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Home My WebLink About2293 COSMOS CT; ; CB011467; PermitV( 1D7/.11/2001 ;" W City of Carlsbad 1635 Faraday Av Carlsbad, CA 92008 Commercial/Industrial Permit Permit No Building Inspection Request Line (760) 602-2725 CB011467 Job Address Permit Type Parcel No Valuation Occupancy Group Project Title 06/07/2001 2293 COSMOS CT CBAD Tl Sub Type INDUST 2130504500 Lot# 0 $5,000 00 Construction Type NEW Reference # CB010567 OCEANSIDE GLASS/TILE-EQUIPMENT ONLY, ROOF BLOWERS & CHEMICAL STORAGE Status Applied Applicant KARNAK ARCHITECTURE Issued Inspect Area Owner AXIOM AIRPORT PARTNERS L P C/O CHRIS PISARIK 3039 CRESTA WAY BEACH CA 92651 ISSUED 04/18/2001 Entered By RMA Plan Approved 07/11/2001 02 CGP 567-01 Total Fees $567 01 Total Payments To Date $000 Balance Due $567 01 Building Permit Add'l Building Permit Fee Plan Check Add'l Plan Check Fee Plan Check Discount Strong Motion Fee P'ark Fee LFM Fee Bridge Fee BTD #2 Fee BTD #3 Fee Renewal Fee Add'l Renewal Fee Other Building Fee Pot Water Con Fee Meter Size Add'l Pot Water Con Fee Reel Water Con Fee $61 19 Meter Size $0 00 Add'l Reel Water Con Fee $39 77 Meter Fee $0 00 SDCWA Fee $0 00 CFD Payoff Fee $1 05 PFF $0 00 PFF (CFD Fund) $0 00 License Tax $0 00 License Tax (CFD Fund) $0 00 Traffic Impact Fee $0 00 Traffic Impact (CFD Fund) $0 00 PLUMBING TOTAL $0 00 ELECTRICAL TOTAL $327 00 MECHANICAL TOTAL $0 00 Master Drainage Fee Sewer Fee $0 00 Redev Parking Fee $0 00 Additional Fees TOTAL PERMIT FEES $000 $000 $000 $000 $000 $000 $000 $000 $000 $000 $2700 $6000 $51 00 $000 $000 $000 $000 $567 01 Inspector FINAL APPROVAL Date i «>» * 11 i i %^^ i i \\ /D-l-Ot Clearance NOTICE Please take NOTICE that approval of your project includes the Imposition of fees dedications reservations or other exactions hereafter collectively referred to as fees/exactions You have 90 days from the date this permit was issued to protest imposition of these fees/exactions If you protest them you must 'follow the protest procedures set forth in Government Code Section 66020(a) and file the protest and any other required information with the City Manager for processing in accordance with Carlsbad Municipal Code Section 3 32 030 Failure to timely follow that procedure will bar any subsequent legal action to attack review set aside void or annul their imposition ..You are hereby FURTHER NOTIFIED that your right to protest the specified fees/exactions DOES NOT APPLY to water and sewer connection fees and capactiy changes nor planning zoning grading or other similar application processing or service fees in connection with this project NOR DOES IT APPLY to any •tees/exactions of which you have previously been given a NOTICE similar to this, or as to which the statute of limitations has previously otherwise expired PERMIT APPLICATION CITY OF CARLSBAD BUILDING DEPARTMENT 1635 Faraday Ave , Carlsbad, CA 92008 y INFO TION Plan Ck Deposit Validated By Date " Address (include Bldg/Suite #)Business Name (at this address) Unit No. „ Phase No Total # of unitsSubdivision Name/NumberLegal Description Assessor s Parcel # Description of Work NTACT:PERSQfCHT different from applicant) State/Zip Telephone # Fax #Address Agent for Contractor Q Owner City Agent for Owner3 APPLICANT D Contractor State/Zip Telephone # Address City State/Zip Telephone #Name B CONTRACTOR COMPANY NAME " "" "*' ": -VAif, "" «';ff^ .., ::''"' (Sec 7031 5 Business and Professions Code Any City or County which requires a permit to construct alter improve demolish or repair any structure prior to its issuance also requires the applicant for such permit to file a signed statement that he is licensed pursuant to the provisions of the Contractor s License Law [Chapter 9 commending with Section 7000 of Division 3 of the Business and Professions Code] or that he is exempt therefrom and the basis for the alleged exerrjptjpn Any violation^ Section 7031 5 by any applicant for ajjermit subjects the applicant tq_a civil penalty of nqt/nore than fjve hundred dollars?f Name State License # Address License Class City State/Zip TelephonV* City Business License # Ifyi O / Jo 2- 1 Designer Name Address City State/Zip Telephone State License tt ;6 WORKERS ^COMPENSATION -, ,. ., •, ,» Jf ; """" .. "" .„ "'M'^- .^ ' »??•*" Workers Compensation Declaration I hereby affirm under penalty of perjury one of the following declarations |~| I have and will maintain a certificate of consent to self insure for workers compensation as provided by Section 3700 of the Labor Code for the performance of the work for which this permit is issued Q I have and will maintain workers compensation as required by Section 3700 of tJjeLabor Code, for the performance of the work for which this permit is issued My worker s compensation insurance carrier and policy numbejxjT§ dje*'^ ^^*^l^-&^ I i (THIS SECTION NEED NOT BE COMPLETED IF THE PERMIT IS FOR ONE HUNDRED DOLLARS [$100] OR LESS) [~l CERTIFICATE OF EXEMPTION I certify that in the performance of the work for which this permit is issued I shall not employ any person in any manner so as to become subject to the Workers Compensation Laws of California WARNING Failure to secure workers compensation coverage is unlawful and shall subject an employer to criminal penalties and civil fines up to one hundred thousand dollars ($100 OOP) in additipnXb the^ost of tpTnpensation damages as provided for in Section 3706 of the Labor coda interest and attorney s fees SIGNATURE ^^^^f^li^i ^^^T^^ _^ DATE ~?/H JO)7 OWNERBU/LDpRDECLARATION/ S*:lA?~~*Z~~ W~=^ ''''"• ;;; , * -1* I hereby affirm tlwH am exempt from the Contractor s License Law for the following reason |~1 | as owner of the property or my employees with wages as their sole compensation will do the work and the structure is not intended or offered for sale (Sec 7044 Business and Professions Code The Contractor s License Law does not apply to an owner of property who builds or improves thereon and who does such work himself or through his own employees provided that such improvements are not intended or offered for sale If however the building or improvement is sold within one year of completion the owner builder will have the burden of proving that he did not build or improve for the purpose of sale) jKi I as owner of the property am exclusively contracting with licensed contractors to construct the project (Sec 7044 Business and Professions Code The Contractor s License Law does not apply to an owner of property who builds or improves thereon and contracts for such projects with contractor(s) licensed pursuant to the Contractor s License Law) PI I am exempt under Section Business and Professions Code for this reason 1 I personally plan to provide the major labor and materials for construction of the proposed property improvement PI YES PINO 2 I (have / have not) signed an application for a building permit for the proposed work 3 I have contracted with the following person (firm) to provide the proposed construction (include name / address / phone number / contractors license number) 4 I plan to provide portions of the work but I have hired the following person to coordinate supervise and provide the major work (include name / address / phone number / contractors license number) 5 I will provide some of the work bi of work) ave contra|cbut-Khi Izi hired) the following persons to provide the work indicated (include name / address / phone number / type yJ?X?- PROPERTY OWNER SIGNATURE ^ COMPLETE THIS SECTION FOR NON RESIDENTIAL BWLDiNG PERMITS ONL Is the applicant or future building occupant required to submit a buwf!ess"/an acutely hazardous materials registration form or risk management and prevention program under Sections 25505 25533 or 25534 of the Presley TanRBTflazardous Substance Account Act? l~l YES l~l NO Is the applicant or future building occupant required to obtain a permit from the air pollution control district or air quality management district' PJ YES PJ NO Is the facility to be constructed within 1 000 feet of the outer boundary of a school site? PI YES PJ NO IF ANY OF THE ANSWERS ARE YES A FINAL CERTIFICATE OF OCCUPANCY MAY NOT BE ISSUED UNLESS THE APPLICANT HAS MET OR IS MEETING THE REQUIREMENTS OF THE OFFICE OF EMERGENCY SERVICES AND THE AIR POLLUTION CONTROL DISTRICT 8 CONSTRUCTION LENDING AGENCY ;, ; ,' •<£" ,i I hereby affirm that there is a construction lending agency for the performance of the work for which this permit is issued (Sec 3097(i) Civil Code) LENDER S NAME LENDER S ADDRESS 9 APPLICANT CERTIFiCAtiON Si: .-NI •*' ... ' '"::: - •!;»::""-:\ -n -' -.i**' .. I certify that I have read the application and state that the above information is correct and that the information on the plans is accurate I agree to comply with all City ordinances and State laws relating to building construction I hereby authorize representatives of the City of Carlsbad to enter upon the above mentioned property for inspection purposes I ALSO AGREE TO SAVE INDEMNIFY AND KEEP HARMLESS THE CITY OF CARLSBAD AGAINST ALL LIABILITIES JUDGMENTS COSTS AND EXPENSES WHICH MAY IN ANY WAY ACCRUE AGAINST SAID CITY IN CONSEQUENCE OF THE GRANTING OF THIS PERMIT OSHA An OSHA permit is required for excavations over 5 0 deep and demolition or construction of structures over 3 stories in height EXPIRATION Every permit issued by the building Official unjlgr the provisions of this Code shall expire by limitation and become null and void if the building or work authorized by such permit is not commenpe^witjjifi 18J) days/ffdmtthe dale of such permij or if the building or work authorized by such permit is suspended or abandoned at any time after the work is commencadfcrfa^teno^&f 18°/&fys fegfSpn 106 4 4 Wnjfefrm Buildffg CodeL SrA«L^S M/^ Jiri^ /vo. jf A-As DATEAPPLICANT S SIGNATURE YELLOW Applicant PINK Finance City of Carlsbad Bldg Inspection Request For 09/27/2001 Permit# CB011467 Title OCEANSIDE GLASS/TILE-EQUIPMENT Description ONLY, ROOF BLOWERS & CHEMICAL STORAGE Inspector Assignment PD 2293 COSMOS CT Lot Type Tl Sub Type INDUST Job Address Suite Location APPLICANT KARNAK ARCHITECTURE Owner AXIOM AIRPORT PARTNERS L P Remarks Phone 7609294073 Inspecto1 Total Time CD Description 19 Final Structural 29 Final Plumbing 39 Final Electrical 49 Final Mechanical Requested By DON Entered By KAREN Act Comments Associated PCRs PCR01190 PENDING Inspection History Date Description Act Insp Comments 07/25/2001 23 Gas/Test/Repairs PA PD 24 HR TEST 07/24/2001 23 Gas/Test/Repairs CO PD TEST CONTINUES 07/18/2001 23 Gas/Test/Repairs PA PD START 24 HR TEST 07/16/2001 23 Gas/Test/Repairs CA PD EsGil Corporation In Tartnerskip u>itfc government for 'BuikCing Safety DATE June 4, 2001 a AEEJJCANT JURISDICTION Carlsbad a PLAN REVIEWER a FILE PLAN CHECK NO O1-1467 SET II PROJECT ADDRESS 2293 Cosmos Court PROJECT NAME Oceanside Glasstile - Manufacturing Equipment Only X] The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes [~~| The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person The applicant's copy of the check list has been sent to Esgil Corporation staff did not advise the applicant that the plan check has been completed Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Telephone # Date contacted (by ) Fax # Mail Telephone Fax In Person REMARKS By Abe Doliente Enclosures Esgil Corporation D GA D MB D EJ D PC 5/25/01 trnsmtldot 9320 Chesapeake Drive, Suite 208 4 San Diego, California 92123 + (858)560-1468 4 Fax (858) 560-1576 EsGil Corporation In Partners/tip With government for Buibfinj Safety DATE May 1, 2001 a APPLICANT CH JURIS^ JURISDICTION Carlsbad a PLAN REVIEWER a FILE PLAN CHECK NO O1-1467 SET I PROJECT ADDRESS 2293 Cosmos Court PROJECT NAME Oceanside Glasstile - Manufacturing Equipment Only The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck X] The check list transmitted herewith is for your information The plans are being held at Esgil Corporation until corrected plans are submitted for recheck The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person 1X1 The applicant's copy of the check list has been sent to Karnak Architecture, Attn Robert Richardson 2802 State St, Suite C, Carlsbad, CA 92008 I | Esgil Corporation staff did not advise the applicant that the plan check has been completed X] Esgil Corporation staff did advise the applicant that the plan check has been completed Person contacted Robert Richardson Telephone # 760/434-8400 Date contacted s-i-oi (by B*^) Fax # fr&^4£4--dfq»> Mail Telephone^" Fax -"' In Person ] REMARKS By Abe Doliente Enclosures Esgil Corporation D GA D MB E3 EJ D PC 4/23/01 trnsmtldot 9320 Chesapeake Drive, Suite 208 4 San Diego, California 92123 + (858)560-1468 * Fax (858) 560-1576 Carlsbad 01-1467 May 1, 2OO1 GENERAL PLAN CORRECTION LIST JURISDICTION Carlsbad PLAN CHECK NO 01-1467 PROJECT ADDRESS 2293 Cosmos Court DATE PLAN RECEIVED BY DATE REVIEW COMPLETED ESGIL CORPORATION 4/23/01 May 1, 2001 REVIEWED BY Abe Doliente FOREWORD (PLEASE READ) This plan review is limited to the technical requirements contained in the Uniform Building Code, Uniform Plumbing Code, Uniform Mechanical Code, National Electrical Code and state laws regulating energy conservation, noise attenuation and disabled access This plan review is based on regulations enforced by the Building Department You may have other corrections based on laws and ordinances enforced by the Planning Department, Engineering Department or other departments The following items listed need clarification, modification or change All items must be satisfied before the plans will be in conformance with the cited codes and regulations Per Sec 106 4 3, 1997 Uniform Building Code, the approval of the plans does not permit the violation of any state, county or city law • Please make all corrections on the original tracings and submit two new complete sets of prints to Esgil Corp ortothebldg dept of the juris • To facilitate recheckmg, please identify, next to each item, the sheet of the plans upon which each correction on this sheet has been made and return this sheet with the revised plans • Please indicate here if any changes have been made to the plans that are not a result of corrections from this list If there are other changes, please briefly describe them and where they are located on the plans Have changes been made not resulting from this list? Q Yes a No Carlsbad 01-1467 May 1, 2001 MECHANICAL CORRECTIONS PLAN REVIEWER Eric Jensen MECHANICAL (1997 UNIFORM MECHANICAL CODE) 1 All sheets of the two sets of plans must be signed by the person responsible for their preparation 2 The "MP" sheets do not match the Glasstile sheets 5 PSI regulator is shown on sheet MP9 detail, 4" gas pipe is shown on MP7 (note 21), F1 &F2 gas pipe sizing is 1 Y2" on Glasstile, 1 V*" on MP Please correct the inconsistencies and review the equipment for proper gas pipe sizing Note If you have any questions regarding this Plumbing, Mechanical, and Energy plan review list please contact Eric Jensen at (858) 560-1468 To speed the review process, note on this list (or a copy) where the corrected items have been addressed on the plans Carlsbad 01-1467 May 1, 20O1 VALUATION AND PLAN CHECK FEE JURISDICTION Carlsbad PREPARED BY Abe Dohente BUILDING ADDRESS 2293 Cosmos Court BUILDING OCCUPANCY B/F-l/S-1 PLAN CHECK NO 01-1467 DATE May 1, 2001 TYPE OF CONSTRUCTION V-N BUILDING PORTION Air Conditioning Fire Sprinklers TOTAL VALUE Jurisdiction Code AREA (Sq Ft) cb Valuation Multiplier By Ordinance Reg Mod VALUE ($) T | Bldg Permt Fee by Ordinance •y | brorr you cnecKea UDmp Keview ana Hourly at the same time Plan Check Fee by Ordinance ^ Type of Review D Repetitive Fee Repeats 0 Complete Review n Other B Hourly D Structural Only Hours * Esgil Plan Review Fee $261 45 * Based on hourly rate Comments Sheet 1 of 1 macvalue doc , I PLANNING/ENGINEERING APPROVAL / £jen7~&-#*L0^<-s , PERMIT NUMBER CB ADDRESS DATE RESIDENTIAL TENANT IMPROVEMENT RESIDENTIAL ADDITION MINOR (<$10,000.00) PLAZA CAMINO REAL CARLSBAD COMPANY STORES VILLAGE FAIRE COMPLETE OFFICE BUILDING OTHER PLANNER ENGINEER DATE DATE I ' Docs/Misforms/Planning Engineering Approvals PLANNING DEPARTMENT BUILDING PLAN CHECK REVIEW CHECKLIST Plan Check No CB C?// 7 Planner Greg Fisher ^ APN P"/1?-^ Address Mr Phone (760) 602-4629. Type oi Project & Use r 7&fl Project Density ."DU/AC Zoning CFD fm/nnt) # Circle One General Plan _Date of participation Facilities Management Zone Remaining net dev acres (For non-residential development Type of land used created by this permit ) Legend /\ Item Complete Item Incomplete - Needs your action I | Environmental Review Required YES NO TYPE DATE OF COMPLETION Compliance with conditions of approval7 If not, state conditions which require action Conditions of Approval Discretionary Action Required APPROVAL/RESO NO PROJECT NO YES NO TYPE DATE OTHER RELATED CASES Compliance with conditions or approval7 If not, state conditions which require action Conditions of Approval I I Coastal Zone Assessment/Compliance Project site located in Coastal Zone7 YES CA Coastal Commission Authority7 YES N0_ NO If California Coastal Commission Authority Contact them at - 3111 Cammo Del Rio North, Suite 200, San Diego CA 92108-1725, (619) 521-8036 Determine status (Coastal Permit Required or Exempt) Coastal Permit Determination Form already completed7 If NO, complete Coastal Permit Determination Form now Coastal Permit Determination Log # YES NO Follow-Up Actions 1) Stamp Building Plans as "Exempt" or "Coastal Permit Required" (at minimum Floor Plans) 2) Complete Coastal Permit Determination Log as needed H \ADMIN\COUNTER\BldgPlnchkRevChklst I I I I Inclusionary Housing Fee required YES (Effective date of Inclusionary Housing Ordinance May 21 1993! NO Data Entry Completed? YES NO (A/P/Ds Activity Maintenance enter CB# toolbar Screens Housing Fees Construct Housing Y/N Enter Fee UPDATE') Site Plan | | 1 Provide a fully dimensional site plan drawn to scale Show North arrow, property lines, easements, existing and proposed structures, streets, existing street improvements, right-of-way width, dimensional setbacks and existing topographical lines I | I I 2 Provide legal description of property and assessor's parcel number Zoning I| || 1 Setbacks D D Front Interior Side Street Side Rear 2 Accessory structure Front Interior Side Street Side Rear Structure separation 3 Lot Coverage Required Required Required Required setbacks Required Required Required Required Required Required Shown Shown Shown Shown Shown Shown Shown Shown Shown Shown D D D 4 Height Required D D | | 5 Parking Spaces Required Guest Spaces Required | I Additional Comments Shown Shown Shown OK TO ISSUE AND-ENTERED APPROVAL INTO COMPUTER H \ADMIN\COUNTER\BldgPlnchkRevChklst Hazardous Material. SAN DIEGO REGIONAL HAZARDOUS MATERIALS QUESTIONNAIRE lanagernent Division etssir sr IA* mil Business Name Contact Person Telephone Mailing Address City TfUrvtSY. State Zip Plan File* Site Address City State Zip Plan File* ART I FIRE DEPARTMENT - HAZARDOUS MATERIALS MANAGEMENT DIVISION OCCUPANCY CLASSIFICATION dicata by circling the item, whether your business will use, process, or store any of the following hazardous materials If any or the items are rclad applicant must contact the Fir* Protection Agency with /ungdiction prior to plan submmal Explosive or Blasting Agents 4 Flammable Solid* Compressed Gases 5 Organic Peroxides Flammable or Combustible Liquid* 6 Oxidizer* 7 Pyrophoric* 10 Cryogenic* 8 Unstable Reactive* 11 Highly Toxic or Toxic Materials 9 Water Reactive* 12 Radioactive* 13 Corrosives 14 Other Health Hazards 4RT II. COUNTY OF SAN DIEGO HEALTH DEPARTMENT HAZARDOUS MATERIALS MANAGEMENT DIVISION ONTINGENCY PLAN REVIEW. the answer to any of the questions is yes applicant must contact the County of San Diego Hazardous Materials Management ivision 1 255 Imperial Avenue, 3rd Floor, San Diego, CA 92186-5261 Telephone (619) 338-2222 pnor to the issuance of a jilding permit EES MAY BE REQUIRED H c:Yes No r"""1 Is your business listed on the raver** side of this form? Will your business dispose of Hazardoua Substances or Medical Waste in any amount? « r~i Will your business store or handle Hezardous Substances in quantities equel to or greater than 55 gallons 500 pound* 200 cubic feet or carcinogens/reproductive toxin* in any quantity? Will your business use an existing or install an underground storage tank? Will your business store or handle Acutely Hazardous Matenals? . ,- ,aa OFFICE USE ONLY (""} RMPP Exempt Date Initials P"| RMPP Required Date Initials r~) RMPP Compfetec Date Initials ART III SAN DIEGO COUNTY AIR POLLUTION CONTROL DISTRICT - 1 ~-Q „ ,_ the answer to any of the question* is yes, applicant must contact the Air Pollution Control Distnct, 9150 Chesapeake Dnve, San Diego, CA 92123 elephone (619) 694-3307 pnor to the issuance of a building permit YES NO r~"| I—I Will the intended occupant install or use any of the equipment listed on the Listing of Air Pollution Control Distnct Permit Catagones. on the reverse side of this form? I—I I-""! (ANSWER ONLY IF QUESTION 1 IS YES ) Will the subject facility be located within 1.0OO feet of the outer boundary of a school IK througr 12) as listed In the current Directory of School and Community College Distnct*, published by the San Diego County Office of Education aru the current California Private School Directory, compiled in accordance with provisions of Education Cod* Section 33190? ney escrie nature of the intended business activity (L lama of Owner or Authorized Agent ' * ignature of Owner or Authonzed Agftnt 1 declare under penalty of perjury that to the best of my knowledge and belief the id correct Date :>o not write below this line IRE DEPARTMENT OCCUPANCY CLASSIFICATION W EXEMPT MOM PERMIT HtOUIHEMENT* COUNTY HMMD APCD i .•-"^r '?"••'. r*. i "-' r •'"' '-' ^rF t^iu^v APPROVED KM BUILOINO PERMIT SUT MOT OCCUP ^^^g~>EVlW QSjoSt*jflk . *i ti * * V /DATE /S. <v f.i \\ ffft / <T % %<?' ' ^0 S APCD p. aTe . Sx^wi^x T^ ^ /farvs*^ fasri4*y\ ^' GCe*^.p .-•V •> r" , < f «4 III ^'o 0 2 •o(->-t.HI -0»—tn ji.ro•o:*:rj•& oi— *y s z-> response* mad* en :n3 m SCT 85 3 ft i P•-* —i •- z*-j ^ L. UJ l>-^oi>-i_n herein are tru COUNTY OF Sftrt DIEGODEPORTMENT OFOWIRQMENTflL'.invironmeoul He*)th Service* DHS KM 9171 INDUSTRIAL WASTE DISCHARGE PERMIT APPLICATION CBNo SENo APPL NCX_ IND CLASS BUSINESS NAME £Ce"AA)S^Oe 6kft££»T\L€ CO. SITE ADDRESS "Z2. <?5> Co5Mo5 OT #Vgi66ftO CONTACT PERSON (at busmess)_ PHONE NUMBER 4*3 A "" 6 0 S j Vfe liVg^ Type of Business (check all that apply) Agricultural Assembly Automotive Chemical Handling Electronics Food Government LT Laboratory D Laundry & Manufacturing Medical Metal Work Office D Photo Lab H Retail I] Service Station Warehouse Other DESCRIBE WASTE OTHER THAN DOMESTIC (Chemicals, Particulates, etc )6>U)E DESCRIBE BUSINESS ACTIVITY GENERAL DESCRIPTION OF ONSITE WASTEWATER PROCESSING (chemical & physical characteristics INTO <>eTM.€'i/^^ TA-yoK. OvS CH^>fi.6.P TP Is business presently in operation at site' D YES $J NO Has Wastewater Discharge Permit been applied for through the Enema Water Authority' D YES @ NO Applicant's Name Title Phone Please Print Agency Signature Date Date Signature of City Representative D EXEMPT D NOT EXEMPT Date forwarded to Enema P- \DOCS\MI SFORMS\FRM00045 REV. 2/10/92 MANUFACTURERS OF KILNS AND FURNACES 2081 S HELLMAN AVE UNIT A ONTARIO, CA 91761 (909) 9472449 Septembers, 2001 City of Carlsbad Carlsbad, CA Attention Building and Safety Inspector Reference Oceanside Glasstile Gas Fire Furnaces Industrial Furnace has been commissioned by Oceanside Glasstile to do an inspection and overview of seven gas fired furnaces They are installing the furnaces at their new facility at 2293 Cosmos Ct, which fell under your jurisdiction All furnaces comply with NFPA 86 guidelines The reports of the furnace evaluations are enclosed We hope that this will satisfy the City of Carlsbad to allow Oceanside Glasstile to obtain necessary permits for operation of the furnaces we evaluated Best Regards, Craige Shaw Industrial Furnace Mfg , LLC ms cc Oceanside Glassitle Enclosures 1 MANUFACTURERS OF KILNS AND FURNACES 2081 S HELLMANAVE, UNIT A ONTARIO, CA91761 (909) 9472449 REPORT ON LARGE GLASS MELTING FURNACE This furnace incorporates three North American Model #4425-5 Fire-All natural gas burners with direct spark ignition and has a maximum input of 750,000 BTUH each The burners are set up for a maximum input of 450,000 BTUH each These burners have individual electrical spark ignition along with Factory Mutual approved flame safety system The fuel train to the burners is also configured to meet Factory Mutual requirements The furnace is positioned on the production floor and no closer than 60 inches to any combustible material The furnaces are vented to the outside via hood and stack and follow NFPA guidelines 1 0 Combustion Safeguards 1 1 Flame Safety System Protection Controls Form 6642VT three-burner flame supervision system This system is Factory Mutual and Industrial Risk Insurers approved and IJL recognized There is a 45 second purge cycle with a 15 second trial for ignition cycle 1 2 Flame Sensing Protection Controls PC-II Ultra-violet scanner to monitor the burner mam flame per NFPA 4-7 4 1, exception 2 The ultra-violet scanner is FM approved and UL recognized 1 3 Ignition The burners are spark ignited by UL interchangeable ignition transformers, issue number C-6488 1 4 Purge Volume of furnace is 80 cubic foot Airflow is 9000 CFH Purge time is 2 5 minutes, which allows 375 cubic feet of fresh air change NFPA requires 4 times the volume of the furnace in air changes before trial for ignition These furnaces have 4 7 times the volume in air changes Section 4- 3 1 1 1 5 Burner Start The mam burner is forced to start on low fire because of "forced low fire" relay logic operated by the Protection Controls flame safety system OceansideLarge Melter Page 1 of 3 MANUFACTURERS OF KILNS AND FURNACES 2 0 Fuel Gas Safety Shut-off System 2 1 Gas Safety Shut-off Valve An Eclipse Locktitc manual reset valve is incorporated along with a Dungs automatic safety valve The manual valve must be manually opened before the automatic valve will open and can only be opened if there is by-pass pilot flame present The manual valve is FM approved, report #16292 and the automatic valve is FM approved and UL listed, file #MH16727 Two valves are required per NFPA section 4-7 2 2 1 2 2 Gas Pressure Switch An Antunes high/low gas pressure switch is incorporated to monitor the gas pressure and insure it is within limits It is FM approved, serial # 19797 NFPA section 4-7 3 1 and 4-7 3 2 2 3 Combustion Air Proving An Antunes combustion air switch is incorporated to monitor the combustion air This switch is FM approved, serial # 18221 NFPA Section 4-6 2 2 4 Manual Shut-off Two manual 14 turn fuel shut-off valves are incorporated One prior to the gas safety system and one at the end of the gas safety system NFPA Section 3-3 3 1 3 0 Furnace Construction 3 1 Frame These furnaces follow traditional furnace design techniques The frame is fabricated from heavy structural steel to support the weight of the refractories and product be processed, yet have some flexibility to allow for expansion 3 2 Refractories The furnace lining is constructed of commercial firebrick, insulating firebrick, insulating castables, as well as ceramic fiber insulation Calculated cold face temperature with an internal furnace temperature of 2350 degrees F is attached 3 3 Flue At 1,350,000 BTUH input, a flue opening of 135 square inches is required Each furnace provides 180 square inches of flue opening OceansideLarge Melter Page 2 of 3 MANUFACTURERS OF KILNS AND FURNACES 2 0 Fuel Gas Safety Shut-off System 2 1 Gas Safety Shut-off Valve An Eclipse Locktite manual reset valve is incorporated along with a Dungs automatic safety valve The manual valve must be manually opened before the automatic valve will open and can only be opened if there is by-pass pilot flame present The manual valve is FM approved, report #16292 and the automatic valve is FM approved and UL listed, file #MH 16727 Two valves are required per NFPA section 4-7 2 2 1 2 2 Gas Pressure Switch An Antunes high/low gas pressure switch is incorporated to monitor the gas pressure and insure it is within limits It is FM approved, serial # 19797 NFPA section 4-7 3 1 and 4-7 3 2 2 3 Combustion Air Proving An Antunes combustion air switch is incorporated to monitor the combustion air This switch is FM approved, serial # 18221 NFPA Section 4-6 2 2 4 Manual Shut-off Two manual % turn fuel shut-off valves are incorporated One prior to the gas safety system and one at the end of the gas safety system NFPA Section 3-3 3 1 3 0 Furnace Construction 3 1 Frame These furnaces follow traditional furnace design techniques The frame is fabricated from heavy structural steel to support the weight of the refractories and product be processed, yet have some flexibility to allow for expansion 3 2 Refractories The furnace lining is constructed of commercial firebrick, insulating firebrick, insulating castables, as well as ceramic fiber insulation Calculated cold face temperature with an internal furnace temperature of 2350 degrees F is attached 3 3 Flue At 1,350,000 BTUH input, a flue opening of 135 square inches is required Each furnace provides 180 square inches of flue opening OceansideLarge Melter Page 2 of 3 MANUFACTURERS OF KILNS AND FURNACES 2081 S HELLMAN AVE UNIT A ONTARIO, CA91761 (909) 9472449 REPORT ON 1RID1ZER FURNACES These four furnaces incorporate single North American Model #4841-2 Hot Spot natural gas burners for each furnace These burners are pilot ignited and have individual electrical spark for pilot ignition along with Factory Mutual approved flame safety system The fuel tram to the burners is also configured to meet Factory Mutual requirements The furnaces are positioned on the production floor and no closer than 60 inches to any combustible material The furnaces are vented to the outside via hood and stack and follow NFPA guidelines 1 0 Combustion Safeguards 1 1 Flame Safety System Protection Controls Form 6642VB single burner flame supervision system This system is Factory Mutual and Industrial Risk Insurers approved and UL recognized There is a no purge required, as burner is open to the atmosphere and only 65,000 BTUH input 1 2 Flame Sensing Protection Controls PC-II Ultra-violet scanner to monitor the pilot flame per NFPA 4-7 4 1, exception 1 The ultra-violet scanner is FM approved and UL recognized 1 3 Ignition The burners are spark ignited by UL interchangeable ignition transformers, issue number C-6488 Oceansidelndizer Page 1 of 3 MANUFACTURERS OF KILNS AND FURNACES 2 0 Fuel Gas Safety Shut-off System 2 1 Gas Safety Shut-off Valve A Karl Dungs manual reset valve is incorporated This valve must be manually opened and can only be opened if there is pilot flame present This valve is FM approved and UL listed, File #MH 16727 2 2 Gas Pressure Switch An Antunes high/low gas pressure switch is incorporated to monitor the gas pressure and insure it is within limits It is FM approved, serial # 19797 NFPA section 4-7 3 1 and 4-7 3 2 2 3 Combustion Air Proving An Anlunes combustion air switch is incorporated to monitor the combustion air This switch is FM approved, serial # 18221 NFPA Section 4-6 2 2 4 Manual Shut-off Two manual V* turn fuel shut-off valves are incorporated One prior to the gas safety system and one at the end of the gas safety system NFPA Section 3-3 3 1 3 0 Furnace Construction 3 1 Frame These furnaces follow traditional furnace design techniques The frame is fabricated from heavy structural steel to support the weight of the refractories and product be processed, yet have some flexibility to allow for expansion 3 2 Refractories The furnace lining is constructed of commercial firebrick, insulating firebrick, insulating castables, as well as ceramic fiber insulation 3 3 Flue Furnace firing chamber is open to the atmosphere and vented outside by way of a hood and stack through the roof 3 4 Hood and Vent A large 32 inch by 84 inch hood is placed over each furnace and is vented to the outside by a 12 inch diameter stack Where the stack penetrates the roof, a 28" fire collar is installed which allows 8 inches of clearance between the stack and combustibles Sketch of the arrangement is attached NFPA 2-2 4 1 and 2-2 4 2 Oceansidelndizer Page 2 of 3 MANUFACTURERS OF KILNS AND FURNACES 3 0 Furnace Construction (Cont) 3 5 Damper N/A 3 6 Auxiliary Equipment Associated safety and control equipment is mounted far enough away to not be affected by the heat of the furnaces Adequate area is provided to allow service to such equipment NFPA 2-2 5 1 and 2-2 5 2 4 0 Combustion Make-up Air A large door opening (10 ft x 12 ft ), which has only a metal grate over it for security, allows sufficient fresh air to enter the building for combustion In summary, it is our opinion that the above-mentioned furnaces, auxiliary equipment, and installation are in accordance with applicable NFPA guidelines and standard industry practice Oceansidelndizer Page 3 of 3 MANUFACTURERS OF KILNS AND FURNACES 2081 S HELLMANAVE UN IT A ONTARIO, CA 91761 (909) 9472449 REPORT ON BOWMAN BELT FURNACE This furnace incorporates twelve Eclipse ThermAir packaged, natural gas burners with direct spark ignition and have a maximum input of 500,000 BTUH each The burners are set up for a maximum input of 250,000 BTUH each These burners have individual electrical spark ignition along with Factory Mutual approved flame safety system The fuel tram to the burners is also configured to meet Factory Mutual requirements The furnace is positioned on the production floor and no closer than 60 inches to any combustible material The furnaces are vented to the outside via hood and stack and follow NFPA guidelines 1 0 Combustion Safeguards 1 1 Flame Safety System Eclipse single burner Model 5600 flame supervision system are incorporated in each burner These systems are Factory Mutual and Industrial Risk Insurers approved and UL recognized 1 2 Flame Sensing Eclipse flame rods are used to monitor the burner main flame per NFPA 4-741, exception 2 1 3 Ignition The burners are spark ignited by UL interchangeable ignition transformers, issue number C-6488 1 4 Purge Purging is incorporated by the large recirculating fans (24) on the furnace All fans must be on before the ignition sequence can start Only two burners at a time are allowed to go through trial for ignition 1 5 Burner Start The mam burner is forced to start on low fire because of "forced low fire" relay logic operated by the Eclipse flame safety system OceansideLehr Page 1 of 3 MANUFACTURERS OF KILNS AND FURNACES 2 0 Fuel Gas Safety Shut-off System 2 1 Gas Safety Shut-off Valve A dual valve Landis&Staefa Model SKP-191-U17 manual reset valve is incorporated along with individual solenoid valves at each individual Eclipse packaged burner The manual valves may be manually opened if there is a c control power present, correct gas pressure present, and all valves proven closed The manual dual safety valve is FM/7400 approved and UL/249 listed Two valves are required per NFPA section 4-7 2 2 1 2 2 Gas Pressure Switch An Antunes high/low gas pressure switch is incorporated to monitor the gas pressure and insure it is within limits It is FM approved, serial # 19797 NFPA section 4-7 3 1 and 4-7 3 2 2 3 Combustion Air Proving An Antunes combustion air switch is incorporated to monitor the combustion air This switch is FM approved, serial # 18221 NFPA Section 4-6 2 2 4 Manual Shut-off Two manual 1A turn fuel shut-off valves are incorporated One prior to the gas safety system and one at the end of the gas safety system NFPA Section 3-331 3 0 Furnace Construction 3 1 Frame These furnaces follow traditional furnace design techniques The frame is fabricated from heavy structural steel and sheet steel 3 2 Insulation The furnace insulation is high temperature (1500 degree) non- flammable insulation encased in sheet steel on the exterior and interior 3 3 Auxiliary Equipment Associated safety and control equipment is wall mounted and far enough away to not be affected by the heat of the furnaces Adequate area is provided to allow service to such equipment NFPA 2-2 5 1 and 2-2 5 2 4 0 Combustion Make-up Air A large door opening (10ft x 12 ft ), which has only a metal grate over it for security, allows sufficient fresh air to enter the building for combustion OceansideLehr Page 2 of 3 MANUFACTURERS OF KILNS AND FURNACES 5 0 Venting 5 1 Hood Hoods are over the entrance and exit of the furnace and are vented outside through stacks that penetrate the roof The stacks have fire collars that provide 8" of clearance between the stack and combustibles in the roof In summary, it is our opinion that the above-mentioned furnaces, auxiliary equipment, and installation are in accordance with applicable NFPA guidelines and standard industry practice OceansideLehr Page 3 of 3 86-22 OVENS AND FURNACES 2226 All parts of equipment operating at elevated tern peratures shall be installed in accordance with 2 1 5 2227 Where impractical to guard, warning signs or per maneni floor markings shall be provided or mounted so as to be visible to personnel entering the area NOTE 1 Exterior of furnaces in excess of 160°F (71°C) should be guarded by location guard rails shields or msu lation to prevent accidental contact with personnel NOTK 2 Bursting discs or panels mixer openings or other pans of the furnace from which flame or hot gases may be discharged should be located or guarded to prevent injury to personnel 2228 Properly located observation ports shall be provided to permit the operator to observe the lighting of individual burners Exception Where observation ports are not practical other means of verifying lighting of individual burners shall be provided 2229 Closed water cooling systems shall have relief valves to protect all portions of the cooling system when its pres- sure may exceed the design pressure In addition, waterflow devices with audible/visual alarms shall be furnished NOTE Open cooling systems utilizing unrestricted sight drains installed for ready observation by the operator do not require relief valves waterflow devices etc 22210 Fuel fired heaters shall not be located directly under the product being heated where combustible mate rials may drop and accumulate Neither shall they be located directly over readily ignitible materials such as cotton unless for a controlled exposure period as in continuous processes where further automatic provisions and/or arrangements of guard baffles preclude the possibility of ignition 22211 The metal frames of furnaces shall in all cases be electrically grounded (See NFPA 77 Recommended Practice on Static Electricity ) 2-2 3 Explosion Vents 2-2 3 1 Furnaces that may contain flammable liquids, vapors, or gases shall be equipped with unobstructed relief vents for freely relieving internal explosion pressures (For additional information regarding relief of equipment and buildings housing the equipment, see NFPA 68, Guide for Venting of Deflagrations ) Exception No 1 Explosion relief panels are not required on fur- naces having the following characteristics shell construction hav- ing 3/i6 m (4 8-mm) or heavier steel plate shells reinforced with structural steel beams and buekstays, which support and retain refrac- tory and insulating materials required for temperature endurance and thus are unsuitable for the installation therein of effective explo- sion vents Exception No 2 Explosion relief panels are not required for low- oxygen atmosphere ovens designed and protected in accordance with Chapter 6 2-2 3 2 Explosion relief panels shall be proportioned in the ratio of their area to the explosion containing volume of the furnace with due allowance being made for openings or hinged panels or access doors equipped with approved explosion-relieving hardware The preferred ratio is 1 15 ic 1 sq ft (00929 m") of relief panel area to every 15 cu ft (0 4248 m3) of furnace volume 2233 Arrangement of Explosion Vents 22331 Explosion venting panels or doors shall be arranged so that, when open, the full vent opening will be an effective relief area The operation of relief vents to their full capacity shall not be obstructed by low ceilings piping building columns or walls instrument panels or other equip ment NO I'E 1 These veins should be provided in the form of work openings doors or panels located in the oven walls or gravity retained roof panels designed to provide adequate insulation and possess the necessary structural strength NOTE 2 Guard rails may be needed to prevent movable equipment from obstructing wall vents If guard rails are impractical warning signs should be posted on the vents NOTES Explosion relief vents where possible should be placed in the top of the furnace or in side walls and located so that employees will not be exposed to injury NOTE 4 Maximum weight per panel allowed by NFPA 68 I Guide for Venting of Deflagrations is 2'/2 Ibs/sq ft (12 2 g/m") for an oven structure rated at 1 psig NOTE 5 Where practical, an explosion relief vent should be placed close to a source of ignition (see NFPA 68 Guide for Ventmg of Deflagrations) 2-2 332 Explosion relief vents for a long furnace shall be reasonably distributed throughout the entire furnace length | 2-2 4 Ductwork 2-2 4 1 Whenever furnace ducts or stacks pass through com bustible walls, floors, or roofs, noncornbustible insulation or clearance or both shall be provided to prevent surface tern peratures exceeding 160°F (71°C) 2-2 4 2 Ducts shall be constructed entirely of sheet steel or other noncombustible material, shall be of adequate strength and rigidity to meet the conditions of service and installation requirements, and shall be protected where subject to phys teal damage 2-2 4 3 No rooms or portions of the building shall be used as an integral part of the system NOTE The entire duct system should be self contained 2-2 44 All ducts shall be made tight throughout and shall have no openings other than those required for the oper- ation and maintenance of the system 2-2 45 All ducts shall be thoroughly braced where requited and substantially supported by metal hangers or brackets 1990 Edition HEATING SYSTEMS 86-23 u NOTE AJI laps in the duct (onus should be made in the direction of the flow 2246 Where ducts pass through noncornbustible walls floors or partitions the space around the duct shall be sealed with noncombusuble material to prevent the passage of flame and smoke NOTE The passing of ducts through fire walls should be a\oided 2247 Ducts handling fumes that leave a combustible deposit shall be provided with cleanout doors Such ducts shall be constructed of not less than 16 gauge steel or equiv alent 2-2 4 8 Hand holes for damper sprinkler, or fusible link inspection or resetting and for purposes of residue cleanout shall be equipped with tight fitting doors or covers provided with substantial latches except in the case of vertical sliding doors held in place by gravity 2249 Dampers in the ducts that affect the volume of fresh air admitted to and vapors or gases exhausted from the fur nace shall be designed so that, when in closed position, they will pass the volume required for safe ventilation If electri- cally or mechanically controlled dampers are used, limit switches shall be utilized to assure proper position of the dampers including those used as gas barriers on carbon diox- ide extinguishing systems 2-2 4 10 The furnace and its location shall be designed to prevent excessive emission of objectionable fumes into the building 22411 AJI exposed hot fan casings and hot ducts within 7 ft (2 1 m) of the building floor shall be protected to pre \ent injury to personnel [temperature not to exceed 160°F (71°C)] Refer to 2 2 2 7 22412 Exhaust ducts shall not discharge near doors, win- dows or other air intakes in a manner that will permit re- entry of effluents into the building NOTE All air inlets outside the furnace should be protected by coarse screens and so guarded that they cannot be obstructed 22413 A suitable collecting and venting system for the | radiant tube type heating systems shall be provided The sys- tem shall be of sufficient capacity to render the total unburned input capacity of the radiant tubes noncombus tible NOTE For additional information pertaining to furnace due twork reference is made to NFPA 54 National Fuel Gas Code NFPA 91 Standard for the Installation of Blower and Exhaust Sys terns for Dust Stuck ami Vapor Removal or Conveying and NFPA 211 Standard for Chimneys fireplaces Vents and Solid. Fuel Burn ing Appliances 2-2 5 Access, Mountings, and Auxiliary Equipment 2-2 5 1 Adequate facilities for access shall be provided to per mit proper inspection and maintenance Facilities shall include motion stops or lockout devices for vertical and/oi horizon tal movement of doors elevators or transfer mechanisms to minimize accidental movement 2252 Mountings for auxiliary equipment shall provide tor mounting of control instruments and safety devices to pro tect against damage by heat, vibration, and mechanical equip ment 2-2 5 3 Where ladders or steps are needed to reach oper atmg valves or other controls, they shall be noncombustible and provided as an integral part of the equipment 2-2 5 4 Auxiliary equipment such as conveyors, racks shelves, baskets, and hangers shall be noncombustible and designed to facilitate cleaning 2-2 55 All external moving parts within 7 ft (2 1 m) of a working platform shall be guarded from mechanical accidents or possibilities of causing personal injury •if 2-2 6 Hydraulic Systems utilize fire-resistant fluids Furnace hydraulic systems shall Exception Other hydraulic fluids can be used if furnace casing temperatures are below the autoignition temperature of the fluid NOTE Drawings for fluid power diagrams should follow ANSI Standards Y14 17 and Y32 10 227 Building Make-Up Air A sufficient quantity of make- up air shall be admitted to oven rooms and buildings to pro- vide the air volume required for safe operation of oven ventilation and combustion air fans Chapter 3 Heating Systems |31 Scope For the purpose of this standard the term fur- nace and associated equipment heating system shall include the heating source (and associated piping/wiring) used to heat the furnace and the work therein as well as for auxiliary quenches atmosphere generator etc 3 2 Electrical Wiring All electrical wiring and applicable electrical components shall be in accordance with NFPA 70, National Electrical Code, and as described hereafter I | 3-3 Fuel Gas Fired Units 331 General | 3-3 1 1 This section includes combustion systems for fur naces and associated equipment fired with commercially dis tnbuted fuel gases such as natural, mixed manufactured, liquefied petroleum gas (LPG) in the vapor phase arid LPG/air systems, and the gas-burning portions of dual fuel or combination burners 3-3 1 2 Additional safety considerations that are beyond the scope of this standard shall be given to dirt laden gases sulfur-laden gases, high hydrogen gases, and low-Btu waste gases where used 1990 Edition 86-24 OVENS AND FURNACES 332 Burner System Selection Burners along with asso ciated mixing valving and safety controls and other auxil lary components shall be properly selected for the intended application suitable for the type and pressure of the fuel gases to be used, and suitable for the temperatures to which they will be subjected 333 User's Fuel Gas Supply Piping 3-3 3 1 Emergency shutoff valves shall be provided to per rnit turning off the fuel in an emergency and shall be located so that fires and explosions, at furnaces will not prevent access to these valves lion The terminating end shall be protected against water entry and bug screened Vent pipe shall be of adequate size so as to not lengthen response time Exception Regulators need not be vented when used with hghter- than-air fuel gases at 1 psig (6 9 kPa) inlet pressure or less pro- vided that the vent connection contains a restricted orifice and disc/targes into a space large enough, or is ventilated well enough so that the gases escaping will not present a hazard 3-3433 Vent lines from multiple regulators, where man- ifolded together shall be piped in such a manner that dia- phragm rupture of one will not backload the others NOTE 1 Installation of LPG storage and handling systems should comply with NFPA 58 Standard far the Storage and Han dling of Liquefied Petroleum Gases NOTE 2 Piping from the point of delivery to the equipment isolation valve should comply with NFPA 54 National Fttel Gas Code 334 Equipment Fuel Gas Piping 3341 Manual Shutoff Valves and Cocks 33411 Individual manual shutoff valves (isolation) shall be provided for shutoff of the fuel to each piece of equip- ment 3-3 412 Valves and cocks shall be maintained in accordance with the manufacturer s instructions NOTE 1 Particular attention is directed to the need for a proper lubrication of lubricated plug cocks NOTE 2 Quarter turn valves are recommended 3-3 413 It shall be the user s responsibility to see that sep- arate wrenches (handles) remain affixed to the valve and that they are properly oriented with respect to the valve port 3-3 4 2 Equipment piping (gas train piping) is defined as the piping that connects isolation valve equipment to the air gas mixing device (or to the burner if nozzle mixing) 3-3 421 Material Material for pipe and fittings shall com- ply with NFPA 54, National Fuel Gas Code 3-3 422 Sizing Pipe fittings and valving equipment shall be sized to prevent excessive pressure losses at the maximum rate of flow 3-3 4 3 Pressure Regulator 3-3 431 A pressure regulator shall be furnished wherever the plant supply pressure exceeds that required for proper burner operation or whenever the plant supply pressure is subject to excessive fluctuations 3-3 432 Regulators shall be vented to a safe location where vented gas cannot reenter the building without extreme dilu 3-3 434 Vents from fuel gas pressure switches but no other devices, may be vented into the fuel regulator vent lines pro- vided that switch or regulator diaphragm failure shall not backload the regulator Exception Fuel gas regulators and zero governors may be back- loaded from combustion air lines, air-gas mixture lines and com bustion chambers, provided that gas escapement through the restricted vent opening will in itself, create no additional liazard This excep tion shall not apply to oxygen-enriched air 3-3 5 Gas Burners 3351 All burners shall maintain stability of the designed flame shape, with neither flashback nor blow off over the entire range of turndown that will be encountered during I operation when supplied with combustion air (oxygen I enriched air or oxygen) and the designed fuels in the proper proportions and in the proper pressure ranges NOTE 1 Burner operation may be adversely affected when other than the designed fuels are used NOTE 2 Attention should be paid to the burner tile main tenarice in order to maintain the designed flame stability 3-3 5 2 Multiple-Port Burners Line , ribbon , pipe ring , radiant-, and diaphragm-type burners shall comply with the provisions of 3-3 5 1 In addition they shall maintain sta bihty of the designed flame shape throughout their entire connected length and/or area under the designed operating conditions 3-3 5 3 Burner Ignition Burners shall have the ignition source located in a position that will permit smooth and reli able ignition of the pilot/main flame over the complete sta ble firing range provided for in 3-3 5 1 3-3 531 Burners having expanding pilots that are an mte gral part of the main burner flame shall have a reliable and smooth transition from pilot flame to mam flame and from mam flame to pilot flame when increasing and decreasing burner firing rates 3-3 532 For burners that cannot be safely ignited at all fir mg rates encountered, positive provision shall be made to reduce the burner firing rates during light off to a level that will assure a smooth and reliable ignition of the mam flame (forced low fire start.) 1990 Edition 86-32 OVENS AND FURNACKS 4-13 It shall also be noted that (a) The presence of safety equipment on an installation cannot in itself assure absolute safety of operation (b) There is no substitute for a diligent capable, well trained operator (c) Highly repetitive operational cycling of any safety device may reduce its life span (d) Electric relays and fuel safety shutoff valves are not sub- stitutes for main shutoff cocks (valves) and disconnects 414 Regularly scheduled inspection and maintenance of all safety devices shall be performed by the user (See Chap ter9) 4-141 It shall be the sole responsibility of the user to estab- lish schedule and enforce the frequency of and the extent of the inspection/maintenance program (as well as the cor- rective action to be taken) because only the user can know what the actual operating conditions are 4-1 42 It shall be the responsibility of the equipment man- ufacturer to provide suitable recommendations and/or sug gestions on maintenance and inspection procedures 4-1 5 Safety devices shall be properly installed, used, and maintained in accordance with the manufacturer s instruc tions 4-1 6 Safety devices shall be located to protect against phys- ical damage and inadvertent tampering 4-1 7 Safety devices shall not be shorted-out, nor shall they be bypassed 4-2 Programmable Controllers 4-2 1 When a programmable controller is used, the follow ing requirements shall apply (a) In the event of a power failure, the programmable con- troller (hardware and software) shall not prevent the system from reverting to a safe condition A safe condition shall be maintained upon the restoration of power (b) The control system shall have a separate manual emer gency switch independent of the programmable controller, that will cause the system to revert to a safe condition (c) The software for the programmable controller shall reside in some form of nonvolatile storage (memory that retains information on loss of system power) (d) The programmable controller shall have the capabil- ity of detecting failures and unprogrammed logic changes of its safety dependent inputs and outputs and, upon detec- tion of same, shall annunciate and cause the system to revert to a safe condition (e) Application software that contains safety logic shall be separate from all other programming Application software that interacts with safety logic or detection logic for input/output devices shall also be separate from all other pro- gramming Application software that contains safety logic or detection logic shall not be modified in any manner that does not comply with this standard The authority having juris diction shall be notified in writing for permanent documen tation of any changes (f) System operation shall be verified for compliance with this standard whenever the programmable controller is replaced, repaired or updated (g) The internal status of the programmable controller shall be monitored In the event of a programmable control ler failure the system shall annunciate and cause the system to revert to a safe condition (h) The supplier of the application software for the pro grammable controller shall provide the end user and the authority having jurisdiction with documentation needed to verify that all related safety devices and safety logic are func- tional before the programmable controller is placed in oper ation (i) The system access shall be limited by incorporating mea- sures to prevent remote or local instructions to the program mable controller that could result in hazards to personnel or equipment (j) Only approved programmable controller-based systems meeting the above requirements shall be used to control the equipment as listed under 4-11 NOTE Other programmable controller based systems may be used only to monitor 4-2 2 When a programmable controller is used in conjunc- tion with the combustion safety circuitry, the following addi tional requirements shall apply (a) Failures that create a hazard shall cause the system to revert to a safe condition (b) Combustion safety interlocks, combustion safeguards, and excess temperature limits shall be wired to directly de energize the safety shutoff valves and their operation shall result in a safe system condition Exception Programmable controller based systems listed for com justion safeguard service may be directly applied NOTE Programmable controllers not listed for combustion safeguard service may be used only to monitor equipment except that isolated programmable controller contacts (not directly connected to a power source) may be wired in series with the above safety circuits 4-3 Preignition (Prepurge, Purging Cycle) 4-3 1 Prior to each furnace startup provision shall be made for the removal of flammable vapors and/or gases that may have entered during the shutdown period 4-3 11 At least 4 standard cu ft (0 11 m3) of fresh air per cu ft (m3) of oven volume shall be introduced during the purging cycle Exception Inert-atmosphere ovens may be purged with an inert gas (see Chapter 6) 4312 Timed preigmtion purge shall be provided on all furnaces in which flammable vapors or fuel can accumulate duung a shutdown period ; 4-3 1 3 The timed preigmtion purge cycle shall be repeated .-'^j after each and every shutdown of the recirculating and/or J exhaust fans '•'•'' 1990 Edition SAFETY EQUIPMENT AND APPLICATION 86-33 Exception Repeating the timed preigmtion purge cycle is not required after each and every shutdown such as might be occasioned by a momentary or short duration stoppage and may be omitted pro vided all of the following items are satisfied (a) Burners and pilots are supervised by an combustion safe- guard m accordance with 464 (b) Each burner system is equipped with gas safety shutoff valves m accordance with 4622 (c) It can be demonstrated that 25 percent of the lower explo- sive limit will not be exceeded during Ike time air-supply stoppage is permitted 4-3 1 4 Preigmuon purging of radiant-tube heating systems is not required however, special conditions may require purg- ing of the furnace work chamber 4-3 2 A natural draft purge shall be permissible when no combustion air blower or exhaust blower is available, pro- vided all of the following conditions are satisfied (a) A furnace door or cover is secured in the fully-open position to admit air, and the flue damper (if any) is secured fully open to vent air or other atmosphere from the furnace These conditions prevail from start to end of the preigmtion purge and light off processes (b) The open positions of the door or cover and damper (if any) is verified at all times Closing of either causes an alarm, prevents ignition, and requires repurge (c) The purge interval is timed and is long enough to reli- ably reduce the flammable vapor or gas concentration in the combustion chamber to 25 percent or less of the lower explo- sive limit of the fuel in air and less than 21 volume percent oxygen (d) The purge time required to ventilate the combustion chamber as prescribed in item (c), has been measured using combustible gas analyzers and oxygen analyzers by the party , responsible for commissioning the burner system This mea- surement has been conducted at a time when the furnace is at normal ambient temperature Confirming calculations and measurement data are available for review at the request of the authority having jurisdiction 4-4 Flue Product Venting A suitable collecting and vent- ing system for the radiant-tube type heating systems shall be | provided The system shall be of sufficient capacity to ren- der the total unburned input capacity of the radiant tubes noncombustible 4-4 1 The flue-venting products system shall be considered as part of the plant exhaust system 4-5 Ventilation Safety Devices 4-5 1 Whenever any fan is essential to the operation of the oven and/or allied equipment, fan operation shall be proven and interlocked as indicated m 4 5 1 1 and 4-5 1 2 4511 Electrical interlocks and flow switches shall be arranged in the safety control circuit so that loss of ventila- tion or airflow will immediately shut down the heating sys- tem of the particular oven section affected or if necessary, loss of ventilation shall shut down the entire oven heating system as well as the conveyor 4-5 1 2 Air pressure switches and air suction switches shall not be used to prove airflow when dampers can be closed to the point of reducing flow to an unsafe operating level 4-5 2 Air pressure switches shall not be installed on the pres sure side of a fan handling air contaminated with any sub stance that might condense or otherwise deposit and interfere with the switches, sensing, or performance 4-5 3 Adjustable or motorized dampers capable of being moved to a position that might contribute to or result in an unsafe condition shall be equipped with mechanical stops cut-away dampers and/or limit switches interlocked into the safety circuitry to assure that dampers are in a proper oper- a^ing position 4 6 Combustion Air Safety Devices (Fuel Fired Units) 461 When the air from the exhaust and/or recirculatmg fans is required for combustion of the fuel, airflow shall be proven prior to ignition attempt and reduction of airflow to I an unsafe level shall result in closure of the safety shutoff valve 4-6 2 When a combustion air blower is used, the minimum combustion air pressure required for proper burner oper- ation shall be proven prior to each attempt for ignition as indicated 4-621 cuitry Motor starter shall be interlocked in the safety cir- 4-6 22 A low-pressure switch shall be used to sense and monitor combustion air pressure or differential pressure and shall be interlocked into the safety circuitry 4-6 3 Whenever it is possible for combustion air pressure to exceed a maximum safe operating pressure as might occur when compressed air is utilized, a pressure reducing valve, high pressure switch and a low pressure switch shall be used 4-7 Fuel Safety Devices 4-7 1 General 4711 As with all safety devices, improper application and/or adjustment can result in repeated and unscheduled shutdowns Improper corrective action (bypassing, jumpenng- out, etc) can lead to a hazardous condition, and shall not be taken to sustain production 4-7 12 A manual reset feature shall be provided to prevent unintentional recycling of the safety system or any portion of it 472 Safety Shutoff Valves (Fuel Gas or Oil) 1990 Edition 86-34 OVENS AND FURNACES 4721 General 47211 The safety shutoff valve shall be the key unit of all safety controls used to protect against the explosion or fire hazards that could result from accidental interruption to var- ious services or operations, such as flame failure failure of fuel pressure failure of combustion air pressure failure of exhaust or recirculation fans excessive temperatures or power failure 47212 Safety shutoff valves shall automatically shut off the fuel to the burner system after interruption of the hold ing medium by any one of the interlocking safety devices They shall be self closing and not readily bypassed or blocked open Safety shutoff valves shall not be used as modulating temperature control valves Exception No 1 Installations requiring a valve 8 m (200 mm) IPS or larger mat employ such safety shutoff valves as a dual-purpose valve namely a temperature control valve Exception No 2 Particulate matter or corrosive materials may impair the. operation of the valve For example, coke oven gas ser ince may employ such a safety shutoff valve as a dual-purpose valve for temperature and/or pressure control 4-7 213 Valve components shall be of a material suitable for the fuel handled and the ambient temperature 4-7 214 Valves shall not be subjected to pressures in excess of manufacturer s ratings 472141 If normal inlet pressure to the fuel pressure reg ulator immediately upstream from the valve exceeds the valve s pressure rating, a relief valve shall be provided and shall be vented to a safe location 4-7 215 Position indication shall be provided for safety shutoff valves to mam burners in excess of 150 000 Btu/hr (44 kW) 47216 Safety shutoff valves shall not be used in lieu of manual cocks/valves when shutting down 4-7 2 2 Fuel Gas Safety Shutoff Valves 4-7 221 When mam or pilot fuel gas burner system capac n> exceeds 400 000 Btu/hr (117 kW), two safety shutoff valves (piped in series) shall be used If main or pilot fuel gas burner capacity is 400 000 Btu/hr (117 kW) or less, a single safety shutoff valve may be used in place of the double safety shutoff valves Exception With a radiant tube fired burner system a single safety shutoff valve mat be used 47222 A permanent and ready means for making tight- ness checks of all mam burner fuel gas safety shutoff valves shall be provided (see Chapter 9, Inspection and Maintenance) 4723 Oil Safety Shutoff Valves | 4-7 2 3 1 A safety shutoff valve or valves shall be provided for shutting off fuel oil to the burner or burners being pro- tected NOTE Two safety shutofT valves should be provided under any one of the following conditions (a) when the pressure is greater than 125 psi (862 kPa) (b) whenever the fuel oil pump opeiates without main oil burner firing regardless of the pres sure (t) with combination gas/oil burners when the fuel oil pump operates during the fuel gas burner operation 473 Fuel Pressure Switches (Gas or Oil) 4-7 31 A low-pressure switch shall be provided for and interlocked with, each burner system s safety shutoff valve 4-7 3 2 Whenever the normal fuel pressure to the pressure regulator immediately upstream from the safety shutoff valve exceeds the design limits of the burner system a high pressure switch shall be provided and interlocked with the burner system s safety shutoff valve, as in 4 7 3 1 4-7 3 3 Pressure switch settings shall be made in accordance with design limits of the burner system and/or the heating unit 4-7 4 Combustion Safeguards (Flame Supervision) 4-7 4 1 Each burner flame shall be supervised by a combus- tion safeguard, having a nominal flame response timing of 4 seconds or less, interlocked with the safety circuitry Exception No 1 It is permissible to supervise flames at the inter section oftlie mam burner flame and the pilot flame rather than pro vide supervision equipment for both Exception No 2 Neither interrupted pilot nor second flame sen sor are required for self-piloted burners as defined in Section 1-4 Exception No 3 Supervision of the main burner flame may be accomplished by either a second sensor applied to the mam flame only or by interruption of the mam burner ignition pilot Exception No 4 Multiple burners, where combustion safeguards for each burner are too numerous to be practical can use contm uous line-burner-type pilots for groups of burners (see 3352) A combustion safeguard shall be provided at the far end of each line burner-type pilot, away from the pilot fuel source with sensing ele >nent located at the junction of the flame paths of both pilot and last main burner The. pilot safety shutoff valve must be initially opened by a manual momentary push button Exception No 5 Where two premtx burners which will reliably gmte one from the other, are used it shall be permissible to use a ingle approved combustion safeguard supervising one ofthe burn, ers, the supervised burner shall bum continuously at a firing rate at all times sufficient to reliably ignite the unsupervised burner Exception No 6 Burners for direct fired healing systems that sup <ly a furnace at a fuel rate not exceeding 150,000 Btu/hr 44 kW) may be equipped with heat-actuated combustion safeguards >r safety pilots For small equipment under constant attendance, approaching in size the household gas range or very small labora ory test furnace, combustion safeguards may be omitted subject to pproval of the authority having jurisdiction 1990 Edition State of California CONTRACTORS STATE LICENSE BOARD ACTIVE LICENSE License Numoef42 I 785 En"1'/ INDIV Buwness Name MULLEN CONSTRUCTION Cia,s,l,ca,,o,,lS) B NIC E,p«a..o..0al. 04/30/2002 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 J> CONSOLIDATE!. FIREPROTECTIO* INC 6108 Avenida Enemas Suite A Carlsbad, CA 92009 (760) 431-9901 Fax (760) 431-9923 V -OS?CP^ CALIFORNIA 641U4 ARUOXA W1VS COLORADO 249 XEY.WA 40282 AW MEXICO 14261 OKUHOMA SS2 UTAH WMSt 55111 WASIIISGWS COMiOt'llli2J7 Technical Opinion & Report Prepared for Oceanside Glassfile 2293 Cosmos Ct Carlsbad, CA 92009 For Submittal to. Carlsbad Fire Department Fire Prevention Bureau 1635 Faraday Avenue Carlsbad, California 92008 C&it I I I I I I I I I I April 13,2001 wF^Ct Mr Mike Smith, Fire Marshal \m. %JFm m Carlsbad Fire Department, Fire Prevention Bureau CONSOLIDATED 1635 Faraday Avenue FIREPROTECTION Carlsbad, California 92008 INC. 6108 A venida Enemas Suite A Carlsbad, CA 92009 (760) 431-9901 Fax (760) 431-9923 CALIFORNIA 641S34 A8/ZO,\'.4 99m COLORADO 249 NEVADA 402K NEW MEXICO 34261 OKLAHOMA 582 UTAH 2936S6-S501 WASHISGTON CONSOFIOS2J7 RE Oceanside Glasstile Technical Report Dear Mr Smith The following technical opinion and report is written on behalf of Oceanside Glasstile Company at the direction of Mr Don Pettey, Principal The report will address minimum requirements for the processes, storage, handling and use of hazardous materials, raw materials and finished goods utilized in the manufacture of mosaic tile This owner/occupant is currently conducting the same business at their existing location at 3235 Tyler Street Carlsbad, CA 92008 The new location will be an owner occupied building, located 2293 Cosmos Ct , Carlsbad, CA 92009 This report will include the following • Classify all products stored and/or used within the building « Review storage of all goods and products and related protection requirements • Chemical analysis and hazardous materials inventory statement (HMtS) • Review of hazardous materials storage, use and quantity limitations in accordance with applicable codes • Present an analysis of the design, operation and use of the building, including heat- producing equipment such as ovens, furnaces and kilns • Results of analysis of stack emissions testing for furnaces at the existing facility • Copies of HazMat Permit and AQMD Certificate of Exemption • Report on gas-fired equipment by Industrial Furnace Corp for the Kiln manufactured by owner • Heat producing equipment catalog cut sheets • Outline general safety procedures for occupant safety and building protection Code Analysis/Technical References: The following applicable codes were used for this evaluation • 1997 California Fire Code • 1997 California Building Code • National Fire Protection Association Standard 13 - Standard for the Installation of Sprinkler Systems, 1999 edition. I I I I I I I I I I I I I I I I I I I fCFf CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 2 Building Construction, Occupancy Classification and Fire Protection- Building, Type of Construction Building Area Analysis 1st Floor 2nd Floor Total Building Area Offices - Manufacturing - Warehouse - Total - IFF N Fully Spnnklered 41,341 sqft. 5.931 soft 47,272 sqft. 11,267 sqft 11,129 sqft 24,875 sqft. 47,272 sqft. Occupancy Classification Offices Glass Products Manufacturing Glass Products Storage Ceiling Height Ceiling Level Sprinkler Density B F-2 S-2 27ft max 45 gpm/3000 sqft General Overview* Oceanside Glasstile manufactures and distributes glass, mosaic and ceramic tile for use m kitchens, bathrooms, etc The tiles are manufactured using re-cycled bottle glass, with chemical additives for color The mixture is fired in one of three gas-fired furnaces and baked m a self-contained kiln described below All items used, stored and distributed (recycled bottle glass, sand, misc powder additives for color and related mastics and mortars) are used in the manufacture or installation of glass tiles Product packaging includes a two-part liquid spray foam m place filler Manufacturing Processes & Machinery: All raw materials used in glass tile making are powdered chemicals or silica sand stored and mixed in the Batch Room Storage is in 50 Ib and 100 Ib bags in pallet quantities The open storage is in plastic drums (500 Ib quantities) or 12" x 18" x 24" plastic tubs (5 Ib - 100 Ib quantities) All open use containers have lids The chemicals are measured m 250 Ib - 300 Ib quantities into steel mixing drums with one quart water (for dust control) and tumbled on side, on rollers The mixed batches are transferred into paper bags (40 Ib capacity) for charging All mixing and bagging takes place in the Batch Room The closed bags of batch are transported to the furnaces in pallet quantities for charging The batch is charged, bag and all, into one of the furnaces to melt the glass, eliminating dust in the furnace area. fCFf CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 3 The melted glass is dumped into pattern forms then loaded into the kiln by hand The tiles exit the kiln in a cooled state where workers score the tiles and break them into individual tiles, boxed and stored for distribution The batch mixing workers are issued proper protective gear and trained to handle and dispose of hazardous materials, which are collected in a polyethylene lined gaylord pallet container and picked up by a licensed disposal company Blast Furnaces: 3 gas-fired 3,000 Ib units constructed of bnck and mortar operating at 2,450 degrees F, used to fire glass tiles Units are provided with automatic gas shut-off valves, which operate within 1/10* of one second following any loss of electrical power Each blast furnace is provided with a fixed exhaust stack, vented through the roof to the atmosphere Exhaust gases measured at 400 degrees F at stack discharge, 600 degrees F within the stack (See attached report on emissions testing by Horizon Air Measurement Services, Inc, dated 2/7/01) Kiln the self-contained annealing lehr kiln is manufactured by E W Bowman Corp The process requires heating and cooling the product within the confines of the oven This unit does not require an exhaust Special Notes. 1 Oceanside Glasstile has received a Certificate of Exemption from the San Diego County Air Pollution Control District #975087 (attached) for their current location, which is transferable to the new location 2 Oceanside Glasstile has a San Diego Regional Hazardous Materials Permit &H39080 (attached) which is also transferable to the new site Hazardous Materials: Allowable Exempt Amounts Aggregate quantities of materials for storage are identified in the following Hazardous Materials Inventory Statement and the Comparative Summary of Hazardous Materials to Exempt Amounts per the Building Code Tables 3-D and 3-E and Fire Code Table 8802 3-A (attached) For the purpose of this report, the entire building shall be considered as one control area. I I I TCFI CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 4 Hazardous Materials Inventory Statement (HMIS) per Area Sample Room Product Tile Mate Thin Set Mortar Hydroment Flex-a-Lastic Flexible Mortar Additive 33SC Sihcone Sealant, Clear Shur-StikC-11 Water Based Glue -Wall Covering Adhesive Form Powder in 50 Ib bags Liquid Paste Clear Translucent Paste Quantity Stored or Used 500 Ibs 55 gal 24 tubes 200 gal in 2 qt containers Quantity Allowed per Control Area CFC Table 7902 5-A N/A N/A N/A N/A CFC Classification or Comments Irritant (Portland cement) Dust No specific Fire Hazard Irritant Dust No specific Fire Hazard Irritant Dust No Specific Fire Hazard Local Exhaust or General Ventilation Recommended Non-Flammable Normal ventilation is adequate no respirator)' protection required I I I CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) PageS Packing & Shipping Area Product fnstnfill Component A (two-part foam-in place packaging materials) Install!], Component B & Instafill Slow Rise Component B Holster/Instapack Solvent Form Liquid Clear, Straw Colored Liquid Clear Liquid Quantity Stored or Used 210 gal 210 gal 10 gal Quantity AUawedper Control Area CFC NL NL NL CFC Classification and Comments Irritant to skin and respiratory system Water reactive if hot Other Health Hazards III- B Combustible Liquid (Flash Pomt = 390 deg.F) User must wear rubber gloves, safety goggles and respirator if ventilation is not adequate Irntant ID- B Combustible Liquid (Flash Point = 390 degF) Other Health Hazards Contain all spills Irntant III- B Combustible Liquid (Flash Point = 232 deg F) Use eye protection, rubber gloves & ventilation when m use Per UFC Table 7902 5-A (note 5), Class III-B Liquids are not limited (NL) within spnnklered buildings Note the Instafill fill system is a closed, self-contained unit, which dispenses a two- part expansive foam packing material into polyethylene bags for a form fitting packing material The unit is provided and serviced by an outside vendor Storage of Parts A & B are m 55 gallon drums, stored m the warehouse on special plastic tub style pallets provided by the manufacturer to contain any possible spills I I I I I I I I 7CFI CONSOLIDATED FIREPROTECTION INC. en "s go co O • a NIOSH Recommendations or CommentKs•« 65 •Q « •Sa >sJ &} Bl t^s aQJ ^S St. §, 'g "9 S %<5)<>; 1 ProductPrevent Eye Contact, Prevent Skin ContactWash Skin when ContactWear Protective ClothingiOQt-r*DustImtantOther Health r_« w-l<N en £ OO 1 O_ U Cobalt Carbonatera 3 Wear protective clothing, gloves protective eveweand ventilator if area not provided with ventilationIrntating fumes when burned Environmental Hazwhen released to air, land or water*** User produces no waste product***1 §•s sofc oi— i C 3 C3Q U cn 0O«o en o0 " " ~- S S fc" *W) ill! •s"!o *o5 3 c Fluorespar, CalciurCalcium difluonde,-— j ^4 Spay application is within a vented hood, with misexhausted through roof ventUsers should wear protective clothing, gloves,protective eyevvear and ventilator if area not provicwith ventilation1s;C3 •S y S« !T!"ti OT H^ | g| ^^ •n "caon>/^ ll c en an •2 J-S §•00 fga" 2 "3 r»Ferric Chloride SoliHexahydrate (IioiIn waterDisposal in approved chemical landfill duo toHydrochloric Acid contentWear protective clothing, gloves, protective eyeweand ventilator if area not provided with ventilationen 1N .lit! Q J3 U 0 O en.£ £ O op O O II o 1o ", a Nickelous CarbonaiMetallic SaltDispose of waste in approv ed landfillg s5 o Dust ImtantSuspected Carien.Q 00 en £ 8cs se O "o p , ^J Iron ChromiteWear protective clothing, gloves, protective eyewe1 VI Q ap en £ 1 1 Csia > O 0 Chomium OxideRisk of serious damage to central nervous system iprolonged inhalation (2 years)1 rr-1 Dust Irritant,Other Health r.CO O JQ O —" C3S !?o -5OH U enC C ^-s Metallic Oxide (CoManganese dioxide TCFI CONSOLIDATED FIREPROTECTION INC. §y, u •O 1cd IO J^nmendatwns or Commen,1 S 5i^ 5 %1 §•C 1•e| §8b8 s-l "Si ff Q ^ £' 11&$ I Productt-a lothing, gloves, protective eyewe1 breathing apparatusWear protective cand self contained5T3 o" !9. •">•° g^ 1>n> ^.- 1 1O KJ U EC Dust Irritant,Other HealthS <o en O "" IT.2 Q- 4?Selenium DioxiiCS image to lungslothing, gloves, protective eyeweted areasRisk of serious daWear protective cand use in \entilal„ a«EC ""cd a EC §> S3 |a CJ u"Dust Irritant,Toxic, Oxidi;en-0 *o .0 o 0J _Powder (wcry stall rne^(U Antimony Oxid2 (3 >-<lothing, gloves, protective eyewevoid breathing dust RiskofhazaWear protective cand respirator Alungs1ta Dust IrritantOther HealthJ 0o VI o t^l en ill c O 3o3 Stannous Chlonj-ji issues with chronic exposure onRisk of inhalationc !> en § 1 a au a:Dust Irritant,Other Health£oo10 o §5 1 'S"o 0s c33S CSU U •3i- c13 o lothing, gloves, protective eyewei not wear contact lenses Ingesticause acute poisoning or deathWear protective cand respirator DCfluoride salts can i(S It 103 •8 1 B^ EC (Hydrogen Flexposed to fitDust Imtant,Other Health£ O ^2 rs g §£ fe~3 0 t/3 ^ i LH wO o.3 .a a u C -HS "o Potassium Alun(Potassium Crv<lolhing, eye protection, glovesWear protective cDust ImtantJo010 0 °.J r— H •HO "n Granular P(white in aIa c3 lotlung, gloves, protective eyeweted areasWear protective cand use m \entilalT31 1Q, •£3«>_ C/l 1 £Dust kntantOther Healthexposure)=2 0o o § JSr-l ""GranualarSoda Ash: mask &. eye protectionWear gloves, dustDust IrritantJ3 oo<r' en-0 O8oo ^. 'ou«"^5 ti It aIi 1 c y lolhing, dust mask, eye protectioiwith clean shovel wash down aiWear protective cClean up all spillswith waterDust Imtant,Oxidizer 1£o 0 VI en oOM-i m 5 Sodium Nitrateb ^ J-contact with skin, wear cartridge, eye protection and protectivereathing fumes Pick up spills wr\i area with waterAvoid prolonged irespirator, gloves,clothing Avoid biclean shovel, was!cn1CSEC Dust IrritantToxic fumesOther HealthMoo 1—4 Jg ^s-i-_- o ^S^?E en ?3 O £' ?Zmc Oxide CONSOLIDATED FIREPROTECTION INC. co O oo J3 (U S^O p* 5*^s NIOSH Recommendations or Comis. 3 toS3•i* X2 « 55 | ^^ ^Sr\ (^ LJ V^-r ^ ^3 "3 i^^ g* *^ Q 5 1| 5 ^ t5 1 J, "•^j Q 2en O.Avoid prolonged contact with soft tissue, eyecause blindness Use in ventilated area, wearclothing, eye protection, gloves'a S E +jVIa Js o0 enjQ 1 J-a — " B "o ^ 13 *3 OS a s Z3 ms Wear protective clotlung, eve protection, glo'ventilated area Avoid prolonged contact1 E1—1 O in Xa^ Mo en OO S!_•§ ^^ s£'b o 1U 01 U S OC/l3 VIo!>Wear protective clothing, eye protection, glo1ventilated area Avoid prolonged contact1 E C/l3 en !£) CM tn 8 1? •f •§>• oo_ tg "3t/2 1t/3 iglish and Spanish languages^ iCi ^1JS*H «s; "1 ^ 1 | ^51 ill be posted immediai^ •SS*S?llowing sign^1 ) change daily, dispose of suits in£ en A B ~ 0aB ^^aE £ 75 O™"irotectivea». R workers must we;te container daily,i ^ 2 !All batchhazardou.e eyewear..2i 2a 75u 1M O T» B tf) 0 O 75) to B 0 tff •o z oz •o0 aaB B i .oft tissue. Wash hands often.•oc B 0>. 0 ff3to £ '§ 0B ** OU 7 73 B £•o B W3•o "5c0 75 c •g O . m o B tti £ B 0 ^^O (0 i Im £ M i ^ 0 £ • •Iff contact. a to £*;z £ O> io o B+* M skin, use shower**i• •If contact, •CO al attentiu€wallowed, see me(A k O TJ » 0at .i all water and spilled chemicals, do no^ B COu„ 1 tn55•« 0 O (ft C B 0 73 £ 1 a B ® O =ato Report allsweep.• I I I I I I I I I I I I I I I I I I I TCFI CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 9 Allowable Exempt amounts Aggregate quantities of materials for use are identified by hazard class m the following Summary of Hazardous Materials to Exempt Amounts per the Building and Fire Code Tables 3-D, 8001 15-C and 8001 15-D Exempt Amounts of Hazardous Materials in Use in a Control Area- CFC Classification Corrosives Irritants Sensitix-ers Other Health Hazards Toxics Carcinogens Oxidizers 1 Amount in Open Use mbs 5 gal 4 000 Ibs 350 gal 0 3,500 Ibs 300 gal 125 Ibs (1 0 Ibs) * 1,1 10 Ibs 505 Ibs Allowable open use perCBC&CFC 2,000 Ibs 100 gal 10,000 Ibs 500 gal 10,000 Ibs 10,000 Ibs 500 gal 250 Ibs (2 5 Ibs)* 5 000 Ibs 1000 Ibs Amount in Storage 150 Ibs 25 gal 92,950 Ibs 455 gal 0 54,150 Ibs 445 gal 800 Ibs (2 libs)* 20 000 Ibs 4,000 Ibs Allowable Stored per CBC & CFC 10,000 Ibs 500 gal NL 1,000 gal NL NL 1,000 gal 1,000 Ibs (500 Ibs) * 20 000 Ibs 4,000 Ibs * Per UFC Table 8001 15-D for gallons of liquids, divide the amount in Ibs by 10 calculations reflect the weight of liquids stored or used under Toxic category Exempt quantities have been increased as allowed for spnnklered buildings Hazardous Materials Handling and Use. All chemicals are stored and used in accordance with the respective manufacturer's written recommendations and procedures Employees exposed to dust and fumes shall be provided with protective clothing, protective rubber gloves, protective eyewear and appropriate dust masks and/or respirators Showers and eye wash units shall be located within the Batch Room for use in emergency exposure cases Protective paper over-suites are provided for workers within the Batch Room Soiled suits are deposited in the Hazardous Waste disposal bin after each shift I I I I I I I I I I I I I I I I I I I TCFI CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 10 Secondary Containment: Per CFC, Article 80, section 8003 1 3 3 - Secondary containment is required per Table 8003 1-A (attached) for the Toxics and Oxidizers plus the volume of sprinkler system water for 20 minutes This will be accomplished with an 8"dyke or berm constructed of water tight materials within the Batch Room. The floor will be epoxy coated and sealed with an 8" tile cove base Volume of chemicals (toxics & oxidizers) = 4,100 Ibs powder + 21 gal liquid Volume of fire sprinkler discharge = 45 gpm x 2,244 sqft = 1,010 gpm x 20 minutes = 20,200 gallons Storage of Materials: Finished goods and packaging materials will be stored within the building's warehouse in storage racks to 20 ft with 8 ft aisles Storage Array. Aisles Height of Storage Type of Racks Commodity Class Ceiling Height >8ft 20 ft max Single and Double Row I 27ft Fire Protection Per NFPA 13, 1999 edition, Figure 7-4221 (a) (attached) the prescribed density for non-encapsulated Class I commodities stored in racks to 20 ft with 286 deg F sprinklers and 8 ft aisles is 0 26 gpm/3,000 sq ft The existing fire sprinkler system was installed by Action Fire Systems, Fullerton, CA and is designed for 0 45gpm per sqft over the most demanding 3,000 sqft of floor area Steel columns located within the storage racks are required to be protected in accordance with NFPA 13, Section 7-9 8 (attached) The tenant shall be required to add column sprinkler protection with sidewall sprinklers located 15 ft above the floor where steel columns are located with the rack storage area General Fire Protection and Life Safety Requirements: The rack storage area will be in accordance with CFC Article 81, Section 8102 including the following • Automatic Fire Extinguishing System • Building Access • Smoke and Heat Removal • Small Hose Valves and Stations I I I I I I I I I I I I I I I I I I I CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 11 Smoke and Heat Removal/Curtain Boards Pursuant to Carlsbad Fire Department Policy and based on foil scale fire testing performed by Factory Mutual Laboratories, we request permission to omit draft curtain boards m this warehouse facility Small Hose Connections: Small hose connections are required per section 7-4 1 6 Per Carlsbad Fire Department Policy, it is requested that the hose, nozzle and rack requirements be waived It is not recommended that employees attempt to fight a fire with 1 Vz inch hose lines in high pile stock areas The request to omit fire hose is based on the following points • The fire department carries hose packets and generally do not use building equipment • Employees are generally instructed not to use this equipment and to evacuate the building in case of fire • Maintenance of this equipment is difficult and therefore the integrity of lie hose cannot be counted on. • This building is fully protected with a fire sprinkler system with a design density greater than the minimum required for the use • Fire extinguishers are provided for incipient fires General Safety Practices ^ No smoking will be permitted in the building v' All employees will receive special training on the use of portable fire extinguishers of the type to be provided in this building An evacuation plan will be in place S Exit doors will be maintained unobstructed and will be opened weekly to ensure their operation S Employees will be trained to handle small spills and cleanup of hazardous materials used or stored within the facility The Fire Department shall be notified of any and all hazmat spills and/or fires contained and cleaned up by employees v' The following signage will be posted immediately outside and witnm the Batch Room, in English and Spanish languages • All batch room workers must wear protective clothing changed daily; dispose of suits in hazardous waste container daily. • Wear approved NIOSH dust filter mask, gloves and chemical protective eyewear. • Avoid inhalation of dust and fume. Avoid contact with skin, eyes and soft tissue. Wash hands often. • If contact with eyes, wash for 15 minutes @ eyewash station. • If contact with skin, use shower station. Wash thoroughly with soap. • If ingested or swallowed, seek medical attention. 1 Report ail spills. Clean up with clean shovel, wash with water, contain all water and spilled chemicals, do not sweep I I I I I I I I TCFI CONSOLIDATED FIREPROTECTION INC. Oceanside Glasstile (Cont) Page 12 Hydrants/Access Roadways: Hydrants and fire department access roadways will continue to be maintained unobstructed and accessible to emergency response crews Exiting/Egress: The basic layout of the building is in conformance with the 1997 CBC The travel distance from any point in the building to an exit does not exceed 250 feet All exit doors are at least three feet wide and proper exit signs over each door will be provided Fire extinguishers: Minimum 2A10BC rated fire extinguishers shall be provided for every 50 feet of travel distance Conclusion/Recommendations Our opinion is based solely upon our review of the proposed storage arrangements and hazardous materials storage or use as disclosed to the writer. Per the UFC, it is the Owner's responsibility to determine material quantities within the building and report them to the Authority Having Jurisdiction. Any deviation from the descriptions provided or additional chemicals or fiammables not disclosed will render this report invalid Based upon the information provided and the recommendations contained in this report, it is our opinion that Oceanside Glasstile will be in full compliance with the requirements of the CBC and CFC 1997 editions If you have any comments or questions regarding this report or the proposed use of this facility, please do not hesitate to contact the undersigned or the owner directly Respectfully submitted, Robert© Caputo President Attachments OCEANSIDE GLASSTILE-2293 COSMOS CT PROJECT PROJECT DESCRIPTION Oceanside Glasstile proposes to install process machinery necessary for the manufacture of glass tile The installation consists of 1 Two 3000 Ib capacity glass melting furnaces 2 Four indizing machines with two exhaust blowers 3 One E W Bowman glass annealing lehr (kiln) 4 Three roof mounted air-circulating blowers One incoming fresh air and two exhaust blowers The Bowman annealing kiln will be installed and test run by the manufacturer The furnaces and indizing machines are built by Oceanside Glasstile The furnaces are built on site with rated flame safety components and the iridizers are of proprietary design, also with complete flame safety components Included is a cover letter from Industrial Furnace outlining their proposal to field certify the glass machinery and related venting The roof-mounted blowers will be inspected by the City Industrial Furnace MANUFACTCJRf-RS OF KILMS AND FCIRNACFS 2081 5 HELLMAM AVE, UNIT A ONTARIO, CA 91761 (909)9472449 January 25, 2001 City oi Carlsbad Carlsbad, CA Attention Building and Safety Inspector Reference Occanside Glasstile gas filed equipment Industrial Furnace has. been commissioned by Oceansidc Glasstile to do a letio-fit inspection and overview of their gas fired equipment the wish to move from their current location to their new location inside the city limits of Carlsbad The current equipment was inspected by us upon the ongmal installation at the present location m Carlsbad There will be a new pieces of equipment at the new facility along with the existing equipment All equipment will be inspected for NFPA 86 guidelines on fuel fired equipment The electrical will be inspected using NfcC guidelines Thepiclmiinary report of the new equipment will follow shortly and will detail the correct equipment configuration and suppoited by Ml PA , LTI-, or AGA documentation or issue numbeis We hope this will be a satisfactory procedure to allow Oceansidc Gla^stile to move forward and obtain the necessary permits horn the City of Carls,bdd Ciaige Stiaw Tndusuial Furnace cc Occanside Glasstile Oceanside City Building and Safety Oceanside, CA I I/ I I I I I I I I I I I I I I I I I Industrial Furnace MAMU FA CTURERS OF KILNS AND FURMA CES 2O81 5 HELLMAH AVE UNIT A OMTARIO CA 91761 (7]4) 9472449 Attention Building and Safety Inspector Industrial Furnace has been commissioned by Oce<.nside Glasstile to do an inspection and overview of their gas fired glass melting furnace located at 614 S Cleveland St , Oceanside, CA We are therefor submitting our report to you with a copy to Don Petty, of Oceanside Glasstile, to assist him in obtaining permits from the City of Oceanside for the above mentioned furnace The furnace incorporates a single Eclipse, Model No 54 NM, burner with a maximum input of 360,000 BTUH The burner is equipped with a pilot burner for main flame ignition The pilot fuel regulator is cross connected to the combustion air supply to maintain proper fuel/air in the event of combustion air fluctuations. Furnace is outside of the building and no closer than 60 inches to a combustible material gas safety system is in accordance with NFPA 86, equipment is as follows Flame supervision Ovens and Furnaces and The 1 0 COMBUSTION SAFEGUARDS 1 1 Flame Safety System 1 2 Flame Sensing 1 3 Ignition Protection Controls Form 6642 single burner Protectofier FM and IRI approved and UL recognized 30 second prepurge with a 15 second ignition trial Protection Controls PC-II Ultra- Violet scanner to monitor the intersection of the pilot and main flame per NFPA 4-7 4 1, exception 1 Scanner is FM approved and UL listed Spark ignited by a Dongan UL inter- changeable ignition transformer Issue Number C-6488 1 0 Industrial Furnace MA M(JFA CTORERS OF KILNS A HD FURVA CES COMBUSTION SAFEGUARDSCCom. ) 1 4 Purge 1 5 Main Burner1 Volume of furnace is 7 5 cubic foot Combustion air flow is 3,600 CFH Purge time is 30 seconds and will allow 30 CF of fresh air change NFPA requires 4 limes volume of furnace, or 30 CF Section 4-3 I I The main buiner is forced to start ignition on low fire because of an interlock between the manually reset safety shutoff valve and the air butterfly actuator 2 0 FUEL GAS SAFETY SHUTOFF SYSTEM FM Type main gas train 2 1 Safety Shutoff 2 2 Pressure Switch 2 3 Air Proving 2 4 Manual Shutoff An Eclipse Locktite manual reset valve is incorporated Only one valve is required because the total BTUH is under 400,000 NFPA section 4-7 2. 2 1 Valve is FM approved, report # 16292 An Antunes high/low gas pressure switch is incorporated It is FM Approved, serial # 19797 NFPA section 4-7 3 1 and 4-7 3 2 An Antunes minimum air pressure switch is incorporated in the combustion air line It is FM Approved, serial # 18221 NFPA Section 4-6 2 A manual 1/4 turn fuel shutoff valve is provided near the gas meter and accessable in the event of a furnace fire NFPA section 3-3 3.1 I I I I I I I I I I Industrial Furnace MANUFACTURERS OF KILNS AND FURNACES 3 0 FURNACE CONSTRUCTION 3 1 Frame The frame follows traditional furnace design techniques Extremely rigid to to support the weight of the refractories and the product being processed, yet flexible enough to allow for the expansion of the refractories 3 2 Refractories: 3 3 Flue The furnace lining is constructed of commercial firebrick, insulating fire- brick, castables, as well as ceramic fiber insulation Calculated cold face temperatures with 2350 F internal temperatures are attached Attached heat shields will reduce the external temperature even more At 360,000 BTUH input, required flue area is 36 square inches (1 sq in per 10,000 BTU input) Adequate area is provided with 64 square inches on this furnace 3 4 Vent 3 5 Damper 3 6 Auxiliary Equipment• Vent pipe is completely exposed and does not penetrate combustable material nor is it close to any combustable material Vent pipe is secured firmly to furnace and building structure NFPA 2-2 4 1 and 2-2 4 2 Flue damper is pinned so that it may not be closed beyond minimum area for proper and safe ventilation (36 sq in ) NFPA 2-2 4 9 Associated safety and control equip- ment is mounted near the furnace and under a roofed area for protection from the elements Equipment mounted near the furnace is protected from heat by means of a sheet metal heat shield Adequate area is provided to allow service to such equipment. NFPA 2-2 5 1 and 2-2 5 2 I Industrial Furnace • MANUFACTURERS OF KILNS AND FURNACES Best Regards, Craige Shaw Industrial Furnace I In summary, it is our opinion that the above mentioned furnace, auxiliary equipment, and installation is in accordance with applicable I NFPA guidelines and standard industry practices ™ Our last installation involved a 500 cubic foot, 120 cubic foot, and a • 100 cubic foot kiln in the City of Santa Ana The largest kiln had a BTUH | input of 4,000,000 BTUH It was a test case for Santa Ana and set precedence for future installations in that City Industrial Furnace • designed and installed the control panels, gas safety systems, and flame I supervision systems for the above mentioned equipment Mr Petty was employed by the Company we did this for and was very much involved with the process and gained considerable knowledge of safety systems and I standard practices He has put this knowledge to practical use with the • furnace he has constructed in Oceanside I I I COCK «. WXL.4.-UX „, 3 M£>UL_rtT IMG I-" K O JD U C T fc» Jt> I V A £> I V £ O J O HI OF McDERMOT T XNC. STCADi SfAll- HEAT FLOW ANALYSIS/FC VERSION CONDITIONS : ROOF ATFIQSFHEKE s STANDARD AMBIENT TEMI-- 8M tMlSOIVl F'i "s B.^S 'CLOCIll s la I-PS I I I I 1 PRODUCT THICK. 4.00 IN KAOLITE L&M BABCOCK * WIL.COX HF 2358 F 4.00 IN KWL BLKT 8« HF BABCOCK & WILCOX IF1 1785 F COLD FACE 223 F. HEAT LOSS 330 BTU/SF/HR. HEAT STORAGE 16010 BTU/SF 4BCQCK S- W J. L_iL,O>. » INSULATING , RROI>UCTS 1> X V tk L/I VI U I Of-il Or ll€_l>E.RMO"l I*"' "CMC . STEhiiV 'jl'iiL ilCttf i-LUW ANALYSIS/PC VERSION CONDITIOMS . WALL ATHUSFHERE : STANDARD AMBIENTMEHF- 80 EMISSIUITf : 0.95 VLLOCIir : Pi FFB iT. PRODUCT PRODUCT IDE THICK. NAME MANUFACTURER 01 7.00 IN B&U 80 F6 KAbCQCK * WJLCOX HF 2o5B F J 3.B0 IN KWL BLKT 84) Hf BABCOCK & WILCOX IFi 209J F COLD FACE 285 I-. HEAT LOSS b&7 BTU/SF/HR. HEAT STORAGE 4o348 BTU/SF K & W X I_L- U. X , IHSULAT X NG F'KOJDUC, f 5r> JD 3. V A OX VI .£-> it,i-l 01- llcJDELRIMO I T ZMO. STEADY Si,,!,. HEAT FLOW AHALtGIS/l C VCRS1QN CONDITIONS . WALL AMBIENT TEMfs 80 I I FRUDUi/i NAME : SIANOAFlD LMISSlVITr : 0.95 ' PRODUCT IIAHUfACTURER VELOCI1V 7.1 IN B&U 80 FB 2.50IN K-26 Li ffb BAfaCOCK 3c WILCOX BABCOGK * WILCOX COLD FACE HEAT LOSS HEAT STORAGE Hi-550 F IF! 1844 F Ei FF& 483 F. BTU/SF/HP. BFU/SF 2-26-O1 8 34AM 858 650 4bbU I i UL. CONTROL NO.189845 COUNTY OP SAN DIEGO, AIR POLLUTION CONTROL DISTRICT 9150 CHESAPEAKE DRIVE, SAN DIEGO, CA 92123-1096 (858)650-4700 FAX (858) 650-4659 CERTIFICATE OF EXEMPTION CERTIFICATE 975087 EXPIRES EXEMPT THE FOLLOWING IS HEREBY SRANTED AN EXEMPTION FROM PERMIT REQUIREMENTS PURSUAHT TO RULE 11 (d) (19) (XVIII) FOR THE ARTICLE,MACHINE,EQUIPMENT OR CONTRIVANCE DESCRIBE? S^OW THIS CERTIFICATE IS NOT TRANSFERABLE TO A NEW OWNER NOR IS IT VALID FOR OPERATION OF THE Eaul*MENT*v,T ANOTHER LOCATION EXCEPT AS SPECIFIED THIS CERTIFICATE OF EXEMPTION OR A COPY MUST BE POSTED ON OR WITHIN 25 FEET OF THE EXEMPT EO.UTPMENT/PROCESS OR BE READILY AVAILABLE ON THE OPERATING PREMISES OCEANSIDB GLASSTILE CO VP PETTEY DON 3235 TYLER ST CARLSBAD CA 92008-0000 EQUIPMENT ADDRESS OCEANSIDE GLASSTILE CO 3235 TYLER ST CARLSBAD, CA 92008-0000 I I I I I I I I I I I EQUIPMENT DBSCRIPTION DECORATIVE AND ORNAMENTAL GLASS TILE MANUFACTURING OPERATION USING THREE GLASS MELTING FURNACES AND ONE ANNEALING OVEN Sector* 15 ID# 07267A P0# 975087 BEC# 10614 Fee Schedules COEOl EVERY PERSON WHO OWNS OR OPERATES THIS EQUIPMENT IS REQUIRED TO COMPLY WITH THE CONDITIONS LISTED BELOW AND ALL APPLICABLE REQUIREMENTS AND DISTRICT RULES, INCLUDING BUT NOT LIMITED TO RULES 2, 10, 11, 40, 50, 51, 67 17 TO OPERATE IN THE EQUIPMENT SHALL BE OPERATED ACCORDING TO THE MANUFACTURER'S INSTRUC- TIONS/RECOMMENDATIONS AND AS DESCRIBED IN THE CERTIFICATE OP EXEMPTION APPLICATION SUBMITTED TO THE DISTRICT THIS CERTIFICATE OF EXEMPTION SHALL ONLY APPLY TO THE EQUIPMENT DESCRIBED ABOVE THE DISTRICT RESERVES THE RIGHT TO CHANGE THE EXEMPTION STATUS OF THE ABOVE EQUIPMENT/PROCESS AT ANY TIME THE FACILITY WILL BE NOTIFIED AT LEAST 30 DAYS IN ADVANCE OF ANY CHANGES WHICH MAY AFFECT THE EXEMPTION STATUS OF THE ABOVE EQUIPMENT/PROCESS THIS CERTIFICATE OF EXEMPTION MUST BE MAINTAINED WITH THE EXEMPT EQUIP- MENT/PROCESS OR BE READILY AVAILABLE AT ALL TIMES THIS AIR POLLUTION CONTROL DISTRICT CERTIFICATE OF EXEMPTION DOES NOT RELIEVE THE HOLDER FROM OBTAINING PERMITS OR AUTHORIZATION REQUIRED BY OTHSR GOVERNMENTAL AGENCIES OR FROM COMPLYING WITH APPLICABLE DISTRICT RULES AND REGULATIONS, STATE AND FEDERAL LAW I azardous Material. I • lanagement Division SAN DIEGO REGIONAL ,i r HAZARDOUS MATERIAtS-QUESTIONNAIRE CtlSTT 8usm«ss Name Contact Person I I I I I Telephone Mailing Address City State Zip Plan File* ST. Site Address City SUM Zip Plan File* cry. ART I FIRE DEPARTMENT • HAZARDOUS MATERIALS MANAGEMENT DIVISION. OCCUPANCY CLASSIFICATION dicata by circling the item, whether your business will use, process, or store any of ths following hazardous materials If any or the items are rcled applicant must contact the Fire Protection Agency with jurisdiction pner to plan submmal Explosive or Blasting Agents 4 Flammable Solids Compressed Gases 5 Organic Peroxides Flammable or Combustible Liquids 6 Owdizers 7 Pyrophorlce 10 Cryogenics 8 Unstable Reactive* 11 Highly Toxic or Toxic Materials 9 Water Reaotivae 12 Radtoactives 13 Corrosive* 14 Other Health Hazards ART II COUNTY OF SAN DIEGO HEALTH DEPARTMENT HAZARDOUS MATERIALS MANAGEMENT DIVISION ONTINGENCY PLAN REVIEW. the answer to eny of the question* ie ye*, applicant must contact the County of Sen Diego Hazardous Matenel* Management ivision, 1 255 Impenel Avenue, 3rd Floor, San Diego, CA 92186-5261 Telephone (619) 338-2222 prior to the issuance of a uildmg permit EES MAY K REQUIRED Is your business listed on the reverse side of this form? ~~\ [P j7-ji Will your business dispose of Hazardous Substance* or Medicel Waste in sny amount? u ',,-.., Will your business stors or handle Hazardous Substances in quantities equsl to or greater than 55 gallon* 500 pounds, 200 cubic feat or carcinogens/reproductive toxins in any quantity? r*"*1 Will your business use an existing or install an underground storage tank? I—I Will your business store or handle Acutely Hazardous Matenals? , fS ta . j OFFICE USE ONLY [""] RMPP Exempt Dete Initials |""| RMPP Required Dete Initials f"| RMPP Compietec Date Initials I I I I I ART III SAN DIEGO COUNTY AIR POLLUTION CONTROL DISTRICT ^1J:C»C ' tha answer to any of the questions is yes, applicant must contact the Air Pollution Control Distnct, 9150 Chesapeake Drive, San Diego. CA 92123 elephone (619) 694-3307 pnor to the issuanca of a building permit YES NO |"*"1 Will the intended occupant Install or use any of the equipment beted on the Listing of Air Pollution Control Dietnct Permit Categories on the reverse side of this form? f""l (ANSWER ONLY IF QUESTION 1 IS YES ) Will the subject facility be located within 1.0OO feet of the outer boundary of a school (K through 12) as listed in the current Directory of School and Community Collage Distnct*, published by the San Diego County Office of Education ant the current California Private School Directory, compiled In accordance with provieiona of Education Code Section 33190? 'nelly dasTlnKTialuTe^rtEeTnTeTBeTEsTnTssTc^ "^™~~^™~™~^~ H lame of Owner or Authonzed Agent 'ignatura of Owner or Authonzed Agent I declare under penalty of perjury that to the best of my knowledge and belief the responaea made herein ere tru <nd correct _ Date ~)o not write below this line IRE DEPARTMENT OCCUPANCY CLASSIFICATION EXEMPT FROM PERMIT HEQUNUMENTS COUNTY-HMMD APCD APPBOVB) fOK IMtDIHO PERMIT iUT NOT OCCUP, 5pviroom«uJ Health Service* DHS HM-9171 I I U IN J. £_ U I I I I I IN IIL Fax I I I To. Don Pettey | Of: Oceanside Glass Tile • Fax. (760) 434-0590 Phone. ((760) 434-005 1 x 1 06 I Pages 1 1, including this cover sheet • Date February 7, 2001 I I Don _ Please find attatched draft results of emissions testing conducted at yor facility on I January 1 4, 2001 I have sent a copy to Bill Powers These lesults are subject to a final review before becoming final I Please call me at (805) 498-8781 if you have any questons • Robert Carrier I I I I I I ff m From the desk of Honzon Air Measurement Services, Incorporated 996 Lawrence Dive Suite 108 Newbury Park California 93021 (805) 498-8781 Fax (805)498-8781 lt-MN.Le-lt/11 III— II^JUI T^U OX TABLE 1 Stack Gas Characteristics and Emission Rates Furnace #2 Oceanside Glass Run Number Date Run Start Time Run End Time Stack Gas Characteristics Stack Temperature Moisture Fixed Gases, CO2 02 N2 Stack Velocity Volumetric Flowrate Volumetric Flowrate Isolonelic Ratio Total Particulate Emissions Concentration Concentration PmlO Emission Rate Hydrogen Chloride Emissions Concentration Emission Rate Hydi ogen Flounde Emissions Concentration Emission Rate ****** ****** ****** ****** F % % % % afpin dsct'm acfm % gr/dscf g/dscf Ib/hr mg/dscf Ib/hr mg/dscf Ib/hr 1 01/14/01 1110 1213 268 17 00 209 791 803 2809 3878 94 OOH9 0 000938 0335 < 0 000002 < < 0 000001 < 5378 1998 2 01/14/01 1340 1440 282 26 00 209 79 1 739 2512 3566 96 00136 0000918 0293 0 000002 0 000001 6899 2293 3 01/14/01 1730 1830 295 35 00 209 791 711 2353 3432 96 00136 0000882 0275 < 0 000003 < 0000001 53^3 1660 Average 282 26 00 209 79 I 751 755S 3625 96 00137 0000912 0301 < 0000002 < 0000001 5870 1984 Horizon Air Measurement Services, Inc M5 421EMITBL F2 0 J. «JO , TABLE 2 Stack Gas Characteristics and Emission Rates Furnace #3 Oceanside Glass Run IN umber Date Run Start Time Run End Time Stack Gas Characteristics Stack Temperature Moisture Fixed Gases, CO2 02 N2 Stack Velocity Volumetric Flowrate Volumetric Flowrate Isokinebc Ratio Total Participate Emissions Concentration Concentration PmlO Emission Rate Hydrogen Chloride Emissions Concentration Emission Rate Hydrogen Flounde Emissions Concentration Emission Rate ****** ****** ****** ****** F % % % % afprn dsotm actm % gr/dsct g/dscf Ib/hr mg/dscf Ib/hr mg/dscf Ib/hr 1 01/14/01 1115 1221 285 19 00 209 791 737 251? 3556 99 0 00073 0 000049 0016 < 0000002 < < 0000001 < 07179 02386 2 01/14/01 1255 1430 291 21 00 209 791 735 2482 3546 100 0 00923 0 000623 0 196 0 000002 0 00000 1 1 111 03648 3 01/14/01 1715 1820 288 33 00 209 79 1 688 2304 3321 105 00142 0 000922 0281 < 0 000002 < 0000001 04579 0 1395 Average 288 24 00 209 791 720 2433 3474 101 00081 0000531 0164 < 0000002 < 0000001 07624 02477 Horuon Air Measurement Services, Inc M5_421EMITBL F3 I J. IN I 11 TABLE 3 Stack Gas Charactenstics-Particulate Emissions Furnace #4 Oceanside Glass "ft* Run Number Date Run Start Time Run End Time Stack Gas Characteristics Stack Temperature Moisture Fixed Gases, CO2 O2 N2 Stack Velocity Volumetric Flowrate Volumetric Flowrale Isokmetic Ratio Total Parnculate Emissions Concentration Concentration PmlO Emission Rate Hydrogen Chloride Emissions Concentration Emission Rate Hydrogen Flounde Emissions Concentration Emission Rate ****** ****** ****** ****** F % % % % atpm dscfrn acfm % gr/dscf g/dscf Ib/hr mg/dscf Ib/hr mg/dscf )b/hr 1 01/14/01 1100 1208 296 1 5 00 209 791 659 2224 3183 99 00246 000166 0468 < 0 000003 < < 0 000001 < 1013 2981 2 01/14/01 1255 1400 293 3 1 00 209 79 I 678 2260 3273 99 00261 000176 0505 0 000003 000000 1 8217 2456 3 01/14/01 1645 1755 282 32 00 209 791 658 2222 3178 101 00293 000190 0557 < 0 000003 < 0000001 7402 2175 Average 290 26 00 209 791 665 2235 1211 100 00266 000177 0510 < 0000003 < 0000001 8584 2537 Horizon Air Measurement Services Inc MS 421EMITBLF4 I I I I I I I I I I I I I I I I I I I I I kJ IN ± £- U I I I I J. IN IH_IIO«JINI_III_I TABLE 4 Stack Gas Charactenstics-Particulate Emissions Ambient- Roof Vent Oceanside Glass Run Number Date Run Start Time Run End Time Stack Gas Characteristics Moisture Fixed Gases, CO2 02 N2 Hydrogen Chloride Emissions Concentration Hydrogen Flourtde Emissions Concentration ****** ****** ****** ****** % % % % 1 01/14/01 1154 1259 10 00 209 791 2 01/14/01 1332 1432 13 00 209 791 3 01/14/01 1630 1730 15 00 209 791 Average 13 00 209 791 mg/dscf < 0000002 < 0000002 < 0000002 < 0000002 mg/dhcf 01362 01412 00920 01231 Horizon Air Measurement Services Inc M5.421EMITBL AM I I u IN j. e. u i I X IN I ll_ I IO Ul r- u SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL AVG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H DGMCALIB FACTOR [Y] WATER COLLECTED CO 2 02 CO CH4 N2 STACK AREA STATIC PRESSURE PITOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULARWTORY EXCESS AIR MOLECULAR WT WET STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOWRATE DRY STD VOLUMETRIC FLOWRATE ACTUAL ISOKINETIC RATIO ****** ****** ••""" ****** Degrees F Inches H20 Inches Inches HG Minutes Cubic Feet Degrees F Inches H20 ****** Milhliters Percent Percent Percent Percent Percent Square Inches Inches WG ****** DSCF SCF Percent ****** Ib/lb Mole Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 1 1/14/01 1110 1213 268 02039 0495 3040 60 43499 67 168 09900 16 00 209 791 6951 001 084 4400 08 17 098 2884 118750 2865 3040 803 2809 3878 94 Furnace 2 2 1/14/01 1340 1440 282 01855 0495 3040 60 39963 70 138 09900 23 00 209 791 6951 001 084 4021 11 26 097 2384 118750 2855 3040 739 2512 3566 96 3 1/14/01 1730 1830 295 01766 0495 3040 60 37315 68 125 09900 29 00 209 791 6951 001 084 3767 14 35 096 2884 118750 2846 3040 711 2353 3432 96 STD TEMP 68 CALCULATIONS FOR GRAIN LOADING AND EMISSION RATES TOTAL PARTICULATE PARTICULATE CONCENTRATION PARTICULATE EMISSION RATE mg gr/dscf Ib/hr 397 00139 0335 355 00136 0293 333 00136 0275 HYDROGEN CHLORIDE mg < 00001 < 00001 < 00001 HYDROGEN CHLORIDE CONCENTRATION mg/dscf < 0000002 < 0000002 < 0000003 HYDROGEN CHLORIDE EMISSION RATE Ib/hr < 0000001 < 0000001 < 0000001 HYDROGEN FLOURIDE mg HYDROGEN FLOURIDE CONCENTRATION mg/dscf HYDROGEN FLOURIDE EMISSION RATE Ib/hr .£366 5378 1998 2774 6899 2293 2009 5333 1660 Horizon Air Measurement Services, Inc M5_421EMITBL F2 iv A e. u i i I"- ' 4s* SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL AVG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H DGM CALIB FACTOR [Y] WATER COLLECTED CO 2 02 CO CH4 N2 STACK AREA STATIC PRESSURE P1TOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULAR WT DRY EXCESS AIR MOLECULAR WT WET STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOWRATE DRY STD VOLUMETRIC FLOWRATE, ACTUAL ISOKINETIC RATIO STD TEMP *"•" ****** ****** ****** Degrees F Inches H20 Inches Inches HG Minutes Cubic Feet Degrees F Inches H20 ****** Millihters Percent Percent Percent Percent Percent Square Inches Inches WG ****** DSCF SCF Percent ****** Ib/lb Mole Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 68 1 1/14/01 1115 1221 285 01848 0501 3040 60 41238 67 137 10034 17 00 209 791 6951 002 084 4225 08 19 098 2884 118750 2863 3040 737 2513 3556 99 Furnace 3 2 1/14/01 1255 1430 291 01835 0501 3040 60 41613 72 122 10034 19 00 209 791 6951 003 084 4221 09 21 098 2884 1187bO 2861 3040 735 2482 3546 100 CALCULATIONS FOR GRAJN LOADING AND EMISSION RATES TOTAL PARTICULATE PARTICULATE. CONCENTF<ATION PARTICULATE EMISSION RATE HYDROGEN CHLORIDE HYDROGEN CHLORIDE CONCENTRATION HYDROGEN CHLORIDE EMISSION RATE HYDROGEN FLOURIDE HYDROGEN FLOURIDE CONCENTRATION HYDROGEN FLOURIDE EMISSION RATE mg gr/dscf Ib/nr mg mg/dscf Ib/nr mg rng/dscf Ib/hr 20 0 00073 0016 < 00001 < < 0000002 < < 0000001 < 3033 07179 02386 253 0 00923 0196 00001 < 0000002 < 0000001 < 4691 1 1115 03648 3 1/14/01 1715 1820 288 01718 0501 3040 60 40322 69 1 06 10034 30 00 209 791 6951 002 084 41 14 14 33 097 2884 118750 2848 3040 688 2304 3321 105 380 0014? 0281 00001 0 000002 0 000001 1883 04579 01395 Horizon Air Measurement Services Inc W5_«1EIHITBI :u ur ux <j .j c-«ji I I i IV I O U IN l_ I 11_ I I SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL WG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H OGMCALIB FACTOR [Y] WATER COLLECTED CO 2 02 CO CH4 N2 STACK AREA STATIC PRESSURE PITOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULAR WT DRY EXCESS AIR MOLECULAR WT WET STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOWRATE DRY STD VOLUMETRIC FLOWRATE ACTUAL ISOKINETIC RATIO STD TEMP «"*"» ****** ****** ****** Degrees F Inches H20 Inches Inches HG Minutes Cubic Feet Degrees F Inches H20 ****** Milhliters Perrent Percent Percent Percent Percent Square Inches Inches WG ****** DSCF SCF Percent ****** Ib/lb Mole Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 68 1 1/14/01 1115 1221 285 01848 0501 3040 60 41238 67 137 10034 17 00 209 791 6951 002 084 4225 08 1 9 098 2884 118750 2863 3040 737 2513 3556 99 Furnace 3 2 1/14/01 1255 1430 291 01835 0501 3040 60 41613 72 122 10034 19 00 209 791 6951 003 084 4221 09 21 098 2884 118750 2861 3040 735 2482 3546 100 CALCULATIONS FOR GRAIN LOADING AND EMISSION RATES TOTAL PARTICULATE PART1CULATE CONCENTRATION PARTICULATE EMISSION RATE HYDROGEN CHLORIDE HYDROGEN CHLORIDE CONCENTRATION HYDROGEN CHLORIDE EMISSION RATE HYDROGEN FLOURIDE HYDROGEN Fl OURIDE CONCENTRATION HYDROGEN FLOURIDE EMISSION RATE mg gr/dscf Ib/hr mg mg/dscf Ib/hr mg mg/dscf Ib/hr 20 0 00073 0016 < 00001 < < 0000002 < < 0000001 < 3033 07179 02386 253 000923 0196 00001 < 0000002 < 0000001 < 4691 1 1115 03648 3 1/14/01 1715 1820 288 01718 0501 3040 60 40322 69 106 10034 30 00 209 791 6951 002 OB4 4114 14 33 097 2884 118750 2848 3040 688 2304 3321 105 380 00142 0281 00001 0 000002 0000001 1883 04579 01395 Horizon Alt Measurement Services Inc M5_W1EIKIITBL F3 I I I I I I I I I I I I I I I I I I I U O • C_OP III—IIOUIXI_I SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL AVG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H DGMCALIB FACTOR [Y] WATER COLLECTED CO 2 02 CO CH4 N2 STACK AREA STATIC PRESSURE PITOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULARWTDRY EXCESS AIR MOLECULAR WT WEI- STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOWRATE, DRY STD VOLUMETRIC FLOWRATE, ACTUAL ISOKINETIC RATIO STD TEMP CALCULATIONS FOR GRAIN LOADING AND EMISSION RATES TOTAL PARTICULATE PARTICULATE CONCENTRA1 ION PARTICULATE EMISSION RATE HYDROGEN CHLORIDE HYDROGEN CHLORIDE CONCENTRATION HYDROGEN CHLORIDE EMISSION RATE HYDROGEN FLOURIDE HYDROGEN FLOURIDE CONCENTRATION HYDROGEN FLOURIDE EMISSION RATE Furnace 4 ******' ***«+ ****** Degrees F Inches H20 Inches Inches HG Minutes Cubic Feet Degrees F Inches H20 ****** Millihters Percent Percent Percent Percent Percent Square Inches Inches WG ****** DSCF SCF Percent ****** Ib/lb Mole Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 68 ISSION RATES mg gr/dscf Ib/hr mg mg/dscf Ib/hr mg mg/dscf Ib/hr 1 1/14/01 1100 1208 296 0 1643 0491 3040 60 34960 62 108 10001 12 00 209 791 6951 001 084 3605 06 15 098 2884 118750 2867 3040 659 2224 3183 99 575 00246 0468 < 00001 < < 0000003 < < 0000001 < 3652 1013 ^S81 2 1/14/01 1255 1400 293 01688 0491 3040 60 36068 69 114 10001 25 00 209 791 6951 001 084 3672 12 31 097 2884 118750 2850 3040 678 2260 3273 99 622 00261 0505 00001 < 0 000003 < 0000001 < 3017 8217 2456 3 1/14/01 1645 1755 282 01650 0491 3040 60 35505 63 109 10001 26 00 209 791 6951 001 084 3653 12 32 097 2884 118750 2848 3040 658 2222 3178 101 694 00293 0557 00001 0 000003 0 000001 2704 7402 2175 Horizon Alt Measurement Services Inc M5_421EMim F4 I I U IN X C- U I I I X IN I 11_ I I O U IN l_ I 11_ I I SOURCE RUN NUMBER DATE OF RUN CLOCK TIME INITIAL CLOCK TIME FINAL AVG STACK TEMPERATURE AVG SQUARE DELTA P NOZZLE DIAMETER BAROMETRIC PRESSURE SAMPLING TIME SAMPLE VOLUME AVG METER TEMP AVG DELTA H DGMCALIB FACTOR [Y] WATER COLLECTED CO 2 02 CO CH4 N2 STACK AREA STATIC PRESSURE PITOT COEFFICIENT SAMPLE VOLUME DRY WATER AT STD MOISTURE MOLE FRACTION DRY GAS MOLECULAR WT DRY EXCESS AIR MOLECULAR WT WET STACK GAS PRESSURE STACK VELOCITY VOLUMETRIC FLOW/RATE DRY STO VOLUMETRIC FLOWRATE ACTUAL ISOKINETIC RATIO STD TEMP Degrees F Inches H20 Inches Inches HG Minutes Cubic Feat Degrees F Inches H20 ****** Milliliters Percent Percent Percent Percent Percent Square Inches Inches WG »•«"" DSCF SCF Percent ****** Ib/lb Mole Percent Ib/lb Mole Inches HG AFPM DSCFM ACFM Percent 68 NA NA NA 3040 60 £3988 72 300 09973 14 00 209 791 NA NA NA 6479 07 1 0 099 2884 118750 2873 3040 NA NA NA NA NA NA NA 3040 60 59326 72 300 09973 17 00 209 791 NA NA NA 6008 08 13 099 2884 118750 2869 3040 NA NA NA NA CALCULATIONS FOR GRAIN LOADING AND EMISSION RATES HYDROGEN CHLORIDE HYDROGEN CHLORIDE CONCENTRATION HYDROGEN FLOLIRIDF HYDROGEN FLOURIDE CONCENTRATION mg mg/dscf mg mg/dscf < 00001 < < 0000002 < 8826 01362 00001 < 0000002 < 8486 01412 Ambient Air Root Vent 1 2 3 1/14/01 1/14/01 1/14/01 1154 1332 1630 1259 1432 1730 NA NA NA 3040 60 59174 69 300 09973 19 00 209 791 NA NA NA 6028 09 15 099 2884 118750 2868 3040 NA NA NA NA 00001 0 000002 5545 00920 Horizon Air Measurement Services Inc NI5_421OHITBL AM I I I I UO.C.UJW IHJIX.tc.UI UUOJ -TOO ^i ,0 "V "V Tstd = £g* T Pstd = 29 92 in /Hg STACK GAS MOISTURE CALCULATION FACILITY dggg <£frt-*g.e, JOB NO SOURCE FcHzU^Cg^ *^^L- TESTDATE HUN < / _ Volume of sample at standard conditions, dry baste (460 + Vmstd = 29 92 (Dn + 460) Where. Vm = dry gas meter volume, ft1 ' *^5 W <? f Y <* DOM calibration factor £ «?. <?«|OO Pm = average AH, luHjO * / 6^ Pb = barometric pressure, in Hg » 3 O- */ ^ 1m = temperature of meter, °F , £ rr.£. = tf1 "TjT^/ ^ £> scf Volume of water vapor in sample at standard conditions . Vwstd = 0 04715 x Vw * ' * ***- Where, Vw - water volume, ml = Fractional moisture content of stack gas ^ - ( ) » 100 C t UJ. UO C-Uf*J l> J. C. U I 1 I I J. l> II1_IIOUIM_||1_| Tstd = Pstd - 29 92 in /Hg STACK VOLUME FLOW RATE CALCULATION SUMMARY FACILITY SOURCE RUN# JOB NO PSI-&*? I TEST DATE Cftfi Dry molecular weight of stack gas Mvw/=044 (%CO,)+032 (%O)+028 (%W2+%CO) Molecular weight of stack gas, wet basis Af_ = 100 - JUbufurv Pitot tube coefldent C (calibration curve) Standard = 0 99 S-Type = 0 84 & Average velocity head of stack gas, inches HZO (v/AP) avg Average absolute stack gas temperature avg = °+ 460 Absolute stack gas pressure (PstatlH 6) t-o.&>^ Where PB = barometric pressure Stack gas velocity -(5130) Cp x JkP Avg x JT, Stack gas volume flow rate Stack ga& volume flow rate, dry basis (460 + ] Q =^1 \ia :M, V]//^y I I I lb/lb-mole lb/lb-mole - V ° ^ in HK ft/mm _2 acfm ciscfm I I I I I I I I I I I I I I I . C_ U I I MX IN O ft- I Of ij CALCULATION DATA SHEET 5~- /v«v.v. £0 Horizon Air Measurement Services, Inc DESIGN APPROACHES 13-131 Table 7-9512 Type of Storage* Single-row rack storage, double-row rack storage, multiple-row rack storage ESFR Protection of Rack Storage without Solid Shelves Maximum Height of Storage Commodity ft m 1 Cartoned unexpanded 25 76 plastic 2 Cartoned expanded 3 Exposed unexpanded plastic 4 Classes I, II, III, and IV commodities, encapsu- lated or unencapsulated 5 Idle wood and plastic pallets 1 Cartoned or exposed 35 10 7 Maximum Ceiling/ Roof Sprinkler Height of Design Hose Stream Building . Pressure In-Rack DemandNominal Sprinkler Durabnn ft m K-factor psi bar Requirements gpm L/mrn (hours) 30 91 14 50 34 No 250 946 1 40 122 14 75 52 No 250 946 1 unexpanded plastic 2 Classes I, II, III, and IV commodities, encapsu- lated or unencapsulated 3 Idle wood and plastic pallets 1 Cartoned or exposed unexpanded plastic 2 Classes I, II, III, and IV commodities, encapsu- lated or unencapsulated 1 Cartoned unexpanded plastic 2 Classes I, II, III, and IV commodities, encapsu- lated or unencapsulated 35 40 20 25 30 35 40 107 122 61 76 91 107 122 45 45 25 30 35 40 45 137 137 76 91 107 122 137 14 14 112 252 252 252 252 90 90 50 20 30 40 50 62 62 34 14 21 28 34 No Yes No No No No No 250 250 250 250 250 250 250 946 946 946 946 946 946 946 1 1 1 1 1 1 1 *No open-top containers 7-9524 ESFR sprinklers shall be limited to wet pipe systems 7-9525 Early suppression fast-response (ESFR) sprinklers shall be used only m buildings equal to, or less than, the height of the building for which they have been listed 7-9 6 Exposure Protection 7-9 6 1* Piping shall be hydraulically calculated in accordance with Section 8-4 to furnish a minimum of 7 psi (0 5 bar) at any sprinkler with all sprinklers facing the exposure operating 7-9 6 2 Where the water supply feeds other fire protection sys- tems, it shall be capable of furnishing total demand for such systems as well as the exposure system demand 7-9 7 Water Curtains Sprinklers in a water curtain such as described in 5-13 4 shall be hydraulically designed to provide a discharge of 3 gpm per lineal foot (37 L/mm per lineal meter) of water curtain, with no sprinklers discharging less than 15 gpm (56 8 L/mm) For water curtains employing automatic sprinklers, the number of sprinklers calculated m this water curtain shall be the number m the length corre- sponding to the length parallel to the branch lines in the area determined by 8-4 4 1 (a) If a single fire can be expected to operate sprinklers within the water curtain and within the design area of a hydraulically calculated system, the water sup- ply to the water curtain shall be added to the water demand of the hydraulic calculations and shall be balanced to the calcu- lated area demand Hydraulic design calculations shall include a design area selected to include ceiling sprinklers adjacent to the water curtain (See 5-13 4 ) 7-9 8 Fire Protection of Steel Columns 798 If "Columns within Storage Racks of Class I through Class IV and Plastic Commodities Where sprinkler protec- uon of building columns within the rack structure or vertical rack members supporting the building are required m lieu of fireproofing, sprinkler protection in accordance with one of the following shall be provided (1) Sidewall sprinklers at the 15-ft (4 6-m) elevation, pointed toward one side of the steel column (2) Provision of ceiling sprinkler density for a minimum of 2000 8? (186 m2) with 165°F (74°C) or 286°F (141°C) rated sprinklers as shown in Table 7-9 8 1 for storage heights above 15 ft (4 6 m), up to and including 20 ft (6 1 m) (3) Provision of large drop or ESFR ceiling sprinkler protec- tion in accordance with 7-9 4 and 7-9 5, respectively 1999 Edition 13-136 INSTALLATION OF SPRINKLER SYSTEMS Table 7-10 23 6 1 Sprinkler Protection for Class 3 Oxidizers Type of - Storage Palletized Bulk Rack Storage Height ft 5 10 10 m 15 3 3 Density gpm/ft2 035 065 035 mm/nun 143 265 143 Area of Application ft2 5000 5000 5000 m2 465 465 465 In-Rack Sprinklers — — 1 level at midpoint of rack (430 Table 5-41) 7-10 23 2 Only wet pipe sprinkler systems shall be employed for protection of buildings or areas containing Class 2 or Class 3 oxidizers (430 2-11 3) 7-10 23 3 Sprinkler System Water Supplies 7-10 23 3 1 Water supplies shall be adequate for the protection of the oxidizer storage by hose streams and automatic sprin- klers The water system shall be capable of providing not less than 750 gpm (2840 L/min) where protection is by means of hose streams, or 500 gpm (1890 L/min) for hose streams in excess of the automatic sprinkler water demand (430 2-1141) 7-10 23 3 2 Duration of the water supply shall be a minimum of 2 hours (430 2-1142) 7-10 23 4 Class 1 Oxidizers Class I oxidizers m noncombus- tible or combustible containers (paper bags or noncombusn- ble containers with removable combustible liners) shall be designated as a Class 1 commodity, as a Class 2 commodity where contained in fiber packs or noncombustible containers in combustible packaging, and as a Class 3 commodity where contained in plastic containers (430 3-3 2) 7 10 23 5 Class 2 Oxidizers 7-10 23 5 1* Sprinkler protection for Class 2 oxidizers shall be designed in accordance with Table 7-10 23 5 1 (430 4-4 1) 7-10 23 5 2 Storage Protection with In-Rack Sprinklers In- rack sprinklers shall be designed to provide 30 psi (2 1 bar) on the hydrauhcally most remote six sprinklers on each level (430 4-44,4-441) 7 10 23 6 Class 3 Oxidizers 7-10 23 6 1* Sprinkler protection for Class 3 oxidizers shall be designed in accordance with Table 7-1023 6 1 (430 5-41) 7-10 23 6 2 Storage Protection with In-Rack Sprinklers In- rack sprinklers shall be designed to provide 30 psi (2 1 bar) on the hydrauhcally most remote six sprinklers on each level (430 5-44,5-441) 7 10 23 7 Class 4 Oxidizers Sprinkler protection for Class 4 oxidizers shall be installed on a deluge sprinkler system to pro- vide water density of 0 35 gpm (143 mm/mm) over the entire storage area (430 6-4 1) 7-10 24 Storage of Organic Peroxide Formulations 7-10 24 1 See NFPA 432, Code far the Storage of Organic Peroxide Formulations, for applicable terms not defined in Chapter 1 7-10 24 2 Where [automatic sprinkler systems are required per NFPA 432, Code for the Storage of Organic Peroxide Formula- tions, they] shall provide the following discharge densities Class I [organic peroxides] — 05 gpm/ft2 (20 4 mm/mm) Class II [organic peroxides] — 04 gpm/ft2 (16 3 mm/nun) Class III [organic peroxides] — 03 gpm/ft (12 2 mm/mm) Class IV [organic peroxides] — 0 25 gpm/ft2 (102 mm/mm) (432 2-S2) 7-10 24 2 1 The system shall be designed to provide the required density over a 3000-ft2 (279-m2) area for areas pro- tected by a wet pipe sprinkler system or 3900 ft2 (363 m2) for areas protected by a dry pipe sprinkler system The entire area of any building of less than 3000 ft2 (279 m2) shall be used as the area of application (432 2-821) 7-10 24 3 Sprinkler System Water Supply Water supplies for automatic sprinkler systems, fire hydrants, and so forth, shall be capable of supplying the anticipated demand for at least 90 minutes (432 2-8 3) 7-10 24 4 Where automatic sprinkler systems are required for Class I organic peroxide formulations in quanuties exceeding 2000 Ib (908 kg) in detached storage, per NFPA 432, Code for the Storage of Organic Peroxide Formulations, automatic sprinkler protection shall be of the deluge type (432 5-5 2) 7-1025 Organic Peroxide Formulations 7-10 25 1 See NFPA 432, Code for the Storage of Organic Peroxide Formulations, for applicable terms not defined in Chapter 1 7-10 25 2 Automatic sprinkler systems for the protection of storage of organic peroxide formulations shall provide the fol- lowing discharge densities Class 1 — 05 gpm/ft2 (20 4 mm/mm) Class II — 0 4 gpm/ft2 (163 mm/mm) Class III — 0 3 gpm/ft2 (122 mm/mm) Class IV— 0 25 gpm/ft2 (102 mm/mm) 7-10 25 3 The system shall be designed to provide the required density over a 3000 ft2 (280 m2) area for areas pro- tected by a wet pipe sprinkler system or 3900 ft2 (360 m2) for areas protected by a dry pipe sprinkler system The entire area of any building of less than 3000 ft2 (280 m2) shall be used as the area of application 7-10 26 Light Water Nuclear Power Plants 7-10 26 1 See NFPA 803, Standard for Fire Protection for Light Water Nuclear Power Plants for applicable terms not defined in Chapter 1 7-10 26 2* The yard mains shall be looped and shall be of suf- ficient size to meet the flow requirements specified in Section 7-10 26 3 of NFPA 13 (803 11-2) 1999 Edition 1998 CALIFORNIA BUILDING CODE TABLE 3-B TABLE 3-C TABLE 3-B—REQUIRED SEPARATION IN BUILDINGS OF MIXED OCCUPANCY1 (HOURS) A1 A2 A21 A3 A4 B E F1 F2 H1 H2 H-3 H4,5 H-6,7 I M R1 R3 S-1 S2 S3 S4 S5 A1 A2 N A21 N N A3 N N N A4 N N N N B 3 1 1 N 1 E N N N N N 1 F1 3 1 1 N 1 Ns 1 F2 3 1 1 N 1 N 1 1 H2 4 4 4 4 4 2 4 2 2 H-3 4 4 4 4 4 1 4 1 1 H4S 4 4 4 4 4 1 4 1 1 H6J2 4 4 4 3 4 1 3 1 1 tffl 3 2 2 1 1 1 2 1 1 \ 3 3 3 2 3 2 1 3 2 M 3 1 1 N 1 N 1 N5 1 R1 1 1 1 1 1 1 1 1 1 R3 1 1 1 1 1 1 1 1 1 S-1 3 1 1 N 1 N 1 N N S-2 3 1 1 N 1 N 1 N N S3 4 3 3 3 3 1 3 1 1 S5 3 1 1 1 U13 1 1 1 1 1 1 1 1 1 NOT PERMITTED IN MIXED OCCUPANCIES SEE SECTION 307 2 8 1 1 1 2 1 1 2 1 1 I 2 1 4 4 1 I 1 4 4 4 4 2 1 1 1 2 4 3 3 4 1 1 4 3 3 4 1 1 N 2 1 1 1 2 I4 3 1 2 1 1 1 2 I4 1 1 1 2 1 1 1 4 1 3 1 1 1 2 1 1 1 3 1 1 1 1 1 1 1 1 1 3 1 1 1 1 1 N 1 OPEN PARKING GARAGES ARE EXCLUDED EXCEPT AS PROVIDED IN SECTION 3 11 2 1 |N N—No requirements for fire resistance 'For detarled requirements and exceptions see Section 302 4 2For special provisions on highly toxic materials see the Fire Code 3For agricultural buildings see also Appendix Chapter 3 4See Section 309 2 2 for exception 5For Group F Division 1 woodworking establishments with more than 2 500 square feet (232 3 m2) the occupancy separation shall be one hour TABLE 3-C—REQUIRED SEPARATION OF SPECIFIC-USE AREAS IN GROUP I, DIVISION 1 1 HOSPITAL AND NURSING HOMES DESCRIPTION OCCUPANCY SEPARATION 1 Employee locker rooms Gift/retail shops Handicraft shops 4 Kitchens 5 Laboratories that employ hazardous materials m quantities less than that which would cause classification as a Group H Occupancy 6 Laundries greater man 100 square feet (9 3 m2)1 7 Paint shops employing hazardous substances and materials in quantities less man that which would cause classification as a Group H Occupancy 8 Physical plant maintenance shop 9 Soiled unen room1 10 Storage rooms 100 square feet (9 3 m2) or less in area storing combustible material 11 Storage rooms more than 100 square feet (9 3 m2) storing combustible material 12 Trash collection rooms1 None None None None One hour One hour One hour One hour One hour None One hour One hour 'For rubbish and hnen chute termination rooms see Section 711 5 1-403 TABLE 3-D 1998 CALIFORNIA BUILDING CODE TABLE 3-D—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A PHYSICAL HAZARD MAXIMUM QUANTITIES PER CONTROL AREA1 When two units are given, values within parentheses are in cubic feet (cu ft) or pounds (Ibs ) CONDITION Material 1 1 Combustibleliquid456789 1 2 Combustible fiber(loose) (baled) 1 3 Cryogenic flammable or oxidizing 2 1 Explosives 3 1 Flammable solid 3 2 Flammable gas (gaseous) (liquefied) 3 3 Flammable liquid456789 Combination I A IB 1C15 4 1 Organic peroxide unclassified detonatable 4 2 Organic peroxide 4 3 Oxidizer 4 4 Oxidizer— -gas (gaseous)"'0 (liquefied)6 10 5 1 Pyrophonc 6 1 Unstable (reactive) 7 1 Water reactive Class n niA 1KB IA IB I-C I n ra IV V 4 3 16 2 1 4 3 2 1 3 2 1 STORAGE2 Solid Lbs 3(Cu Ft.) x 0 4538 lor kox 0 0283 for a? NA NA NA (100) (1000) NA jlO 13 125610 NA NA NA NA NA NA 11012 5610 50610 125s 10 500610 NL 11012 10610 250s 10 4000s10 NA NA 410 12 j!0 12 5610 50610 NL 56 10 SO610 1251011 LiquidGallons3 (Lbs) x 3 785 lor Lx 8 4536 lor kg I2010 33010 13 20010 H NA NA 45 (1)1013 NA NAj5610 3010 6010 90io 12010 (1)1012 (5)6 10 (50)6 10 (125)6 10 (500)6 10 NL (D'012 (10)6 10 (250)6 10 (4000)610 NA 15 (4)10 12 (1)1012 (5)6 10 (50)6 10 NL (5)6 10 (50)6 10 (125)lou GasCu Ft. x 8 6283 lor m3 NA NA NA NANA NA NA NA 750s 10 NA NA NA NA NA NA NA NA N.A NA NA NA NA NA NA 1500 NA 5010 12 1Q1012 50610 250s 10 750s 10 NA NA NA USE*— CLOSED SYSTEMS Solid Lbs(Cu Ft) x 0 4536 lor kgx 8 8283 lorn? NA NA NA (100) (1000) NA V2 14 NA NA NA NA NA NA l/412 1s 50s 1256 500s NL V412 2« 250s 40006 NA NA I12 l/412 1S 50s NL 5s 50s 12511 Liquid Gallons(Lbs) x 3 785 (or Lx 8 4S36 lor kg 120 330 13 20011 NA NA 45 C/4)'2 NA NA 15610 30 60 90 120 C/4)12 (I)6 (50)s (125)s (500)6 NL C/4)l2 (2)s (250)s (4000)6 NA 15 (I)12 C/4)12 (I)6 (50)s NL (5)6 (50)s (125)H GasCu Ft x 8 0283 lor m> NA NA NA NA NA NA NA N.A 750s 1°NA N.A NA NA NA NA NA NA NA N A NA NA N.A NA N.A 1500NA IQlO 12 210 12 1Q610 250s 10 NL NA NA NA USE*— OPEN SYSTEMS Solid Lbs(Cu R.) x 8 4536 lor kox 0 0213 for a? NA NA NA (20) (200) NA V412 14 N.ANA NA NA NA NA 1/412 I6 10s 25s 100s NL l/4'2 2s 50s 1000s NA NA 0 V412 1s 10s NL 1s 10s 2511 Liquid Gallons(Lbs) x 3 785 lor Lx 8 4536 tor kg 30 80 3 300n NA NA 10 (</4)i2 NA NANA 10 15 20 30 (V4)12 (I)6 (10)s (25)s (100)s NL C/4)12 (2)6 (50)s (1000)s NA NA 0 C/4)'2 (i)6 (10)s NL (I)6 (10)s (25)H N A —Not applicable N L —Not limited 1 Control areas shall be separated from each other by not less than a one-hour fire resistive occupancy separation The number of control areas within a building used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four See Section 2042The aggregate quantity m use and storage shall not exceed the quantity listed for storage3The aggregate quantity of nonflammable solid and nonflammable or noncombustible liquid hazardous materials within a single control area of Group M Occupan cies used for retail sales may exceed the exempt amounts when such areas are in compliance with the Fire Code4The quantities of alcoholic beverages in retail sales uses are unlimited provided the liquids are packaged in individual containers not exceeding 4 liters The quantities of medicines foodstuffs and cosmetics containing not more than 50 percent of volume of water miscible liquids and with the remainder of thesolutions not being flammable m retail sales or storage occupancies are unlimited when packaged in individual containers not exceeding 4 liters5For aerosols see the Fire Code Quantities may be increased 100 percent in spnnklered buildings When Footnote 10 also applies the increase for both footnotes may be appbed7For storage and use of flammable and combustible liquids in Groups ABEFHIMRSandU Occupancies see Sections 303 8 304 8 305 8 306 8 307 1 3 through 307 1 5,308 8 309 8 310 12 311 8 and 312 48For wholesale and retail sales use, also see the Fire Code9Spray application of any quantity of flammable or combustible liquids shall be conducted as set forth in the Fire Code1 "Quantities may be increased 100 percent when stored in approved storage cabinets gas cabinets or exhausted enclosures as specified m the Fire Code When Footnote 6 also applies the increase for both footnotes may be applied1lThe quantities permitted in a spnnklered building are not limited. ^Permitted in spnnklered buildings only None is allowed m unspnnklered buildings I30ne pound of black sporting powder and 20 pounds (9 kg) of smokeless powder are permitted in spnnklered or unspnnklered buildings14See definitions of Divisions 2 and 3 in Section 307 1 1-404 1998 CALIFORNIA BUILDING CODE TABLE 3-D TABLE 3-D 1 FOOTNOTES TO TABLE 3-D—(Continued) '^Containing not more than the exempt amounts of Class I A. Class I B or Class I C flammable liquids16A maximum quantity of 200 pounds (90 7 kg) of solid or 20 gallons (75 7 L) of liquid Class 3 oxidizers may be permitted when such materials are necessary | for maintenance purposes or operation of equipment as set forth in the Fire Code TABLE 3-D 1 [For SFM]—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS, LIQUIDS AND CHEMICALS PRESENTING A PHYSICAL HAZARD BASIC QUANTITIES PER LABORATORY SUITED When two units are given, values within parentheses are In cubic feet (Cu Ft) or pounds (Lbs) CONDITION MATERIAL 1 1 Combustible liquid 1 2 Combustible dust Ibs /1000cu.fi 1 3 Combustible fiber (loose) (baled) 1 4 Cryogenic flammable or oxidizing 2 1 Explosives 3 1 Flammable solid 3 2 Flammable gas (gaseous) (liquefied) 3 3 Flammable liquid Combination I A IB 1C 4 1 Organic peroxide unclassified detonatable 4 2 Organic peroxide 4 3 Oxidizer 4 4 Oxidizer — Gas (gaseous) (liquefied) 5 1 Pyrophonc 6 1 Unstable (reactive) 7 1 Water (reactive) CLASS II IUA IIIB IA IB 1C I II III IV V 4 3 21 4 3 21 3 2 1 STORAGE Solid Lbs.(Cu Ft) — — — 1 (100) (1000) 1* 1252 — — — — — I2 52 SO2 1252 500 NL 12 I02 2502 10002 ~ 42 I2 52 SO2 1252 52 502 1252 LiquidGallons(Lbs.) 1202 3302 13 2002 — — 45 (I)2 — Is2 302 602 902 1202 (i)2 (5)2 (SO)2 (125)2 (500) NL (I)2 (10)2 (250)2 (1 OOO)2 is2 <4)2 (V*<5>,(SO)2 (125)2 (S)2 (SO)2 (125)2 GasCu Ft. — — — ~ — —— 7502 — — — — — — — 15002 SO2 10 SO2 2502 7502 USE— CLOSED SYSTEMS Solid Lbs.(Cu Ft) — — — 1 (100)(1000) —'* 25 ~ — — — —'/, (I)50 125 500 NL. >/4 2501000 — I 1/41 50125 5 50125 LiquidGallons(Lbs) 120 330 13200 — 45 ('/<) — ~152 30 60 90 120 f'/4) (1)(SO) (125) (500) NL (J/4)(2) (250)(1000) 152 (I) ('/<) (1)(SO) (125) (5)(50) (125)2 OmCu Ft — — — — — — — 7502 — — — — — — — 15002 102 22 102 2502 7502 E USE— OPEN SYSTEMS Solid Lbs(CuFt) — — — I (20)(200) — '* 25 — — — — — '/4 1 10 25 100 NL '2 50200 — 0 1/41 1025 I 10 25 LiquidBallon*(Lbs) 30 80 3300 — 10 ('/4) — — 10 15 20 30 C/4) 1 (10) (25) (100)NL (l/4) (2) (SO)(200) — 0 ('/4) (1) (10) (25) (1)(10) (25) GasCu Ft — —— — — — — — — — — — — — — — 0 0 0 0 0 E NL — Not limited 'A laboratory suite is a space up to 10 000 square feet (929 n2) bounded by not less than a one hour fire resistive occupancy separation within which the exempt amounts of hazardous materials may be stored, dispensed, handled or used. Up through the third floor and down through the first basement floor the quantity in this table shall apply Fourth, fifth and sixth floors and the second and third basement floor level quantity shall be reduced to 75 percent of this table The seventh through 10th floor and below the third basement floor level quantity shall be reduced to 50 percent of this table ^Quantities may be increased 100 percent when stored in approved exhausted gas cabinets exhausted enclosures or fume hoods 1-405 TABLE 3-E 1998 CALIFORNIA BUILDING CODE TABLE 3-E—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A HEALTH HAZARD MAXIMUM QUANTITIES PER CONTROL AREA1 2 When two units are given, values within parentheses are In pounds (Ibs) MATERIAL 1 Corrosives10 2 Highly toxics7 3 Irritants9 4 SensiUzers9 5 Other health hazards9 6 Toxics7 STORAGE Solid Lbs458 x 04536 for kg 5000 10 NL NL NL 500 Gallons4" (Lbs) X 3 785 for L x 04536 for kg 500 (10) NL NL L NL (500) GasCu RS x 0 028 for m3 810s 208 810s u 810*11 8106n 810s USE3— CLOSED SYSTEMS Solid Lbs M x 0 4536 for kg 5000 10 NL NL NL 500 LiquidGallons4:(Lbs.) X 3 785 for L x 0 4536 for kg 500 (10) NL NL NL (500) GasCu Ft.5 x 0 028 for m3 8106 208 8106U 810s n 810611 8108 USE3— OPEN SYSTEMS Solid Lbs" x 0 4536 for kg 1000 3 5 OOO11 500Q11 5 OOO11 125 LiquidGallons" (Lbs) X 3 785 for L x 0 4536 for kg 100 (3) 50011 500U 50011 (125) NL = Not limited 'Control areas shall be separated from each other by not less than a one hour fire resistive occupancy separation The number of control areas within a building used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four See Section 2042The quantities of medicines foodstuffs and cosmetics containing not more than 50 percent by volume of water miscible liquids and with the remainder of the solutions not being flammable in retail sales uses are unlimited when packaged m individual containers not exceeding 4 liters3The aggregate quantity in use and storage shall not exceed the quantity listed for storage4The aggregate quantity of nonflammable solid and nonflammable or noncombusuble liquid health hazard materials within a single control area of Group M Occu pancies used for retail sales may exceed the exempt amounts when such areas are m compliance with the Fire Code 'Quantities may be increased 100 percent in spnnklered buildings When Footnote 6 also applies the increase for both footnotes may be applied6Quantities may be increased 100 percent when stored in approved storage cabinets gas cabinets or exhausted enclosures as specified in the Fire Code When Foot note 5 also applies the increase for both footnotes may be applied7For special provisions see the Fire Code ^Permitted only when stored in approved exhausted gas cabinets exhausted enclosures or fume hoods 'irritants sensitizers and other health hazards do not include commonly used building materials and consumer products that are not otherwise regulated by this code10For stationary lead acid battery systems see the Fire Code UThe quantities allowed in a spnnklered building are not limited when exhaust ventilation is provided in accordance with the Fire Code See Table 8001 15 B Footnote 12 1-406 TABLE 7902 5-B 1997 UNIFORM FIRE CODE TABLE 7902 3-A—OUTDOOR LIQUID STORAGE IN CONTAINERS AND PORTABLE TANKS (See Sections 7902 3 3 1 and 7902 332) CLASSOF LIQUID IA I-B I-Cn ID CONTAINER STORAGE— MAXIMUMPER PILE Quantity1 2 (gallons) x 3 785 for L 1,100 2,200 4,400 8,800 22,000 Height fleet) x 304 8 for mm 10 12 12 12 18 PORTABLE TANKSTORAGE— MAXIMUM PER PILE Quantity1 2 (gallons) x 3 785 for L 2,200 4,400 8,800 17600 44,000 Height(feet) MINIMUM DISTANCEBETWEEN PILES ORRACKS (feet) MINIMUM DISTANCETO PROPERTY LINEOF PROPERTY THATCAN BE BUILTUPON3«(feet) MINIMUM DISTANCE TO STREET ALLEY ORA PUBLIC WAY4 (feet) x 304 8 for mm 7 14 14 14 14 5 5 5 5 5 50 50 50 25 10 10 10 10 5 5 ipor mixed class storage, see Section 7902 331 2Foi storage in racks, the quantity limits per pile do not apply, but the rack arrangement shall be limited to a maximum of 50 feet (15 240 mm) in length and two rows or 9 feet (30 480 mm) in depth 3If protection by a public fire department or private fire brigade capable of providing cooling water streams is not available, the distance shall be doubled4When the total quantity stored does not exceed 50 percent of the maximum allowed per pile, the distances are allowed to be reduced 50 percent, but not less than 3 feet (914 4 mm) TABLE 7902 5-A— EXEMPT AMOUNTS OF FLAMMABLE AND COMBUSTIBLE LIQUIDS- MAXIMUM QUANTITIES STORED PER CONTROL AREA1 2 3 (See Section 7902 5 7) I I I I I I TYPE OF LIQUID Flammable Class I A Class I B Class I-C Combination I-A, I-B, I-C Combustible Class n Class HI A Class ffl B EXEMPT AMOUNT (gallons) x 3 785 for L 30 60 90 1204 120 330 13,200s 1Control areas shall be separated from each other by not less than a one hour fire-resistive occupancy separation The number of control areas wjthm a building used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four See Sections 204 and 800110 2 Quantities are allowed to be increased 100 percent when stored in approved storage cabinets When Footnote 3 applies, the increase for each footnote is allowed Quantities are allowed to be increased 100 percent in buildings equipped with an approved automatic sprinkler system When Footnote 2 applies the increase for each footnote is allowed 4Combinations shall not contain more than the exempt amounts of any individual class 'Quantities permitted in a building equipped with an approved automatic sprinkler system are not limited TABLE 7902 5-B—EXEMPT AMOUNTS OF FLAMMABLE AND COMBUSTIBLE LIQUIDS IN WHOLESALE AND RETAIL SALES USES- MAXIMUM QUANTITIES STORED PER CONTROL AREA1 (See Section 7902 571) TYPE OF LIQUID Flammable Class I-A Flammable and combustible Combination Class I-B I C II and ffl-A Combustible Class III-B EXEMPT AMOUNTS (gallons) x 3.785 for L Sprlnklered2 per Footnote Densities and Arrangements 60 75003 Unlimited Sprlnklered per Tables 7902 5-F through 7902.5-K 60 15.0003 Unlimited Unsprlnklered 30 1,600 13,200 Control areas shall be separated from each other by not less than a one hour fire resistive occupancy separation The number of control areas within a building used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four See Sections 204 and 8001102 2To be considered as spnnklered, buildings shall be protected with approved automatic sprinkler systems with designs providing minimum densities as follows For uncartoned commodities on shelves 6 feet (1829 mm) or less in height where the ceiling height does not exceed 18 feet (5486 mm), quantities are those per mitted with a minimum sprinkler design density of Ordinary Hazard Group 2 For cartoned, palletized or racked commodities where storage is 4 feet 6 inches (1372 mm) or less in height and where the ceiling height does not exceed 18 feet (5486 mm), quantities are those permitted with a minimum sprinkler design density of 0 21 gpm per square foot [8 56 IV(min«m2)] over the most remote 1,500-square-foot (139 m2) area 3When wholesale and retail sales or storage areas exceed 50,000 square feet (4645 m2) in area, exempt amounts are allowed to be increased by 2 percent for each 1,000 square feet (92 9 m2) of area m excess of 50,000 square feet (4645 m2), up to a maximum of 100 percent of the table amounts A control area separation is not required The cumulative amounts, including amounts attained by having an additional control area, shall not exceed 30,000 gallons (113 562 L) I I 1-184 1997 UNIFORM FIRE CODE be free from residual material and vapor as defined by DOT, the Resource Conservation and Recovery Act (RCRA) or other regu- lating authority or maintained as specified for the storage of the hazardous matenal 800147 Maintenance 8001471 General Equipment, machinery and required detec- tion and alarm systems associated with hazardous materials shall be maintained in an operable condition Defective containers, cyl- inders and tanks shall be removed from service, repaired or dis- posed of in an approved manner Defective equipment or machinery shall be removed from service and repaired or replaced Required detection and alarm systems shall be replaced or repaired where defective See also Section 8001 4 4 8001472 Tanks out-of-service for 90 days Stationary tanks not used for a period of 90 days shall be properly safeguarded or removed in an approved manner Such tanks shall have the fill line, gauge opening and pump connection secured against tamper- ing Vent lines shall be properly maintained Tanks which are to be placed back in service shall be tested in an approved manner 80014 7.3 Defective containers and tanks Defective contain- ers and tanks shall be removed from service, repaired or disposed of in an approved manner 80014 8 Liquid-level limit control Atmospheric tanks which have a capacity greater than 500 gallons (1893 L) containing haz- ardous matenal liquids shall be equipped with a liquid-level limit control to prevent overfilling of the tank EXCEPTION Tanks monitored by a system which limits net con tents by weight 80014 9 Seismic protection Machinery and equipment utiliz- ing hazardous materials shall be seismically anchored in accord- ance with the Building Code 80015 Release of Hazardous Matenals 8001 51 General Hazardous materials shall not be released into a sewer, storm drain, ditch, drainage canal, lake, nver or tidal waterway, or upon the ground, sidewalk, street, highway or into the atmosphere EXCEPTION Matenals released in accordance with federal state or local governing regulations or permits of the junsdictional Air Quality Management Board with a National Pollutant Discharge Elim- ination System Permit, with waste discharge requirements established by the junsdictional Water Quality Control Board or with local sewer pretreatment requirements for publicly owned treatment works 80015 2 Unauthorized discharges 8001521 Records Accurate records shall be kept of the unau- thorized discharge of hazardous materials by the permittee 80015.2 2 Notification The chief shall be notified immediate- ly when an unauthorized discharge becomes reportable under state, federal or local regulations 80015 23 Preparation Provisions shall be made for control- ling and mitigating unauthorized discharges 8001 524 Control When an unauthorized discharge due to pri- mary container failure is discovered, the involved primary con- tainer shall be repaired or removed from service 8001525 Responsibility for cleanup The person, firm or cor- poration responsible for an unauthorized discharge shall institute and complete all actions necessary to remedy the effects of such unauthorized discharge, whether sudden or gradual, at no cost to 800(1 4 6 80019 the jurisdiction When deemed necessary by the chief, cleanup may be initiated by the fire department or by an authorized indi- vidual or firm Costs associated with such cleanup shall be borne by the owner, operator or other person responsible for the unau- thorized discharge 80016 Matenal Safety Data Sheets Material safety data sheets (MSDS) shall be readily available on the premises for haz- ardous matenals regulated by Article 80 See also Sec- tion 8001 3 2 80017 Identification Signs Visible hazard identification signs as specified in UFC Standard 79-3 shall be placed on stationary aboveground tanks and at entrances to locations where hazardous matenals are stored, dispensed, used or handled in quantities requiring a permit Signs shall be provided at specific entrances and locations designated by the chief EXCEPTION The chief may waive this requirement in special cases when consistent with safety if the owner or operator has submitted a hazardous matenals management plan and hazardous materials inventory statement See Appendix IIE and Sections 8001 3 2 and 8001 3 3 Individual containers, cartons or packages shall be conspicu- ously marked or labeled in accordance with nationally recognized standards Rooms or cabinets containing compressed gases shall be con- spicuously labeled COMPRESSED GAS Signs shall not be obscured or removed Signs shall be in English as a primary language or in symbols allowed by this code Signs shall be durable The size, color and lettering shall be in accordance with nation- ally recognized standards 80018 Signs In addition to the hazard identification signs re- quired by Section 8001 7, additional hazard identification and warning signs shall be provided as follows 1 Stationary containers and tanks shall be placarded with haz- ard identification signs as specified m UFC Standard 79-3 for the specific material contained 2 Signs prohibiting smoking shall be provided in the following situations 2 1 In rooms or areas where hazardous matenals are stored or dispensed or used in open systems in amounts requiring a permit in accordance with Section 8001 3 1 2 2 Within 25 feet (7620 mm) of outdoor storage, dispens- ing or open-use areas Signs shall not be obscured or removed Signs shall be in Eng- lish as a primary language or in symbols allowed by this code Signs shall be durable The size, color and lettenng shall be in ac- cordance with nationally recognized standards 80019 Sources of Ignition Smoking shall be prohibited in the following locations 1 Within 25 feet (7620 mm) of outdoor storage or dispensing areas 2 In rooms or areas where hazardous matenals are stored or dis- pensed or used m open systems in amounts requmng a permit in accordance with Section 8001 3 1 Open flames and high-temperature devices shall not be used in a manner which creates a hazardous condition EXCEPTION Energy consuming equipment listed for use with the hazardous materials stored or used I I I I II I I 'I I I 1-203 8001 108001 11 5 1997 UNIFORM FIRE CODE 800110 Construction Requirements 800110 1 General Buildings, or portions thereof, in which hazardous materials are stored, handled or used shall be con- structed in accordance with the Building Code 800110 2 Control areas 800110 21 Construction requirements Control areas shall be separated from each other by not less than a one-hour fire-resis- tive occupancy separation 800110 2 2 Number The number of control areas in buildings or portions of buildings used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four 800110 3 Gas rooms 800110 3 1 General When a gas room is used to increase com- pressed gas exempt amounts or when the location of compressed gases in a gas room is required or allowed by Section 8003 or 8004, the gas room shall be in accordance with Section 8001 10 3 800110 3 2 Construction Gas rooms shall be separated from the remainder of the building by not less than a one-hour fire-resis- tive occupancy separation For highly toxic and toxic compressed gases used in conjunction with or serving a Group H, Division 6 Occupancy, also see the Building Code 800110 3 3 Ventilation system The ventilation system for gas rooms shall be designed to operate at a negative pressure in rela- tion to the surrounding area For toxic and highly toxic gases, the requirements set forth in Section 8003 3134 shall also be met 800110 4 Exhausted enclosures 800110 41 General When an exhausted enclosure is used to increase exempt amounts or when the location of hazardous mate- rials in exhausted enclosures is either required or allowed by Sec- tion 8003 or 8004, the exhausted enclosure shall be in accordance with Section 8001 10 4 80011042 Construction combustible Exhausted enclosures shall be non- 8001 10 4 3 Ventilation The ventilation system for exhausted enclosures shall be designed to operate at a negative pressure in relation to the surrounding area For toxic and highly toxic gases, the requirements set forth in Section 8003 3133 shall also be met 800110 5 Gas cabinets 800110 5 1 General When a gas cabinet is used to increase ex- empt amounts or when the location of compressed gases in gas cabinets is either required or allowed by Section 8003 or 8004, the gas cabinet shall be in accordance with Section 8001 10 5 800110 5 2 Construction Gas cabinets shall be constructed in accordance with the following 1 Constructed of not less than 0 097-inch (2 46 mm) (12 gage) steel 2 Be provided with self-closing limited access ports or non- combustible windows to give access to equipment controls 3 Be provided with self-closing doors 800110 5 3 Ventilation The ventilation system for gas cabi- nets shall be designed to operate at a negative pressure in relation to the surrounding area For toxic and highly toxic gases, the re- quirements set forth in Section 8003 3132 shall also be met 800110 6 Hazardous materials storage cabinets 800110 6 1 General When storage cabinets are used to in- crease exempt amounts or to comply with Article 80, such cabi- nets shall be in accordance with Section 8001 10 6 800110 6 2 Construction Cabinets shall be constructed of metal The interior of cabinets shall be treated, coated or con- structed of materials that are nonreactive with the hazardous mate- rial stored Such treatment, coating or construction shall include the entire interior of the cabinet Cabinets shall either be listed as suitable for the mtended storage or constructed in accordance with the following 1 Cabinets shall be of steel having a thickness of not less than 0 044 inch (1 12 mm) (18 gage) The cabinet, including the door, shall be double walled with 1 V2-mch (38 1 mm) airspace between the walls Joints shall be riveted or welded and shall be tightfitting Doors shall be well fitted, self-closing and equipped with a self- latching device, and 2 The bottoms of cabinets utilized for the storage of liquids shall be liquid tight to a minimum height of 2 inches (50 8 mm) For requirements regarding electrical equipment and devices within cabinets used for the storage of hazardous gases or liquids, see the Electrical Code 800111 General Safety Precautions 8001111 Personnel training and written procedures 80011111 General Persons responsible for the operation of areas in which hazardous materials are stored, dispensed, handled or used shall be familiar with the chemical nature of the materials and the appropriate mitigating actions necessary in the event of fire, leak or spill 80011112 Fire department liaison Responsible persons shall be designated and trained to be liaison personnel for the fire department These persons shall aid the fire department in pre- planning emergency responses and identification of the locations where hazardous materials are located and shall have access to material safety data sheets and be knowledgeable in the site emer- gency response procedures 8001112 Security The storage, dispensing, use and handling areas shall be secured against unauthorized entry and safeguarded with such protective facilities as public safety requires 8001113 Protection from vehicles Guard posts or other ap- proved means shall be provided to protect storage tanks and con- nected piping, valves and fittings, dispensing areas, and use areas subject to vehicular damage When guard posts are installed, the posts shall be 1 Constructed of steel not less than 4 inches (1016 mm) in di- ameter and concrete filled, 2 Spaced not more than 4 feet (1219 mm) between posts on center, 3 Set not less than 3 feet (914 mm) deep in a concrete footing of not less than a 15-inch (381 mm) diameter, 4 Set with the top of the posts not less than 3 feet (914 mm) above ground, and 5 Located not less than 5 feet (1524 mm) from the tank 8001114 Electrical wiring and equipment Electrical wiring and equipment shall be installed in accordance with the Electrical Code 800111 5 Static accumulation When processes or conditions exist where a flammable mixture could be ignited by static elec- 1-204 1997 UNIFORM FIRE CODE 800116 2.3 Liquefied flammable gases and flammable gases in solution Containers of liquefied flammable gases and flam- mable gases in solution shall be positioned in accordance with Section 8004113 800116 3 Oxidizing gases 800116 3 1 Emergency shutoff Compressed gas systems con- veying oxidizing gases shall be provided with emergency shutoff capability in accordance with Section 8004 112 800116 3.2 Ignition source control Ignition sources in areas containing oxidizing gases shall be controlled in accordance with Section 8001 9 800116 4 Pyrophoric gases 800116 41 Emergency shutoff Compressed gas systems con- veying pyrophonc gases shall be provided with emergency shut- off capability in accordance with Section 8004 112 SECTION 8002 — CLASSIFICATION BY HAZARD 80021 General Hazardous materials shall be classified according to hazard categories The categories include materials regulated by Article 80 and materials regulated elsewhere in this code 80022 Hazard Categories 8002 21 Physical hazards The materials categones listed in this section are classified as physical hazards A material with a primary classification as a physical hazard can also present a health hazard 1 Explosives and blasting agents, regulated elsewhere in this code 2 Compressed gases, regulated in Article 80 and elsewhere in this code, as follows 21 Air, 8001 1623 80023 2 2 Flammable, 23 Inert, 2 4 Oxidizing, 2 5 Pyrophonc, 2 6 Simple asphyxiant, 2 7 Unstable (reactive), and 2 8 Health hazards identified in Section 8002 2 2 3 Flammable and combustible liquids regulated elsewhere in this code 4 Flammable solids 5 Organic peroxides 6 Oxidizer solids and liquids 7 Pyrophonc solids and liquids 8 Unstable (reactive) solids and liquids 9 Water-reactive solids and liquids 10 Cryogenic fluids, regulated elsewhere in this code 8002 2 2 Health hazards The materials categones listed in this section are classified as health hazards A material with a primary classification as a health hazard can also present a physical hazard 1 Highly toxic and toxic matenals, including highly toxic and toxic compressed gases 2 Radioactive matenals 3 Corrosives 4 Carcinogens, irntants, sensitizers and other health hazards 8002.3 Descriptions and Examples For descnptions and ex- amples of matenals included in hazard categones, see Appendix VI-A, except that refrigerants regulated under Article 63 shall be classified in accordance with Table A-VI-F-1 if the refrigerant used is included m Table A-VI-F-1 I I I I I I I I I I I 1-209 TABLE 800115-A 1997 UNIFORM FIRE CODE TABLE 8001 15-A—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A PHYSICAL HAZARD MAXIMUM QUANTITIES PER CONTROL AREA1 When two units are given, values within parentheses are in cubic feet (cu ft) or pounds (Ibs) (Apply table as specified in Section 8001 15) CONDITION Material 1 1 Combustible liquid456789 1 2 Combustible fiber17 (loose) (baled) 1 3 Cryogenic, flammable or oxidizing17 2 1 Explosives12 17 3 1 Flammable solid17 3 2 Flammable gas17 (gaseous) (liquefied) 3 3 Flammable liquid4-5 6 7 8 9 Combination I A, I B,I c4,5 6 7 8 9 15 4 1 Organic peroxide, unclassified detonatable 4 2 Organic peroxide 4 3 Oxidizer 4 4 Oxidizer — gas (gaseous)6"517 (liquefied)61017 5 1 Pyrophoric17 6 1 Unstable (reactive)17 7 1 Water reactive Class — — — — — — — — I n m rv V 4 316 2 1 — — 4 3 2 1 3 2 1 STORAGE2 Solid Lbs 3(cubic feat) x 04536 tor koxO 0283 for a? — (100) (1,000) NA 11013 125s 10 NA.NA. — 11012 5610 50610 125610 500610 NL 11012 10610 250610 4,000* 10 NA. NA 41012 11012 5610 50610 NL 5610 50610 1251011 Liquid Gallons3 (pounds) x 3 785 lor I x 04536 tor kg — NA NA. 45 (1)10 13 N.A NA15610 — (1)1012 (5)6 i° (50)6 10 (125)61° (500)610 NL (1)1012 (10)610 (250)6 10 (4.000)6 10 NA 15 (4)10 12 (1)10 12 (5)610 (50)6 10 NL (5)610 (50)6 10 (125)1011 GasCubic Feal x 0 0283 (or m3 — N.A. N.A NA. NA NA. 7506 10 NA. — NA. NA NA. NA NA NA. NA NA. NA NA 1,500 NA. 501012 1Q10 12 50610 750610 NL610 NA. NA. NA. USES-CLOSED SYSTEMS Solid Lbs(cubic fgal) x 04536 for kax 00233 (or n? — (100) (1,000) NA V4 14 NA NA — V4 12 I6 SO6 1256 5006 NL V412 26 250* 4,000s N.A. NA I12 V4 12 16 SO6 NL S6 506 12511 Liquid Gallons(pounds) x 3 785 lor L x 04536 tor kg — NA NA 45 (V4) NA NA15610 — (V4)12 (I)6 (50)6 (125)6 (500)6 NL (V4)12 (2)6 _ (250)5 (4,000)6 NA 15 (I)12 (V4)12 (I)6 (50)6 NL (5)6 (50)6 (125)11 GasCubic Feaf x 0 0283 (or m3 — NANA. NA. NA NA. 7506 10 NA. — NA. NA. NA NA. ' NA. NA. NA NA NA NA. 1,500 NA. 1010 12 21012 1Q610 750610 NL NA NA NA. USE2— OPEN SYSTEMS Solid Lbs(cubic faef) x 04536 for kg x 00283 form3 — (20) (200) NA. V4 14 NANA — V4 12 I6 106 256 1006 NL V4 12 26 506 1,000s NA N.A. 0 V4 12 i6 10s NL 16 10s 2511 Liquid Gallons(pounds) x 3 785 torLx 04536 lor kg — NA NA 10 (V4) NA NA NA — (V4)12 (1)6 (10)6 (25)6 (100)6 NL (V4)12 (2)6 (50)6 (l.OOO)6 NA NA 0 (V4)12 (1)6 (10)6 NL (1)6 (10)6 (25)11 N.A —Not applicable N L —Not limited 1Control areas shall be separated from each other by not less than a one hour fire resistive occupancy separation The number of control areas within a building used for retail or wholesale sales shall not exceed two The number of control areas in buildings with other uses shall not exceed four See Sections 204 and 8001 10 2 2The aggregate quantity in use and storage shall not exceed the quantity listed for storage Quantities shall not exceed limits set forth in. Section 800115 2 3The aggregate quantity of nonflammable solid and nonflammable or noncombustible liquid hazardous materials within a single control area of Group M Occupan cies used for retail sales may exceed the exempt amounts when such areas are in compliance with Section 800114 4For flammable and combustible liquids, see Article 79 See also Section 800111, Exception 2 5For aerosols, see Article 88 Quantities may be increased 100 percent in spnnklered buildings When Footnote 10 also applies, the increase for both footnotes may be applied 7For storage and use of flammable and combustible liquids in Groups A, B E, F, H I M, R S and U Occupancies, see also UBC Sections 303 8,304 8 305 8,306 8 30713-307 15, 308 8,309 8,310 12,3118 and 312 4 8For wholesale and retail sales use, see Section 7902 5 10 2 9Spray application of any quantity of flammable or combustible liquids shall be conducted as set forth in Article 45 10Quantities may be increased 100 percent when stored in approved storage cabinets, gas cabinets or exhausted enclosures as specified m Sections 8001 3 2, 8003 3 13 2 and 8003 3133 When Footnote 6 also applies, the increase for both footnotes may be applied 11The quantities permitted m a spnnklered building are not limited 12Permitted m spnnklered buildings only None is allowed m unspnnklered buildings 13One pound (454 kg) of black sporting powder and 20 pounds (9 kg) of smokeless powder are permitted in spnnklered or unspnnklered buildings 14See definitions of Group H, Divisions 2 and 3 Occupancies in Section 216 15See Article 79 16A maximum quantity of 200 pounds (90 7 kg) of solid or 20 gallons (75 7 L) of liquid Class 3 oxidizers is allowed when such matenals are necessary for mainte nance purposes, operation or sanitation of equipment Storage containers and the manner of storage shall be approved 17For any amount, see Articles 28, 30 45, 46 48,50,74,75 76,77 and 78 as applicable for the hazard category 1-210 1998 CALIFORNIA FIRE CODE TABLE 8001 15 B TABLE 800t 15-B—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A HEALTH HAZARD MAXIMUM QUANTITIES PER CONTROL AREA' 2 When two units are given, values within parentheses are in pounds (Ibs )(Apply table as specified in Section 8001 15) MATERIAL 1 Carcinogens7 8 2 Corrosives 3 Highly toxics11 4 Irritants7 5 Radioacnves13 Alpha emitters Beta emitters Gamma emitters 6 Sensitizers7 7 Other health hazards7 g Toxics11 STORAGE3 Solid Pounds4-5.6 x 0.4536 for kg 100009 5000 10 NL 2mCi (74MBq) 200 Ci (7 4 X 106 MBq) 14 Ci (5 2 x 10s MBq) NX NL 500 LiquidGallons4-58 (pounds) x 3 785 lor L x 04536 for kg 10009 500 (10) NL 2mCi (74 MBq) 200 Ci (7 4 x 106 MBq) 14 Ci (5 2 x 105 MBq) NX NL (500) Gas Cubic Feet5 x 0 D28 tor m3 81069 8106 20" 810«9 0 2 mCi6 (7 4 MBq) 20 Ci6 (74 x 105 MBq) 14Ci* (5 2 x 104 MBq) 810«9 8L069 8106 USE3— CLOSED SYSTEMS Solid Pounds5 x 04536 for kg 100009 5000 10 NL 2mCi (74 MBq) 200 Ci (7 4 x 106 MBq) 14 Ci (52 x 105 MBq) NX NL 500 Liquid Gallons' (pounds) x 3 785 f or L x 0 4536 for kg 10009 500 (10) NL 2mCi (74 MBq) 200 Ci (7 4 x 106 MBq) 14 Ci (5 2 x 10s MBq) NL NL (500) GasCubic Feet5 x 0 028 for m3 8I069 810s 20<2 81069 02mCi (7 4 MBq) 20 Ci (7 4 x 105 MBq) 14Ci (52x10* MBq) 810s 9 810s9 81012 USE3— OPEN SYSTEMS Solid Pounds x 0 4536 for kg 500010 1 OOO5 3s 5 OOO9 ImCi (37 MBq) 100 Ci (3 7 x 106 MBq) 0 ICi (3700 MBq) 5 OOO9 5 OOO9 1255 Liquid Gallons (pounds) x 3 785 for L x 0 4536 for kg 50010 1005 (3)5 5009 1 mCi (37 MBq) lOOCi (3 7 x 106 MBq) OlCi (3700 MBq) 5009 5009 (125)5 I I I I I N L = Not Limited 'Control areas shall be separated from each other by not less than a one hour fire-resistive occupancy separation The number of control areas within a building used for retail or wholesale sales shall not exceed two The number of control areas m buildings with other uses shall not exceed four See Sections 204 and 8001102 2See Section 8001 1 1 Exception 2 3The aggregate quantity in use and storage shall not exceed the quantity listed for storage Quantities shall not exceed limits set forth in Sections 8001 15 2 and 8001 15 3 4The aggregate quantity of nonflammable solid and nonflammable or noncombustible liquid health hazard materials within a single control area of Group M Occu pancies used for retail sales may exceed the exempt amounts when such areas are in compliance with Section 8001 14 5Quantities may be increased 100 percent in spnnklered buildings When Footnote 6 also applies the increase for both footnotes may be applied 6Quantmes may be increased 100 percent when stored in approved storage cabinets gas cabinets or exhausted enclosures as specified in Sections 8001 3 2 8003 3 1 3 2 and 8003 3133 When Footnote 5 also applies the increase for both footnotes may be applied 7Carcmogens irritants sensitizers and other health hazards do not include commonly used building materials and consumer products which are not otherwise regu- lated by this code 8See also applicable federal and state OSHA guidelines 'The quantities allowed in a spnnkjered building ace not limited when exhaust ventilation in accordance with Sections 8003 1 4 8004 111 8004 222 and 8004 2 3 3 as applicable to the material condition is provided IUThe quantities allowed in a spnnklered building are not limited when exhaust ventilation in accordance with Sections 8003 1 4 8004 1 11 8004 222 and 8004 2 3 3 and spill control and secondary containment in accordance with Sections 8003 1 3 8004 1 4 8004 2 2 5 and 8004 2 3 6 as applicable to the material condition is provided 1 'For special provisions see Sections 8003 3, 8003 12 8004 2 3 7 and 8004 3 6 12Permitted only when located in approved gas cabinets exhausted enclosures or gas rooms See Sections 8003 3132 8003 3133 and 8003 3134 '^Licensed sealed sources for instruments calibration devices and equipment are exempt Licensing requirements and determination of whether a source is sealed or nonsealed shall be as set forth in Nuclear Regulatory Commission regulations Individual containers shall not exceed a quantity of 2 mCi (7 4 x 1Q7 becquerels) for alpha emitters 200 Ci (7 4 x 1012 becquerels) for beta emitters and 0 1 Ci (37 x 109 becquerels) for gamma emitters Ci = curies mCi = milhcunes 1-211 TABLE 800115-C TABLE 8001 15-D 1998 CALIFORNIA FIRE CODE TABLE 8001 15-C—EXEMPT AMOUNTS OF HAZARDOUS MATERIALS PRESENTING A PHYSICAL HAZARD—MAXIMUM QUANTITIES ALLOWED IN AN OUTDOOR CONTROL AREA1 2 3 CONDITION Material Flammable gas Gaseous Liquefied Flammable solid Organic peroxide Organic peroxide Oxidizer Oxidizer gas Gaseous Liquefied Pyrophonc Unstable (reactive) Water reactive Class Unclassified Detonable III III IVV 4 3 2 1 4 32 1 3 2 1 STORAGE SolidPounds X 04536 for kg NA NA 125 1 5 50 125 500 NL 1 10 250 4000 NA NA 4 J 5 50 NL 5 50 125 Liquid Gallons(pounds) x 3 785 lor LX 04536 lor kg NA 15 NA (1) (5) (50) (125) (500) NL (1) (10) (250) (4000) NA 15 4 (1) (5) (50) NL (5) (50) (125) GasCu FtatNTP x 00283lorirrl 750NA NA NA NA NA NA NANA NA NANA NA 1500NA 50 10 50 250 750 NA NA NA USE— CLOSED SYSTEM SolidPounds X 0 4536 forkg NANA 25 l/4 I50125500NL *2504000 NANA 1 '(-50 NL 550125 Uquid Gallons(poiuds) x 3785 for Lx 0(536 for kg N A 15 N A (V4) (1)(50) (125) (500) NL ('A) (2) (250) (4000) NA 15 (1) <'/4) (1)(50) NL (5)(50) (125) GasCu FtatNTP x 0 0283 for nf 750NA NA NA NA NANA NA NA NA NA NA NA 1500NA 10 2 10 250 NL NA NANA USE— OPEN SYSTEM Solid Pounds x 04536 tor kg NANA 25 V4 1 1025 100 NL V42 501000 NANA 0 V4 10 NL 1 1025 Liquid Gallons(pounds) x 3 785 for LX 04536 for kg NA NA NA C/4) (1)(10) (25) (100)NL (V4) (2)(50) (1000) NANA 0 0/4) 10 NL U)(10)(25) N A —Not applicable N L —No limit 'For gallons of liquids divide the amount in pounds by 10 2The aggregate quantities in storage and use shall not exceed the quantity listed for storage 3The aggregate quantity of nonflammable solid and nonflammable or noncombusuble liquid hazardous materials allowed in outdoor storage per single property under the same ownership or control used for retail or wholesale sales is allowed to exceed the exempt amounts when such storage is in accordance with Sec tion 8001 14 TABLE 8001 15-D—MATERIALS PRESENTING A HEALTH HAZARD- MAXIMUM QUANTITIES ALLOWED IN AN OUTDOOR CONTROL AREA1-2 3 MATERIAL Carcinogens Corrosives Highly toxics Irritants Other health hazards Radioactive5 5 7 Alpha emitters Beta emitterss Gamma emitters Sensittzers Toxics STORAGE Solid Pounds x D4536 for kg lOOOO 5000 1 10000 10000 2mCi(74MBa) 200 mCi (7 4 x 106 MBa) 14Ci(52 x10s MBa). 10000 500 Liquid Gallons(pounds) x 3 785 lor Lx 04536 for kg 1000 500 (1) 1000 1000 2 mCi (74 MBa) 200 mCi (7 4 x 10s MBa) 14Ci(52 x 105 MBa) 1000 (500) GasCu Fl atNTP xO 0283 form* 810 810 20" 810 810 2 mCi (74 MBa) 200mCi(74 x lO^MBa) I4Ci(52 x 105 MBa) 810 810 USE— CLOSED SYSTEM Solid Pounds X 0 4536 for kg 10000 5000 1 10000 10000 0 0 0 10000 500 liquid Gallons(pounds) x 3 785 lor Lx 04536 for kg 1000 500 (1) 1000 1000 0 0 0 1000 50 GasCu Ft aINTP X 00283 form1 810 810 204 810 810 0 0 0 810 810 USE-OPEN SYSTEM Solid Pounds x 04536 for kg 5000 1000 V4 5000 5000 0 0 0 5000 25 Liquid Gallons(pounds) X 3 785 lor Lx 04536 for kg 500 100 (V4) 500 500 0 0 0 500 (25) 'For gallons of liquids divide the amount in pounds by 10 2The aggregate quantities m storage and use shall not exceed the quantity listed for storage 3The aggregate quantity of nonflammable solid and nonflammable or noncombustible liquid hazardous materials allowed in outdoor storage per single property under the same ownership or control used for retail or wholesale sales is allowed to exceed the exempt amounts when such storage is in accordance with Sec tion 8001 14 ^Permitted only when used in approved exhausted gas cabinets exhausted enclosures or fume hoods 5For licensed nonsealed sources the maximum quantity allowed and the maximum quantity per container in outdoor storage per single property under the same ownership or control are as follows alpha emitters 2 millicunes (7 4 x 107 becquerels) beta emitters 200 curies (7 4 x 1012becquerels) for gamma emitters the maximum quantity allowed is 14 cunes (5 2 x 105 MBa) and the maximum quantity allowed per container is 0 1 cune (3 7 x 109 becquerels) 5Licensed sealed sources in instruments calibration devices and equipment are exempted 7 mCi—millicunes Ci—cunes 1-212 1998 CALIFORNIA FIRE CODE 8003 8003 134 SECTION 8003 — STORAGE 80031 General 800311 Applicability Storage of hazardous matenals where the aggregate quantity is in excess of the exempt amounts set forth in Section 8001 15 shall be in accordance with Sections 8001 and 8003 Storage of hazardous matenals where the aggregate quantity does not exceed the exempt amounts set forth in Section 80O1 15 shall be in accordance with Section 8001 For display and storage in retail and wholesale sales occupan- cies see Section 8001 14 8003 12 Signs Signs prohibiting smoking shall be provided in storage areas and within 25 feet (7620 mm) of outdoor storage areas 8003 13 Spill control and secondary containment for hazard- ous matenals liquids and solids 8003131 Applicability. Rooms buildings or areas used for the storage of liquid or solid hazardous matenals shall be provided with spill control and secondary containment in accordance with Section 8003 1 3 EXCEPTION Outdoor storage of containers on approved contain- ment pallets in accordance with Section 8003 1 3 4 8003132 Spill control for hazardous materials liquids Rooms, buildings or areas used for the storage of hazardous mate- nals liquids in individual vessels having a capacity of more than 55 gallons (208 2 L) or when the aggregate capacity of multiple vessels exceeds 1,000 gallons (3785 L) shall be provided with spill control to prevent the flow of liquids to adjoining areas Floors in indoor locations and similar surfaces in outdoor loca- tions shall be constructed to contain a spill from the largest single vessel by one of the following methods 1 Liquid-tight sloped or recessed floors in indoor locations or similar areas in outdoor locations 2 Liquid-tight floors in indoor locations or similar areas in out- door locations provided with liquid-tight raised or recessed sills or dikes, or 3 Sumps and collection systems Except for surfacing, the floors, sills, dikes sumps and collec- tion systems shall be constructed of noncombustible material and the liquid-tight seal shall be compatible with the rnatenal stored When liquid-tight sills or dikes are provided, they are not required at penmeter openings which are provided •with an open-grate trench across the opening that connects to an approved collection system 8003 133 Secondary containment for hazardous materials liquids and solids. When required by Table 8003 1-A, buildings, rooms or areas used for the storage of hazardous matenals liquids or solids shall be provided with secondary containment in accord- ance with this section when the capacity of an individual vessel or the aggregate capacity of multiple vessels exceeds the following Liquids Capacity of an individual vessel exceeds 55 gal- lons (208 2 L) or the aggregate capacity of multi- ple vessels exceeds 1,000 gallons (3785 L) Solids Capacity of an individual vessel exceeds 550 pounds (248 8 kg) or Che aggregate capacity of multiple vessels exceeds 10 000 pounds (4524 8 kg) The building room or area shall contain or drain the hazardous materials and fire-protection water through the use of one of the following methods 1 Liquid-tight sloped or recessed floors in indoor locations or similar areas m outdoor locations 2 Liquid-tight floors in indoor locations or similar areas in out- door locations provided with liquid-tight raised or recessed sills or dikes, 3 Sumps and collection systems, or 4 Drainage systems leading to an approved location Incompatible materials shall be separated from each other in the secondary containment system Secondary containment for indoor storage areas shall be designed to contain a spill from the largest vessel plus the design flow volume of fire-protection water calculated to discharge from the fire-extinguishing system over the minimum required system design area or area of the room or area in which the storage is located, whichever is smaller, for a penod of 20 minutes Secondary containment for outdoor storage areas shall be designed to contain a spill from the largest individual vessel If the area is open to rainfall, secondary containment shall be designed to include the volume of a 24-hour rainfall as determined by a 25-year storm and provisions shall be made to drain accumula- tions of groundwater and rainwater A momtonng method shall be provided to detect hazardous matenals m the secondary containment system The momtonng method is allowed to be visual inspection of the primary or secon- dary containment or other approved means Where secondary containment is subject to the intrusion of water, a momtonng method for detecting water shall be provided. When momtonng devices are provided, they shall be connected to distinct visual or audible alarms Drainage systems shall be in accordance with the Plumbing Code and the following 1 The slope of floors HI indoor locations or similar areas in out- door locations to drains shall not be less than 1 percent, 2 Drains from indoor storage areas shall be sized to carry the volume of the fire-protection water as determined by the design density discharged from the automatic fire-extinguishing system over the minimum required system design area or area of the room or area m which the storage is located whichever is smaller 3 Drains from outdoor storage areas shall be sized to carry the volume of the fire flow and the volume of a 24-hour rainfall as determined by a 25-year storm, 4 Matenals of construction for drainage systems shall be com- patible with the matenals stored, 5 Incompatible matenals shall be separated from each other in the drainage system, and 6 Drains shall terminate in an approved location away from buildings, valves, means of egress, fire access roadways adjoin- ing property and storm drains 80031.3 4 Containment pallets When used as a substitute for spill control and secondary containment for outdoor storage in accordance with the exception in Section 8003 1 3,1, containment pallets shall comply with the following 1 A liquid-tight sump accessible for visual inspection shall be provided 2 The sump shall be designed to contain not less than 66 gallons (249 8 L), 1-213 1997 UNIFORM FIRE CODE 80031 15 TABLE 80031-A 8003 115 Required detached storage Group H Occupancies containing quantities of hazardous materials in excess of those set forth in Table 8003 1-B shall be m buildings used for no other pur- pose, shall not exceed one story in height and shall be without basements, crawl spaces or other under-floor spaces TABLE 8003 1 A—REQUIRED SECONDARY CONTAINMENT—HAZARDOUS MATERIALS SOLIDS AND LIQUIDS STORAGE MATERIAL INDOOR STORAGE Solids Liquids OUTDOOR STORAGE Solids Liquids 1 Physical Hazard Matenals Combustible dusts Combustible liquids Class II Class 01 A Class m-B Cryogenic liquids Explosives Flammable liquids Class I A Class I-B Class I-C Flammable solids Organic peroxides Oxidizers Class UD Class I Class II Class m Class IV Class V Class 4 Class 3 Class 2 Class 1 Pyrophoncs Unstable (reactives) Water reactives Class 4 Class 3 Class 2 Class 1 Class 3 Class 2 Class 1 NR NA NA NA NA NA See Article 79 See Article 79 See Article 79 See Article 75 See Article 77 NA NA NA NR R R R R R NR R R R R NR R R R NR R R NR See Article 79 See Article 79 See Article 79 NA R R R R R NR R R R R R R R R NR R R NR NR NA NA NA NA NA See Article 79 See Article 79 See Article 79 See Article 75 See Article 77 NA NA NA NR NR NR NR NR NR NR NR NR NR NR NR R R R R R R R See Article 79 See Article 79 See Article 79 NA NR NR NR NR NR NR NR NR NR NR R R R R R R R R 2 Health Hazard Materials Carcinogens Corrosives Highly toxics Irritants Other health hazards Radioactives Sensitizers Toxics NR NR R NR NR R NR R NR R R NR NR R NR R NR NR R NR NR R NR R R R R R R R R R NA = Not Applicable NR = Not Required R = Required UD = Unclassified Detonatable 1-215 NU o 0) TILE-MATE Dual Purpose Thin-Set Mortars PRODUCT DESCRIPTION TILE-MATE Thin-Set Mortars are composed of select, proprietary chemicals, carefully graded aggregates and Portland cement TILE-MATE Thin-Set Mortars are pre-blended and ready to use TILE-MATE Mortars are recommended for setting cerarmc tMe and dimensional stone over brick, cement plaster, concrete, concrete block and glass mesh mortar units. When used In conjunction with HYQRQMENT Multi-purpose Acrylic Latex Additive, TILE MATE Mortars can be used for setting tie over structurally sound, exterior grade plywood and for setting glass block All TILE MATE Thin Set Mortar* are suitable for use on horizontal and vertical surfaces Product selection should be based on the absorptive characteristics of the tile being installed Ail TILE-MATE Thin-Set Mortars can be usedfor both interior and exterior applications TILE MATE 710/760/70713 This product Is the premium TILE MATE Thin Setting System TILE MATE 710 and 760 are specially designed for setting absorptive, semi-vitreous and vitreous tiles, marble and dimensional stone, while giving maximum work ability/troweling characteristics 710-wntte, rao-gray, 70713-whJte (West Coast) TILE-MATE HOT WEATHER FORMULA Specially formulated, TILE-MATE Hot Weather Formula Is designed for setting all semi-vitreous and vitreous tile,marble, dimensional stone, slate and absorptive tile when job site conditions require extended open time at higher temperatures. , Color white TILE-MATE 972 MP This dual purpose thin-set mortar is designed for setting quarry tile, pavers, ceramic mosaics, elate, stone and all vitreous, and semi-vitreous tileColor gray TILE-MATE 971 (Floors Only) TILE-MATE 971 is a high grade thin-set designed to set quarry tile, pavers, ceramic mosaics and all vitreous, and semi-vitraous tlieColor gray TYPICAL PHYSICAL PROPERTIES Alt TILE-MATE Mortars meet or exceed ANSI A 1181-1985All TILE-MATE Mortars meet or exceed ANSI A 118.4-1985 for latex-Portland cement mortar when used with HYDRO-WENT Multi-Purpose Acrylic Latex Mortar Admixture and Grout Additive Bostik Boston Street, Middteton, MA 01949 (800) 7-BOSTIK . (508) 777-0100 • Technical Services (800) 523^530 O, OH . UDNG85«CH,CW • CQNVERS GA • CM.LUS TX NU • Easy mixing * High Compreesiva strengths • High Tensile strengths • Excellent Initial grab PRODUCT FEATURES AND BENEFITS • Non shrinking • Excellent Workability • Select aggregate Gradation IMPORTANT For ail back-mounted tiles, be certain that sufficient TILE-MATE is used to bond each Individual tile. COVERAGE For ail TILE MATE Thin-Set Mortars up to 13 square feet per pound at 3/32" to 1/8" bed thickness PACKAGING Moisture-proof three-ply 50 pound sacks DIRECTIONS FOR USE Mixing: Add 5 to 6 quarts of Hydroment Multipurpose Latex Addlt.ve or cool, clean drinkable water ONLY to 50 pounds of TiLE-MATE Thin Set Mortars, and mix to a stilt, trowelabie consistency Use only slow speed bucket mixers or mortar boxes for mixing, do not use high speed drills (greater than 200 rprrfs; High speed mixing entraps air and decreases the ultimate strengths of the mortar Allow the mixture to stake for 15 minutes and remix before applying Tl L&MATE Th in Set Mortars should be remixed occasionally during use- The pot life of TILE-MATE Thm-Set Mortars is approximately 2 to 3 hours depending upon temperature and humidity Requirements For Plywood Subfloors (Interior Uso Only) Maximum joist spacing shall be 16" on center with a maximum der lection of I/360 of the span Plywood type shall be underlayment with exterior glue or exterior type C-C plugged (exterior untierlayment or better) If the existing floor Is less than 1" thick, glue and nail 1/2" plywood to the floor Glue and nail using 5d or 6d cement coated or screw shank nails on 6' center along with pane! edges and a maximum 8" on center each way throughout the panel Allow 1/4" gap between underlayment sheet edges and all areas where they abut walls, drains, posts, etc. These areas shall be filled with TILE-MATE Thin-Set Mortars when the tilas are installed Clean and rough send the plywood Due to the limitations of plywood as « su&stnte material, TILE MATE Thin-Set Mortars is not Intended for use on plywood In exterior/ wet applications or on plywood in heavy traffic areas. Substrate deflection is greater than 1/380 but lass than 1/240 (up to 1* per 20 ft span) TILE-MATE Thin-Set Mortars must be mixed with B-7 quarts of Flex-s-Lastic Mortar Admixture per 50 pounds of mortar. Caution Flex a-Lastic is not recommended for use with TILE MATE 972 MP Application AM surfaces to receive tile must be clean and tree of dust, grease, oil, curing compounds and any foreign material Apply a thin coat of TILE-MATE Thin-Set Mortars with the flat edge of th« trowel to achieve a good mechanical bond Then apply the mortar with the appropriate sized notch trowel (See Illustration Below) Recomb the mortar with a notched trowel if any evidence or skinning or setting is evident Apply TILE-MATE Thin-Set Mortars to an area no greater than can be tiled In 30-45 minutes Always test the bond of backmounted sheets of tile to insure adhesion of the full sheet Suggested Notched Trowtte For Maximum Performamw AAAAAi 3/tfi"xs/aa* I nrui ceramic moniesmounted ceramics ceramics & pav»r» 8'xft'iB'xB" 8'x 8"*. 12* X12' quarry tile lugged back & Mexican purer ttle Tiling: Tile should be applied with a twisting motion Into a fresh bed of TILE-MATE ThlrvSel Mortars. Always beat the t »e in wttn a beating block as soon as possible TO insure maximum contact and bond A finished mortar bed thick- ness 3/32" to 1/8" thick after "beat In" is required Curing' All traffic should be kept off th« installation for 72 hours Grouting. Grouting may begin using Hydroment Joint Filler/ Ceramic Tile Grout, Hydroment 1800, or U-Poxy AARII, only after • firm set has taken place. Set times will vary depending upon the mortar selected for use, ambient, slab and material temperatures. Follow normal grouting clean-up procedures. When U-Poxy AAR II is used for grouting, the installation must be protected tor 48 hours before grouting com*rnencvti >n iCt*t*H*U«i"»* who™ «vt«trot«4*fl«M»ti«»n I* smarter th«o U9«0 bet l«*e than IS34O, yndilu+art Mydnemant Multi-Purpose Acrylic must be used to mix Hydroment Joint Filler/Ceramic Tile Grout Marble installations with grout joints 1/16* or less may be grouted with Hydroment Dry Tile Grout Cleaning Clean excess mortar aa work progresses. Do not allow to dry on surface of tila rafi MS HYDROMENT® FLEX-A-LASTIC™ FLEXIBLE MORTAR ADMIXTURE PRODUCT DESCRIPTION HydromenP Flex A Lastic™ Mortar Admixture is a new generation acrylic polymer emulsion designed to incorporate flexibility and superior adhesive performance into Tile Mate Thin Set Mortars When used to mix Tile-Mate* 710/ 713,760, or 971 Thin Set Mortars, Hydrament Ffex-A Lastic provides the following performance benefits • Outstanding Flexural and Tensile Strengths • Outstanding Shear Bond Strengths • Tenacious Grab » Bonding Capabilities to "difficult substrates" such as vinyl composition We, vinyl flooring asphalt- based cutback adhesive residue and exterior grace plywood • Outstanding Freeze/Thaw Resistance • Self Curing/Non Reemulstfytng • Can be used to set ceramic tile, synthetic marble and stone in installations subject to deflection of up to \l 240• Can be used to install heavy/large ceramic tile (such as 12*x12" X3/8") marble and stone vertically PRODUCT USES Hytjroment Flex A Lastic when used to mix Tile-Mate 710/713,760, or 971 is designed to set all types of ceramic Hie, marble and dimensional atone Indoors and outdoors, for both vertical and horizontal Installations RECOMMENDED SUBSTRATES. Fiex-A-Lastic modified Thin Sets are designed lor u&e over • Concrete * Exterior Grade Plywood • Asphalt Based Cutback Adhesive Residue • Cementitious Backer Units • Hydroment® Ultra Set™ • Existing Ceramic THe • Existing Vinyl Composition Tile/Vinyl Flooring * Existing Brick • Gypsum Plaster {when coated witn Hydroment Ultra-Set) • Gypsum Board (when coated with Hydroment Ultra-Set) • Formica and other Laminated Surfaces STANDARDS Hydroment Flex A-Lastic meets or exceeds ANS1118 4 when mixed with Tile-Mate 710/713,760, or 971 Thin Set Mortar Typical Physical Properties with Tile-Mate 710/713, 760, or 971 Thin Sets Open Time 70*F Adjustability 70'F Coverage Fiexural Strength Tensile Strength Shear Strength Ceramic Mosaic Tile Quarry to Wood 90-120 minutes50-90 minutes 70-60 sq ft at 1/8" bed thickness U days 635 psi 14 days 400 psl 23 days 350 psi Shear Strength (psi)7 day 28 day 350 482 170 190 Packaging 2,5, and 56 gallon containers Bostik Boston Slreet MfcttMon, MA 01949 (800) 7-BOSTtK • (SOfi) 777-0100 * Technical Son/ices (800) 523-6530 NO 123 P005/005 SUBSTRATE PREPARATION Ail surfaces to receive tile must be ciean and free of dust, grease, oil, curing compounds, vinyl floor waxes and any other foreign material All substrates must be properly anchored, structurally sound and free from deflection In excess of 1/240 "~N, Plywood floors must ba exterior grade Maximum joist spacing shall be 16" on center with a maximum j deflection of 1/240 of the span Plywood shall be undertayment type C-C plugged (exterior underlayment or better) if the existing floor is less than 1" thick, glue and nail 1/2" plywood 1o the floor Glue and nail using 5d or6d cement coated or screw shank nails 6" on center along panel edges and a maximum 8" on center each way throughout the panel Allow 1/4" gap between underfayment sheet edges and all areas where they abut walls, drains, poets, etc These areas are to be filled with Hydroment Flex A Laatic modified Thin Set Mortar Clean and rough aand the plywood NOTE Due to the limitations of plywood as a substrate material, this product is not Intended for use on plywood in exterior/wet applications or on plywood in heavy traffic areas Caution Due to the relatively low compressive strength ana over-all softness of quarried marble, natural marble should never be installed over substrates with deflection in excess of I/360 MIXING Adc 6 7 quarts of Rex-A-Lastic Mortar Admixture per 50 pounds ol Tile-Mate Thin Set Mortar and mix tc a creamy consistency Use only slow speed mixers or mortar boxes for mixing, do not use high speed dniis{o/eater than 200 RPM's) Allow the mixturetoslake for 10-15 minutes and remix Do not add water or any other liquids before, during or after the initial mixing APPLICATION Apply a thin coat of Thin Set Mortar with the flat edge of the trowel to achieve a good mechanical bond to trie substrate, then comb the mortar with the appropriate sized notched trowel as indicated below Recomb fhe mortar li any evidence of skinning is present Temperatures and humidity will effect open time, therefore, both Ftex-A Lastic and Tile-Mate should be kept in a cool, shaded area to control the products setting characteristics. Hot ambient and material temperatures (greater than 85"F) will acceler- ate the set of Ftex-A-Lastic modified Thin Set Mortars. Cooler ambient and material temperatures (less tiian 65"F) will retard the set time It ic advisable to spread no more Thm Set Mortar than can be tiled within 30-40 minute* OVER EXISTING VINYL FLOORING *> Hydroment Flex A Lastic modified Tile-Mate Thin Set Mortar can be used to set tile over existing vinyl "— flooring, provided it is well bonded to the substrate. Any loose pieces of vinyl tile, flooring or cutback adhesive should be removed prior to the application of Flex A Lastic, again making sure the exposed substrate is suitable for application Follow mixing Instructions listed above Caution. Do not sand or abrade vinyl asbestos tile prior to applying Flex-A-Lastlc modified Tile Mate Thm Set Mortar The use of F!ex-A-Ustic is not recommended over cushion backed sheet vinyl flooring OVER HYOROMENT ULTRA-SET* Refer to Ultra-Set installation instructions and apply Ultra Sat as directed Application of Flex-A-last ic modified thin set mortar over Ultra-Set must commence wittvn 72 hours of Ultra-Set curing GROUTING Grouting may begin using Hydroment Joint Filler/Ceramic Tile Grout, Hydroment 1900, or U Poxy AAR II, only after a firm set has taken place. Set times will vary depending upon the mortar selected for use, ambient, slab and material temperatures Follow normal grouting clean-up procedures When U-Poxy AAR II is used for grouting, allow the Flex-A-Lastlc modified mortar to cure for 48 hours before grouting commences, in installations where substrata deflection is greater than I/360 but less than i/240, undiluted Hydroment Multi Purpose Acrylic must be used to mix Hydroment Joint Filler/ Geramie THe Grout Marble Installations with grout joints 1/16" or less may be grouted with Hydroment Dry Tile Grout CLEAN UP Clean up should begin as soon as possible due 1o the superior adhesive capabilities of Flex A Lastic modified Thm Sets Partially cured material may be removed from tools using Hydroment Remove and a scrubbing pad Fully cured material is extremely difficult to remove Suggested Notched Trowel* For Maximum Performance AAAAA I aiie-M>usa- I 1/4'KIM' ceramic mosaics mounted mosaicsAvg 7545 Sq ft 4" X 4' &. 4" X 8* ceramics & pavers Avg 70-804$ ft. inn 1/4* x 3*' 8' x 6" & 6' x 8" quarry tile MS 50-60 sq ft 6* X 8* & 12' x 12* lugged back & Mexican paver tile Avg 35-40 K) ft T1» 1/35 HIM * J.U n Laurence xnc 2503 E VERNW AVE LOS ANOE.ES, CA 90053 (213) 588 1281 EMERGENCY PHONE NUMBER {24 MRS) U S - CHEMTREC (800) 424-9300 OR (703) 527-38S7 CANADA • CANUTEC (613)995-666o DATS PREPARED MSDS NUMBER 3/28/95 33SC/96 33SCSIUCONE SEALANT, CLEAR CHEMICAL PRODUCT IDENTIFICATION GENERIC DESCRIPTOR SUOONE RASTOMER PHY3I5AL FOIW PASTE COIOP CLEAR ODOR ACETIC ACID ODOR N'FPA PROFILE HEALTH t FWMMASIUTY I REACTIVfTY t.NOTE NFRA * NATIONAL FIFE PROTECTION ASSOOATQN OSHA HAZARDOUS INGREDIENTS CAS NUMBER OOW3343 OTO'DSB WIN 2 11 COMPONENT METHYJRiACSTOXYSILANE SILICA. AMORPHOUS ETKYLrftl*C£TCXY5lLANE EXPOSURE LIMITS SEE ACETIC ACID COMMENTS OBSERVE PARTCUUTES LIMITS OSHA PEL SEE ACETIC AC'D COMMENTS BilfiT fi mntal COMHENTS ACE IIC ACID 13 FORMED UP04 CONTACT WITH WATER OR HUMID AIR PROVIDE ADEQUATE VENTILATION TO CONTROL EXPOSURES WlT gUIOCUMES OF OSHA 3a TWA 10 30m AND ACGIH TLV TWA Ifl.pun STSt. ISeom EFFECTS OF OVEREXPOSURE ACUTE EFFECTS BY8S DIBKT CaMTACT IPRiWtS MODEPATELV WITH HECNESS AND SWatlNG <*IN * "4iMRi i= snnm PVPfi«UBS ^EBS -WAN :« irounr -, MW irnrrm: ncrcATC!i ppOLewsiss &ew I IhHAWTIQN WPQR OVEREXPQSURE MW !RRn?ATE EYE^ N03E AND THROAT OftA* SMALL AMOUNTS ' USf =TC SHOULD NOT INJURE SWALLOWING 'jWGE AMOUNTS MAY CAUSE Of8E3TOE DtSCOMFOP' E£R^eC TO TnE MOUTH 3Y HNGERS OUR NG REPEATED EXPOSURE EFFECTS SKIN NCNE (CWXVN INHALADOM MNEKMOV/N ORAL NONE KNOWN SPECIAL HAZARDS THIS MAIsRIV CONTWMS TH« FOLLOWINa COMPOKEtfTS WITH THE SPSOAL KAZAROS LISTED B6LOW CARCINOGENS NONE KNOWN, TSRATOOENS NONE KNOWN MUTAQENS. NONE KNOWN BEPKOOUCnVE TOXINS NCNE K.NOWJ SLKSITI2EAS NOfffi KNOWN THE ABOVE LISTED POfENTIAl. EFFECTS Of OVEREXPOSJRE ABE BASED ON ACTUAL DMA RESULTS OF STUDIES PERFORMED UPON 5IMILAP COMFOSITIOMS COMPOivENT DATA ANO/OB EXPEHT HEMCW OF T»Z PFOOLIgT j FIRST AID MEASURES EYES IMMEDIATEiy FL'JSH WITH W«TER FOR 15 MINUTES SET MEWCAL ATTENTION SKM PEhOVE FROM SKIN AND WASH THC«OIX5HLY MTH SO*P AND VWiTER OR WATERLESS CLEAN5FR GET MEOCAL ATTEVHON \f iRRITATKttl CP OTHER iLL EFPECTS DEvaOP OR PERSIST INHALATION REMOVE TO FRESH AIR OPAL. NO FIBSr AIQ SHOD1 C BE NEEDED ACCOqOlNC "0 F^KbLIMS COMDITiON .jUkO SPECIFICS OF EXPOSURE. FIRE FIGHTING MEASURES FLASH POIHT [CLOSED CUP): NOT APPLICABLE SOLID.AUYOIGMmON TEMPERATURE r«T DETEPMNEO FUHWASLfn UMTS IN AIR r>CT OETCPMIN2D C.WBON DWXIDE (CO.J WATER VMTEH F03 (0=1 SPRAY) 3FY CH£MCAL FOAM UH3U(TABL5 IXTtH3UI5HtW MEDIA NCAE PISE RGHT1NG PR05FDUBES SELF CONTAINED 3REATHIHG APPARATUS AND PPOTrCTIVS CLOTUNG SHOULD BE WCflM IN FI5HTIWG FIRES NVOLVING CKiMCAlS. IF LAROE UHOSC IS IWCLVED EVACUATE AREA. UNUSUAL r\M HAZARDS HCH-ifc HAZAR50US DSCOMPOSIT10N PRODUCTS "TCWlAi BREAKDOWN OFTHS PftOIHJCT DUWNQ FIRE OR VERY HIGH HEAT i ONjriONS NAV EVOLVE THb HXLOWNG HAZARDOUS OECOMPCSITION PRCDUCTS SILICON DIOXIDE CAH83N OXIDES AND TRACES OF KtOOMPLBTEtt BURNED CAPBOM CO'JIPOyHOS ' ACCIDENTAL RELEASE MEASURES CONTAINMENT/CLEANUP- DiSP-OSAi. OF COLLECTED PRODUCT RESIDUES AND CLEANUP VATE.^MLS MAYBE QOVEnNMEvmLU PEGi-LArtD. OBSERVE ALL APPLICAB. E LOCAu STATE AND FEDERAL AASTE MANAGEMENT REGULATION SCRAPE UP AND CCWTAIM FOR SALVAGE OR DISPOSAL OBSERVE ALL PER SONAt PTOTECTIOh EQUW.1EV flH OMMENDATIONS DESCRIB5D IN SECT|0»K 5 AND I y^AJ,, STflfF Mil FFDFrW R^PORTlhifi HFnil.fPWFWT? WHY irtS MAIERIW. iNTO THE ENVIRONMENT SEE APPLCAflLE REGULATORY COM1W iCE INFOPMATiON « SECT,ON 15 KITE SEE SECTION S FOS PERSONAL PPOTECTIVE 3QUFWENT FOR SPILES HANDLING AND STORAGE fANDUNG NO SPECIAL PPECAUT1CNS STORA6E XEE:» CONTAINER CLOSED AND STORE AWAY FROM WATER OR MO'STURE PRODUCT. 33SC SILICONS SEALANT, CLEAR EXPOSURE CONTROLS/PERSONAL PROTECTION ENQWEeNHa CONTROLS LOCAL EXHAUST RECOMMENDED GENERAL. WNnUTION RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT FOR KHJTIME HANDUNC EVES USE PROPER PROTECTION SAFETY GLASSES AS A MtWUM SKIH WASHING a MEAriME AND END OF SHIFT IS ADEQUATE BISTABLE GLOVES MO SPECIAL PROTECTION NEEDED WHALATION. USE RESPIRATORY PROTECTION UNLESS ADEQUATE LOCAL EXHAUST VENT'LATOK (S PROVIDED OR AIR SAMPLING DATA SHOW EXPOSURES *fl£ WTH'N RECOMMENDED EWOSURE GUIDELINE! INDUSTRIAL HYGIENE PERSONNEL CAN ASSIST |ft JUDSNG THE ADEQUACY OF EXISTING ENGINEERING CONTROLS. SUITABLE RESPIRATOR ORGANIC VAPOR TVPE PERSONAL PROTECTIVE EQUIPMENT FOR 6PILL3 EYES. USE PROPER PPOTECTCN SAFETY QLASSES AS A MIWM SKIN WASHIN3 AT MEALTIME Ah)0 END OF SHIFT IS ADEQUATE INMAUTION/SWTAaE RESPIRATOR USE RESPIRATORY PROTECTION UNLESS ADEQUATE LOCAL EXHAUST VEIY7ILATION IS PRO- VIDED OR AIR SAMPLING DATA SHOW EXPOSURES ARE WITHIN RECOMMENDED EXPOSURE 3UIDELINE3 INDUSTRIAL HYGIENE PERSOWEL CAN ASSIST N JUDGING THF ADEQUACY DF EXISTING ENGINEERING CONTROLS. WICAUTlONAfff MEASURES WOO EYE CONTACT AVOID BflEATHKO VAPOR KEEP CON-TAINER CLOSED USE REASONABLE CARE. OOMMSNTS. PRODUCT EVOLVES ACETIC AClD (HOAc! WHEN EXPOSED TO ilWER Cfi H JMIO AIR, PROVIDE VEND UT10N OURING USE TO CONTROL HOAC WITHIN EXPOSURE GUIDELINES (SEE SECTON 2) OB USE RESPIRATORY PROTECTION MOTH THESE PF1ECAUTIONS A3E FOP ROOM TEUPEPATURE HAMUNO USE AT ELEVATED TtMPfcHAIUHE OR AEHOSOL/SPHAY APPLICATIONS MAY REQUIRE AOOED PHECWTKJNS. IX PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL F0fl«. PASTE SPECIFIC GRAVITY fl 2SC 1 04 BOUNQ POINT NOT APPLICABLE SOLUBILITY « WATER NONE COLOR; COLORLESS VISCOSITY HOTAPPLI3ABLE VAPCS PRESSURE 0 IX NOT APPLICABLE pH NOT APPLICABLE OOOB ACETIC ACO OOOR FSSEDNa/MELTUW POHT NCT OETERMINEO MPOROENaTY NOT APPLICABLE VOLATILE CONTENT NOT APPLICABLE NOTE ThE ABOVE INFORMATION IS HOT INTENDED TOR USE IN PflEHWINS PROOtCT SPECIRC/mONS. CONTACT SUPPUER BEFORE WfWINQ SPECIRCATIONS STABILITY AND REACTIVITY CHEMCAL STABILITY STABLE HAZARDOUS POLYHEWZATOH: HAZARDOUS PCiYMERIZVIOM WILL NOT OCCUR CONDITIONS TO AVOB- NONE MATERIALS TO AVOID OXIDiBHO MATERIAL CAN CAUSE A REACTiON COMMENTS WTER MOISTURE OR HLMIO AID CAN CAUSE HAZARDOUS VAPORS FO FORM AS OESCRI8S> 9* SECTION 2 IOX!COLOG5CAL INFORMATION i OPTIONAL SSCT10M CCMPLCTg INFORMATION NCT YH AVAHA6LE ECOLOGICAL INFORMATION I OPTJOWt SECTION OOMRETS IHfORHWIQHT NCT YET AVAILABLE DISPOSAL INFORMATION ROW HAZARD CLASS (40CFR Mt) ttHEN A DECISION IS MADE TO DISCARD THIS MATERIAL AS RECEIVED 'S IT CLASSIFIED AS A HAZARDOUS WASTE"- NO FEDERAL HAZARDOUS WASTE CODE W CHARACTERISTIC WASTE IQNITABLE MA CORROSIVE NA REACTIVE NA TCLP MA STATE OB LOCAL UUVS MAY IMPOSE ADDITIONAL REGULATORY REQUIREMENTS WOAWINa DISPOSAL DOT IMTOMAT1QN (4KFR 17Z.T01) HAZARD CLASS NOT APPLICABLE TRANSPORT INFORMATION PBOP6R SWPTOIQ NAVE NOT APPLICABLE UMUL NUMBER. NCR APPUCABLE HAZARD TECHNICAL (Ultt NOT APPLICABLE PACKING GROUP NOT APPLICABLE REGULATORY INFORMATION CONTENTS Or THS MSOS COMPLY VmHTHEC««AHAZAKiCOMMUHOnONSTOOA«>29CfH H101200 T8CA STATUS ALL CHEMICAL SUBSTANCES FOUND N THS PRODUCT COMPl* WITH THE TOXIC SUBSTANCES CONTFKX ACT IWENTORY REPORTING REQUIREMENTS. BPA SARA TITLE U CHEMICAL U8T1N08 SeCTOH 302 EXTREMELY HAZARDOUS SUBSTANCES NONE SECTION W CEBCU HAZARDOUS MMTANCES; NONE SECTION S1* HAZARD CLASS ACUTE I£S CHRONIC MC FIRE «B PRESSURE $0. REACTIVE ISECTION 313 TDXC CHEMICALS NONE PRESENT OR NOME PRESENT IK REGULATED QUANTITIES, SUPPLEMENTAL STATE COMPLIANCE INKMUDONCALIFORNIA WARNING THIS PRODUCT COMMNS THE FOLLOWING CHEMICAL® LISTED SY THE STATE Of CAUPOPNIA UNDER THE SAFE DRMON6 WATER AND "OXlC ENFORCEMENT ACT OF 1986 (PROPOSITION fli| AS SEWS KNOWN TO CAUSE CANCER- NONE KNOWN WARMING THIS PRODUCT CONTAINS THE FOLLOWING CHEMIOAUS) JSTED BY THE STATE OF CALIFORNIA UNDER 1HE SAFE DRNK'NG VWffER AND TOXIC ENFORCB«NT ACT OF 1968 (PflDPOSlTIOS 65) AS BEMG KNOWN TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM NOME KNOWN MAaSACHUSEHS CAS NUMBER WT* COMPONENT M76J»S6? 11 Sl'O AVORPHOUS CASNUMBEB 370)31878 DOUS3340017489779 OC7SJ18B CASMUHSER 070131678 007431869 WT% COMPONENT«3 DI«THYLSLOXAN:2 METKYLTHWCEHOXVSILANE2 ETHYLTRIACETOXYSILANE11 SILICA AMORPHOUS FUMED 11656 «m. COMPONENT 63 DIVETHYL SILOKANE HVDROXY TERMINATED 11 9iLCA ASWRPHOJS WARRANTY INFORMATION THIS MffORmMTON IS OFFEflEO K 3000 FAITH AS TYHCAL VALUES AND hOT AS A PWXXXn'SPECPCATIOfI NO WARRANTY EXPRESSED OR IMPLIED. IS HEREBY MADE THE RECOMMENDED INCUSTOAL HYQIENE AND SAFE HANDLING PROCEOURE6 ARE BELIEI^D TO BE GENERALLY APPLICABLE. HOWEVER EACH USER SHOULD RE^EW THESE RECOHMENOATIONS IN THE SP£O-'lC OMTECT OP THE INTENDED USE AMD 5ETEBS1HE WHETHER THEY ARE APPflOPRIATS AVD3424-C REV B/96 I MATERIAL SAFETY DATA SHEET THE GIBSON-HOMANS COMPANY 8701 1 PAGE 1 ABBREVIATIONS NA = NOT APPLICABLEND = NOT DETERMINEDNE = NOT ESTABLISHED SECTION I-MATERIAL IDENTIFICATION AND USE HEALTH = 0 FLAMMABILITY = 0 REACTIVITY = 0PERSONAL PROTECTION = + + SEE SECTION VIII MATERIAL NAME/IDENTIFIER SHUR-STIK C-ll ULTRA-CLEAR ADH MANUFACTURERS NAME AND ADDRESS GIBSON-HOMANS COMPANY1755 ENTERPRISE PARKWAY TWINSBURG, OHIO 44087 EMERGENCY TELEPHONE NO (DAY) 330/425-3255 (24 HOUR) 440/843-2982 DATE PREPARED JANUARY 20, 1988 REVISED DECEMBER 6, 1994 CHEMICAL FAMILY MIXTURE CHEMICAL FORMULA/MOLECULAR WT NA TRADE NAME AND SYNONYMS NAMATERIAL USE WALLCOVERING ADHESIVE SECTION II-HAZARDOUS INGREDIENTS CHEMICAL NAME OSHA-PEL ACGIH-TLV LD50/LC50 % WT NACAS #-CARCINOGEN - Sara Title III, Sect 313 reportable SECTION III-PHYSICAL/CHEMICAL CHARACTERISTICS VAPOR PRESSURE(MM) 25 DEG C 18 MMBOILING POINT 212 DEG FVAPOR DENSITY(AIR-1) >1 SPECIFIC GRAVITY/DENSITY (G/ML) 1 0-1 05 MELTING/FREEZING POINT NA EVAPORATION RATE(BUAC=1) <1 SOLUBILITY IN WATER MISCIBLE %VOLATILE BY VOLUME 85-95 PH 70-90COEFFICIENT OF WATER/OIL DISTRIBUTION ND ODOR THRESHOLD (PPM) ND APPEARANCE, PHYSICAL STATE AND ODOR CLEAR, TRANSLUCENT PASTE I SECTION IV-FIRE AND EXPLOSION DATA FLASH POINT >200 DEG F - WATER BASED UPPER EXPLOSION LIMIT NA AUTO IGNITION TEMPERATURE NA LOWER EXPLOSION LIMIT NA SENSITIVITY TO CHEMICAL IMPACT NA RATE OF BURNING NAEXPLOSIVE POWER NA SENSITIVITY TO STATIC DISCHARGE NAEXTINGUISHING MEDIA NA SPECIAL FIRE FIGHTING PROCEDURES NA UNUSUAL FIRE AND EXPLOSION HAZARDS PRODUCT WILL NOT BURN AS SUPPLIED DRIED FILM MAY BURN IF SUBJECT TO SOURCE OF IGNITION FLAMMABILITY NOUNDER WHAT CONDITIONS NA I I I I I SECTION V-REACTIVITY DATA STABILITY-MATERIAL IS~ STABLE CONDITIONS TO AVOID NA INCOMPATIBILITY (MATERIALS TO AVOID) STRONG OXIDIZERSHAZARDOUS DECOMPOSITION/COMBUSTION PRODUCTS BURNING OF DRIED FILM MAY RE- LEASE OXIDES OF CARBON AND NITROGENHAZARDOUS POLYMERIZATION WILL NOT OCCURCONDITIONS TO AVOID NA ============ SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY SKIN - INGESTION EFFECTS OF OVEREXPOSURE, CHRONIC NONE KNOWN EFFECTS OF OVEREXPOSURE, ACUTE SKIN MAY CAUSE SLIGHT IRRITATION CAUSE IRRITATION INGESTION LARGE AMOUNTS MAY CAUSE NAUSEA,VOMl T X NG EYES MAY 'MATERIAL SAFETY DATA SHEET THE GIBSON-HOMANS COMPANY 8701 1 PAGE 2 EMERGENCY AND FIRST AID PROCEDURES SKIN WASH WITH SOAP AND WATER EYES FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES INGESTION SEEK MEDICAL ATTENTION MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE PRE-EXISTING SKIN DISORDERS CARCINOGENICITY NOLD50 OF PRODUCT ND LC50 OF PRODUCT NDIRRITANT9 NO SENSITIZER' NOSYNERGISTIC MATERIALS NAREPRODUCTIVE EFFECTS NO TERATOGENIC NO MUTAGENIC NO SECTION VII-PREVENTIVE MEASURES, SAFE HANDLING AND USE LEAK AND SPILL PROCEDURES SCOOP UP AND RETURN TO CONTAINERWASTE DISPOSAL METHOD DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCALREGULATIONSPRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE KEEP CONTAINER CLOSED WHEN NOTIN USE STORE IN COOL, DRY AREA PROTECT FROM FREEZINGOTHER KEEP OUT OF THE REACH OF CHILDREN < s5 = = = = == = B = 3TS33BS = ssBS = :B = = =s5s= = 5: = = sss=s = =:BSS = = = = = = = = = = s:=:= = = s:ss=s= = = = =: = 3 = =:=ssssss»:x=»s===: = SECTION VIII-CONTROL MEASURES/PROTECTION INFORMATION VENTILATION- NORMAL VENTILATION ADEQUATERESPIRATORY PROTECTION NOT NECESSARYPROTECTIVE GLOVES NOT NORMALLY REQUIRED EYE PROTECTION NAOTHER PROTECTIVE EQUIPMENT NAWORK/HYGENIC PRACTICES REMOVE CONTAMINATED CLOTHING, LAUNDER BEFORE REUSE SECTION IX-REGULATORY INFORMATION REPORTABLE QUANTITY (MIN UNDER ANY ACT) 9,900 LBS RCRA HAZARDOUS WASTE NO (FED) NONESHIPPING NAME ADHESIVES, NOINORTH AMERICAN EMERGENCY RESPONSE GUIDE NUMBER NADOT CLASSIFICATION NOT REGULATEDIDENTIFICATION NO NMFC ITEM NO 04620 SUB 5 NMFC CLASS 060VOLATILE ORGANIC COMPOUNDS(VOC) 10 G/L MAX IMDG CLASSIFICATION NOT REGULATED THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOTWARRANTED TO BE, WHETHER ORIGINATING WITH THE COMPANY OR NOT RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,APPLICABLE AND SUITABLE TO THEIR CIRCUMSTANCES MATERIAL SAFETY DATA SHEET Air Corporation ^Product* Division iTnpk Danbury CT 06810 (203)7913500 FILMS Page 1 of5 Issued 4/98 IGENCY NUMBERS: Sealed Air Corporation (203) 791-3500 For emergency and general information 8 30am-5 00pm, (Eastern Tune), Monday-Friday CHEMTREC (800) 424-9300 For Chemical Emergency - spill, leak fire, exposure or accident 24 hours :Name [Name iical Family deal Formula INSTAMATE®, ANTI-STATIC INSTAMATE®, INSTAPACKER™, ANTI-STATIC INSTAPACKER™, SPEEDYPACKER™, ANTI-STATIC SPEEDYPACKER™, DURAMATE™ and PTYA FILM Polyolefins, Propnetary Polyolefins Polyolefins, Anti-static agent, Color concentrates NA ous Ingredient CAS No Wt% OSHA-PEL ACGIH-TLV THIS MATERIAL IS NOT CONSIDERED HAZARDOUS UNDER 29 CFR 1910 1200 [None EMERGENCY OVER VIEW Film additives may cause slight skin irritation No immediate hazard Pink, Silver or other color 1 the entire MSDS for a more thorough evaluation of the hazards . Not a likely route of exposure Wash exposed skin with soap and water Flush eyes with water for at least 10 minutes Obtain medical attention if problem persists Not a likely route of exposure Consult a physician Symptomatic and supportive care as needed N E = NOT ESTABLISHED N A - NOT APPLICABLE A I - ACTIVE INGREDIENT Cifi J8t£fS85.eel or imPllecl except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet Seated Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILMS Page 2 of5 Issued 4/98 I I I I I I I I I Flash Point Approximately 600° F (315° C) Flammable limits (lower) Not applicable Flammable limits (upper) Not applicable Extinguishing Media Carbon dioxide (CQz), chemical foam, dry chemical, water spray Fire and Explosion Hazards None known Special Fire Fighting Procedures Firefighters should be equipped with self-contained breathing apparatus in enclosed areas NFPA Hazard Code Health 1 Flammability 1 Reactivity 0 Special Hazard None Not applicable due to material form Storage Temperature Mm 20° F (-7° C) Max 120° F (49° C) Average Shelf Life Not applicable ••<T*ff « J_ Special Sensitivity None Precautions to be Taken in Handling and Storage Not applicable Exposure Limits HMIS Hazard Code OSHA-PEL NE ACGIH-TLV NE Health Flammability Reactivity PPE 1 1 0 B (Personal Protective Equipment) Respiratory Protection None required in normal use Eye Protection Avoid indirect contact with hands N E - NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT This information Is furmshprt without < Sealed Air Corporation )Engineered Products Division 10 Old Sherman Tnpk Danbury CT06810 (203)7913500 FILMS Page 3 of5 Issued 4/98 Protective Clothing None normally required If special sensitivity exists, use protective gloves Ventilation Good general ventilation during normal use Other Eye wash station Wash hands before eating or handling food Form Plastic Film Color Pink, Silver or other Odor None Vapor Density (Air = 1) NA Molecular Weight NE Melting Point 115- 140° C (240-285° F) Boiling Point NA Vapor Pressure Nil Specific Gravity 092-098 Bulk Density NA Solubility in Water Insoluble % Volatile bv Volume Nil Stability Stable Polymerization Will not occur Conditions to Avoid None Incompatible Materials None Hazardous Decomposition Products By fire or extreme heat, oxides of carbon, oxides of nitrogen I t Toxicity Data LD50,Oral NE LDjo, Dermal N E LC50, Inhalation N E Primary Route(s) of Exposure Skin contact Inhalation Unlikely due to material form Skin Contact Some people may experience skin sensitivity or minor irritation due to film additives Eve Contact Film additives can cause irritation of the mucous membranes N E = NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT This information is furnished without wa «• ited Air Corporation Ei „ «ered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILMS Page 4 of5 Issued 4/98 Ingestion Unlikely due to material form Chronic Effects No applicable data Carcinogemcitv The ingredients of this product (>0 1%) are not classified as carcinogenic by ACGIH or IARC, not regulated as carcinogens by OSHA, and not listed as carcinogens by NTP Mutagemcity No applicable data Reproductive Effects No applicable data Teratogenicitv and Fetotoxicitv No applicable data No applicable data for this section Dispose of in accordance with existing federal, state and local environmental control regulations This material is not a hazardous waste under RCRA 40 CFR 261 when disposed of in its purchased form DOT Not regulated IMP Not regulated IATA/ICAO Class Not regulated Reportable Quantity (RQ) Not applicable OSHA Status This product is NOT considered hazardous under the Federal OSHA Hazard Communication Standard 29 CFR 1910 1200 TSCA Status All ingredients listed or are not required to be listed N E = NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT information Is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheetes nnlv In the soecific material dptinnatori rmmm Sealed Air Corooration assumes no leaal resoonsibilitv for use or reliance uoon these data Sealed Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILMS Page 5 of5 Issued 4/98 SARA 302 Extremely Hazardous Substances None SARA 311/312 Hazard Type Not applicable SARA 313 Listed Ingredients None RCRA Status Discarded product is not a hazardous waste under RCRA, 40 CFR 261, when disposed of in its purchased form No applicable information for this section Section(s) Revised Format changes Printed on recycled paper (50% secondary material, minimum 10% post consumer) using vegetable based inks M-23 Rev 4/98 N E = NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT This information Is furnished without warranty exoressed or imolied exrsnt that it i« armrato in th« heet tn« 1=^^,0 -» o_.i-j « - ^ •*•>- MATERIAL SAFETY DATA SHEET Seated Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILL-A Page 1 of6 Issued 4/98 EMERGENCY NUMBERS: Sealed Air Corporation (203)791-3500 For emergency and general information 8 30am-5 00pm, (Eastern Time), Monday-Friday CHEMTREC (800) 424-9300 For Chemical Emergency - spill, leak, fire, exposure or accident 24 hours Product Name Chemical Name Trade Name Chemical Family Chemical Formula INSTAFILL® COMPONENT "A" Polymethylene Polyphenylisocyanate Polymeric MDI Aromatic Isocyanates NA Hazardous Ingredients Polymeric Diphenylmethane 1 Dusocyanate ("polymeric" MDI) _Jf Contains 4,4'-Diphenylmethane dnsocyanate (4,4'-MDI, CAS 101-68-8, « 55% ) Other MDI isomers and ohgomers CAS No 9016-87-9 Wt% 100 OSHA-PEL NE 0 02 ppm (Ceiling) ACGIH-TLV NE 0 005 ppm (TWA) NE NE J EMERGENCY OVER VIEW Health Hazards Irritating to eyes, respiratory system and skin Inhalation at levels above the occupational exposure limit could cause respiratory sensitization The onset of the respiratory symptoms may be delayed for several hours after exposure A hyper-reactive response to even minimal concentrations of MDI may develop in sensitized persons Sensitized persons should not be exposed to any mixture containing unreacted MDI Physical Hazards Reacts slowly with water to produce carbon dioxide that may rupture closed containers This reaction accelerates at higher temperatures Appearance Dark brown liquid Odor Slightly aromatic (musty) Note Read the entire MSDS for a more thorough evaluation of the hazards N E = NOT ESTABLISHED N A = NOT APPLICABLE A I - ACTIVE INGREDIENT This information is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet ••*Sealed Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILL-A Page 2 of6 Issued 4/98 Inhalation Remove from further exposure and obtain medical attention Treatment is symptomatic for primary irritation or difficulty in breathing If breathing is labored, oxygen should be administered by qualified personnel Apply artificial respiration if breathing has ceased or shows signs of failing Asthmatic-like symptoms, if manifested, may develop immediately, or be delayed for up to several hours Skin Contact Wash affected area thoroughly with soap and water Launder contaminated clothing thoroughly before reuse If irritation, redness, or a burning sensation develops and persists, obtain medical advice Eye Contact Flush with copious amounts of water for at least 15 minutes, holding lids open with fingers If irritation persists, repeat flushing Refer individual to a physician for immediate follow-up Ineestion DO NOT INDUCE VOMITING Provided the patient is conscious, wash out mouth with water then give 1 or 2 glasses of water to drink Refer person to medical personnel for immediate attention Note to Physicians Symptomatic and supportive therapy as needed Following severe exposure medical follow- up should be monitored for 48 hours Pulmonary disorders may be aggravated by overexposure Flash Point 390° F (199° C) [Pensky-Martens Closed Cup] Flammable Limits flower) Not available Flammable Limits (upper) Not available Extinguishing Media Carbon dioxide (CQz), dry chemical, or chemical foam If water is used, large quantities are required Contain run-off water with temporary barriers Fire and Explosion Hazards Containers may burst under intense heat Avoid water contamination in closed containers, carbon dioxide is evolved which can cause pressure build-up Caution: Reaction between water and hot isocyanate can be vigorous Special Fire Fighting Procedures Firefighters must wear self-contained breathing apparatus to protect against toxic and irritating vapors, full protective clothing should also be worn O NFPA Hazard Code Health 2 Flammabihty 1 Reactivity 1 Special Hazard None Evacuate area surrounding the spill and prevent further leakage, spillage or entry into drains Eye and skin protection should be worn during spill cleanup and ventilation maintained If the potential for airborne concentrations of MDI above the PEL exists, then respiratory protection should be worn i N E -- NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT ' Seated Air Corporation Engineered Products Division • lOOldSffllfmanTnpk Danbury CT 06810 (203)7913500 FILL-A Page 3 of 6 Issued 4/98 Contain and cover spill with loose absorbent (earth, sand, sawdust or other absorbent material), or absorbent pillows, pads or socks Collect absorbed material in open containers or plastic bags, and treat with deactivating solution (90% water, 8% concentrated ammonia, 2% detergent) Allow to stand uncovered for 48-72 hours to permit carbon dioxide to escape and solidification to occur Wash spill area with deactivating solution and let stand for 15 minutes or longer Dispose of spilled material properly Storage Temperature Mm 50° F (10° C) Max 100°F(38°C) Average Shelf Life 6 months Special Sensitivity Reacts with moisture to produce carbon dioxide gas Precautions to be Taken in Handling and Storage Do not store product containers uncovered outdoors Do not reseal containers unless it is certain that no moisture contamination has occurred Do not breathe vapors or allow skin contact 1 Exposure Limits HMIS Hazard Code OSHA-PEL 4,4'-Diphenylmethane dusocyanate, ACGIH-TLV 4,4'-Diphenylmethane dnsocyanate, Ceiling = 0 02 ppm TWA = 0 005 ppm Health Flammabihty Reactivity PPE 3 1 1 B (Personal Protective Equipment) Respiratory Protection Due to the low vapor pressure of this material, the PEL is not likely to be exceeded under normal conditions If the material is heated or spilled in a confined area, respiratory protection should be worn Because of their short life and lack of breakthrough indicators, cartridge type respirators equipped for organic vapors are generally not recommended for use with isocyanates They can be used for short-term emergency situations at concentrations below the PEL where the presence of adequate breathing oxygen can be assured Where concentrations exceed the PEL, air supplied respirators must be used Eye Protection Goggles or safety glasses with side shields Protective Clothing Chemical resistant butyl rubber, nitrile rubber, neoprene, or other suitable protective gloves Ventilation Use local exhaust ventilation if necessary to maintain levels below the PEL For guidance on engineering controls refer to the ACGIH publication "Industrial Ventilation " Other Eyewash station, safety shower and deactivating solution should be available Refer to the "Recommendations for the Safe Use and Handling of Instapak® Foam-in-Place Chemicals" bulletin before handling Instapak® chemicals N E = NOT ESTABLISHED N A - NOT APPLICABLE A I - ACTIVE INGREDIENT led Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILL-A Page 4 of6 Issued 4/98 n Liquid Color Dark brown •)dor Slightly aromatic (musty) ^apor Density (Air — 1) 8 5 olecular Weight Approx 350 Siting Point N E M I Boiling Point 406° F (208° C) Vapor Pressure < 10'5 mm Hg @ 25° C (for Polymeric MDI) Specific Gravity 1 24 @ 25° C Bulk Density 10 3 Ibs/gal % Volatile bv Volume Nil Solubility in Water Not soluble Reacts slowly with water to liberate CO2 gas Stable under normal conditions Avoid temperatures above 110° F (43° C) or below 40° F (4° C) )lvmenzation May occur at elevated temperatures in the presence of moisture, alkalies, tertiary amines and metal compounds iditions to Avoid Contact with moisture and other materials that contain active hydrogen ^compatible Materials Water, amines, strong bases and alcohols The reaction with water is slow at iperatures less than 120°F (49°C) but is accelerated at higher temperatures(azardous Decomposition Products Highly unlikely under normal industrial use Exposure to fire or extreme sat may generate oxides of carbon, oxides of nitrogen, and traces of hydrogen cyanide o I I Ivmenc MDI LDJO, Oral LDJO, Dermal LC50, Inhalation >15,800 mg/kg (rat) >5000 mg/kg (rabbit) 370 - 490 mg/m3/4 hours (rat) for an aerosol of polymeric MDI jnary Route(s) of Exposure Skin contact from liquid Inhalation However, due to the low vapor pressure, overexposure is not expected under normal conditions unless material is heated or used in a poorly ventilated Inhalation This product is a respiratory irritant and potential respiratory sensitizer Inhalation of vapor or •rosol at levels above the occupational exposure limit can cause respiratory sensitization Symptoms may |clude irritation to the eyes, nose, throat, and lungs, possibly combined with dryness of the throat, tightness of chest and difficulty in breathing The onset of respiratory symptoms may be delayed for several hours after jsure A hyper-reactive response to even minimal concentrations of MDI may develop in sensitized persons sitized persons should be removed from any further exposure Persons with asthma-type conditions or other chronic respiratory diseases should be excluded from working with MDI In a single evaluation of 5 men Kupationally exposed to MDI and hydrocarbon solvent vapors under conditions where adequate ventilation or er safety precautions were not used, neuropsychologic findings were attributed to MDI , Skin Contact May cause irritation or rash Can cause skin discoloration Repeated and/or prolonged contactKy result in skin sensitization There is limited evidence from laboratory tests that skin contact may play a role •espiratory sensitization This data reinforces the need to prevent direct skin contact and the importance of protective glovesr o N E « NOT ESTABLISHED N A = NOT APPLICABLE A I ACTIVE INGREDIENT iformation Is furnished without warranty expressed or implied exceot that it is accurate to the best knowledae of Sealed Air Corooratmn The H»t» nn this sh««t Seated Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILL-A Page 5 of 6 Issued 4/98 Eve Contact Liquid can cause eye irritation, tearing, reddening and swelling Permanent comeal injury is unlikely Exposure to MDI vapors in excess of 0 02 ppm may cause irritation Ingestion Ingestion is unlikely Based on the acute oral LD50, this product is considered practically non-toxic by ingestion Ingestion can cause irritation and corrosive action in the mouth, stomach and digestive tract Chronic Effects A study was conducted where groups of rats were exposed for 6 hours/day, 5 days/week for a lifetime to atmospheres of respirable polymeric MDI aerosol either at concentrations of 0, 0 2,1, or 6 mg/m3 (which corresponds to MDI levels equal to the OSHA-PEL, 5 times the OSHA-PEL and 30 tunes the OSHA- PEL) No adverse effects were observed at 0 2 mg/m3 concentrations At the 1 mg/m3 concentration, minimal nasal and lung irritant effects were seen Only at the top concentration (6 mg/m3) was there an increased incidence of benign tumor of the lung (adenoma) and one malignant tumor (adenocarcinoma) Overall, the tumor incidence, both benign and malignant, and the number of animals with tumors were not different The increased incidence of lung tumors is associated with prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung In the absence of prolonged exposure to high concentrations leading to chronic irritation and lung damage, it is highly unlikely that tumor formation will occur Carcinogemcity The ingredients of this product (>0 1%) are not classified as carcinogenic by ACGIH or IARC, not regulated as carcinogens by OSHA and not listed as carcinogens by NTP Mutagemcitv There is no substantial evidence of mutagemc potential Reproductive Effects No adverse reproductive effects are anticipated Teratogemcitv and Fetotoxicitv No birth defects were seen in two independent animal (rat) studies Fetotoxicity was observed at doses that were extremely toxic (including lethal) to the mother The dose that produced this effect (12 ppm) is 60 times higher than the OSHA-PEL Fetotoxicity was not observed at doses that were not maternally toxic The doses used in these studies were maximal, respirable concentrations well in excess of the defined occupational exposure limits i i i i i i i i i Environmental Fate and Distribution It is unlikely that significant environmental exposure in the air or water will arise, based on consideration of the production and use of the substance Persistence and Degradation Immiscible with water, but will react with water to produce carbon dioxide, and inert and non-biodegradable solids Aquatic Toxicity ECso (24 hour) EC$o >1000 mg/1 (Zebra fish) At the highest level of 1000 mg/1, there were no deaths >1000 mg/1 (Daphnea magna) >100 mg/1 (E Cob) Incinerate or dispose of in accordance with existing federal, state and local environmental control regulations This matenal is not a hazardous waste under RCRA 40 CFR 261 when disposed of in its purchased form Small quantities should be treated with deactivation solution outlined in Section 6 Refer to the "Recommendations for die Safe Use and Handling of Instapak® Foam-in-Place Chemicals" bulletin for additional information concerning disposal of wastes and empty containers Chemical waste, regardless of quantity, should never be poured into drains, sewers or waterways N E - NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT I I I I I I Seated Air Corporation Engineered Products Division 10 Old Sherman TnpK Danbury CT 06810 (203)7913500 FILL-A Page 6 Of6 Issued 4/98 DOT Containers less than 5,000 pounds are not regulated IMP Not regulated IATA/ICAO Class Not regulated Reportable Quantity (RCO 5,000 Ibs for Methylene diphenyl dusocyanate (MDI), CAS #101-68-8 (« 55% of product) OSHA Status This product is considered hazardous under the Federal OSHA Hazard Communication Standard 29 CFR 1910 1200 TSCA Status All ingredients are listed or are not required to be listed SARA 302 Extremely Hazardous Substances None SARA 311/312 Hazard Categories Immediate (acute) Health Hazard Delayed (chronic) Health Hazard SARA 313 Listed Ingredients This product contains the following chemicals subject to the reporting requirements 100% Dusocyanate compounds (Category Code N120) RCRA Status Discarded product is not a hazardous waste under RCRA, 40 CFR 261, when disposed of in its purchased form o The following states have regulations that apply to the use of this product. MA Massachusetts Hazardous Substance List PA Pennsylvania Hazardous Substance List NJ New Jersey Hazardous Substance List The appropriate state agency should be contacted for further details on regulatory requirements for the substances shown below Ingredient Methylene bisphenyl isocyanate (MDI) (Benzene, 1,1 '-methylenebis[4-Jisocyanato-) CAS No 101-68-8 55 Section(s) Revised Section 15-ReguIatory Information Printed on recycled paper (50% secondary material, minimum 10% post consumer) using vegetable based inks M-18 Rev 4/98 N E - NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT This information Is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet L MATERIAL SAFETY DATA SHEET Sealed Air Corporation Engineered Products Division i 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 HS Page 1 of5 Issued 4/98 EMERGENCY NUMBERS: Sealed Air Corporation (203) 791-3500 For emergency and general information 8 30am-5 00pm, (Eastern Time), Monday-Friday CHEMTREC (800) 424-9300 For Chemical Emergency - spill, leak, fire, exposure or accident 24 hours Product Name Chemical Name Trade Name Chemical Family Chemical Formula HOLSTER/INSTAPAKER® SOLVENT Tnpropylene Glycol Methyl Ether NA Glycol Ethers HO(C3H60)2C3H6OCH3 Hazardous Ingredient CAS No Wt % OSHA-PEL ACGIH-TLV Tnpropylene Glycol Methyl Ether 025498-49-1 > 99 NE NE EMERGENCY OVERVIEW Health Hazards Irritating to eyes and skin Physical Hazards No immediate hazard Appearance Clear Odor Mild ether-like Note Read the entire MSDS for a more thorough evaluation of the hazards Inhalation Remove from further exposure and obtain medical attention Administer oxygen if necessary Skin Contact^ Wash area thoroughly with soap and water Launder contaminated clothing before reuse Eve Contact Flush with copious amounts of water for at least 15 minutes, holding lids open with fingers Consult an eye physician if blinking, redness or tears persist , Ingestion If large quantity is swallowed, induce vomiting and obtain medical attention f Note to Physicians Symptomatic and supportive care as needed Kidney, urethra or bladder disease may be aggravated by repeated, prolonged, gross overexposure N E = NOT ESTABLISHED N A = NOT APPLICABLE A I - ACTIVE INGREDIENT This information is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheetrelates only to the specific material designated herein Sealed Air Corporation assumes no legal responsibility for use or reliance upon these data Seated Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 HS Page 2 of5 Issued 4/98 Flash Point 232°F (111° C) [Setaflash] Flammable limits (lower) Not applicable Flammable limits (upper) Not applicable Extinguishing Media Carbon dioxide (CO2), chemical foam, dry chemical, water spray Fire and Explosion Hazards None known Special Fire Fighting Procedures Firefighters must wear self-contained breathing apparatus and full protective clothing NFPA Hazard Code Health 0 Flammabihty 1 Reactivity 0 Special Hazard None Evacuate area surrounding the spill and prevent further leakage, spillage or entry into drains Eye and skjn protection should be worn during spill cleanup and ventilation maintained Contain and cover spill with loose absorbent (earth, sand, sawdust or other absorbent material) or absorbent pillows, pads or socks Collect absorbed matenal in open containers or plastic bags Dispose of spilled material properly Storage Temperature Mm 20° F (-7° C) Max 120° F (49° C) Average Shelf Life 2 years Special Sensitivity None Precautions to be Taken in Handling and Storage Avoid breathing vapor if generated Exposure Limits OSHA-PEL N E ACGIH-TLV N E HMS Hazard Code Health Flammabihty Reactivity PPE 1 1 0 B (Personal Protective Equipment) NE = NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT ' Sealed Air Corporation OEngineered Products Division 10 Old Sherman Tnpk Danbury CT0681Q (203)7913500 HS Page 3 of5 Issued 4/98 Respiratory Protection The use of respiratory protection should not be needed under normal use and handling conditions If protection is chosen, an air-purifying respirator, equipped with organic vapor cartridges, is appropriate Eye Protection Safety glasses with side shields or goggles Protective Clothing Chemical resistant butyl rubber, nitnle rubber, neoprene, or other suitable protective gloves Ventilation Good general ventilation For guidance on engineering controls refer to the ACGIH publication "Industrial Ventilation " Other Eyewash station should be available Refer to the "Recommendations for the Safe Use and Handling of Instapak Foam-in-Place Chemicals" bulletin before handling Instapak® chemicals Form Liquid Color Clear Odor Mild Glycol Ether Vapor Density (Air =n 715 Molecular Weight 206 Melting Point -100° F (-73° C) VOC Content 965 g/1 or 8 03 1/gal as per Rule 443 1 of California SCAQMD Boiling Point 468° F (242° C) Vapor Pressure 0 02 mm Hg @ 25° C Specific Gravity 0 96 @ 25° C Bulk Density 8 1 Ibs/gal Solubility in Water Complete Evaporation Rate (BuAc = 100) < 1 Stability Stable Polymerization Will not occur Conditions to Avoid None Incompatible Materials Strong oxidizers Hazardous Decomposition Products Oxides of carbon Toxicitv Data LD50, Oral LD50, Dermal Inhalation 3200mg/kg (Rats) > 20,000 mg/kg (Rabbits) NE NE NOT ESTABLISHED NA NOT APPLICABLE A I = ACTIVE INGREDIENT I ISeated Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 HS Page 4 of5 Issued 4/98 I I I I I I Primary Route(s) of Exposure Skin absorption Inhalation Gross overexposure may result in anesthetic or narcotic effect Skin Contact Not considered an irritant Repeated or prolonged exposure may cause mild irritation and/or absorption of potentially toxic amounts In rabbits, toxicity by single dose is low, by repeated doses, moderate Eye Contact May cause temporary eye irritation Comeal injury is unlikely Ingestion Toxiciry is low, however, ingestion of large amounts could cause injury Systemic Central nervous system depression at high levels Rat studies suggest the kidney may be the target organ with overexposure Birth defects are unlikely Even exposures having an adverse effect on the mother should have no effect on the fetus Results of in vitro ("test tube") mutagenicity tests have been negative Carcinogenicrtv The ingredients of this product (X) 1%) are not classified as carcinogenic by ACGIH or IARC, not regulated as carcinogens by OSHA and not listed as carcinogens by NTP Mutagenicity No applicable data Reproductive Effects No applicable data Teratogemcity and Fetotoxicity No applicable data No applicable data for this section Incinerate or dispose of in accordance with existing federal, state and local environmental control regulations This material is not a hazardous waste under RCRA 40 CFR 261 when disposed of in its purchased form Also see "Recommendations for the Safe Use and Handling of Instapak* Foam-in-Place Chemicals" bulletin for additional information concerning disposal of wastes and empty containers Chemical waste, regardless of quantity, should never be poured into drains, sewers or waterways DOT Not regulated I IMP Not regulated / IATA/ICAO Class Not regulated • Reportable Quantity (RQ) Not applicable • N E = NOT ESTABLISHED N A • NOT APPLICABLE A I = ACTIVE INGREDIENT This information Is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet------ --— _„ „„ ,„„,! .cnnnoihiiitu <nr n<u> nr rnhanra uDon these data J Sealed Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 HS Page 5 of5 Issued 4/98 OSHA Status This product is considered hazardous under the Federal OSHA Hazard Communication Standard 29 CFR 1910 1200 TSCA Status All ingredients are listed or are not required to be listed SARA 302 Extremely Hazardous Substances None SARA 311/312 Hazard Categories Immediate (acute) Health Hazard SARA 313 Listed Ingredient(s) None RCRA Status Discarded product is not a hazardous waste under RCRA, 40 CFR 261, when disposed of in its purchased form No applicable information for this section I I I I I I I I II J Section(s) Revised Format changes Th ret Printed on recycled paper (50% secondary material, minimum 10% post consumer) using vegetable based inks M-5 Rev 4/98 N E -NOT ESTABLISHED N A = NOT APPLICABLE A I =• ACTIVE INGREDIENT This information Is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheetrelates only to the specific material designated herein Sealed Air Corporation assumes no legal responsibility for use or reliance upon these data MATERIAL SAFETY DATA SHEET | Seated Air Corporation , Engineered Products Dlvlsldn • *10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILL-B Page 1 of5 Issued 4/98 EMERGENCY NUMBERS: Sealed Air Corporation (203) 791-3500 For emergency and general information 8 30am-5 00pm, (Eastern Time), Monday-Friday CHEMTREC (800) 424-9300 For Chemical Emergency - spill, leak, fire, exposure or accident 24 hours I I I Product Name Chemical Name Trade Name Chemical Family Chemical Formula Hazardous Ingredient Amine Catalyst INSTAFILL® COMPONENT "B" and INSTAFILL® SLOW RISE COMPONENT "B" Polyurethane Foam Resin Polyol NA NA CAS No Proprietary Wt % 2-4 OSHA-PEL NE ACGIH-TLV NE I I I I I I I I EMERGENCY OVERVIEW Health Hazards Irritating to eyes and skin Inhalation may result in irritation Physical Hazards No immediate hazard Appearance Clear, Straw Odor Slight amme Note Read the entire MSDS for a more thorough evaluation of the hazards Inhalation Remove from further exposure and obtain medical attention Administer oxygen if necessary Skin Contact Wash area thoroughly with soap and water Launder contaminated clothing before reuse Eye Contact Flush with copious amounts of water for at least 15 minutes, holding lids open with fingers Ingestion Drink water" to dilute and obtain medical attention Note to Physicians Symptomatic and supportive care as needed • NE NOT ESTABLISHED N A = NOT APPLICABLE A I - ACTIVE INGREDIENT This information is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet Sealed Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILL-B Page 2 of5 Issued 4/98 I i Flash Point Product as supplied does not have a flash point [Pensky-Martens Closed Cup] Flammable limits (lower) Not applicable Flammable limits (upper) Not applicable Extinguishing Media Carbon dioxide (CO2), chemical foam, dry chemical, water spray Fire and Explosion Hazards Containers may burst under intense heat Special Fire Fighting Procedures Firefighters must wear self-contained breathing apparatus to protect against toxic and irritating vapors, full protective clothing should also be worn NFPA Hazard Code Health 2 Flammabihty 1 Reactivity 0 Special Hazard None Evacuate area surrounding the spill and prevent further leakage, spillage or entry into drains Eye and skin protection should be worn during spill cleanup and ventilation maintained Contain and cover spill with loose absorbent (earth, sand, sawdust or other absorbent material) or absorbent pillows, pads or socks Collect absorbed material in open containers or plastic bags Dispose of spilled material properly \t Storage Temperature Min 35° F (2° C) Max 110° F (43° C) Average Shelf Life 12 months Special Sensitivity None Precautions to be Taken in Handling and Storage None Exposure Limits OSHA-PEL N E ACGIH-TLV N E HMIS Hazard Code Health1 Flammabihty Reactivity PPE 2 0 0 B (Personal Protective Equipment) N E = NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT This information is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet I I I Seated Air Corporation Engineered Products Division \10OMShermanTnpK Danbury CT 06810 (203)7913500 FILL-B Page 3 of5 Issued 4/98 I Respiratory Protection The use of respiratory protection should not be needed under normal use and handling conditions If protection is chosen, an air-punfying respirator, equipped with organic vapor cartridges, is appropriate I I I Eye Protection Safety glasses with side shields or goggles Protective Clothing Chemical resistant butyl rubber, nitnle rubber, neoprene, or other suitable protective gloves Ventilation Good general ventilation For guidance on engineering controls refer to the ACGIH publication "Industrial Ventilation " Other Eyewash station and safety shower should be available Refer to the "Recommendations for the Safe Use and Handling of Instapak* Foam-in-Place Chemicals" bulletin before handling Instapak* chemicals • Form Liquid Color Clear, Straw • Odor Slight Amine • Vapor Density (Air = 1) >1 • Molecular Weight NA Melting Point -20° F (-29° C) Boiling Point >201°F (94°C) Vapor Pressure N E (low) Specific Gravity 103@25°C Bulk Density 8 6 Ibs/gal Solubility in Water Soluble % Volatile bv Volume Nil I I I Stability Stable Polymerization Will not occur Conditions to Avoid None • Incompatible Materials Isocyanates, avoid contact unless mixed at proper ratio Hazardous Decomposition Products By fire or extreme heat, oxides of carbon and nitrogen I I Toxicitv Data LD50, Oral LD5o, Dermal LC50, Inhalation NE NE NE I larcs NE =NOT ESTABLISHED N A = NOT APPLICABLE A I - ACTIVE INGREDIENT (formation Is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet only to the specific material designated herein Sealed Air Corporation assumes no legal responsibility for use or reliance upon these data Jted Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbuty CT 06810 (203)7913500 FILL-B Page 4 of 5 Issued 4/98 Primary RouteCs") of Exposure Skin contact from liquid Inhalation However, overexposure is not expected under normal conditions Inhalation Vapors may be irritating if hot Skin Contact Repeated contact may be irritating Eye Contact Can cause eye irritation Permanent corneal injury is unlikely Ingestion Ingestion is unlikely Large quantities could cause irritation of mouth and stomach Chronic Effects No applicable data Carcinogenicitv The ingredients of this product (>0 1%) are not classified as carcinogenic by ACGIH or IARC, not regulated as carcinogens by OSHA, and not listed as carcinogens by NTP Mutagemcity No applicable data Reproductive Effects No applicable data . jratogenicity and Fetotoxicitv No applicable data f" No applicable data for this section Incinerate or dispose of in accordance with existing federal, state and local environmental control regulations This material is not a hazardous waste under RCRA 40 CFR 261 when discarded in its purchased form Also see "Recommendations for the Safe Use and Handling of Instapak* Foam-in-Place Chemicals" bulletin for additional information concerning disposal of wastes and empty containers Chemical waste, regardless of quantity, should never be poured into drams, sewers or waterways DOT Not regulated IMP Not regulated IATA/ICAO Class Not regulated Jeportable Quantity (RQ) Not applicable N E = NOT ESTABLISHED N A = NOT APPLICABLE A I = ACTIVE INGREDIENT t that .t i« arniratp tn the best knowledae of Sealed Air Corporation The data on this sheet Seated Air Corporation Engineered Products Division 10 Old Sherman Tnpk Danbury CT 06810 (203)7913500 FILL-B Page 5 of5 Issued 4/98 OSHA Status This product is considered hazardous under the Federal OSHA Hazard Communication Standard 29 CFR 1910 1200 TSCA Status All ingredients are listed or are not required to be listed SARA 302 Extremely Hazardous Substances None SARA 311/312 Hazard Categories Immediate (acute) Health Hazard SARA 313 Listed Ingredient(s) None RCRA Status Discarded product is not a hazardous waste under RCRA, 40 CFR 261, when disposed of in its purchased form No applicable information for this section Section(s) Revised Section 1- Chemical Product and Company Identification I Printed on recycled paper (50% secondary material, minimum 10% post consumer) using vegetable based inks M-19 Rev 4/98 NE - NOT ESTABLISHED NA * NOT APPLICABLE A I = ACTIVE INGREDIENT This information Is furnished without warranty expressed or implied except that it is accurate to the best knowledge of Sealed Air Corporation The data on this sheet relates only to the specific material designated herein Sealed Air Corporation assumes no legal responsibility for use or reliance UDon these data COBALT CARBONATE MSDS Number- C4917 Effective Date: 11/17/99 1 Product Identification Synonyms Cobaltous carbonate, carbonic acid, cobalt salt CAS No.- 513-79-1 Molecular Weight 118.94 Chemical Formula CoCO3 Product Codes* 1666 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Cobalt Carbonate 513-79-1 90 - 100% Yes 3. Hazards Identification Emergency Overview WARNING' HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION CHRONIC EXPOSURE MAY AFFECT THYROID, LUNGS, HEART, AND KIDNEYS J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating- 1 - Slight Flammability Rating: 0 - None Reactivity Rating 2 - Moderate Contact Rating 1 - Slight Lab Protective Equip- GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation Causes irritation to the respiratory tract, symptoms may include coughing, shortness of breath, and nausea. Respiratory hypersensitivity, asthma may appear Inhalation of cobalt dust and fumes is associated with an increased incidence of lung disease Ingestion Causes abdominal pain, nausea, vomiting, flushing of the face and ears, mild hypotension/ rash, and ringing in the ears May have cumulative toxic action where elimination cannot keep pace with absorption Large amounts depress erythrocyte production Skin Contact May cause dermatitis. Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact Causes irritation, redness, and pain Chronic Exposure: Repeated oral administration may produce goiter and reduced thyroid activity. Prolonged or repeated skin exposure may cause dermatitis Chronic exposure associated with kidney, heart and lung damage. Aggravation of Pre-existing Conditions* Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more susceptible to the effects of the substance. Persons with allergies or sensitivity to cobalt may also be more susceptible to the effects of the substance 4. First Aid Measures Inhalation Remove to fresh air If not breathing, give artificial respiration. If breathing is difficult, give oxygen Get medical attention. Ingestion Induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately 5 Fire Fighting Measures Fire Contact with strong oxidizers may cause fire. Explosion Not considered to be an explosion hazard Fire Extinguishing Media- Use any means suitable for extinguishing surrounding fire. Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode 6 Accidental Release Measures Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8. Spills Sweep up and containerize for reclamation or disposal Vacuuming or wet sweeping may be used to avoid dust dispersal US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7 Handling and Storage Keep m a tightly closed container, stored in a cool/ dry, ventilated area. Protect against physical damage. Wash hands before eating and do not eat, drink, or smoke in workplace. Isolate from incompatible substances Containers of this material may be hazardous when empty since they retain product residues (dust, solids), observe all warnings and precautions listed for the product 8. Exposure Controls/Personal Protection Airborne Exposure Limits For Cobalt Compound -OSHA Permissible Exposure Limit (PEL)• 0.1 mg/m3 (TWA) Cobalt metal dust and fume as Co -ACGIH Threshold Limit Value (TLV)• inorganic cobalt compounds 0 02 mg/m3 (TWA) as Co, A3 Animal carcinogen. Ventilation System- A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition/ for details. Personal Respirators (NIOSH Approved) If the exposure limit is exceeded, a half-face high efficiency dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest A full-face piece high efficiency dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator WARNING Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing Eye Protection Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible Maintain eye wash fountain and quick-drench facilities in work area. 9 Physical and Chemical Properties Appearance• Red crystalline powder. Odor No information found Solubility: Negligible. Specific Gravity 4 13 pH- No information found. % Volatiles by volume @ 21C (70F) 0 Boiling Point* No information found. Melting Point No information found Vapor Density (Air=l)• No information found. Vapor Pressure (mm Hg) No information found Evaporation Rate {BuAc=l) No information found. 10. Stability and Reactivity Stability- Stable under ordinary conditions of use and storage May air-oxidize. Hazardous Decomposition Products Burning may produce carbon monoxide, carbon dioxide, phosphorous oxides and benzoic acid Hazardous Polymerization- Will not occur. Incompatibilities Strong oxidizers, tert-butyl hydroperoxide Conditions to Avoid* Air, incompatibles. 11. Toxicological Information Oral Rat LD50 640 mg/kg Investigated as a tumorigen \Cancer Lists\ NTP Carcinogen Ingredient Known Anticipated IARC Category Cobalt Carbonate (513-79-1) No No 2B 12. Ecological Information Environmental Fate No information found Environmental Toxicity No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated 15 Regulatory Information \Chemical Inventory Status - Part 1\ Ingredient TSCA EC Japan Australia Cobalt Carbonate (513-79-1) Yes Yes Yes Yes \Chemical Inventory Status - Part 2\ • —Canada— Ingredient Korea DSL NDSL Phil. Cobalt Carbonate (513-79-1) Yes Yes No No \Federal, State & International Regulations - Part 1\ -SARA 302- SARA 313 Ingredient RQ TPQ List Chemical Catg Cobalt Carbonate (513-79-1) No No Yes No \Federal, State & International Regulations - Part 2\ -RCRA- -TSCA- Ingredient CERCLA 261 33 8(d) Cobalt Carbonate (513-79-1) No No No Chemical Weapons Convention: No TSCA 12 (b): No CDTA* No SARA 311/312 Acute. Yes Chronic Yes Fire. No Pressure. No Reactivity No (Pure / Solid) Australian Hazchem Code No information found Poison Schedule: No information found WHMIS This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR 16 Other Information NFPA Ratings Health 1 Flammability 0 Reactivity 0 Label Hazard Warning WARNING' HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. CHRONIC EXPOSURE MAY AFFECT THYROID, LUNGS, HEART, AND KIDNEYS. Label Precautions- Avoid breathing dust. Keep container closed Use with adequate ventilation. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Label First Aid If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh azr. If not breathing, give artificial respiration. If breathing is difficult, give oxygen In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention. Product Use Laboratory Reagent Revision Information- No changes. Disclaimer **************** Mallinckrodt Baker, Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER, INC MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. **************** Prepared by. Strategic Services Division Phone Number- (314) 539-1600 (U.S.A.) MATERIAL SAFETY DATA SHEET Hazardous according to criteria of Worksafe Australia Date of issue Oct1997 1 IDENTIFICATION General Product Name FLUORSPAR POWDER Other Names FLUORJTE , METSPAR, CALCIUM FLUORIDE UN No N/A Dangerous Goods Class None Allocated Subsidiary Risk None Allocated HazchemCode N/A Pack Group 0 EPG N/A Poisons Schedule N/A Uses Principal source of fluorine and its compounds by way of hydrogen fluoride, flux m open hearth steel furnaces and in meta! smelting, in ceramics, for synthetic cryolite, in carbon electrodes, emery wheels, etectnc arc welders, certain cements, dentrrfices, phosphors, paint pigment, catalyst in wood preservatives, optical equipment 11 Physical Description / Properties Appearance Light grey to brownish fine powder Formula CaF2 Boiling Point N/A deg C Melting Point >1350degC Vapour Pressure N/A Specific Gravity 3.18 (water = 1) Flash Point Test Unknown >300 PH N/AO I I I I I I I I I I I I Solubility in water 0016g/l(25deg C) Ffammabitlty Limits (as percentage volume in air) Lower Explosion Limit N/A Upper Exptosron Limrt N/A 1.2 Other Properties No data available 1 3 ingredients Chemical Entity CALCIUM FLUORIDE SHJCA (AMORPHOUS) (CRYSTALLINE) CAS No [ 7789-75-5] [7631-86-9] [14808-60-7] Proportions (%) >97 <1 5 2 HEALTH HAZARD INFORMATION 2.1 Health Effects - Acute Swallowed Unlikely to cause significant effects Eye Physical nature of powder may cause mechanical irritation Skin Unlikely to cause irritant effects Inhaled Acute exposure to dust may cause irritation to respiratory tract 2.2 Health Effects - Chronic Fluorspar may contain up to 1 5% silica (amorphous or crystalline) as an impurity Chronic inhalation exposure to crystalline silica may result in serious adverse health effects particularly if the silica is of respirable size (approximately < 7 micron aerodynamic diameter). CrystaBine silica has been shown to induce lung cancer m laboratory animals and mere is limited evidence ttat rt may cause king cancer m humans The International Agency for Research on Cancer (IARC) has classified crystalline silica as a probable human carcinogen (2A) 2.3 First Aid Swallowed If swallowed, give a glass of water If feeling unwell contact a doctor or poisons information centre. Eye If in eyes wash with water for at least 15 minutes If irritation persists see a doctor Skin Wash affected areas thoroughly with water Inhaled If discomfort or irritation occurs remove to fresh air First Aid Facilities Ensure an eye bath and safety shower are available and ready for use 2.5 Advice to Doctor Treat symptomatically based on judgement of doctor and individual reactions of patient 26ToxicrtyData Oral LD50 = 4250 mg/kg (Rat) Derma) LD50 = not available Inhalation LC50 = not available 3 PRECAUTIONS FOR USE 31 Exposure Standards The following exposure limits have been established by Worksafe Australia Inorganic fluorides (as F) TWA 2 5 mg/m3 Crystalline silica TWA 0 1 or 0 2 mg/m3 3 2 Engineering Controls The generation of dusts should be avoided Where possible, dampen material If dust generation is unavoidable, local exhaust ventilation should be used to achieve concentrations below TWA 3.3 Personal Protection A Class P1 paniculate filter respirator should be used where dusts may be formed, in accordance with Australian and New Zealand Standard AS/NZS 1716.1994 Eye goggles should be worn as a general precaution if dust is likely to be formed Wash hands and face thoroughly after handling and before work breaks, eating, dnnking, smoking and using toilet facilities 3 4 Flammabilrty Not flammable SAFE HANDLING INFORMATION 41 Storage / Transport The product is not a dangerous good No special storage or transport operations are required 4 2 Packaging / Labelling UN No N/A Class None Allocated Sub Risk None Allocated Hazchem Code N/A Pack Group 0 EPGNo N/A Shipping Name FLUORSPAR POWDER Hazard Risk Phrases R48 FLUORS Danger of serious damage to health by prolonged inhalation exposure R49 May cause cancer by inhalation Safety Phrases S22 Do not breathe dust S53 Avoid exposure • obtain special instructions before use 4.3 Spflte and Disposal Spills Clean-up personnel should wear fall protective clothing including breathing protection Avoid generation of dust Use an industrial vacuum deaner to pick up material and transfer to suitable containers for reuse or disposal Disposal Dispose of in accordance with all Local, State and Federal regulations at an approved waste disposal facility 4.4 FIRE AND EXPLOSION HAZARD Fire / Explosion Fluorine gas may be released on decomposition Extinguishing Media Fire-fighters should wear full protective equipment including breathing apparatus Mtenal is not flammable Use equipment/media appropriate to surrounding materials and fire conditions 5 OTHER INFORMATION I Other Information No data available 51 Contact Points Organisation Redox Chemicals Pty Ltd Poisons information Centre Location Wethenll Park NSW Westmead Telephone 02-97255155 131129 1800-251525 Ask For Technical Officer iiirsday Iviarch 22 2001 Page 1 •mage] I I I I irric Chloride Solution :DS Number F1080 Effective Date 02/21/00 Product Identification Synonyms Iron (III) Chloride Solution CAS No 7705-08-0 Molecular Weight Not applicable to mixtures Chemical Formula FeC13 in H20 Product Codes 5251 Composition/Information on Ingredients Ingredient CAS No Percent Hazardous I I I I I I I I I I I I I I [Ferric Chloride 7705-08-0 35-45% Yes Fater 7732-18-5 55 - 65% No Hazards Identification Emergency Overview DANGER1 CORROSIVE CAUSES BURNS TO ANY AREA OF CONTACT HARMFUL IF SWALLOWED OR INHALED AFFECTS THE LIVER J T Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating 2 - Moderate Flamtnability Rating 0 - None Reactivity Rating 2 - Moderate Contact Rating 3 - Severe (Corrosive) Lab Protective Equip GOGGLES & SHIELD LAB COAT & APRON VENT HOOD PROPER GLOVES Storage Color Code White (Corrosive) potential Health Effects Inhalation Extremely destructive to tissues of the mucous membranes and upper respiratory tract Symptoms may include burning sensation coughing wheezing laryngitis shortness of breath headache nausea and vomiting Ingestion Corrosive Swallowing can cause severe burns of the mouth throat and stomach Can cause sore throat vomiting diarrhea Low systemic toxicity in small quantities but larger doses may cause systemic effects Pink urine discoloration is a strong indicator of iron poisoning Liver damage coma and death may follow sometimes delayed as long as three days Skin Contact Corrosive Symptoms of redness pain and severe burn can occur Eye Contact Corrosive Contact can cause blurred vision redness pain and severe tissue burns Chronic Exposure Repeated ingestion may cause liver damage Prolonged exposure of the eyes may cause discoloration Aggravation of Pre-existing Conditions No information found First Aid Measures inhalation Remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen Get medical attention immediately Ingestion If swallowed DO NOT INDUCE VOMITING Give large quantities of water Never give anything by mouth to an unconscious person Get medical attention immediately Skin Contact file ///mac k2m A5%20don/Desktop'y ZOFolder/MSDS/FerrlcV 20Chlorldey ZOSolution tiursday toarch 22 2001 Page Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Get medical attention immediately Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes lifting lower and upper eyelids occasionally Get medical attention immediately 5 Fire Fighting Measures Fire Not considered to be a fire hazard Irritating hydrogen chloride fumes may form in fire Explosion Not considered to be an explosion hazard Fire Extinguishing Media Water dry chemical foam or carbon dioxide Do not allow water runoff to enter sewers or waterways Special Information In the event of a fire wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode 6 Accidental Release Measures Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8 Isolate hazard area Keep unnecessary and unprotected personnel from entering Contain and recover liquid when possible Collect liquid in an appropriate container or absorb with an inert material (e g vermiculite dry sand earth) and place in a chemical waste container Do not use combustible materials such as saw dust Do not flush to sewer1 US Regulations (CERCLA) require reporting spills and releases to soil water and air in excess of reportable quantities The toll free number for the US Coast Guard National Response Center is (800) 424-8802 7 Handling and Storage Keep in a tightly closed container stored in a cool dry ventilated area Protect against physical damage Isolate from incompatible substances Containers of this material are hazardous when empty since they retain product residues observe all warnings for the product 3 Exposure Controls/Personal Protection Airborne Exposure Limits -ACGIH Threshold Limit Value (TLV) 1 mg/m3 (TWA) soluble iron salt as Fe Ventilation System A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source preventing dispersion of it into the general work area Please refer to the ACGIH document Industrial Ventilation A Manual of Recommended Practices most recent edition for details Personal Respirators (NIOSH Approved) If the exposure limit is exceeded a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier whichever is lowest For emergencies or instances where the exposure levels are not known use a. full-facepiece positive-pressure air-supplied respirator WARNING Air purifying respirators do not protect workers in oxygen-deficient atmospheres Skin Protection Wear impervious protective clothing including boots gloves lab coat apron or coveralls as appropriate to prevent skin contact Eye Protection Use chemical safety goggles and/or a full face shield where splashing is possible Maintain eye wash fountain and quick-drench facilities in work area Physical and Chemical Properties file ///mac / 20 AA5%20don/Desktop / 20Folder/MSDS/Ferrlc'y 20Chlorlde / 20Solutlon I I I I I I I I I I I I I I I I I I I hursdi I I I I I I I 1 I I lay li/larch 22 2001 Page 3 Appearance Orange to brown liquid Odor Acid odor Solubility Complete (100%) Specific Gravity 1 40 PH No information found % Volatiles by volume @ 21C (70F) 55-65 Boiling Point 230C (446F) Melting Point No information found Vapor Density (Air=l) No information found Vapor Pressure (mm Hg) No information found Evaporation Rate (BuAc=l) No information found Stability and Reactivity Stability Stable under ordinary conditions of use and storage Hazardous Decomposition Products May produce hydrogen chloride Hazardous Polymerization This substance does not polymerize Incompatibilities Metals allyl chloride sodium potassium Conditions to Avoid Incompatibles Toxicological Information Oral rat LD50 450 mg/kg (anhydrous) investigated as a mutagen reproductive effector —\Cancer Lists\ NTP Carcinogen ingredient Known Anticipated IARC Category 'erne Chloride (7705-08-0) No No None Water (7732-18-5) No No None I Ecological Information Environmental Fate No information found Environmental Toxicity No information found I I I Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility Although not a listed RCRA hazardous waste this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements Processing use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state and local requirements I I Transport Information Not regulated Regulatory Information I \Chemical Inventory Status - Part 1\ Ingredient TSCA EC Japan Australia file ///mac / 20°/ A5 /o20don/Desktop / 20Folder/MSDS/Ferric /<,20Chlor!de%20Solutlon hursday Inarch 22 2001 Page Ferric Chloride (7705-08-0) Water (7732-18-5) \Chemical Inventory Status - Part 2\- Ingredient Yes Yes Yes Yes Yes Yes Yes Yes --Canada-- Korea DSL NDSL Phil Ferric Chloride (7705-08-0) Water (7732-18-5) Ingredient Ferric Chloride (7705-08-0) Water (7732-18-5) Ingredient Ferric Chloride (7705-08-0) Water (7732-18-5) Yes Yes No Yes Yes Yes No Yes RQ TPQ List Chemical Catg No No No No No No No No -RCHA- -TSCA- CERCLA 261 33 8(d) 1000 No No No No No Chemical Weapons Convention No TSCA 12 (b) No CDTA No SARA 311/312 Acute Yes Chronic Yes Fire No Pressure No Reactivity No (Mixture / Liquid) Australian Hazchem Code No information found Poison Schedule No information found WHMIS This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR 16 Other Information NFPA Ratings Health 3 Flammability 0 Reactivity 0 Label Hazard Warning DANGER' CORROSIVE CAUSES BURNS TO ANY AREA OF CONTACT HARMFUL IF SWALLOWED OR INHALED AFFECTS THE LIVER Label Precautions Do not get in eyes on skin or on clothing Do not breathe mist Keep container closed Use only with adequate ventilation Wash thoroughly after handling Label First Aid In case of contact immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Wash clothing before reuse If inhaled remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen If swallowed DO NOT INDUCE VOMITING Give large quantities of water Never give anything by mouth to an unconscious person In all cases get medical attention immediately Product Use Laboratory Reagent Revision Information MSDS Section(s) changed since last revision of document include 1 3 4 5 6 7 8 9 10 11 13 16 Disclaimer Mallinckrodt Baker Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER INC MAKES NO REPRESENTATIONS OR WARRANTIES EITHER EXPRESS OR IMPLIED INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDINGLY MALLINCKRODT BAKER INC WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION Prepared by Strategic Services Division Phone Number (314) 539-1600 (USA) I file ///mac%20 AA5%20don/Desktop%20Folder/MSDS/Ferric / 20Chlorlda / 20Solutlon sday March 22 2001 Nickelous Carbonate Page 1 Nickelous Carbonate •iSDS Number N297Q — Effective Date 04/15/99 I. Product Identification Synonyms Nickel (II) Carbonate, Carbonic Acid, Nickel Salt CI 77779 I CAS No 3333-67-3 Molecular Weight 11870 Chemical Formula NiCO3 Product Codes 2764 s. Composition/Information on Ingredients Iln0redient CAS No Percent Hazardous .Nickel Carbonate 3333-67-3 99 - 100% Yes I I I I I I I I I Hazards Identification Emergency Overview WARNING' HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT MAY CAUSE NASAL OR LUNG DAMAGE MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION CANCER HAZARD CAN CAUSE CANCER Risk of cancer depends on duration and level of exposure J T Baker SAF-T-DATA(tm> Ratings (Provided here for your convenience) Health Rating 3 - Severe (Cancer Causing) Flammability Rating 0 - None Reactivity Rating 0-None Contact Rating 3 - Severe (Life) Lab Protective Equip GOGGLES, LAB COAT, VENT HOOD, PROPER GLOVES Storage Color Code Blue (Health) Potential Health Effects Inhalation Can cause headaches, dizziness, and difficult breathing Finer dust participates may irritate the respiratory tract Symptoms may include coughing, sore throat and shortness of breath Inhalation of nickel and nickel compounds is associated with nasal and lung damage and cancer Ingestion May cause irritation to the gastro-intesunal tract Large oral dose may cause nausea vomiting, abdominal pain and diarrhea Skin Contact Causes irritation, redness, pain May cause allergic dermatitis Nickel is a contact allergen and sensitizer Eye Contact Causes irritation, redness, and pain Chronic Exposure Prolonged exposure to excessive concentrations of dust may cause chronic pulmonary disorders Nickel and certain nickel compounds are considered carcinogenic and noted for producing nasal and lung cancer Aggravation of Pre-existing Conditions Skin contact with some nickel compounds in sensitive individuals may cause dermatitis (nickel itch) i i First Aid Measures Inhalation Remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen Get medical attention Ingestion Induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person Get medical attention file ///mac%20 / A5 ^20don/Desktop%20Folder/MSDS/Nickelous%20Carbonate hursday March 22 2001 Nickelous Carbonate Page Skin Contact Immediately flush skin with plenty of soap and water Remove contaminated clothing and shoes Get medical attention Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally Get medical attention immediately 5. Fire Fighting Measures Fire Not considered to be a fire hazard Explosion Not considered to be an explosion hazard Fire Extinguishing Media Use any means suitable for extinguishing surrounding fire Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode Toxic gases and vapors such as nickel carbonyl may be released in a fire involving nickel 6. Accidental Release Measures Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8 Spills Sweep up and containerize for reclamation or disposal Vacuuming or wet sweeping may be used to avoid dust dispersal 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area Protect against physical damage Wear special protective equipment (Sec 8) for maintenance break-in or where exposures may exceed established exposure levels Wash hands, face, forearms and neck when exiting restricted areas Shower dispose of outer clothing, change to clean garments at the end of the day Avoid cross-contamination of street clothes Wash hands before eating and do not eat, drink, or smoke in workplace Containers of this material may be hazardous when empty since they retain product residues (dust, solids) observe all warnings and precautions listed for the product 8. Exposure Controls/Personal Protection Airborne Exposure Limits For Nickel, Metal and Insoluble Compounds, as Ni - OSHA Permissible Exposure Limits (PEL) - 1 mg/m3 (TWA) For Nickel, Elemental / Metal - ACGIH Threshold Limit Value (TLV) - 1 5 mg/m3 (TWA), A5 - Not suspected as a human carcinogen For Nickel, Insoluble Compounds, as Ni - ACGIH Threshold Limit Value (TLV) - 0 2 mg/m3 (TWA) Al - Confirmed human carcinogen Ventilation System A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices , most recent edition, for details Personal Respirators (NIOSH Approved) If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier whichever is lowest A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest For emergencies or instances where die exposure levels are not known, use a full-facepiece positive-pressure, air-supphed respirator WARNING Air-punfying respirators do not protect workers in oxygen-deficient atmospheres Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact Eye Protection Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible Maintain eye wash fountain and quick-drench faculties in work area I ). Physical and Chemical Properties Appearance Light green powder Odor Odorless Solubility file Wmac%20%A5 ^20don/Dasktop / 20FoWer/MSDS/Nicketous / 20Cart>onate I I I I March 22 2001 Nickelous Carbonate Page 3 Negligible Specific Gravity No information found PH No information found % Volatiles by volume @ 21C (70F) 0 Boiling Point No information found Melting Point Decomposes before reaching melting point Vapor Density (Air=l) Not applicable Vapor Pressure (mm Hg) Not applicable Evaporation Rate (BuAc=l) No information found 10. Stability and Reactivity I I I I Stability Stable under ordinary conditions of use and storage Hazardous Decomposition Products Carbon dioxide and carbon monoxide may form when heated to decomposition Toxic gases and vapors such as nickel carbonyl may be released Hazardous Polymerization Will not occur Incompatibilities For Nickel Aluminum, aluminum trichloride, ethylene p-dioxan, hydrogen, methanol, non-metals, oxidants, sulfur compounds Slowly attacked by dilute hydrochloric or sulfunc acid, readily attacked by nitnc acid Not attacked by fused alkali hydroxides Conditions to Avoid Incompatibles 11. Toxicological Information INo LD50/LC50 information found relating to normal routes of occupational exposure Investigated as a tumongen and mutagen \Cancer ListsX NTP Carcinogen ngredienc Known Anticipated IARC Category Nickel Carbonate (3333-67-3) No Yes 1 1 I I . Ecological Information Environmental Fate No information found Environmental Toxicity No information found 13. Disposal Considerations IWhatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility Processing use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal, state and local requirements I I . Transport Information Not regulated F. Regulatory Information \Chemical Inventory status - Part 1\ Ingredient TSCA EC Japan Australia I'ickel Carbonate (3333-67-3) Yes Yes Yes Yes file ///mac / 20 / A5%20don/Desktop%20Folder/MSDS/Nickelous / 20Carbonate hursday March 22 2001 Nickelous Carbonate \Chemical Inventory Status - Part 2\ --Canada— Ingredient Korea DSL NDSL Phil Nickel Carbonate (3333-67-3) Yes Yes No Yes \Federal State & International Regulations - Part 1\ -SARA 302- SARA 313 Ingredient RQ TPQ List Chemical Catg Nickel Carbonate (3333-67-3) No No No Nickel compo -------- \Federal State & International Regulations - Part 2\ ---------------- -RCRA- -TSCA- Ingredient CERCLA 261 33 8(d) Nickel Carbonate (3333-67-3) No No No Chemical Weapons Convention No TSCA 12 (b) No CDTA No SARA 311/312 Acute Yes Chronic Yes Fire No Pressure No Reactivity No (Pure / Solid) WARNING THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER Australian Hazchem Code No information found Poison Schedule No information found WHMIS This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR 16. Other Information NFPA Ratings Health 2 Flammability 0 Reactivity 0 Label Hazard Warning WARNING' HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT MAY CAUSE NASAL OR LUNG DAMAGE MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION CANCER HAZARD CAN CAUSE CANCER Risk of cancer depends on duration and level of exposure Label Precautions Wash thoroughly after handling Do not breathe dust Keep container closed Use only with adequate ventilation Do not get in eyes on skin or on clothing Label First Aid If swallowed, induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person If inhaled, remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen. In case of skin contact, immediately flush skin with plenty of soap and water Remove contaminated clothing and shoes Wash clothing before reuse In case of eye contact immediately flush eyes with plenty of water for at least 15 minutes In all cases get medical attention. Product Use Laboratory Reagent Revision Information MSDS Section(s) changed since last revision of document include 8 Disclaimer********* Mallmckrodt Baker, Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent judgment m determining its appropriateness for a particular purpose MALLINCKRODT BAKER, INC MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDINGLY, MALLINCKRODT BAKER, INC WELL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION Prepared by Strategic Services Division Phone Number (314) 539-1600 (USA) file ///mac / 20 ^A5%20don/Desktop / 20Folder/MSDS/Nickelous%20Carbonate Chromium Oxide MSDS Number C4356 Effective Date 03/01/00 1. Product Identification Synonyms Chromium (III) Oxide, Chromic Oxide, Chrome Oxide Green CAS No 1308-38-9 Molecular Weight- 151.99 Chemical Formula- Cr203 Product Codes 1616, 1617 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Chromium (III) Oxide 1308-38-9 90 - 100% Yes 3 Hazards Identification Emergency Overview WARNING1 HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. J T Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating- 2 - Moderate Flammability Rating: 0 - None Reactivity Rating 1 - Slight Contact Rating 2 - Moderate Lab Protective Equip- GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code Blue (Health) Potential Health Effects- Inhalation: Causes irritation to the respiratory tract Symptoms may include coughing, shortness of breath. Ingestion Causes irritation to the gastrointestinal tract Symptoms may include nausea, vomiting and diarrhea Skin Contact* Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact Causes irritation, redness, and pain Chronic Exposure Prolonged or repeated skin contact may produce severe irritation or dermatitis Aggravation of Pre-existing Conditions No information found. 4. First Aid Measures Inhalation Remove to fresh air If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact Immediately flush skin with plenty of water for at least 15 minutes Remove contaminated clothing and shoes Get medical attention Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally Get medical attention immediately. 5 Fire Fighting Measures Fire- Not considered to be a fire hazard Explosion Not considered to be an explosion hazard. Fire Extinguishing Media Use any means suitable for extinguishing surrounding fire. Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face-piece operated in the pressure demand or other positive pressure mode €. Accidental Release Measures Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section. 8 Spills Pick up and place in a suitable container for reclamation or disposal in a method that does not generate dust. Do not sweep. Damp mop any residue. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area Protect against physical damage Do not store on wooden floors Containers of this material may be hazardous when empty since they retain product residues (dust, solids), observe all warnings and precautions listed for the product 8. Exposure Controls/Personal Protection Airborne Exposure Limits - OSHA Permissible Exposure Limit (PEL) for Cr(III) compounds = 0.5mg/m3 (TWA) -ACGIH Threshold Limit Value (TLV) for Cr(III) compounds = 0.5 mg/m3 (TWA), A4 - Not classifiable as a human carcinogen Ventilation System A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details Personal Respirators (NIOSH Approved) If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest For emergencies or instances where the exposure levels are not known, use a full-face piece positive- pressure, air-supplied respirator WARNING Air-purifying respirators do not protect workers in oxygen-deficient atmospheres Skin Protection- Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact Eye Protection- Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area 9 Physical and Chemical Properties Appearance Light to dark green Crystalline solid Odor: Odorless. Solubility Negligible (< 0.1%) Specific Gravity 5 10 pH No information found % Volatiles by volume @ 21C (70F) 0 Boiling Point 4000C (7232F) Melting Point- 2435C (4415F) Vapor Density (Air=l) Not applicable Vapor Pressure (mm Hg) Not applicable. Evaporation Rate (BuAc=l). No information found. 10. stability and Reactivity Stability Stable under ordinary conditions of use and storage. Hazardous Decomposition Products No information found Hazardous Polymerization Will not occur Incompatibilities- Lithium, glycerol. Conditions to Avoid. Dusting. 11 Toxicological Information Investigated as a tumorlgen, mutagen \Cancer ListsN NTP Carcinogen— Ingredient Known Anticipated IARC Category Chromium (III) Oxide (1308-38-9) No No 3 12 Ecological Information Environmental Fate When released into the soil, this material is not expected to biodegrade. This material is not expected to significantly bioaccumulate. Environmental Toxicity No information found 13 Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal, state and local requirements. 14 Transport Information Not regulated 15. Regulatory Information \Chemical Inventory Status - Part 1\ Ingredient TSCA EC Japan Australia Chromium (III) Oxide (1308-38-9) Yes Yes Yes Yes \Chemical Inventory Status - Part 2\—Canada- Ingredient Korea DSL NDSL Phil Chromium (III) Oxide (1308-38-9) Yes Yes No Yes Federal, State & International Regulations - Part 1\SARA 302—SARA 313 Ingredient RQ TPQ List Chemical Catg Chromium (III) Oxide (1308-38-9) No No No Chromium com Federal, State & International Regulations - Part 2\ -RCRA- -TSCA- Ingredient CERCLA 261 33 8(d) Chromium (III) Oxide (1308-38-9) No No No Chemical Weapons Convention No TSCA 12(b) No CDTA' No SARA 311/312 Acute Yes Chronic Yes Fire No Pressure No Reactivity No (Pure / Solid) Australian Hazchem Code No information found Poison Schedule No information found WHMIS* This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR 16. Other Information Label Hazard Warning WARNING' HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Label Precautions: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling Avoid breathing dust Keep container closed Use only with adequate ventilation Label First Aid If swallowed, induce vomiting immediately as directed by medical personnel Never gave anything by mouth to an unconscious person. If inhaled, remove to fresh air If not breathing, give artificial respiration If breathing is difficult, give oxygen In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse In all cases, get medical attention Product Use' Laboratory Reagent. Revision Information No changes Disclaimer Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION Prepared by Strategic Services Division Phone Number (314) 539-1600 (USA) 0 Health i* 0 F 1 dfirnab i 1 i ty 0 Reactivity FOOTE MINERAL COMPANY DATE 1/19/82 MATERIAL SAFETY SHEET SECTION 1 MANUFACTURER S NAMEFoote Mineral Company ADDRESS (Number Stieet City SUU jnd ZIP Code!Route 100 Exton, PA \33k] CHEMICAL NAME AND SYNONVMS Chromite CHEMICAL FAMILY FORMULA Hi neral EMERGENCY TELEPHONE NO215/363-6500 TRADE NAME AND SYNONYMS Chromite AF and Chromite SG * Cr?0., FeO. SECTION II HAZARDOUS INGREDIENTS PAINTS PRESERVATIVES & SOLVENTS PIGMENTS CATALYST VEHICLE SOLVENTS ADDITIVESi OTHERS\ x TLV (Uniti)ALLOYS AND METALLIC COATINGS BASE METAL ALLOYS , METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS -T. _.' HAZARDOUS MIXTURES OF OTHER LIQUIDS SOLIDS, OR GASES Chromite is not a serious hazard Cr2°3 FeO X % ^ 2k TLV (Units) TLV (Unitil SECTION III PHYSICAL DATA BOILING POINT (°F ) ' VAPOR PRESSURE (mm He ) VAPOR DENSITY (AIR-1) SOLUBILITY IN WATER NA NA NA Nf>ol ?n!hU SPECIFIC GRAVITY JH2O-1) PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE ( -1) k k NA NA APPEARANCE AND ODOR . ' _, ,Brown powder. Odorless SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (M.ihoa uMd FLAMMABLE LIMITS U.I EXTINGUISHING MEDIA NA FIRE FIGHTING PROCEDURES Nonflammahl UNUSUAL FIRE AND EXPLOSION HAZARDS none OC-2(1)(11 71) I I I I I I I I I I I I I I I I I I I SECTION V HEALTH HAZARD DATA THRESHOLD LIMIT VALUE NA EFFECTS OF OVEREXPDSURENo known hazard except as a nuisance dust Suspected but indefinite careinoqenic EMERGENCY AND FIRST AID PROCEDURES SECTION VI REACTIVITY DATA I STABILITY UNSTABLE STABLE CONDITIONS TO AVOID INCOMPATABILITY (Mtt.rl.iU to avoid) HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID STEPS TO BE TAKEN Sweep up SECTION VH SPILL OR LEAK IN CASE MATERIAL IS RELEASED OR SPILLED and return to container PROCEDURES - WASTE DISPOSAL METHOD Landf i 11 , within all pollution regulations - " SECTION VELI SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify typ«) ical VENTILATION LOCAL EXHAUST 'MECHANICAL (G.n.rjl) SPECIAL OTHER PROTECTIVE GLOVES EYE PROTECTIONgoggies for oust protection OTHER PROTECTIVE EQUIPMENT SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Norma1 OTHER PRECAUTIONS C QC-2(2)(11 71)by 8FSDS - MANGANESE DIOXIDE 1 - PRODUCT IDENTIFICATION PRODUCT NAME FORMULA FORMULA WT CAS NO MANGANESE DIOXIDE MN02 86 94 1313-13-9 NIOSH/RTECS NO.: OP0350000 COMMON SYNONYMS BLACK MANGANESE OXIDE, CEMENT BLACK, MANGANESE (IV) OXIDE PRODUCT CODES 2134,2526,8392,5308,2527,5298 EFFECTIVE 09/08/86 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 1 SLIGHT FLAMMABILITY - 0 NONE REACTIVITY - 1 SLIGHT CONTACT - 1 SLIGHT HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD) LABORATORY PROTECTIVE EQUIPMENT SAFETY GLASSES; LAB COAT PRECAUTIONARY LABEL STATEMENTS WARNING CAUSES IRRITATION HARMFUL IF INHALED DURING USE AVOID CONTACT WITH EYES, SKIN, CLOTHING WASH THOROUGHLY AFTER HANDLING. WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER SAF-T-DATA(TM) STORAGE COLOR CODE ORANGE (GENERAL STORAGE) 2 - HAZARDOUS COMPONENTS COMPONENT MANGANESE DIOXIDE % CAS NO 90-100 1313-13-9 3 - PHYSICAL DATA BOILING POINT: N/A MELTING POINT 535 C ( 995 F) SPECIFIC GRAVITY 5.02 VAPOR PRESSURE(MM HG) N/A VAPOR DENSITY(AIR=1) N/A EVAPORATION RATE N/A (H2O=1) (BUTYL ACETATE=1) SOLUBILITY(H20) NEGLIGIBLE (LESS THAN 0.1 %) % VOLATILES BY VOLUME N/A APPEARANCE & ODOR ODORLESS BLACK CRYSTALLINE POWDER. 4 - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP N/A FLAMMABLE LIMITS- UPPER - N/A % LOWER - N/A % FIRE EXTINGUISHING MEDIA USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED (POSITIVE PRESSURE IF AVAILABLE) BREATHING APPARATUS WITH FULL FACEPIECE MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE & EXPLOSION HAZARDS STRONG OXIDIZER CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE 5 - HEALTH HAZARD DATA TLV LISTED DENOTES CEILING LIMIT THRESHOLD LIMIT VALUE (TLV/TWA) 5 MG/M3 { PPM) CARCINOGENICITY NTP NO IARC- NO Z LIST NO OSHA REG NO EFFECTS OF OVEREXPOSURE DUST MAY IRRITATE SKIN OR EYES. INHALATION OF EXCESSIVE AMOUNTS OF DUST MAY CAUSE NAUSEA, WEAKNESS, CHILLS, AND LOSS OF APPETITE INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT, INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. PROLONGED INHALATION OF MANGANESE IN THE FORM OF ITS INORGANIC COMPOUNDS MAY CAUSE MANGANISM TARGET ORGANS RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM, BLOOD, KIDNEYS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INGESTION, INHALATION EMERGENCY AND FIRST AID PROCEDURES INGESTION IF SWALLOWED AND THE PERSON IS CONSCIOUS, IMMEDIATELY GIVE LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION IF A PERSON BREATHES IN LARGE AMOUNTS, MOVE THE EXPOSED PERSON TO FRESH AIR GET MEDICAL ATTENTION EYE CONTACT' IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION SKIN CONTACT IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES 6 - REACTIVITY DATA STABILITY STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOID- HEAT, FLAME, OTHER SOURCES OF IGNITION INCOMPATIBLES STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG REDUCING AGENTS, NITRATES, COMBUSTIBLE MATERIALS, HYDROGEN PEROXIDE, A2IDES, CHLORINE, CHLORATES, CHLORINE TRIFLUORIDE 7 - SPILL AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SUITABLE PROTECTIVE CLOTHING. KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC ) AWAY FROM SPILLED MATERIAL WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER, REMOVE FROM AREA FLUSH SPILL AREA WITH WATER. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. 8 - PROTECTIVE EQUIPMENT VENTILATION- USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST IF AIRBORNE CONCENTRATION EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION SAFETY GOGGLES, UNIFORM, APRON, PROPER GLOVES ARE RECOMMENDED 9 - STORAGE AND HANDLING PRECAUTIONS SAF-T-DATA(TM) STORAGE COLOR CODE ORANGE (GENERAL STORAGE) SPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED STORE SEPARATELY AND AWAY FROM FLAMMABLE AND COMBUSTIBLE MATERIALS 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION DOMESTIC (D,O.T ) PROPER SHIPPING NAME CHEMICALS, N 0 S (NON-REGULATED) INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME CHEMICALS, N 0 S (NON-REGULATED) [Q'Max Header] [Image] Q'MAX MATERIAL SAFETY DATA SHEET Section I. IDENTIFICATION OF PRODUCT Product Name QUICKLIME (Pebble, Crushed, Pulverized) Various Calcium Oxide Cas No 1305-78-8 Eye and Skin Irritant Not Applicable Not Applicable Not Applicable Product Use- Chemical Family. WHMIS CLASSIFICATION WORK PLACE HAZARD TDG CLASSIFICATION. PACKAGE GROUP PIN' Section II HAZARDOUS INGREDIENTS Ingredient Percent CAS Number LC(50) Calcium Oxide 95 I 1305-78-8 N/AV Section III: TOXICOLOGICAL PROPERTIES Route of [Image] SKIN [Image]EYE CONTACT [Image]INHALATION INGESTION Entry SKIN CONTACT, soft, LD{50) N/AV [Image] contact The contact contact EYE CONTACT solutions may destruction, can conjunctivitis. INHALATION coughing, headache, may result pulmonary edema penetration are common INGESTION' Physician Exposure Limits Irritancy of Product- Skin, Exposed Can penetrate the skin slowly, producing necrotic, deeply penetrating areas on extent of damage depends on duration of A chronic dermatitis may follow repeated Direct contact with the solid or aqueous cause con^unctival edema and corneal lead to and may cause blindness. Prolonged contact may cause Low concentrations may cause sore throat, choking, dyspnea, and variable symptoms of dizziness, and weakness. Intense exposures in tightness in the chest and delayed The solubility of substance allows further that may continue for several days. Bronchial irritation with chronic cough Corrosive. If ingested, consult a immediately 5 mg/m'> Lime Respiratory System Nasal Passages, Eyes, Section IV FIRST AID MEASURES SKIN CONTACT' large amounts of Lime dust Acid solution, EYE CONTACT' then vinegar Keep bandaged INHALATION- artificial INGESTION water. Do not attention Section V PHYSICAL DATA APPEARANCE AND ODOUR- Odourless SPECIFIC GRAVITY BOILING POINT (°C) MELTING POINT (°C). SOLUBILITY IN WATER pH @ 1 0% PERCENT VOLATILE BY VOLUME EVAPORATION RATE VAPOUR PRESSURES (mm Hg). VAPOUR DENSITY (Air=l) Section VI FIRE AND EXPLOSION DATA FLASH POINT- AUTOIGNITION TEMPERATURE. FLAMMABLE LIMITS EXTINGUISHING MEDIA which is SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION PROCEDURES- Section VII- REACTIVITY DATA STABILITY [Image] INCOMPATIBILITY (conditions to and many avoid)• swell and burst Oxide, exposed to air, Cuts or Scrapes Flush affected eye "immediately" with water. Do not rub eyes if irritated by Following eye wash with water, use Boric then get medical attention Wash thoroughly with soap and warm water, to remove all Lime. Apply burn ointment. during healing to prevent infection. Remove to fresh air. if not breathing give respiration and call a doctor Give three to four glasses of milk or induce vomiting. Get immediate medical Greyish white solid, various sizes - (H20=l) 3 2 - 3.4 2850 C 5162 F Not Applicable Insoluble 12 - Strong Alkaline Mot Applicable butylacetate=l) NM/AP 20C (68F) Not Available None Applicable Not Applicable Not Applicable Non flammable, use extinguishing media appropriate for surrounding fire. None None Stable [Image] Unstable Boric Oxide, Acids, Fluorine, water, steam organic materials Calcium, Oxide will generate heat when moistened and could containers Fluorine will attack Calcium evolving much heat and some light When it will react with moisture and Carbon Dioxide in the HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION [Image] Section VIII: PREVENTIVE MEASURE SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION excessive dust VENTILATION, airborne levels PROTECTIVE GLOVES material getting air. None Will not occur [Image] May Occur Approved filter mask should be worn if is created. Local exhaust as necessary to maintain within prescribed limits Gauntlet type work gloves to prevent inside Tight fitting goggles should be worn Should be worn to prevent Lime from EYE PROTECTION CLOTHING- contacting skin. OTHER PROTECTIVE EQUIPMENT (specify) Long sleeved shirt with collar buttoned, trousers with legs down over boot tops. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid creating dust Keep containers closed to avoid breathing dust and eye contact Keep product dry Store in coo, "DRY", well-ventilated area out of direct contact with weather. STEPS TO BE TAKEN IN CASE THE MATERIAL IS SPILLED OR RELEASED Ventilate area of spill Keep spilled material away from Organic Material and Water. Carefully pick up solid material and collect in metal containers with covers for disposal WASTE DISPOSAL METHOD Trace amounts of residue can be flushed into the drain, using plenty of water. Large amounts may require neutralization by Acid Check local regulations Alternately, waste lime can be used for neutralizing plant acid wastes. Section IX- PREPARATION The information contained herein is given in good faith, but no warranty, expressed or implied, is made. DATE ISSUED: July 1, 1995 BY Calgary Division Office DATE UPDATED October 1, 1999 [Image] Return to MSDS Menu [Image] Return to Main Menu [Image] site design and construction by Cobra Internet Design 2000 SELENIUM DIOXIDE MSDS Number: S1130 Effective Date- 11/17/99 . Product Identification Synonyms Selenium oxide, selenious anhydride CAS No.' 7446-08-4 Molecular Weight- 110 96 Chemical Formula- SeO2 Product Codes U995 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Selenium Dioxide /SeO2/ 7446-08-4 90 - 100% Yes 3. Hazards Identification Emergency Overview DANGER' MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. HIGHLY TOXIC BY INHALATION OF DUST OR VAPOR. CONTACT CAUSES INTENSE LOCAL IRRITATION OF SKIN AND EYES TARGET ORGANS SKIN, EYES, KIDNEY, LIVER, GASTROINTESTINAL TRACT, LUNGS MAY CAUSE ALLERGIC SKIN REACTION. J T Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating 3 - Severe (Life) Flammability Rating- 0 - None Reactivity Rating: 1 - Slight Contact Rating 3 - Severe (Life) Lab Protective Equip GOGGLES, LAB COAT, VENT HOOD, PROPER GLOVES Storage Color Code Blue (Health) Potential Health Effects Acute toxicity of soluble selenium compounds is high A general tissue poison like arsenic, presumably attacking sulfhydryl enzymes. Inhalation Highly toxic via inhalation May cause severe breathing problems that may not appear for several hours after exposure. Irritates the upper respiratory tract. May cause headache, fever, chills. Ingestion Toxic May be fatal if swallowed May cause severe stomach problems. Skin Contact May cause skin burns May be absorbed through the skin in toxic quantities May cause skin rash Prolonged contact may cause skin sensitization. Eye Contact Causes eye irritation May cause "Rose eye", an allergy of the eyelids in which they become puffy Chronic Exposure* Chronic exposure may cause paleness, coated tongue, stomach disorders, nervousness, metallic taste and garlic breath. Aggravation of Pre-existing Conditions Person with a history of asthma, allergies, or known sensitization to selenium, or with a history of other chronic respiratory disease, gastrointestinal disturbances, disorders of the liver or kidneys, or recurrent dermatitis would be expected to be at increased risk from exposure. 4 First Aid Measures Inhalation Remove to fresh air If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately Ingestion Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally Get medical attention immediately 5. Fire Fighting Measures Fire' Not considered to be a fire hazard. Explosion. Not considered to be an explosion hazard Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8 Spills Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area Protect against physical damage Isolate from incompatible substances- Protect from moisture. Wear special protective equipment {Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels Wash hands, face, forearms and neck when exiting restricted areas Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink, or smoke in workplace Containers of this material may be hazardous when empty since they retain product residues (dust, solids), observe all warnings and precautions listed for the product. 8, Exposure Controls/Personal Protection Airborne Exposure Limits -OSHA Permissible Exposure Limit (PEL) 200 ug (Se)/m3(TWA) -ACGIH Threshold Limit Value (TLV) 200 ug(Se)/m3(TWA) Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source/ preventing dispersion of it into the general work area Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact Eye Protection Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9 Physical and Chemical Properties Appearance White crystalline powder Odor- Vapor has a pungent sour smell. Solubility 28% in water @ 20C (68F) Specific Gravity: 3 95 PH No information found % Volatiles by volume @ 21C (70F) 0 Boiling Point Not applicable Melting Point 340C (644F) Vapor Density (Air=l) No information found. Vapor Pressure {mm Hg) 1 @ 157C (315F) Evaporation Rate (BuAc=l) No information found. 10 Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products Toxic metal fumes may form when heated to decomposition Hazardous Polymerization: Will not occur Incompatibilities Organic materials, phosphorous trichloride, strong acids, ammonia Conditions to Avoid* Moisture and incompatibles. 11 Toxicological Information Oral rat LD50 68.1 ictg/kg. Investigated as a mutagen, reproductive effector. \Cancer ListsN NTP Carcinogen Ingredient Known Anticipated IARC Category Selenium Dioxide /Se02/ (7446-08-4) No No None 12 Ecological Information Environmental Fate- No information found. Environmental Toxicity No information found 13 Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility Processing, use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements 14 Transport Information Domestic (Land, D.O.T..) Proper Shipping Name SELENIUM COMPOUND, N 0 S. (SELENIUM DIOXIDE) Hazard Class 6 1 UN/NA UN3283 Packing Group I Information reported for product/size 100G International (Water, I.M.O.) Proper Shipping Name SELENIUM COMPOUND, N 0 S (SELENIUM DIOXIDE) Hazard Class 6 I UN/NA: UN3283 Packing Group I Information reported for product/size 100G International (Air, I C.A.O.) Proper Shipping Name SELENIUM COMPOUND, N.O S. (SELENIUM DIOXIDE) Hazard Class' 6.1 UN/NA. UN3283 Packing Group III Information reported for product/size 100G 15 Regulatory Information \Chemical Inventory Status - Part 1\ Ingredient TSCA EC Japan Australia Selenium Dioxide /Se02/ (7446-08-4) Yes Yes Yes Yes \Chemical Inventory Status - Part 2\ —Canada— Ingredient Korea DSL NDSL Phil Selenium Dioxide /Se02/ (7446-08-4) Yes Yes No Yes \Federal, State S International Regulations - Part 1\ -SARA 302- SARA 313 Ingredient RQ TPQ List Chemical Catg. Selenium Dioxide /Se02/ (7446-08-4) No No No Selenium cmp \Federal, State & International Regulations - Part 2\ -RCRA- -TSCA- Ingredient CERCLA 261.33 8(d) Selenium Dioxide /SeO2/ (7446-08-4) 10 No No Chemical Weapons Convention No TSCA 12(b). No CDTA No SARA 311/312 Acute Yes Chronic Yes Fire No Pressure- No Reactivity: No (Pure / Solid) Australian Hazchem Code No information found Poison Schedule No information found WHMIS- This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR 16 Other Information NFPA Ratings Health. 3 Flammability 0 Reactivity. 0 Label Hazard Warning- DANGER' MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN HIGHLY TOXIC BY INHALATION OF DUST OR VAPOR CONTACT CAUSES INTENSE LOCAL IRRITATION OF SKIN AND EYES. TARGET ORGANS- SKIN, EYES, KIDNEY, LIVER, GASTROINTESTINAL TRACT, LUNGS MAY CAUSE ALLERGIC SKIN REACTION Label Precautions Do not breathe dust or vapor Do not get in eyes, on skin, or on clothing Keep container closed. Use only with adequate ventilation Wash thoroughly after handling Label First Aid If swallowed, induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person If inhaled, remove to fresh air If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes Wash clothing before reuse In all cases get medical attention immediately. Product Use. Laboratory Reagent Revision Information No changes. Disclaimer Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent ^judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER, INC MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. •*•*•*•**•*•*•*•**•*•***** Prepared by Strategic Services Division Phone Number (314) 539-1600 (USA.) nurSfa/ March 22 2001 Page [Image] ANTIMONY TRIOXIDE MSDS Number A7236 Effective Date 08/02/00 I 1 Product Identification Synonyms Antimony oxide antimony peroxide CAS No 1309-64-4 Molecular Weight 291 50 Chemical Formula Sb203 Product Codes J T Baker 0886 0887 5305 Mallinckrodt 0216 2 Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Antimony Trioxide 1309-64-4 99 - 100% Yes 3 Hazards Identification Emergency Overview WARNING' HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN EYES RESPIRATORY AND GASTROINTESTINAL TRACTS AFFECTS THE CARDIOVASCULAR SYSTEM J T Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating 3 - Severe (Life) Flammability Rating 0 - None Reactivity Rating 0 - None Contact Rating 2 - Moderate Lab Protective Equip GOGGLES LAB COAT VENT HOOD PROPER GLOVES Storage Color Code Blue (Health) Potential Health Effects Inhalation Causes irritation to the respiratory tract Symptoms can include sore throat cough Ingestion Ingestion causes irritation to the mouth nose and stomach Other symptoms include salivation cough metallic taste nausea vomiting bloody diarrhea dizziness irritability and muscular pains May cause heart to beat irregularly or stop Skin Contact Causes irritation to skin Symptoms include redness itching and pain Eye Contact Causes irritation redness and pain Chronic Exposure Prolonged or repeated exposure may damage the liver and the heart muscle Prolonged skin contact may cause irritation dermatitis itching and pimple eruptions There is an association between antimony trioxide production and an increased incidence of lung cancer Aggravation of Pre-existing Conditions Persons with pre-existing skin disorders impaired respiratory function or heart disorders (or disease) may be more susceptible to the effects of the substance First Aid Measures Inhalation Remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen Call a physician Ingestion Induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person file ///mac /20%A5%20don/DesktopA20Folder/MSDS/ANTIMONY /620TRIOXIDE ^rsdi I I I lay March 22 2001 Page 2 Skin Contact Immediately flush skin with plenty of soap and water for at least 15 minutes Remove contaminated clothing and shoes Get medical attention Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes lifting lower and upper eyelids occasionally Get medical attention immediately Note to Physician A urine test can be used to confirm exposure to antimony trioxide 1 Big / ml is indicative of potentially harmful exposure Chelators such as BAL and unithiol have been used in some countries 5 Fire Fighting Measures I I I I I Fire Non-combustible but powdered antimony trioxide may ignite and burn when heated in air Explosion Not considered to be an explosion hazard Tnvalent antimony compounds tend to form explosive mixtures with perchloric acid Fire Extinguishing Media Use any means suitable for extinguishing surrounding fire Special Information In the event of a fire wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode Accidental Release Measures Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8 Spills Sweep up and containerize for reclamation or disposal Vacuuming or wet sweeping may be used to avoid dust dispersal US Regulations (CERCLA) require reporting spills and releases to soil water and air in excess of reportable quantities The toll free number for the US Coast Guard National Response Center is (800) 424-8802 7 Handling and Storage I I I I I I I I I Keep in a tightly closed container stored in a cool dry ventilated area Protect against physical damage Isolate from incompatible substances Containers of this material may be hazardous when empty since they retain product residues (dust solids) observe all warnings and precautions listed for the product Exposure Controls/Personal Protection Airborne Exposure Limits -OSHA Permissible Exposure Limit (PEL) 0 5 mg (Sb) m3 (TWA) -ACGIH Threshold Limit Value (TLV) 0 5 mg (Sb)/m3 (TWA) for handling and use A2 suspected human carcinogen for production Ventilation System A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source preventing dispersion of it into the general work area Please refer to the ACGIH document Industrial Ventilation A Manual of Recommended Practices most recent edition for details Personal Respirators (NIOSH Approved) If the exposure limit is exceeded a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier whichever is lowest For emergencies or instances where the exposure levels are not known use a full-facepiece positive-pressure air-supplied respirator WARNING Air purifying respirators do not protect workers in oxygen-deficient atmospheres Skin Protection Wear impervious protective clothing including boots gloves lab coat apron or coveralls as appropriate to prevent skin contact Eye Protection Use chemical safety goggles Maintain eye wash fountain and file ///mac / 20 / A5%20don/Desktop%20Folder/MSDS/ANTIMONY%2r>TRIOXIDE hursday March 22 2001 quick-drench facilities in work area 9 Physical and Chemical Properties Appearance White polymorphic crystals Odor Odorless Solubility Insoluble in water @ 25C (77F) Slightly soluble in water @ 100C (212F) Density 5 2 pH No information found % Volatiles by volume @ 21C (70F) 0 Boiling Point 1425C (2597F) Melting Point 655C (1211F) Vapor Density (Air=l) No information found Vapor Pressure (mm Hg) 1 @ 574C (1065F) Evaporation Rate (BuAc=l) No information found 10 Stability and Reactivity Stability Stable under ordinary conditions of use and storage Hazardous Decomposition Products Toxic metal fumes may form when heated to decomposition Hazardous Polymerization Will not occur Incompatibilities Bromine trifluoride strong acids strong bases reducing agents perchloric acid and chlorinated rubber Reduction with hydrogen or if used near acids it may form a deadly gas (stibine) Conditions to Avoid Dusting and incompatibles LI lexicological Information Oral rat LD50 > 20 g/kg investigated as a mutagen tumorigen reproductive effector \Cancer ListsN NTP Carcinogen Ingredient Known Anticipated IARC Category Antimony Tnoxide (1309-64-4) No No 2B 2 Ecological Information Environmental Fate When released into the soil this material is not expected to leach into groundwater When released into the soil this material is not expected to evaporate significantly When released into water this material is not expected to evaporate significantly Environmental Toxicity The LC50/96-hour values for fish are over 100 mg/1 3 Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility Processing use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state and local requirements 4 Transport Information Domestic (Land DOT) Ilia ///mac'!' 20 ^A5%20don/Dssklop''/ 20Folder/MSDS/ANTIMONY%20THIOXIDE ^Ub< I I I I I I ,'day March 22 2001 Page 4 Proper Shipping Name ANTIMONY COMPOUND INORGANIC SOLID N 0 S (ANTIMONY TRIOXIDE) Hazard Class 6 1 UN/NA DN1549 Packing Group III Information reported for product/size 250LB International (Water I M 0 ) Proper Shipping Name ANTIMONY COMPOUND INORGANIC SOLID N 0 S (ANTIMONY TRIOXIDE) Hazard Class 6 1 UN/NA UN1549 Packing Group III Information reported for product/size 250LB International (Air I C A 0 ) Proper Shipping Name ANTIMONY COMPOUND INORGANIC SOLID N 0 S (ANTIMONY TRIOXIDE) Hazard Class 6 1 UN/NA UNI549 Packing Group III Information reported for product/size 250LB Regulatory Information —\Chemical Inventory Status - Part 1\ Ingredient TSCA EC Japan Australia timony Trioxide (1309-64-4) Yes Yes Yes Yes \Chernical Inventory Status - Part 2\ --Canada-- Ingredient Korea DSL NDSL Phil I timony Trioxide (1309-64-4) Yes Yes No Yes El —\Federal State & International Regulations - Part 1\ -SARA 302- SARA 313 :ngredient RQ TPQ List Chemical Catg timony Trioxide (1309-64-4) No No No Antimony com I \Federal State & International Regulations - Part 2\ : -RCRA- -TSCA- ngredient CERCLA 261 33 8(d) Antimony Trioxide (1309-64-4) 1000 No No Hanical Weapons Convention No TSCA 12 (b) No CDTA No •RA 311/312 Acute Yes Chronic Yes Fire No Pressure No Reactivity No (Pure / Solid) I I I WARNING THIS PRODUCT CONTAINS A CHEMICAL (S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER Australian Hazchem Code 2X Poison Schedule S6 WHMIS This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR L6 Other Information I I I I NFPA Ratings Health 2 Flammability 1 Reactivity 0 Label Hazard Warning WARNING1 HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN EYES RESPIRATORY AND GASTROINTESTINAL TRACTS AFFECTS THE CARDIOVASCULAR SYSTEM Label Precautions Avoid breathing dust Avoid contact with eyes skin and clothing Keep container closed Use only with adequate ventilation Wash thoroughly after handling Label First Aid If swallowed induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person If inhaled remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen In case of flle///mac%20/A5/20don/Desktop%20FoWer/MSDS/ANTIMONY%20TRIOXIDE iursday March 22 2001 contact immediately flush eyes or skin with plenty of water for at least 15 minutes Remove contaminated clothing and shoes Wash clothing before reuse In all cases call a physician Product Use Laboratory Reagent Revision Information No changes Disclaimer Mallmckrodt Baker Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER INC MAKES NO REPRESENTATIONS OR WARRANTIES EITHER EXPRESS OR IMPLIED INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDINGLY MALLINCKRODT BAKER INC WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION Prepared by Strategic Services Division Phone Number (314) 539-1600 (USA) file ///mac k201 A5%20don/Desktop%20Folder/MSDS/ANTIMONYy 20TRIOXIDE (I i I I I I I I I I I I I I I I I I iday March 22 2001 Page 1 :mage] 'ANNOUS CHLORIDE DS Number S6434 Effective Date 04/15/98 Product Identification Synonyms Tin (II) chloride dihydrate stannochlor stannous chloride dihydrate Tin Dichloride Dihydrate CAS No 7772-99-8 (Anhydrous) Molecular Weight 225 63 Chemical Formula SnC12 2H20 Product Codes J T Baker 3980 3986 Mallmckrodt 8176 8584 Composition/Information on Ingredients Ingredient CAS No Percent Hazardous iStannous Chloride 7772-99-8 98 - 100% Yes Hazards Identification Emergency Overview WARNING1 HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN EYES AND RESPIRATORY TRACT J T Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating 2 - Moderate Flammability Rating 0 - None Reactivity Rating 1 - Slight Contact Rating 2 - Moderate Lab Protective Equip GOGGLES LAB COAT VENT HOOD PROPER GLOVES Storage Color Code Orange (General Storage) Potential Health Effects Inhalation Causes irritation to the respiratory tract Symptoms may include coughing shortness of breath Ingestion Causes irritation to the gastrointestinal tract Symptoms may include nausea vomiting and diarrhea May cause burning in mouth and throat abdominal pain reduced blood pressure stomach bleeding collapse and convulsions May cause liver and kidney damage Skin Contact Causes irritation to skin Symptoms include redness itching and pain Eye Contact Causes irritation redness and pain Chronic Exposure Repeated skin contact with solutions may cause skin rashes in susceptible individuals Prolonged inhalation of dust or fume may result in a benign pneumoconiosis producing distinctive changes in the lungs with no apparent disability or complications Aggravation of Pre-existing Conditions Persons with pre-existing skin disorders or eye problems or impaired liver kidney or respiratory function may be more susceptible to the effects of the substance I First Aid Measures I I Inhalation Remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen Get medical attention Ingestion Induce vomiting immediately as directed by medical personnel file ///mac ^20 / AS^Odon/Desttop ^20Folder/MSDS/STANNOUS ^20CHLORIDE lursday March 22 2001 Page Never give anything by mouth to an unconscious person Get medical attention Skin Contact Immediately flush skin with plenty of water for at least 15 minutes Remove contaminated clothing and shoes Get medical attention Wash clothing before reuse Thoroughly clean shoes before reuse Eye Contact immediately flush eyes with plenty of water for at least 15 minutes lifting lower and upper eyelids occasionally Get medical attention immediately I 5 Fire Fighting Measures Fire Not considered to be a fire hazard Explosion Not considered an explosion hazard but reacts explosively when mixed with nitrates or hydrogen peroxide (> 3% solution) Sealed containers may rupture when heated Fire Extinguishing Media Use any means suitable for extinguishing surrounding fire Special Information In the event of a fire wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode Aqueous solutions of this material are acidic Avoid its contact with eyes and skin Avoid breathing its fumes or dust When heated to decomposition it emits toxic and corrosive fume of hydrochloric acid 6 Accidental Release Measures Ventilate area of leak or spill Wear appropriate personal protective equipment as specified in Section 8 Spills Sweep up and containerize for reclamation or disposal Vacuuming or wet sweeping may be used to avoid dust dispersal 7 Handling and Storage Keep in a tightly closed container stored in a cool dry ventilated area Protect against physical damage Isolate from incompatible substances Aqueous solutions are acidic use only in corrosion-resistant vessels Containers of this material may be hazardous when empty since they retain product residues (dust solids) observe all warnings and precautions listed for the product 3 Exposure Controls/Personal Protection Airborne Exposure Limits inorganic Tin Compounds as Sn -OSHA Permissible Exposure Limit (PEL) 2 mg/m3 (TWA) -ACGIH Threshold Limit Value (TLV) 2 mg/m3 (TWA) -NIOSH Recommended Exposure Limits (REL) 2 mg/m3 (TWA) Ventilation System A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source preventing dispersion of it into the general work area Please refer to the ACGIH document Industrial Ventilation A Manual of Recommended Practices most recent edition for details Personal Respirators (NIOSH Approved) If the exposure limit is exceeded a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier whichever is lowest For emergencies or instances where the exposure levels are not known use a full-facepiece positive-pressure air-supplied respirator WARNING Air purifying respirators do not protect workers in oxygen-deficient atmospheres Skin Protection Wear impervious protective clothing, including boots gloves lab coat apron or coveralls as appropriate to prevent skin contact Eye Protection Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible Maintain eye wash fountain and quick-drench facilities in work area file ///mac him A5 A20don/Desktop / 20Folder/MSDS/STANNOUSA20CHLORIDE ursday March 22 2001 Page 3 Physical and Chemical Properties Appearance Colorless crystals Odor Slight odor of hydrochloric acid Solubility 118g/100ml water @ OC (32F) Specific Gravity 2 71 PH No information found % Volatiles by volume @ 21C (70F) 0 Boiling Point No information found Melting Point 38C (100F) When rapidly heated Vapor Density (Air=l) No information found Vapor Pressure (mm Hg) No information found Evaporation Rate (BuAc=l) No information found Stability and Reactivity Stability Powerful reducing agent Small quantities of hydrochloric acid are present in aqueous solutions Absorbs oxygen from air and forms the insoluble oxychloride Forms an insoluble basic salt when dissolved with much water Hazardous Decomposition Products When heated to decomposition it emits toxic and corrosive fume of hydrochloric acid Hazardous Polymerization Will not occur Incompatibilities Sodium potassium bromine trifluoride calcium carbide calcium acetylide ethylene oxide and nitrates Reacts with hydrazine hydrate to form dihydrazine chloride which decomposes explosively when heated Contact with strong oxidizing agents or alkalis will generate heat and fumes Conditions to Avoid Moisture heat flames ignition sources and incompatibles I Toxicological Information Anhydrous Oral rat LD50 700 mg/kg Investigated as a tumorigen mutagen reproductive effector Hydrate Investigated as a _ mutagen reproductive effector I \Cancer Lists\• NTP Carcinogen Ingredient Known Anticipated IARC Category Istannous Chloride (7772-99-8) No No None I Ecological Information Environmental Fate No information found Environmental Toxicity No information found 3 Disposal Considerations I I Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility Processing, use or contamination of this product may change the waste management options State and local disposal regulations may differ from federal disposal regulations Dispose of container and unused contents in accordance with federal state and local requirements I file Illrmtf/ 20%A5%20don/DesktOp%20Folder/MSDS/STANNOUSy 20CHLORIDE hursday March 22 2001 Page 14 Transport Information Domestic (Land DOT) Proper Shipping Name CORROSIVE SOLIDS N O S (STANNOUS CHLORIDE) Hazard Class 8 UN/NA UN1759 Packing Group III Information reported for product/size 100LB International (Water I M O ) Proper Shipping Name CORROSIVE SOLIDS N 0 S (STANNOUS CHLORIDE) Hazard Class 8 UN/NA UN1759 Packing Group III Information reported for product/size 100LB International (Air I C A 0 ) Proper Shipping Name CORROSIVE SOLIDS N 0 S (STANNOUS CHLORIDE) Hazard Class 8 UN/NA UN1759 Packing Group III Information reported for product/size 100LB I 15 Regulatory Information \Chemical Inventory Status - Part 1\ Ingredient TSCA EC Japan Australia Stannous Chloride (7772-99-8) Yes Yes Yes Yes \Chemical Inventory Status - Part 2\ —Canada— Ingredient Korea DSL NDSL Phil Stannous Chloride (7772-99-8) Yes Yes No Yes \Federal State & International Regulations - Part 1\ -SARA 302- SARA 313 Ingredient RQ TPQ List Chemical Catg Stannous Chloride (7772-99-8) No No No No \Federal State & International Regulations - Part 2\ -RCRA- -TSCA- Ingredient CERCLA 261 33 8(d) Stannous Chloride (7772-99-8) No No No Chemical Weapons Convention No TSCA 12(b) No CDTA No 3ARA 311/312 Acute Yes Chronic Yes Fire No Pressure No Reactivity No (Mixture / Solid) Australian Hazchem Code 2X Poison Schedule No information found WHMIS This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR L6 Other Information NFPA Ratings Health I Flammability 0 Reactivity 0 Label Hazard Warning WARMING1 HARMFUL IF SWALLOWED OR INHALED CAUSES IRRITATION TO SKIN EYES AND RESPIRATORY TRACT Label Precautions Avoid contact with eyes skin and clothing Avoid breathing dust Keep container closed Use only with adequate ventilation Wash thoroughly after handling Label First Aid If swallowed induce vomiting immediately as directed by medical personnel Never give anything by mouth to an unconscious person If inhaled remove to fresh air If not breathing give artificial respiration If breathing is difficult give oxygen In case of contact immediately flush eyes or skin with plenty of water for file ///macA20 AA5"C 20don/Desktop / 20Folder/MSDS/STANNOUS1)' 20CHLORK3E r«day March 22 2001 Page 5 at least 15 minutes Remove contaminated clothing and shoes Wash clothing before reuse In all cases get medical attention product Use • Laboratory Reagent Revision Information I MSDS Section(s) changed since last revision of document include ' 3 16 Disclaimer I Mallinckrodt Baker Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy This document is intended only as a I guide to the appropriate precautionary handling of the material by a properly trained person using this product Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose MALLINCKRODT BAKER INC MAKES NO REPRESENTATIONS OR WARRANTIES I EITHER EXPRESS OR IMPLIED INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS ACCORDINGLY MALLINCKRODT BAKER INC WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR I RELIANCE UPON THIS INFORMATION prepared by Strategic Services Division Phone Number (314) 539-1600 (USA) I I I I I I I I I I I I file ///mac%20%A5 / 20don/Desktop%20Folder/MSDS/STANNOUS A20CHLORIDE hursday March 22 2001 HEALTH RELATED INFORMATION ON SILICA Click on the URL below to connect with [Image] http //www osha-slc gov/SLTC/silica_advisor/mainpage html [Image] http //www cdc gov/niosh/silicpag html U S SILICA COMPANY MSDS - MATERIAL SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Names/Trade Names Silica Sand sold under various names ASTM TESTING SANDS ¥ GLASS SAND ¥ FLINT SILICA ¥ DM-SERIES ¥ F-SERIES ¥ FOUNDRY SANDS ¥ FJ-SERIES ¥ FP-SERIES ¥ H-SERIES ¥ L-SERIES ¥ N-SERIES ¥ NJ-SERIES ¥ OK-SERIES ¥ P-SERIES ¥ T-SERIES ¥ HYDRAULIC FRACING SANDS ¥ MIN-U-SIL ¥ MYSTIC WHITE ¥ #1 DRY ¥ #1 SPECIAL ¥ PENN SAND ¥ Q-ROK ¥ SIL-CO-SIL ¥ SUPERSIL Synonyms/Common Names Sand Silica Sand, Quartz Crystalline Silica Flint Ground Silica Manufacturer s Name U S Silica Company P 0 Box 187 Berkeley Springs WV 25411 Emergency Telephone Number 304-258-2500 304-258-8295 (fax) Date Prepared September 15 2000 SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS Ingredients Crystalline Silica (Quartz) Aluminum Oxide Iron Oxide Titanium Oxide Chemical Formula Si02 A1203 Fe203 Ti02 Typical % Weight 99 0 - 99 By Exposure Limits for Hazardous Ingredients Crystalline Silica (Quartz) OSHA PEL 10 mg/m3 % Si02 + 2 ACGIH TLV 05 CAS # 14808-60-7 1344-28-1 1309-37-1 13463-67-7 NIOSH REL 05 The exposure limits are time-weighted average concentrations for an 8-hour workday and a 40-hour workweek Crystalline silica exists in several forms the most common of which is quartz If crystalline silica (quartz) is heated to more than 870,C it can change to a form of crystalline silica known as trydimite and if crystalline silica (quartz) is heated to more than 1470,C, it can change to a form of crystalline silica known as cristobalite The OSHA PEL for crystalline silica as trydimite and cristobalite is one-half of the OSHA PEL for crystalline silica (quartz) SECTION 3 - HAZARD IDENTIFICATION Emergency Overview The U S Silica Company material is a white or tan sand or ground sand It is not flammable combustible or explosive It does not cause burns or severe skin or eye irritation A single exposure will not result in serious adverse health effects Crystalline silica (quartz) is not known to be an environmental hazard Crystalline silica (quartz) is incompatible with hydrofluoric acid fluorine, chlorine trifluoride or oxygen difluoride Potential Health Effects Inhalation file ///mac / 20 / A5%20don/Desktop / 20Folder/MSDS/sllica'y 20sand hursday March 22 2001 Page 2 I I I I I I I I I I I a Silicosis Respirable crystalline silica (quartz) can cause silicosis a fibrosis (scarring) of the lungs Silicosis may be progressive it may lead to disability and death b Cancer Crystalline silica (quartz) inhaled from occupational sources is classified as carcinogenic to humans c Autoimmune There are some studies that show excess numbers Diseases of cases of scleroderma and other connective tissue disorders in workers exposed to respirable crystalline silica d Tuberculosis Silicosis increases the risk of tuberculosis e Nephrotoxicity There are some studies that show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica Eye Contact Crystalline silica (quartz) may cause abrasion of the cornea Skin Contact Not applicable Ingestion Not applicable Chronic Effects The adverse health effects — silicosis cancer autoimmune diseases tuberculosis and nephrotoxicity — are chronic effects Signs and Symptoms of Exposure Generally there are no signs or symptoms of exposure to crystalline silica (quartz) Medical Conditions Generally Aggravated by Exposure The condition of individuals with lung disease (e g , bronchitis emphysema chronic obstructive pulmonary disease) can be aggravated by exposure See Section 11 Toxicological Information for additional detail on potential adverse health effects SECTION 4 - FIRST AID MEASURES Inhalation No specific first-aid is necessary since the adverse health effects associated with exposure to crystalline silica (quartz) result from chronic exposures If there is a gross inhalation of crystalline [silica (quartz) remove the person immediately to fresh air give artificial respiration as needed seek medical attention as needed I Eye Contact Wash immediately with water If irritation persists seek medical attention Skin Contact Not applicable Ingestion Not applicable SECTION 5 - FIRE FIGHTING MEASURES Crystalline silica (quartz) is not flammable combustible or explosive iECTION 6 - ACCIDENTAL RELEASE MEASURES ills Use dustless methods (vacuum) and place into closable container for disposal or flush with water Do not dry sweep Wear protective equipment specified below Disposal Method See Section 13 SECTION 7 - HANDLING AND STORAGE Krecautions During Handling and Use Do not breath dust Use adequate entilation and dust collection Keep airborne dust concentrations below EL Do not rely on your sight to determine if dust is in the air Silica may be in the air without a visible dust cloud If dust cannot be kept (elow permissible limits wear a respirator approved for silica dust when sing handling, storing or disposing of this product or bag Practice ood housekeeping Do not permit dust to collect on walls floors, sills edges machinery or equipment Maintain clean and fit test respirators in accordance with OSHA regulations Maintain and test fentilation and dust collection equipment Wash or vacuum clothing that as become dusty See also control measures in Section 8 Precautions During Storage Avoid breakage of bagged material or spills of bulk material See control measures in Section 8 I file ///mac / 207 A5%20don/Desktop%20Folder/MSDS/silica(y 20sand hursday March 22 2001 Page Do not use U S Silica Company materials for sandblasting The OSHA Hazard Communication Standard 29 CFR Sections 1910 1200 1915 1200 1917 28, 1918 90 1926 59 and 1928 21 and state and local worker or community right-to-know laws and regulations should be strictly followed WARN YOUR EMPLOYEES (AND YOUR CUSTOMERS IN CASE OF RESALE) BY POSTING AND OTHER MEANS OF THE HAZARDS AND THE REQUIRED OSHA PRECAUTIONS PROVIDE TRAINING FOR YOUR EMPLOYEES ABOUT THE OSHA PRECAUTIONS See also American Society for Testing and Materials (ASTM) standard practice E 1132-99a 'Standard Practice for Health Requirements Relating to Occupational Exposure to Respirable Crystalline Silica SECTION 8 - EXPOSURE CONTROL / PERSONAL PROTECTION Local Exhaust Use sufficient local exhaust to reduce the level of respirable crystalline silica to below the PEL See ACGIH Industrial Ventilation A Manual of Recommended Practice (latest edition) Respiratory Protection The following chart specifies the types of respirators which may provide respiratory protection for crystalline silica Particulate Concentration MINIMUM RESPIRATORY PROTECTION* Any particulate respirator except single-use or quarter-mask respirator 10 x PEL or less Any fume respirator or high efficiency particulate filter respirator Any supplied-air respirator Any self-contained breathing apparatus A high efficiency particulate filter respirator with a full facepiece 50 x PEL or less Any supplied-air respirator with a full facepiece helmet or hood Any self-contained breathing apparatus with a full facepiece A Type C supplied-air respirator operated in 500 x PEL or less pressure-demand or other positive pressure or continuous-flow mode Self-contained breathing apparatus with a full facepiece operated in pressure-demand mode A Greater than 500 x combination respirator which includes a Type C PEL or entry and supplied-air respirator with a full facepiece escape from unknown operated in pressure-demand or other positive concentrations pressure continuous-flow mode and an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive pressure mode *Use only NIOSH-approved or MSHA-approved equipment See 29 CFR 1910 134 and 42 CFR 84 See also ANSI standard Z88 2 (latest revision) American National Standard for Respiratory Protection Permissible Exposure Levels Exposure Guidelines Component CAS No Percentage OSHA ACGIH NIOSH (by wt ) TWA STEL TWA STEL TWA STEL Unit Crystalline Silica (Quartz) 14808-60-7 99 0-99 9 10 None 05 None 05 None mg/m3 % Si02 + 2 SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance White or tan sand granular crushed or ground Boiling Point 4046 ,F Odor None Vapor Pressure (mm Hg ) None Specific Gravity (Water =1) 2 65 Vapor Density (Air = 1) None file ///mac ^20%A5%20don/Desktop'y 20Folder/MSDS/silica'y 20sand 1 hursday March 22 2001 Page 4 • Melting Point 3110 ,F Solubility in Water Insoluble in water H Evaporation Rate (Butyl Acetate = 1) None SECTION 10 - STABILITY AND REACTIVITY Stability Crystalline silica (quartz) is stable I I I I I Incompatibility (Materials to Avoid) Contact with powerful oxidizing agents such as fluorine, chlorine trifluoride and oxygen difluoride may cause fires Hazardous Decomposition or Byproducts Silica will dissolve in hydrofluoric acid and produce a corrosive gas - silicon tetraf luoride Hazardous Polymerization Will not occur SECTION 11 - TOXICOLOGICAL INFORMATION A SILICOSIS The major concern is silicosis caused by the inhalation and retention of respirable crystalline silica dust Silicosis can exist in several forms chronic (or ordinary) accelerated or acute Chronic or Ordinary Silicosis (often referred to as Simple Silicosis) is the most common form of silicosis, and can occur after many years of exposure to relatively low levels of airborne respirable crystalline silica dust It is further defined as either simple or complicated silicosis silicosis is characterized by lung lesions (shown as radiographic pacities) less than 1 centimeter in diameter primarily in the upper lung zones Often simple silicosis is not associated with symptoms detectable changes in lung function or disability imple silicosis may be progressive and may develop into complicated ilicosis or progressive massive fibrosis (PMF) Complicated silicosis or PMF is characterized by lung lesions (shown as radiographic opacities) greater than 1 centimeter in diameter Although there may be no symptoms .ssociated with complicated silicosis or PMF the symptoms if present, ,re shortness of breath, wheezing cough and sputum production 'omplicated silicosis or PMF may be associated with decreased lung function and may be disabling Advanced complicated silicosis or PMF may lead to death Advanced complicated silicosis or PMF can result in heart isease secondary to the lung disease (cor pumonale) g: I I.ccelerated Silicosis can occur with exposure to high concentrations of respirable crystalline silica over a relatively short period the lung ^Lesions can appear within five (5) years of the initial exposure The •(regression can be rapid Accelerated silicosis is similar to chronic or Hsrdinary silicosis except that the lung lesions appear earlier and the ^progression is more rapid Icute Silicosis can occur with exposures to very high concentrations of espirable crystalline silica over a very short time period, sometimes as horc as a few months The symptoms of acute silicosis include progressive shortness of breath fever cough and weight loss Acute silicosis is fatal I CANCER IARC - The International Agency for Research on Cancer ( IARC ) concluded that there was sufficient evidence in humans for the carcinogenicity ofIrystallme silica in the forms of quartz or cristobalite from ccupational sources and that there is sufficient evidence in xperimental animals for the carcinogenicity of quartz and cristobalite The overall IARC evaluation was that crystalline silica inhaled in the ^orm of quartz or cristobalite from occupational sources is carcinogenic Bo humans (Group 1) The IARC evaluation noted that carcinogenicity was Hot detected in all industrial circumstances studies Carcinogenicity may T5e dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its olymorphs For further information on the IARC evaluation see IARC tonographs on the Evaluation of Carcinogenic Risks to Humans Volume 68 JSilica, Some Silicates (1997) NTP - The National Toxicology Program in its Ninth Annual Report on Iarcinogens classified silica crystalline (respirable) as a known uman carcinogen OSHA - Crystalline silica (quartz) is not regulated by the U S Occupational Safety and Health Administration as a carcinogen I fil8///mac%20'yA5'y20don/Desktop'y20Folder/MSDS/silica%20sand hursday March 22 2001 Page There have been many articles published on the carcinogenicity of crystalline silica which the reader should consult for additional information the following are examples of recently published articles (1) Crystalline Silica and Lung Cancer The Problem of Conflicting Evidence Indoor Built Environ Volume 8 pp 121-126 (1998) (2) Crystalline Silica and the risk of lung cancer on the potteries , Occup Environ Med Volume 55 pp 779-785 (1998) (3) Is Silicosis Required for Silica-Associated Lung Cancer' American Journal of Industrial Medicine Volume 37 pp 252- 259 (2000) (4) Silica Silicosis and Lung Cancer A Risk Assessment American Journal of Industrial Medicine Volume 38 pp 8-18 (2000) (5) Silica Silicosis and Lung Cancer A Response to a Recent Working Group Report Journal of Occupational and Environmental Medicine Volume 42 pp 704-720 (2000) C AUTOIMMUNE DISEASES There is evidence that exposure to respirable crystalline silica (without Silicosis) or that the disease silicosis is associated with the increased incidence of several autoimmune disorders -- scleroderma systemic lupus erythematosus rheumatoid arthritis and diseases affecting the kidneys For a review of the subject the following may be consulted Occupational Exposure to Crystalline Silica and Autoimmune Disease Environmental Health Perspectives Volume 107 Supplement 5 pp 793-802 (1999) Occupational Scleroderma Current Opinion in Rheumatology Volume 11 pp 490-494 (1999) D TUBERCULOSIS Individuals with Silicosis are at increased risk to develop pulmonary tuberculosis if exposed to persons with tuberculosis The following may be consulted for further information Occupational Lung Disorders Third Edition Chapter 12 entitled Silicosis and Related Diseases Parkes W Raymond (1994) Risk of pulmonary tuberculosis relative to Silicosis and exposure to silica dust in South African gold miners Occup Environ Med Volume 55 pp 496-502 (1998) E KIDNEY DISEASE There is evidence that exposure to respirable crystalline silica (without Silicosis) or that the disease Silicosis is associated with the increased incidence of kidney diseases including end stage renal disease For additional information on the subject the following may be consulted Kidney Disease and Silicosis Nephron Volume 85 pp 14-19 (2000) SECTION 12 - ECOLOGICAL INFORMATION Crystalline silica (quartz) is not known to be ecotoxic i e there is no data which suggests that crystalline silica (quartz) is toxic to birds fish invertebrates microorganisms or plants For additional information on crystalline silica (quartz) see Sections 9 (physical and chemical properties) and 10 (stability and reactivity) of this MSDS SECTION 13 - DISPOSAL CONSIDERATIONS General The packaging and material may be landfilled however material should be covered to minimize generation of airborne dust RCRA Crystalline silica (quartz) is not classified as a hazardous waste under the Resource Conservation and Recovery Act or its regulations 40 CFR 261 et seq The above applies to materials as sold by U S Silica Company The material may be contaminated during use and it is the responsibility of the user to assess the appropriate disposal of the used material SECTION 14 - TRANSPORT INFORMATION Crystalline silica (quartz) is not a hazardous material for purposes of transportation under the U S Department of Transportation Table of Hazardous Materials 49 CFR 172 101 SECTION 15 - REGULATORY INFORMATION UNITED STATES (FEDERAL AND STATE) TSCA No Crystalline silica (quartz) appears on the EPA TSCA inventory under the CAS No 14808-60-7 RCRA Crystalline silica (quartz) is not classified as a hazardous waste under the Resource Conservation and Recovery Act or its regulations 40 CFR 261 et seq CERCLA Crystalline silica (quartz) is not classified as a hazardous substance under regulations of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) 40 CFR 302 file///mac%20yA5%20don/Desktop/20Folder/MSDS/silica%20sand I hursdai I I I I I i I iy March 22 2001 Page i Emergency Planning and Community Right to Know Act Crystalline silica (quartz) is not an extremely hazardous substance under Section 302 and is not a toxic chemical subject to the requirements of Section 313 Clean Air Act Crystalline silica (quartz) mined and processed by U S Silica Company was not processed with or does not contain any Class I or Class II ozone depleting substances FDA Silica is included in the list of substances that may be included in coatings used in food contact surfaces 21 CFR 175 300(b) (3) (xxvi) NTP Respirable crystalline silica (quartz) is classified as a carcinogen OSHA Carcinogen Crystalline silica (quartz) is not listed California Proposition 65 Crystalline silica (quartz) is classified as a substance known to the State of California to be a carcinogen CANADA Domestic Substances List U S Silica Company products as naturally-occurring substances are on the Canadian DSL WHMIS Classification D2A OTHER JEINECS No 238-878-4 EEC Label (Risk/Safety Phrases) R 48/20 R 40/20 S22 S38 •IARC Crystalline silica (quartz) is classified in IARC Group 1 [National state provincial or local emergency planning community right-to-know or other laws regulations or ordinances may be applicable—consult applicable national state provincial or local laws •SECTION 16 - OTHER INFORMATION Hazardous Material Information System (HMIS) I P: I :ealth * lammability 0 .eactrvity 0 Protective Iquipment E For further information on health effects see Sections 3 and 11 of :his MSDS (ational Fire Protection Association (NFPA) ealth 0 lammability 0 Reactivity 0 ^BVeb Sites with Information about Effects of Crystalline Silica Exposure [Image] Ftp //www osha-slc gov/SLTC/silicacrystalline/index html - The cupational Safety and Health Administration [Image] »ttp //www cdc gov/niosh/silicpag html - NIOSH Hotlinks to Silicosis revention T'he U S SILICA COMPANY DISCLAIMER he information and recommendations contained herein are based upon data believed to be correct However no guarantee or warranty of any kind Kxpress or implied is made with respect to the information contained erein We accept no responsibility and disclaim all liability for any armful effects which may be caused by purchase resale use or exposure to our silica Customers-users of silica must comply with all applicable health and safety laws regulations and orders including the OSHA (•Jazardous Communication Standard I BACK HOME NEXT [employment opportunities][home] [news] file Wmac / 20 / AST 20don/0esktop1' 20Folder/MSOS/sillca%20san<i hilrsday March 22 2001 Pa9« North American Operations | Glass Sands | Foundry Sands | Ground Silica Calcined Kaolin Clay | Building Products | Pool Filter Sands Recreational Products | Golf Course Sands I Other Products Florisil | Plant Locations | Online Product Information Data Base | U S S People Job Opportunities | MSDS/Links to Silica Health & Safety Information What s New I Contact Us I file///mac/.20%A5'5'20don/D6sktop/20Folder/MSDS/silioa%20sand r-UUU I 3 UJC IU I760a340590 P 02 **,*•>•» •( ^w w-KBAHgysJnc, MATEfilAL SAFfTY PAT* SMffiT KB ALLOYS, IMC. ENVIRONMENTAL, HEALTH ft SAFETY SERVICES PO 60X14AZ7 READING, PA 18612-4627 (215) 570-3350 POTASSIUM ALUMINUM FLUORIDE MSOS IDENTIFICATION NUMBER A400 DATE ISSUED 12/16/86 DATE REVISED 3/19/92 ISSUED SY DUNN EMERGENCY PHONE NUMBER CHEWraeC..HffHjrt BTX? PERCttHT CAB NUHBW NOSHmce»Nutuxeft EXPOSURE MTTS CSHA1WA ACt»M-n.V AJumtwn FTwrtX tQQ Norn FkxxW* 2.5, AJ- Ou«t«19, Rinpiratil* PractiorMS z$, AJ- Oud 1(i 0; PuniM 9 0 * M<^«ut»t«rKMcM9fw(h«y«awique«cpocur«flma. Tht •DMTX* of an «xpe«w» Smtt few not fewer corwtdwration for «xpo»ur« r(ak lnth«ibMAMO(speclteKTfanntflon,prQ(«sakxutfju4g«rnwtt^ y ^- ^ W REPTING RE«3UJREMeKT8 1 V ELEMENT Awrmum nuorl* SUBJECT TO HO vi toiu . P 03 IV. PHYSICAL PROPERTIES *. , v FREEZING POINT- Not Applicable VAPOR PRESSURE (mmHg). Not ApoNcable MELTING POINT 1010-1030*0 VAPOR DENSITY (AJFU1)- Not AppfcaWe 80IUNG POtNT Decomposes DENSITY 1)266 SUBLIMES 0 Not Applicable SOLUBILITY IN WATER:Sight EVAPORATION RATS Not Applicable %VOUT1LES BY VOLUME. Not Applicable APPEARANCE AND ODOR Powder or Lumps- Wttt* QytUOirw Gofer - No Odor ,:, v. :FIRE, EXPLOSION AKD FLASH POINT {WITH TEST METHOD) Nona UEL None UEL Nona EXTINGUISHING MEDIA TN» matwi* * iwnwmbuafcto. Use sxtingulahty me« appropriate to th*aunounctng firs. SPECIAL flRE FIGHTING PROCEDURES IT this malarial fe involved in * flra-flghtino tart, UM « WMw« «Jr-*t^q«W. posftlv* UNUSUAL FIRE AND EXPLOSION HAZARDS No unusual «n or ttptotto) hazards tn Mtod«Md w«n tM» GENERAL RHACrnVTTY TW» product i* « Matt* mattridL INCOMPATBIUTY (MATERIALS TO AVOID) HAZARDOUS DEOOMPOetTION PRODUCTS Owing m«ttng oMrtffan* md ^ «tova»d ttmpwaturM, variou* fluwfcfe compound*w»l bw Ubtrattd inducing, tut not United to, hytingen ffuorM* «nd pat^nium PRIMARYROUTES) OPEXPOSURE INHALATION Inrwatton of Huorld* wto m«y rwult during btondna mUng m««Jna pouring, crvnWngBrinding operation* which g«Mrtf* «lrbofn« pwtteutaM duilig UM c7thk nutortaL a 1NQESTION Hand, dothlnj and <«r* contact wtth tuorfo* salts, du* Of funw can tagw Ingwtton rfpcrtlcuMo during hand to mouth acthritiai auch at wtlng, drinking, wwWng, nai Ming, ata SKIN SMn contact with nuorlda aate can causa Matton, radnaw, awaBng of tissue and paonanont tcamngor EYES. PartK^ata1hioridasaltductor1umaeaneawaMv«r«tournir«anatwaln0tot^surrounding tiaaua Airbocr»partteula«a1«a)wafi«problam aawt»a» irmrtfng frwan itto the ty« »odc«if th« hand or dothtng is exmtamlnatad with fkMnda aalu TOXICTTY Exposure to the dust or fume of fluorlda salts may present significant healh hazards. Fluoride salts cancausa acute poisoning or death (prfnopaiy by figestton) Sign contact and exposure to mucousmembranes can cause severe irritation and tissue damage Nose Meeds and stow heating scan in the nasal passage haw bean reported Gripping bone change* and mottfmg of tooth anamaTani chrontoeffects of exposure although they ara not common among currant industrial employees ACUTE Ingastlon o( fluorlda sans can eitM aavara gast« pak\ Man« blaadli^Jtsatw tfamaoa and^ daath Acuta poisoning from Inhalation la not common. Nos« Weeds, akin Irritation, ey» Wtation, tl«w« damaga and alow haalfrtg scars can rfsuft if axpqaum is excessiva Fluroida aalts are soluble m body fluids and sweat and ara corroaiv* to the akm and mv«cous mambranea.EFFECTS OF OVEfl£XPOSURE CHRONIC Chronic axposura to fluonda compounds has baan reported to causa * calcification of boneand Sgatnants known a* ostaosdawais (haro^ifMJofth»boriaduatodapc4*k«offkKino«}arKlm(pttlrgof looth enamel atthough nelgher tffacJ b common in industrial population*. Prolonged axposura tofluorlda aalts may causa damaga to the skin, eye and mucous membranes. , , n a MUI-U I 3 WCINH I Utt 17604340590 P 04 VI HEALTH HAZARD INFORMATION (oon«nu»d} CARCINOGENICREFERENCES Neither product nor its Ingredient* are fated a* « carcinogen by the National Toxtedogy Program,International Agency for Research on Cancer, or Urw«j state* Occupational Safety end HealthAdministration. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Pewon* with pro-sxtetfng eye and skin disorders or damage to mvwoue memt>r«ne« may be more•ueceptatte to the effect* of fluoride exposure Because faerie* duet and fume can b* a respiratoryJffftart and haa been linKed to akeMal ahnormailil** and gastric oompfloatlone, proper screening orexamination* »hoiW be conducted on Individual* who m*y be exposed to further rtek If handBng anduae of thm material causea excessive expoeure. INHALATION oTfflewfty caueed by Wwiattoo of ttuoiMe eomr wxa>*» removal to froeh aft, rf, ha* stopped, perform artificial respiration ancT obtain medical ejalatante «t one* OtoeeJon for respiratory cempBoatlon* and pulmonary edema, ahouM foBow tor at least 48 hoursdepending on exposure Specific cflnteaj teats may be Indicated nmaounda•no obtain INGCSTION Swaftowrw fluoride compounda require* medical a**f*tance at once. Do NOT Indues vomiting for anyamount Mutton of fnijeeted fluoride muai be oof»e with caution. Control of anode, Inflammation of<e taaue deauuctten and electrolyte Imotlanee require «loat oDeetveKon for at least46 houra.progr fiNN 8Mn out* and afrawcn* and contamirudon muct be flushed «mme<Satery under • drenctdrig rinee ofooof water MM «Wn eflee** can be teeeted byJ»^.M)di*Ti gjuconate appled ttpieaty ]Mor« sever* pain and tissue wthcalGiumgkjoonate. suned medical treatment it neoeaaary to control Fluoride EVES Pain can be reBevedahould be obtained atcompound*. compound* ahoJd be fluehed from the eyet t wfthTor 3 drop* of S% eontoealne op*** at onoe. Cofitaot ienaa* *nouw not be worn with ooptoua amourts of dean water ntetolutlon. MeoTcal •aantanca V worWnfl with ftiorWe aatt* or VENTILATION Local exhaust vertflalion^houW be used to control expowre to airbome ftoonde oompounda whenever poeslbie RESPIRATORY PROTECTION Use NIOSH approved retpirater* M specified by an InduttneJ Hygienat or Ouaflbexf Safety ProteeslonaL tuns luncflon lett* are reoommended for u»er» of negetrve prewure devk»». PROTECTIVE GLOVES Wear tfove* to prevent hand contact w*h lluorto* oompounda. QaunM^typa gtove* anrecommended and, where fluoride containing aolutiona or add* are used, uw gloves should be acxt EYE PROTECTION Wear safety 9l«*»ea, chemical oogglea (ptastle lens) or fui^Tace thteM when handltng fluoride compounoa. Do not wear contact lenses. OTHER PROTECTIVE EQUIPMENT Protective clothing tuch as uniforms, disposable coveralls, safety shoes, etc may be required curing nandNno operabons as appropriate to the dreum«tancee of exposure For Increased protection H may be aoViwwe to wear acid re««tant jacket, boots, trousers, etc., aa appropriate. RECOMMENDED MONITORING PROCEDURES ENVIRONMENTAL SURVEILLANCE Exposure to the elements Identified in Section ll can be beat determined by having or sample* taken In the employee breathing zone, worfc area or department Sample analysis should be for total ftuofdg content pha any other constituent of concern. MEDICAL SURVEILLANCE. Lung fwwion t««t», chest x-rays and routine physical examinations may be useful to determine effect* of dust or fume expotur* Urinary fluoride anarysl* can be a useful indicator of exposure, but require* Dasebne te*Ung and pott-expoaure sample*. K B HLLUl'b uJtNrUCHfc£TQ = 0: K. INVfllQNMfNTAL PROTECTION INFORMATION STEPS TO 9E TAKEN IF MATERIAL IS RELEASED OR (f ttifc m«t«rltt( v* in pww or oust form, own-up oftoutt tw conducted w«ft g vacuumutilizing * nigh efficiency paniculate atr flttrafion «yst«rn Cauttor. ahouW bo takeft to mlnlmteo artww generation of powd* w dust and avoid <wntamln*tloft of aw and w«t«r Sp4tl» «f f<wo(KJ* ccfitatruns *oWfoft« or eci& shcwlo b* rwutralizwd by carefvt adc&ioro of« Hmu eiurry Boc1^ asb «r othw aw»)l Stn«il fcmooits may t» i/»a<«i by u^ng «xe«a wat»r to wk«w sicfcifty CiauJion mustc« uik«n during n«utrali2aifon to nvori *xpotwr« to r^drogttn ftoondo ga» or 8t«t« «• fed»raf rsguJatlorw m«y pracadur««. Conuet an WASTE DISPOSALMEWOO aJ {Englnoor or eorwuttart and cornpourxte may Mw*AWxxn* nmtoiom,«urte» «o« ENVJRONMEMTAL HAZARDS <Kc.) »hou(d 6» conwtxted <mm*i*rt^/ tf wch peMntiaf tor • dcvticp «n «m«rmncy spiff r«porw» plua tt h «l«o advteabto TO enmU«r rnonttcrmg wwbtarrt air •t w*fl«* «ny ffffluera which m*y oonttin ttiKtrieto » potvntiar «KJUt» tor *»m«s« to *qu«lte ortawetnti «cc«y»lema. HANDUNG STORAGE PRECAUTIONS product mutt to hand** accofdfoHty to »•» tot, «hap* «ftf qutrtty of mutwiti tnvoiv<kw mlrtmtt*pdw to to Stor» tt»l« product m « dry cr*« Fhwnde sa«s flhowtf n« I* stored «$aonnc to acfeSs. K*0p«mr/ from contact with food or tod products. JfTflpflMftt POTASSUM AUMWJM dUGWCi OANCEfl! iNKAlATiON OF OUST Ofl FUMi MAY CAUSE CAJ8€ SE«OU3 LUNG iWURI SS3W, ErE AND MJCOOS M^BRAHE JRWTATON MAY OCCUR MAY 66 FATAL IF SWNiOWS) lo^ u» vxmw«lMm1wrtw-ti^mtp^&n^qx:tn. prgte«(lutt«Iuir<uwappro«^ tomeonaeturtftduMorlURMi, »!«qura»«t*«^«»r«r^ B HU_UT3 WtfNH I LHtt TO 17604340590 P 06 CONTiNT 4 DESCRIPTION OF K8 ALLOYS INC MATERIAL SAFETY DATA SHEETS Tba*» definition* ara Inwrcfcd for UM with Malarial S*fcty Data Sh*«t» tupoN* by KB ALLOYS, INC Questio«tKMts should be dlraciad to. MANAGER OF INDUSTRIAL HYGIENE KB ALLOYS, INC PO 80X14927READING, PA 10612-4927 SECTION 1 - PRODUCT tOEHTWCATlON vnVflFllCVl NwffW* »"» ifwirw w»»iaji^i •' ** irivi « w i ^FitrwinMWkMw mwmu* WPA6orth»Ch«mk>alAlMtr«<ttS«fVte«(CA8).TradeN«n« Thtnam«ih*pfoo\irt)««owby.it.th«productrCtMmkml Namr, AwotraldattanationferaQrowpofatoinanrtorcompounda, Formuta; TN«ci«^daBigndonibranafaraar«orcmipo^ SiCTION II - HAZAHOOOS OONSTTTVENTS Conatttu«fit(a)t Tha ctwntcai oomponant«(s) of th» productcfhaatth hazardPwcanli Thtatrioumefooinpenantorrangapivaaritlnthaf+A^t •^•MbaA^Aan * •*•**----*^— -*- - —--.-—1 *J *i*_^.*i__—. — — *t vxi«ffirwa*d on*w«ghlbMl«i Owmie«l SutatewitOWAPCLi TlwOee trt)aht«d *» CTW ADMM Number tor •KMdnihntor mMfcngro p»«k«xpoiur»limn (P) mprmod •» PPM (pint po digL nJior} ori» M(Mm,ldenHcaltatht08HAPeL.•heuW not to ttCMoid ^ «ny time. >«^afOcvwnrn«SJllf)e»u«rttMy^rt^^ACQIH also ftoomm»nd»«^xxtt»rm«iyo»Mf«ifnit(STEgter certain «uboncet»<t seOTTOH M-SARA TITLE II SECTION IV - PHYSICAL PROPERTIES Point Th«temp«f«iw»«wrtchaHquldeh«ft9f»to«»olW Aran0«RMyatgtv«aolimThtt*mp*wur*«lwMoh«Ma<lch«igwtoaHquid. ArariMfMytofliraaBoiling Point: Th« t«np«f«ur« at wWcrt a ««uW chanflw tea vapor, Usually ««p*«»»«d at »«mtevrtpr«»ur»(760mtn-Ha)SubUfiM«i8: Tn«t«mp«f0(uMatwhJefta«oiwetiangndir*c<lyt9VtporEvapotitlon ("Utr (ndievttd M f»«»«r or ttowr than Elhyl Bftar unteas 9tat«dAppaaranM and Odor. A ascription of tht product in twma of form, eoJor, odor, tte. Vapor Prtraur* (mmMfl). TMpr«aaur«ofa«aturat«dvtporabov«ftll^«tpraa<^an«nHg«a^ Vapor Dan«8y5lr«1). 7lwr«iativtd^na«yofaviv>ororgweompar«dtoin«6^vo(uin»ofalr Alrte wwatenttsl 0Sp«etflearaytty(HaO*lV Th« raflo of th« w«tgh» of a vwh«n« of material toth* wsigW of an aqutivofcm* of ivatar Wat«ri»•qutatenttot 0<$44C. TH«t«fm"DENSITY"MMHOMthe<onotntraticnofmao«a»thamanporwrtvolur»a,i.g.pourids/cuttolneh.SotobllltyJnWattr; Th %Volatll**ByV0lum swi i r. o nu_u r 3 IU 17S04340590 P 07 SECTION V - FfRE, EXPLOSION AND REACTTYTrY INFORMATION Flaert Point (WHO Teat Mtthod), The towwi temperature at wMcn • vapotfair mbctur« wn propagate a flame above theaurtace ol tha ft^erWbting lasted i--»-w— FtammaMo (Exptoalve) Umlt» V/V%. LEU LOWER EXPLOSION UMIT Thetoweat vapor coweotrattatri aft at which tanlHon b UELt UPPER EXPLOSION LIMIT The highest vapor concentration in air «t which Ignition by apart or flam* wW occurThetoweat vapor coweotrattatri aft at which tanlHon by wart or flame w« occur Rjrtlngulehlng Media. The type of fire extinguishing madia to be ueed taking into account tha typeof cham«al and k»Tla/nmaoia charactanatica SpaoiaJ Plra Fighting ProctOwrt a- Indlcataa aquipmant to protaet flraman front toxx products of combuatioaUnuaual Flra «(M ficnjoalon Haxarda: Crtamleal enangaa Aw may occur under haat of flr« candMona. Qanaral RaaoUvlty: Tha tandancy o< a matarial to undargocnamieatfaaction with tha raltaaa of anargy. lneompattWHty(Mattriala To Avoid)' MittarlalawtwincouMeauaadangarouaraaetiont.Hoardcut DacompeMtion Products: Tha braakdown of a malarial Into compound* or rtamantsth* may hav» apaclflchazard proparwadrffarart than tha original /p*artaJ. ^^ SECTION VI - HEALTH HAZARD INFORMATION Primary Routate) ot Expoaura: inMiatlocu TV»br«axrir»8lno(ao^1urna. vaporInoaatton: Thaiwaflowr^ofaauoBtancaaaaccrtrttwtkjntoaxposura.tWru ThEyaa; Th««flaotToidalty; tnaava oomponanta. Moat ao^1urnauoBtanca uralvthaaxpoauraontnaaya. aaMha/ooaaorlM . laatraau(t»ara from axposuratatta conduct* on animalaauchaarataorniioa.andeauionlaraoornmandad to making (Bract comparison to human balnga.•TfaetOrOvaraxpoatira' Afltfa: n»Matla<aof«npoaurawlthaavBraiymptoma. Xawonte Enactidualoaxpaauratnatoavatopala^cvaratongparlodoftln^orwrKnra^Carclnoga««cRaf*fancaa: AvaMtordiBrancaawnl^lrKleataifMpotartiarforamataMiteojoal CoodWona Aggnivatad By Bxpoaurai IMo)calconollomtnatwariantconalo>rajhmraaardii SECTION VII - EMERGENCY ft FIWT AID PROCEDURES Inhalation; Em«rowicy act to to ao^a*aaoVaf*aar?»ct«A» to Inhalation of a ha^^htgaatton: Emwsereyactlontoao^awadvaraaaltactao^toJngaationofahazaittaJanwt^^ Skin: EmargaiKyacflontoao^racaaovaraaalliaetadiwtoaldnoontaetorabaori]^ Cytat SECTION Vtil - INDUSTRIAL HYGIENE CONTROL MEASU VamOaUom Racoovrwnbed type of vanrttatten for control ofry Prataotlort: (frnaral information on 1ha typaof lovfa: R^commartiatlenlorprotaetlontopravani Sya Protection' RjaeCfnmandaijpn to protact agaJnat aya IrjutyOtnaf i or particutata. "rprtfactlon recommended.- 1 with the material, Protective Equipment Other pefeor»lprotaalveeoj»ipmertpP€)aueh«B€lo^ eta that may be riata to prated again* injury or expoeura. jmanded Monitoring Procedure*:environmental SunrtUlancej Person* air aampllng or ratted procaduree to evaluate exposure of an Individual. _ Medical SurveBlaoca; SJotogicaJ mortlortng or reJaled taata/eKamirtatJont to evaluate the anectac^expoaura to an indhriduai. SECTION fX - ENVIRONMENTAL PROTECTION INFORMATION Siapa To Ba Taken If Material la Relaaaed Or Spinad. Spedncafly refer* 10 containment, cleanup and control. Waatt DIapoaaJ Mtthod: Refara to rooommendad disposal practices orapplcable regulatory requirement* when known.Environmental Hazard*? Refer* to formation aucnaa aquae or vagecanwtox^.art^which are available »cm regufatory or pubitoned tachnkalaarvfce*. SECTION X - SPECIAL PRECAUTIONS Handllno Precautlorta: Safe movement of the product may require specific handling procedure*. Storag* Precaution*'. Safe suxag* of tha product may require apecme ctecaga procedufee ADOmONAL INFORMATION COMPLETCNi&S OF THIS INPORMATm THS RESULTS TO BE OBTAINtp FROM USB OF THIS INFORMATION OR THE PRODUCT, THE aAWTYOi* "THIS PRODUCT, OR TWI HAZARDS RSUSTED TO ITS USE 1>^irtfQrtn«icn«ndthaprodutt«ekjn«4lwdenttie oendRMn «« ** paraon raving them «ha» metali*>airo*n TOTflL P 07 [Image] Material Safety Data Sheet Ashland Chemical Co. BORAX 5 MOL TYPE F Date Prepared 01/26/98 Date Printed 06/21/99 MSDS No 999 0000683-004 0041 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name. BORAX 5 MOL TYPE F General or Generic ID' SALTS Company Ashland Chemical Co P.O. Box 2219 Columbus, OH 43216 614-790-3333 Emergency Telephone Number. 1-800-ASHLAND (1-800-274-5263) 24 hours everyday Regulatory Information Number 1-800-325-3751 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS Number % (by weight) SODIUM TETRABORATE PENTAHYDRATE 1330-43-4 100 0 HAZARDS IDENTIFICATION Potential Health Effects Eye Can cause eye irritation Symptoms include stinging, tearing, redness, and swelling of eyes Skin Can cause skin irritation Symptoms may include redness and burning of skin, and other skin damage. Additional symptoms of skin contact may include allergic skin reaction (delayed skin rash which may be followed by blistering, scaling and other skin effects) Passage of this material into the body through the skin is possible, and may add to toxic effects from breathing or swallowing. Swallowing Swallowing small amounts of this material during normal handling is not likely to cause harmful effects Swallowing large amounts may be harmful Inhalation This material is a dust or may produce dust Symptoms of Exposure Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include, stomach or intestinal upset {nausea, vomiting, diarrhea) irritation (nose, throat, airways), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness), hair loss, shock Target Organ Effects No data Developmental Information No data Cancer Information No data Other Health Effects No data Primary Route(s) of Entry Inhalation, Skin absorption 4. FIRST AID MEASURES Eyes If symptoms develop, immediately move individual away from exposure and into fresh air Flush eyes gently with water for at least 15 minutes while holding eyelids apart, seek immediate medical attention Skin Remove contaminated clothing. "Wash exposed area with soap and water If symptoms persist, seek medical attention. Launder clothing before reuse Swallowing Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth, place individual on the left side with the head down Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting If possible, do not leave individual unattended. Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention, keep person warm and quiet. If person is not breathing, begin artificial respiration If breathing is difficult, administer oxygen Note to Physicians Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material skin, lung (for example, asthma-like conditions) 5 FIRE FIGHTING MEASURES Flash Point Not applicable Explosive Limit Not applicable Autoignition Temperature No data Hazardous Products of Combustion No data Fire and Explosion Hazards No special fire hazards are known to be associated with this product Extinguishing Media regular foam, water fog, carbon dioxide/ dry chemical. Fire Fighting Instructions Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipment Refer to the personal protective equipment section of this MSDS NFPA Rating Not determined 6 ACCIDENTAL RELEASE MEASURES Small Spill Sweep up material for disposal or recovery Large Spill Shovel material into containers. Thoroughly sweep area of spill to clean up any residual material. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Chemical splash goggles in compliance with OSHA regulations are advised, however, OSHA regulations also permit other type safety glasses Consult your safety representative Skin Protection Wear resistant gloves such as neoprene/ To prevent repeated or prolonged skin contact, wear impervious clothing and boots Respiratory Protections If needed/ use a NIOSH/MSHA jointly approved dust respirator. {Ask your safety representative ) Engineering Controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s) Exposure Guidelines Component SODIUM TETRABORATE PENTAHYDRATE (1330-43-4) OSHA VPEL 10,000 mg/m3 - TWA 9 PHYSICAL AND CHEMICAL PROPERTIES Boiling Point Not applicable Vapor Pressure No data Specific Vapor Density Not applicable Specific Gravity 1 815 @ 68.00 F Liquid Density Not applicable Percent Volatiles No data Evaporation Rate Not applicable Appearance No data State SOLID Physical Form POWDER Color WHITE, NO ODOR Odor No data pH Not applicable 10 STABILITY AND REACTIVITY Hazardous Polymerization Product will not undergo hazardous polymerization. Hazardous Decomposition No data Chemical Stability Stable. Incompatibility No data 11 TOXICOLOGICAL INFORMATION No data 12 ECOLOGICAL INFORMATION No data 13 DISPOSAL CONSIDERATION Waste Management Information Dispose of in accordance with all applicable local, state and federal regulations 14 TRANSPORT INFORMATION DOT information - 49 CFR 172 101 DOT Description NON-REGULATED BY D 0 T Container/Mode 55 GAL DRUM/TRUCK PACKAGE NOS Component* None RQ (Reportable Quantity) - 49 CFR 172 101 Not applicable 15. REGULATORY INFORMATION US Federal Regulations TSCA (Toxic Substances Control Act) Status TSCA (UNITED STATES) The intentional ingredients of this product are listed. CERCLA RQ - 40 CFR 302 4(a) None listed SARA 302 Components - 40 CFR 355 Appendix A None Section 311/312 Hazard Class - 40 CFR 370 2 Immediate(X) Delayed( ) Fire{ ) Reactive! ) Sudden Release of Pressure( ) SARA 313 Components - 40 CFR 372 65 None International Regulations Inventory Status Not determined State and Local Regulations California Proposition 65 None Pennsylvania RTK Label Information BORON SODIUM OXIDE (B4NA2O7) 1330-43-4 16 OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Last page [image] [Image] a l i. Ml I P IT I I I I I I I I I RHOM-POULENC BASIC CFIEM3CALS CO Dfivt Box lil Shdton, CT 054W <20J)92i jJCC 24-HOUR IMEXGENCY TELEPHONE CHEMTRJEC 1 JOW24-S3W PROHUCT SAMP'S] SODA ASS (SODIUM CAUROKA.TE,Eff«ctiv» Ditt Mi/ Jl Jl April U, "M I «n(-.r<iroui WIJCHTI IDS CU »0dl, D INOR£DrE^^rS/SUMMAIlY OF 4I7 Kir,<Jg -1I-I OJJU HAIMBOOt («)/ 109 ON MPKXXIO OOHTAC- MM CAUjrX fXIH Av«i<l »nt»et vltt •>••' •lt^. IIN* «l««M»f «»«» »H«»v«hly »«»»r h<n4Llnf ««rvhtn «yj»j m 6* not t*X» ifit%rixkl)/ vz MTJOKM. riU »KOttCTICUI UWCIXtJOU KIN.TH riu Ntxncvtn Kr« * 9 r~TT "i 5 6 0 | 9 SAM TirLX tH KAIAM «ULJ1 JflW.TICH (UAilK 01 HO I IB PHYSICAL DATA OMVITTlIVXX Pt>»lWiMirMd fOIKT («0 t*y>)i J.JJJ rt 400'C (7JJVI b««UI t« «vaU« CO,11,3 (IV IN u»rc» (uro Mom (Tit kddLtloiul yt*n«l«r ,.»««-t<.3-<.»0) IV FIR£ A.ND DATA »?piic4bu (•€ I'M)' Net r:u QU« ii:*4 to i/MJ[C« Do»> not. conulbut*Lit < (lr» «i;0 K1 l , -.t 1 ' i * ci. DATA TQ (CM M TO AVOID I tout* vitfl ltr«as »5U»,vltn *l,. ,j Mtofltl wtum oont4ii with «trt*in f*«d prMu<vi t» »*«u MiUuir .runcoatiLa roduclnf l««<jri, MY »«««1 It fen dotdly cirwri *o»««u. fti rr -,.ri*nk onift ttt enoxlat «U«<« wllfi 1 »OWLJ.V X*( 1000'c VI HEALTH HAZARD AID PROCEDURES IXX3SUU !K«ft*«lt*6Hlh«d for N«t Ott^j-vii.IflITVJ.Ite»«l IKI/l' (3), •-- Ikln t((«cd KlUi.v, KU<I (3) 4 Kr •14 hr (3) 30 ,.c rtr.M, (J, em trrtcta or SIMOU «j,u<*ind •kin JKIA Canticxi Conttcti or eu«ii, «1 di.« fklit »A«»rpelon through Unit »Un II Hk«l>- <« t>< n«<JltglBl« t« to* MH, vnio*t tn4 l*ipir*tery irict in pr«i•oiiiur* ai tw«4t »*y 41 CVVMUTOIUMl 4M/oc irncfi c/eOA**ntratwi ••lutlaii* U ««n or ih My ctut* eh«alei' sviru IXin liil^l with ... , eCHpmOM M9»IIII,r AMfUVATIO llf1UD lmmi«n uy •« 4ttX4V4l«4 in Ir*4«KiA« «( 4u4t m*j «ff(4V4ti 4CVtl orpvilaenuy 4li«4)4 flMT MP fnCCIPWIi If vlMb* U •anicleui lAd 4ltrl, <]Wf two OC M«« 91414*4 or v« n•ilk k* drink »« n«« UJ-». vMillM If faallLnt 4»4« 4f««r •> fiuitli 404in »• not fiv with iO4f 4nd il in«li4n ««n«ui Btt IM091XTI MttieXL AtttVTIOK tu ««o( vtl«n ht» aa«uff>«t, thtn« «*tn«r «»^««u*» e4n4 <Ka« b«for» rtuj. err HIO At wietla to fr«»h tlr I/ net fertitftlng nff »lrli wlrA t rt'V /ilK«*«r« •*m«v«in*t.>4» aa«uff>«t, thtn «c «r*l(L«l.«\. tttpLrttL«n Ifor IrrU.tlefi 4«v«l«»«, «1T KtOIOAL XtTINTIOil In cut tt conxiex, Li**dUt«Vy (luth «y«»tvith pUniy e<Ii4*t 1] «lnu««« vi|n« »n »y*»iiii (ovMiln, If »v4ii«j5l«iAd lo««r 1U< 4n4 rU.. wll anil» thai tit HttltU. tn to M In frtm <lM4 by P 18 070617 DOD Hazardous Materials Information System DoD 6050 5-L AS OF July 1998 FSC 5610 NUN OON038360 Manufacturer's CAGE- 74754 Part No Indicator A Part Number/Trade Name &8PHELINE SYENITE--MINEX 10 General Information Item Name Company's Name UNIMIN SPECIALTY MINERALS INC Company's Street ROUTE 127 Company's P O, Box 33 Company's City ELCO Company's State IL Company's country OS Company's Zip Code 62929 Company's Emerg Ph # 618-747-2328 Company's Info Ph # 618-747-2328 Distributor/Vendor # 1 Distributor/vendor # i Cage- Distributor/Vendor # 2 Distributor/Vendor # 2 Cage Distributor/Vendor ft 3 Distributor/Vendor # 3 Cage- Distributor/ Vendor # 4 Distributor/Vendor # 4 Cage Safety Data Action Code Safety Focal Point K Record No For Safety Entry 001 Tot Safety Entries This Stk# 001 Status SMJ Date MSDS Prepared 20MAY92 Safety Data Review Date 31DEC92 Supply Item Manager MSDS Preparer's Name Preparer's Conpany- Preparer's St Or P O Box Preparer's City Preparer's State Preparer's Zip Code Other MSDS Number- MSDS Serial Number BQXKK Specification Number Spec Type, Grade, class- Hazard Characteristic Code UK Unit Of Issue - Unit Of Issue Container Qty Type Of Container Net Unit Weight Report for NUN OON038360 NRC/State License Number Net Explosive Weight- Net Propellant Weight-Ammo Coast Guard Ammunition Code Ingredients/Identity Information Page 1 070617 Proprietary NO Ingredient BEPHELINE SYENITE Ingredient sequence Number 01 Percent N/K Ingredient Action Code- Ingredient Focal Point N NIOSH (RTECS) Number 1003350NE CAS Number 37244-96-5 OSHA PEL NOT APPLICABLE ACGIH TLV NOT APPLICABLE Other Recommended Limit N/K Proprietary NO Ingredient <0 003% NATURALLY OCCDRING CONTAMS IWCL ANTIMONY, ARSENIC, BARIUM, CADMIUM, CHROMIUM, LEAD, MERCURY, SELENIUM, & SILVER Ingredient Sequence Number 02 Percent H/K Ingredient Action Code Ingredient Focal Point N NIOSH (RTBCS) Number 9999999ZZ CAS Number OSHA PEL NOT APPLICABLE ACGIH TLV NOT APPLICABLE Other Recommended Limit N/K Physical/Chemical Characteristics Appearance And Odor WHITE, NO ODOR Boiling Point N/A Melting Point 2233F,1223C Vapor Pressure (MM Hg/70 F) N/A Vapor Density (Air=l) N/A Specific Gravity 2 61 (H*20=l) Decomposition Tentperature N/K Evaporation Rate And Ref NOT APPLICABLE Solubility In Water NEGLIGIBLE Percent Volatiles By Volume N/K Viscosity pH 10 1 Radioactivity Form (Radioactive Matl) Magnetism (Milligauss) Corrosion Rate (IPY). N/K Autoignition Temperature Report for NIIN- OOK038360 Fire and Explosion Hazard Data Flash Point NONFLAMMABLE Flash Point Method N/P Lower Explosive Limit N/A Upper Explosive Limit N/A Extinguishing Media- FOLLY OXIDIZED, WILL NOT BURN USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS (FP N). Special Fire Fighting Proc WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N) Unusual Fire And Expl Hazrds Page 2 I I I I I I I I I I I I I I I I I I I 070617 Reactivity Data Stability YES Cond To Avoid (Stability) NONE Materials To Avoid NONE Hazardous Decomp Products NONE Hazardous Poly Occur NO Conditions To Avoid (Poly) NOT RELEVANT = s:=£ = = :=:c:=:=7S = :=s:£==:r:s=::£:r = —s~== = = = = = ~«=~~ —— ~ —=~ = ~=£===£~~~~ —== = —— ~==~~ = —= ~~=—3====z = ==== Health Hazard Data 3=3= ;==£ ;=3£ s;s=£ ;===:=:=.=::=:= ==s==: 3= =± =:?= 3=,±=c==:~=3==—==^—=—== 3S=3s=:=si==:3:3=.5= 3= 3= =======:==———===3=35=5= ==323= =3=:=== =i =5 LD50-LC50 Mixture NONE SPECIFIED BY MANUFACTURER Route Of Entry - Inhalation: YES Route Of Entry - Skin NO Route Of Entry - Ingestion NO Health Haz Acute And Chronic EXCESSIVE OR PRLNGD INHAL OF DUST MAY RESULT IN HARM OR INJURY TO THE RESPIR SYST CONTAINS MERCURY AND LEAD WHICH APPEAR ON THE NAVY LISTING OF OCC CHEM REPRO HAZ SEEK CONSULTATION FROM APPROPRIATE HEALTH PROF CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING & EXPOSURE INFORMATION (FP N) Carcinogenicity - NTP NO Carcinogenicity - IARC NO Carcinogenicity - OSHA. NO Explanation Carcinogenicity: NOT RELEVANT Signs/Symptoms Of Overexp SYMPTOMS OF EXCESSIVE EXPOSURE INCLUDE SHORTNESS OF BREATH AND REDUCED PULMONARY FUNCTION THIS INERT MATERIAL GIVES HO POTENTIAL ACUTE TOXIC HAZARD Med Cond Aggravated By Exp: INDIVIDUALS WITH RESPIRATORY DISEASE, INCLUDING, BUT NOT LIMITED TO, ASTHMA AND BRONCHITIS, OR SUBJECT TO EYE IRRITATION SHOULD BE PRECLUDED FROM EXPOSURE Emergency/First Aid Proc EYES FLUSH WITH HATER FOR AT LEAST 15 MINUTES INHALATION- REMOVE TO FRESH AIR GIVE OXYGEN WITH ARTIFICIAL RESPIRATION AS NEEDED SEEK MEDICAL ATTENTION FOR TREATMENT, OBSERVATION AND SUPPORT AS NEEDED SKIN FLUSH WITH COPIOUS AMOUNTS OF WATER (FP N) INGESTION CALL MD IMMEDIATELY {FP N) Precautions for Safe Handling and Use =s = s==s=;=E=^a3e = = =£ss;=:=£=s=:=ss;r=i=£= = =:ss = s~=?=s=:=:=rs = = — — «~=; = c=se=e=S3: = e:s=s=s==s=s=:=:s=====;=s==;===:s=: Steps If Matl Released/Spill IF UNCONTAMINATED, COLLECT USING DUSTLESS METHOD (WATER OR VACUUM) IF CONTAMINATED, USE APPROPRIATE METHOD IN LIGHT Report for NUN OON038360 OF NATURE OF CONTAMINATION USE APPROPRIATE CONTAINER Neutralizing Agent NONE SPECIFIED BY MANUFACTURER Waste Disposal Method IF UNCONTAMINATED, DISPOSE AS AN INERT NON- METALLIC MINERAL DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, & LOCAL REGULATIONS (FP N) IF CONTAMINATED USE APPROPRIATE METHOD IN LIGHT OF CONTAMINATION IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL LAWS Precautions-Handling/Storing NORMAL PRECAUTIONS AGAINST BAG BREAKAGE OR SPILLS OF BULK MATERIAL AVOID CREATION OF RSSPIRABLE DUST Other Precautions USE ADEQ VENT & DUST COLLECTION DO NOT PERMIT DUST TO ACCUMULATE IN WORK AREA.MAINTAIN & USE PROPER & CLEAN NIOSH/MSHA APPRVD RESP EQUIP CLEAN CLTHQ WHICH HAS BECOME DUSTY WARN & TRAIN YOUR EMPLOYEES & WARN YOUR CUSTOMERS (IN EVENT (SUPDAT) Control Measures Respiratory Protection USE NIOSH/MSHA APPRVD CONVENTIONAL PARTICULATE RESP PRDT BASED ON CONSIDERATIONS OF AIRBORNE CONG & DURATION OF EXPOS SEE MOST RECENT STDS OF ANSI (Z 88 2), OSHA {29 CFR PART 1910 134), MSHA (30 Page 3 070617 CFR PART 56) AND NIOSH (NIOSH POCKET (S0PDAT) Ventilation TO MEET PEL REQUIREMENTS Protective Gloves IMPERVIOUS GLOVES (FP N) Eye Protection CHEMICAL WORKERS GOGGLES (FP N) Other Protective Equipment AS APPROPRIATE IN LIGHT OF SPECIFIC APPLICATION Work Hygienic Practices AVOID CREATING AND BREATHING DUST CLEAN CLOTHING WHICH HAS BECOME DUSTY Suppl Safety & Health Data OTHER PRECAUTIONS OF RESALE) IN ACCORDANCE WITH ALL APPLICABLE FEDERAL AND STATE "RIGHT TO KNOW" LAWS AND REGULATIONS RESPIRATORY PROTECTION GUIDE TO CHEMICAL HAZARDS) = = = = == = = = = = = =: = = = ==^= 5=s === = s= = = = = = ^ = = =: = =: = =:z=== = = =5 = = = = = = = = = = = =s = — ±=:3 = = = = =:=; ;==: = = = = = Transportation Data Transportation Action Code Transportation Focal Point Trans Data Review Date DOT PSN Code DOT Symbol DOT Proper Shipping Name DOT Class DOT ID Number- DOT Pack Group DOT Label DOT/DoD Exemption Number IMO PSN Code IMO Proper Shipping Name IMO Regulations Page Number IMO UN Number IMO UN Class IMO Subsidiary Risk Label IATA PSN Code IATA UN ID Number IATA Proper Shipping Name IATA UN Class Report for NUN OON038360 IATA Subsidiary Risk Class IATA Label AFI PSN Code API Symbols- AFI Prop Shipping Name AFI Class AFI ID Number AFI Pack Group AFI Label- AFI Special Prov AFI Basic Pac Ref MMAC Code N 0 S Shipping Name Additional Trans Data Disposal Data Disposal Data Action Code Disposal Data Focal Point Disposal Data Review Date- Rec f For This Disp Entry Tot Disp Entries Per NSN Landfill Ban Item Page 4 I I I I I I I I I I I I I I I I I I I 070617 Disposal Supplemental Data 1st EPA Haz Wst Code New 1st EPA Haz Wst Name New 1st EPA Haz Wst Char New 1st EPA Acute Hazard New 2nd EPA Haz Wst Code New 2nd EPA Haz Wst Name New 2nd EPA Haz Wst Char New 2nd EPA Acute Hazard New 3rd EPA Haz Wst Code New 3rd EPA Haz Wst Name New 3rd EPA Haz Wst Char New 3rd EPA Acute Hazard New Label Data Label Required YES Technical Review Date Label Date MFR Label Huaiber- Label Status G Common Name NEPHKLINE SYENITE--MINSK 10 Chronic Hazard N/P Signal Word Acute Health Hazard-None- Acute Health Hazard-Slight. Acute Health Hazard-Moderate Acute Health Hazard-Severe Contact Hazard-None Contact Hazard-Slight- Report for NUN OON038360 Contact Hazard-Moderate Contact Hazard-Severe Fire Hazard-None Fire Hazard-Slight Fire Hazard-Moderate Fire Hazard-Severe Reactivity Hazard-None Reactivity Hazard-Slight Reactivity Hazard-Moderate Reactivity Hazard-Severe Special Hazard Precautions EXCESSIVE OR PRLNGD INHAL OF DUST MAY RESULT IN HARM OR INJURY TO THE RESPIR SYST CONTAINS MERCURY AND LEAD WHICH APPEAR ON THE NAVY LISTING OF OCC CHEM REPRO HAZ SEEK CONSULTATION FROM APPROPRIATE HEALTH PROF CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING & EXPOSURE INFORMATION {FP N) SYMPTOMS OF EXCESSIVE EXPOSURE INCLUDE SHORTNESS OF BREATH AND REDUCED PULMONARY FUNCTION THIS INERT MATERIAL GIVES NO POTENTIAL ACUTE TOXIC HAZARD protect Eyes protect Skin Protect Respiratory Label Name UNIMIS SPECIALTY MINERALS INC Label Street ROUTE 127 Label P 0 Box 33 Label City ELCO Label State IL Label zip Code 62929 Label Country US Label Emergency Number- 618-747-2328 Page 5 hursday March 22 2001 Page MSDS - SODIUM NITRATE CRYSTAL I 1 - PRODUCT IDENTIFICATION PRODUCT NAME SODIUM NITRATE CRYSTAL FORMULA NAN03 FORMULA WT 84 99 CAS NO 07631-99-4 NIOSH/RTECS NO WC5600000 COMMON SYNONYMS SODIUM)I) NITRATE NITRIC ACID SODIUM SALT SODA NITER CHILE SALTPETER PRODUCT CODES 3771 3770 4501 EFFECTIVE 01/22/87 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 1 SLIGHT FLAMMABILITY - 0 NONE REACTIVITY - 3 SEVERE (OXIDIZER) CONTACT - 1 SLIGHT HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD 4 = EXTREME HAZARD) LABORATORY PROTECTIVE EQUIPMENT SAFETY GLASSES LAB COAT PRECAUTIONARY LABEL STATEMENTS DANGER CAUSES IRRITATION HARMFUL IF SWALLOWED OR INHALED STRONG OXIDIZER - CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS DO NOT STORE NEAR COMBUSTIBLE MATERIALS AVOID CONTACT WITH EYES SKIN CLOTHING KEEP IN TIGHTLY CLOSED CONTAINER WASH THOROUGHLY AFTER HANDLING IN CASE OF FIRE SOAK WITH WATER IN CASE OF SPILL SWEEP UP AND REMOVE FLUSH SPILL AREA WITH WATER SAF-T-DATA(TM) STORAGE COLOR CODE YELLOW (REACTIVE) 2 - HAZARDOUS COMPONENTS COMPONENT % CAS NO SODIUM NITRATE 90-100 7631-99-4 3 - PHYSICAL DATA BOILING POINT N/A MSDS for SODIUM NITRATE CRYSTAL BELTING POINT 306 C ( 583 F) SPECIFIC GRAVITY 2 26 VAPOR PRESSURE (MM HG) Page 2 VAPOR DENSITY(AIR=1) EVAPORATION RATE N/A 2 90 N/A (H20=l) (BUTYL ACETATE=1) SOLUBILITY (H20) APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME 0 APPEARANCE & ODOR COLORLESS CRYSTALS OR WHITE POWDER WITH NO ODOR FLASH POINT (CLOSED CUP N/A NFPA 704M RATING 0-0-0 OXY ?LAMMABLE LIMITS UPPER - N/A % LOWER - N/A % "IRE EXTINGUISHING MEDIA USE WATER SPRAY SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL JNUSUAL FIRE & EXPLOSION HAZARDS STRONG OXIDIZER CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE file ///mac%20<)' A5%20don/Desktop%20Folder/MSDS/sodiunumtrate txt hursday March 22 2001 • CAN REACT VIOLENTLY WITH SHOCK FRICTION OR HEAT TOXIC GASES PRODUCED __ NITROGEN OXIDES 5 - HEALTH HAZARD DATA BlRI EFFl I :CINOGENICITY NTP NO IARC NO Z LIST NO OSHA REG NO f FECTS OF OVEREXPOSURE INHALATION OF DUST MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION PROLONGED EXPOSURE MAY CAUSE DERMATITIS INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION INHALATION AND INGESTION MAY CAUSE CYANOSIS THE EFFECTS OF EXPOSURE MAY INCLUDE HEADACHE NAUSEA VOMITING DIZZINESS WEAKNESS RAPID INEFFECTIVE I BREATHING LOW BLOOD PRESSURE LOSS OF CONSCIOUSNESS, OR CONVULSIONS liRGET ORGANS NONE IDENTIFIED IDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INHALATION INGESTION SKIN CONTACT EYE CONTACTk! _.J I. II; LGENCY AND FIRST AID PROCEDURES 'CALL A PHYSICIAN IF SWALLOWED IF CONSCIOUS IMMEDIATELY INDUCE VOMITING IF INHALED REMOVE TO FRESH AIR IF NOT BREATHING GIVE ARTIFICIAL .ESPIRATION IF BREATHING IS DIFFICULT GIVE OXYGEN IN CASE OF CONTACT IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT 'LEAST is MINUTES FLUSH SKIN WITH WATER 6 - REACTIVITY DATA STABILITY STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR DITIONS TO AVOID SHOCK FRICTION HEAT COMPATIBLES CYANIDES COMBUSTIBLE MATERIALS STRONG REDUCING AGENTS ALUMINUM ^IMPOSITION PRODUCTS OXIDES OF NITROGEN 7 - SPILL AND DISPOSAL PROCEDURES TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SUITABLE PROTECTIVE CLOTHING KEEP COMBUSTIBLES (WOOD PAPER OIL ETC ) AWAY FROM SPILLED MATERIAL WITH CLEAN SHOVEL CAREFULLY PLACEFTERIAL INTO CLEAN DRY CONTAINER AND COVER REMOVE FROM AREA FLUSH ILL AREA WITH WATER JISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL STATE AND LOCALriRONMENTAL REGULATIONS AZARDOUS WASTE NUMBER DO01 (IGNITABLE WASTE) 8 - PROTECTIVE EQUIPMENT I •ENTILATION USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE I I PIRATORY PROTECTION NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST IF AIRBORNE CONCENTRATION IS HIGH USE AN APPROPRIATE RESPIRATOR OR DUST MASK /SKIN PROTECTION SAFETY GLASSES WITH SIDESHIELDS BUTYL RUBBER GLOVES ARE RECOMMENDED I 9 - STORAGE AND HANDLING PRECAUTIONS -T-DATA(TM) STORAGE COLOR CODE YELLOW (REACTIVE) PECIAL PRECAUTIONS •EBP CONTAINER TIGHTLY CLOSED STORE SEPARATELY AND AWAY FROM FLAMMABLE file ///mac"/ 20 /oA5 /»20don/Desktop /o20Folder/MSDS/sodlum_mtrate Ixt hursday March 22 2001 AND COMBUSTIBLE MATERIALS 10 - TRANSPORTATION DATA AMD ADDITIONAL INFORMATION DOMESTIC (DOT) PROPER SHIPPING NAME SODIUM NITRATE HAZARD CLASS OXIDIZER UN/NA UN1498 LABELS OXIDIZER INTERNATIONAL (I M O ) PROPER SHIPPING NAME SODIUM NITRATE HAZARD CLASS 5 1 UN/NA UN1498 LABELS OXIDIZING AGENT file ///mac"/ 20 /oA5 /o20don/Desktop°/ 20Fold8r/MSDS/sodium_nitrate txt I I I I I I I I I I I I I I I I I I I hursday March 22 2001 MSDS - ZINC OXIDE PRODUCT IDENTIFICATION §DUCT NAME MULA MULA WT NIOSH/RTECS NO MON SYNONYMS DDUCT CODES ZINC OXIDE ZNO 81 37 01314-13-2 ZH4810000 CALAMINE ZINC WHITE FLOWERS OF ZINC 4358 4360 4361 5171 5070 (EFFECTIVE 09/05/86 REVISION #02 •KER I PRECAUTIONARY LABELLING SAF-T-DATA(TM) SYSTEM HEALTH - 2 MODERATE FLAMMABILITY - 0 NONE REACTIVITY - 0 NONE CONTACT - 0 NONE .ZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD 4 = EXTREME HAZARD) LABORATORY PROTECTIVE EQUIPMENT tETY GLASSES LAB COAT CAUTIONARY LABEL STATEMENTS JaiD BREATHING DUST VENTILATION WARNING HARMFUL IF INHALED KEEP IN TIGHTLY CLOSED CONTAINER F-T-DATA(TM) STORAGE COLOR CODE USE WITH ADEQUATE ORANGE (GENERAL STORAGE) I 2 - HAZARDOUS COMPONENTS • COMPONENT % CAS NO SINC OXIDE 90-100 1314-13-2 • 3 - PHYSICAL DATA 30ILING POINT N/A VAPOR PRESSURE (MM HG) N/A •.TING POINT 1975 C ( 3587 F) VAPOR DENSITY(AIR=1) N/A jPECIFIC GRAVITY 5 67 EVAPORATION RATE N/A (H20=l) (BUTYL ACETATE=1) MOBILITY (H20) NEGLIGIBLE (LESS THAN 01%) % VOLATILES BY VOLUME 0 APPEARANCE & ODOR WHITE OR YELLOWISH-WHITE ODORLESS POWDER 14 - FIRE AND EXPLOSION HAZARD DATA 5,SH POINT (CLOSED CUP N/A BLE LIMITS UPPER - N/A % LOWER - N/A % IRE EXTINGUISHING MEDIA JSE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE 5 - HEALTH HAZARD DATA IESHOLD LIMIT VALUE (TLV/TWA) 5 MG/M3 ( RT-TERM EXPOSURE LIMIT (STEL) 10 MG/M3 ( EISSIBLE EXPOSURE LIMIT (PEL) 5 MG/M3 ( CITY LD50 (ORAL-RAT) (MG/KG) - 630 ARCINOGENICITY NTP NO IARC NO Z LIST NO OSHA REG NO IECTS OF OVEREXPOSURE file ///mac/20^A5%20don/Desktop0/20Folder/MSDS/zlnc_oxide txt PPM) PPM) PPM) 'lursday March 22 2001 Page INHALATION OF VAPORS MAY CAUSE SEVERE IRRITATION OF THE RESPIRATORY SYSTEM OVEREXPOSURE TO VAPORS MAY CAUSE IRRITATION OF MUCOUS MEMBRANES DRYNESS OF MOUTH AND THROAT HEADACHE NAUSEA AND DIZZINESS CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION TARGET ORGANS RESPIRATORY SYSTEM MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INHALATION EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN IF INHALED REMOVE TO FRESH AIR IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION IF BREATHING IS DIFFICULT GIVE OXYGEN IN CASE OF CONTACT IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES FLUSH SKIN WITH WATER I 6 - REACTIVITY DATA STABILITY STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOID NONE DOCUMENTED INCOMPATIBLES MAGNESIUM STRONG ACIDS 7 - SPILL AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING WITH CLEAN SHOVEL CAREFULLY PLACE MATERIAL INTO CLEAN DRY CONTAINER AND COVER REMOVE FROM AREA FLUSH SPILL AREA WITH WATER DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL STATE AND LOCAL ENVIRONMENTAL REGULATIONS 8 - PROTECTIVE EQUIPMENT /ENTILATION USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS RESPIRATORY PROTECTION RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV AT CONCENTRATIONS UP TO 75 PPM A HIGH-EFFICIENCY PARTICULATE RESPIRATOR IS RECOMMENDED ABOVE THIS LEVEL A SELF-CONTAINED BREATHING APPARATUS IS ADVISED JYE/SKIN PROTECTION SAFETY GLASSES WITH SIDESHIELDS PROPER GLOVES ARE RECOMMENDED 9 - STORAGE AND HANDLING PRECAUTIONS jAF-T-DATA(TM) STORAGE COLOR CODE ORANGE (GENERAL STORAGE) aPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION 30MESTIC (DOT) 'ROPER SHIPPING NAME ZINC OXIDE IAZARD CLASS ORM-E .ABELS NONE IEPORTABLE QUANTITY 1000 LBS NTERNATIONAL (I M 0 ) 'ROPER SHIPPING NAME CHEMICALS N O S (NON-REGULATED) file///mac? 20%A5/o20don/Desktop/20Folder/MSDS/zmc_oxide txt ^Si I iday March 22 2001 Page 1 [Q Max Header] [Image] MAX MATERIAL SAFETY DATA SHEET iction I IDENTIFICATION OF PRODUCT •oduct Name QUICKLIME (Pebble Crushed Pulverized) Various Calcium Oxide Cas No 1305-78-8 Eye and Skin Irritant Not Applicable Not Applicable Not Applicable Percent 95 1 CAS Number 1305-78-8 [Image]INHALATION LD(50) N/AV LC(50) N/AV [Image] INGESTION Use iemical Family CLASSIFICATION PLACE HAZARD TDG CLASSIFICATIONEKAGE GROUP tion II HAZARDOUS INGREDIENTS gredient Calcium Oxide Action III TOXICOLOGICAL PROPERTIES Boute of [Image] SKIN [Image] EYE CONTACT •ntry SKIN CONTACT Can penetrate the skin slowly producing soft necrotic deeply penetrating areas on contact The • extent of damage depends on duration of contact A chronic dermatitis may follow repeated contact E CONTACT Direct contact with the solid or aqueous solutions may cause conjunctival edema and corneal destruction can lead to and may cause blindnessrProlonged contact may cause conjunctivitis LATION Low concentrations may cause sore throat coughing choking dyspnea and variable symptoms of headache dizziness and weakness Intense exposures may result in tightness in the chest and delayed pulmonary edema _ The solubility of substance allows further penetration • that may continue for several days • Bronchial irritation with chronic cough are common WcESTION Corrosive If ingested consult a Physician immediately 5 mg/m' Lime Respiratory System Nasal Passages Eyes Skin Exposed Cuts or Scrapes 3ESTION osure Limits ritancy of Product Action IV FIRST AID MEASURES SKIN CONTACT e&E BlALA' WGEST: CONTACT .TION 1ESTION :tion V PHYSICAL DATA EARANCE AND ODOUR GRAVITY POINT (,o 1ELTING POINT (,C) LUBILITY IN WATER 1 0% VOLATILE BY VOLUME ORATION RATE /APOUR PRESSURES (mm Hg) DENSITY (Air=l) :tion VI FIRE AND EXPLOSION DATA POINT VUTOIGNITION TEMPERATURE LAMMABLE LIMITSENGUISHING MEDIA IAL FIRE FIGHTING PROCEDURES INUSUAL FIRE AND EXPLOSION 'ROCEDURES §tion VII REACTIVITY DATA ABILITY NCOMPATIBILITY (conditions to ivoid) Flush affected eye immediately with large amounts of water Do not rub eyes if irritated by Lime dust Following eye wash with water use Boric Acid solution then get medical attention Wash thoroughly with soap and warm water then vinegar to remove all Lime Apply burn ointment Keep bandaged during healing to prevent infection Remove to fresh air If not breathing give artificial respiration and call a doctor Give three to four glasses of milk or water Do not induce vomiting Get immediate medical attention Greyish white solid various sizes - Odourless (H20=l) 32-34 2850 C 5162 F Not Applicable Insoluble 12 - Strong Alkaline Not Applicable butylacetate=l) NM/AP 20C (68F) Not Available None Applicable Not Applicable Not Applicable Non flammable use extinguishing media which is appropriate for surrounding fire None None Stable [Image] Unstable [Image] I KARDI •VZAR; lOUS DECOMPOSITION PRODUCTS .ZARDOUS POLYMERIZATION ection VIII PREVENTIVE MEASURE .PECIAL PROTECTION INFORMATION•PIRATORY PROTECTION Boric Oxide Acids Fluorine water steam and many organic materials Calcium Oxide will swell and generate heat when moistened and could burst containers Fluorine will attack Calcium Oxide evolving much heat and some light When exposed to air it will react with moisture and Carbon Dioxide in the air None Will not occur [Image] May Occur [Image] Approved filter mask should be worn if excessive dust is created flle///mac%20%A5%20don/Desktop%20Folder/MSDS/llme lursday March 22 2001 Page VENTILATION Local exhaust as necessary to maintain airborne levels within prescribed limits PROTECTIVE GLOVES Gauntlet type work gloves to prevent material getting inside EYE PROTECTION Tight fitting goggles should be worn CLOTHING Should be worn to prevent Lime from contacting skin OTHER PROTECTIVE EQUIPMENT (specify) Long sleeved shirt with collar buttoned trousers with legs down over boot tops PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid creating dust Keep containers closed to avoid breathing dust and eye contact Keep product dry Store in coo DRY well-ventilated area out of direct contact with weather STEPS TO BE TAKEN IN CASE THE MATERIAL IS SPILLED OR RELEASED Ventilate area of spill Keep spilled material away from Organic Material and Water Carefully pick up solid material and collect in metal containers with covers for disposal WASTE DISPOSAL METHOD Trace amounts of residue can be flushed into the drain using plenty of water Large amounts may require neutralization by Acid Check local regulations Alternately waste lime can be used for neutralizing plant acid wastes Section IX PREPARATION The information contained herein is given in good faith but no warranty expressed or implied is made DATE ISSUED July 1 1995 BY Calgary Division Office DATE UPDATED October 1 1999 [Image] Return to MSDS Menu [Image] Return to Main Menu [Image] site design and construction by Cobra Internet Design 2000 I file ///mac%20 /4A5 /420don/Desktop%20Folder/MSDS/llme [The Hummel Croton Web Page] MATERIAL SAFETY DATA SHEET [The Hummel Croton Homepage * msds] COPPER CARBONATE (BASIC) HUMMEL CROTON INC 10 HARMICH ROAD BUSINESS HRS.. 908-754-1800 SOUTH PLAINFIELD, NJ O7080 EMERGENCY PHONE NUMBERS BUSINESS HRS 908-754-1800 CHEMTREC- 800-424-9300 I PRODUCT IDENTIFICATION: PRODUCT NAME. . Copper Carbonate CHEMICAL FAMILY . .- Copper Compound CHEMICAL NAME Cupric Carbonate Basic SYNONYMS • Copper Carbonate Hydroxide, Cupric Subcarbonate, Bremen Blue, Bremen Green CAS NUMBER CAS #• 12069-69-1 FORMULA . . CH2CU205 II HAZARDOUS INGREDIENTS INGREDIENT NAME Copper Carbonate CAS # 12069-69-1 EXPOSURE LIMITS OSHA • 1 mg/m3 * ACGIH Img/m3 * * as copper CONCENTRATION (%) Essentially 100 % Ill PHYSICAL PROPERTIES PHYSICAL FORM • Amorphous Powder COLOR . Green to Blue ODOR Odorless MOLECULAR WEIGHT ... 221 11 pH • Neutral BOILING POINT Not Applicable MELTING/FREEZING POINT Decomposes above 200oC VISCOSITY Not Applicable SOLUBILITY IN WATER : Insoluble SPECIFIC GRAVITY . 4 00 BULK DENSITY Not Established VAPOR PRESSURE Not Applicable VAPOR DENSITY .. . . - Not Applicable (Air = 1) IV FIRE AND EXPLOSION DATA: FLASH POINT Not Applicable AUTO-IGNITION TEMPERATURE. . . Not Established EXTINGUISHING MEDIA Noncombustible Use extinguishing media appropriate to surrounding fire conditions. SPECIAL FIRE FIGHTING PROCEDURES Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. UNUSUAL FIRE / EXPLOSION HAZARDS' Emits toxic fumes under fire conditions HUMAN HEALTH DATA ROUTE(S) OF ENTRY.. . • Eye Contact; Skin Contact, Inhalation, Ingestion HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE ACUTE INHALATION • Inhalation may irritate the respiratory tract. Symptoms may include coughing, shortness of breath, sore throat and runny nose If sufficient amounts are inhaled and absorbed, symptoms may resemble those in acute ingestion. ACUTE SKIN CONTACT Skin contact may cause irritation with symptoms of redness, swelling, itching and pain. ACUTE EYE CONTACT Eye contact may cause irritation with symptoms of redness, swelling, itching, tearing and pain. ACUTE INGESTION . . Ingestion may cause gastroenteritis (inflammation of the lining membrane of the stomach and intestines) with abdominal pain, nausea, vomiting and diarrhea Systemic effects may follow and may include ringing of the ears, dizziness, elevated blood pressure, blurred vision and tremors. CHRONIC EFFECTS OF EXPOSURE . CARCINOGENICITY This product is not listed by NTP/ IARC or regulated as a carcinogen by OSHA MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE.." Persons with preexisting eye or skin conditions or impaired pulmonary function may be more susceptible to the effects of this product. VI. EMERGENCY AND FIRST AID PROCEDURES' FIRST AID FOR EYES In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. FIRST AID FOR SKIN In case of contact, flush skin with water Wash clothing before reuse. Call a physician if irritation occurs FIRST AID FOR INHALATION If inhaled, remove to fresh air. If not breathing, give artificial respiration if breathing is difficult, give oxygen. Call a physician. FIRST AID FOR INGESTION If swallowed, call a physician immediately. VII EMPLOYEE PROTECTION RECOMMENDATIONS EYE PROTECTION REQUIREMENTS OSafety glasses or goggles. SKIN PROTECTION REQUIREMENTS. PVC gloves with impervious boots, apron or coveralls. Employees should wash their hands and face before eating, drinking or using tobacco products RESPIRATOR REQUIREMENTS Work ambient concentrations should be monitored and if the recommended exposure limit is exceeded, a NIOSH/MSHA approved dust respirator must be worn. VENTILATION REQUIREMENTS Use local ventilation if dusting is a problem, to maintain air levels below the recommended exposure limit. ADDITIONAL PROTECTIVE MEASURES Emergency showers and eye wash stations should be available. Educate and train employees in the safe use and handling of hazardous chemicals. VIII REACTIVITY DATA STABILITY : Stable under ordinary conditions of use and storage. HAZARDOUS POLYMERIZATION. Will not occur INCOMPATIBILITIES : Strong Acids INSTABILITY CONDITIONS Excessive temperatures (see INCOMPATIBILITIES) DECOMPOSITION TEMPERATURE above 200oC DECOMPOSITION PRODUCTS Carbon Monoxide, Carbon Dioxide and Oxides of Copper IX. SPILL AND LEAK PROCEDURES' SPILL OR LEAK PROCEDURES Utilize recommended protective clothing and equipment. Clean spills in a manner that does not disperse dust into the air. Spill area can be washed with water Collect wash water for approved disposal Keep from entering water or ground water WASTE DISPOSAL METHOD Waste disposal should be in accordance with existing federal, state and local environmental regulations. X. SPECIAL PRECAUTIONS & STORAGE DATA STORAGE TEMPERATURE(MIN/MAX) Ambient/Ambient. SHELF LIFE • Unlimited in tightly closed container. SPECIAL SENSITIVITY . None HANDLING/STORAGE PRECAUTIONS. Avoid breathing dust. Avoid getting in eyes or on skin. Wash thoroughly after handling Store in a dry place away from direct sunlight, heat and incompatible materials (see Section VIII). Reseal containers immediately after use. Store away from food and beverages XI SHIPPING INFORMATION Contact Hummel Croton for current shipping Information XII TOXICITY DATA- ACUTE EFFECTS Harmful if swallowed, inhaled, or absorbed through skin Causes severe eye irritation causes skin irritation Material is irritating to mucous membranes and upper respiratory tract. Exposure can cause* coughing/ chest pains, difficulty in breathing Gastrointestinal disturbances nausea, vomiting, diarrhea ADDITIONS!, INFORMATION- Symptoms of systemic copper poisoning may include capillary damage, headache, cold sweat, weak pulse, kidney and liver damage, central nervous system excitation followed by depression, jaundice, convulsions, paralysis and coma Death may occur from shock or renal failure RTECS #• GL6910000 COPPER(II) CARBONATE HYDROXIDE (2 1 2} TOXICITY DATA ORL-RAT LD50-1350 MG/KG SKEZAP 26,605,85 ORL-RBT LD50:159 MG/KG GUCHAZ 6,128,13 ORL-BRD LD50 900 MG/KG PCOC** -,258,66 TARGET ORGAN DATA Behavioral (somnolence), behavioral (coma), gastrointestinal (hypermotility, diarrhea), blood (normocytic anemia), nutritional and gross metabolic (weight loss or decreased weight gain) Only selected registry of toxic effects of chemical substances (RTECS) data is presented here See actual entry in RTECS for complete information XIII REGULATORY INFORMATION OSHA STATUS • This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200 TSCA STATUS On TSCA Inventory CALIFORNIA PROPOSITION 65 To the best of our knowledge, this product contains no levels of listed substances, which the state of California has found to cause cancer, birth defects or other reproductive effects RCRA STATUS ' If discarded in its purchased form, this product would not be hazardous waste either by listing or by characteristic However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. (40 CFR 261.20-24) SARA SECTION 313 . This product is subject to reporting requirements EUROPEAN INFORMATION Toxic R 23/24/25 Toxic By Inhalation, In Contact With Skin And If Swallowed R 36/37/38 Irritating To Eyes, Respiratory System And Skin. R 41 Risk Of Serious Damage To Eyes S 45 In Case Of Accident Or If You Feel Unwell, Seek Medical Advice Immediately (Show The Label Where Possible) S 26 In Case Of Contact With Eyes, Rinse Immediately With Plenty Of "Water And Seek Medical Advice S 36/37/39 Wear Suitable Protective Clothing, Gloves And Eye/Face Protection. XIV. ECOLOGICAL INFORMATION- Data not Available at the present time XV APPROVALS REASON FOR ISSUE. Update to new format PREPARED BY ' Mark Dugan APPROVED BY Mark Dugan APPROVAL DATE : 05/17/96 [bul] WARRANTY [toe] USE "BROWSER" OR SECONDARY MOUSE KEY TO RETURN TO PREVIOUS ENTRY PANEL ' RETURN TO BEGINNING OF WEB PAGE [email] hum chemSaol com [email] : htmmelgearthlink net hursday iClarch 22 2001 •' MSDS - SODIUM SULFATE H 1 - PRODUCT IDENTIFICATION tODUCT NAME SODIUM SULFATE RMULA NA2SO4 RMULA WT 142 04 S NO •7757-82-6 NIOSH/RTECS NO WE1650000 fODUCT CODES 3375 3887 3902 3891 3898 5059 EFFECTIVE 05/02/86 REVISION #01 mKKEl I PRECAUTIONARY LABELLING iR SAF-T-DATA(TM) SYSTEM HEALTH - 0 NONE FLAMMABILITY - 0 NONE REACTIVITY - 0 NONE 1 CONTACT - 1 SLIGHT ZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD 4 = EXTREME HAZARD) LABORATORY PROTECTIVE EQUIPMENT EETY GLASSES LAB COAT CAUTIONARY LABEL STATEMENTS CAUTION • MAY BE HARMFUL IF SWALLOWED• MAY CAUSE IRRITATION BRING USE AVOID CONTACT WITH EYES SKIN CLOTHING WASH THOROUGHLY AFTER HANDLING WHEN NOT IN USE KEEP IN TIGHTLY CLOSED CONTAINER •F-T-DATA(TM) STORAGE COLOR CODE ORANGE (GENERAL STORAGE) 2 - HAZARDOUS COMPONENTSICOMPONENT % CAS NO NOT APPLICABLE 3 - PHYSICAL DATA I .LING POINT N/A VAPOR PRESSURE (MM HG) N/A ,TING POINT 884 C ( 1623 F) VAPOR DENSITY(AIR=1) N/A aPECIFIC GRAVITY 2 68 EVAPORATION RATE N/A §(H2O=1) (BUTYL ACETATE=1) UBILITY(H2O) APPRECIABLE (MORE THAN 10 %) % VOLATILES BY VOLUME 0 APPEARANCE & ODOR ODORLESS WHITE POWDER OR CRYSTALS I4 - FIRE AND EXPLOSION HAZARD DATA iH POINT (CLOSED CUP N/A ILE LIMITS UPPER - N/A % LOWER - N/A % EXTINGUISHING MEDIA 'SE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE : F I I 'IAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED .REATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE .1C GASES PRODUCED IULFUR DIOXIDE 5 - HEALTH HAZARD DATA OXICITY LD50 (ORAL-MOUSE) (MG/KG) - 5989 I1CINOGENICITY NTP NO IARC NO Z LIST NO OSHA REG NO file///mac%20 / A5%20don/Desktopy 20Folder/MSDS/sodium_sulfate txt hursday March 22 2001 Page EFFECTS OF OVEREXPOSURE DUST MAY BE IRRITATING TO EYES NOSE THROAT OR LUNGS CONTACT WITH SKIN OR EYES MAY CAUSE IRRITATION INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION TARGET ORGANS NONE IDENTIFIED MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY NONE INDICATED EMERGENCY AND FIRST AID PROCEDURES INGESTION IF SWALLOWED AND THE PERSON IS CONSCIOUS IMMEDIATELY GIVE LARGE AMOUNTS OF WATER GET MEDICAL ATTENTION INHALATION IF A PERSON BREATHES IN LARGE AMOUNTS MOVE THE EXPOSED PERSON TO FRESH AIR GET MEDICAL ATTENTION EYE CONTACT IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES GET MEDICAL ATTENTION SKIN CONTACT IMMEDIATELY WASH WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES I 6 - REACTIVITY DATA STABILITY STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOID NONE DOCUMENTED INCOMPATIBLES ALUMINUM MAGNESIUM MINERAL ACIDS STRONG ACIDS STRONG BASES DECOMPOSITION PRODUCTS OXIDES OF SULFUR 7 - SPILL AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SUITABLE PROTECTIVE CLOTHING CAREFULLY SWEEP UP AND REMOVE DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL STATE AND LOCAL ENVIRONMENTAL REGULATIONS 8 - PROTECTIVE EQUIPMENT /ENTILATION USE ADEQUATE GENERAL OR LOCAL, EXHAUST VENTILATION TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE RESPIRATORY PROTECTION NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST IF AIRBORNE CONCENTRATION IS HIGH USE AN APPROPRIATE RESPIRATOR OR DUST MASK TE/SKIN PROTECTION SAFETY GLASSES WITH SIDESHIELDS PROPER GLOVES ARE RECOMMENDED 9 - STORAGE AND HANDLING PRECAUTIONS >AF-T-DATA(TM) STORAGE COLOR CODE ORANGE (GENERAL STORAGE) >PECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION 10MESTIC (DOT) ROPER SHIPPING NAME CHEMICALS N 0 S (NON-REGULATED) NTERNATIONAL (I M 0 ) ROPER SHIPPING NAME CHEMICALS N 0 S (NON-REGULATED) file ///mac0/ 20°/ A5V 20don/Desktop / 20Folder/MSDS/sodmm_sulfate txt COooo CD 8 9 0332 8 o 03 33 7; to05 DO X X\ V. \f s ,N \ \' f H Z Q P 03 ////// mx O O OCEANSIDEGLASSTILE-2293 COSMOS CT FURNACE CONSTRUCTION l\3 rr c D T CD co CD 3-N CD T3CD y///////////////////////^^ CJl co CD O — * cn CO ^r C35O) CDicn _JL ro Tl cB CD C CD 3o - to"3 0 o0 o N American Fire-Allcrc B CD—tCO J^-fxrocn cn CO s o oCD CO cn Q CO cB COc_ i-fo 0 (U £2 CD CO D™t 5 P fv•r1" O5 IV1i \j rb 00 two burner ProtectlfeCOo CO CDo *-*• 3 S"|^ CD ~^ ^UDC controller (prog3 1 CD 4^. rbo ^^> 0 S.oc« ^ cn S= CO 5 0 Q. 'sQ. Z3- 2. Ol 1 5" manual solmoid— 1.roo o T—1 1 CO ^ _JL cn cp 0 CDw CO cB0cao—t COoo> NQ CO modutrol motorN>Low air pressure swilo 13«— i-C 13 CDCO c_oiro 3o — *•O)COrv> •— L 5 I CO T3 CDCOCO C CD CO o" " Zii— i- Crs CDCO IJJ Ir~Q-g •3 O _L CJ5COCO •^ 0) CQ JU CD OCEANSIDEGLASSTILE-2293 COSMOS CT FURNACE INSTALATION DETAIL -* oo 3 ffl Q l\3O 5 CO I O 4'-4" 3 ffl TJ roo 5 5 CO 00 11 1/8" 3 ffl OCEANSIDEGLASSTILE-2293 COSMOS CT FRJNACE HOOD ELEVATIONW/VENT DETAIL CO a R OCEANSIDEGLASSTILE IRDIZER FLUE + BURNER DETAIL CD13 Q. CDX 05 CO oT3< CD W Q. CD < CD OCEANSIDEGLASSTILE-2293 COSMOS CT IRDIZER INSTALLATION enCJ CDCO 2 nin -Q O o3O CO m SCO S3 ft m cz oz oc: Zo CO 1 ' • | m P ^ H Os: m toIT- W §»3 • • *•| FURNISHE0 O3 3 0o 0 sm ~* ^8 — i •j ENCLOSUS _3 w o § *"* tn to COo -oa: o o oso WN •HKW I' 1^ COt-3 I-o 3D Z {J cno —, ^^0 o o -H ^^^»^» § m 3 o </l BEARING RAKK1 «M.1 ARRANGEMENTto t-< 1 ro E • ••j ROTATION Ci3 DISCHARGE Uw "H O —1 i i i i IIP «j r> irj ^ § oCM o n CD ° 3= C~5 N3 ^ j^ O -^ to — o g z § » m "~* ^ -^- ^ >• ^ S "3 K *— t S CM r— *-Z = O — >O -^ ^ O — *mil p en fr C? *" ^ — k rrim 3* -L, =o 3 " i— • o 5 —<z o i — s:3> m^o > CO O-n CONSTRUC-—i O SPARE PARTSi j VIBRATION ISO22.XS.1 CO 0_>_ jO 3W •*3 "»S1Ulen ^ ^ CO=5 O m 0^'{ £| GRAVITY DAMPm33 O LIFTING LUGS (.CM 2;o | INLET DAMPERZo INLET FLANGEO a-oomCOCO oo O SCROLL DRAIN•"". o P ^q *| FLEX COLLAR2 S SCREENS (PVC* — * 2O | 1COO pr( W SHAFT SEAL2 WO » §w CD O i> !ulu|u|u|u[u|u 38 . 15 TUNNEL HT 2535 96 B&.T j— 96 BELT c 15 Of OCEANSIDEGLASSTILE-2293 COSMOS CT Bowman Anneallmg Kiln to be installed by manufactuer i i i i i Quality... Efficiency... Economy... Reliability... Service... for over 40 years. E W Bowman,Inc PO Box849 Umontown,PA USA 15401 Phone 412-438-0503 Fax 412-439-5880 EXAMPLE: Bowman Electric Lehr at Ball Corporation Ball Corporation Installed this new Bowman Electric Lehr In 1963, benefited from significant energy reductions and, subsequently, ordered more Bowman Lehrs Belt Width Tunnel Overall Length Bated Capacity 96" 80'0" 120'0" 118 TPD Performance/Energy Data: Ware Type Gob Weight Production Speed Tonnage Average Power Consumption Energy Cost* (Per Ton) Energy Cost (Per Day) 'Based on Eastern Metropolitan Utility Rate of 6 Vi */kwh. 28 oz soda 17% oz 122 BPM 94 TPD 2 04 kwh/ton 11 2*/ton $10 83/day Productf QOZ flask 9%oz 171 BPM 72 TPD 2 33 kwh/ton 12 8Vton $9 22/day IIIIII I I II I I I I I I I I I I I I I I I I I I I E. W. BOWMAN, INCORPORATED PO BOX 849, UNIONTOWN, PA 15401 PHONE 724-438-0503 FAX 724-439-5880 lass producers constantly face the challenge of finding technologies that reduce fuel consump- tion, improve product quality and increase pro- "duction rates while maintaining precise temperature control on annealing and decorat- ing lehrs In an attempt to address the needs of annealed glass man- ufacturers, E W Bowman, Inc and Hauck Manufacturing Co pined forces in 1992 to develop a new lehr combustion system The goals of the project were to reduce fuel consump- tion, improve product quality and allow flexible temperature control The result of the development was a packaged gas burner* designed to provide proportionate and automatic control in a heating or cooling mode in response to the tem- perature curve for a specific glass or ceramic product The Annealing Process To understand the impact of a heat/cool combustion system on an annealing lehr, it is helpful to review the annealing process. The annealing process minimizes internal stresses in glass, allowing commercially useful glass to be produced. Typically, two temperature control zones are necessary to accomplish this. First, as ware enters the charge zone of the lehr, it is heated to a temperature slightly above its annealing point In the second zone, the ware is cooled to the strain point For container or tableware annealing, five to eight temper- ature control zones are typical In the subsequent zones, the set point temperature is slowly ramped down (cooled) to the strain point, and the ware travels through the final, more rapid cooling zones and exits the lehr. Although this may seem simple, temperature control in the range from the annealing point to the strain point is critical Without proper temperature control, exiting ware is at risk of Ming industry standard testing for acceptable annealing. In general, the annealing temperature for most soda lime glass is about 1020°F, and the strain point is 970°F In the first zone of the lehr, the ware temperature must be uniform. If heating is not uniform, stress remains, and breakage is possi- ble as the ware cools in the lehr ControEed cooling on lehrs is also important since the inn*a1'ng transformation occurs in a 50°F temperature range. If the ware has been properly heated to die annealing tem- perature and slowly cooled to the strain point, it should be acceptably annealed. Once the ware is below the strain point, annealing ts complete. Changes in the cooling rate beyond this point, provided die entire ware is subject to the same cooling rate, wffl not affect anneal quality Dedicated cooling commences from this stage. Cool air drawn into the lehr mixes with warm lehr air Cooling must occur at a proper rate to avoid surface contraction on the MheEWB 66, which Haw* mnuto*raecbsl«frferE.W Bowman he. ware and subsequent breakage With poor heating or cooling uniformity, a temperature gradient exists in the glass, and temporary stress results Controlled Thermal Environment Applying heat/cool combustion with the packaged gas burner offers a solution to the demands of the annealing process The burner supplies a controlled thermal environment in each of the lehr's zones Control over heating or cooling output from the burner is proportional throughout its operation In other words, if the zone temperature remains below the set point, the controller will ignite the burner and modulate the burner accordingly to achieve set point (heating mode) If, on the other hand, the process variable is above the set point, the burner operates in the "off" or "cooling" mode. The "off" or "cooling" mode introduces combustion air through the burner into the lehr interior, modulating the butterfly valve, to maintain the curve and process requirements. Each zone in a lehr operates with two burner units. The actual temperature control, however, depends on the lehr design. If a narrow lehr with a single reorculation fan per zone is used, then both burners act in concert from the temperature controller output On a wide lehr (typically 12* to 18') with two reorculaung fens per zone, each burner operates autonomously (see Figure 1) In wide lehr applications, temperature uniformity is maintained by each burner compensating for temperature variations across the charge of ware. For example, in charging a 16-foot wide lehr, the first piece of ware in the row across the front of the lehr has more time to cool before it enters the lehr Conversely, the last piece to enter the charge table, in the same row, will be warmer The advantage of allowing individual temperature control is obvious With a uniform temperature across the load, less tem- perature gradient exists, and proper annealing results Process Flexibility Additional process flexibility results from the capability to use a heat/cool combustion system. This flexibility allows the lehr to combat variations in charge temperatures. For example, on the heating extreme, if the ware is too cool when it enters the lehr, the burners in the first zone can fire at capacity to achieve the set point On the other extreme, cooling control of the combustion sys- tem allows compensation for ware that is too hot upon entering the first zone. For example, heavier ware may tend to have a higher temperature as it enters the lehr The cooling mode of the combustion system shuts the burner off, and air-only operation cook the ware to the annealing temperature. Most systems are designed around a ware entrance tem- perature of 950°F If variations in the entrance temperature exist, the lehr provides automatic ware entry temperature * compensation. Other applications may have ware that is hot enough to sustain its own »ntu^lmg temperature through the lehr. With heat/cool combustion, controlled cooling occurs LEHRS • FURNACES • MACHINERY • SUPPLIES FOR THE GLASS INDUSTRIES Reprinted from Ceramic Industry magazine/ February 1999 rather than merely shutting down the burner and hoping for the correct temperature to result Additionally, maintaining a slight posi- tive pressure in the lehr prevents cold air infil- tration, further improving temperature uniformity Appropriate sizing of the burner to the zone allows back-up operation in case of a burner failure For example, if one burner in a zone shuts down, the partner burner in the zone has sufficient capacity to fire by itself until the other burner is corrected Further- more, the burner operates on lehrs with either updraft or downdraft air flow Figure 1 Cross section of a typical updraft annealing lehr Note the dual recirculation fans in the zone Decorating The decorating process offers different application condi- tions Although heat/cool combustion is not as common on decorating lehrs as on annealing, it is useful. Since most deco- rating lehrs are charged with ambient temperature ware, uni- form heating and subsequent zone temperature control are critical for proper bonding of dec- orations to ware Heat/cool con- trol and wide burner turndown can help reduce decal and label blistering and pin holing from incorrect heat up rates. In some decorating applica- tions, dust can cause pin holing and other defects. To prevent this problem, an inlet filter was devel- oped for the burner to eliminate dust infiltration into the lehr Improved Annealing The heat/cool system averts many potential annealing and decorating problems with the capability to add heat or inject cool air into the lehr Many glass manufacturers en;oy improved annealing with heat/cool combustion. Others have un- proved fuel efficiency and increased production rates from the combination of lehr design and heat/cool control © EWB-56 bunwrs en two zones of a amteaCoe lehr. I I I I I I I I I I I Photo courtesy of E.W. Bowman, Inc. 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CERTIFICATE OF LIABILITY INSURANCE PRODUCER AEG Insurance Services, Inc PO Box281900 San Francisco, CA 94128-1900 Came Crozat (877) AEG-4407 x1 57 INSURED Mullen Construction c/o American Employers Group PO Box 281 900 Sfln' Fran/"'SCO CrA Q^.'lT'R-'IQnn r-n^i-rt I-XCQ DATE (MWDD/YY) 1/8/01 THIS CERTIFICATE IS ISSUED AS A MATTER OF INFORMATION ONLY AND CONFERS NO RIGHTS UPON THE CERTIFICATE HOLDER THIS CERTIFICATE DOES NOT AMEND, EXTEND OR ALTER THE COVERAGE AFFORDED BY THE POLICIES BELOW INSURERS AFFORDING COVERAGE INSURER A Virginia Si iraty Company INSURER B • INSURER C INSURER D INSURER E COVERAGES THE POLICIES OF INSURANCE LISTED BELOW HAVE BEEN ISSUED TO THE INSURED NAMED ABOVE FOR THE POLICY PERIOD INDICATED NOTWITHSTANDING ANY REQUIREMENT TERM OR CONDITION OF ANY CONTRACT OR OTHER DOCUMENT WITH RESPECT TO WHICH THIS CERTIFICATE MAY BE ISSUED OR MAY PERTAIN, THE INSURANCE AFFORDED BY THE POLICIES DESCRIBED HEREIN IS SUBJECT TO ALL THE TERMS EXCLUSIONS AND CONDITIONS OF SUCH POLICIES AGGREGATE LIMITS SHOWN MAY HAVE BEEN REDUCED BY PAID CLAIMS INSRLTR A TYPE OF INSURANCE GENERAL LIABILITY COMMERCIAL GENERAL LIABILITY | CLAIMS MADE [ | OCCUR GEN L AGGREGATE LIMIT APPLIES PER H POLICY PI J^T HLOC AUTOMOBILE LIABILITY ANY AUTO ALL OWNED AUTOS SCHEDULED AUTOS HIRED AUTOS NON-OWNED AUTOS GARAGE LIABILITY ANY AUTO EXCESS LIABILITY | OCCUR \_ | CLAIMS MADE DEDUCTIBLE RETENTION $ WORKERS COMPENSATION AND EMPLOYERS LIABILITY OTHER POLICY NUMBER 05-00005420 POLICY EFFECTIVEDATE (MM/DD/YY) 1/1/01 POLICY EXPIRATIONDATE (MM/DD/YY) 1/1/02 LIMITS EACH OCCURRENCE FIRE DAMAGE (Any one fire) MED EXP (Any one person) PERSONAL & ADV INJURY GENERAL AGGREGATE PRODUCTS COMP/OPAGG COMBINED SINGLE LIMIT (Ea accident) BODILY INJURY (Per person) BODILY INJURY (Per accident) PROPERTY DAMAGE (Per accident) AUTO ONLY EA ACCIDENT DTHFP THAN EA ACC AUTO ONLY AGQ EACH OCCURRENCE AGGREGATE vJ WC STATU OTHXI TORY LIMITS ER E L EACH ACCIDENT E L DISEASE EA EMPLOYEE E L DISEASE POLICY LIMIT $ $ $ $ $ $ $ $ $ $ $ $ $ $ $ $ $ $ i 1 .000,000 s 1 ,000,000 i 1 000 000 Coverage is provided for all classifications and codes approved for the policy including the Alternate Employees Endorsement Mullen Construction, 2890 Pio Pico Drive, Carlsbad, CA 92018-0000 ** License # 421785 CERTIFICATE HOLDER ADDITIONAL INSURED INSURER LETTER CANCELLATION Contractors State License Board PO Box 26000 Sacramento, CA 95826-0000 SHOULD ANY OF THE ABOVE DESCRIBED POLICIES BE CANCELLED BEFORE THE EXPIRATION DATE THEREOF THE ISSUING INSURER WILL ENDEAVOR TO MAIL 30 DAYS WRITTEN NOTICE TO THE CERTIFICATE HOLDER NAMED TO THE LEFT BUT FAILURE TO DO SO SHALL IMPOSE NO OBLIGATION OR LIABILITY OF ANY KIND UPON THE INSURER ITS AGENTS OR REPRESENTATIVES AUTHORIZED REPRESENTATIVE ^'""""'Z''''' -— <s^^..*^&£S^Z»~' "- 0715118 ACORD 25-S (7/97) ^•is^f~ '^ACORD CORPORATION 1988 &, 3 -\ s< I3 r* 0 -« 31 0>5 r -N»s_ R k sSilu^vr^\ 5 Hrs\ 0>» N "~ —K O CD "o o co m "or- m -n O Z Cb [" OT o> 03 Q X I 33 : mm X TJ m = O TJ m ~ i m 33 33O m 3j H < !^ m fr ld O oo S ~ZL *cn 5om m V> Ocn o O Hm 3 m m MQO i W ogS m =o Qm°> 2 m