXIDE) Hazard Class 6 1 UN/NA UN1549 Packing Group III Information reported for product/size 250LB Regulatory Information —\Chemical Inventory Status - Part 1\ .gradient TSCA EC Japan Australia timony Trioxide (1309-64-4) Yes Yes Yes Yes \Chemical Inventory Status - Part 2\ --Canada— Ingredient Korea DSL NDSL Phil timony Trioxide (1309-64-4) Yes Yes No Yes•timony \Federal, State & International Regulations - Part 1\ -SARA 302- SARA 313 •edient RQ TPQ List Chemical Catg Itimony Trioxide (1309-64-4) No No No Antimony com IHt I i i I i 1 I i -\Federal, State & International Regulations - Part 2\ -RCRA- -TSCA- xedient CERCLA 261 33 8(d) imony Trioxide (1309-64-4) 1000 No No cal Weapons Convention No TSCA 12 (b) No CDTA No 311/312 Acute Yes Chronic Yes Fire No Pressure No ivity No (Pure / Solid) WARNING THIS PRODUCT CONTAINS A CHEMICAL (S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER Australian Hazchem Code 2X Poison Schedule S6 WHMIS This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of che information required by the CPR ther Information NFPA Ratings Health 2 Flammability 1 Reactivity 0 Label Hazard Warning WARNING1 HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN, EYES, RESPIRATORY AND GASTROINTESTINAL TRACTS AFFECTS THE CARDIOVASCULAR SYSTEM Label Precautions Avoid breathing dust Avoid contact with eyes, skin and clothing. Keep container closed Use only with adequate ventilation Wash thoroughly after handling Label First Aid If swallowed, induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person If inhaled, remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen In case of nie7//mac%20%A5%20don/DesKtop%20Folder/MSDS/ANTIMONY%20TRIOXIDE lursday March 22. 2001 ! Page contact, immediately flush eyes or skin with plenty of water for i at least 15 minutes Remove contaminated clothing and shoes Wash ! clothing before reuse In all cases call a physician ; Product Use. j Laboratory Reagent Revision Information i No changes ! Disclaimer : Mallinckrodt Baker, Inc provides the information contained herein • in good faith but makes no representation as to its ; comprehensiveness or accuracy This document is intended only as a ! guide to the appropriate precautionary handling of the material by i a properly trained person using this product Individuals receiving the information must exercise their independent judgment : in determining its appropriateness for a particular purpose MALLINCKRODT BAKER, INC MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY j WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO I WHICH THE INFORMATION REFERS ACCORDINGLY, MALLINCKRODT BAKER, j INC WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR ! RELIANCE UPON THIS INFORMATION i**»*****»*»*********************.**«*******»***************«**,**»***,*»»»*******»***********[*** Prepared by Strategic Services Division i Phone Number (314) 539-1600 (USA) i Ill97//mac%20%A5%2MorVDasWop%20Folder/MSDS/ANTIMONY%20TRIOXIDE I I I I I I I I I I I I I I I I I I I : March 22, 2001 page 1 ge] rl I I i I 'OUS CHLORIDE Number S6434 Effective Date 04/15/98 Produce Identification Synonyms Tin (II) chloride dihydrate, stannochlor, stannous chloride dihydrate, Tin Dichloride, Dihydrate CAS No 7772-99-8 (Anhydrous) Molecular Weight 225 63 Chemical Formula SnC12 2H20 Product Codes J T Baker 3980, 3986 Mallinckrodt 8176, 8584 I Composition/Information on Ingredients Ingredient CAS No Percent Hazardous iStannous Chloride 7772-99-8 98 - 100% Yes i Hazards Identification B Emergency Overview WARNING1 HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT J T Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating 2 - Moderate Flammability Rating 0 - None Reactivity Rating 1 - Slight Contact Rating 2 - Moderate Lab Protective Equip GOGGLES, LAB COAT, VENT HOOD, PROPER GLOVES Storage Color Code Orange (General Storage) Potential Health Effects Inhalation Causes irritation to the respiratory tract Symptoms may include coughing, shortness of breath Ingestion Causes irritation to the gastrointestinal tract Symptoms may include nausea, vomiting and diarrhea May cause burning in mouth and throat, abdominal pain, reduced blood pressure, stomach bleeding, collapse and convulsions May cause liver and kidney damage Skin Contact Causes irritation to skin Symptoms include redness, itching, and pain Eye Contact Causes irritation, redness, and pain Chronic Exposure Repeated skin contact with solutions may cause skin rashes in susceptible individuals Prolonged inhalation of dust or fume may result in a benign pneumoconiosis, producing distinctive changes in the lungs with no apparent disability or complications Aggravation of pre-existing Conditions Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more susceptible to the effects of the substance First Aid Measures • Inhalation I Remove to fresh air if not breathing, give artificial • respiration if breathing is difficult, give oxygen Get medical attention I Ingestion • Induce vomiting immediately as directed by medical personnel • Hie ///mac%20%A5%20don/Desktop%20Folder/MSDS/STANNOUS%20CHLORIDE luraday, March 22, 2001 Page i Never give anything by mouth to an unconscious person Get medical ; attention Skin Contact Immediately flush skin with plenty of water for at least 15 minutes Remove contaminated clothing and shoes Get medical attention Wash clothing before reuse Thoroughly clean shoes j before reuse : Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally Get medical attention immediately I 5 Fire Fighting Measures Fire Not considered to be a fire hazard Explosion Not considered an explosion hazard, but reacts explosively when mixed with nitrates or hydrogen peroxide (> 3% solution) Sealed containers may rupture when heated Fire Extinguishing Media Use any means suitable for extinguishing surrounding fire Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode Aqueous solutions of this material are acidic Avoid its contact with eyes and skin Avoid breathing its fumes or dust When heated to decomposition it emits toxic and corrosive fume of hydrochloric acid Accidental Release Measures Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8 Spills Sweep up and containerize for reclamation or disposal Vacuuming or wet sweeping may be used to avoid dust dispersal Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area Protect against physical damage Isolate from incompatible substances Aqueous solutions are acidic, use only in corrosion-resistant vessels Containers of this material may be hazardous when empty since they retain product residues (dust, solids), observe all warnings and precautions listed for the product Exposure Controls/Personal Protection Airborne Exposure Limits Inorganic Tin Compounds, as Sn -OSHA Permissible Exposure Limit (PEL) 2 mg/m3 (TWA) -ACGIH Threshold Limit Value (TLV) 2 mg/m3 (TWA) -NIOSH Recommended Exposure Limits (RED 2 mg/m3 (TWA) Ventilation System A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details Personal Respirators (NIOSH Approved) If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator WARNING Air purifying respirators do not protect workers in oxygen-deficient atmospheres Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact Eye Protection Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible Maintain eye wash fountain and quick-drench facilities in work area flleV//mac%20%A5%20don/Desktop%ZOFolder/MSDS/STANNOUS%20CHLORIOE nuraday,March 22, 2001 Page 3 Physical and Chemical Properties Appearance Colorless crystals Odor Slight odor of hydrochloric acid solubility llSg/lOOml water 8 OC (32F) Specific Gravity 2 71 PH NO information found % Volatiles by volume @ 21C (70F) 0 Boiling Point NO information found Melting Point 38C (100F) When rapidly heated Vapor Density (Air=l) NO information found vapor Pressure (mm Hg) No information found Evaporation Rate (BuAc=l) No information found Stability and Reactivity Stability Powerful reducing agent Small quantities of hydrochloric acid are present in aqueous solutions Absorbs oxygen from air and forms the insoluble oxychloride Forms an insoluble basic salt when dissolved with much water Hazardous Decomposition Products When heated to decomposition it emits toxic and corrosive fume of hydrochloric acid Hazardous Polymerization Will not occur Incompatibilities Sodium, potassium, bromine trifluoride, calcium carbide, calcium acetylide, ethylene oxide, and nitrates Reacts with hydrazine hydrate to form dihydrazine chloride, which decomposes explosively when heated Contact with strong oxidizing agents or alkalis will generate heat and fumes Conditions to Avoid Moisture, heat, flames, ignition sources and incompatibles ^ lexicological Information • Anhydrous Oral rat LD50 700 mg/kg Investigated as a tumorigen, mutagen, reproductive effector Hydrate Investigated as a mutagen, reproductive effector \Cancer Lists\ NTP Carcinogen gredient Known Anticipated IARC Category I .annous Chloride (7772-99-8) No No None "l Ecological Information I Environmental Fate No information found Environmental Toxicity No information found 3 Disposal Considerations I Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility Processing, use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal, state and local requirements flle7//mac%20%A5%20aon/Desktop%20Fold9r/MSDS/STANNOUS%20CHLORIDE luraday, March 22, 2001 14 Transport Information Domestic (Land, DOT) Proper Shipping Name CORROSIVE SOLIDS, N 0 S (STANNOUS CHLORIDE) Hazard Class 8 UN/NA UN1759 Packing Group III Information reported for product/size 100LB International (Water, I M O ) Proper Shipping Name CORROSIVE SOLIDS, N 0 S (STANNOUS CHLORIDE) Hazard Class 8 UN/NA UN1759 Packing Group ill Information reported for product/size 100LB International (Air, I C A O ) Proper Shipping Name CORROSIVE SOLIDS, N 0 S (STANNOUS CHLORIDE) Hazard Class 8 UN/NA UN1759 Packing Group III Information reported for product/size 100LB .5 Regulatory Information \Chemical Inventory Status - Part 1\ ingredient TSCA EC Japan Australia Stannous Chloride (7772-99-8) Yes Yes Yes Yes \Chemical Inventory Status - Part 2\ —Canada— ingredient Korea DSL NDSL Phil Stannous Chloride (7772-99-8) Yes Yes No Yes \Federal, State & International Regulations - Part 1\ -SARA 302- SARA 313 ingredient RQ TPQ List Chemical Catg Stannous Chloride (7772-99-8) No No No No \Federal, State & International Regulations - Part 2\ -RCRA- -TSCA- Ingredient CERCLA 261 33 8(d) Stannous Chloride (7772-99-8) No No No Page I hemical Weapons Convention No TSCA 12 (b) No CDTA No ARA 311/312 Acute Yes Chronic Yes Fire No Pressure No eactlvity No (Mixture / Solid) Australian Hazchem Code 2X Poison Schedule No information found WHMIS This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR 5 Other Information NFPA Ratings Health 1 Flammability 0 Reactivity 0 Label Hazard Warning WARNING' HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT Label Precautions Avoid contact with eyes, skin and clothing Avoid breathing dust Keep container closed Use only with adequate ventilation Wash thoroughly after handling Label First Aid If swallowed, induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person If inhaled, remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen In case of contact, immediately flush eyes or skin with plenty of water for fne^//mac%20%A5%20don/Desktop%20Folder/MSOS/STANNOUS%20CHLORIOE lay March 22 2001 Page 5 at least 15 minutes Remove contaminated clothing and shoes Wash clothing before reuse In all cases, get medical attention Product Use Laboratory Reagent Revision Information MSDS Section(s) changed since last revision of document include 3, 16 Disclaimer Mallinckrodt Baker, Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER, INC MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDINGLY, MALLINCKRODT BAKER, INC WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION Prepared by Strategic Services Division Phone Number (314) 539-1600 (USA) I I I I I I I I I I i I flle///mac%20%A5%20don/Desttop%20Folder/MSDS/STANNOUS%20CHLORIDE hursday. March 22 2001 HEALTH RELATED INFORMATION ON SILICA Click on the URL below to connect with [Image] http //www osha-slc gov/SLTC/silica_advisor/mainpage html [Image] http //www cdc gov/niosh/silicpag html U S SILICA COMPANY MSDS - MATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Names/Trade Names Silica Sand sold under various names ASTM TESTING SANDS ¥ GLASS SAND ¥ FLINT SILICA ¥ EM-SERIES ¥ F-SERIES ¥ FOUNDRY SANDS ¥ FJ-SERIES ¥ FP-SERIES ¥ H-SERIES ¥ L-SERIES ¥ N-SERIES ¥ NJ-SERIES ¥ OK-SERIES ¥ P-SERIES ¥ T-SERIES ¥ HYDRAULIC FRACING SANDS ¥ MIN-U-SIL ¥ MYSTIC WHITE ¥ #1 DRY ¥ #1 SPECIAL ¥ PENN SAND ¥ Q-ROK ¥ SIL-CO-SIL ¥ SUPERSIL Synonyms/Common Names Flint, Ground Silica Sand, Silica Sand, Quartz, Crystalline Silica, Manufacturer's Name U S Silica Company P 0 Box 187 Berkeley Springs, WV 25411 Emergency Telephone Number 304-258-2500 304-258-8295 (fax) Date Prepared September 15, 2000 SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS Ingredients Crystalline Silica (Quartz) Aluminum Oxide Iron Oxide Titanium Oxide Chemical Formula Si02 A1203 Fe203 Ti02 Typical %, By Weight 99 0 - 99 9 Exposure Limits for Hazardous Ingredients Crystalline Silica (Quartz) OSHA PEL 10 mg/m3 % Si02 + 2 ACGIH TLV 05 CAS # 14808-60-7 1344-28-1 1309-37-1 13463-67-7 NIOSH REL 05 The exposure limits are time-weighted average concentrations for an 8-hour workday and a 40-hour workweek Crystalline silica exists in several forms, the most common of which is quartz If crystalline silica (quartz) is heated to more than 870,C, it can change to a form of crystalline silica known as trydimite, and if crystalline silica (quartz) is heated to more than 1470,C, it can change to a form of crystalline silica known as cristobalite The OSHA PEL for crystalline silica as trydimite and cristobalite is one-half of the OSHA PEL for crystalline silica (quartz) SECTION 3 - HAZARD IDENTIFICATION Emergency Overview The U S Silica Company material is a white or tan sand, or ground sand It is not flammable, combustible or explosive It does not cause burns or severe skin or eye irritation A single exposure will not result in serious adverse health effects Crystalline silica (quartz) is not known to be an environmental hazard Crystalline silica (quartz) is incompatible with hydrofluoric acid, fluorine, chlorine trifluoride or oxygen difluoride Potential Health Effects Inhalation file///mac%20%A5%20don/Desktop%20Folder/MSDS/silica%20sand ursday Mated 22, 2001 Page 2 •I I •j I ^ H a Silicosis Respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs Silicosis may be progressive, it may lead to disability and death b Cancer Crystalline silica (quartz) inhaled from occupational sources is classified as carcinogenic to humans c Autoimmune There are some studies that show excess numbers Diseases of cases of scleroderma and other connective tissue disorders in workers exposed to respirable crystalline silica d Tuberculosis Silicosis increases the risk of tuberculosis e Nephrotoxicity There are some studies that show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica Eye Contact Crystalline silica (quartz) may cause abrasion of the cornea •kin Contact Not applicable Ingestion Not applicable ronic Effects The adverse health effects — silicosis, cancer, atoimmune diseases, tuberculosis, and nephrotoxicity — are chronic Efects ns and Symptoms of Exposure Generally, there are no signs or symptoms exposure to crystalline silica (quartz) ical Conditions Generally Aggravated by Exposure The condition of individuals with lung disease (e g , bronchitis, emphysema, chronic structive pulmonary disease) can be aggravated by exposure te Section 11, Toxicological Information, for additional detail on stential adverse health effects [•ION 4 - FIRST AID MEASURES alation No specific first-aid is necessary since the adverse health Efects associated with exposure to crystalline silica (quartz) result from chronic exposures If there is a gross inhalation of crystalline L|lica (quartz) , remove the person immediately to fresh air, give Btificial respiration as needed, seek medical attention as needed Eye Contact Wash immediately with water If irritation persists, seek fical attention n Contact Not applicable Ingestion Not applicable tlON 5 - FIRE FIGHTING MEASURES talline silica (quartz) is not flammable, combustible or explosive ICTION 6 - ACCIDENTAL RELEASE MEASURES ills Use dustless methods (vacuum) and place into closable container r disposal, or flush with water Do not dry sweep Wear protective equipment specified below e Disposal Method See Section 13 ION 7 - HANDLING AND STORAGE kcautions During Handling and Use Do not breath dust Use adequate tilation and dust collection Keep airborne dust concentrations below Do not rely on your sight to determine if dust is in the air Silica may be in the air without a visible dust cloud If dust cannot be kept slow permissible limits, wear a respirator approved for silica dust when ~|mg, handling, storing or disposing of this product or bag Practice housekeeping Do not permit dust to collect on walls, floors, sills, es, machinery, or equipment Maintain, clean, and fit test respirators in accordance with OSHA regulations Maintain and testKtilation and dust collection equipment Wash or vacuum clothing that become dusty See also control measures in Section 8 cautions During Storage Avoid breakage of bagged material or spills of bulk material See control measures in Section 8 I flle///mac%20%A5%20don/Desktop%20Fold8r/MSDS/3il!ca%203and tufsday. March 22, 2001 Do not use U S Silica Company materials for sandblasting The OSHA Hazard Communication Standard, 29 CFR Sections 1910 1200, 1915 1200, 1917 28, 1918 90, 1926 59 and 1928 21, and state and local worker or community "right-to-know" laws and regulations should be strictly followed WARN YOUR EMPLOYEES (AND YOUR CUSTOMERS IN CASE OF RESALE) BY POSTING AND OTHER MEANS OF THE HAZARDS AND THE REQUIRED OSHA PRECAUTIONS PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT THE OSHA PRECAUTIONS See also American Society for Testing and Materials (ASTM) standard practice E 1132-99a, "Standard Practice for Health Requirements Relating to Occupational Exposure to Respirable Crystalline Silica " SECTION 8 - EXPOSURE CONTROL / PERSONAL PROTECTION Local Exhaust Use sufficient local exhaust to reduce the level of respiroble crystalline silica to below the PEL See ACGIH 'Industrial Ventilation, A Manual of Recommended Practice" (latest edition) Respiratory Protection The following chart specifies the types of respirators which may provide respiratory protection for crystalline silica Particulate Concentration 10 X PEL or less 50 x PEL or less 500 x PEL or less Greater than 500 x PEL or entry and escape from unknown concentrations MINIMUM RESPIRATORY PROTECTION* Any particulate respirator, except single-use or quarter-mask respirator Any fume respirator or high efficiency particulate filter respirator Any supplied-air respirator Any self-contained breathing apparatus A high efficiency particulate filter respirator with a full facepiece Any supplied-air respirator with a full facepiece, helmet, or hood Any self-contained breathing apparatus with a full facepiece A Type C supplied-air respirator operated in pressure-demand or other positive pressure or continuous-flow mode Self-contained breathing apparatus with a full facepiece operated in pressure-demand mode A combination respirator which includes a Type C supplied-air respirator with a full facepiece operated in pressure-demand or other positive pressure continuous-flow mode and an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive pressure mode *Use only NIOSH-approved or MSHA-approved equipment 1910 134 and 42 CFR 84 See 29 CFR See also ANSI standard Z88 2 (latest revision) "American National Standard for Respiratory Protection" Permissible Exposure Levels Component CAS No Percentage (by wt ) OSHA Exposure Guidelines ACGIH NIOSH TWA STEL TWA STEL TWA STEL Unit Crystalline Silica (Quartz) 14808-60-7 99 0-99 9 10 Si02 None 05 None 05 None mg/m3 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance White or tan sand, granular, crushed, or ground Boiling Point 4046,F Odor Hone Vapor Pressure (mm Hg ) None Specific Gravity (Water =1) 2 65 Vapor Density (Air = 1) None fila///mac%20%A5%20don/Desktop%20Folder/MSDS/silica%20sand uirsday March 22 2001 Page 4 •Melting Point 3110 ,F Solubility in Water Insoluble in water taporation Rate (Butyl Acetate = 1) None CTION 10 - STABILITY AND REACTIVITY (tability Crystalline silica (quartz) is stable ncompatibility (Materials to Avoid) Contact with powerful oxidizing gents, such as fluorine, chlorine trifluoride and oxygen difluoride, may cause fires I; azardous Decomposition or Byproducts Silica will dissolve in ydrofluoric acid and produce a corrosive gas - silicon tetrafluoride .Hazardous Polymerization Will not occur RECTION 11 - TOXICOLOGICAL INFORMATION A SILICOSIS I 'he ma^or concern is silicosis, caused by the inhalation and retention of espirable crystalline silica dust Silicosis can exist in several forms, inronic (or ordinary), accelerated, or acute Chronic or Ordinary Silicosis (often referred to as Simple Silicosis) is most common form of silicosis, and can occur after many years of osure to relatively low levels of airborne respirable crystalline 'ilica dust It is further defined as either simple or complicated silicosis ?le silicosis is characterized by lung lesions (shown as radiographic acities) less than 1 centimeter in diameter, primarily in the upper ng zones Often, simple silicosis is not associated with symptoms, detectable changes in lung function or disability jle silicosis may be progressive and may develop into complicated Llicosis or progressive massive fibrosis (PMF) Complicated silicosis or is characterized by lung lesions (shown as radiographic opacities) greater than 1 centimeter in diameter Although there may be no symptoms ssociated with complicated silicosis or PMF, the symptoms, if present, (re shortness of breath, wheezing, cough and sputum production plicated silicosis or PMF may be associated with decreased lung function and may be disabling Advanced complicated silicosis or PMF maytad to death Advanced complicated silicosis or PMF can result in heart sease secondary to the lung disease (cor pumonale) celerated Silicosis can occur with exposure to high concentrations of respirable crystalline silica over a relatively short period, the lung lesions can appear within five (5) years of the initial exposure The ••egression can be rapid Accelerated silicosis is similar to chronic or B-dinary silicosis, except that the lung lesions appear earlier and the progression is more rapid Acute Silicosis can occur with exposures to very high concentrations of •spirable crystalline silica over a very short time period, sometimes as Hort as a few months The symptoms of acute silicosis include progressive shortness of breath, fever, cough and weight loss Acute silicosis is fatal HRI CANCER RC - The International Agency for Research on Cancer ("IARC") concluded that there was "sufficient evidence in humans for the carcinogenicity of stalline silica in the forma of quartz or cristobalite from |cupational sources", and that there is "sufficient evidence in perimental animals for the carcinogenicity of quartz and cristobalite " The overall IARC evaluation was that "crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic»humans (Group 1) " The IARC evaluation noted that "carcinogenicity was detected in all industrial circumstances studies Carcinogenicity may dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of itsP'ymorphs " For further information on the IARC evaluation, see IARC ographs on the Evaluation of Carcinogenic Risks to Humans, Volume 68, lica, Some Silicates " (1997) NTP - The National Toxicology Program, in its Ninth Annual Report on rcinogens, classified "silica, crystalline (respirable)" as a known an carcinogen - Crystalline silica (quartz) is not regulated by the U S Occupational Safety and Health Administration as a carcinogen I (IIS///mac%20%A5%20don/D9sktop%20Fold9r/MSDS/sillca%20sand hursday March 22, 2001 There have been many articles published on the carcinogenicity of crystalline silica, which the reader should consult for additional information, the following are examples of recently published articles (1) "Crystalline Silica and Lung Cancer The Problem of Conflicting Evidence", Indoor Built Environ, Volume 8, pp 121-126 (1998), (2) •Crystalline Silica and the risk of lung cancer on the potteries", Occup Environ Med , Volume 55, pp 779-785 (1998), (3) "Is Silicosis Required for Silica-Associated Lung Cancer'", American Journal of Industrial Medicine, Volume 37, pp 252- 259 (2000), (4) " Silica, Silicosis, and Lung Cancer A Risk Assessment", American Journal of Industrial Medicine, Volume 38, pp 8-18 (2000), (5) "Silica, Silicosis, and Lung Cancer A Response to a Recent Working Group Report", Journal of Occupational and Environmental Medicine, Volume 42, pp 704-720 (2000) C AUTOIMMUNE DISEASES There is evidence that exposure to respirable crystalline silica (without Silicosis) or that the disease Silicosis is associated with the increased incidence of several autoimmune disorders, — scleroderma, systemic lupus erythematosus, rheumatoid arthritis and diseases affecting the kidneys For a review of the subject, the following may be consulted "Occupational Exposure to Crystalline Silica and Autoimmune Disease", Environmental Health Perspectives, Volume 107, Supplement 5, pp 793-802 (1999), "Occupational Scleroderma", Current Opinion in Rheumatology, Volume 11, pp 490-494 (1999) D TUBERCULOSIS Individuals with Silicosis are at increased risk to develop pulmonary tuberculosis, if exposed to persons with tuberculosis The following may be consulted for further information Occupational Lung Disorders, Third Edition, Chapter 12, entitled "Silicosis and Related Diseases", Parkes, W Raymond (1994), "Risk of pulmonary tuberculosis relative to Silicosis and exposure to silica dust in South African gold miners," Occup Environ Med , Volume 55, pp 496-502 (1998) E KIDNEY DISEASE There is evidence that exposure to respirable crystalline silica (without Silicosis) or that the disease Silicosis is associated with the increased incidence of kidney diseases, including end stage renal disease For additional information on the subject, the following may be consulted "Kidney Disease and Silicosis", Nephron, Volume 85, pp 14-19 (2000) SECTION 12 - ECOLOGICAL INFORMATION Crystalline silica (quartz) is not known to be ecotoxic, i e , there is no data which suggests that crystalline silica (quartz) is toxic to birds, fish, invertebrates, microorganisms or plants For additional information on crystalline silica (quartz), see Sections 9 (physical and chemical properties) and 10 (stability and reactivity) of this MSDS SECTION 13 - DISPOSAL CONSIDERATIONS General The packaging and material may be landfilled, however, material should be covered to minimize generation of airborne dust RCRA Crystalline silica (quartz) is not classified as a hazardous waste under the Resource Conservation and Recovery Act, or its regulations, 40 CFR 261 et seq The above applies to materials as sold by U S Silica Company The material may be contaminated during use, and it is the responsibility of the user to assess the appropriate disposal of the used material SECTION 14 - TRANSPORT INFORMATION Crystalline silica (quartz) is not a hazardous material for purposes of transportation under the U S Department of Transportation Table of Hazardous Materials, 49 CFR 172 101 SECTION 15 - REGULATORY INFORMATION UNITED STATES (FEDERAL AND STATE) TSCA No Crystalline silica (quartz) appears on the EPA TSCA inventory under the CAS No 14808-60-7 RCRA Crystalline silica (quartz) is not classified as & hazardous waste under the Resource Conservation and Recovery Act, or its regulations, 40 CFR 261 et seq CERCLA Crystalline silica (quartz) is not classified as a hazardous substance under regulations of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) , 40 CFR 302 file.///mac%20%A5%20don/D8Sktop%20Fold«r/MSOS/3illca%20sand lay March 22 2001 Page 6 nergency Planning and Community Right to Know Act Crystalline silica l(quartz) is not an extremely hazardous substance under Section 302 and is not a toxic chemical subject to the requirements of Section 313 I lean Air Act Crystalline silica (quartz) mined and processed by U S < ilica Company was not processed with or does not contain any Class I or lass II ozone depleting substances Silica is included in the list of substances that may be included in Boatings used in food contact surfaces, 21 CFR 175 300(b)(3)(xxvi) Respirable crystalline silica (quartz) is classified as a carcinogen IiSHA Carcinogen Crystalline silica (quartz) is not listed 'alifornia Proposition 65 Crystalline silica (quartz) is classified as a substance known to the State of California to be a carcinogen •ANADA Domestic Substances List U S Silica Company products, as (naturally-occumng substances, are on the Canadian DSL •HMIS Classification D2A OTHER 3CS No 238-878-4 Label (Risk/Safety Phrases) R 48/20, R 40/20, S22, S38 C"RC Crystalline silica (quartz) is classified in IARC Group 1 tional, state, provincial or local emergency planning, community ght-to-know or other laws, regulations or ordinances may be applicable—consult applicable national, state, provincial or local laws PION 16 - OTHER INFORMATION azardous Material Information System (HMIS) talth * ammability 0 activity 0 otective Equipment E IFor further information on health effects, see Sections 3 and 11 of .is MSDS itional Fire Protection Association (NFPA) alth 0 ammability 0 Reactivity 0 Sites with Information about Effects of Crystalline Silica Exposure age] //www osha-slc gov/SLTC/silicacrystallme/index html - The cupational Safety and Health Administration I I age] tp //www cdc gov/niosh/silicpag html - NIOSH Hotlinks to Silicosis vention S SILICA COMPANY DISCLAIMER information and recommendations contained herein are based upon data believed to be correct However, no guarantee or warranty of any kind, press or implied, is made with respect to the information contained rein We accept no responsibility and disclaim all liability for any ful effects which may be caused by purchase, resale, use or exposure our silica Customers-users of silica must comply with all applicable health and safety laws, regulations, and orders, including the OSHA zardous Communication Standardjtoza I BACK HOME NEXT [employment opportunities][home] [news] ffie///mac%20%A5%20don/083ktop%20Fold8r/MSDS/silica%20sand hcrrsday March 22 2001 Page. i| North American Operations | Glass Sands | Foundry Sands | Ground I Silica i Calcined Kaolin Clay | Building Products | Pool Filter Sands ; Recreational Products | Golf Course Sands | Other Products i Florisil | Plant Locations | Online Product Information Data Base | U S S People ; Job Opportunities | MSDS/Links to Silica Health & Safety Information What's New I Contact Us I flle.///mao%20%A5%20don/Dasktop%20Folcier/MSDS/silica%20sand I i I MATERIAL SAFETY 0ATA *HttT'j__!.'^,u > ,.r._ ;:;«^ H...-'.«,iij:-4v KB ALLOYS, INC. EMVWQNHENTAU HEALTH & SAFETY SERVICE* P.O. SOX 14627 READING, PA ttt12<4827 (215) 670-3350 M808 IDENTIFICATION NUMBER A400 OATS ISSUED 12/16/86 3/19/92 POTASSIUM ALUMINUM FLUORIDE ISSUED BY DUNN EMERGENCY PHONE NUMBER CHEMICAL NAMEt Aluminum RuXkfc TRAD£NAM6; PAF - PottMluin Oiyott* CHEMICAL FAMILY: FORMULA: KMMCK3ATO PBHOWT CAS MUMNUt NIOSMmcc« KUHMEIl Nora EXPOSURE UMTS OSKA1YVA : 2.5; Ah Dwtt«is; ACQIHTW : Z5; Aft OvM 10.0; far «xpo»uf« ritfc EUSMSNT SUBJECT TO SECTION 973 REPORTING Aluminum fari* IV. "FRgSZlNQ POINT Not Applieabla VAPOR PRESSURE (mmHfl):Not AppMcabia MELTING POfNTi 1010-1030*C VAPOR DENSHY (AIR-lh NtfApafcabta 80IUNGPOWT:Daccfnpoaaa DENSITY fl«J 2.66 SU8UME3©:Not Applteabla 80LUWUTY IN WATCH:Sight "StallEVAPORATION RATS' Not % VOU71l£8 BY VOLUMft APPEARANCE AND ODOR; Powdaf or Lumps - WhKa CfyttaRlna Color - No Odor ;P:.V. -J'FIRE, EXPLOSION ' * *••* •' ** tfN- f*_ FLASH POINT {WITH EXTINGUISHING MEDIA TNa inataf^ noncanburtbte. UMatttoguiahingmadto «pproprt*»tothaaurremdncj tlnh PTOCEOURES tf tNft AHMfW to InvotMd In • r* Mtpin^ki **--—-i-i-o? nuonot p«Mr«ieMtoa«i UNUSUAL Rfte ANDEXPUDSJON HAZARDS GENERAL REACTTVITY 7W» product to « •tati* mMrU INOOMPATBIUTY (MATOMALSTOAVO<0} HAZARDOUS OEQOMPOeiTiON PRODUCT? .bu not United to, hydragtn PRIMARY ROUTED)OFEXPOSURE INHALATION1, inhtlatlonef ._..grinding cparatfona which ganarata 1NQEST1ON' Hand, tiothlngaflddrfnfccontactwtthtuorfdaaatta,dual*fanwc*Aeak«»tagaatlonof_. . .* .•_•_ * i — *_.„*! _^_ . *». .» .*.*. _ _. *_ . _». . __ .•_.•_•_— aMafcja^^aMft aa^d" kbtjw« ^aW* iwaVno of tiaaua and parmajtant leaningSKIN: Skin eenecet with flucfid* sate canorcKaaMRty.inflation, i EYES;•urreundlngtiMua.ifth*rwnde<de4hingia aalt9. tha aya and'tathaayaaockat TOXICITY Expoaur* to tha dual «r mm* c* fluorida salt* may praaant •kjnMeant h«aioauMicute poi*dn4r»B or cJeath farincpalV!»Inflaisor^. *Wn contact anmambfaiMwcaneauaaaavaraln%atiefiarKitlM4Md«tRiiga Noaa Waada and afow Inaaal paaaaga hava baan raportad. GrlpcfrqbomchangaaandmotDlnqoftoom«.._fffacta of «poaur« although they ara not common among ewrant Muama) amptpyaai, aatta can in tha fcFFECIS Of of ffuorlda saw can ewaa atvara gaatnc pan, irtamaj bwMIng, Uaaua damaga and_..- »polaonlng from Jnhalatfan la net common. Now bfaada, aWn Irrfiaiion, ay» irrigation, tiawadamaga and aiow haalfng acan can raauR Ifaxpoauni It txcaaaiva. Fluroida aaftc ara aolubt* in bodyfluids and awaat and ara ccrroaiva to tha akin and mucoua rnarnbranaa. ACUTc: mgaaoondaath. Acuta polac CHRONIC: Chronic axposur • to fluortda eompoonda h« batn raportad to eauM «----- -----and fioarnants known •§ oataoa of tooth anamai atttwugh nakjnafluotida aaiu may eauaa damagit to tha akH aya and'mucoua mwnbranaii. jicaoon of bona VI HEALTH HAZARD INFORMATION (00rtln«*d) CARCINOGENIC REFERENCES Neither product nor Ka Ingredient* are listed *»« earorrInternational Agency for Research on Cane*r, or Unit*Administration. tn* National Toxicology Program,Occupational WWy and Health WECMCAL CONDITIONS AGGRAVATED BYEXPOSURE Peraon* »rth prc-MMting eye and *Wn disorders or damage to muo»u» membmn** may ba mom«j»»*ptatte to tl***eciao1 fluoride expoeur*. B*e*)ea fluoric* dualimlinl and fm b<wn fln*»dte iktWaJ cfanormalftltt *M *j*lfufr»oin b*»reepir*orypropw tcr»«rtng orbe conduct*} on kxflvWu«J« who rwy to* «pOMd to furthtr rW( V hvdtng andu»« of thm nwttrial eausm •XCMMTV* «xpo«ur«. INHALATION «K( puunor^ «d«m«twuM faRow for « (Mat 49 hour*.cNnocl tMts nny I fluoride compound* raqulr** medical i Do NOT loouos vofnltino for anyUIIBIWITWIU ii«vii«» vwiupwuiitHp i»v(»«iw» uiwovi •vmtB tamount D«u«on of ingwrtad fluorkto muai b* don* ««h caution. Control of ahock, Wtammation ofdaaua, progra»»VatiBwi«da$tniciJon aixi *J««roV«« Imbtiano* r«q^««k»« obaarvatkxi forat lust48 hours. SKIN 8Wn out* and aor»»^ arid cc**amJnaaonmt*t»mj*h*dlmoootwater. MMbumamay pain and tk Htact* oan IM traeMd by us^ e*J«ium ojueonate *^*d topioaly.afar with cafcfcjm gluconate. sxm*d me3faBi treetment la ntmasw/ to contra* aavar*r EYES Pain can ba llut2 or 3 41 opt of ,9% pontocailna ptna . _^__.Modtarf aaafatanooahoutd be obtalnad at onoa* Contvot fanaoa tnoud not ba worn • wortdnfl wtUi wocWo aaKa or VENTILATION Local axtwjst v«rrt«tion-«hould ba uaad to control txpowa to airbom* Ifaorida oompounda wnamvarposalbf*. RESPIRATORY PROTECTION Ua* NIOSH approvad racplratoni M apaoKlad by an IndwtrW Hygitniat or ouaflftod SafetyPreteaaionaL ljung mnctftxi taa<» ara raoommafldad for u»ara of negwiv* praaauradtMoa*. PROTECTJVfi GLOVES Wearreoorrr**i*t«nt hand corflact wth «uorida eompoortda. QauiM>tvpa giova* ant~ ' 'ridaowwcornmended and, wrwr* fluorid* contaWng aokition* or add* are used, the gibve* should be acid PROTB Ww aatat/ ot«*»M chwnieal yoogla* (pi«Me lana) or tul^fae* «nWd whan handing fluoride compound*. Oo not wear contact fanaa*. OTHERPROTECTIVEEQUIPMENT Protective clothing *uch aa uniforms, ditpoaable oavorall*, safety anon. ate., may be reoutrad during handNng operaiiona as appropriate to the okeumautnoaa of exooeure. For inereavao protection k may ba aoViubia to waar acn r««i«ianl jacket, bootf. frouaars. etc., as appropriate. RECOMMENDED MONrrORING PROCEDURES ENVtRONMENTALSURVeiLlANOE. Exposure totiie eiernenta tdentrlled In Section II can ba beat determined byhavjng air aampiea taken in tna employe* bfeathtnjj zone, work ar*a or department. Sample anafyai* ahouid ba Tor total fjoridj eorttert phi* any other constituent of conuecn MEDICAL SURVEILLANCE Lung fwwion te*t«,cheat x-rty* and routine orwaKaJ *xantin«tior*» may M u*aful to d*t*mHn* affect* of dust or turns exposure, Urinary Huond* analyai* can be a uaafui indtoator of expoaur*. but require* basebne te*ung and p«*t-*xpo*ue aempJe*. K. KNVIKDNMErfTAL PROTECTION INFORMATION STEPS TO BE TAKEN IFMATERIAL IS OR SPILUED If trim mttwJa) 19 in powd* or Oust term, ««m/p trwuM CMI cooduciW wftft utilizing * nigh «fflc«mcy parttailat* atr fWnaten tysten. Caution ahojuW t vacuumb» wten to mlnimte* ecids stowkl b* fMMraiiz»d by car0M «dcfiltoni! or * Nffl« tfurry, aoda ash oth«f a/h«JI, Small •mounts may t* p««t*d &y t*ing «xe«M watw to r«due9 *aktty. Caution mustoa taK»n during neuu «laaitcn to nvofd mcpaw* to t^drogon ftuorkJw g|3» or otter fluwld* compound WASTE DISPOSALMETHOD f«d«M^ragorwffl^r«quir*i iramport preoadurM. C«H«t w ErortwmwnMl EnglnMf Of conwitorte tamKiar wrttti" Ruofktt oompoundg may hava tfrnfflcar* Import onajr and way qua* ty. ...and nNMtMNi to the •flvfr ontrt4flt {<MorMtf30 to atrMRtt, MWW cyiianttti ofound' ' thoukl bo oortnMMMt ImrnocMolyi If tuch MMndaf for • ml Of ^WVIM • nrrlwlonv, ENVWONMENTAI, HAZARDS «oftksiri to •quttto cc KANDUNG Thto product routtba_rj«xflo<laocoixfeigty to ^••^ 9h£L2M> ( bs eoncK,«M toto wring or 3tor»'mi« product in * {try *r»a PiuorW* aaJt* «rwuti not b« «tef«J K}»«int to adds. K*opfrom contact with food or (»«d prorfucto. ! DANCER!MAY OCCUR MAYBE FATAL IF SWAilOWai This prsctuctceoMni Iwganw Ffcwotffl «**>• uucoiis CONTENT 4 DESCRIPTION OP K8 ALLOYS, INC. MATERIAL SAFETY DATA SHEETS definition* ar» Inttndad for UM wnri Material Safaty Data 8hMt* auppfed by KB ALLOYS, INC. Quarter* concerning ' ' should ba dlr*d«d la* MANAGER OF INDUSTRIAL HYOJENE KB ALLOYS, INC. P.O. BOX 14827 READING, PA IMlft-4927 i 070*3350 SECTION 1 - PRODUCT WeNTtPtCATION Ctwmtetl Mama; Anamaconelatf>r*wtthih«AQfftemUj^ayBt^WPAC) or tf»» Crwntea( AbitrMM $«Moi (CAS).TOdANfffitt Thtngm«ih«producttoaoMby,La.,thtprodu— - - -- - • '• • .. - • • ^— ^B_a0 of viflinvi toraampoundlT wt ffCTION N - HAZMIOOtW CONSTTTVEKT9 W of <h# product. ANawkN«eanri ThtlackofaOAB ofTodoBtetooT A)^{^a^SiSn>ffitffS) - uauaty a tkm ^CqH)Thrwttt(dLhitVa)u«aT.Vl.inm<rV" 1oroaitalnMbatanoai(M« fCCTTON W-tAHA TITLE B 6«etton 313 ofTtfr JB of ih« Supwfund ArinjphomfW«ft<J te subjoet to Part 972-Toxic,, .. ipsulMfaqulramari&haaL arid mttft ba copiadtnd ftdiattbutad wham SCCTWN IV * PHYSICAL PROPERTIES PraazhtoPoInf Thatamp*r«iM«twhtcnaliquidehan9«atoaiolld ArangamaybagivaaMafthiiVoJrmThttamp«r«tur»aiwtiioha»aiIdcfiariQ»»teaBc^ ArawmayVtflftwv Boiling Point; ThatamparaturaatwriiehallQbidehangaatoavapor. UouaV«WMMdataaatov»lpraaita9(780mm-Htf. H Evtporrton (Utt! lrxttn<td««f«i«f or OowtrtfwnAppMnnotwdOdort A description or thfpro*ietJnt«nn« of fomi,eolor.cdor,«te. Th* radio of »h«w«4*C. T)»» term "OENSrrr »v»»worj^eomp<irtdtoan«6A^wrufn»of«lr. Airto«qu?viienttol.OgM of tvowm* of matorlal to thowrtgW of m Mutfvolum«ofw»tor. W«<3McribMth0«onoir«r«ion of m«w««th*m««pwuxtYc1um«,«.g, %Vol«tlM«VyVolumr. I wtlMJ- MCfflON V - FIRE, EXPLOSION ANO ttEACTJVTrY INFOm*ATlON FMnfl Point (With Tart M * malarial flbcplMh*LfU U3WER EXPLOSION UMIT: Tr» Iowa* vapor aurtaea of (ft* malarial oatae;FlammaM* flbcplMh*) Unit* athod); Thano; Mated.Jm»t*V/V%: UCL: UPPER EXPLOSION UMtT Th«ncentration in #*wWch b| apark or flam* «N occur. Extlngulantog Madia; thaty|x^fira*J<tin0uWngmatoto6auaadtaWngi^ Spaeiai Fir* Fighting Procaduraa: Indteataa aquipmant to protaet fframan from toxic product*Unuaual Flra tnd Exajoalon Hazard*] Chamteaj ehangaa 6«t may oo - -Qanarvl RaaotMty: ThatandaiKyofi ^ •--Incompatibility (MatarH* To Avoid): SECTION VI - HEALTH HAZARD WPORMATION Primary Routtte) el e»o«ur* eontr tiatnQi.r f^im^^j^^ J*Mm^^mt~ ruvanupoaufa: ift-i-«!tf 1*?»*«B*'^«S* «?V_^.f»^-•Wwonw; ito«joaurabyth«cutanaom«wa.althaf*^abeorptlonor»Wncori^ aalatt«dOMorMha)conc^rabonc/tham««flaJarft$ *• rat* AT nlcVt and rMHiori I* , In Man or anfntaJa. axpoauratoatoxle _aartvaod By ixpo«ur«t •iCTIOM V» -1MEHQCNCY ft FWWT AD PHOC Emaraancy action to < Emargancy action » rEinaro^ncyaetion(oa6ti(«a«aoVaraaafaotoduataalbAoor»Mtor ,Cy**,' Enwr9ancyacttonto*o*rfaa**wfW««*^ SECTION VIII-INOU«miALtfrGlir«eONmOLIKASU matwlaL nojttion for flrflBtCwO^ *o iBNhUfm nino oodlAoi wHn tftt RNRttfiav* < OShar paraoMl prcwcUv* aquipmant PP^ aucl) *• olothing,aafatyal|waa, ata that may bajury or axpoaura. i PwsenalilrMtdical Suivtaianet: Skstogjc*! monftoringwIncMduaL or rattad proeadurwte tvakjata •xpoauw ofanjndMduattaaMfaMnnirtationt to avakMNi tha 4l**ct> of,*xpoaufa to an SeCTIQN (X-ENV1RONMENTA1. PROTECTION INFORMATION SMMTo B*Takan If M«t*rlaJ to Rttiastd Or Spm«d: Spadfcafly rafmio tontatmnant. daanup • id control.WatMDlapoMJ MtUMd: R«ia<»torflcornmandaddlipoaaJpraaica»orapplcaMf«^^invirorvnantat Hazwdts R«far»telnfermaticmauoh8»aqi«toorv«oata^toxH9,arT^^~which ara avaJtaMt from rajulatofy or pubtehad tachntealaarviCM. SECTION X - SPECIAL PRECAUTIONS Handling.Pracauttona: Sato mcvamant of tha product may raquitatpiracaut)oft*i Safaatofa^«dtnapioQ^mayraojulMap«N^iMraB*p^eaduraa. AOOmONAL MFORMATION aaot»»«ui>JwMdL FROM USe Of TMS INKiRMATWSM OR THE PRODUCT. TOTflL P.07 [Image] Material Safety Data Sheet Ashland Chemical Co. BORAX 5 MOL TYPE F Date Prepared: 01/26/98 Date Printed: 06/21/99 MSDS No: 999.0000683-004.0041 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name: BORAX 5 MOL TYPE F General or Generic ID: SALTS Company Ashland Chemical Co. P.O. Box 2219 Columbus, OH 43216 614-790-3333 Emergency Telephone Number: 1-800-ASHLAND (1-800-274-5263) 24 hours everyday Regulatory Information Number: 1-800-325-3751 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS Number % (by weight) SODIUM TETRABORATE PENTAHYDRATE 1330-43-4 100.0 3. HAZARDS IDENTIFICATION Potential Health Effects Eye Can cause eye irritation. Symptoms include stinging, tearing, redness/ and swelling of eyes. Skin Can cause skin irritation. Symptoms may include redness and burning of skin, and other skin damage. Additional symptoms of skin contact may include: allergic skin reaction {delayed skin rash which may be followed by blistering, scaling and other skin effects) Passage of this material into the body through the skin is possible, and may add to toxic effects from breathing or swallowing. Swallowing Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. Inhalation This material is a dust or may produce dust. Symptoms of Exposure ', Signs and symptoms of exposure to this material through:breathing, swallowing, and/or passage of the material through the $kin may include: stomach or intestinal upset {nausea, vomitingj diarrhea) irritation (nose, throat, airways), central nervous system depression (dizziness/ drowsiness, weakness, fatigue, nausea, headache, unconsciousness), hair loss, shock. Target Organ Effects No data ; Developmental Information No data j Cancer Information No data Other Health Effects i No data ; Primary Route(s) of Entry Inhalation, Skin absorption. 4. FIRST AID MEASURES Eyes i If symptoms develop, immediately move individual away fr<pm exposure and into fresh air. Flush eyes gently with wator for at least 15 minutes while holding eyelids apart; seek immediate medical attention. iI Skin : Remove contaminated clothing. Wash exposed area with so^P and water. If symptoms persist, seek medical attention. Launder clothing before reuse. • Swallowing ! Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the lo|ft side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce (vomiting. If possible, do not leave individual unattended. Inhalation If symptoms develop, immediately move individual away frojm exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, {begin artificial respiration. If breathing is difficult, administer oxygen. i i Note to Physicians i Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material: skin, lufrg (for example, asthma-like conditions). ! 5. FIRE FIGHTING MEASURES Flash Point Not applicable Explosive Limit Not applicable Autoignition Temperature No data Hazardous Products of Combustion No data Fire and Explosion Hazards No special fire hazards are known to be associated with this product. Extinguishing Media regular foam, water fog, carbon dioxide, dry chemical. Fire Fighting Instructions Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipment. Refer to the personal protective equipment section of this MSDS. NFPA Rating Not determined 6. ACCIDENTAL RELEASE MEASURES Small Spill Sweep up material for disposal or recovery.i Large Spill Shovel material into containers. Thoroughly sweep area of spill to clean up any residual material. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid/ and/or solid), all hazard precautions given in the data sheet must be observed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Consult your safety representative. ! Skin Protection ; Wear resistant gloves such as: neoprene, To prevent repeated or prolonged skin contact, wear impervious clothing and boots.. Respiratory Protections If needed, use a NIOSH/MSHA jointly approved dust respiriator. (Ask your safety representative.) Engineering Controls Provide sufficient mechanical (general and/or local exhaiist) ventilation to maintain exposure below TLV(s). j Exposure Guidelines Component SODIOM TETRABORATE PENTAHYDRATE (1330-43-4) OSHA VPEL 10.000 mg/m3 - TWA 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point Not applicable Vapor Pressure No data Specific Vapor Density Not applicable Specific Gravity 1.815 @ 68.00 F Liquid Density Not applicable Percent Volatiles No data Evaporation Rate Not applicable Appearance No data State SOLID Physical Form POWDER Color WHITE; NO ODOR Odor No data PH Not applicable 10. STABILITY AND REACTIVITY Hazardous Polymerization Product will not undergo hazardous polymerization. Hazardous Decomposition No data Chemical Stability Stable. Incompatibility No data 11. TOXICOLOGICAL INFORMATION No data 12. ECOLOGICAL INFORMATION No data 13. DISPOSAL CONSIDERATION Waste Management Information Dispose of in accordance with all applicable local/ state and federal regulations. 14. TRANSPORT INFORMATION DOT information - 49 CFR 172.101 DOT Description: NON-REGULATED BY D.O.T. Container/Mode: 55 GAL DRUM/TRUCK PACKAGE NOS Component: None RQ (Reportable Quantity) - 49 CFR 172.101 Not applicable 15. REGULATORY INFORMATION US Federal Regulations i TSCA (Toxic Substances Control Act) Status j TSCA (UNITED STATES) The intentional ingredients ofj this product are listed. i CERCLA RQ - 40 CFR 302.4(a) ; None listed i SARA 302 Components - 40 CFR 355 Appendix A None ; Section 311/312 Hazard Class - 40 CFR 370.2 Immediate(X) Delayed( ) Fire{ ) Reactive( ) Release of Pressure< } SARA 313 Components - 40 CFR 372.65 None International Regulations Inventory Status Not determined State and Local Regulations California Proposition 65 None • Sudden Pennsylvania RTK Label Information BORON SODIUM OXIDE (B4NA2O7)1330-43M 16. OTHER INFORMATION ! j The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. ! Last page [image][Image] P IT BASIC CHEMICALS CO. t Corpora* Drtv* Bex 811 SKdton, CT, 06484 (203)« 24-HOUR EMERGENCY TELEPHONE CHEMTWEC 1-JOCM24-HOO SOBA ASS tSQBIUM CAHJUJW.TE. AJNHYBROW ffwiivt D«f Ma/31, VI Supersedes- Aptil !», '/Jl Hk]CO)rottnuuk WIGHT i <]« »,),, et«6onl< t. PJOMDIEftTS/SUMMAHY OF HA enf mr,<417-Tf- 011U KAIAMOUI (M)/ 100 llAZXMCXlli HXWIINOI ckg«i* nx NMUMCSO OX MPSXXIO OOHTACT MAY CXUfV fKIH IWItKTfO«, in* * w.T{g«K> rtu VZ /or cM wh*n K.tlth UJOCIXHOK MIIHC toura nu UMTtvm »rn i a Kfll- J 0 o j « t'llljht IMA Tim Ut KAUM •UUIiriCATIOM [CXJUJHIC' IUA1TM IOTDIK UUWI 0» fUUVM "ACT t VI H: 1C. PHYSICAL DATA IVIKWLTIM4 MIKt (•«rotw IH 1.1)3 400*0 (7JJ-7I t>«VUl I* «volv« CO, IX. > (I 11. t (i UKMUNCI MM I (Mr e»U .-I99-** J-<JOO| IV. FIRE ANP EXPLOSION UAZAJU3 DATA Met WTOJ4JETIOM TUUIMTVU I'C l'H)i Hot u r:u t» JKVIUW, MM MID 11UW1IOK Do«> net eeoirlbut*ntordt In • (in 0*00*5.74.. <.,. v, RjCACiivrrv DATA i IttTtJUXM TO AVOID Itetot* wUn Itrtaa taldi, «»rt«U */ v.ry M^*iklvtT« |100Q'c. VI. HEALTH HAZAKJD DAT/LfFtKST AID PROCEDURES kfCTK rttVi (kit cam U !>«/•' ttttl 4«>t S BitAIiB«r»*l (3), 4919 P . 18 tti. . •f/k* ()l IC»0 (mi) I JJ9C aq/V/JX (J|fkln Cf(««ll (rtiSUDI H«n-l«<lt*ft\( 4 hy *«p««iir« (3)KJU Irru^ii. 14 hr 4«po<ur« C) M114 l|-rl«»nt (199 M vltfc )« f«c rlnMl (J) a«4» Mt eenttiA tnyOtlU 4* 1 ^c«k4»U hwiun crrccr* or uxau N4]r ««u<« burn* »t «h« »cuth, throit, if «co*i*eK -<«rirt inmt t« th« n«n, Vftiff4t <nd 41 tn «rIUp«««*«l otnu UI«TSNO KUKUtUa Urlttti«A«t r> Mr I-**4 «» irrltittcii 4M/o? i»a«itlrUy or (h< ik ••lutl»A« U i«nt4«t witn akin 4n* •)••• My e«u»« eH4«Lt*: uiwithIMMVATID tr»«or fkln lfi;<»M. fXMT MB vietU te (r«»>i «lr t ee UfU«tl»n 4*, MI 1)11 I tn TO dlt" 4v.r.«p.iur., «r»t In th. toUivlnf •<-» 'V 070617 DOD Hazardous Materials Information System DoD 6050.5-L AS OF July 1998 FSC- 5610 NIIN: OON038360 Manufacturer's CASE- 74754 Part No. Indicator: A Part Number /Trade Name: JBBPHBLINE SXBMITE--MS8EX 10 General Information 22 s3=3E=52s:=:=:2ss:73:=::====^==:==:=s=:=s:=t==:===S3£==:==s:=:=s=s:£= =:=£—£: =:=:==£====:= Item Name: Company's Name. ONIMIN SPECIALTY MINERALS INC Company's street: ROOTS 127 Company's P. (X Box: 33 Company's City: BLCO Company's State- IL Company's country OS Company's zip Code: €2929 Company's Emerg Ph #• 618-747-2328 Company's info Ph # 618-747-2328 Distributor/Vendor # 1: Distributor/Vendor * l Cage: Distributor/Vendor # 2 Distributor/Vendor # 2 Cage Distributor/Vendor f 3: Distributor/Vendor # 3 Cage: Distributor/Vendor # 4: Distributor/Vendor t 4 Cage: Safety Data Action Code: Safety Focal Point: N Record No. For Safety Entry. 001 Tot Safety Entries This Stk#- 001 Status SMJ Date MSDS Prepared- 20MAY92 Safety Data Review Date: 31DEC92 Supply Item Manager. MSDS Preparer's Name: Preparer'a Co^any; Preparer's St Or P. O. Box: Preparer's City: Preparer's State- Preparer's Zip Code: Other MSDS Humber: MSDS Serial Number- BQXKK Specification Number: Spec Type/ Grade, Class: Hazard Characteristic Code: NK Unit Of Issue: Unit Of Issue Container Qty: Type Of Container: Met raiit Weight.- Report for NIIN- OON038360 SRC/State License Wusaber: Het Ejq>losive Height: Net Propellant Weight-Ammo: Coast Guard Ammunition Code: Ingredients/Identity Information Page l 070617 Proprietary: NO | Ingredient: HEPHELIWE SYENITE Ingredient Sequence Number 01 Percent- N/K j Ingredient Action Code: Ingredient Focal Point: N NIOSH (RTECS) Number- 1003350NE CAS Number 37244-96-5 '• OSHA PEL-. NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Other Recommended Limit. N/K \ Proprietary- NO Ingredient: <0.003% NATURALLY OCCORING CONTAMS IHCL ANTIMONY, ARSENIC, • BARIDM, CADMIUM, CHROMIUM, LEAD, MERCURY, SELENIUM, & SILVER. j Ingredient Sequence Number- 02 Percent: S/K '. Ingredient Action Code: i Ingredient Focal Point- N } NIOSH (RTBCS) Number: 9999999ZZ ; CAS Number : OSHA PEL: HOT APPLICABLE ACGIH TLV: NOT APPLICABLE : Other Recommended Limit N/K | Physical/Chemical Characteristics • Appearance And Odor- WHITE, NO ODOR. Boiling Point- N/A Melting Point: 2233F,1223C i Vapor Pressure (Mi Hg/70 P): N/A Vapor Density (Air=l).- N/A Specific Gravity. 2.61 (H*2O=1) Decomposition Temperature: N/K Evaporation Rate And Ref: MOT APPLICABLE : Solubility In Water: NEGLIGIBLE j Percent Volatiles By Volume: N/K ! Viscosity: pH: 10.1 : Radioactivity: i Form (Radioactive Matl).- '. Magnetism (Milligauss): Ccxrrosion Rate (IPY): N/K i Autoignition Tenperat\ire • Report for NIIH: OOH0383«0 j Fire and Explosion Hazard Data I = e—'=ci=-!^~ss^~=s*~SB:E:is~is*=*:'—= K~=^* —~—sst=!=:s""=^"~ ———ss=ss———as =S£sa3s~a~s=ss==5S: — _:s_=!_s Flash Point: NONFLAMMABLE ! Flash Point Method: N/P < Lower Explosive Limit- N/A '. Upper Explosive Limit: N/A , Extinguishing Media: FULLY OXIDIZED, HILL NOT BORN. USE MEDIA SUITABLE FC-R SURROUHDQK3 FIEE COHDITIONS (FP H). i Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULL : PROTECTIVE EQUIPMENT (FP N) . ', Unusual Fire And Expl Hazrds: NOUS. Page 2 070617 Reactivity Data Stability: YES Cond To Avoid (Stability) • MOKE Materials To Avoid. NONE Hazardous Decomp Products: NONE Hazardous Poly Occur: NO Conditions To Avoid (Poly) • NOT RELEVANT. Health Hazard Data LDSO-LC50 Mixture NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: NO Route Of Entry - Ingest ion: NO Health Haz Acute And Chronic: EXCESSIVE OR PRLNGD INHAL OF DUST MAY RESULT IN HARM OR INJURY TO THE RESPIR SYST. CONTAINS MERCURY AND LEAD WHICH APPEAR ON THE NAVY LISTING OF OCC CHEM REPRO HAZ. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROF CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING fc EXPOSURE INFORMATION (FP N) . Carcinogenic!ty - NTP- NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity; NOT RELEVANT. Signs/Symptoms Of Overexp. SYMPTOMS OF EXCESSIVE EXPOSURE INCLUDE SHORTNESS OF BREATH AND REDUCED PULMONARY FUNCTION. THIS INERT MATERIAL GIVES NO POTENTIAL ACUTE TOXIC HAZARD. Med Cond Aggravated By Exp; INDIVIDUALS WITH RESPIRATORY DISEASE, INCLUDING, BUT NOT LIMITED TO, ASTHMA AND BRONCHITIS, OR SUBJECT TO EYE IRRITATION SHOULD BE PRECLUDED FROM EXPOSURE. Emergency/First Aid Proc: EYES: FLUSH WITH HATER FOR AT LEAST 15 MINUTES. CTHALSTIOH; REMOVE TO FRESH AIR. GIVE OXYGEN WITH ARTIFICIAL RESPIRATION AS NEEDED SEEK MEDICAL ATTENTION FOR TREATMENT, OBSERVATION AND SUPPORT AS NEEDED. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER (FP N) . INOESTION- CALL MD IMMEDIATELY {FP N). Precautions for Safe Handling and Use Steps If Matl Released/Spill: IF UNCONTAMINATED, COLLECT USING DUSTLESS MKTiKU) (WATER OR VACUUM) . IF CONTAMINATED, USE APPROPRIATE METHOD IN LIGHT Report for NUN: OON038360 OF NATURE OF CONTAMINATION. USE APPROPRIATE CONTAINER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER,. Waste Disposal Method: IF UNCONTAMINATED, DISPOSE AS AN INERT, NON- METALLIC MINERAL. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, & LOCAL REGULATIONS (FP N) . IF CONTAMINATED USE APPROPRIATE METHOD IN LIGHT OF CONTAMINATION IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL LAWS. Precautions-Handling/Storing: NORMAL PRECAUTIONS AGAINST BAG BREAKAGE OR SPILLS OF BULK MATERIAL. AVOID CREATION OF RESPIRABLE DUST. Other Precautions: USE ADEQ VENT & DUST COLLECTION.DO NOT PERMIT DUST TO ACCUMULATE IN WORK AREA.MAINTAIS & USE PROPER & CLEAN NIOSH/MSHA APPRVD RESP EQUIP.CLEAN CLTHG WHICH HAS BECOME DUSTY.WARN & TRAIN YOUR EMPLOYEES & WARN YOUR CUSTOMERS (IN EVENT (SUPDAT) Control Measures Respiratory Protection: USE NIOSH/MSHA APPRVD CONVENTIONAL PARTICULATE RESP PROT BASED ON CONSIDERATIONS OF AIRBORNE CONG & DURATION OF EXPOS.SEE MOST RECENT STDS OF ANSI (Z.88.2), OSHA (29 CFR PART 1910.134), MSHA (30 Page 3 070€17 CPR PART 56} AND NIOSH (KIOSH POCKET (S0PDAT) Ventilation: TO MEET PEL REQUIREMENTS. Protective Gloves- IMPERVIOUS GLOVES (FP N) . Bye Protection- CHEMICAL WORKERS GOGGLES (FP N). Other Protective Equipment: AS APPROPRIATE IK LIGHT OF SPECIFIC APPLICATION. Work Hygienic Practices- AVOID CREATING AND BREATHING DUST CLEAN CLOTHING WHICH HAS BECOME DUSTY. Suppl. Safety & Health Data; OTHER PRECAUTIONS: OF RESALE) IN ACCORDANCE WITH ALL APPLICABLE FEDERAL AMD STATE "RIGHT TO KNOW" LAWS AND HBGULATIpNS. RESPIRATORY PROTECTION: GUIDE TO CHEMICAL HAZARDS) — ==ss:s5:s£=sssKS55=:srsi^=:=f= —=3!SsssT—ST5s=:^si;r:3i3;5^S! = 335Siss = :s5—zrssirc—3SSK—— sssssj-aBjsss —tf ±s:a;a= •Transportation Data_^__ _ff__f _^ ^ ___. _.. ~_— „__ ,_ i Transportation Action Code. ! Transportation Focal Point: : Trans Data Review Date: POT PSN Code: DOT Symbol: : DOT Proper Shipping Hame: ! DOT Class DOT ID Number: ; DOT Pack Group: DOT Label: ; DOT/DoD Exemption Number: | IMO PSN Code i IMO Proper Shipping Name: i UK) Regulations Page Number: IMO ON Number: j IMO ON Class- IMO Subsidiary Risk Label: : IATA PSN Code: IATA ON ID Number: : IATA Proper Shipping Name: ' IATA UN Class- I ! Report for NIIN: OON038360 I IATA Subsidiary Risk Class- IATA Label: ! AFT PSR Code: : AFI Symbols.- i AFX Prop Shipping Name. : AFI Class: j AFI ID Number: AFI Pack Group: AFI Label: AFI Special Prov- : AFI Basic Pac Ref: MMAC Code- \ N.O.S Shipping Name: Additional Trans Data: j =SSSS=SS: = = 3?±S=SS==aBSa5=tfS9BS^±«SSS=at^StoS£a=BSSaS = SSSSS3ta3^ = Sa:S=Bai=l=73K=3BasSSB=S3aSS=4~ = Disposal Data i Disposal Data Action Code- ' Disposal Data Focal Point- Disposal Data Review Date: : Rec # For This Disp Entry: : Tot Disp Entries Per NSN: ; Landfill Ban Item- ', Page 4 070617 Disposal Supplemental Data: 1st EPA Haz Wst Code New: 1st EPA Haz Wst Kama New 1st EPA Haz Wst Char New: 1st EPA Acute Hazard New- 2nd EPA Haz wst Code New: 2nd EPA Haz Wet Name New: 2nd SPA Haz Wat C*v"" New: 2nd EPA Acute Hazard New- 3rd EPA Haz Wst Code New 3rd EPA Haz Wst Name New 3rd EPA Haz Wst Char New: 3rd EPA Acute Hazard New- Label Data Label Required: YES Technical Review Date- Label Date.- MFR Label Number: Label status: € Common Name: NEPHBLINE SYENITE--MINEX 10 Chronic Hazard- N/P Signal Word- Acute Health Hazard-None: Acute Health Hazard-Slight: Acute Health Hazard-Moderate: Acute Health Hazard-Severe- Contact Hazard-Hone: Contact Hazard-Slight: Report for NUN- OON038360 Contact Hazard-Moderate- Contact Hazard-Severe: Fire Hazard-None: Fire Hazard-Slight: Fire Hazard-Moderate: Fire Hazard-Severe: Reactivity Hazard-None: Reactivity Hazard-Slight- Reactivity Hazard-Moderate -. Reactivity Hazard-Severe: Special Hazard Precautions: EXCESSIVE OR PRLWGD ISHftL OF DOST MAY RESULT IS HARM OR INJURY TO THE RESPIR SYST. COHTAINS MSRCORY AND LEAD WHICH APPEAR ON THE NAVY LISTING OF OCC CHEM REPRO HAZ. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROP CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLISG & EXPOSURE INFORMATION (FP N). SYMPTOMS OF EXCESSIVE EXPOSURE INCLUDE SHORTNESS OF BREATH AND REDUCED PULMONARY FUNCTION. THIS INERT MATERIAL GIVES NO POTENTIAL ACUTE TOXIC HAZARD. Protect Eyei Protect Skin: Protect Respiratory: Label Name: UH2GN SPECIALTY MINERALS INC Label Street: ROUTE 127 Label P.O. Box- 33 Label City: ELCO Label State: XL Label Zip Code: £2929 Label Country- US Label Emergency Number: 618-747-232B Page 5 I huredayT March 22 2001 MSDS - SODIUM NITRATE, CRYSTAL 1 - PRODUCT IDENTIFICATION PageI PRODUCT NAME FORMULA FORMULA WT CAS NO SODIUM NITRATE, CRYSTAL NANO3 84 99 07631-99-4 NIOSH/RTECS NO WC5600000 COMMON SYNONYMS SODIUM(I) NITRATE, NITRIC ACID, SODIUM SALT, SODA NITER, CHILE SALTPETER PRODUCT CODES 3771,3770,4501 EFFECTIVE 01/22/87 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 1 SLIGHT FLAMMABILITY - 0 NONE REACTIVITY - 3 SEVERE (OXIDIZER) CONTACT - 1 SLIGHT HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD, 4 = EXTREME HAZARD) LABORATORY PROTECTIVE EQUIPMENT SAFETY GLASSES, LAB COAT PRECAUTIONARY LABEL STATEMENTS DANGER CAUSES IRRITATION HARMFUL IF SWALLOWED OR INHALED STRONG OXIDIZER - CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS DO NOT STORE NEAR COMBUSTIBLE MATERIALS AVOID CONTACT WITH EYES, SKIN, CLOTHING KEEP IN TIGHTLY CLOSED CONTAINER WASH THOROUGHLY AFTER HANDLING IN CASE DF FIRE, SOAK WITH WATER IN CASE OF SPILL, SWEEP UP AND REMOVE FLUSH SPILL AREA WITH WATER SAF-T-DATA(TM) STORAGE COLOR CODE YELLOW (REACTIVE) 2 - HAZARDOUS COMPONENTS COMPONENT 3ODIUM NITRATE 3 - PHYSICAL DATA 3OILING POINT N/A ISDS £or SODIUM NITRATE, CRYSTAL ELTING POINT 306 C ( 583 F) .PECIFIC GRAVITY 2 26 90-100 VAPOR PRESSURE (MM Page VAPOR DENSITY (AIR= EVAPORATION RATE 7631-99-4 HG) N/A 2 1) 2 90 N/A (H20=l) ,OLUBILITY(H20) iPPEARANCE & ODOR (BUTYL ACETATE=1) APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME 0 COLORLESS CRYSTALS OR WHITE POWDER WITH NO ODOR NFPA 704M RATING LOWER - N/A % 0-0-0 OXY'LASH POINT (CLOSED CUP N/A 'LAMMABLE LIMITS UPPER - N/A % TRE EXTINGUISHING MEDIA USE WATER SPRAY PECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL NUSUAL FIRE & EXPLOSION HAZARDS STRONG OXIDIZER CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE fileJ//mac%20%A5%20don/D8Sktop%20Folder/MSOS/sodiununitrat9lxt lureday, March 22, 2001 Page 2 •CAN REACT VIOLENTLY WITH SHOCK, FRICTION OR HEAT TOXIC GASES PRODUCED NITROGEN OXIDES I5 - HEALTH HAZARD DATA I :CINOGENICITY DTP NO IARC NO Z LIST NO OSHA REG NO 'ECTS OF OVEREXPOSURE INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT INTACT WITH SKIN OR EYES MAY CAUSE IRRITATION 'ROLONGED EXPOSURE MAY CAUSE DERMATITIS .NGESTION MAY CAUSE GASTROINTESTINAL IRRITATION iTION AND INGESTION MAY CAUSE CYANOSIS THE EFFECTS OF EXPOSURE MAY INCLUDE HEADACHE, NAUSEA, VOMITING, DIZZINESS, WEAKNESS, RAPID INEFFECTIVE IREATHING, LOW BLOOD PRESSURE, LOSS OF CONSCIOUSNESS, OR CONVULSIONS 3ET ORGANS IDENTIFIED ilCAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE ONE IDENTIFIED SS OF ENTRY INHALATION, INGESTION, SKIN CONTACT, EYE CONTACTtENCY AND FIRST AID PROCEDURES L A PHYSICIAN SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING IF INHALED, REMOVE TO FRESH AIR IF NOT BREATHING, GIVE ARTIFICIAL SPIRATION IF BREATHING IS DIFFICULT, GIVE OXYGEN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT 15 MINUTES FLUSH SKIN WITH WATER I - REACTIVITY DATA TABILITY STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR ETIONS TO AVOID SHOCK, FRICTION, HEAT PKPATIBLES CYANIDES, COMBUSTIBLE MATERIALS, STRONG REDUCING AGENTS, ALUMINUMr'OSITION PRODUCTS OXIDES OF NITROGEN 7 - SPILL AND DISPOSAL PROCEDURES Ms TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE mKR SUITABLE PROTECTIVE CLOTHING KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC ) AWAY FROM SPILLED MATERIAL WITH CLEAN SHOVEL, CAREFULLY PLACE fERIAL INTO CLEAN, DRY CONTAINER AND COVER, REMOVE FROM AREA FLUSH LL AREA WITH WATER SAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCALrRONMENTAL REGULATIONS Z I .ZARDOUS WASTE NUMBER D001 (IGNITABLE WASTE) - PROTECTIVE EQUIPMENT NTILATION USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE I I RATORY PROTECTION NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST IF AIRBORNE CONCENTRATION IS HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK 1KIN PROTECTION SAFETY GLASSES WITH SIDESHIELDS, BUTYL RUBBER GLOVES ARE RECOMMENDED 9 - STORAGE AND HANDLING PRECAUTIONS I'-DATA(TM) STORAGE COLOR CODE YELLOW (REACTIVE) 3CIAL PRECAUTIONS JK? CONTAINER TIGHTLY CLOSED STORE SEPARATELY AND AWAY FROM FLAMMABLE file ///mac%20%A5%20don/Desktop%20Folder/MSDS/sodium_nltrate txt lursday, Mart* 22. 2001 AND COMBUSTIBLE MATERIALS 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION DOMESTIC (DOT) PROPER SHIPPING NAME HAZARD CLASS UN/NA LABELS INTERNATIONAL (I M O PROPER SHIPPING NAME HAZARD CLASS UN/NA LABELS SODIUM NITRATE OXIDIZER UN1498 OXIDIZER SODIUM NITRATE 5 1 UN1498 OXIDIZING AGENT file ///mac%20%A5%20dorVDesMop%20Folder/MSDS/sodium_nltrate txt lay March 22, 2001 Page 1 - ZINC OXIDE 1 - PRODUCT IDENTIFICATION ZINC OXIDE ZNO 81 37 NO 01314-13-2 ^IOSH/RTECS NO ZH4810000 SYNONYMS CALAMINE, ZINC WHITE, FLOWERS OF ZINC 5DUCT CODES 4358,4360,4361,5171,5070 IFFECTIVE 09/05/86 ISION #02 PRECAUTIONARY LABELLING SAF-T-DATA(TM) SYSTEM HEALTH - 2 MODERATE FLAMMABILITY - 0 NONE REACTIVITY - 0 NONE CONTACT - 0 NONE RATINGS ARE 0 TO 4 (0 = NO HAZARD, 4 - EXTREME HAZARD) MORATORY PROTECTIVE EQUIPMENT ^ GLASSES, LAB COAT riONARY LABEL STATEMENTS 1°•Mm HARMING HARMFUL IF INHALED BREATHING DUST KEEP IN TIGHTLY CLOSED CONTAINER USE WITH ADEQUATE 'ILATION IF-T-PATA(TM) STORAGE COLOR CODE ORANGE (GENERAL STORAGE) I- HAZARDOUS COMPONENTS 1 COMPONENT % CAS NO OXIDE 90-100 1314-13-2 1 I - PHYSICAL DATA OILING POINT N/A VAPOR PRESSURE (MM HG) N/A §ING POINT 1975 C ( 3587 F) VAPOR DENSITY(AIR=1) N/A IFIC GRAVITY 5 67 EVAPORATION RATE N/A (H20=l) (BUTYL ACETATE=1) •BILIT SARANC I IILITY(H20) NEGLIGIBLE (LESS THAN 01%) % VOLATILES BY VOLUME 0 IE & ODOR WHITE OR YELLOWISH-WHITE, ODORLESS POWDER - FIRE AND EXPLOSION HAZARD DATA JVSH POINT (CLOSED CUP N/A LIMITS UPPER - N/A % LOWER - N/A % RE EXTINGUISHING MEDIA 'SE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE f - HEALTH HAZARD DATA KHOLD LIMIT VALUE (TLV/TWA) 5 MG/M3 ( PPM) -TEEM EXPOSURE LIMIT (STEL) 10 MG/M3 ( PPM) f SSIBLE EXPOSURE LIMIT (PEL) 5 MG/M3 ( PPM) ITY LD50 (ORAL-RAT)(MG/KG) - 630 JICINOGENICITY NTP NO IARC NO Z LIST NO OSHA REG NO •CTS OF OVEREXPOSURE • file ///mac%20%A5%20don/Desktop%20Folder/MSDS/zlnc_oxlde txt •luraday Man* 22. 2001 INHALATION OF VAPORS MAY CAUSE SEVERE IRRITATION OF THE RESPIRATORY SYSTEM OVEREXPOSURE TO VAPORS MAY CAUSE IRRITATION OF MUCOUS MEMBRANES, DRYNESS OF MOUTH AND THROAT, HEADACHE, NAUSEA AND DIZZINESS CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION TARGET ORGANS RESPIRATORY SYSTEM MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INHALATION EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN IF INHALED, REMOVE TO FRESH AIR IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION IF BREATHING IS DIFFICULT, GIVE OXYGEN IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES FLUSH SKIN WITH WATER Page i 6 - REACTIVITY DATA STABILITY STABLE CONDITIONS TO AVOID INCOMPATIBLES HAZARDOUS POLYMERIZATION WILL NOT OCCUR NONE DOCUMENTED MAGNESIUM, STRONG ACIDS 7 - SPILL AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER, REMOVE FROM AREA FLUSH SPILL AREA WITH WATER DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS 8 - PROTECTIVE EQUIPMENT 7ENTILATION IESPIRATORY PROTECTION !YE/SKIN PROTECTION USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV AT CONCENTRATIONS UP TO 75 PPM, A HIGH-EFFICIENCY PARTICULATE RESPIRATOR IS RECOMMENDED ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE RECOMMENDED 9 - STORAGE AND HANDLING PRECAUTIONS lAF-T-DATA(TM) STORAGE COLOR CODE ORANGE (GENERAL STORAGE) iPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION OMESTIC (DOT) ROPER SHIPPING NAME AZARD CLASS ABELS EPORTABLE QUANTITY NTERNATIONAL (I M 0 ) ROPER SHIPPING NAME ZINC OXIDE ORM-E NONE 1000 LBS CHEMICALS, N 0 S (NON-REGULATED) file ///mac%20%A5%20don/De3ktop%20Folder/MSDS/zlnc_oxide M March 22, 2001 Page 1 [Q'Max Header] [Image] MATERIAL SAFETY DATA SHEET ttion I IDENTIFICATION OF PRODUCT duct Name •oduct Use ,cal Family IS CLASSIFICATION _ PLACE HAZARD TDG CLASSIFICATION LCKAGE GROUP'ACK I [Image]INHALATION [Image] INGESTION QUICKLIME (Pebble, Crushed, Pulverized) Various Calcium Oxide Cas No 1305-78-8 Eye and Skin Irritant Not Applicable Not Applicable Not Applicable tion II HAZARDOUS INGREDIENTS gredient Percent CAS Number LD(50) LC(50) Calcium Oxide 95 1 1305-78-8 N/AV N/AV 8ion III TOXICOLOGICAL PROPERTIES te of [Image] SKIN [Image]EYE CONTACT ry CONTACT Can penetrate the skin slowly, producing soft, necrotic, deeply penetrating areas on contact The , extent of damage depends on duration of contactIA chronic dermatitis may follow repeated contact CONTACT Direct contact with the solid or aqueous solutions may cause conjunctival edema and corneal destruction, can lead to and may cause blindness Prolonged contact may cause conjunctivitis •ELATION Low concentrations may cause sore throat, coughing, H choking, dyspnea, and variable symptoms of headache, B dizziness, and weakness Intense exposures may result in tightness in the chest and delayed pulmonary edema The solubility of substance allows further penetration f that may continue for several days Bronchial irritation with chronic cough are common STION Corrosive If ingested, consult a Physician immediatelyIsure Limits 5 mg/m? Lime tancy of Product Respiratory System Nasal Passages, Cuts or Scrapes i Eyes, Skin, Exposed :ion IV FIRST AID MEASURES KIN CONTACT ICONTACT ATION -ption V PHYSICAL DATA E AND ODOUR IFIC GRAVITY POINT (,o SLTING POINT (,C) AJBILITY IN WATER 1 0% VOLATILE BY VOLUME (RATION RATE ^POUR PRESSURES (mm Hg) MR DENSITY (Air=l) on VI FIRE AND EXPLOSION DATA POINT GNITION TEMPERATURE 4AMMABLE LIMITS IGUISHING MEDIA FIRE FIGHTING PROCEDURES JAL FIRE AND EXPLOSION IOCEDURES ton VII REACTIVITY DATA ilblTY PATIBILITY (conditions to Flush affected eye 'immediately" with large amounts of water Do not rub eyes if irritated by Lime dust Following eye wash with water, use Boric Acid solution, then get medical attention Wash thoroughly with soap and warm water, then vinegar to remove all Lime Apply burn ointment Keep bandaged during healing to prevent infection Remove to fresh air If not breathing give artificial respiration and call a doctor Give three to four glasses of milk or water Do not induce vomiting Get immediate medical attention Greyish white solid, various sizes - Odourless (H20=l) 32-34 2850 C 5162 F Not Applicable Insoluble 12 - Strong Alkaline Not Applicable butylacetate=l) NM/AP 20C (68F) Not Available None Applicable Not Applicable Not Applicable Non flammable, use extinguishing media which is appropriate for surrounding fire None None Stable [Image] Unstable [Image] OUS DECOMPOSITION PRODUCTS OS POLYMERIZATION ction VIII PREVENTIVE MEASURE ECIAL PROTECTION INFORMATION iKRATORY PROTECTION Boric Oxide, Acids, Fluorine, water, steam and many organic materials Calcium. Oxide will swell and generate heat when moistened and could burst containers Fluorine will attack Calcium Oxide, evolving much heat and some light When exposed to air, it will react with moisture and Carbon Dioxide in the air None Will not occur [Image] May Occur [Image] Approved filter mask should be worn if excessive dust is created flle.///mac%20%A5%20dorVDesktop%20Folder/MSDS/llme tursday, March 22 2001 Page VENTILATION Local exhaust as necessary to maintain airborne levels within prescribed limits PROTECTIVE GLOVES Gauntlet type work gloves to prevent material getting inside I EYE PROTECTION Tight fitting goggles should be worn I CLOTHING Should be worn to prevent Lime from contacting skin j OTHER PROTECTIVE EQUIPMENT (specify) Long sleeved shirt with collar buttoned, trousers with legs down over boot tops : PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING : Avoid creating dust Keep containers closed to avoid breathing dust and eye contact Keep product dry Store in coo, "DRY", well-ventilated area out of direct contact with weather i STEPS TO BE TAKEN IN CASE THE MATERIAL IS SPILLED OR RELEASED : Ventilate area of spill Keep spilled material away from Organic Material and Water Carefully pick up solid material and collect in metal containers with covers for disposal rfASTE DISPOSAL METHOD Trace amounts of residue can be flushed into the drain, using plenty of water Large amounts nay require neutralization by Acid Check local regulations Alternately, waste lime can be : jsed for neutralizing plant acid wastes Section IX PREPARATION ', The information contained herein is given in good faith, but no warranty, expressed or ; Implied, is made DATE ISSUED July 1, 1995 ! 3Y Calgary Division Office ', DATE UPDATED October 1, 1999 [Image] Return to MSDS Menu [Image] Return to Main Menu : [Image] site design and construction by Cobra Internet Design 2000 : I flle.///mac%20%A5%20don/Desktop%20Folder/MSDS/l!me [The Hummel Croton Web Page] MATERIAL SAFETY DATA SHEET [The Hummel Croton Homepage * msds] COPPER CARBONATE (BASIC) HUMMEL CROTON INC. 10 HARMICH ROAD BUSINESS HRS.: 908-754-1800 SOUTH PLAINFIELD, NJ O7080 EMERGENCY PHONE NUMBERS BUSINESS HRS.: 908-754-1800 CHEMTREC: 800-424-9300 I. PRODUCT IDENTIFICATION: PRODUCT NAME : Copper Carbonate CHEMICAL FAMILY : Copper Compound CHEMICAL NAME : Cupric Carbonate Basic SYNONYMS : Copper Carbonate Hydroxide/ Cupric Subcarbonate, Bremen Blue, Bremen Green CAS NUMBER : CAS #: 12069-69-1 FORMULA : CH2Cu205 II. HAZARDOUS INGREDIENTS: INGREDIENT NAME Copper Carbonate CAS #: 12069-69-1 EXPOSURE LIMITS OSHA : 1 mg/m3 * ACGIH: Img/m3 * * as copper CONCENTRATION (%) Essentially 100 % III. PHYSICAL PROPERTIES: j. PHYSICAL FORM : Amorphous Powder COLOR : Green to Blue ODOR : Odorless MOLECULAR WEIGHT : 221.11 pH , : Neutral BOILING POINT : Not Applicable MELTING/FREEZING POINT : Decomposes above 200oC VISCOSITY : Not Applicable SOLUBILITY IN WATER : Insoluble SPECIFIC GRAVITY : 4.00 BULK DENSITY : Not Established VAPOR PRESSURE : Not Applicable VAPOR DENSITY : Not Applicable (Mr = 1) j_ TV. FIBE AND EXPLOSION DATA: , FLASH POINT : , Not Applicable. ! AUTO-IGNITION TEMPERATURE : Not Established ! EXTINGUISHING MEDIA : Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. UNUSUAL FIRE / EXPLOSION HAZARDS: Emits toxic fumes under fire conditions. V.HUMAN HEALTH DATA: ROUTE (S) OF ENTRY '. Eye Contact; Skin Contact; Inhalation; Ingestion HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE: ACUTE INHALATION : Inhalation may irritate the respiratory tract. Symptoms may include coughing, shortness of breath, sore throat and runny nose. If sufficient amounts are inhaled and absorbed, symptoms may resemble those in acute ingestion. ACUTE SKIN CONTACT : Skin contact may cause irritation with symptoms of redness/ swelling, itching and pain. ACUTE EYE CONTACT : Eye contact may cause irritation with symptoms of redness, swelling, itching, tearing and pain. ACUTE INGESTION : Ingestion may cause gastroenteritis (inflammation of the lining membrane of the stomach and intestines) with abdominal pain, nausea, vomiting and diarrhea. Systemic effects may follow and may include ringing of the ears, dizziness, elevated blood pressure, blurred vision and tremors. CHRONIC EFFECTS OF EXPOSURE...: CARCINOGESnCITY : This product is not listed by NTP, IARC or regulated as a carcinogen by OSHA. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE..: Persons with preexisting eye or skin conditions or impaired pulmonary function may be more susceptible to the effects of this product. VI. EMERGENCY AND FIRST AID PROCEDURES: FIRST AID FOR EYES : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. FIRST AID FOR SKIN : In case of contact, flush skin with water. Wash clothing before reuse. Call a physician if irritation occurs. FIRST AID FOR INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration., if breathing is difficult, give oxygen. Call a physician. FIRST AID FOR INGESTION.: If swallowed, call a physician immediately. VII. EMPLOYEE PROTECTION RECOMMENDATIONS: EYE PROTECTION REQUIREMENTS : OSafety glasses or goggles. • SKIN PROTECTION REQUIREMENTS : PVC gloves with impervious boots, apron or • coveralls. Employees should wash their hands and face before eating, drinking or using tobacco products. RESPIRATOR REQUIREMENTS : Work ambient concentrations should be ; monitored and if the recommended exposure , limit is exceeded, a NIOSH/MSHA approved -, dust respirator must be worn. | VENTILATION REQUIREMENTS : j Use local ventilation if dusting is a problem, to maintain air levels below the recommended : exposure limit. ADDITIONAL PROTECTIVE MEASURES : ; Emergency showers and eye wash stations should : be available. Educate and train employees in ! the safe use and handling of hazardous i chemicals. ; VIII. REACTIVITY DATA: STABILITY : Stable under ordinary conditions of use and storage. HAZARDOUS POLYMERIZATION...: Will not occur. INCOMPATIBILITIES : Strong Acids INSTABILITY CONDITIONS : Excessive temperatures (see INCOMPATIBILITIES). DECOMPOSITION TEMPERATURE..: above 200oC DECOMPOSITION PRODUCTS : Carbon Monoxide, Carbon Dioxide and Oxides of copper IX. SPILL AND LEAK PROCEDURES: SPILL OR LEAK PROCEDURES : Utilize recommended protective clothing and equipment- Clean spills in a manner that does not disperse dust into the air. Spill area can be washed with water. Collect wash water for approved disposal. Keep from entering water or ground water. WASTE DISPOSAL METHOD : Waste disposal should be in accordance with existing federal/ state and local environmental regulations. X. SPECIAL PRECAUTIONS & STORAGE DATA: STORAGE TEMPERATURE(MIN/MAX): Ambient/Arablent. SHELF LIFE : Unlimited in tightly closed container. SPECIAL SENSITIVITY ; None BUNDLING/STORAGE PRECAUTIONS: Avoid breathing dust. Avoid getting in eyes or on skin. Wash thoroughly after handling. Store in a dry place away from direct sunlight, heat and incompatible materials (see Section VIII). Reseal containers immediately after use. Store away from food and beverages. XI. SHIPPING INFORMATION: Contact Hummel Croton for current shipping Information XII. TOXICITY DATA: ACUTE EFFECTS: Harmful if swallowed, inhaled, or absorbed through skin. Causes severe eye irritation, causes skin irritation. Material is irritating to mucous membranes and upper respiratory tract. Exposure can cause: coughing, chest pains, difficulty in breathing. Gastrointestinal disturbances nausea/ vomiting, diarrhea ADDITIONS!. INFORMATION: Symptoms of systemic copper poisoning may include: capillary damage, headache, cold sweat, weak pulse, kidney and liver damage, central nervous system excitation followed by depression, jaundice, convulsions, paralysis and coma. Death may occur from shock or renal failure. RTECS *: GL6910000 COPPER(II) CARBONATE HYDROXIDE (2:1:2) TOXICITY DATA ORL-RAT LD50:1350 KG/KG SKEZAP 26,605,85 ORL-RBT LD50:159 MG/KG GDCHAZ 6,128,73 ORL-BRD LD50:900 MG/KG PCOC** -,258,66 TARGET ORGAN DATA Behavioral (somnolence), behavioral (coma), gastrointestinal (hypermotility, diarrhea), blood (normocytic anemia), nutritional and gross metabolic {weight loss or decreased weight gain) Only selected registry of toxic effects of chemical substances (RTECS) data is presented here. See actual entry in RTECS for complete information. XIII. REGULATORY INFORMATION: OSHA STATUS : This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA STATUS On TSCA Inventory CALIFORNIA PROPOSITION 65 : To the best of our knowledge, this product contains no levels of listed substances, which the state of California has found to cause cancer, birth defects or other reproductive effects. RCRA STATUS * : If discarded in its purchased form, this product would not be hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40 CFR 261.20-24) SARA SECTION 313 : This product is subject to reporting requirements EUROPEAN INFORMATION Toxic R 23/24/25 Toxic By Inhalation, In Contact With Skin And If Swallowed. R 36/37/38 Irritating To Eyes, Respiratory System And Skin. R 41 Risk Of Serious Damage To Eyes. S 45 In Case Of Accident Or If You Feel Unwell, Seek Medical Advice Immediately (Show The Label Where Possible). S 26 In Case Of Contact With Eyes, Rinse Immediately With Plenty Of Water And Seek Medical Advice. S 36/37/39 Wear Suitable Protective Clothing, Gloves And Eye/Face Protection. XIV. ECOLOGICAL INFORMATION: Data not Available at the present time. XV. APPROVALS; REASON FOR ISSUE. Update to new format. PREPARED BY '. Mark Dugan APPROVED BY : Mark Dugan APPROVAL DATE : 05/17/96 fbul] WARRANTY ftoc] USE "BROWSER" OR SECONDARY MOUSE KEY TO RETURN TO PREVIOUS ENTRY PANEL ! RETURN TO BEGINNING OF WEB PAGE [email] : hum chem@aol.com femail3 : hmnroelgearthlink.net wisclay, ftarch 22 2001 /Page 1 SDS - SODIUM SULFATE 1 - PRODUCT IDENTIFICATION §DVCT NAME MULA MULA WT NIOSH/RTECS NO IODUCT CODES§' EFFECTIVE 05/02/86 REVISION #01 ER SAF-T-DATA(TM) SYSTEM SODIUM SULFATE NA2S04 142 04 7757-82-6 WE1650000 3375,3887,3902,3891,3898,5059 PRECAUTIONARY LABELLING HEALTH - 0 NONE FLAMMABILITY - 0 NONE REACTIVITY - 0 NONE CONTACT - 1 SLIGHT RATINGS ARE 0 TO 4 (0 = NO HAZARD, 4 = EXTREME HAZARD) iRATORY PROTECTIVE EQUIPMENT 'ETY GLASSES, LAB COAT OTIONARY LABEL STATEMENTS CAUTION MAY BE HARMFUL IF SWALLOWED MAY CAUSE IRRITATION ING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING WASH THOROUGHLY AFTER DLING WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER B-T-DATA(TM) STORAGE COLOR CODE ORANGE (GENERAL STORAGE) "2 - HAZARDOUS COMPONENTS I I COMPONENT NOT APPLICABLE CAS NO - PHYSICAL DATA ~ILING POINT HTNG POINT PECIFIC GRAVITY 2 68 j (H20=l) N/A 884 C ( 1623 F) VAPOR PRESSURE (MM HG) N/A VAPOR DENSITY (AIR=1) N/A EVAPORATION RATE N/A (BUTYL ACETATE=1) •jBILITY (H20) APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME 0 'PEARANCE & ODOR ODORLESS, WHITE POWDER OR CRYSTALS I - FIRE AND EXPLOSION HAZARD DATA JH POINT (CLOSED CUP N/A iLE LIMITS UPPER - N/A %LOWER - N/A % EXTINGUISHING MEDIA EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE FIRE-FIGHTING PROCEDURES IREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED 'JREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE GASES PRODUCED DIOXIDE - HEALTH HAZARD DATA XICITY LD50 (ORAL-MOUSE) (MG/KG) B:NOGENICITY NTP NO IARC NO - 5989 Z LIST NO OSHA REG NO file /Hmac%20%A5%20don/Oe3ktop%20Foldei/MSDS/sodlum_sulfat6 txt hursdaj-, March 22, 2001 Page EFFECTS OF OVEREXPOSURE DUST MAY BE IRRITATING TO EYES, NOSE, THROAT, OR LUNGS CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION TARGET ORGANS NONE IDENTIFIED MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY NONE INDICATED EMERGENCY AND FIRST AID PROCEDURES INGESTION IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE LARGE AMOUNTS OF WATER GET MEDICAL ATTENTION INHALATION IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED PERSON TO FRESH AIR GET MEDICAL ATTENTION EYE CONTACT IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES GET MEDICAL ATTENTION SKIN CONTACT IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES I 6 - REACTIVITY DATA STABILITY STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOID NONE DOCUMENTED INCOMPATIBLES ALUMINUM, MAGNESIUM, MINERAL ACIDS, STRONG ACIDS, STRONG BASES DECOMPOSITION PRODUCTS OXIDES OF SULFUR 7 - SPILL AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SUITABLE PROTECTIVE CLOTHING CAREFULLY SWEEP UP AND REMOVE DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS 8 - PROTECTIVE EQUIPMENT fENTILATION USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE ^SPIRATORY PROTECTION NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST IF AIRBORNE CONCENTRATION IS HIGH, USE AN APPROPRIATE RESPIRATOR OR DUST MASK IYE/SKIN PROTECTION SAFETY GLASSES WITH SIDESHIELDS, PROPER GLOVES ARE RECOMMENDED 9 - STORAGE AND HANDLING PRECAUTIONS AF-T-DATA(TM) STORAGE COLOR CODE ORANGE (GENERAL STORAGE) PECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION OMESTIC (DOT) ROPER SHIPPING NAME CHEMICALS, N O S (NON-REGULATED) MTBRNATIONAL (I M O ROPER SHIPPING NAME CHEMICALS, N 0 S (NON-REGULATED) file W/mac%20%A5%20don/DeskIop%20Folder/MSDS/9odium_sulla(e bet azardous MatenaL 1 SAN DIEGO REGIONAL HAZARDOUS MATERIALS QUESTIONNAIRE Management Division civirr SF its ting Business Name Contact Person Telephone Mailing Address City State Zip Plan File* TfLtrvt ST.^2 60 8 Site Address City State Zip Plan File* PART I FIRE DEPARTMENT • HAZARDOUS MATERIALS MANAGEMENT DIVISION OCCUPANCY CLASSIFICATION indicate by circling the item, whether your business will use, process, or store any of the following hazardous materials circled, applicant must contact the Fire Protection Agency with jurisdiction pnor to plan submitta!. If any or the items are 1 Explosive or Blasting Agents 4 Flammable Solids 7 Pyrophorics 10 Cryogenics 13 2 Compressed Gases 5 Organic Peroxides S Unstable Reactives 11 . Highly Toxic or Toxic Materials 14 3 Flammable or Combustible Liquids 6 Oxidizers 9 Water Reactives 12 Radioactive* PART II COUNTY OF SAN DIEGO HEALTH DEPARTMENT - HAZARDOUS MATERIALS MANAGEMENT DIVISION CONTINGENCY PLAN REVIEW. If the answer to any of the questions is yes, applicant must contact the County of San Diego Hazardous Materials Management Division, 1 255 Imperial Avenue, 3rd Roor, San Diego, CA 92186-5261 Telephone (6191 338-2222 pnor to the issuance of a building permit FEES MAY BE REQUIRED Yes No 1 7T] Is your business listed on the reverse side of this form? . ~, ~~ ' •_ • , 2 I I r^i Will your business dispose of Hazardous Substances or Medical Waste in any amount? ., ,,.. , 4 r | | 1 Will your ousiness store or handle Hazardous Substances in quantities equal 10 or greater than 55 gallons, 500 pounds. 200 cubic feet or carcinogens/reproductive toxins in any quantity? 4 | | £^j Will your business use an existing or install an underground storaga tank? 5 f"1! I — I Will your business store or handle Acutely Hazardous Matenals? -, ...» -.,- , -„ - PART III SAN DIEGO COUNTY AIR POLLUTION CONTROL DISTRICT Corrosives Other Health Hazards OFFICE USE ONLY [""] RMPP Exempt / Date Initials r] RMPP Required 1 ~ '' ^ Date Initials [""} RMPP Completec / Date Initials -l -:C»:_, • If the answer to any of the questions is yes, applicant must contact the Air Pollution Control District, 9150 Chesapeake Dnve, San Diego, CA 92123 Telephone (619) 694-3307 pnor to the issuance of a building permit YES NO 1 I — I [ — | Will the intended occupant install or use any of the equipment listed on the Listing of Air Pollution Control Distnct Permit Categones, on the reverse side of this form? 2 I — I [ — | (ANSWER ONLY IF QUESTION 1 IS YES ) Will the sublet facility be located within 1,000 feet of the outer boundary of a school (K through 1 2) as listed in the current Directory of School and Community College Distncts, published by the San Diego County Office of Education arv the current California Private School Directory, compiled in accordance with provisions of Education Code Section 33190? Snary escribe H Name of Owner or Authorized Agent Signature of Owner or Authorized Agent I declare under penalty of perjury that to the best of my knowledge and belief the responses made herein are tru and correct Date Do not write below this line FIRE DEPARTMENT OCCUPANCY CLASSIFICATION BY EXEMPT FROM PERMIT REQUIREMENTS COUNTY-HMMD APCD /P\S\ Couoty of Sm DietEnvironmental Health Service* DHS HM-9171 (6/92) hazardous Materials ' j SAN DIEGO REGIONAL HAZARDOUS MATERIALS QUESTIONNAIRE Management Division COtlTV »f III DlltO Business Name Contact Person Telephone Mailing Address City State Zip Plan File* ST. Site Address C£5MOS CT- City State Zip Plan File* Cft PART I FIRE DEPARTMENT - HAZARDOUS MATERIALS MANAGEMENT DIVISION OCCUPANCY CLASSIFICATION Indicate by circling the item, whether your business will use, process, or store any of the following hazardous materials If any or the items are circled, applicant must contact the Fire Protection Agency with jurisdiction pnor to plan submittal 1 Explosive or Blasting Agents 4 Rammable Solids 2 Compressed Gases 5 Organic Peroxides 3 Flammable or Combustible Liquids 6 Oxidizers 7 Pyrophoncs 10 Cryogenics 8 Unstable Reactives 11 Highly Toxic or Toxic Materials 9 Water Reactives 12 Radioactives 13 Corrosives 14 Other Health Hazards PART II COUNTY OF SAN DIEGO HEALTH DEPARTMENT - HAZARDOUS MATERIALS MANAGEMENT CONTINGENCY PLAN REVIEW If the answer to any of the questions is yes, applicant must contact the County of San Diego Hazardous Division, 1255 Imperial Avenue, 3rd Floor, San Diego, CA 92186-5261 Telephone (619) 338-2222 pn< building permit FEES MAY BE REQUIRED Yes No 1 |~ — 1 l~~l Is your business listed on the reverse side of this form? 2 P~| I — 1 Will your business dispose of Hazardous Substances or Medical Waste in any amount? 3 4 5 | — | Will your business store or handle Hazardous Substances in quantities equal to or greater t 500 pounds, 200 cubic feet or carcinogens/reproductive toxins in any quantity? H I — ] Will your business use an existing or install an underground storage tank? | — | Will your business store or handle Acutely Hazardous Materials? DIVISION Materials Management >r to the issuance of a ~.'~c] rn • ~ han 55 gallons. OFFICE USE ONLY | | RMPP Exempt Date Initials [~"j RMPP Required Date Initials | | RMPP Completed (. -^3Date Inftiajs^C PART lit SAN DIEGO COUNTY AIR POLLUTION CONTROL DISTRICT If the answer to any of the questions is yes, applicant must contact the Air Pollution Control Distnct, 9150 Chesapeake Drive, San Diego, CA 92123 Telephone (619) 694-3307 prior to the issuance of a building permit YES NO 1 £ — | |~n Will the intended occupant install or use any of the equipment listed on the Listing of Air Pollution Control Distnct Permit Categories, on trie" reverse side of this form? 2 CD | — | (ANSWER ONLY IF QUESTION 1 IS YES ) Will the subject facility be located within 1.OOO feet of the outer boundary of a school (K through 1 2) as listed in the current Directory of School and Community College Distncts, published by the San Diego County Office of Education and the current California Pnvate School Directory, compiled in accordance with provisions of Education Code Section 33190? Briefly describe nature of the ™^ Name of Owner or Authorized Agent Signature of Owner or Authorized Agent, I declare under penalty of perjury that to the best of my knowledge and belief the responses made herein are true and correct Date Do not write below this line FIRE DEPARTMENT OCCUPANCY CLASSIFICATION . BY Date EXEMPT FROM PERMIT REQUIREMENTS COUNTY-HMMD APCD APPROVED FOR BUILDING PERMIT BUT NOT OCCUPANCY APCD APPROVED FOR OCCUPANCY COUNTY-HMMD APCD Environment*] Health Service! DHS HM-9171 (6792) _\ -J - I ff^ /"}^fewviLx T>ri MkAf^ji *=k\ AAJr County of San Dicf o ofHetllfa Servica77 UJ O CO O scc llRQ IIiio o H tr JJj z•^ ti n ^s »r ••"•ji <rO.:Srf|!iggeSI.UJ COCO. CDT*^prk^D.1JM??UZUJc-*^<-\Vw\•**,tf UJQCu_Q"**.•5-Cj^1i>s\)rw O 3CD TO FROMAPPLICANT APPLICANTfy6^M V.\*w^^Q?5Q1ri ^ iJ ,\ ^\5-s.•1J^r.V V rxi ^rv.^I V^r>'i Ov~^ $!"^^ ^v^^ r *lci 5 s" ° ^U 4 "^ Avc vJ J , -^ vJ HM^^ IA O 5 ^'\3^ I 5.1,1,^)1^^^ <\I M l) ^ k^<^ r<\C^ -Ngs.X3^<5^^^-\\x^\-^^.,!^\ ^^ \ Q, CL. -C/0 J ioo -r)r o v3 rO City of Carlsbad 1635 Faraday Av Carlsbad, CA 92008 09-05-2001 Plan Check Revision Permit No PCR01190 Building Inspection Request Line (760) 602-2725 Job Address 2293 COSMOS CT CBAD Permit Type PCR Status PENDING Parcel No 2130504300 Lot# 0 Applied 08/20/2001 Valuation $0 00 Construction Type NEW Entered By JM Reference # Plan Approved Issued Project Title OCEANSIDE GLASS TILE Inspect Area INSTALL UNDERGROUND TANK IN BATCH ROOM Applicant Owner RICHARDSON ROBERT GERRY REVOCABLE LIVING TRUST 08-06-96 C 2802 STATE ST 2033 SHIPWAY LN CARLSBAD CA 92008 NEWPORT BEACH CA 92660 760-434-8400 Total Fees $240 00 Total Payments To Date $000 Balance Due $240 00 Plan Check Revision Fee $240 00 Additional Fees $0 00 FINAL APPROVAL Inspector Date Clearance NOTICE Please take NOTICE that approval of your project includes the "Imposition" of fees dedications, reservations, or other exactions hereafter collectively referred to as "fees/exactions" You have 90 days from the date this permit was issued to protest imposition of these fees/exactions If you protest them, you must follow the protest procedures set forth in Government Code Section 66020(a), and file the protest and any other required information with the City Manager for processing in accordance with Carlsbad Municipal Code Section 3 32 030 Failure to timely follow that procedure will bar any subsequent legal action to attack, review, set aside, void, or annul their imposition You are hereby FURTHER NOTIFIED that your right to protest the specified fees/exactions DOES NOT APPLY to water and sewer connection fees and capactiy changes, nor planning, zoning, grading or other similar application processing or service fees in connection with this project NOR DOES IT APPLY to any fees/exactions of which you have previously been given a NOTICE similar to this, or as to which the statute of limitations has previously otherwise expired PERMIT APPLICATION CITY OF CARLSBAD BUILDING DEPARTMENT 1635 Faraday Ave , Carlsbad, CA 92008 O3&/0 ft 7 PROJECT INFORMATION FOR OFFICE USE ONLY PLAN CHECK NO EST VAL Plan Ck Deposit-— Validated By_x Date Address (include Bldg/Suite #)Business Name (at this address) Legal Description Lot No Subdivision Name/Number Unit No Phase No Total # of units Assessor's Parcel ft Existing Use Proposed Use #of Stories tt of Bedrooms # of Bathrooms Nome / 3." ' APPLICANT w|;G] Coritraatbr"' Address City State/Zip Telephone #Fax ff Name 4L-, ^RQPERTYXJWNER'S Address City State/Zip Telephone # Name Address City State/Zip Telephone # .Si-' CONtRACTOR- COMPANY NAME :'^S" "j:'^: ..-./:,:-:f '.-"'.'.': . . : " .' ' "'.:.' "••' •'i,..,:...".' ':'T-Ji'- (Sec 7031 5 Business and Professions Code Any City or County which requires a permit to construct, alter, improve, demolish or repair any structure, prior to its issuance, also requires the applicant for such permit to file a signed statement that he is licensed pursuant to the provisions of the Contractor's License Law [Chapter 9, commending with Section 7000 of Division 3 of the Business and Professions Code] or that he is exempt therefrom, and the basis for the alleged exemption Any violation of Section 7031 5 by any applicant for a permit subjects the applicant to a civil penalty of not more than five hundred dollars ($5001) Name State License ff Address License Class City State/Zip City Business License ff Telephone # Designer Name State License # Address City State/Zip Telephone Workers' Compensation Declaration I hereby affirm under penalty of perjury one of the following declarations D I have and will maintain a certificate of consent to self-insure for workers' compensation as provided by Section 3700 of the Labor Code, for the performance of the work for which this permit is issued [~1 I have and will maintain workers' compensation, as required by Section 3700 of the Labor Code, for the performance of the work for which this permit is issued My worker's compensation insurance carrier and policy number are Insurance Company Policy No Expiration Date (THIS SECTION NEED NOT BE COMPLETED IF THE PERMIT IS FOR ONE HUNDRED DOLLARS [$100] OR LESS) Q CERTIFICATE OF EXEMPTION I certify that in the performance of the work for which this permit is issued, I shall not employ any person in any manner so as to become subject to the Workers' Compensation Laws of California WARNING Failure to secure workers' compensation coverage is unlawful, and shall subject an employer to criminal penalties and civil fines up to one hundred thousand dollars ($100 000) in addition to the cost of compensation, damages as provided for in Section 3706 of the Labor code interest and attorney s fees SIGNATURE DATE 7;,; OWNER-BUiLbERibEClARATION"!;- ' :v' . "137:-'-: SC ^.v^-SI?1 '5v, '.". -itf7.^ '? ^F' ,./, ; s::r ;^'; _•**.'•> ''"''"•. "*l "I..K "I* ';'':\,, V:L ^ I hereby affirm that I am exempt from the Contractor's License Law for the following reason l~1 I, as owner of the property or my employees with wages as their sole compensation, will do the work and the structure is not intended or offered for sale (Sec 7044, Business and Professions Code The Contractor's License Law does not apply to an owner of property who builds or improves thereon, and who does such work himself or through his own employees, provided that such improvements are not intended or offered for sale If, however, the building or improvement is sold within one year of completion, the owner builder will have the burden of proving that he did not build or improve for the purpose of sale) 0 I, as owner of the property, am exclusively contracting with licensed contractors to construct the project (Sec 7044, Business and Professions Code The Contractor's License Law does not apply to an owner of property who builds or improves thereon, and contracts for such projects with contractor(s) licensed pursuant to the Contractor's License Law) (~l I am exempt under Section Business and Professions Code for this reason 1 I personally plan to provide the major labor and materials for construction of the proposed property improvement f~l YES l~lNO 2 I (have / have not) signed an application for a building permit for the proposed work 3 I have contracted with the following person (firm) to provide the proposed construction (include name / address / phone number / contractors license number) 4 I plan to provide portions of the work, but I have hired the following person to coordinate, supervise and provide the major work (include name / address / phone number / contractors license number) 5 I will provide some of the work, but I have contracted (hired) the following persons to provide the work indicated (include name / address / phone number / type of work) DATEPROPERTY OWNER SIGNATURE COMPLETE THIS SECTION Is the applicant or future building occupant required to submit a business plan, acutely hazardous materials registration form or risk management and prevention program under Sections 25505, 25533 or 25534 of the Presley-Tanner Hazardous Substance Account Act? D YES D NO Is the applicant or future building occupant required to obtain a permit from the air pollution control district or air quality management district? CD YES Q Is the facility to be constructed within 1,000 feet of the outer boundary of a school site? Q YES Q NO IF ANY OF THE ANSWERS ARE YES, A FINAL CERTIFICATE OF OCCUPANCY MAY NOT BE ISSUED UNLESS THE APPLICANT HAS MET OR IS MEETING THE REQUIREMENTS OF THE OFFICE OF EMERGENCY SERVICES AND THE AIR POLLUTION CONTROL DISTRICT NO I hereby affirm that there is a construction lending agency for the performance of the work for which this permit is issued (Sec 3097(0 Civil Code) LENDER'S NAME _ LENDER S ADDRESS I certify that I have read the application and state that the above information is correct and that the information on the plans is accurate I agree to comply with all City ordinances and State laws relating to building construction I hereby authorize representatives of the CitV of Carlsbad to enter upon the above mentioned property for inspection purposes I ALSO AGREE TO SAVE INDEMNIFY AND KEEP HARMLESS THE CITY OF CARLSBAD AGAINST ALL LIABILITIES. JUDGMENTS, COSTS AND EXPENSES WHICH MAY IN ANY WAY ACCRUE AGAINST SAID CITY IN CONSEQUENCE OF THE GRANTING OF THIS PERMIT OSHA An OSHA permit is required for excavations over 5'0" deep and demolition or construction of structures over 3 stories in height EXPIRATION Every permit issued by the building Official under the provisions of this Code shall expire by limitation and become null and void if the building or work authorized by such permit is not comrnj at any time after the work is comm APPLICANT'S SIGNATURE e date of such permit or if the building or work authorized by such permit is suspended or abandoned ection 106 4 4 Uniform Building Code) DATE WHITE File YELLOW Applicant PINK Finance 05/24/2002 RICHARDSON ROBERT C 2802 STATE ST CARLSBAD CA92008 Re Application Date 08/20/2001 0 00 00 Plan Check # PCR01190 Address 2293 COSMOS CT Expiration Date 08/20/2002 0 00 00 Permit Type PCR Description OCEANSIDE GLASS TILE INSTALL UNDERGROUND TANK IN BATCH ROOM You applied to have your plans checked on the date noted above To date, the related building permit has not been obtained The original plan review application will expire as no building permit has been issued Plans submitted and not retrieved from the building department prior to the plan check expiration date noted above will be destroyed The provisions of sections 304 (d) of the Uniform Building Code state "Section 304 9d) Expiration of Plan Review Applications for which no permit is issued within one year following the date of application shall expire by limitation, and plans and other data submitted for review may thereafter be returned to the applicant or destroyed by the Building Official In order to renew action on an application after expiration, the applicant shall resubmit plans and pay a new plan review fee " In order to provide better service, please indicate your handling choice for the plans originally submitted and return this letter to the Building Department Toject Abandoned - I will pick up plans within 10 days Project Abandoned - Plans may be destroyed /\//) JJ'^v^C^ lz> n 7/1 If you have any questions, please contact the Building Bepartment at (760) 602-2718 Raenette Abbey Building Department EsGii Corporation In Partners/tip with government for Quitting Safety DATE August 29, 2OO1 a ARELJCANT JURISDICTION Carlsbad a PLAN REVIEWER a FILE PLAN CHECK NO 01-0567 Rev. 1 (PCR01-190) SET I PROJECT ADDRESS 2293 Cosmos Court PROJECT NAME Oceanside Glasstile XI The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes PLEASE SEE REMARKS BELOW The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff I | The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck I | The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person The applicant's copy of the check list has been sent to Esgil Corporation staff did not advise the applicant that the plan check has been completed Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Telephone # Date contacted (by ) Fax # Mail Telephone Fax In Person REMARKS 1 Special inspection is required for concrete with compressive strength of 3000 psi The Architect of Engineer of record shall submit a special inspection program to the City Building Official for his review and approval prior to issuance of the building permit By Abe Doliente Enclosures Esgil Corporation D GA D MB D EJ D PC 8/21/01 tmsmtldot 9320 Chesapeake Drive, Suite 208 * San Diego, California 92123 + (858)560-1468 + Fax (858) 560-1576 -\ Carlsbad O1-O567 Rev. 1 (PCR01-190) August 29, 20O1 SPECIAL INSPECTION PROGRAM ADDRESS OR LEGAL DESCRIPTION 2293 Cosmos Court PLAN CHECK NUMBER 01-0567 Rev. 1 OWNER'S NAME Oceanside Glasstile I, as the owner, or agent of the owner (contractors may not employ the special inspector), certify that I, or the architect/engineer of record, will be responsible for employing the special mspector(s) as required by Uniform Building Code (UBC) Section 1701 1 for the construction project located at the site listed above UBC Section 10635 Signed I, as the engineer/architect of record, certify that I have prepared the following special inspection program as required by UBC Section 106 3 5 for the construction project located at the site listed above Engineer's/Architects Seal & Signature Here Signed 1 List of work requiring special inspection D Soils Compliance Prior to Foundation Inspection D Field Welding D Structural Concrete Over 2500 PSI D High Strength Bolting D Prestressed Concrete D Expansion/Epoxy Anchors D Structural Masonry D Sprayed-On Fireproofmg D Designer Specified D Other 2 Name(s) of mdividual(s) or firm(s) responsible for the special inspections listed above. A B C. 3. Duties of the special inspectors for the work listed above A B Special inspectors shall check in with the City and present their credentials for approval prior to beginning work on the job site Carlsbad 01-0567 Rev. 1 (PCRO1-190) August 29, 2001 VALUATION AND PLAN CHECK FEE JURISDICTION Carlsbad (PCR01-190) PREPARED BY Abe Doliente BUILDING ADDRESS 2293 Cosmos Court BUILDING OCCUPANCY B/F-2/S-2 PLAN CHECK NO 01-0567 Rev. 1 DATE August 29, 2001 TYPE OF CONSTRUCTION III-N BUILDING PORTION Rev No 1 Underground Tank Air Conditioning Fire Sprinklers TOTAL VALUE Jurisdiction Code AREA (Sq Ft) cb Valuation Multiplier By Ordinance Reg Mod VALUE ($) Bldg Permit Fee by Ordinance Plan Check Fee by Ordinance $240.00 Type of Review CH Repetitive FeeRepeats D Complete Review D Other r-1 Hourly Structural Only Hours Esgil Plan Review Fee $192.00 * Based on hourly rate Comments Construction of underground tank Sheet 1 of 1 macvalue doc Garisbad Fire Department 01190 1635 Faraday Ave Carlsbad, CA 92008 Plan Review Requirements Category: Date of Report 08/23/2001 Fire Prevention (760) 602-4660 Building Plan Reviewed by Name Address Karnak Architecture 2802 State Street Suite C City, State Carlsbad CA 92008 Plan Checker Job Name Oceanside Glasstile Job# 01190 Job Address 2293 Cosmos Court U Bldg# PCR01190 Ste orBldg No Approved The item you have submitted for review has been approved The approval is based on plans, information and / or specifications provided in your submittal, therefore any changes to these items after this date, including field modifications, must be reviewed by this office to insure continued conformance with applicable codes and standards Please review carefully all comments attached as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements LJ Approved Subject to The item you have submitted for review has been approved subject to the attached conditions The approval is based on plans, information and/or specifications provided in your submittal Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements Please resubmit to this office the necessary plans and / or specifications required to indicate compliance with applicable codes and standards 0 Incomplete The item you have submitted for review is incomplete At this time, this office cannot adequately conduct a review to determine compliance with the applicable codes and / or standards Please review carefully all comments attached Please resubmit the necessary plans and / or specifications to this office for review and approval Review FD Job # 1st 01190 2nd 3rd Other Agenry ID FDFile# Building Plan Requirement Pending 0514 Provide Technical Report To determine the acceptability of technologies, processes, products, facilities, materials and uses attending the design, operation or use of a building or premises subject to the inspection of the department, the Chief is authorized to require the owner or the person in possession or control of the building or premises to provide, without charge to the jurisdiction, a technical opinion and report The opinion and report shall be prepared by a qualified engineer, specialist, laboratory or fire-safety specialty organization acceptable to the Chief and the owner and shall analyze the fire-safety properties of the design, operation or use of the building or premises and the facilities and appurtances situated thereon, to recommend necessary changes Page 1 08/23/01 ^)0£p3 TO FROMAPPUCANT APPUCANT03 TJOCO 111-