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Home My WebLink About2732 LOKER AV WEST; ; CB044550; Permit02-04-2005 City of Carlsbad 1635 Faraday Av Carlsbad, CA 92008 Commercial/Industrial Permit Permit No: CB044550 Building Inspection Request Line (760) 602-2725 Job Address: Permit Type: Parcel No: Valuation: Occupancy Group: Project Title: 2732 LOKER AV WEST CBAD Tl Sub Type: 2090812900 Lot #: $78,895.00 Construction Type: Reference #: HISAMITSU PHARM-2545 SF OFFICE MANUFACT TO OFFICE MANUFACT INDUST 0 VN Applicant: SHIMIZU AMERICA CORP STE800 800 WILSHIRE BLVD 90017 213 362-7500 Status: Applied: Entered By: Plan Approved: Issued: Inspect Area: Plan Check*: ISSUED 12/20/2004 RMA 02/03/2005 02/04/2005 Building Permit Add'l Building Permit Fee Plan Check Add'l Plan Check Fee Plan Check Discount Strong Motion Fee Park Fee LFM Fee Bridge Fee BTD #2 Fee BTD #3 Fee Renewal Fee Add'l Renewal Fee Other Building Fee Pot. Water Con. Fee Meter Size Add'l Pot. Water Con. Fee Reel. Water Con. Fee $465.71 Meter Size $0.00 Addl Reel. Water Con. Fee $302.71 Meter Fee $0.00 SDCWA Fee $0.00 CFD Payoff Fee $16.57 PFF $0.00 PFF (CFD Fund) $0.00 License Tax $0.00 License Tax {CFD Fund) $0.00 Traffic Impact Fee $0.00 Traffic Impact (CFD Fund) $0,00 PLUMBING TOTAL $0.00 ELECTRICAL TOTAL $0.00 MECHANICAL TOTAL $0.00 Master Drairrage^fee Sewer Fee $0.00 Redev Parking Fee $0.00 Additional Fees TOTAL PERMIT F€£S $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $0.00 $55.00 $160.00 $46.00 $0.00 $0.00 $0.00 $0.00 $1,045.99 Total Fees:$1,045.99 Total Payments To Date:$302.71 Balance Due:$743.28 BUILDING PLANS IN STORAGE ATTACHED 1132 02/04/05 0002 01 02 CGR 743-28 Inspector: FINAL APPROVAL Date:Clearance: NOTICE: Please take NOTICE that approval of your project includes the Imposition" of fees, dedications, reservations, or other exactions hereafter collectively referred to as lees/exactions." You have 90 days from the date this permit was issued to protest imposition of these fees/exactions. If you protest them, you must follow the protest procedures set forth in Government Code Section 66020(a), and file the protest and any other required information with the City Manager for processing in accordance with Carlsbad Municipal Code Section 3.32.030. Failure to timely follow that procedure will bar any subsequent legal action to attack, review, set aside, void, or annul their imposition. You are hereby FURTHER NOTIFIED that your right to protest the specified fees/exactions DOES NOT APPLY to water and sewer connection fees and capacity changes, nor planning, zoning, grading or other similar application processing or service fees in connection with this project. NOR DOES IT APPLY to any fees/exactions of which vou have previously been ojven a NOTICE similar to this, or as to which the statute of limitations has previously otherwise expired. PERMIT APPLICATION CITY OF CARLSBAD BUILDING DEPARTMENT 1635 Faraday Ave., Carlsbad CA 92008 FOR OFFICE USE O PLAN CHECK NO. EST. VAL. ""7 Plan Ck. Deposit Validated By Date 02,71 Address (include Bldg/Suite #)Business Name (at this address) Name Address x State/Zip Telephone # Name Address State/Zip Telephone # 302-71 Fax* (Sec. 7031.5 Business and Professions Code: Any Ctty or County which requires a permit to construct, alter, improve, demolish or repair any structure, prior to Its Issuance, also requires the applicant for such permit to file a signed statement that he Is licensed pursuant to the provisions of the Contractor's License Law [Chapter 9, commending with Section 7000 of Division 3 of the Business and Professions Code] or that he Is exempt therefrom, and the basis for the alleged exemption. Any violation of Section 7031.5 by any applicant for a permit subjects the applicant to a civil penalty of not more than five hundred dollars E$500]). Address License Class Ctty Designer Name State License # C-"2#j7/ Address City State/Zip City Business License # CA State/Zi Telephone # Workers'Compensation Declaration: I hereby affirm under penalty of perjury one of the following declarations: D I have and will maintain a certificate of consent to self-Insure for workers' compensation as provided by Section 3700 of the Labor Code, for the performance of the work for which this permit is issued. D I have and will maintain worker's compensation, as required by Section 3700 of the labor Code, for the performance of the work for which this permit is issued. My worker's compensation Insurance carrier and policy number are: f't)5j£\A3 'P^lr-* *^n Insurance Company Af>j ^\Sfc- SERy IC£S \t\fL- Policy No. I ^H^ft^So Expiration Date_ (THIS SECTION NEED NOT BE COMPLETED IF THE PERMIT IS FOR ONE HUNDRED DOLLARS [$100] OR LESS) D CERTIFICATE OF EXEMPTION: I certify that In the performance of the work for which this permit is issued, I shaH not employ any person in any manner so as to » become subject to the Workers' Compensation Laws of California. WARNING: FaJhira to MCUI* worittnV compensation covmga ta untawful, and slwH wbjeet an «mploy*r to criminal penittlM and clvl UTIM up to on* hundred thousand doltara($100,000), In addition to lhijjijal<if|iiBii|»«iiitllniii damao** in provided far hi Section 3706 of the Labor Code, Interest and attorn*/* SIGNATURE .^V^^ i ?T^,r^ DATE I hereby affirm that I am exempt from the Contractor's License Law for the following reason: D I, as owner of the property or my employees with wages as their sole compensation, will d the work and the structure Is not intended or offered for sale (Sec. 7044, Business and Professions Code: The Contractor's License Law does not apply to an owner of property who builds or Improves thereon, and who does such work himself or through his own employees, provided that such improvements are not intended or offered for sale. If, however, the building or improvement is sold within one year of completion, the owner-builder will have the burden of proving that he did not buld or Improve for the purpose of sale). n I, as owner of the property, am exclusively contracting with licensed contractors to construct the project (Sec. 7044, Business and Professions Code: The Contractor's License Law does not apply to an owner of property who buNds or improves thereon, and contracts for such projects with contractors) licensed pursuant to the Contractor's License Law). D I am exempt under Section _ Business and Professions Code forthis reason: 1. I personally plan to provide the major labor and materials for constrtKaton of the proposed property improvement. D YES D NO 2. I (have/have not) signed an application for a bulding permit for the proposed work. 4. I plan to provide portions of the work, but I have hired the following person to coordinate, supervise and provide the major work (Include name / address / phone number / /ontractors license number): _ 5. I wiN provide some of the work, but I have contracted (hired) the following persons to provide the work Indicated (Include name / address / phone number / type of work): PROPERTY OWNER SIGNATURE.DATE. WHITE: File YELLOW: Applicant PINK: Finance PERMIT APPLICATION CITY OF CARLSBAD BUILDING DEPARTMENT 1635 Faraday Ave., Carlsbad CA 92008 Page 2 of 2 Is the applicant or future building occupant required to submit a business plan, acutely hazardous materials registration for or risk management and prevention program under Sections25505,25533or25534ofthePresley-TannerHazardousSub8tanceAccouWAct? DYES H NO / Is the applicant or future building occupant required to obtain a permit from the air pollution control district or air quality management district? P YES Or NO Is the facility to be constructed within 1,000 feet of the outer boundary of a school site? D YES HNO IF ANY OF THE ANSWERS ARE YES, A FINAL CERTIFICATE OF OCCUPANCY MAY NOT BE ISSUED UNLESS THE APPLICANT HAS MET OR IS MEETING THE REQUIREMENTS OF THE OFFICE OF EMERGENCY SERVICES AND THE AIR POLLUTION CONTROL DISTRICT. I hereby affirm that there is a construction lending agency for the performance of the work for which this permit is Issued (Sec. 3097(1) Civil Code). LENDER'S NAME * LENDER'S ADDRESS. I certify that I have read the application and state that the above information is correct and that the information on the plans is accurate. I agree to comply with all City ordinances and State laws relating to building construction. I hereby authorize representatives of the City of Carlsbad to enter upon the above mentioned property for inspection purposes. 1 ALSO AGREE TO SAVE, INDEMNIFY AND KEEP HARMLESS THE CITY OF CARLSBAD AGAINST ALL LIABILITIES, JUDGEMENTS, COSTS AND OSHA: An OSHA permit is required for excavations of 5'CT deep and demolition or construction of stiuctures over 3 stories In height EXPIRATION: n 106.4.4 Uniform Byjidjng Code) APPLICANT'S SIGNATURE WHITE: File YELLOW: Applicant PINK: Finance CitytfCirisftii Final Building Inspection Dept: Building Engineering Planning CMWD Plan Check #: Permit*: CB044550 Project Name: HISAMITSU PHARM-2545 SF OFFICE MANUFACT TO OFFICE MANUFACT Address: 2732 LOKER AV WEST Contact Person: MIKE Phone: 9492897784 Sewer Dlst: CA Water Dist: CA Inspected /V? Date / 1 Bv: (3M^ Inspected: unftlt Inspected Date By: Inspected: Inspected Date By: Inspected: Comments: StLite FJfc Date: 06/30/2005 Permit Type: Tl Sub Type: INDUST Lot: 0 « (/>} Approved: ^ Disapproved: Approved: Disapproved: Approved: Disapproved: City of Carlsbad Bldg Inspection Request For: 07/15/2005 Permit* CB044550 Title: HIS AM ITS U P HARM-2545 SF OFFICE Description: MANUFACT TO OFFICE MANUFACT Inspector Assignment: TP 2732 LOKERAVWEST Lot 0 Type: Tl Job Address: Suite: Location: APPLICANT SHIMIZU AMERICA CORP Owner: Remarks: am please Sub Type: INDUST Phone: 9492897784 Inspector: Total Time: CD Description 19 Final Structural 29 Final Plumbing 39 Final Electrical 49 Final Mechanical Requested By: MIKE Entered By: CHRISTINE Act Comment Associated PCRs/CVs PCR02235 ISSUED HITSAMITSU/OCCUP.CHANGE,DELETE; CONTAINMENT PIT & DOOR 501 PCR02236 ABANDOND HIS; PCR02248 ISSUED HISAMITSU; CHANGE PLUMBING MATERIAL FROM POLY PRO TO PVC Inspection History Date Description Act Insp 06/30/2005 89 Final Combo CO TP 05/25/2005 13 Shear Panels/HD's WC TP 05/25/2005 14 Frame/Steel/Bolting/Welding PA TP 05/25/2005 34 Rough Electric AP TP 05/13/2005 84 Rough Combo NR PY 04/27/2005 24 Rough/Topout AP TP 04/25/2005 14 Frame/Steel/Bolting/Welding AP TP 04/25/2005 17 Interior Lath/Drywall AP TP 04/21/2005 14 Frame/Steel/Bolting/Welding AP TP 04/21/2005 34 Rough Electric AP TP 03/31/2005 11 Ftg/Foundation/Piers WC TP 03/31/2005 12 Steel/Bond Beam AP TP 03/23/2005 63 Walls WC TP 03/23/2005 66 Grout AP TP Comments T CEIL IN NEW AREA RE LOG CEIL LITES ADD F.S. @ 202 1 HR TUNNEL N/INCL 1 HR TUNNEL VAULT DECK CMU FINAL LIFT (SEE CARD) City of Carlsbad Bldg Inspection Request For: 07/15/2005 Permit* CB044550 Inspector Assignment: TP 03/22/2005 63 Walls NR TP 03/21/2005 66 Grout AP TP 1ST LIFT 03/11/2005 12 Steel/Bond Beam AP TP VAULT SUB 03/11/2005 21 Underground/Under Floor AP TP SINKS City of Carlsbad Bldg Inspection Request For: 06/30/2005 Permit* CB044550 Title: HISAMITSU PHARM-2545 SF OFFICE Description: MANUFACT TO OFFICE MANUFACT Inspector Assignment: TP 2732 LOKERAVWEST Lot 0 Type:TI Sub Type: INDUS! Job Address: Suite: Location: APPLICANT SHIMIZU AMERICA CORP Owner: Remarks: EARLY AM PLEASE Phone: 9492897784 Inspector: Total Time: CD Description 19 Final Structural 29 Final Plumbing 39 Final Electrical 49 Final Mechanical Requested By: MIKE Entered By: CHRISTINE Act Comment C*. Associated PCRs/CVs PCR02235 ISSUED HITSAMJTSU/OCCUP.CHANGE.DELETE; CONTAINMENT PIT & DOOR 501 PCR02236 ABANDOND HIS; PCR02248 ISSUED HISAMITSU; CHANGE PLUMBING MATERIAL FROM POLY PRO TO PVC Inspection History Comments T CEIL IN NEW AREA RE LOG CEIL LITES ADD F.S. © 202 1 HR TUNNEL N/INCL 1 HR TUNNEL VAULT DECK CMU FINAL LIFT (SEE CARD) Date 05/25/2005 05/25/2005 05/25/2005 05/13/2005 04/27/2005 04/25/2005 04/25/2005 04/21/2005 04/21/2005 03/31/2005 03/31/2005 03/23/2005 03/23/2005 03/22/2005 Description 13 14 34 84 24 14 17 14 34 11 12 63 66 63 Shear Panels/HD's Frame/Steel/Bolting/Welding Rough Electric Rough Combo Rough/Topout Frame/Steel/Bolting/Welding Interior Lath/Drywall Fram e/Steel/Boiting/Weld ing Rough Electric Ftg/Foundation/piers Steel/Bond Beam Walls Grout Wails Act we PA AP NR AP AP AP AP AP we AP we AP NR lns| TP TP TP PY TP TP TP TP TP TP TP TP TP TP CITY OF CARLSBAD BUILDING DEPARTMENT DATE NOTICE LOCATION. PERMIT NO. (760) 602-2700 1635 FARADAY AVENUE TIME. - **?; ,. FOR INSPECTION CALL (760) 602-2725. RE-INSPECTION FEE DUE? FOR FURTHER INFORMATION, CONTACT YES PHONE BUILDING INSPECTOR CODE ENFORCEMENT OFFICER 03/10/2005 12J14 FAX B001 Technical Field Services, lac* X */,'/ A Th<L I C- 03/10/2003 FAI CHW8TWHK* * MNMOW ftEWFORCED COWCftete SPECIAL INSPECTOR ms individual nam*a hsrwn is CWTISBD fn ws cawgory shown, Expiration date: August wt, ND. 5M5S6S-M Chr»toph*r A Plnnow a«» MwiwUonBt Bufldine Coda The JndMdww n«n«j iw«on is OKTiReo M aw category snown,haviflfl »*en so earthed oureuantfts^ccestf ui mmpittfcm of the Explrsrion date: Jiay 1^ NO. 9O4IH944 Not ff.'C etrrlflcation JEWSti to corapwmi fcnoH-wfec o/raAj antf stamtvot, •me indivtauai named ntreon ts CERTIRED m me categoryshown, r?*vmgtwn roc*rtrfi*d pumont to succassfui expiration daie; Morcti 19 Me The »**«««, ^ * 03/10/2003 12:15 FAX a 00 2 f^^*f(£:iiiv^^g^^nt • '-"CJT '''•"TV i ' irj^':j;:','C'v> ''''•'''';'ti;''^'-. ^|^^^|5^tp4^^^@^^f;^ |L_., 'QcgNse NUMBER" iiPE - 1103^ L 04/30/06 5tTATt OC HAWAC OePAflTMEN* 6^ COMMERCE ANB OON3UMBK-PROFESSIONAL CHRISTOPHER A ?I1199 TAMARACK AVCARLSBAD CA 92003 EsGil Corporation In Qartnersfiip -with government for Quitting Safety DATE: 2/1/O5 Q AEPJJCANT JURIS, JURISDICTION: City of Carlsbad a PLAN REVIEWERa FILE PLAN CHECK NO.: 04-4550 SET: II PROJECT ADDRESS: 2732 Loker Avenue West PROJECT NAME: Hisamitsu Pharmaceutical - TI The plans transmittedJterewith have been corrected where necessary and substantially comply with the jurisdiction's gilding codes. The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff. The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corseted and resubmitted for a complete recheck. The check list transmitted herewith is for your information. The plans are being held at Esgil Corporation until corrected plans are submitted for recheck. The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person. The applicant's copy of the check list has been sent to: Esgil Corporation staff did not advise the applicant that the plan check has been completed. Esgil Corporation staff did advise the applicant that the plan check has been completed. Person contacted: Telephone #: Date contacted: (by: ) Fax #: Mail Telephone Fax In Person REMARKS: By: Doug Moody Enclosures: Esgil Corporation D GA D MB D EJ D PC 1/24/05 tmsmti.dot 9320 Chesapeake Drive, Suite 208 + San Diego, California 92123 * (858)560-1468 4 Fax (858) 560-1576 EsGil Corporation In Partnership witH government for Quitting Safety DATE: 1/4/05 a AEHJCANT JURISDICTION: City of Carlsbad Q PLAN REVIEWER Q FILE PLAN CHECK NO.: 04-4550 SET: I PROJECT ADDRESS: 2732 Loker Avenue West PROJECT NAME: Hisamitsu Pharmaceutical - TI The plans transmitted herewith have been corrected where necessary and substantially comply with the jurisdiction's building codes. The plans transmitted herewith will substantially comply with the jurisdiction's building codes when minor deficiencies identified below are resolved and checked by building department staff. The plans transmitted herewith have significant deficiencies identified on the enclosed check list and should be corrected and resubmitted for a complete recheck. The check list transmitted herewith is for your information. The plans are being held at Esgil Corporation until corrected plans are submitted for recheck. The applicant's copy of the check list is enclosed for the jurisdiction to forward to the applicant contact person. The applicant's copy of the check list has been sent to: Shimizu America Corp. / Mark Matsumoto 800 Wilshire Blvd Suite 800, Los Angeles, CA 90017 Esgil Corporation staff did not advise the applicant that the plan check has been completed. X] Esgil Corporation staff did advise the applicant that the plan check has been completed. Person contacted: Mark Matsumoto Telephone #: 213-362-7500 Date contacted: f f *-f/o5 (by: ^ ) Fax #: 213-362-7511 Mail*—"telephone-^ Fax ~xin Person REMARKS: By: Doug Moody Enclosures: Esgil Corporation D GA D MB D EJ D PC 12/21/04 tmsmtl.dot 9320 Chesapeake Drive, Suite 208 4 San Diego, California 92123 4- (858)560-1468 + Fax (858) 560-1576 City of Carlsbad 04-4S50 1/4/05 PLAN REVIEW CORRECTION LIST TENANT IMPROVEMENTS PLAN CHECK NO.: 04-4550 OCCUPANCY: B/F1 TYPE OF CONSTRUCTION: VN ALLOWABLE FLOOR AREA: SPRINKLERS?: YES REMARKS: DATE PLANS RECEIVED BY JURISDICTION: 12/20/04 DATE INITIAL PLAN REVIEW COMPLETED: 1/4/O5 JURISDICTION: City of Carlsbad USE: Pharmaceutical Manufacturing ACTUAL AREA: 2545sf STORIES: 1 HEIGHT: OCCUPANT LOAD: 25 DATE PLANS RECEIVED BY ESGIL CORPORATION: 12/21/04 PLAN REVIEWER: Doug Moody FOREWORD (PLEASE READ): This plan review is limited to the technical requirements contained in the Uniform Building Code, Uniform Plumbing Code, Uniform Mechanical Code, National Electrical Code and state laws regulating energy conservation, noise attenuation and access for the disabled. This plan review is based on regulations enforced by the Building Department. You may have other corrections based on laws and ordinances enforced by the Planning Department, Engineering Department, Fire Department or other departments. Clearance from those departments may be required prior to the issuance of a building permit. Code sections cited are based on the 1997 UBC. The following items listed need clarification, modification or change. All items must be satisfied before the plans will be in conformance with the cited codes and regulations. Per Sec. 106.4.3, 1997 Uniform Building Code, the approval of the plans does not permit the violation of any state, county or city law. To speed up the recheck process, please note on this list (or a copy) where each correction item has been addressed, i.e., plan sheet number, specification section, etc. Be sure to enclose the marked up list when you submit the revised plans. TENANT IMPROVEMENTS WITHOUT SPECIFIC ENERGY DATA OR POLICY SUPPLEMENTS (1997UBC)tiforw.dot City of Carlsbad O4-455O 1/4/O5 Please make all corrections on the original tracings, as requested in the correction list. Submit three sets of plans for commercial/industrial projects (two sets of plans for residential projects). For expeditious processing, corrected sets can be submitted in one of two ways: 1. Deliver all corrected sets of plans and calculations/reports directly to the City of Carlsbad Building Department, 1635 Faraday Ave., Carlsbad, CA 92008, (760) 602-2700. The City will route the plans to EsGil Corporation and the Carlsbad Planning, Engineering and Fire Departments. 2. Bring one corrected set of plans and calculations/reports to EsGil Corporation, 9320 Chesapeake Drive, Suite 208, San Diego, CA 92123, (858) 560-1468. Deliver all remaining sets of plans and calculations/reports directly to the City of Carlsbad Building Department for routing to their Planning, Engineering and Fire Departments. NOTE: Plans that are submitted directly to EsGil Corporation only will not be reviewed by the City Planning, Engineering and Fire Departments until review by EsGil Corporation is complete. 1. Provide a statement on the Title Sheet of the plans stating that this project shall comply with the 2001 edition of the California Building Code (Title 24), which adopts the 1997 UBC, 2000 UMC, 2000 UPC and the 1999 NEC. 2. A complete description of the activities and processes that will occur in this tenant space should be provided. A listing of all hazardous materials should be included. The materials listing should be stated in a form that would make classification in Tables 3-D and 3-E possible. The building official requires a technical report to identify and develop methods of protection from hazardous materials. Section 307.1.6. 3. Provide a section view of all new interior partitions. Show: a) Method of attaching top plates to structure. (Please revise the spacing of the studs used for lateral bracing to 4' or provide calculations to show the 8' spacing to be adequate). 4. Provide an exit analysis plan (may be 8 1/2" x 11" or any convenient size). Show in this analysis the occupant load of each area, the general exit flow patterns (by using arrows), accumulated occupant loads and required exit widths. 5. Show rated corridors, lobbies, reception or foyers cross-hatched on the floor plans. 6. For exit access purposes, hallways shall be considered as intervening rooms. Section 1004.3.3.1. The hallway may have to be considered as a corridor (and thus possibly fire-rated) under the following conditions: a) If occupants from a room or area (having a cumulative occupant load of 10 or more) have already exited through an intervening room, and the next component of the exit access is into a hallway, that hallway would represent too many intervening rooms. Section 1004.2.2. City of Carlsbad 04-455O 1/4/05 b) If a room or area requires two exits, only one exit may be through an intervening room. Section 1004.2.2. If the other exit is into a hallway, that hallway would have to comply with the corridor provisions of Section 1004.3.4. 7. Exit corridors shall not be interrupted by intervening rooms. Foyers, lobbies or reception rooms constructed as for corridors shall not be construed as intervening rooms. Section 1004.3.4.4. 8. Please show the doors to offices 107 and 106 and all doors in rated corridors to comply with the following: Corridors shall have interior door openings protected by tight-fitting smoke and draft control assemblies rated 20 minutes. Doors shall be maintained self-closing or be automatic closing by action of a smoke detector per Section 713.2. Doors shall be gasketed to provide a smoke and draft seal where the door meets the stop on sides and top. Section 1004.3.4.3.2.1. 9. Please revise the detail for the rated corridor to show the gypsum wall board to be type X. 10. Please note on the plans "AC Cable is not allowed in A, B, E, H, and I occupancies. NM cable is restricted (without City approval) to one and two family dwellings. Note on plans that an equipment ground conductor is to be installed in all flexible conduits". 11. On the cover sheet of the plans, specify any items requiring special inspection, in a format similar to that shown below. Section 106.3.2. • REQUIRED SPECIAL INSPECTIONS In addition to the regular inspections, the following checked items will also require Special Inspection in accordance with Sec. 1701 of the Uniform Building Code. ITEM REQUIRED? REMARKS • STRUCTURAL CONCRETE OVER 2500 PSI • STRUCTURAL MASONRY 12. When special inspection is required, the architect or engineer of record shall prepare an inspection program which shall be submitted to the building official for approval prior to issuance of the building permit. Please review Section 106.3.5. Please complete the attached form. To speed up the review process, note on this list (or a copy) where each correction item has been addressed, i.e., plan sheet, note or detail number, calculation page, etc. City of Carlsbad O4-4550 1/4/05 Please indicate here if any changes have been made to the plans that are not a result of corrections from this list. If there are other changes, please briefly describe them and where they are located in the plans. Have changes been made to the plans not resulting from this correction list? Please indicate: Yes Q No Q The jurisdiction has contracted with Esgil Corporation located at 9320 Chesapeake Drive, Suite 208, San Diego, California 92123; telephone number of 858/560-1468, to perform the plan review for your project. If you have any questions regarding these plan review items, please contact Doug Moody at Esgil Corporation. Thank you. Post-it" Fax No(e 7671 City of Carlsbad 04-4550 1/4/03 &1& Phone # pages City QTiUarlsbad S:uiIdi n:gi ;D <e-partm e h t NOTICE OP REQUIREMENT FOR SPECIAL INSPECTION Do Not Remove Prom Hans Plan Check No. O4-4SSO I Job Address or Legal Description 2732 Letter Avenge West Address -2/72 Wcsr YW are hereby notified that in addition to the inspection of construction provided by the Building Department, an approved Registered Special Inspector is required to provide continuous inspection during the performance of the phases of construction indicated on the reverse side of this sheet. j The Registered Special Inspector shaIJ.be approved by the City of Carlsbad Building v • Department prior to the issuance of the building permit Special Inspectors having a current certification from the City of San Diego, Loa Angelas, or ICBO are approved as Special Inspectors for the type of construction for which they are certified. i Tbe inspections by a Special Inspector do not change the lefpirements for inspections by personnel of the City of Carlsbad building department. The inspections by a Special Inspector are in addition to the inspections normally required by the County Building Code. |ii The Special Inspector is not authorized to inspect and approve any work other than that for which he/she is specifically assigned to inspect. The Special Ijispeotor is not authorized to accept alternate materials, structural changes, or any requests for ^lan changes. The Special Inspector is required to submit written reports to the City of Carlsbad! building department of all work that he/she inspected and approved. The final inspection approval will not be given until all Special Inspection reports have been received and approved by the City of Carlsbad building department, iPlease submit the names of the inspectors who will perfbnrj the special inspections on each of the items indicated on the reverse side of this sheet. | (over) CUKH.vt>ya City of Carlsbad 04-4550 ! I/4fOS I SPECIAL INSPECTION HROSRAM i ADDRESS OR LEGAL DESCRIPTION: r?j2. Utetjayuwt IV£ST PLAN CHECK NUMBER:OWNER'S NAME: I, as the owner, or agent of the owner (contractors may not employ the special inspector), certify that I, or the architect/eng/neer of record, will be responsible for employing the special inspactorfB) as required by Uniform Building Code (UBC) Section 1701.1 for the construction project located at the site listed above. UBC Section 106,3.6- ^2>" "SignedX /^?. ^ 1, S3 The engineer/architect of record, certify that I have prepared the following epsdal inspection program as required by UBC Section 106,3,5 for the construct^ project located at the Bite listed above. Signed 1. List of work requiring special Inspection: Soils Compliance Prior to Foundation Inspection Structural Concrete Over 2500 PSI Prestres$ed Concrete s 2£| Structural Masonry Designer Specified High Strength Bolting Expanslon/Epoxy Anchors Sprayed-Oo Fireprooflng D other, 2, Name(s) of indMduaI(s) or flrm{s) respensiblD for thq special inspections listed above: c. 3. Duties of the special Inspectors for the work listed above; o ^£ t M ^ , 4 MP ALL £ g^'yv 6 . ^P ^-A T/ c ^ 5. City of Carlsbad 04-4550 1/4/05 VALUATION AND PLAN CHECK FEE JURISDICTION: City of Carlsbad PLAN CHECK NO.: 04-4550 PREPARED BY: Doug Moody DATE: 1/4/05 BUILDING ADDRESS: 2732 Loker Avenue West BUILDING OCCUPANCY: B/F1 TYPE OF CONSTRUCTION: VN BUILDING PORTION Tl Air Conditioning Fire Sprinklers TOTAL VALUE Jurisdiction Code AREA (Sq.Ft.) 2545 cb 1QQ4 IIFV RiiHrlinn Permit Fat* V Valuation Multiplier City Valuation By Ordinance Reg. Mod. VALUE ($) 78,895 78,895 $456.71 1994 UBC Plan Check Fee Type of Review: Repetitive FeeRepeats Complete Review D Other Hourly Structural Only Hour Esgll Plan Review Fee $296.86 $255.76 Comments: Sheet 1 of 1 macvalue.doc cHisamitsu Hlsamlteu Pharmaceutical Co., Inc. Hlsamltou Callfomla Laboratories 2732 Loker Anenue West Carlsbad, CA 92008 U.S.A January 19, 2005 EsGil Corporation 9320 Chesapeake Drive, Suite 208 San Diego, CA 92123 Subject: Description of the activities and processes Tenant Renovation for Hisamitsu California Laboratories 2732 Loker Avenue West, Carlsbad, CA 92008 Plan check No.: 04-4550 Dear Sir or Madam: Hisamitsu Pharmaceutical, Co., Inc. has laboratories called Hisamitsu California Laboratories located at the above-mentioned address. In our existing facility, we have a manufacturing area to produce samples for clinical studies, an analytical laboratory, a vault room, a conference room, and offices. We manufacture samples for clinical studies and test the quality of the samples. Our initial clinical studies were successful, and we are now planning to convert the clinical study facility into a commercial production facility by incorporating the following renovation work. 1. A new vault room to store finished products 2. A material storage room 3. A packaging room After receiving approvals from the FDA, we will start commercial production and manufacture pharmaceutical products that contain fentanyl, which is a Class II control substance defined by the PEA. Our manufacturing process is broken into the following steps: 1. Mixing 2. Coating 3. Cutting 4. Pouching 5. Packaging After the packaging step, finished products will be stored in the new vault room and be shipped out from the room. The estimated total number of people working in the building : 10 people Receptionist: 1 Staff in the analytical laboratory: 4 Staff in the manufacturing area: 5 The purpose and activity of those rooms will be as follows: The raw material area in the material storage room: We will store the following materials in the raw material area before production. • Polyisobutylene (High Molecule) 10 kg • Polyisobutylene (Low Molecule) 50 kg • Mineral Oil 20 kg • Isopropyl Myristate 15 kg • Toluene 70 kg • Plastic Film 2 roll(36cm X 1,000m) • Backing Film 2 roll(36cm X 1,000m) • Ethanol 20kg • Ethyl Acetate 20kg • Packing Film 5 rolls(36cm X 2,000m) (made of aluminum and plastic films) The packaging material area in the material storage room: We will store the following materials in the packaging material area before production. • Packaging Case (size: 135 X 25 X 135mm) 25,000 cases (made of paper) - Cartonbox (size:280X 160 X 280mm) 1,000 boxes (made of paper) The packaging room: After the pouching process in the production area is completed, all pouched units will be temporarily stored in the new vault room. Then, we will transfer pouched units to the packaging room, and 5 units of pouched products will be packed into a case. Then, 24 units of cases will be packed into a carton box. This is the final packaging process, and they become the finished products. The new vault room: We will store the following products: • Pouched, but not boxed products - approximately 100,000 pouches. • Finished products in boxes to be stored until shipment - approximately 2,200 boxes. • Finished products in cases to be stored in the chamber inside the vault room for stability testing - approximately 500 cases. Material safety data sheets shall be provided here, but the technical report to identify the methods of protection from hazardous material which we were requested to provide is currently being prepared. The report will be submitted for your review as soon as it is finished. Materials will be stored and handled according to industry safety standards and also is subject to meet DBA requirements. Our company brochure is enclosed with this letter for your reference. If you have any questions, please feel free to call me at (760) 431-4670 Sincerely, / Yasuhiro Ikeura Director Hisamitsu California Laboratories Attachments: PLANNING/ENGINEERING APPROVALS PERMIT NUMBER CB PATE ADDRESS RESIDENTIAL RESIDENTIAL ADDITION MINOR « $10,000.00) TENANT IMPROVEMENT PLAZA CAMINO REAL CARLSBAD COMPANY STORES VILLAGE FAIRE COMPLETE OFFICE BUILDING OTHER PLANNER ENGINEER DATE DATE t Docs/Misformsmanning Englnttring Approvals CarTsbad Fire Department 044550 1635 Faraday Ave. Carlsbad, CA 92008 Plan Review Requirements Category: Date of Report: 01/03/2005 Fire Prevention (760) 602-4660 Building Plan Reviewed by: Name: Address: City, State: Shimizu America 800 Wilshire Blvd.Suite 800 Los Angeles CA 90017 Plan Checker: Job Name: Job Address: Job #: 044550 Hisamitsu 2732 Loker Ave. West Bldg #: CB044550 Ste. or Bldg. No. Approved The item you have submitted for review has been approved. The approval is based on plans, information and / or specifications provided in your submitted; therefore any changes to these items after this date, including field modifications, must be reviewed by this office to insure continued conformance with applicable codes and standards. Please review carefully all comments attached as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements. D Approved Subject to The item you have submitted for review has been approved subject to the attached conditions. The approval is based on plans, information and/or specifications provided in your submittal. Please review carefully all comments attached, as failure to comply with instructions in this report can result in suspension of permit to construct or install improvements. Please resubmit to this office the necessary plans and / or specifications required to indicate compliance with applicable codes and standards. Incomplete The item you have submitted for review is incomplete. At this time, this office cannot adequately conduct a review to determine compliance with the applicable codes and / or standards. Please review carefully all comments attached. Please resubmit the necessary plans and / or specifications to this office for review and approval. Review FD Job # 1 st 2nd 3rd 044550 FD File # Othfir Agfinry ID The purpose and activity of those rooms will be as follows: The raw material area in the material storage room: We will store the following materials in the raw material area before production. 1 Polyisobutylene(High Molecule) 10 kg Polyisobutylene(Low Molecule) 50 kg Mineral Oil 20 kg Isopropyl Myristate 15 kg Toluene 70 kg Plastic Film 2 roll(36cmX 1000m) Backing Film 2 roll(36cmX 1000m) Ethanol 20kg Ethyl Acetate 20kg The packaging material area in the material storage room: We will store the following materials in the packaging material area before production. • Packaging Case (size: 135 X 25 X 135mm)25000 cases (made of paper) • Carton box (size:280 X 160 X 280mm) 1000 boxes (made of paper) ' Packing Film 5 rolls(36cm X 2000m) (made of aluminum and plastic film) The packaging room: After the pouching process in the production area is completed, all pouched units will be temporarily stored in the new vault room. Then, we will transfer pouched units to the packaging room, and 5 units of pouched products will be packed into a case. Then, 24 units of cases will be packed into a carton box. This is the final packaging process, and they become the finished products. The new vault room: We will store the following products: • Pouched, but not boxed products - approximately 100,000 pouches. • Finished products in boxes to be stored until shipment - approximately 2,200 boxes. • Finished products in cases to be stored in the chamber inside the vault room for stability testing - approximately 500 cases. Material safety data sheets shall be provided here but the technical report to identify the methods of protection from hazardous material which we were requested to provide is currently being prepared. The report will be submitted for your review as soon as it is finished. Materials will be stored and handled according to industry safety standards and also is subject to meet DEA requirements. /y Material Safety Data Sheet Company: Tgyo Aluminium K.K. Foil division, Yao Works Address:Aioi-cho 4-1,Yao city,Osaka pref. Department in charge:Dept.of Quality Assurance Prepare(Name):Hiroshi Abe Signature: Tel:(07Z9)93-151 I F«x:(07 29)94-87 55 Contact in emergency: Tel:(0729)93-l 51 7 Reference MSDS~No.AE09 Prepared/am en ded;0ctober2 0,1999 Name of productCohemical name,trade name,ate.}:Alumlnium foil Properties of substance: Distinction of single substance/mixture:Single product Chemical mm*:Aluminium Composition and content: JIS-4160 Alloy No.8021 Chemical Compos.ition Content(S) Si 3,15 nax. Fft 1.2 to 1,7 Cu 3.05 •nax. Mn — ME — Zr> — Ti — Others zToh 3.05 nax. Total 0.15 max. Al Remainder Chemical formula or structural formula:AI Reference number in Notification of Official Gazette (Industrial Safety and Health Law.Law Concerning the Examination and Regulation of Manufacture,etc.of Chemical Substances): CAS Number:7429-9Q-5 UN Classification end UN Number: Classification of Hazard and Noxiousness Name of Classification; Harard:nil Noxiousnassinil Environmental impact:ni! First aid in emergency; Eya contact:Wh«n powder and dust is contacted with the eyes,wash the eyes with clean running water,and contact an eye doctor immediately if pain is left. Skin contact:When molten aluminium is contacted with the skin.wash the affected part with • large volume of water 1 •" L V L I immediately to cool the affected pa rt.and immediately contact a doctor if the skin is seriously damaged. Inha,lation:When a large volume of powder and dust is inhaled,shift tha patient to a place with fresh air irnmediately to ke»p him at rest and warm.and contact a doctor immediately. Ingestion: When a large volume of aluminium product is ingested, obtain the diagnosis from a doctor. Treatment in fire: Though aluminium foils and sheets are not ignited,high- temperature combustion or explosion can be generated in the case of aluminium powdar or chips.The initial fire is covered with non-oombustible material such as gypsum to shut off oxygen,and the extinguishment by smothering is performed using the dry sand. If aluminium foils and sheets their coil are wat with Yiater and left as they are,explosion can be generated by the rapid oxidation.Shift the wet coi! immediately to a safe place,and prohibit persons from entering the place. Treatment in leakaniunnecesaary Precautions in handling and storage: HandIing:Pay attention not to give shocks to causa a dent, hand can be cut by the edge of the foil,and handling by bar« hands shall be prohibited. In tht case of powders,high temperature or spark flame shall be avoided, the measures shall be taken against the static electricity,and rough handling such as toppling of the containers,dropping,giving shocks,or dragging shall b« prevented. Storage:Pay attention not to ba wet with rain. Aluminium shall not be stored in a place in contact with chemicals such as acid,alkali,strong oxidizing agents,chlorides. In tht «ase of the powders,not only th» contact v»ith th« substances to be reacted with aluminium such as water, acid.and alkali.but also exposure of tha container to the direct sunshine shall be avoided,and the powder shall be stored in a cold,dark place in a sealed condition. For other items.the requirement of the Fire Servica law. etc.shall be foil owed. Exposure preventive device; Concentration to be controlle<l:nil Allowable concentration:Society of Occupational Health in 7K.- Jaoan{ - year edition) ACGIH( - year edition) Measure for equipment;unnacessary Protective equipment: Protective equipment for breathing:unnecessary for" aluminium foil and sh«»ts. Wear the protective mask when dust,fine chips,lathe chips or powder are present. Protective goggle:W«ar the protective toggle in the work in which powders and fine chips are generated. Protective glovesiUsa the protective gloves in a case whan finger tips can be damaged. Protective cloth:Wear the special cloth(heat Insulation w«ar)in handling the molten aluminium. Physical and chemical properties: Appearance and odor:silver-colored ductile metal odorless Boiling point:2060°C Vapor pressure:- oaf- *C) Volatility: Melting point:660°C Density:2.72Mg/m' Solubility in waterinsoluble Reactivity to water:non-reactive in solid Others: Information on Hszardtstabiljty,reactivity) F!ashpoint:-"C Ignition point:-°C Explosion limit; upptr limit;-* lower limit;-* Combuativility: Ignition propertyCnatural ignition,reactivity with wattr): When tht coiled aluminium foil is wet with water,tnin foil can be exploded due to the heat of reaction. Oxidizing prop«rty:The aluminium surface is protected thin natural oxide film in the normal atmosphere.and further oxidization is absent. self-reactivity:nil dust explosivity:ea3ily explosive in the dust condition. in paticular.dangerous in the presence of the discharge source, stability,reactivity:stable if aluminium foil is stored in the normal atmospheric condition. others:nil Information on NoxioysnessCincluding the human cases and epidemiologies! information) Skin causticity:nil IrrititionCsk'tn.eyeV-nil Sensitivenessrnil Acut» toxicityGncluding 50% lethal dose):nil Subacute toxicityinil Chronic toxicityinil Carcinoganicity:nil Mutagenicity(microorganism,chromosome abnormality):nil Reproduction toxicity:nil Teratog«nicity:nil OthersCincluding generation of noxious eas in reaction with water):nil Information on environmental impact Degradability.nil Acoumulation:nil Fieh-toxicity:nil Othersin il Precautions on disposal: Do not leave the coiled aluminium foil outdoors. Store the dross in a dry place because it generate* methane or ammonium in the wet atmosphere. Precautions on Pay attention not to give a shock to aluminium foil large enough to cause a dent. Pay attention not to be wet in rain. Applicable taws and regulation: Industrial Safety and Health Law,Ordinance on Prevention of Hazards due to DustCCabinet Order Nfl.13,1979) Others(Referenae of contents,lit«rature cited.etc.) ./< TOYOBO ESTER FILM E5102 vsw\n\yTOYOBOJ Revised :May. 30, 2003 MSDSNo. P0331K Material Safety Data Sheet 1 PRODUCT AND COMPANY IDENTIFICATION ^ I x , Product Name TOYOBO ESTER FILM E5102 . /^CF'^ # ' Product Code E5102 SUPPLIER Name TOYOBO Co., Ltd. Address 2-8 Dojima Kama 2-chome, Kita-Ku OSAKA 530-8230 JAPAN Films Production & Logistics Department Telephone No. +81-6-6348-4129 (9am - 6pm Japan Standard Time Mon-Pri) Fax No. +81-6-6348-3774 EMERGENCY TELEPHONE NUMBER Toyobo America, Inc. Telephone : (212)317-9245 9am - 6 pm EST Mon-Fri 2 COMPOSITION /INFORMATION ON INGREDIENTS Chemical Product Preparation (Substance/Preparation) Chemical Name Polyethylene terephthalate Synonyms Polyester^PET Chemical formula (-COtCsH^COOCCH^OOn CAS No, 25038-59-9 Concentration ^ 99% Chemical Name Silicon dioxide Synonyms Silica Chemical formula Si02 CAS No. 7631-86-9 Concentration < 1% Components Contributing Substances classified as hazardous are less than 1%. to the Hazard 3 HAZARDS IDENTIFICATION Most Important Hazards Adverse Human Health Few adverse human health effects are anticipated. Effects Physical and Chemical Combustible with the existence of ignition source. Hazard Specific Hazards May scratch the surface of the eye and skin. Fumes or vapours generated from melting product may cause the irritation of respiratory organ and eyes. 4 FIRST-AID MEASURES Inhalation Remove to fresh air if effect occurs. Consult a physician if necessary. Skin Contact Wash off in running water or shower- In caee of molten product, cool down and wash with cold water, immediately. Do not remove it. Consult a physician if necessary. Ey« Contact Immediately rinse eyes with plenty of water for at least 15 minutes. Call a physician if aecessary. Ingestion Induce vomiting. If indisposition continues, seek medical attention. 2/4 TOYOBO ESTER FILM E51Q2 First issue ; Aug. 5,1999 Revised :May. 30,2003 MSDSNo. P0331K Material Safety Data Sheet 5 FIRE-FIGHTING MEASURES Extinguishing Media Water Spray, Carbon Dioxide, Dry Chemical Powder Specific Hazards Toxic gas as acetaldehyde and CO(Carbon Monoxide) may be generated under imperfect combustion. Specific Methods Extinguish -with a lot of water Protection of Firefighters In case of a big fire, wear self-contained breathing apparatus and protective clothing. 6 ACCIDENTAL RELEASE MEASURES Personal Precautions Take care not to slip on the film and not to scratch eyes or skin by the edges. Environmental Precautions Do not discard in environment, since it stays for a long time and spoils the sight. Methods for Cleaning up Collect and place in a disposal container. 7 HANDLING AND STORAGE HANDLING Technical Measures Prevent collapse and. drop. It is necessary to discharge the electrostatic charges built up during processing or handling the ffl™ by electrostatic discharger. For dust evolving process or molding, set up a good ventilation and a local exhaust system in the work area. Wear the protective equipments to avoid scratching the skin or eyes. Precautions Keep away from fire or heat. Safe Handling Advice Do not touch material with unprotected hands. STORAGE Technical Measures Bo not pile up higher than 1.5m for preventing collapse or drop. Storage Conditions Keep away from flame and heat-source. Incompatible Products Strong oxidizing materials Packaging Materials Paper 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING MEASURES Set up a good ventilation and exhaust system in the work area. Eye washing apparatuses and showers should be provided near the work place. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection For dust evolving process or molding, filter respirator Hand Protection Gloves Eye Protection Eye-protection goggles Skin and Body Protection Long sleeves Material Safety Data Sheet 3/4 TOYOBO ESTER FILM E5102 ; issue ; Aug. 5,1999 Revised iMay, 30,2003 MSDSNo. F0331K 9 PHYSICAL AND CHEMICAL PROPERTIES Physical State Solid Plastic film Colour Opacity- Odour None pH Not Applicable Melting point 255*0 Decomposition point over 500^ (in N2 gas) Auto ignition point 508*0 (Due to PET heat decomposition) Explosion Properties If a lot of dust generated, it may explode with electrostatic ignition, Density 1.3—1,4 gfan* Solubility Insoluble in water and general solvent (Soluble in concentrated Sulfuric acid and phenolic solution) 10 ST^ILFTY AND REACTIVITY Stability Stable at ambient temperature Possible Hazardous Partially decompose at as high as melting temperature. Reactions Can burn with ignition source. Conditions to Avoid High temperature over 500"C, ignition sources, direct sun- light Material to Avoid Oxidizing agents Hazardous Decomposition Toxic gases (acet aldehyde, CO etc.) are generated by heat Products decomposition or imperfect combustion, 11 TOXLCOLOGICAL INFORMATION Acute Toxtcity Although there is no data in this product, acute toxicity is thought to be very low. Local Effects Although there is no data in this product, it is thought to have few adverse effects. 12 ECOLOGICAL INFORMATION Persistence/Degradability Not degradahle and stay for a long time, Bioaccumulation Thought to be no. Possible Environmental Disposal in the oceans may damage the marine organism Impact and birds. 13 DISPOSAL CONSIDERATIONS Waste from Residues Disposes of in accordance with all applicable local and national laws and regulations. Do not dump this material into sewers, on the ground or into any body of water. Contaminated Packaging Dispose of as well as the material 4,4 TOYOBO ESTER FILM E5102 First issue : Aug. 5,1999 (TOYOBO) Revised May. 30,2003 MSDSNo. F0331K Material Safety Data Sheet 14 TRANSPORT INFORMATION International Regulations UN Classification Number Not classified. US DOT Not regelated Follow all of the laws and regulations in your country. Specific Precautions Avoid water and handling the material gently for not crushing1 the carton. 15 REGULATORY INFORMATION OSHA STATUS: Not a hazardous material TSCA STATUS: Listed on TSCA inventory EINECS Monomers and other ingredients are all listed on EINECS. CERCLA REPORTABLE QUANTITY: Not a hazardous substance SAHA TITLE HI: section 302 extremely hazardous substances: No section 311/312 hazardous categories;None hazardous section 313 toxic chemicals No RCRA STATUS: Not a hazardous waste California proposition 65: No Follow all of the laws and regulations in your country. 16 OTHER INFORMATION Hazard rating: classication NFFA HMIS Health 0 0 Flammability 1 1 Reactivity 0 0 (physical hazard) Specific Hazard; none Protective Equipment; G Notice The information in this MSDS, to the best of our knowledge, is accurate and correct However, TOTOBO makes no warranty and assumes no liability whatsoever in connection with any use of this information. The MSDS is subject to revision as new information becomes available. PRODUCT SAFETY SUMMARY Scotchpak™ 1022 Scotchpak™ 1022 Release Liner has been subjected to the safety evaluations as outlined below. Results of each are summarized. Agar Overlay Cytotoxicity This test was conducted in accordance with the Food and Drug Administration; s Good Laboratory Practices Regulation of 1978. The protocol was modeled after: Guess, W.L. et al: Agar Diffusion Method for Toxicity Screening of Plastics on Cultured Monolayers, J. Pharm. Sci. 54:1545-1547 (1965) Results found that Scotchpak 1022 was not cytotoxic. Primary Skin Irritation This test was conducted in accordance with the Food and Drug Administration's Good Laboratory Practices Regulation of 1978. The protocol was modeled after: Draize: Appraisal of the Safety of Chemicals in Foods, Drugs and Cosmetics (1965). Results found that Scotchpak 1022 to be non-irritating when applied directly to the skin. Acute Systemic Toxicity These tests were conducted in accordance with the Food and Drug Administration's Good Laboratory Practice Regulation of 1978 using the U.S.P. procedure for Class V Plastics. Results of these tests found that Scotchpak 1022 did not contain any components which are leachable in saline, cottonseed oil, 1:20 ethanol: saline or PEG 400 which are toxic when injected systemically into mice. r F-U PRODUCT SAFETY SUMMARY SCOTCHPAK™ 9723 Scotchpak™ 9723 Polyester Film Laminate has been subjected to the safety evaluations as outlined below. Results of each are summarized. All testing was conducted in accordance with the FDA Good Laboratory Practices Regulation of 1978. These evaluations satisfy the USP XII Class V biological test requirements for plastics. Acute Systemic Toxicitv Contains no components which are leachable in saline, 1:20 ethanohsaline, cottonseed oil or polyethylene glycol which are toxic when injected systemically. Intracutaneous Irritation Contains no components which are leachable in saline, 1:20 ethanol:saline, cottonseed oil or polyethylene glycol which produce irritation when injected intracutaneously. In Vitro Cytotoxicity Non-cytotoxic Primary Skin Irritation No evidence of irritation when applied directly to skin. 3M MATERIAL SAFETY DATA SHEET SCOTCHPAK FILMS 10/29/2003 3M Material Safety Data Sheet Copyright, 2003, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. This material safety data sheet (MSDS) is provided as a courtesy in response to a customer request This product is not regulated under, and a MSDS is not required for this product by the OSHA Hazard Communication Standard (29 CFR 1910.1200) because, when used as recommended or under ordinary conditions, it should not present a health and safety hazard. However, use or processing of the product not in accordance with the product's recommendations or not under ordinary conditions may affect the performance of the product and may present potential health and safety hazards. SECTION 1: PRODUCT AND COMPANY -IDENTIFICATION PRODUCT NAME: SCOTCHPAK FILMS MANUFACTURER: 3M DIVISION: Specialty Film Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 10/29/2003 Supercedes Date: 06/10/2002 Document Group: 18-0352-7 General packaging. Product Use: Specific Use: SECTION 2: INGREDIENTS Ingredient SCOTCHPAK BRAND POLYESTER FILMS C.A.S. No. NONE % by Wt 100 (typically 100) SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Film Odor, Color, Grade: clear to hazy General Physical Form: Solid Immediate health, physical, and environmental hazards: May cause thermal bums. This product, when used under reasonable conditions and in accordance with the 3M directions for use, should not present a health hazard. However, use or .Page 1 of 7 3M MATERIAL SAFETY DATA SHEET SCOTCHPAK FILMS 10/29/2003 processing of the product in a manner not in accordance with the product's directions for use may affect the performance of the product and may present potential health and safety hazards. Contains a chemical or chemicals which can cause cancer. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Vapors from heated material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Thermal Bums: Signs/symptoms may include severe pain, redness and swelling, and tissue destruction. Skin Contact: Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching. Thermal Bums: Signs/symptoms may include intense pain, redness and swelling, and tissue destruction. Inhalation: Vapors from heated material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: No health effects are expected. Contains a chemical or chemicals which can cause cancer. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Get immediate medical attention. Skin Contact: Immediately flush skin with large amounts of cold water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Cover affected area with a clean dressing. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse. ' _ Page 2 of 7 3M MATERIAL SAFETY DATA SHEET SCOTCHPAK FILMS 10/29/2003 Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. If Swallowed: No need for first aid is anticipated. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Not Applicable Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable 5.2 EXTINGUISHING MEDIA Material will not burn. Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Unusual Fire and Explosion Hazards; No unusual fire or explosion hazards are anticipated. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Not applicable. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING This product is considered to be an article which does not release or otherwise result in exposure to a hazardous chemical under normal use conditions. Avoid skin contact with hot material. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. 7.2 STORAGE Not applicable. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Not applicable. Provide appropriate local exhaust when product is heated. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) Page 3 of 7 3M MATERIAL SAFETY DATA SHEET SCOTCHPAK FILMS 10/29/2003 8.2.1 Eye/Face Protection Not applicable. Avoid eye contact. The following eye protection^) are recommended: Safety Glasses with side shields. 8.2.2 Skin Protection Not applicable. Avoid skin contact with hot material. Wear appropriate gloves, such as Nomex, when handling this material to prevent thermal burns. 8.2.3 Respiratory Protection Not applicable. Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. 8.2.4 Prevention of Swallowing Not applicable. 8.3 EXPOSURE GUIDELINES None Established SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Film Odor, Color, Grade: clear to hazy General Physical Form: Solid Autoignition temperature Not Applicable Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable Boiling point Not Applicable Density Not Applicable Vapor Density Not Applicable Vapor Density Vapor Pressure Not Applicable Specific Gravity >=1.000 [RefStd: WATER=1] pH Not Applicable Melting point No Data Available Solubility In Water Solubility in Water Nil Evaporation rate Not Applicable Volatile Organic Compounds Not Applicable Percent volatile Not Applicable VOC Less H2O & Exempt Solvents No Data Available Viscosity Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Page 4 of 7 3M MATERIAL SAFETY DATA SHEET SCOTCHPAK FILMS 10/29/2003 Materials and Conditions to Avoid: None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material. SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not applicable. CHEMICAL FATE INFORMATION Not applicable. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Reclaim if feasible. Dispose of waste product in a sanitary landfill. As a disposal alternative, incinerate in an industrial or commercial facility. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 70-0708-6704-2 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. Page 5 of 7 3M MATERIAL SAFETY DATA SHEET SCOTCHPAK FILMS 10/29/2003 SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to Page 6 of 7 3M MATERIAL SAFETY DATA SHEET SCOTCHPAK FILMS 10/29/2003 be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Section 1: Product use information was modified. Copyright was modified. Section 4: First aid for eye contact - intervention - was modified. Section 3: Potential effects from inhalation information was modified. Section 6: Release measures information was modified. Section 8: Eye/face protection phrase was modified. Section 4: First aid for skin contact - intervention - was modified. Section 2: Ingredient table was modified. Section 16; NFPA explanation was modified. Page Heading: Product name was modified. Section 1: Initial issue message was modified. Section 12: Ecotoxicological phrase was added. Section 12: Chemical Fate phrase was added. Section 6: Release measures note - reportability - was deleted. Section 12: Ecotoxicological ecotox article information was deleted. Section 12: Ecotoxicological ecofate information was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com .Page 7 of 7 PRODUCT HEALTH AND SAFETY DATA PAGE 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION PRODUCT: CRYSTOL 352 ESSO SEKIYU PRIVATE LTD. PRODUCT #: K-61-009 tf Bui Iding 1-8-15 PHSD #: 61-4020009 Kohnan, Minato-ku, Tokyo DATE OF ISSUE: 19 DECEMBER 1994 JAPAN 108-8005 For Contact: Lubricants TEL:0120-337-168 FAX:03-5495-2689 Fuels TEL: 045-503-7626 FAX: 045-503-7617 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients present at or above 0.1 wt% (classified as toxic or very toxic) or 1 wt% (classified as harmful, irritant or corrosive). HAZARDOUS INGREDIENT APPROXIMATE CONCENTRATION None 3. HAZARD IDENTIFICATION This product contains highly refined white mineral oil. It is of low oral and dermal toxicity and under normal conditions of use should present no significant health hazards. 4. FIRST AID INHALATION: At ambient/normal handling temperatures, inhalation of vapors is normally not a problem. |f overexposed to oil mist, remove from further exposure. Administer artificial respiration if breathing is irregular or has stopped. Get prompt medical attention. SKIN CONTACT: No adverse effects due to skin contact are expected. EYE CONTACT:If irritation should occur, rinse eyes with water and obtain medical advice. PRODUCT HEALTH AND SAFETY DATA PAGE 2 PRODUCT: CRYSTOL 352 ESSO SEKIYU PRIVATE LTD. 4. FIRST AID (Continued) INGEST I ON: No adverse effects due to ingestion are expected. 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Foam, dry chemical powder, carbon dioxide. EiEE AND EXPLOSION HAZARDS:low hazard. The product can form flammable mixtures or canT5urn only on heating above the flash point. However, minor contamination by hydrocarbons of higher volatility may increase the hazard. SPECIAL FIRE-FIGHTING PROCEDURES: Water fog or spray, to cool fire-exposed surfaces (e.g. containers) and t9 protect personnel, should only be used by personnel trained in fire fighting. Cut off "fuel"; depending on circumstances, either allow the fire to burn out under controlled conditions or use foam or dry chemical powder to extinguish the fire. Respiratory and eye protection required for fire fighting personnel exposed to fumes or smoke. HAZARDOUS COMBUSTION PRODUCTS: Smoke, and carbon monoxide may be formed in the event of incomplete combustion. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: See Section 8. LAND SPILL:Shut off source taking normal safety precautions. Prevent liquid from entering sewers, water courses or low |ying areas: advise the relevant authorities if it has, or if it contaminates so i I/vegetation. Take measures to minimise the effects on ground water. Recover by skimming or pumping using explosion-proof equipment, or PRODUCT HEALTH AND SAFETY DATA PAGE 3 PRODUCT: CRYSTOL 352 ESSO SEK1YU PRIVATE LTD. 6. ACCIDENTAL RELEASE MEASURES (Continued) contain spilled liquid with booms, sand, or other suitable absorbent and remove mechanically into containers. If necessary, dispose of adsorbed residues as directed in Section 13. WATER SPILL:Confine the spill immediately with booms. Warn other shipping. Notify port and other relevant authorities. Remove from the surface by skimming or with suitable absorbents. Disperse the residue in unconfined waters, if permitted by local authorities and environmental agencies. 7. HANDLING AND STORAGE Store the product in cool, well ventilated surroundings, well away from sources of ignition.Provide suitable mechanical equipment for the safe handling of drums and heavy packages. Electrical equipment and fittings must comply with local regulations regarding fire prevention with this class of product. Empty containers may contain product residue. Do not pressurize cut, heat, or weld empty containers. Do not reuse empty containers without commercial cleaning or reconditioning. Do not handle or store near an open flame, sources of heat, or sources of ignition. LOAD/UNLOAD TEMPERATURE deg. C: Ambient to max. 40 C STORAGE TEMPERATURE deg. C: Ambient to max. 40 C SPECIAL PRECAUTIONS: Keep containers closed when not in use. Prevent small spills and leakages to avoid slip hazard. Take extreme care to avoid contamination by other products and materials. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMIT: 5 mg/m3 for oil mists (TWA, 8h - workday) recommended based upon the ACGIH TLV (Analysis according to US NIOSH Method 5026, NIOSH Manual of Analytical Methods, 3rd Ed.). PRODUCT HEALTH AND SAFETY DATA ' PAGE 4 PRODUCT: CRYSTOL 352 ESSO SEK1YU PRIVATE LTD. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION (Continued) PERSONAL PROTECTION: In open systems where contact is likely, wear safety glasses with side shields. When concentrations in air may exceed the occupational exposure limit, and where engineering, work practices, or other means of exposure reduction are not adequate, approved respirators may be required. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE / ODOUR: Clear colourless liquid, neutral odour. DENSITY, g/ml: 0.87 at 15 deg. C Range 0.858 - 0.875 BOILING RANGE: Data not available. VISCOSITY, imi2/S: 68 at 40 deg. C Range 67.0-74.0 VAPOUR PRESSURE, kPa: at 20 deg. C Non-volatile VAPOUR DENSITY AT 1 BAR (Air=1): Heavier than air EVAPORATION RATE (n-butyl acetate=1): Non-volatile SOLUBILITY IN WATER: 20 deg. C Negligible pH: Not AppIi cab Ie. FLAMMABILITY LIMITS IN AIR, % BY VOL: LEL: 0.9 UEL: 7.0 Approx. AUTOIGNIT10N TEMPERATURE: Data not available. PARTITION COEFFICIENT n-octanol/water: Data not available. 10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC): Stable PRODUCT HEALTH AND SAFETY DATA ' PAGE 5 PRODUCT: CRYSTOL 352 ESSO SEKIYU PRIVATE LTD. 10. STABILITY AND REACTIVITY (Continued) CONDITIONS TO AVOID: Keep away from heat sources, open flames and other sources of ignition. INCOMPATIBLE MATERIALS: Avoid contact with strong oxidants such as liquid chlorine and concentrated oxygen. HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient temperature. 11. TOXICOLOaiCAL INFORMATION EFFECTS OF'OVER EXPOSURE: INHALATION:Negligible hazard at ambient/normal handling temperatures. Elevated temperatures or mechanical action may form vapours, mists, or fumes which may be irritating to the eyes, nose, throat, and lungs. Avoid breathing vapours, mists, or fumes. SKIN CONTACT: Not considered to be a hazard. EYE CONTACT: Not considered to be a hazard. INGEST I ON: No hazard in normal industrial use. May cause laxative effects when ingested. Excessive ingestion of white mineral oils has been associated with oi droplet formation in tissues, a condition which is considered to be clinically unimportant in humans. CHRONIC: White mineral oils of similar composition and refining history have not exhibited chronic or carcinogenic activity in laboratory animals. PRODUCT HEALTH AND SAFETY DATA ' PAGE 6 PRODUCT: CRYSTOL 352 ESSO SEKIYU PRIVATE LTD. 11. TOXICOLOGICAL INFORMATION (Continued) TOXICITY DATA: ACUTE: White mineral oils have a low order of acute toxicity. They are not irritating to the eyes or skin and are not skin sensitizing. The acute toxicity of white oiIs is: Oral : LD50 > 5000 mg/kg Dermal : LD50 > 5000 mg/kg Inhalation: LC50 > 4000 mg/m3 CHRONIC: Subchronic studies conducted with similar white mineral oils have not resulted in any adverse biological effects. Chronic studies of white mineral oils and other highjy refined mineral hydrocarbons have shown no indication of chronic toxicity or carcinogenicity. 12. ECOLOGICAL INFORMATION in the absence of specific environmental data for white mineral oils, this assessment is based on information for general hydrocarbon components found in white mineral oils. White mineral oils released to the environment will remain largely on the soil surface, and in water, will remain largely on the water surface. Based on chemical and physical information for this product category, harmful effects to terrestrial or aquatic organisms are expected to be minimal. There is a potential for bioaccumulation. White mineral oils are expected to biodegrade and not persist in the environment. 13. DISPOSAL CONSIDERATIONS Collect and dispose of waste product at an authorised disposal facility, in conformance with national and local regulations, and in accordance with EEC Directives on the disposal of waste oil. 14. TRANSPORT INFORMATION USUAL SHIPPING CONTAINERS: Tank trucks, drums, cans. PRODUCT HEALTH AND SAFETY DATA PAGE 7 ' PRODUCT: CRYSTOL 352 ESSO SEKIYU PRIVATE LTD. 14. TRANSPORT INFORMATION (Continued) TRANSPORT TEMPERATURE deg. C: Ambient to max. 40 C JAPANESE TRANSPORT REGULATIONS Indicate Product Name, Quantity, Danger Class, and "No Fire" on transport container and packing. When transport is in excess of the quantity designated, indicate "Danger" on front and rear ends of the vehicle and provide a fire extinguishing device. For land transport the height of the pile should be less than 3 meters. Do not load together with dangerous substance Class 1 or Class 4. In addition, follow every applicable law and regulation. 15. REGULATORY INFORMATION DANGEROUS SUBSTANCES/PREPARATIONS CLASSIFICATION: Not regulated Refer to your national legislation implementing the EC Directive 91/155/EC JAPANESE REGULATORY INFORMATION: Law Concerning the Examination and Regulation of Manufacture: ect.: of Chemical Substances. Fire Law: Note F.P.>200 Dangerous substance, CL4, No.4 Water Pollution Control Law Oil effluent regulation (5mg/l) Water Pollution Control Law Oil effluent regulation (Banded as principle) Sewage Water Law Mineral oil effluent regulation (5mg/l) Law on Waste Treatment and Cleaning Industrial waste regulation PRODUCT HEALTH AND SAFETY DATA ' PAGE 8 PRODUCT: CRYSTOL 352 ESSO SEKIYU PRIVATE LTD. 16. OTHER INFORMATION PRODUCT TYPE / USES: White mineral oil, meets following international standards: FDA 21 CFR 172.878 and CFR 178.3620 (a) US Pharmacopoeia European Pharmacopoiea equivalent national standards Types of uses according to relevant national or international regulations: PRODUCT USED AS DIRECT FOOD ADDITIVE/FOOD PROCESSING AIDS as per: FDA 21 CFR 172.878 and 178.3620 (a) and equivalent national standards PRODUCTS USED AS INDIRECT FOOD ADDITIVES as per: FDA 21 CFR 174 to 179 and equivalent national standards PRODUCTS USED IN COSMETICS and PHARMACEUTICALS as per: European Pharmacopoeia US Pharmacopoeia XXIII and equivalent standards SOURCE OF KEY DATA: The recommendations presented in this Material Safety Data Sheet were compiled from actual test data (when available), comparison with similar products, component information from suppliers and from recognised codes of good practice. The information and recommendations contained herein are, to the best of Exxon's knowledge and belief, accurate and reliable as of the date issued, but are offered without guarantee or warranty. They relate to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Conditions of use of the material are under the control of the user; therefore, it is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. PRODUCT NAME: VISTANEX(R) MM L-LOO _ PAGE 1 MSDS NUMBER: HDHP-J-00303 REVISION: 1 February 2000 F. 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION IDENTIFICATION OF THE PRODUCT: VISTANEX (RJ MM L-100 CHEMICAL FAMILY-. PRODUCT DESCRIPTION; White to pale yellow rubbery solid. See Notes Section for applicable grades. SUKPHBR: EXXON CHEMICAL H3TER1TATIONAL SERVICES LTD. 22/F, CENTRAL PLAZA IS HARBOUR ROAD WAUCHAI HONG KONG Telephone; 8S2-2SB2-0889 Facsimile; B52-2S82-0239 EMERGENCY TELEPHONE NUMBER: 352-2582-0888 (office hours) B52-9163-05SS (outside office hours) 2 COMPOSITION/INFORMATION- ON INGREDIENTS HEALTH HAZARDOUS COMPONENTS : NOI3E ~~— — ^•.^*^«H+-^W<*M*4^^^W^_v._**.**V*.^—^_*_____ — **~~.^-. 3 5IAZARDS IDE1TTIFICATXON PHYSICAL AND CHEMICAL HAZARDS / FIRE AND EXPLOSION HAZARDS . Low hazard. Material can form flammable mixtures or can 1mm. only upon heating ro temperatutes at or above the flash point. Decomposes. Flammable/toxic gases will form upon decomposition, See Section 10 "STABILITY AMD REACTIVITY". Toxic gases will form upon cornbuscion. See Section 5 "FIRfl-FlGHTtNG MEASURES". Dust. Material in form of dust is s'ubject to explosions. Fire is accompanied by chc evolution of a dense black smoke with an acrid odour. It may cause watery eyes (lachrymacion) . * ExxonMobil Chemical includes ExxonMobil Chemical Company and its stewarded affiliates. PRINT SATE: 29 May 2000 Cent PRODUCT NAME: VISTANEX(R) MM L-100 MSTDS NDMBE3.; REVISION: PAGE 2 HDHP-J-QD303 1 February 2000 FIRST AID MEASURES Using proper respiratory protection, immediately remove the affected victim from exposure. administer artificial respiration, if breathing ia stopped. Keep at rest. Call for prompt medical attention, SKIU CONTACT: o For hot product; immediately immerse in or flush the affected area with large amounts of cold water to dissipate heat. Cover with clean cotton sheeting or gauze and get prompt medical attention. No attempt should be made to remove material from skin, or to remove contaminated clothing, as the damaged flesh can be easily torn. EYX CONTACT: o This product is an inert solid. If in the eye for any foreign, object by flushing with water obtain medical INGESTION: Noc applicable. remove as one would do If irritation occurs, 5 PIHE- FIGHTING MEASURES FIRE FIGHTING PROCEDURES: Use water spray to cool fire exposed surfaces and to protect personnel. Block Che supply to the fire. Extinguish Che fire by cooling with water spray. SPECIAL FIUS PRECAUTIONS: Respiratory and eye protection required for fire fighting personnel. See also Section 4 "FIRST AID MEASURES" as well as Section 10 "STABILITY AND REACTIVITY". HAZARDOUS COMBUSTION PRODUCTS: Utider Oxygen lean condicions, Carbon Monoxide (CO) and irritating smoke may be produced. PRINT DATE: 29 May 2000 ContJ PRODtTCT NAME : VISTANEX(R) MM L-100 MSDS WJMBBR: REVISION: PAGE 3 KDKe-J-00303 1 February 2000 6 ACCIDENTAL RELEASE LAND SPILL: Sweep up spilled malarial and place in suitable containers for recycle or disposal. Consult an expert on disposal of recovered material and ensure conformity co local disposal regulations. WATER SPILL: o Racover the spilled material and place in suitable containers for recycle or disposal. o Consult an expert on disposal of any recovered material and ensure conformity co local disposal regulations. 7 HANDLING AND STORAGE STORAGE TEMPERATURE (DegC) : Ambient TRANSPORT TEMPERATURE (DegC} : Ambient LOADING/UNLOADING TEMPERATURE (DegC} : Ambient VISCOSITY (cst) : Not Applicable STORAGE/TRANSPORT PRESSURE! (JcBa) : Atmospheric ELECTROSTATIC ACCUMULATION HAZARD? No, £uc use proper grounding procedure USUAL SHIPPING CONTAINERS: Cardboard units MATERIALS AND COATINGS SUITABLE: Not Applicable MATERIALS AKD COATINGS UNSUITABLE: Not Applicable STORAGE / HANDLING, GENERAL o This material is not a static accumulator but use proper bonding and/or grounding procedures. PRINT DATE: 29 May 2000'""Cont. PRODUCT NAME: VISTANEX(R) MM L-100 MSDS NUMBER: REVISION: PAGE 4 HDHP-J-Q0303 1 February 2000 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROL MEASURES / VENTILATION Local exhaust ventilation of process equipment may be needed Co control aerosol exposures to below the recommended threshold exposure limic. Sea personal protection recommendations. The ACGIH recommends a TWA of 10 mg-/m3 for Inhalable particulate {total dust) and a TWA of 3 mg/mS for Respirable p&rticulate (total dust) for particulates not otherwise classified (PHOC) PERSONAL PROTECTION: o For open systems where contact is likely/ wear safety glasses with, side shields, o Where contact may occur with hot materials, wear thermal resistant gloves, arm protection and a face shield, o Where overexposure by inhalation may occur and engineering; work practice or other means of exposure reduction, are not adecpiate, approved respirators may be necessary. 9 PHYSICAL AND CHEMICAL PROPERTIES These are indica.ta.wa values only, specification, sheet. Pl&ase refer also to che product PHYSICAL STATE: FORM/COLOUR: ODOR: Solid PH () ( DegC) : FREEZ./MELT/ POINT: BOILING POINT RANGE: FLASHPOINT (} : AUTOIGNITION TEMPERATURE: EXPLOSIVE LIMITS (in. air) VAPOR PRESSURE ( DegC): DegC DegC > 250 DegC DegC Volt Not Applicable Not Applicable Decomposes Noc Applicable Wot Applicable DENSITY SPECIFIC GRAVITY 0 : VolV g/cm3 0.92 Not Applicable Solid PRINT DATE: 29 May 2000 Cone. PRODUCT NAME: VISTANEX (K) MM L-100 MSDS NUMBER: PAGE 5 HDHP-J-00303 1 February 2.QQQ VAPOR DENSITY {101.3 kPa/air=l); SOLUBILITY IN WATER ( DegC) ; IS MATERIAL HYGROSCOPIC: VISCOSITY EVAPORATION RATE (n-Bu Acetate* 1) COEFF. OF THERMAL EXPANSION (Lig.) MOLECULAR WEIGHT: CSC DegC Noc Applicable Insoluble Not Applicable Not Applicable Not Applicable 10 STABILITY AND REACTIVITY HAZARDOUS POLYMERIZATION? CONDITIONS TO AVOID POLYMERIZATION; STABILITY: CONDITIONS TO AVOID INSTABILITY: No Applicable Stable Not Applicable MATERIALS AND CONDITIONS TO AVOID (INCOMPATIBILITY) : None HAZARDOUS DECOMPOSITION PRODUCTS: Hydrocarbons 11 TOJCZCOLOGICAL INFORMATION ACUTS: INHALATION: Negligible hazard at ambient temperature (-18 to 38 Deg C) . SKIM CONTACT: No hazard in normal industrial use, Exposure Co hot material may cause thermal burns. EYB CONTACT: Parciculates may ecratch eye surfaces/cause mechanical irritation. INGESTIONt No hazard in normal industrial use. Additional information is available on special request • PRINT DATE: 29 Mav 2000 Cont PRODUCT NAME: VISTANEX(R) MM L-100 MSDS NUMBER: REVISION: SAGE S HDHP-J-00303 1 February 2000 12 ECOLOGICAL INFORMATION __.*_«•*••—— .*_____•.** — — —— — — »*^ — 4— —»'- — ———— — __^ — — — »,-— — •«•— fc»-fc»* -* ^ *• — _ -« ^ .« ** _ .« A .. • * H M •• ^ - 13 DISPOSAL CONSIDERATIONS The following advice only applies to Che product as supplied. Combination with other materials may well indicate another route of disposal. If in doubt, conta.cc local ExxonMobil chemical Company supplier or local Authorities. Empty drums should be taken for recycling, recovery or disposal through a suitably-qualified or licensed contractor. Care should in any case be taken to ensure compliance with national and local regulations. ^^^•———*.^—^^»-^ — *t-^*,^».^— — ta,^^«^^w——— — *-^^.»^— ••*——— — — — ————— — — — —-* — —' — ———————^-*—-* — — 14 TRANSPORT INFORMATION LAND This product is not regulated for road/rail transport SEA - IMDG (PACKAGED GOODS AND BLCa) This produce is noc regulated for sea transport. AIR (ICAO/IA.TA) This product is not regulated for air transport,. -»—••»—^^•-'"<«<»^^«-^^».*>*v—^-.— — H___^^.h«—^———«.^v^..*i-v4v.*<«*-»«—^—^^—^ — 15 REGULATORY INFORMATION1 CIASSIFICATION AMD LABELLING ACCORDING TO StJRO?EAN DIRECTIVES CLASSIFICATION/SYMBOL: NOT REGULATED GOVERNING DIRECTIVE: According to the EC Directives, th« product does not require classification and labelling. PRINT DkTE: 29 May 2000 ~~ ~"~Cent. PRODUCT NAME: VJSTANEXfR) MM L-100 MSDS NUMBER: REVISION: PAGE 7 HDEP-J-Q0303 l February 2000 IS OTHER INFORMATION 1. Applicable grades ate Vistanex REVISION SUMMARY: L-SO, L-100, L-120, L-140, L-1GO. Scrap Since 3 September 1997, Chi3 KSDS has been revised in Section(s) : & THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AfclD MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITS ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE BEST OF ExxonMobil Chemical Company's KNOWLEDGE AND BELIEVED ACCURATE AND RELIABLE AS OF THE DATE INDICATKP. HOWEVER, NO REPRESENTATION, WARRANTY OR GUARANTEE IS MADE A6 TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY AND COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE. PRINT DATE; 29 May 2000 J f( • MATERIAL SAFETY DATA SHEET • EXXON CHEMICAL COMPANY A Division of EXXON CORPORATION PAGE: 1.- / _ *• DATE PREPARED: APR 13, 1396 MSDS NO. ; 84320000 VISTANEX LM = — — — o« •!«= — = a »re = ^^ CM »«K(=s: = = »»»= = = s: = »••« = = =: = = «** — = — —=""E = s=:ata3«**c = ^==:a«««===:=S = SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME; VISTANEX LM CHEMICAL NAME: Polyiaobutylene 9003-27-4 CHEMICAL ' FAMILY : Polyigobutylene PRODUCT DESCRIPTION: CONTACT ADDRESS: EXXON CHEMICAL COMPANY, P.O. BOX 3272, HOUSTON, TEXAS 77253-3272 **EMERGENCY TELEPHONE NUMBERS: (24 Hour?) ** ** CHBMTREC (BOO) 424-9300 ** ** EXXON CHEMICAL COMPANY (800) 726-2015 ** NOW EMERGENCY TELEPHONE NUMBERS : (Bam-Spm M-F) FOR HEALTH AKD SAFETY INFORMATION CALL i (2B1) 970-6884 FOR GENERAL PRODUCT INFORMATION CALL : (281) 970-6000 SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS This product is not hazardous as defined in 29 CFR191Q.1200 SECTION 3 HAZARDS IDENTIFICATION POTENTIAL HEALTH EFFECTS EYE CONTACT: Slightly irritating but does not injure eye tissue. SKIN CONTACT: Low order of toxicity, INHALATION: Negligible hazard at ambient temperature (-19 to 38 Deg C; 0 to 100 Deg F) INGESTION: Minimal toxicity. SECTION 4 FIRST AID MEASURES EYE CONTACT: Flush eyea with large amounts of water'until irritation subsides. If irritation, persists, get medical attention. Continues on page 2 MATERIAL SAFETY DATA SHEET EXXON CHEMICAL COMPANY A Division of EXXON CORPORATION PAGE: 2 DATE PREPARED: APR 13, 1S3S MSDS NO.: B4320000 VISTANEX LM SKIN CONTACT: First aid is normally not required. INHALATION: First aid is not applicable. INQESTION: First aid is normally not required. SECTION 5 FIRE-FIGHTING MEASURES NOTE; Closed cup fl.pt. is 300F NoFAvaTf NOTE: Not Available ,y burn at or above the flashpoint. Commercial use of this product often involves high shear mixing, under these conditions high localized temperatures can be generated, possibly in excess of the closed cup flash point. Care should be taken to ensure that equipment parts are properly grounded to prevent static discharge. The vapor space of closed mixing equipment should be purged with nitrogen. FIRE FIGHTING Use water spray to cool fire exposed surfaces and to protect personnel. Isolate "fuel" supply to fire. Extinguish the fire by cooling with water spray. Avoid spraying water directly into storage containers due to danger of boilover, -•••'. DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS No unusual SECTION S ACCIDENTAL RELEASE MEASURES LAND SPILL Eliminate sources of ignition. Prevent additional discharge of material, if possible to do so without hazard. For small spills implement cleanup procedures; for large spills implement cleanup procedures and, if in public area/ keep public away and advise authorities. Also, if thia product is subject to CERCLA reporting (see Section 15 REGULATORY INFORMATION) notify the National Response Center. Recover spilled material and place in suitable containers for recycle or disposal. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. WATER SPILL Prevent additional discharge of material, if possible to do so without hazard. Advise authorities if floating material enters a watercourse or conrinuea on page 3 MATERIAL SAFETY DATA SHEET EXXON CHEMICAL COMPANY A Division of EXXON CORPORATION PAGE r 4 DATE PREPARED: APR 13; 1996 MSDS NO. : 94320000 VISTANEX LM VISCOSITY OF LIQUID, cSt at Deg F: Not Applicable SP, GRAV. OF VAPOR, at 1 atm (Air-l) : Not Available FREEZING/MELTING POINT, Deg F: Not Applicable EVAPORATION RATE/ n-Bu Acetate=l: Not Applicable S» SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID INSTABILITY: Not Applicable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION: Not Applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY: Strong oxidizing agents HAZARDOUS DECOMPOSITION PRODUCTS; None SECTION 11 TOXICOLOGICAL INFORMATION Please refer to-Section 3 for available information on potential health effects. = = = = ea3Mw«=== = =:Biw™a=c=== = («M«™====:=eTm«««Be= = = = se=a3« «»•« = = === ==a»«*«ict==:=S = a»™««D=====;=== = SECTION 12 ECOLOGICAL INFORMATION No specific ecological data are available for this product. Plaaae refer to Section S for information regarding accidental releases and Section IS for regulatory reporting information. SECTION 13 DISPOSAL CONSIDERATIONS =t»«i«=I==:===eii««1KC=====iW«i== = = ===;»*«===== = = i«i"iii = =====:= = ™"»™™C====^==3'« •«== = = ====""•• «•*•="= Please refer to Sections 5, S and 15 for disposal and regulatory information. SECTION 14 TRANSPORT INFORMATION DEPARTMENT OF TRANSPORTATION (DOT) : This product is not DOT regulated. SECTION 15 REGULATORY INFORMATION TSCA: This product is listed on the TSCA Inventory at CAS Registry Number 9003-27-4 3B»nnc= = := = a HK nic — = = = n »nst = ;= = = = « • ^ c = = = == ™»wi==: = = = = = = **• ===:" = = = = ™ «*>« = —=== = CT™1 Continues on page S MATERIAL SAFETY DATA SHEET EXXON CHEMICAL COMPANY A Division of EXXON CORPORATION PAGE : 3 DATS PREPARED: APR 13, 1396 MSDS NO.; 84320QOQ VI3TANEX LM sewer- If possible, try to contain floating material . Skim from surface. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations, SECTION 7 STORAGE AND HANDLING ====n==s— =*=»«"»»»««»•« W»»»« = E:===s=====5:=:===in^w»»«B===—===:c^»«««« «•« w±3S =======: t==3 ELECTROSTATIC ACCUMULATION HAZARD: Yes, use proper grounding procedure. STORAGE TEMPERATURE, Deg F: Ambient LOADING/UNLOADING TEMPERATURE, Deg F: Arribi ent STORAGE /TRANSPORT PRESSURE, mmHgi Atmospheric LOADING/UNLOADING VISCOSITY, cSt: Not Applicable STORAGE AND HANDLING: Keep container closed. Handle and open containers with. care. Store in a cool, well ventilated place away from incompatible materials Do isfOT handle or store near an open flame, heat or other sources of ignition. Protect material from direct sunlight. Material will accumulate static charges which may cause an electrical apark (ignition source) . Use proper grounding procedures. SECTION B EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE CONTROLS Ventilation should be provided to control worker exposures and prevent health riak. PERSONAL PROTECTION For open systems where contact ia lively, wear safety glasses with aide shields, long sleeves, and chemical resistant gloves. Where contact may occur, wear safety glasses with side shields. Where overexposure by inhalation may occur and engineering, work practice or other means of exposure reduction are noc adequate, approved respirators may be necessary. EXPOSURE GUIDELINES: No workplace exposure limits have been established for this product. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES SPECIFIC GRAVITY at Deg F: 0.92 at SB VAPOR PRESSURE, mmHg at Deg F: 0 at 100 Maximum SOLUBILITY I1T WATER, wt , %• at Deg 51 : Negligible Continues on page MATERIAL SAFETY DATA SHEET EXXON CHEMICAL COMPANY A Division of EXXON CORPORATION PAGE: DATS PREPARED: MSDS NO,; APR 13, 1996 8432QQQQ VISTANEX LM CSRCLA; If this product ia accidentally spilled; it is not subject to any special reporting under the requirements of the Comprehensive Environmental Response, Compensation and Liability Act. We recommend you contact local authorities to determine if there may be other local reporting requirements. SARA TITLE III: Under the provisions of Title III, Sections 311/312 of the Superfund Amendments and Reauthorization Act, this product is claaaified into the following hazard categories: Not Hazardous. SECTION 16 OTHER INFORMATION This MSDS is applicable to the following grades: Vistanex LM-MS-LC, -MH-LC, H-LC, .-NS -S, -MS, -MH, -H, -MISC REVISION SUMMARY; Since September 26, 1935 this MSDS has been revised in Section(a): REFERENCE NUMBER: HDHA-M-Q030T SUPERSEDES ISSUE DATS: September 26, 1935 This information relates to the specific material designated and may not be valid for such, material used in combination with any other materials or in any process. Such information is to the beat of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee ia made as to its accuracy, reliability or completeness. It is the users responsibility to satisfy himself as to the suitability and completeness of such information far his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer warranty against patent infringement. LAST PAGE nhoimwi P ' " T -"••"•.PRODUCTS INC SSSSS Product Information (203) 740-3471 / Emergency Assistance CHEMTREC 1-800-424-9300 MATERIAL SAFETY DATA SHEETS SECTION I PRODUCT AND COMPANY IDENTIFICATION Product: Ethyl Acetate This MSDS is valid for all grades and catalog #'s Synonyms: Acetic acid ethyl ester; ethyl ethane-ate; ethyl acetic ester Formula: CH3COOC2H5 Manufacturer: Pharmco Products Inc. 58 Vale Road Brookfield, Connecticut 06804, USA Phone (203) 740-3471 Fax (203) 740-3481 Emergency Contact: CHEMTREC 1-8QQ-424-9300 SECTION II COMPOSITION /INFORMATION ON INGREDIENTS Exposure %wt Material CAS Limits 100%Ethyl Acetate 141-78-6 400ppm- OSHA/PEL; ACGIH/ TLV SECTION HI HAZARDS IDENTIFICATION Routes of Exposure: Swallowing: May cause headache, nausea, vomiting, dizziness , gastrointestinal irritation Skin Absorption: Not identified Inhalation: Irritation of nose and throat, headache, nausea, vomiting, narcosis, respiratory failure, low blood pressure, central nervous system depression. Skin Contact: May cause irritation Eye Contact: May cause irritation including stinging, tearing, and redness Effects of Repeated Overexposure: May result in the development of kidney, liver, heart, or lung damage and/or central nervous system depression Other Health Hazards: None currently known Medical Conditions Aggravated by Overexposure: Skin contact may aggravate an existing dermatitis. Respiratory system disease and anemia may be aggravated by exposure. SECTION IV FIRST AID Obtain medical attention for all cases of over-exposure. Swallowing: If patient is fully conscious, induce vomiting. Obtain medical attention. Skin: Wash skin with soap and water for at least 15 minutes Inhalation: Remove to fresh air; Give artificial respiration if not breathing; If breathing is difficult oxygen may be given by qualified personnel; Obtain medical assistance is discomfort persists. Eye Contact: Flush eyes with water for at least 15 minutes. Obtain medical attention. SECTION V FIRE FIGHTING MEASURES Fire/Explosive Properties Flammable Limits in Air: 2.2 - 11.0% (by volume) NFPARating: Health 1 Fire 3 Reactivity 0 1996 North American Emergency Response Guidebook: Guide 129 Extinguishing Media: Apply alcohol-type or all-purpose foam by manufacturer's recommended techniques for large fires. Use carbon dioxide or dry chemical media for small fires. Special Fire Fighting Procedures: Use water spray to cool fire-exposed containers and structures; Use water spray to disperse vapors - re-ignition is possible; Use self-contained breathing apparatus and protective clothing. Unusual Fire and Explosion Hazards: * Vapors may travel to source of ignition and flash back. » Vapors may settle in low or confined spaces. » May produce a floating fire hazard. « Static ignition hazard can result from handling and use. SECTION VI SPILL/ACCIDENTAL RELEASE MEASURES All spills: Eliminate all ignition sources; ground all equipment; do not walk through spill; stop spill if possible; prevent entry into sewers, confined spaces, etc.; use a vapor suppressing foam to reduce vapors; absorb spill with non-combustible matter and transfer to containers; use non-sparking tools to collect absorbed material. MSDS 061, Revision 2.0 / Revision Date 12/18/01 JC Ethyl Acetate/ Page 1 of 2 SECTION VII HANDLING AND STORAGE * Flammable material - keep away from heat, sparks, and flame; sudden releases of hot organic vapors or mists from process equipment operating at elevated temperature may result in ignitions without the presence of obvious ignition sources. * Avoid contact with eyes. * Keep container closed. * Use with adequate ventilation. » Ground container when transferring product. * Vapors may collect in containers; treat empty containers as hazardous. » Wash thoroughly after handling * Vapors may settle in low or confined areas SECTION VIII EXPOSURE CONTROLS / PERSONAL PROTECTION Ventilation: Special, local ventilation is needed where vapors escape to the workplace air Respiratory Protection: Use self-contained breathing apparatus in high vapor concentration Personal Protective Equipment: gloves, lab coat or uniform, safety glasses, eye wash, safety shower SECTION IX PHYSICAL AND CHEMICAL PROPERTIES Odor: characteristic Vapor pressure @ 20C: 76 mm Hg Vapor density: 3.0 (air =1) MeltingPoTnt: -84C (-119F) Solubility in Water: Moderate (1-10%) @ 20C Density @25C: .8942 g/ml Evaporation Rate: 4.1 (butyl acetate = 1) Percent Votatiles: 100% SECTION X STABILITY/REACTIVITY INFORMATION Stability: Stable Conditions to avoid: Heat, flame, etc. Incompatibility/Materials to avoid: strong oxidizing/reducing agents; strong inorganic acids/bases; alkalies Hazardous Combustion/Decomposition Products: Carbon monoxide and/or carbon dioxide Hazardous Polymerization: Will not occur SECTION XI DISPOSAL CONSIDERATIONS Vapors may collect in empty containers. Treat empty containers as hazardous. Dispose of spill-clean up and other wastes in accordance with Federal, State, and local regulations. SECTION XII TRANSPORTATION INFORMATION Proper Shipping Name: Ethyl Acetate Hazard Class: 3 UN Number: 1173 RQ: 50001bs Packaging Group II IMO Information: Ethyl Acetate Label of Class: 3.2 Packaging Group II Intermediate flashpoint group SECTION XIII REGULATORY INFORMATION Federal EPA Comprehensive Environmental Response Compensation, and Liability Act of 1980 (CERCLA) requires notification of the National Response Center of release quantities of Hazardous Substances equal to or greater than the reportable quantities (RQs) in CFR. Components present in this product at a level which could require reporting under this statute are: Chemical CAS Number Upper Bound Cone. % Ethyl Acetate 141-78-6 100% Superfund Amendments and Reautborization Act of 1986 (SARA) Title III requires emergency planning based on threshold planning quantities and release reporting based on reportable quantities in 40 CFR 355 (used for SARA 302, 304, 311, and 312). Components present in this product at a level which could require reporting under this statute are: Not available Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). This information must be included in all MSDS's that are copied and distributed for this material. Components present in this product at a level which could require reporting under the statute are: None. Toxic Substances Control Act (TSCA) Status: The ingredients of this product are on the TSCA inventory. State Right to Know This product contains ethyl acetate (CAS 141-78-6) upper bound concentration 100% which may be listed as a hazardous substance by individual states. California SCAQMD Rule 443.1 VOC's: Not available The information contained herein is based on data considered to be accurate. However, no warranty is expressed regarding the accuracy of these data or the results to be obtained from the use thereof. It is the user's obligation to determine the conditions of safe use of the product. MSDS 061, Revision 2.0 / Revision Date 12/18/01 JC Ethyl Acetate/Page 2 of 2 phornvcQ ^ , - """"•••' .'..PRODUCTS INC :=:;•:::::; Product Information (203) 740-3471 / Emergency Assistance CHEMTREC 1-800-424-9300 MATERIAL SAFETY DATA SHEETS SECTION I PRODUCT AND COMPANY IDENTIFICATION Product: 200 Proof Ethyl Alcohol USP/ACS/EP/Grain/Synthetic/Kosher This MSDS is valid for all grades and catalog #'s Synonyms: Ethyl Alcohol Absolute; Dehydrated Ethanol; Anhydrous Ethanol, Methylated Spirits Formula: CH3CH2OH Manufacturer: Pharmco Products Inc. 58 Vale Road Brookfield, Connecticut 06804, USA Phone (203) 740-3471 Fax (203) 740-3481 Emergency Contact: CHEMTREC 1-800-424-9300 SECTION II COMPOSITION /INFORMATION ON INGREDIENTS Exposure %wt Material CAS Limits 100%Ethanol 64-17-5 lOOOppm TWA SECTION III HAZARDS IDENTIFICATION Carcinogen Status: Not classifiable as a human carcinogen Routes of Exposure: Swallowing: May cause dizziness, faintness, drowsiness, decreased awareness or responsiveness, nausea, vomiting, staggering gait, lack of coordination, and coma Skin Absorption: No harmful affects with normal skin. Inhalation: High vapor concentration may cause burning sensation in nose and throat and stinging and watering in the eyes. At concentrations which cause irritation, dizziness, faintness, drowsiness, nausea and vomiting may also occur. Skin Contact: No evidence of harmful effects from available information. Eye Contact: May cause irritation including stinging, tearing, and redness Effects of Repeated Overexposure: Long term repeated oral exposure to ethanol may result in the development of progressive liver injury with fibrosis Other Health Hazards: Repeated ingestion of ethanol by pregnant mothers has been shown to adversely affect the central nervous system of the fetus, producing a collection of effects which together constitute fetal alcohol syndrome. These include mental and physical retardation, disturbances of learning, motor and language deficiencies, behavioral disorders and small size head. Medical Conditions Aggravated by Overexposure: Repeated exposure to ethanol may aggravate liver injury produced from other causes. SECTION IV FIRST AID Obtain medical attention for all cases of over-exposure. Swallowing: If patient is fully conscious, give two glasses of water. Induce vomiting. Obtain medical attention. Skin: Wash skin with soap and water for at least 15 minutes Inhalation: Remove to fresh air; Give artificial respiration if not breathing; If breathing is difficult oxygen may be given by qualified personnel; Obtain medical assistance is discomfort persists. Eye Contact: Flush eyes with water for at least 15 minutes. Note to Physician: Symptoms vary with alcohol level of the blood. Mild alcohol intoxication occurs at blood levels between 0.5-.15%. Approximately 25% of individuals show signs of intoxication at these levels. Above .15% the person is definitely under the influence of ethanol; 50-95% of individuals are clinically intoxicated at these levels. Severe poisoning occurs when die blood is ethanol level is 0.3- 0.5%. Above 0.5% the individual will be comatose and death can occur. The unabsorbed ethanol should be removed by gastric lavage after intubating the patient to prevent aspiration. Avoid the use of depressant drugs or the excessive administration of fluids. SECTION V FIRE FIGHTING MEASURES Fire/Explosive Properties Flash Point: (21C)Tag Open Cup Flammable Limits in Air: 3.3 - 19.0% (by volume) Flammability Classification: 3 (NFPA) 1993 Emergency Response Guidebook: Guide 26 1996 North American Emergency Response Guidebook: Guide 127 Extinguishing Media: Apply alcohol-type or all-purpose foam by manufacturer's recommended techniques for large fires. Use carbon dioxide or dry chemical media for small fires. Special Fire Fighting Procedures: Use water spray to cool fire-exposed containers and structures; Use water spray to disperse vapors - re-ignition is possible; Use self-contained breathing apparatus and protective clothing. Unusual Fire and Explosion Hazards: » Vapors may travel to source of ignition and flash back. . Vapors may settle in low or confined spaces. * May produce a floating fire hazard. * Static ignition hazard can resuit from handling and use SECTION VI SPILL/ACCIDENTAL RELEASE MEASURES Small spills can be flushed with large amounts of water. Large spills: Eliminate all ignition sources; ground all equipment; do not walk through spill; stop spill if possible; prevent entry into sewers, confined spaces, etc.; use a vapor suppressing foam to reduce vapors; absorb spill with non- combustible matter and transfer to containers; use non- sparking tools to collect absorbed material. ^ MSDS 006, Revision 2.0/ Revision Date 12/18/011C Ethanol 200 Proof/ Page 1 of 2 SECTION VII HANDLING AND STORAGE * Flammable material - keep away from heat, sparks, and flame; sudden releases of hot organic vapors or mists from process equipment operating at elevated temperature may result in ignitions without the presence of obvious ignition sources. « Avoid contact with eyes. » Keep container closed. » Use with adequate ventilation. » Ground container when transferring product. * Vapors may collect in containers; treat empty containers as hazardous. » Wash thoroughly after handling * Vapors may settle in low or confined areas SECTION V1I1 EXPOSURE CONTROLS / PERSONAL PROTECTION Ventilation: Special, local ventilation is needed where vapors escape to the workplace air Respiratory Protection: Use self-contained breathing apparatus in high vapor concentration Personal Protective Equipment: gloves, lab coat or uniform, safety glasses, eye wash, safety shower SECTION IX PHYSICAL AND CHEMICAL PROPERTIES Appearance: clear, colorless liquid Odor: characteristic Vapor pressure @ 20C: 44.6 mm Hg Vapor density: 1.6 (air =1) Boiling point @ 760mm Hg: 78.3C (172.9F) Freezing Point: -114.1C (-173.4F) Solubility in Water: 100% @ 20C Specific Gravity : .7906 @ 20/20C Density @ 15.56C (60F) 6.611bs/gal Evaporation Rate: 3.3 (butyl acetate = 1) Percent Volatiles: 100% SECTION X STABILITY/REACTIVITY INFORMATION Stability: Stable Conditions to avoid: None known Incompatibility/Materials to avoid: strong oxidizing agents; strong inorganic acids Hazardous Combustion/Decomposition Products: Carbon monoxide and/or carbon dioxide Hazardous Polymerization: Will not occur SECTION XI DISPOSAL CONSIDERATIONS Vapors may collect in empty containers. Treat empty containers as hazardous. Dispose of spill-clean up and other wastes in accordance with Federal, State, and local regulations. SECTION XII TRANSPORTATION INFORMATION Proper Shipping Name: Ethyl Alcohol Hazard Class: 3 UN Number: 1 170 IMO Information: Ethanol or ethanol solutions Label of Class: 3 uroupTl Intermediate flashpoint group SECTION XIII REGULATORY INFORMATION Federal EPA Comprehensive Environmental Response Compensation, and Liability Act of 1980 (CERCLA) requires notification of the National Response Center of release quantities of Hazardous Substances equal to or greater than the reportable quantities (RQs) in CFR. Components present in this product at a level which could require reporting under this statute are: Chemical CAS Number Upper Bound Cone. % Acetone 67-64-1 .0002 Methanol 67-56-1 - .0150 Acetaldehyde 75-07-0 .0020 Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning based on threshold planning quantities and release reporting based on reportable quantities in 40 CFR 355 (used for SARA 302, 304, 311, and 312). Components present in this product at a level which could require reporting under this statute are: none. Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). This information must be included in all MSDS's that are copied and distributed for this material. Components present in this product at a level which could require reporting under the statute are: none. Toxic Substances Control Act (TSCA) Status: The ingredients of mis product are on the TSCA inventory. State Right to Know California Proposition 65: This product contains trace levels of acetaldehyde known to the State of California to cause cancer. Massachusetts: Hazardous substances and extraordinarily hazardous substances must be identified. Components present which could require reporting: Extraordinarily Hazardous (=> 0.0001%): Acetaldehyde (CAS 75-07-0) upper bound cone. .0020% Hazardous (=>!%): Ethanol (CAS 64-17-5) upper bound cone. 100% Pennsylvania: Hazardous substances must be identified. Hazardous (=>!%): Ethanol upper bound cone. 100% California SCAQMD Rule 443.1 (VOC's) A Volatile Organic Compound (VOC) is any volatile compound of carbon excluding methane, carbon monoxide, carbonic acid, metallic carbides, or carbonates, ammonium carbonate, 1,1,! tri-ckloroetkane, methylene chloride. (FC-23), (CFC-ll 3). (CFC-I2), (CFC-ll), (CFC-22), (CFC- 114) and (CFC-ll5). VOC 790g/l; vapor pressure 44.6 mm Hg @20C The information contained herein is based on data considered to be accurate. However, no warranty is expressed regarding the accuracy of these data or the results to be obtained from the use thereof. It is the user's obligation to determine the conditions of safe use of the product. MSDS 006, Revision 2.0 / Revision Date 12/18/01 JC Ethanol 200 Proof/ Page 2 of 2 99 I fa* * II pharixvco p. - '"' ':PRODUCTS IHC S-.T::.;::.; Product Information (203) 740-3471 / Emergency Assistance CHEMTREC 1-800- 424-9300 or 202-483-7616 MATERIAL SAFETY DATA SHEETS Part Number/Trade Name: TOLUENE This MSDS is valid for all grades and catalog numbers General Information Company's Name: PHARMCO PRODUCTS, INC. Company's Street: 58 VALE RD. Company's City: BROOKFIELD Company's State: CT Company's Zip Code: 06804 Company's Emerg Ph #: (203) 740-3471 Company's Info Ph #: (203) 740-3471 Date MSDS Revised: Nishant-1/21/02 Safety Data Review Date: 8/23/99 Preparer's Company: PHARMCO PRODUCTS, INC. Preparer's St Or P. O. Box: 58 VALE RD. Preparer's City: BROOKFIELD Preparer's State: CT Preparer's Zip Code: 06804 Ingredients/Identity Information Proprietary: NO Ingredient: TOLUENE (SARA El) Ingredient Sequence Number: 01 Percent: >60 NIOSH (RTECS) Number: XS5250000 CAS Number: 108-88-3 OSHA PEL: 200 PPM/150 STEL ACGIH TLV: 50 PPM; 9293 Physical/Chemical Characteristics Appearance And Odor: COLORLESS, BENZENELIKE ODOR Boiling Point: 232F Vapor Pressure (MM Hg/70 F): 38 Vapor Density (Air=l): 4.5 Specific Gravity: 0.871 Evaporation Rate And Ref: 4.5,ETHER Solubility In Water: NEGLIGIBLE Percent Volatiles By Volume: 100 Fire and Explosion Hazard Data Flash Point: 40F TCC. Lower Explosive Limit: 1.2 Upper Explosive Limit: 7.0 Extinguishing Media: DRY CHEMICAL,REGULAR FOAM,WATER FOG,CARBON DIOXIDE Special Fire Fighting Proc: SELF-CONTAINED BREATHING APPARATUS WITH FULL MSDS 166, Rev 2.0; Revision Date 12/19/01 JC Toluene/Page 1 of 3 FACEPIECE Unusual Fire And Expl Hazrds: VAPORS MAY TRAVEL ALONG THE GROUND & CAUSE FLASH FIRES OR BE IGNITED BY PILOT LIGHTS,FLAMES,SPARKS. Reactivity Data Stability: YES Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS Hazardous Decomp Products: CO*2,CO WHEN BURNED Hazardous Poly Occur: NO Health Hazard Data Signs/Symptoms Of Overexp: EYES: SEVERE IRRITATION.SKIN:MODERATE IRRITATION, DEFATTING.BREATHING: NASAL& RESPIRATORY IRRITATION Emergency/First Aid Proc: SKIN: WASH AREA WITH SOAP & WATER.REMOVE CONTAMINATED CLOTHING-WASH BEFORE RE-USE.EYES: FLUSH WITH LARGE AMTS OF WATER.SWALLOWED: DONOT INDUCE VOMITING, KEEP PERSON WARM,QUIET,GET MEDICAL ATTENTION.BREATHED: REMOVE TO FRESH AIR.KEEP PERSON WARM, QUIET Precautions for Safe Handling and Use Steps If Matl Released/Spill: SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT & TRANSFER TO HOOD.LARGE SPILL: ELIMINATE ALL IGNITION SOURCES.EXCLUDE PEOPLE FROM AREA NIOT WEARING PROTECTIVE EQUIPMENT.STOP SPILL AT SOURCE.RESIDUAL LIQUID MAY BE TAKEN UPON SAND, CLAY Waste Disposal Method: SMALL SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN DESTROY BTY LIQUID INCINERATION UNDER CONTROLLED CONDITIONS .MATERIAL COLLECTED ON ABSORBENT MATERIAL MAY BE DEPOSITED IN LANDFIL Precautions-Handling/Storing: PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. OUTDOOR OR DETACHED STORAGE IS PREFERABLE.I Other Precautions: WEAR CHEMICAL GOGGLES, CHEMICAL CARTRIDGE RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS & RUBBER GLOVES, Control Measures Respiratory Protection: NIOSH/MESA JOINTLY APPROVED SELF-CONTAINED BREATHING APPARATUS Ventilation: AS REQUIRED TO CONTROL TLV IN AIR Protective Gloves: BUNG-N GLOVES Eye Protection: CHEMICAL SPLASH GOGGLES Other Protective Equipment: WEAR IMPERVIOUS CLOTHING & BOOTS Suppl. Safety & Health Data: SWALLOWING: STOMACH IRRITATION, NAUSEA, VOMITING, DIARRHEA, CHEMICAL PNEUMONITIS (FATAL). SELF CONTAINED BREATHING APPARATUS MUST BE OPERATED IN A PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. MSDS 166, Rev 2.0; Revision Date 12/19/01 JC Toluene/Page 2 of 3 Transportation Data Trans Data Review Date: 83094 DOT PSN Code: OJY DOT Proper Shipping Name: TOLUENE DOT Class: 3 DOT ID Number: UN 1294 DOT Pack Group: II DOT Label: FLAMMABLE LIQUID IMO PSN Code: OSR IMO Proper Shipping Name: TOLUENE IMO Regulations Page Number: 3285 IMO UN Number: 1294 IMO UN Class: 3.2 IMO Subsidiary Risk Label: - IATA PSN Code: YEL IATA UN ID Number: 1294 IATA Proper Shipping Name: TOLUENE IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID AFI PSN Code: YEL API Prop. Shipping Name: TOLUENE AFI Class: 3 AFI ID Number: UN 1294 AFI Pack Group: H AFI Label: FLAMMABLE LIQUID AFI Basic Pac Ref: 7-7 Disposal Data Landfill Ban Item: YES Disposal Supplemental Data: SWALLOWING: STOMACH IRRITATION, NAUSEA, VOMITING, DIARRHEA, CHEMICAL PNEUMONITIS (FATAL). SELF CONTAINED BREATHING APPARATUS MUST BE OPERATED IN A PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. IN CASE OF ACCIDENTAL EXPOSURE OR DISCHARGE, CONSULT HEALTH AND SAFETY FILE FOR PRECAUTIONS. 1st EPA Haz Wst Code New: U220 1st EPA Haz Wst Name New: TOLUENE; METHYLBENZENE 1st EPA Haz Wst Char New: TOXIC (T) 1 st EPA Acute Hazard New: NO 2nd EPA Haz Wst Code New: D001 2nd EPA Haz Wst Name New: IGNITTBLE 2nd EPA Haz Wst Char New: IGNTTABILrrY 2nd EPA Acute Hazard New: NO Label Data Label Required: YES Label Status: F Special Hazard Precautions: MAY BE POISONOUS IF INHALED OR ABSORBED THROUGH SKIN. VAPORS MAY CAUSE DIZZINESS OR SUFFOCATION. CONTACT MAY IRRITATE OR BURN SKIN AND EYES. FIRE MAY PRODUCE IRRITATING OR POISONOUS GASES. RUNOFF FROM FIRE CONTROL OR DILUTION WATER MAY CAUSE POLLUTION. The information contained herein is based on data considered to be accurate. However, no warranty is expressed regarding the accuracy of these data or the results to be obtained from the use thereof. It is the user's obligation to determine the conditions of safe Use of the product. MSDS 166, Rev 2.0; Revision Date 12/19/01 JC Toluene/Page 3 of 3 Material Safety Data Sheet NFPA ^> HMIS Personal Protective Equipment t^pfsg^^^^^^^^m. A JUS Reactivity Q 9t See Section 15. Section 1. Chemical Product and Company Identification Page Number: 1 common Name/ Isopropyl myristate Manufacturer spECTR(JM CHEM|CAL MFQ QQRp 14422 S. SAN PEDRO STREET GARDENA, CA 90248 Commercial Name(s) Not available. Synonym TetradecarKjj^BIL 1-methylethyl ester Chemical Name Not available. Chemical Family Not available. Chemical Formula CH3(CH2)1 2COOCH(CH3}2 Catalog ,S145 Number(s). CAS# 110-27-0 RTECS XB8600000 TSCA TSCA 8(b) inventory: Isopropyl myristate CI# Not available. IN CASE OF EMERGENCY CHEMTREC (24hr) 800-424-9300 CALL (31 0)51 6-8000 Supplier SPECTRUM CHEMICAL MFG. CORP. 14422 S. SAN PEDRO STREET GARDENA, CA 90248 Section 2.Composition and Information on Ingredients Exposure Limits Name 1 ) Isopropyl myristate CAS# TWA (mg/m3) 110-27-0 STEL (mg/m3) CEIL (mg/nvl) % by Weight . 100 Toxicologies) Data Isopropyl myristate on Ingredients LD50: Not available. LC50: Not available. Section 3. Hazards Identification Potential Acute Health Effects Hazardous in case of eye contact (irritant), of ingestion. Slightly hazardous in case of skin contact (irritant, permeator), of inhalation. Potential Chronic Health CARCINOGENIC EFFECTS: Not available. Effects MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICfTY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition. J Continued on Next Page ^•Aw^^^^^^^^^^^^^^^^^^^^^B^^^^^^^^^^Bh^b.M I Isopropyl myristate Page Number: 2 Section 4. First Aid Measures Eye Contact Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention. Skin Contact After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. 8e particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. Serious Skin Contact Not available. Inhalation Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Serious Inhalation Not available. Ingestion Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Serious Ingestion Not available. Section 5. Fire and Explosion Data Flammability of the Product May be combustible at high temperature. Auto-Ignition Temperature Not available. Flammable Limits Not available. Products of Combustion These products are carbon oxides (CO, CO2). Fire Hazards in Presence of Not available. Various Substances Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available, of Various Substances Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media SMALL FIRE: Use DRY chemical powder. and Instructions LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Special Remarks on Not available. Fire Hazards Special Remarks on Explosion Not available. Hazards Section 6. Accidental Release Measures Small Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal. arge Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. I Continued on Next Page" Isopropyf myristate Page Number: 3 Section 7. Handling and Storage Precautions Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not breathe gas/fumes/ vapour/spray. Avoid contact with eyes Wear suitable protective clothing If you feel unwell, seek medical attention and show the label when possible. Storage Keep container dry. Keep in a coot place. Ground all equipment containing material. Keep container tightly closed. Keep in a cod, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing agents. Section 8. Exposure Controls/Personal Protection Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal Protection Splash goggles. Lab coat. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a a Large Spill specialist BEFORE handling this product. Exposure Limits Not available. Section 9. Physical and Chemical Properties Molecular Weight pH(l%soln/water) Melting Point 270.45 g/mole Not applicable. Odor Not available. Taste Not available. Color Not available. 3°C (37.4'F) Critical Temperature Not available. Specific Gravity 0.8532 (Water = 1) Vapor Pressure Not available. Vapor Density Not available. Volatility Not available. Odor Threshold Not available. Water/Oil DisL Coeff.Not available. lonicity (in Water)Not available. Dispersion Properties See solubility in water, methanol, acetone. Solnbilitv Soluble in acetone. Partially soluble in methanol. Insoluble in cold water. 1 Continued on Next Page- I Isopropyl myristate Page Number: 4 Section 10. Stability and Reactivity Data Stability Instability Temperature Conditions of Instability The product is stable. Not available. Not available. Incompatibility with various Not available. substances Corrosivitv Non-corrosive in presence of glass. Special Remarks on Reactivity Special Remarks on Corrosivitv Polvmerization Not available. Not available. No. Section 11. Toxicological Information Routes of Entry Eye contact. Ingestion. Toxicitv to Animals LD50: Not available. LC50: Not available. Chronic Effects on Humans Not available. Other Toxic Effects on Humans Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant, permeator), of inhalation. Special Remarks on Not available. Toxicitv to Animals Special Remarks on Chronic Effects on Humans Not available. Special Remarks on other Not available. Toxic Effects on Humans Section 12. Ecological Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicitv of the Products of Biodegradation The products of degradation are more toxic. Special Remarks on the Not available. Products of Biodegradation I Continued on Next Page Isopropyl myristate Page Number: 5 Section 13. Disposal Considerations Waste Disposal Section 14. Transport Information DOT Classification Not a DOT controlled material {United States). Identification Not applicable. Special Provisions for Transport Not applicable. DOT (Pictograms) Section 15. Other Regulatory Information and Pictograms Federal and State Regulations TSCA 8{b) inventory: Isopropyl myristate Lauiomia reposition 65 arnings prop. DO. i nis product contains ine roiiowing ingreaierus TCT wnicn me iiaie or oaiiiornia nas Touna to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. Other Regulations Not available. Other Classifications WHMIS (Canada) Not controlled under WHMIS (Canada). DSCL (EEC)R36- Irritating to eyes. (U.S.A.)National Fire Protection Association (U.S.A.) Health WHMIS (Canada) (Pictograms) DSCL (Europe) (Pictograms) TDG (Canada) (Pictograms) }Continued on Next Page— — Isopropyl myristate Page Number: 6 \ ADR (Europe) X""1^ (Pictograms) /XyC\ Protective Equipment /41%i/a ^ 9 Not applicable. Lab coat. Not applicable. Splash goggles. Section 16. Other Information MSDS Code P4780 References Not available. Other Special N^ available. Considerations Validated by Sonia Owen on 1/20/2003. CALL (310) 516-8000 Notice to Reader Verified by Sonia Owen. Printed 1/22/2003. All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product a combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable. Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein. LOGKWOOD GREENE A J.A. JONES COMPANY ENGINEERING & CONSTRUCT! 0 N Job Name Subject Long Beach HhSlMJTSO Job. No. Sheet No. Date Computed By Checked By V/Jutt* 21732. Oooe; O Si TNf e g S «5»*ii c v/yrw \MuLr: ^ .5 A •? f.44) ^ f>QO44Kjj W =: y ) TO LG FORM 47A (3/01) bOCKWOOD GREENE A JA JONES COMPANY ENGINEERING & CONSTRUCT! ON Long Beach Job Name Subject Job. No. Sheet No. Date Computed By Checked By 42o - c SUING 4&1 >*!Pi 18'-°' A- A>* T M - LG FORM 47A (3/01) bOCKWOOD GREENE*,, ENGINEERING & CO NSTRUCTI 0 N Long Beach Job Name {-/iS/tA^TTM fM& . Subject Job. No. Sheet No. Date Computed By Checked By /2/Z oo ~ 1 -2 17-4 LG FORM 47A (3/01) bOCKWOOD GREENE - A J.A, JONES COMPANY - ENGINEERING & CONSTRUCT! ON Long Beach Job Name Subject Job. No. Sheet No. Date Computed By Checked By <=f" ^ /4 v 3 14 A c ,oi»ofi ?-»?- a10 " 17 LG FORM 47A (3/01) LOCKWOOD GREENE A J.A. JONES COMPANY ENGINEERING & CON STRUCT! ON Job Name Subject Long Beach -)4t5/lAfrtu Vftubr Job. No. Sheet No. Date Computed By Checked By s* - £$0*1 I&D CVt * 8ft if ^ ' -7 * 47,5 LG FORM 47A (3/01) bOCKWOOD GREENE A J.A. JONES tDMPAHY ENGINEERING 5C0NSTRUCT I 0N Long Beach Job Name Subject WuLT Job. No. Sheet No. Date Computed By Checked By 4>gQ (0 ° C ^ LG FORM 47A (3/01) LOCKWOOD GREENE - -A J.A. JONES COMPANY - ENGINEERING & CONSTRUCTION Long Beach "7 Job Name Subject \tftV I T~ Job. No. Sheet No. Date it/loo Computed By Checked By -\ ' rtf* A"* iff* n-*** in $-<>- QIC Y.\ \ ~ .33) - LG FORM 47A (3/01) LiOGKWOOD GREENE — A J.A. JONES COMMHV ENGINEERING & CONSTRUCT! ON Long Beach & Job Name Subject VfojUT Job. No. Sheet No. Date Jl/lsoj Computed By Checked By 3 k/1 10 IP* x 3-.?M7lf/d f 0 ) = -x = £732 . j-'j - ,59 - s^*******.^ LG FORM 47A (3/01) LOCKWOOD GREENE - A J.A. JONES COMPANY - ENGINEERING & CONSTRUCT! ON Long Beach Job Name Subject ULT_ Job. No. Sheet No. Date Computed By Checked By 9 \ "7 /gv£ 9 4--2-7^.7. 278.7 PL CLO LG FORM 47A (3/01) L.OGKWOOD GREENE - A J.A. JONES COMPANY - ENGINEERING & CONSTRUCT! ON Long Be^ch Job Name Subject Job. No. Sheet No. t Date 12/2 Computed By p£<£ Checked By Q - o PL SI - = 330,7 f~ JA 33.OK D fw- ( 4) LG FORM 47A (3/01) ^ffik UOGKWOOD GREENE VSjGf ENGINEERING & CONSTRUCTION Long Beach Job Name M- 1 5j&M / TSO PM9 £ M Subject V#ui r Job. No. ^ Sheet No. Date / Computed By ! Checked By v I'/Zoafy 3c& r-fl Iff * • • c e^^— ^^-F D £• j^^, ^(^ ^V DC^-V LG FORM 47A (3/01) LOGKWOOD GREENE - A J.A. JONES COMPANY - ENGINEERING & CONSTRUCT! ON Long Beach I1 Job Name Subject Job. No. Sheet No. Date Il'hao4 Computed By Checked By <J/A»o - . 76 ^ * 13/1 B f c - -35 I3.o (1.0 f - >- (1.3 5y=o •f D 0*4 14*1 ) LG FORM 47A (3/01) L.OCKWOOD GREENE A J.A. JONES COMPANY ENGINEERING & CONSTRUCT! ON Long Beach Job Name Subject Job. No. Alto-tip Sheet No. Date Computed By Checked By LG FORM 47A (3/01) LOGKWOOD GREENE - A J.A. JONES COMPANY - ENGINEERING & CON5TRU CTI ON Long Beach Job. No. Sheet No. Date Job Name Subject Computed By QC6 Checked By ojc ? ft T& K)AU_- 1-& I "10 pool-' ftwob} - 1 LG FORM 47A (3/01) LOCKWOOD GREENE A J.A. JONES COMPANY ENGINEERING & CONSTRUCT! ON Long Beach Job Name j^S/3 1^ tSu Subject Job. No. Sheet No. Date PC-£, Computed By Dee. Checked By V/OOO 3C(1&W5 7-0 #00^ </5t wAw — / -4s LG FORM 47A (3/01) UOCKWOOD GREENE - A J.A. JONES COMPANY - ENGINEERING & CONSTRUCTION Long Beach Job Name Subject Job. No. Sheet No. Date Computed By Checked By CoDe; iool A/2* c/9 ^ /• c:c/-7, /& vy/rw ro LG FORM 47A (3/01) IjQCKWOOD GREENE - A J.A. JONES COMPANY - ENGINEERING & CONSTRUCT! ON Long Beach Job Name Subject Job. No. 420 - Sheet No. < Computed By Checked By C&1UNG l8-o' I = 1oo = \\0 LG FORM 47A (3/01) L.OGKWQOD GREENE A J.A. JONES COMPANY ENGINEERING & CONSTRUCT! ON Long Beach Job Name Subject Job. No. Sheet No. S Date /2/?oo Computed By DC€ Checked By f&i —~^—^t«~l-r_H'_ -vujK^ LG FORM 47A (3/01) IjOCKWOOD GREENE - A J.A. JONES COMPANY - ENGINEERING & CO N STRUCTION Long Beach Job Name Subject Job. No. Sheet No. Date Computed By Checked By 4" J/'4 3 2, Iv M !i!£!Ls22—1 <5/C 49 « -~HV LG FORM 47A (3/01) UOCKWOOD GREENE J°b N° A J.A. JOHES COMPANY ENGINEERING & CONSTRUCTI ON Sheet No. 5 Long Beach Date Job Name lSAfinrSu PHtol. Computed By Subject Vftubr Checked By CU V, ,/Zo Ft) ew PO <? 81 LG FORM 47A (3/01) UDCKWOOD GREENE A JJl. JONES COMPANY ENGINEERING & CONSTRUCT! ON Long Beach Job Name Subject Job. No. Sheet No. Date Computed By Checked By G* D6& 0 ( 10 6v (l tt>f2-4 )( 83 LG FORM 47A (3/01) U3GKWOOD GREENE A J.A. JONES COMPMTf ENGINEERING & CONSTRUCTION Long Beach Job. No. Sheet No. Date *7 Job Name Subject Computed By QC& Checked By _____ 4' Its ;* eit " LG FORM 47A (3/01) Job Name Subject bOGKWOQD GREENE ENGINEERING & CONSTRUCT! ON Long Beach W^n/rfU P/Wfti* VtfUlT Job. No. 4* Sheet No. Date / Computed By Checked By 2o-0'tod9?.K>J B 1/2*o 4 &t£ x f 0- ) = ,7 LG FORM 47A (3/01) LiOCKWOOD GREENE A JA JONES COMPAW ENGINEERING & CONSTftUCTI ON Long Beach Job Name jfilS ft AH ? Subject VAt i\ JT Job. No. Sheet No. Date Computed By Checked By o$fro -t A A it** /8v^ fw- 17 > PL CL6 t£ LG FORM 47A (3/01) U3GKWOOD GREENE - A M. JONK COMPANY - ENGINEERING & CONSTRUCT! ON Long Beach Job Name Subject Job. No. Sheet No. Date Computed By Checked By /o 00 6 PL $-.33)= f " D N 5/^5-6,3,5 LG FORM 47A (3/01) UOCKWOOD GREENE A J.A. JONES COMPANY ENGINEERING & CONSTRUCTION Long Beach Job Name _j-f Subject r Job. No. Sheet No. Date Computed By Checked By <To5r f c W-2. ^0.000 /) , ~-/.15(18x^^3 M1 £1 c 0 F $ _ /» P-^Ks 6 p-i?^ > 212- D - oV & P*~ »n LG FORM 47A (3/01) UOCKWOOD GREBNE - A J.A. JONES COMPANY - ENGINEERING & CONSTRUCT! ON Long Beach Job Name Subject Job. No. Sheet No. Date Computed By Checked By - 13/1 v=^ 28.i :** .33 f -- -Htf'9 er, -y y-c 2, f - ^e IJ.3 o -»- ON f) LG FORM 47A (3/01) UOCKWOOD GREENE A J.A. JONES COMPANY ENGINEERING & CONSTRUCT! ON Long Beach Job Name i/lMfa f'Su Subject Job. No. Sheet No. Date Computed By Checked By P/ LG FORM 47A (3/01) ACOKD,CERTIFICATE OF INSURANCE ISSUE DATE 12/20/2004 PRODUCER AON RISK SERVICES, INC, OF NEW YORK 55 EAST 52ND STREET, 36TH FLOOR NEW YORK, NY 10055 This certificate is Issued as a matter of information only and confers no rights upon the Certificate Holder. This Certificate does not amend, extend" or alter the coverage afforded by the policies below. COMPANIES AFFORDING COVERAGE Company A American Int'l South Ins Co INSURED ADMINISTAFF COMPANIES, INC. 19001 CRESCENT SPRINGS DRIVE KINGWOOD.TX 77339 * SEE BELOW Company B Company C Company D Company E This is to certify that the policies of insurance described herein have been issued to the Insured named herein for the policy period indicated. Notwithstanding any requirement, term or condition of contract or other document with respect to which thjs certificate may be issued or may pertain, the insurance afforded by the policies described herein is subject to all the terms, conditions and exclusions of such policies. Limits shown may have been reduced by paid claims. CO LT TYPE OF INSURANCE POLICY NUMBER EFFECTIVE EXPIRATION LIMITS OF LIABILITY GENERAL LIABILITY n Commercial General Liability Q Claims Made D Occurrence Q Owners' and Contractors' Protection D D General Aggregate Limit applies per D Policy D Project QLocatton EACH OCCURRENCE FIRE DAMAGE MEDICAL EXPENSE PERS. AND ADVERTISING INJURY GENERAL AGGREGATE PRODUCTS AND COMP. OPER. AGO. AUTOMOBILE LIABILITY G Any Automobile Q AH Owned Automobiles Q Scheduled Automobiles D Hired Automobiles D Non-owned Automobiles D COMBINED SINGLE LIMIT BODILY INJURY (Per person) BODILY INJURY (Per accident) PROPERTY DAMAGE {Per accident) COMPREHENSIVE COLLISION WORKERS' COMPENSATION AND EMPLOYERS' LIABILITY 1498638 09/16/2004 10/01/2005 WC Statutory Limit | x I Other EL EACH ACCIDENT 1,000,000 EL DISEASE (Each employee)1,000,000 EL DISEASE (Policy Limit)1,000,000 EXCESS LIABILITY D Occurrence Qciaims Made EACH OCCURRENCE AGGREGATE * SHIMIZU AMERICA CORPORATION (1501700) IS COVERED THROUGH BLANKET ALTERNATE EMPLOYERS ENDORSEMENT FOR ALL EMPLOYEES UNDER CLIENT SERVICE AGREEMENT. CERTIFICATE HOLDER SHIMIZU AMERICA CORPORATION 1820 WATER PLACE SUITE 255 ATLANTA, GA 30339 SHOULD ANY OF THE ABOVE DESCRIBED POLICIES BE CANCELLED BEFORE THE EXPIRATION DATE THEREOF, THE INSURER WILL ENDEAVOR TO MAIL 30 DAYS WRITTEN NOTICE TO THE CERTIFICATE HOLDER NAMED TO THE LEFT, BUT A FAILURE TO MAfL SUCH NOTICE SHALL IMPOSE NO OBLIGATION OR LIABILITY OF ANY KIND UPON THE ISSUER, COMPANY, ITS AGENTS OR REPRESENTATIVES. Authorized Representative /*&**+*Bf Cs*&*-"^•au*^^^ Certificate ID: PBIWEOU3 cfi p H g: § o