HomeMy WebLinkAbout1969 PALOMAR OAKS WAY; ; CB100192; PermitAI
City of Carlsbad''
1635 Faraday ,Carlsbd, CA 92008
02-01-2010 • Mechanica.I.Permut ' •Permit No: CB100192
Building Inspection Request Line (760) 602-2725
,•. •
- - •• . dl. Job Address: ., .1969 PALOMAR OAKS WY CBAD
Permit Type: MECH • •
I Status:'ISSUED ..
Parcel No: 2130922000 •- Lot#: .0. . Applied: , 02/01/2010
Valuation: $0.00 •• . 4 'Entered By: JMA.
- Reference #: , . . ... ••
e Plan Approved: 02/01/2010 . Pc #: ..
• . Issued: 02/01/2010 '
Project Title: • AIR PRODUCTS: REPLACE DUCTS . Inspet Area:. . .
LIKE FOR LIKE • - • .
I .1 1...
Applicant: • ,._Owner:-4i,... .. .. . r, ' • . APEX MECHANICAL AIR PRODUCTS&CHEMICALS INC
7440 TRADE ST •
•: C/..0.J..p SCHUMACHER .CO,
STE. A • . 1969PALOMR OAKS WAY • S •
SANDIEGO 92121 bARLSB4D'C 92Ô11 .
858-536-8700 \ ~'-4 Z3 t &P//) 4
Fireplade Installation Fee $0.00
Installation/Relocation Ven Fee f : 0 • $0.00 •
Hood Fee '/' / \ Vsô.00
Other, $0.00
to 15HP / • \0 —.-.-_i'
. \ • • • •
•
rAdditional Fees
.0O
TOTAL PERMIT FEES &9
(
':.
/l 1 r, ((,J_fl/, - 1 •
Total Fees \$24 00 Due
/
$0.00
INCO
. . FINAL APPROVAL •, -
Inspector , Date /'V" '\ , Clearance
NOTICE Please take NOTICE that approval of your project includes the Imposition of fs dedicatiis reservations or other exactions hereafter collectively
referred to as fees/exactions. You have 90 days from the date this permit was issued to'prbtest irfipbsitión of these fees/exactions. It you protest them, you must
follow the protest procedures set forth in Government Code Section 66020(a), and file the prtest and any other required informaflon with the City Manager for.
processing in accordance with Carlsbad Municipal Code Section 3.32.030. Failure to Umely follow that procedure will bar any subsequent legal action to attack,
review, set aside, void, or annul their imposition. • , -
You are hereby FURTHER NOTIFIED that your right to protest the specified fees/exactions DOES NOT APPLY to water and sewer connection fees and capacity
,changes, nor planning, zoning, grading or other similar appllcation frocessing orseriice feed in connection with this project. NOR DOES IT APPLY to any
fees/exactions of which you have previously been given a NOTICE similar to this, or as to which the statute of li,itations has previously otherwise expired. -
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Plan Check No.. . Diilding Permit Application
1635 Faraday Ave Carlsbad CA 92008 ESt Value
.760,;6022717I2718J2719 PlanCk Deposit '
I Date
JOB ADDRESS . . i. . . ••. . SUITEI/SPACEI/UNITD...............APN ,
AO F1/9r/- t9H( - st/P OJEC B - .. LOTIl. .. PHASE R U OF UNITS II BEDROOMS B BATHROOMS '. TENANT BUSINESS NAME. • . COTGTR. TYPE 0CC. GROUP I' I I n'- I • -
DESCRIPTION OF WORM: IncIudeSqua,e:FeetoMffectedA,ea(s) . : , -I : ' I •: P' .. .
N.
XISTING.USE PROPOSED USE . ••• GARGE (SF.) PATIOS-(SF" DECItS(SF) FIREPLACE: d CONDifIONING FIRE SPRINKIERS-
YES# NOD
JAIR
YES DNO YESD NOE
CONTACT.NAME(lf011ferentFcmAppticanl) - . - . - ......, APPLICANT NAME: - :- : •• •• . - .. • -
- 4 APOV. A0CA1W14#,1. tt
ADDRESS • ADDRESS I
7W0 7?2#PE , 4
CITY STATE .. ' ZIP ' CITY q STATE ,ZIP -
CA
-
PHONE . . -- . FAX . . . PHONE-- . - - -- . -.:- - -. . .• .: •:-'- .... -. -
8c-c3s-777
EMAIL . EMAIL
2)99P6gC I i-f ,CD'4
PROPERTY OWNER NAME CONTRACTOR BUS NAME --" ..:.- - -:- - . :' -' .. -. -'- • - - MEa/'f'"M £ ADDRESS' ADDRESS
_74'90 " 7AMR--57,'.
CITY STATE .. ZIP CITY - STATE ZIP
PHONE- . -- --- . .F*x -' •. :..-..PHONE -.. - .• .Ftu.x .......- .4-_'. -
39777
EMAIL --. ...... r • .'_. ., : EMAIL-..'-I_' ..'I Ø4 4jh/,CO4
.4RCHJDE$IGNER NAME & ADDRESS STTE UC. U STATE LICJ cuss ny c BuSt uc a
............... j.t77.
izec..tujiz uusiness and vroTesslons coae:.Any City -or county wniCnrequureS a-permIt toconStruCvalter, Improve. demolish or repair any structure. prior to Its Issuance, alsOreQuireS the --. applicant for Such permitto fe a s1gneds13tement that he Is licensedpursuant to the provisIons of the Contractor's Ucensle Law-(Chapter9. commendingwith Section 700001 Oivislon3 orthe .BuslnessandProfesslons Code) or that he Is exempt therefrom, and thebasis for the alleged exemption. AnyviolationolSectioii 7031.5 by any applicant for a.permit subjectsthe applicant to a Civil penalty of not more than five hundred dollars IS500ll . 4 -
Woilcers Compensation Declaration IhembyeffinundernalIlyor pepeijury aria oIthe fc!1owngdrJaiabons
flihave an wif I maintain a certificate of consent to self Insure for waiters compensation as provided by Section 3700o1 the I.abar Code for the performance of the work for which this Permit is issued I3 ave and will maintain worke cojgpensatlon as required 1 ii 3700 ci the La)ar Code for the performance of the wait for which this permit is issued My workers oompensalionlps pier and policy
numheraie Insurezve'Co ' 'Xi' c IIcyNo__- ExpiallonDate4 Ob)f'ZO/D
Thi section need not be completed if the permul Is for one hundred do11rs ($100) or less.
Cedilicateof Exemption Icertufythatin rfomiancoof Iii wouli torwiuldo this pemutls Issued. IshalI not employ any person in any mannersoastobecome subject to-ft Workers ConipensabonLawsof
Cabtomia WARNING Failure to secure workers compensation coverage Is unlawfulnd th aeft subject en employer to criminal and penalties 'cuvll fines up to thou do one hundr d sand llars (&100 000) In
0
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I hereby affinw thallam eeempt frcn Contiadots License Lewf hefolion,re reason ' " I" I as owner of the property or my employees with wages as their sole compensation twit do the wait and theiiucture is not intended or offered for sale (Sec. 7044 Business and Professions Code The Contractofs License Law does fbI apply to an owner of property who builds or improves thereon and who does such walk himseff or through his own employees provided that such improvements are rail intended ooffered for
sale If however, the building orimpiovement is sold within one year o(coinpletion the owner builder will have the burden of proving that he did not build or urprove for the purpose of site).a
property who builds or unproves thereon and conlracts for such projects wit
61.
h contractor(s) licensed pwsuanito tha Contractoi's License Law) '
[J I am exem0i under Section_ Business and Professions Code fr this reason
1 I personally plan to provide the major labor and materials for construction of the proposed property improvemenL Dyes
2 I (have! have not) sgned an application for a building pemut for the proposed wait
'. 3 I have contracted with the following person (tim) to provide the proposed construction (include name address Iphone lcontractors license number)
4 I plan to provide portions of (he wait, bull have hired the followIng plscn to coordinate supervise and provide the major work (include name!address!phonelcontractor's license number) I v
5.1 will provide some of the walk, but I have contracted (hired) the following persons to provide the work Indicated (include namelavidresslphone! type of wont)
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PROPERTY OWNER SIGNATURE []AGENT' DATE
---- - Is the applicant or future buildmg oipant required to submit a business tan acutely hazaidous matenats iegistiabn form or nsk management and prevention program under Sections 25505 25533 cr25534 the Plesty Tànr Hazardous Substanca Aunt Act? Yes No -
Is the applicant or future buling oca,pant required to obtain a permit from the air pollutioncontroldistriclor.alfggality manageme dislncr'l Dyes DNo P Is the facthty to be nsliucted thin 1000 feet of the outer boundary of a sdiool site? I:lves ONO .
w:ANyoF.THEANswERs ARE YES,FINAL• CERTIFICATE OF OCCUPANCY.MAYNOT BEISSUED UNLESS:THEAPPLICANT HASMETOR IS MEETING THE-.REQUtREMENTS OF THEOFFICEOF
EMERGENCY SERVICES AND THE AIR POLLUTiON CONTROL DISTRICT t I
I hereby affirm that there is a constiucbon lending agency for the performance of the welt this permit t'issued (Sec 3097 (i) CA 66)5 V — Lende?s Name' . Lender's Address . . S t iina_
onliddhecti p1 instsanate a 'i"capvwi~iii0~,i4n"'aWS6~ii"iing~'btdlding -ft. Mice
I herebyan em ntative of the City of Carlsbad teenier upon aben'enhened cIrca purpose IAI.SOAGREE TO SAVE INDEMNIFYAND KEEP HARMI.ESS THE ciw OF CARLSBAD
AGAINST AU. LIABIUT1ES JUDGMENTS COSTS AND EXPENSES WHICH MAY IN ANY WAY ACCRUE AGAINST SAID Cli? IN CONSEQuENCE OF THE GRANTING OF THIS PERMIT f'g
EXPIRA11ON Everypermdussrd b'Uie &iildln Oftoatundertheprovi of this Code shall exprre by ütatca and beme null arid void if thebwlngorwoitauthonzed bysuthpennilisiiotmmerdwshin 18Odasfm toot sidlpethtdorift rig pemid issuspondedorabandoned atanytiam afterth twortismmenendforapenodof i80da>(SecIbn 106.4:44Unibmi Building Coda)
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FILE COPY
KLAUS0RUCcNER 4lossonento VOW Blvd.
),J AND ASSOCIATES Son Diego. CAfl121
TeL (858)671-9878
Fa,c (868) 677.9894
July 21, 2010
Cynthia Wong
Carlsbad Fire Department
1635 Faraday Ave
Carlsbad, CA 92008
RE: Air Products and Chemicals, Inc. [Previously Called Schumacher Engineering]
1969 Palomar Oaks Way, Carlsbad, CA [Rooms 313, 315, and 316]
Updatedinventory for Existing H-3/H-7 Occupancy
Dear Ms Wong:
I am writing at the request of Air Products to provide you with an update to the hazardous
materials inventory for their existing H-3/H-7 occupancy. The purpose of this update is threefold:
The first is to add hazardous materials to the inventory to reflect a new hazardous material
process (i.e. DEMS Distillation and Packaging).
The second is to bring the overall accuracy of the inventory up to date, so it correctly
indicates the hazardous materials and the amount of hazardous materials used and stored
in these rooms.
The third and last reason is to correctly reflect that one of the hazardous material processes
In these rooms involves pressurizing some amount of IPA/ATRP to> 15 psi. Note that
the amount that is pressurized is below the Maximum Allowable Quantities (MAQs) for
closed system use.
In all three instances, the occupancy for these rooms remains the some (H-3/11-7). Please seethe
attached updated Hazardous Materials Inventory Report for details. If you have any questions or
need additional information, do not hesitate to call.
Sincerely,
Elley Klausbruckner
Fire Code Consultant
By way of my signature, Air Products agrees to the conditions and restrictions stated in this
letter & in the updated inventory report.
~AWV~~ /Adeir.4 vsk"Afco -,--12-2-ho
Air Products [Sign A Print] Date
KLAUSBRUCKNER
)JJ AND ASSOCIATES
FILE COPY
4105 Sorrento Valley Blvd.
San Diego, CA 92121
Tel: (858) 677-9878
Fax: (858) 677-9894
AIR PRODUCTS
EXISTING H3H7
ROOMS 313, 315, 316
1969 PALOMAR OAKS WAY
CARLSBAD, CA
Hazardous Materials Inventory
Report
Rev.. 3.2
July 13, 2010
Air Products (Sign, Print and Date)
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Revision Comments , . : Date IY -
Rev. 1.0 Report printed. November 5, 2009 MM
Rev. 1.1 Report updated to reflect the addition of the DEMS February 22, 2010 MM
process.
Rev. 2.0 Inventory Revised. Occupancy to remain the same. May 11, 2010 MM
Rev. 3.0 Inventory revised to show that some flammable liquids July 9, 2010 MM
are pressurized >15psi. Amount of flammable liquids that
are pressurized >l5psi is below the MAQ for closed-
system use, therefore occupancy to remain the same.
Rev. 3.1 Some quantities revised. Occupancy to remain the same. July 12, 2010 MM
Rev. 3.2 Quantities revised even further. Occupancy to remain the July 13, 2010 MM
same.
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DISCLAIMER
This report is the property of Klausbruckner & Associates and was prepared exclusively for use by Air
Products, for the hazardous materials inventory and occupancy conditions specifically described in this
report. Air Products' quantities and locations addressed herein are based on information provided for the
report by Air Products. Discrepancies between the information presented herein and actual conditions and
conditions presented on plans are the sole responsibility of Air Products. Verification of compliance with
the Code requirements and provisions addressed herein is outside the scope of this report. Copies of this
report retained by Air Products shall be utilized only by Air Products for the hazardous materials inventory
and the 2001 California Codes maximum allowable quantity requirements addressed in this report for the
above-mentioned facility. This is a hazardous materials inventory report for indoor storage and use
conditions only. This is not a complete code compliance report. Hazardous materials analysis of the
remainder of the building, including adjacent tenant spaces, is not part of the scope of this report.
This report shall not be used as, or in lieu of, construction documents or plans for this project or any other
project or for any other purpose or conditions not specifically addressed in this report.
Rev 3.2 —Air Products I
KLAUSBRUCKNC
Page ii
Rooms 313, 315, 316 SSS AND A8SOCIATIS
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Table of Contents: Existing H3H7 - Rooms 313, 315, 316
Report Format Page
Health Hazards: Inventory Totals for Hazard Categories I
Physical Hazards: Inventory Totals for Hazard Categories 2
Inventory 3
Inventory Sorted by Classification 8
Classification Symbols 34
Classification Definitions 36
Rev 3.2 —Air Products I I Page iii I
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Rooms 313, 315, 316 LAUSBRUCKNER I AND AS$OC6AYt3 I
- - - - - - - - - - - - HAZARDOUS MATERIALS and OCCUPANCY CLASSIFICATION ANALYSIS
CBC TABLE 3-E - CFC TABLE 8001.15-B SUMMARY - HEALTH HAZARD MATERIALS
Air Products - Existing H3H7 - Production (Rooms 313, 315, 3161 -1969 Palomar Oaks Way, Carlsbad, CA
STORAGE
Solids Liquid Gas Solid
Material Lbs Gins Cf Lbs
USE CLOSED
Liquid Gas
Gins Cf
USE OPEN
Solid Liquid Gas
Lbs Gins Cf
Carcinogens 6.3000 88.5000
Corrosives 67.3000 305.0000
Highly Toxics 0.5000 223.0000
Irritants 5.0000 258.7000 91.0500 2067.5007 0.5000
Other Health Hazards 185.4000 890.8000
Sensitizers • 11.0000
Toxics 8.0000
2001 California Codes: EXISTING AREA IS CLASSIFIED AS A H3H7 OCCUPANCY BASED ON THE USE and STORAGE OF HEALTH HAZARD MATERIALS.
-. Storage Amount= Maximumltotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at anytime.
Automatic fire sprinkler system protection.
SUMMARY - HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 1
- - - - - - - - - - - - - M M - - HAZARDOUS MATERIALS and OCCUPANCY CLASSIFICATION ANALYSIS
CBC TABLE 3-13 - CFC TABLE 7902.5-A, 7903.2-B, 8001.15-A SUMMAY - PHYSICAL HAZARD MATERIALS
Air Products - Existing H3H7 - Production (Rooms 313, 315, 3161 -1969 Palomar Oaks Way, Carlsbad, CA
Material
STORAGE
Solids Liquid Gas
Lbs Gins Cf
USE CLOSED
Solid Liquid
Lbs Gins
Gas Solid
Cf Lbs
USE OPEN
Liquid Gas
Gins Cf
Combustible Liquids II 115.0000 401.0000
Combustible Liquids Ill-B 7.0000 231.3000
Compressed Gases -
Inert/Nonhazardous
3241.0000
Cryogenic Liquids -
Inert/Nonhazardous
66.0000
Flammable Gases 600.0000
Flammable Liquids I-B 193.6000 1466.7007 0.5000
Flammable Liquids I-C 10.8000 370.0000
Oxidizer Gases 90.0000
Water Reactives 1 3.3000 593.0000
Water Reactives 2 11.5000 305.0000
Water Reactives 3 55.0000
2001 California Codes: EXISTING AREA IS CLASSIFIED AS A H3H7 OCCUPANCY BASED ON THE USE and STORAGE OF PHYSICAL HAZARD MATERIALS.
Storage Amount= Maximumltotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% In use at anytime.
Automatic fire sprinkler system protection.
SUMMARY -HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 2
- - - - - - - - - - - - - Air.Products -Existing H3H7 -Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Hazardous Materials Inventory
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
1 67-64-1 1 100 Acetone (2-Propanone) (Autoignhtion: FL1B, IR 2.0000 Gins 2.0000 Gins 0.5000 Gins V Existing - 1969181 -Chemical
869oF; FP loF: BP 133oF] ILEL: 2.60/a Production 1313, 315, 3161
UEL: 12.80/4 [VD: 2.01; SG 0.786; VP:
120.7] [FV per Gin: 2020 ci) [RTECS#
AL3150000] [HR: H2 F3]
2 25635-88-5 CG 100 Air [Compressed Air] [Breathing Air] [Oil CG-NH 0.0000 Cf 311.0000 Cf 0.0000 Cf V Existing - 1969/81-Chemical
Free Air] (HR: 01 Production [313, 315,316]
3 744044-0 S 100 Carbon [Acvtivated Carbon NH 0.0000 Lbs 600.0000 Lbs 0.0000 Lbs Existing - 1969/131-Chemical
Filtration/Treatment System - Production [313, 315, 316]
Seated/Oxygen-Free Environment] [HR: 01
4 7440-59-7 CG 100 Helium (He) law: 4.001(96.71 cfflb] (HR: 01 CG-NH . 0.0000 Cf 2930.0000 Cf 0.0000 Cf Y Existing - 1969/81-Chemical
Production [313. 315,316]
5 110-54-3 L 100 Hexane (n-) [BP 156oF; FP -1009 [LEL: FL18, IR 15.0000 Gins 31.7007 Gins 0.0000 Gins V Existing - 1969/81-Chemical
1.1; IJEL: 7.5] (SG 0.655; VD 2.9831 Production P13,315,316]
(LDSO-O 28710 mg/kg) (RTECS#
MN9275000) (HR: H2 F3]
6 1333-74-0 CG 100 Hydrogen [H2) [mw: 2.02] (Flammable FG, RMP-T2 0.0000 Cf 600.0000 Cf 0.0000 Cf Y Existing - 1969/81-Chemical
Range in Air. 4.1-74.20/4 [192 cf/tb) [HR: - Production (313,315,316]
F4J
7. 64742-54-7 1 100 Mineral Oil [Mineral Petroleum Distillate] CL3B, IR 0.0000 Gins 5.0000 Gins 0.0000 Gins Existing - 1969181-Chemical
(AMOCO AW Oil) (Mobil Almo) (MX-237 Production P13, 315, 316]
Oil) (Cutting Oil] (Turbo I Oil 32) (Cindol)
[Vacuum Pump Oil) (Paraffinic Oil) (Tellus
Oil 32] (Waylube Spindle Oil) (FP 330-
47509 (HR: H1 Fl)
8 7727-37-9C C 100 Nitrogen [Cryogenic] (LN2] (13.8 cf/tb; CRY-NH 0.0000 Gins 66.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
93.11 cf/gIn] [HR: H2] Production (313, 315. 316]
9 7782-447 CG 100 Oxygen [02] (aw: 32.00] (12.08 cf/lb] (HR: OX 0.0000 Cf 90.0000 Cf 0.0000 Cf Y Existing - 1969/81-Chemical
OXG) Production (313,315,316)
10 9016-00-6 L 100 Poiydimethylsiloxane [Latex] pow CUB, IR, OHH 0.0000 Gins 36.3000 Gins 0.0000 Gins Existing - 1969/81-Chemical
Coming 360] [Latex 2588] [FP >200oF] Production [313, 315, 316]
[RTECS#T02690000) (HR: Fl Hi)
11 00-01-146 S 100 Safe Step [Aluminum Silicates] (HR:H2] IR 0.0000 Lbs 60.0000 Lbs 0.0000 Lbs Existing-1969/8i-Chemical
Production [313, 315. 3161
12 629-59-4 L 100 Tetradecane (N-) [MP 5.5oC; BP CL3B, IR 0.0000 Gins 5.0000 Gins 0.0000 Gins Existing - 1969/81-Chemical
252oCI760mm; FP 21109 H2 Fl] Production [313, 315. 3161
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 3
- - - - - - - - - - - - - - - Air Products -Existing H3H7 -Production [Rooms 313, 315, 316] - 1969 Palomar Oaks Way, Carlsbad, CA: Hazardous Materials Inventory
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >1512sl Location
13 78.40.0 1 100 lriethyl Phosphate [Ethyl Phosphate] CL3B4O1-11-1,WR1 1.0000 Gins 185.0000 Gins 0.0000 Gins Y Existing-1969/B1-Chemical
[TEPO] (BP 215oC; FP 240o9 [RTECS# Production 1313, 315, 316]
TC79000001 (HR: H2 Fl Ri)
14 512-56-1 1 100 Trimethyl Phosphate [MPO] (Methyl CA, IR, OHH, P65 0.3000 Gins 88.5000 Gins 0.0000 Gins Y Existing - 1969/Bi-Chemical
Phosphonate) (MP-46oC: BP 197oC; FP Production [313, 315,3161
None] (LD50-0 840 mg/kg) (RTECS#
TC82250001 [Aldrich 241024] [HR: 1-12]
15 121.45-9 L 100 Trimethyl Phosphite [MPI] [Methyl CR, FL1C, OHH, 0.5000 Gins 185.0000 Gins 0.0000 Gins V Existing- 1969/81-Chemical
Phosphite] (Phosphorous Acid, Trimethyl WR1 Production [313, 315,316)
Ester) (MP -78oC; BP liloC; FP 82oF)
(SG 1.054; VD 4.281 (RTECS#
TH14000001 [HR: H3 F3 Ri CORWRJ
16 128-37.0 S 100 Di-tert-Butyl4Methylphenol (2,6-) [Butyl- IR 5.0000 Lbs 0.0500 Lbs 0.0000 Lbs Y Existing - 1969/81-Chemical
4-Hydroxymethylphenol] (Butytated Production (313, 3151
Hydroxytoluene] (BHTI [Aldrich D474041
(HR: H21
17 186598-40-3 L 100 Bis(Tert-Butylamino)Silane (BTBAS] [FP CR, FL1C, TX, 2.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
30oC (86oF); BP >195oF; Autoignition: WR2 Production [313]
374o9 (LEL: 0.574 (LD50-Oral: 78 mg/kg)
(HR: H3 F3 R2 WR] -
18 78-10-4 1 100 Tetraethylorthosilicate [Ethyl Orthosilicate) C12, IR, OHH 5.0000 Gins 61.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
(Ethyl Silicate) (Tetraethyl Silicate) [EOS) Production [313]
(LD50-0 6270 mg/kg; LD50-S 5878
mg/kg; LC50-Inhalation: >2000 ppm] [FP
>125oF] [HR: H3 F2]
19 3275-24-9 L 100 Tetrakis(Dimethylamino)Titanium CR, FL1B, WR2 0.5000 Gins 120.0000 Gins 0.0000 Gins V Existing - 19691B1-Chemical
(TDMAT) [BP 50oCI0.5mm; FP 25oF; SG Production 13131
0.942; Density 0.947; VD 7.5; LEL 0.76;
IJEL 4.1) [pH 11] [HR: H3 F3 R2 CDR
WR)
20 2370-88-9 L 100 Tetramethylcydotetrasiloxane (1,3,5,7-) FL1C, IR, WR2 1.0000 Gins 185.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
[2,4,6,8-Tetramethylcyclotetrasiloxane) Production [3131
[TMCTS] [TOMCATS) (MW 240.51) (MP -
69oC; BP 135oCI760mm; FP 75.2oF]
[LELO.7; UEL 101 (SG 0.991; VD 8) (HR:
H2 F3 R2 WRlHydrogen Evolution)
Storage Amount = Maximumltotal amount in use and storage, unless otherwise noted. Not all materials are In use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRLJCKNER & ASSOC. - 7/13/2010 - PAGE 4
Air Products -Existing 1-131-17 -Production [Rooms 313,315,3161- 1969 Palomar Oaks Way, Carlsbad, CA: Hazardous Materials Inventory
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >151Psi Location
21 156-60-5 L. 100 Trans-1,2-Dichloroethene[Trans-1,2- FOB, IR, OHH, 1.3000 Gins 0.0000 Gins 0.0000 Gins Y Existing-1969181-Chemical
Dichioroethylene] [TRANS] [FP 39oF; BP WR1 Production (313)
59oC) [LEL: 9.7% UEL: 12.80A) [LD50-0
1235 mg!kg; LD50-S >5 gmlkg; LC50
24,100 ppm] [RTECS# KV9400000] [HR:
H2F3RI]
22 71-55-6 .. L *75 lrIchloroethane(1,1,1-)(Methyt IR,OHH 0.3000 Gins 0.0000 Gins 0.0000 Gins Existing-1969181-Chemical
Chloroform) [TCA] (Adhesive Thinner] Production [313]
[MP -35oC; BP 74oCI760mm; FP None)
[RTECS# KJ2975000] [HR: 1-12]
23 150-46-9 L 100 Triethylborate [TEB] [Tnethoxyborane] FL1B, IR, OHH 1.0000 Gins 255.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
[FP 52oF; BP 117oC] [RTECS# Production [313]
ED50750001 (HR: F3 1-121
24 121-43-7 L. 100 Trimethyl Borate (Methyl Borate) FL1B, HT, IR, WR1 0.5000 Gins 223.0000 Gins 0.0000 Gins Y Existing - 19690-Chemical
[Trimethoxyboline) (Boric Acid, Trimethyl Production [313)
Ester] [FMB] IMP -34oC; FP 8-17oF; BP
69oC] (SG 0.927; VI) 3.59] [LD50-0 140
mg/kg; LDSO-S 198 mg1kg] [RTECS#
ED5600000] [Aldrich 4472181 [HR: H4 F3
RIWR]
25 99-86-5 L 100 Terpinene(a-)(1-isopropyl-4-Methyl-1,3- CL2,IR 0.0000 Gins 260.0000 Gins 0.0000 Gins Existing-1969/B1-Chemical
Cyclohexadiene] [BP 173o; FP 115oF] Production (313); New P1 51
[RTECS# 0S8060000] (HR: H2 F2)
26 121-46-0 L 100 Bicycio(2.2.1)hepta-2,5-diene (2,5- FL1B, IR 1.3000 -Gins 0.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
Norbomadiene) [Norbomadiene] [BP Production (315)
89oC; FP 12oF] [Aldrich B33803] [HR: F3
H2]
27 292-64-8 - L 100 Cyclooctane IFP 86) [HR: H2 F3] FL1C,IR 1.0000 Gins 0.0000 Gins 0.0000 - Gins Y Existing - 1969lB1-Chemical
Production (315)
28 2172-02-3 . - L 100 Hafnium(IV) tert-butoxide (Aldrich FLIC, IR 5.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
4455411: [mw 470.94 g!moi]; [FP 82oF; Production (315)
BP 194oF]; [SG 1.1661; (H0-F3-R0]
29 109-99-9 L 100 Tetrahydrofuran (FP loF; BP 69oC] [LEL FL1 B, IR, OHH, SN 5.0000. Gins 0.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
1.8; UEL 11.8) (SG 0.889: VD 2.51 (LD50- Production (315)
0 1650 mg/kg; LCSO 21,000 ppm] -
[RTECS# LU5950000] (HR: H2 F3)
Storage Amount = Maximumitotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with clO% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 5
- - - - - - - - - - - -
Air Products -Existing 1-131-17 -Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Hazardous Materials Inventory
-
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
30 352535-014 1 100 Tetrakis(ethylmethylamido)hathium(IV) FL1B, CR, WR2 2.0000 Gins 0.0000 Gins 0.0000 Gins Y Existing - 19691B1 -Chemical
[TEMAH] [Aldrich 5531231: [mw 410.9 Production [3151
9/mall; [FP 52oF; BP 174.2oF], [SG
1.324]; [H3-F2-R2)
31 175923-04-3 1 100 Tetrakis(ethylmethylamido)zirconium(IV) FLIB, CR, OHH, 55.0000 Gins 0.0000 Gins 0.0000 Gins V Existing-1969181-Chemical
[Aldrich 553131]: [mw 323.63 g/mol]; [FP WR3 Production (315)
• 50oF; BP 17809; [SG 1.049]; (1-13-F3-112)
32 681-84-5 L 100 Tetramethyl Orihosilicate (Methyl Silicate) CR, FL1C 1.3000 Gins 0.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
(FP 84oF; BP 121019 [MP -4o9 [SG Production (3151
1.032; 'ID 5.25] [RTECS# W98000001
(HR: H3 F3 COR)
33 15606-95-8 L 100 Triethylarsenate [EASAT) [TEAsat] CL38, CR, OHH, 6.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
[Ethyl Arsenate, Arsenic Acid Triethyl CA, TX, SN, WR2 Production [315]
Ester): [mw 226.1 g/moll; (FP 230oF; BP
• 457o9; (SG 1.302; VD 7); [1050-Oral:
71 mg/kg]; (H3-F2-R2)
34 67-63-0 1 >/70 Isopropanol (Isopropyl Alcohol] 12- FL1B, IR 110.0000 Gins 0.0000 Gins 0.0000 Gins New-1969181-Chemical
• Propanol] [Alcohol] (A870-25 Solder Flux] Production 313 [former TEOS
• 1425 Thinner] [LD50-0 >1,840 mg/kg; area & Filling Station]
LD50-S13,000 mg/kg] (FP 53oF; BP
- 82.5oCJ [LEL: 2.50/a; UEL: 120A] (SG
0.785; VI) 2.0791 (1D50-0 5045 mg/kg)
[RTECS# N18050000] (HR: H2 F31
35 67-63-0 1 '/70 IsopropanoI(lsopropyl Alcohol] [2- .- FL1B,IR 0.0000 Gins 80.0000 Gins 0.0000 Gins V New-1969!B1-Chemical
• Propanol] [Alcohol] (A870-25 Solder Flux) Production 313 [former TEOS
[425 Thinner] [LD50-0 >1,840 mg/kg; area & Filling Station]
. LD50-S13,000 mg/kg) (FP 53oF; BP
82.5oC) [LEL: 2.5°h UEL: 12%] (SG
• 0.785; 'ID 2.0791 (1050-05045mg/kg]
[RTECS# NT8050000] [HR: H2 F3]
36 99-86-5 1 100 Terpinene (a-) [1-IsopropyI-4-Methyl-1,3- CL2. IR 0.0000 Gins 40.0000 Gins 0.0000 Gins V New-1969/B1-Chemical
. . Cydohexadiene] [BP 173o; FP 115oF] Production 313 (former TEOS
(RTECS# 0S8060000) (HR: H2 F21 area & Filling Station)
37 99-86-5 1 100 Terpinene (a-) (1-Isopropyl-4-Methyl-1,3- CL2, IR 110.0000 Gins 40.0000 Gins 0.0000 Gins New-1969/B1-Chemical
• Cyclohexadiene] (BP 1730; FP 11509 Production 313 (former TEOS
(RTECS# OS80600001 (HR: H2 F2] area & Filling Station)
Storage Amount = Maximumltotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALSIOCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. -7/1312010-PAGE 6
Air Products -Existing: H3H7 -Production [Rooms 313, 315, 316] - 1969 Palomar Oaks Way, Carlsbad, CA: Hazardous Materials Inventory
Item CAS# State Conc% Material: Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
38 2031-62-1 1 100 Methydiethoxysilane [Diethoxy- FOB, IR 0.0000 Gins 755.0000 Gins 0.0000 Gins New-1969!111-Chemical
methylsilane] (Aldrich 66612]: [mw 134.25 Production 316 (former BBr3
g/mofl; [FP 500F; BP 201 oF]; (SG 0.838; area & Filling Station]
VD 4.6]; (1-12-F3-1101
39 13499-05-3 S 100 Hafnium chloride IMP 3190C1 [Acros IR 0.0000 Lbs.•, 31.0000 Lbs 0.0000 Lbs New-19691B1-Chemical
29325] (HR: 1-121 Production 316 [former POC13
area & Filling Station]
Storage Amount= Maximumltotal amount In use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% In use at anytime.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 7
Air Products - Existing H3H7 -Production (Rooms 313,315,3161-1969 Palomar Oaks Way, Carlsbad, CA: Carcinogens/LIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs 15Psi Location
1 15606-95-8 L 100 Triethylarsenate (TEASATI (FEAsat) CL3B, CR, OHH, 6.0000 Gins 0.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
[Ethyl Arsenate, Arsenic Acid Triethyl CA, TX, SN, WR2 Production [315]
Ester]: [mw 226.1 glmolj; (FP 2300F; BP
457o9; [SG 1.302; VD 7]; (L050-Oral:
71mg!kgl; [H3-F2-R2]
2 512-56-1 L 100 Trimethyl Phosphate [FMPO] [Methyl CA, IR, OHH, P65 0.3000 Gins 88.5000 Gins 0.0000 Gins V Existing - 1969/Si-Chemical
Phosphonate] IMP -46oC; BP 197oC; FP Production [313,315,3161
None] (LD50-0 840 mg/kg] [RTECS#
TC8225000] [Aldrich 241024] [HR: 1-12]
TOTAL - Carcinogens/LIQUIDS 6.3000 Gins 88.5000 Gins 0.0000 Gins
AGGREGATE TOTAL - Carcinogens/LIQUIDS 94.8000 Gins
Storage Amount = Maximumltotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 8
- - -- - - - - - - = - MM MM - - -
Air Products -Existing H31-17 -Production [Rooms 313,315,3161-1969 Palomar Oaks Way, Carlsbad, CA: Compressed Gases -inert/Nonhazardous/COMPRESSED
Item CAS# State Conc% Material . Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psl Location
3 25635-88-5 CG 100 Air [Compressed Air] [Breathing Air] (Oil CG-NH 0.0000 Cf 311.0000 Cf 0.0000 Cf Y Existing-1969/81-Chemical
Free Air] [HR: 01 Production [313 315,3161
4 7440-59-7 CG 100 Helium [He] law: 4.001 [96.71 cfflb] [HR: 0] CG-NH 0.0000 Cf 2930.0000 Cf 0.0000 Cf V Existing- 1969/81-Chemical
D,,.4i.... r2l ii i41
TOTAL - Compressed Gases - lnert/Nonhazardous!COMPRESSE, 0.0000 Cf 3241.0000 - Cf 0.0000 Cf
AGGREGATE TOTAL - Compressed Gases - Inert/Nonhazardous! 3241 .0000 Cf
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 9
- - - - - - - - = - - - - M - - Air Products -Existing H31-17 -Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Combustible Liquids Ii/LIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
5 99-86-5 L 100 Terpinene (a-)(1-lsopropyl-4-Methyl-1,3- CL2, IR 110.0000 Gins 40.0000 Gins 0.0000 Gins New-19691B1-Chemical
Cydohexadiene) [BP 1730: FP 11509 Production 313 (former TEOS
(RTECS# 0S80600001 [HR: H2 F2] area & Filling Station]
6 78-10-4 L 100 Tetraethylorthosilicate [Ethyl Orihosilicate) CL2, IR, OHH 5.0000 Gins 61.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
[Ethyl Silicate] (Tetraethyl Silicate] [TEOS] Production [313]
[LD50-0 6270 mg/kg: LD50-S 5878
mg/kg; LC50-Inhalation: >2000 ppm] [FP
>12509 (HR: H3 F2]
7 99-86-5 L 100 Terpinene (a-) [1 -Isopropyl-4-Methyl-1 ,3- CL2, IR 0.0000 Gins 260.0000 Gins 0.0000 Gins Existing - 1969181-Chemical
Cyclohexadiene] [BP 1730: FP 11509 Production (313]: New (315]
(RTECS# 0S80600001 (HR: H2 F21
8 99-86-5 L 100 Terpinene (a-) [1-lsopropyl4-Methyl-1,3- CL2, IR 0.0000 Gins 40.0000 Gins 0.0000 Gins V New-1969181-Chemical
Cydohexadiene] (BP 1730; FP 11509 Production 313 [former TEOS
[RTECS# 0S8060000] [HR: H2 F21 area & Filling Station]
TOTAL - Combustible Liquids Il/LIQUIDS 115.0000 Gins 401.0000 Gins 0.0000 Gins
AGGREGATE TOTAL - Combustible Liquids IIILIQUIDS 516.0000 Gins
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic tire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010- PAGE 10
- - - - - - - - - - - - - Air Products -Existing H31-117 -Production [Rooms 313, 315, 316] - 1969 Palomar Oaks Way, Carlsbad, CA: Combustible Liquids Ill-BILIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Uflits Cabs >15Psi Location
9 78-40-0 1 100 Triethyl Phosphate [Ethyl Phosphate] CL3B, OHH, WR1 1.0000 Gins 185.0000 Gins 0.0000 Gins- Y Existing - 1969/81-Chemical
[IEPO] [BP 215oC; FP 24009 (RTECS# Production 1313,315,3161
1C79000001 [HR: H2 Fl Ri]
10 629-59-4 1 100 Tetradecane (N-) (MP 5.5oC; BP CL3B, IR 0.0000 Gins 5.0000 Gins 0.0000 Gins Existing - 19690-Chemical
252oC!760mm; FP 21109 H2 Fl) Production [313, 315, 3161
11 15606-95-8 L 100 Triethylarsenate (TEASAT) [rEAsat) CL3B. CR, OHH, 6.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 19691B1-Chemical
[Ethyl Arsenate, Arsenic Acid Triethyl CA, TX, SN, WR2 Production [315]
Ester]: [mw 226.1 9/moll; [FP 230oF; BP
45709; [SG 1.302; VD 71; (LD50-Oral:
71mg/kg); (H3-F2-R2)
12 64742-54-7 L 100 Mineral Oil (Mineral Petroleum Distillate] CL3B, IR 0.0000 Gins 5.0000 Gins 0.0000 Gins Existing - 1969/81-Chemical
(AMOCO AW Oil] (Mobil Almo)(MX-237 Production [313, 315.316]
Oil) (Cutting Oil) [Turbo T Oil 32] [Cindol]
(Vacuum Pump Oil) (Paraffinic Oil) (Tellus
Oil 32] [Waylube Spindle Oil] (FP 330-
475oF)[HR:H1F1]
13 9016-00-6 L 100 Polydimethylsiloxane [Latex] [Dow CL3B, IR, OHH 0.0000 Gins 36.3000 Gins 0.0000 Gins Existing - 19690-Chemical
Corning 360] (Latex 2588) (FP >20009 Production [313.315,316)
[RTECS#TQ2690000](HR: Fl Hi)
TOTAL - Combustible Liquids Ill-BILIQUIDS 7.0000 Gins 231.3000 Gins 00000 Gins
AGGREGATE TOTAL - Combustible Liquids Ill-B/LIQUIDS 238.3000 Gins
Storage Amount = Maximumltotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at anytime.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 11
Air Products -Existing H3H7 -Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Corrosives!LIQUIDS
Item,.- CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
14 .15606-95-8 L 100 Triethylarsenate [EASAT] (TEAsati CL39, CR, OHH, 6.0000 Gins 0.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
[Ethyl Arsenate, Arsenic Acid Triethyl CA, TX, SN, WR2 Production [315)
Ester]: [mw 226.1 glmol); (FP 2300F; BP
457oF); (SG 1.302; VD 71; [L050-0ral:
71mg/kg); (H3-F2-R2)
15 3275-24-9 L 100 Tetrakis(oimethylamino)Titanium CR, FL1B, WR2 0.5000 Gins 120.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
(TDMA1] (BP 500C/0.5mm; FP 25oF; SG Production [313)
0.942; Density 0.947; VD 7.5; tEL 0.76;
UEL 4.11 [pH 11] [HR: H3 F3 R2 CDR
WR)
.16 681-84-5 L 100 Tetramethyl Orthosilicate [Methyl Silicate] CR, FL1C 1.3000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
(FP 84oF; BP 121 oF) IMP -4oF] [SG Production [315)
1.032; VD 5.25) (RTECS# W98000001
[HR: H3 F3 CDR]
17 121.45-9 L 100 Trimethyl Phosphite (TMPII [Methyl CR, FL1C, OHH, 0.5000 Gins 185.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
Phosphite] [Phosphorous Acid, Tnmethyl WR1 Production (313,315,316]
Ester) (MP -78oC; BP illoC; FP 82oF)
[SG 1.054; VD 4.281 [RTECS#
Th1400000] [HR: H3 F3 RI CORWR]
18 . 175923.04-3 L 100 Tetrakis(ethylmethylamido)zirconium(IV) FL1B, CR, OHH, 55.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
[Aldrich 5531311: [mw 323.63 gimo; IFP WR3 Production (315]
50oF; BP 178oF); (SG 1.049);(H3-F3-R2)
19 18659840-3 L 100 Bis(Tert-Butylamino)Silane [BTBAS] [FP CR, FL1C, TX, 2.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
30oC (86oF); BP >195oF; Autoignition: WR2 Production [313]
374oF) [LEL: 0.50A] [LD50-0ral: 78mg/kg]
[HR: H3 F3 R2 WR]
20 352535-014 L 100 Tetrakis(ethylmethylamido)hafnium(IV) FL1B, CR, W112 2.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
[IEMAH] [Aldrich 553123]: [mw 410.9 Production (315)
g/mo; [FP 52oF; BP 174.209; (SG
1.3241; [H3-F2-R2]
TOTAL - Corrosives/LIQUIDS 67.3000 Gins 305.0000 Gins 0.0000 Gins
AGGREGATE TOTAL - Corrosives/LIQUIDS 372.3000 Gins
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 12
- - - - - - - - - - - - - Air Products - Existing H3H7 -Production (Rooms 313,315,3161-1969 Palomar Oaks Way, Carlsbad, CA: Cryogenic Liquids - lnertlNonhazardous!CRYOGENICS
Item CAS# State Conc% Material - Hazard Class
-
Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location I
21 7727-37-9C C 100 Nitrogen [Cryogenic) tLN2] 113.8 cfllb; CRY-NH 0.0000 Gins 66.0000 Gins 0.0000 Gins V Existing - 1969!B1-Chemical
M II ,.fb.I.1 fljD. U')l r'H') 14C '41
TOTAL - Cryogenic Liquids - lnert!NonhazardousICRYOGENlCS 0.0000 Gins 66.0000 Gins 0.0000 Gins
AGGREGATE TOTAL - Cryogenic Liquids - lnerUNonhazardouslC - 66.0000 Gins
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection. -
HAZARDOUSMATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 13
- - - - - - - - - - - - - - - - - - Air Products -.Existing H3H7 -Production (Rooms 313, 315, 3161-1969 PalomarQaks Way, Carlsbad, CA: Flammable GasesICOMPRESSED GASES
Item CAS# -. State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location I
22 1333-74-0 CG 100 Hydrogen [H2] [mw: 2.02] [Flammable FG, RMP-T2 0.0000 Cf 600.0000 Cf 0.0000 Cf Y Existing - 19691B1-Chemical
Range in Air: 4.1-74.29A] [192 cfllb] [HR: . Production (313, 315,316)
F4]
TOTAL - Flammable Gases/COMPRESSED GASES 0.0000 Cf 600.0000 Cf 0.0000 Cf
AGGREGATE TOTAL- Flammable Gases/COMPRESSED GASES 600.0000 Cf -
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at anytime.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 14
- - - - - - - .- - - - - - - - - - - - Air Products -Existing H3H7 -Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Flammable Liquids I-B/LIQUIDS
Item CAS# State Conc% Material Hazard Class
23 67-63-0 1 *70 Isopropanol [Isopropyl Alcohol] 12- FL1B, IR
Propanol) (Alcohol] [A870-25 Solder Flux)
(425 Thinner] (LD50-0 >1840 mg/kg;
1.1350-S13000 mg/kg) [FP 53oF: BP
82.5oC) [LEL: 2.5%; UEL: 12%) (SG
0.785; VD 2.0791 (LD50-0 5045 mg/kg)
[RTECS# NT8050000] (HR: H2 F3]
24 121-46-0 1 100 Bicyclo[2.2.1]hepta-2,5-diene [2,5- FL1B, IR
Norbomadiene] (Norbornadiene) [BP
89oC; FP 12oF](Aidiicli B33803] (HR: F3
H2]
Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
110.0000 Gins 0.0000 Gins 0:0000 Gins New-1969/B1-Chemical
Production 313 [former TEOS
area & Filling Station)
1.3000 Gins 0.0000 Gins 0.0000 Gins Y Existing-1969/B1-Chemical
Production [315)
25 110-54-3 L 100 Hexane (n-) [BP 156oF; FP -lOoF] (LEL: FL1B, IR 15.0000 Gins 31.7007 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
1.1; UEL: 7.51 (SG 0.655; VD 2.983) Production [313.315,316]
[LD50-0 28710 mg/kg] (RTECS#
MN9275000] [HR: H2 F3]
26 2031-62-1 L 100 Methydiethoxysilane [Diethoxy- FL1B, IR 0.0000 Gins 755.0000 Gins 0.0000 Gins New-1969/BI-Chemical
methylsilane] (Aldrich 666121: [mw 134.25 Production 316 (former BBr3 area
g!mol]; (FP 50oF; BP 20109: [SG 0.838: & Filling Station]
27 12143-7 L 100 Tnmethyl Borate [Methyl Borate) FL1B, HT, IR, WR1 0.5000 Gins 223.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
(Trimethoxyborine) (Boric Acid, Tnmethyl Production [313]
Ester) (TMB] IMP -34oC; FP 8-17oF; BP
69oC] (SG 0.927; VD 3.59) (LDSO-O 140
mg/kg; 1D50-S 198 mg/kg) (RTECS#
ED5600000) (Aldrich 447218) (HR: H4 F3
RI WR]
28 67-64-1 L 100 Acetone (2-Propanone)(Autoignition: FL1B, IR 2.0000 Gins 2.0000 Gins 0.5000 Gins Y Existing - 1969/81-Chemical
869oF: FP loF: BP 133oF) (LEL: 2.6%: Production [313, 315, 316]
UEL: 12.80/4 ND: 2.01; SG 0.786: VP:
120.71 (FV per Gin: 2020 ci) [RTECS# -
AL3150000] (HR: H2 F3)
29 150-46-9 L 100 Tdethylborate (TEBI (Tnethoxyborane) FL1B, IR, OHH 1.0000 Gins 255.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
[FP 52oF; BP 117oC) (RTECS# Production [313)
ED5075000) (HR: F3 H2]
Storage Amount = Maximumltotal amount in use and storage; unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time:
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRLJCKNER & ASSOC. - 7/13/2010- PAGE 15
mmm mmm - _ ---- --
Air Products -Existing 1-131-17 -Production [Rooms 313, 315, 316] - 1969 Palomar Oaks Way, Carlsbad, CA: Flammable Liquids I-B/LIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
30 67-63-0 L *70 Isopropanol [Isopropyl Alcohol] (2- FL1B, IR 0.0000 Gins 80.0000 Gins 0.0000 Gins Y New-1969!81-Chemical
Propanol) (Alcohol] [A870-25 Solder Flux] Production 313 (former TEOS
1425 Thinner] [LD50-0 >1,840 mg/kg; area & Filling Station]
LD50-S13,000 mg/kg] [FP 53oF; BP
82.5oC] (LEL: 2.5%; UEL: 120A) (SG
0.785; VU 2.079] [L050-0 5045 mg/kg]
[RTECS# N180500001 (HR: H2 1731
31 352535-014 L 100 Tetrakis(ethylmethylamido)hafnium(IV) FL1B, CR, WR2 2.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 19690-Chemical
[TEMAH] (Aldrich 553123]: [mw 410.9 . Production (315]
ghnol]; [FP 52oF; BP 174.2oF]; [SG
1.324]; [H3-F2-R2]
32 109-99-9 L 100 Tebahydrofuran [FP loF; BP 69oC](LEL FLIB, IR, OHH, SN 5.0000 Gins 0.0000 Gins 0.0000 Gins V . Existing - 1969/81-Chemical
1.8; UEL 11.8] [SG 0.889; VD 2.5] [LD50- Production (315]
01650 mg/kg; 1050 21,000 ppm]
[RTECS# LU5950000] (FIR: H2 F31
33 175923-04-3 L 100 Tetrakis(ethylmethylamido)zirconium(IV) FL1B, CR, OHH, 55.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/13I -Chemical
(Aldrich 5531311: [mw 323.63 glmol]; [FP WR3 . Production (315]
500F; BP 17809; [SG 1.049]; [1-13-F3-112]
34 3275-24-9 L 100 Tetrakis(Dimethylamino)Titanium CR, FL1B, WR2 0.5000 Gins 120.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
(TDMAT] (BP 50oC/0.5mm; FP 25oF; SG Production (313]
0.942; Density 0.947; VD 7.5; LEL 0.76;
UEL 4.11 [pH 11][HR: H3 F3 R2 CDR
WR]
35 156-60-5 L 100 Trans-1,2-Dichloroethene [Trans-1,2- FL1B, IR, OHH, 1.3000 Gins 0.0000 Gins - 0.0000 Gins V Existing - 1969/81-Chemical
Dichloroethylene] [TRANS] [FP 39oF; BP WR1 Production (313]
59oC] [LEL: 9.7°h UEL: 12.81M [LD50-0
1235 mg/kg; LD50-S >5gm/kg; LC50
24.100 ppm] [RTECS# KV9400000] [HR:
H2F3R1]
TOTAL - Flammable Liquids I-B/LIQUIDS 193.6000 Gins 1466.7007 Gins 0.5000 Gins
AGGREGATE TOTAL - Flammable Liquids 1-13ILIQUlDS 1660.8007 Gins
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC.'- 7/13/2010 - PAGE 16
Air Products - Existing H3H7 - Production [Rooms 313, 315, 316] - 1969 Palomar Oaks Way, Carlsbad, CA: Flammable Liquids I-C/LIQUIDS
Item CAS# . . State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
36 292-64-8 L 100 Cydooctane [FP 861 [HR: H2 1`31 FL1C,IR .1.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
Production [3151
37 2370-88-9 L . 100 Tetramethylcyclotetrasiloxane (1,3,5,7-) FL1C, IR, WR2 . 1.0000 Gins 185.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
[2,4,6,8-Tetramethylcydotetrasiloxane] Production [313]
[1MCTS] [TOMCATS] [MW 240.51] [MP -
69oC; BP 135oCI760mm; FP 75.2oF)
[LEL 0.7; UEL 10] LSG 0.991; VD 8] [HR:
H2 F3 R2 WRlHydrogen Evolution]
38 186598-40-3 1 100 Bis(Tert-Butylamino)Silane [BTBAS] [FP CR, FL1C, TX, 2.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
30oC (86oF); BP >195oF; Autoignition: WR2 . Production [313]
374o9 [LEL: 0.5%] (L050-Oral: 78 mg/kg)
(HR: H3 F3 R2 WR)
39 681-84-5 L 100 Tetramethyl Orthosilicate (Methyl Silicate) CR, FL1C . .1.3000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
(FP 84oF; BP 121019 EMP -4oF] (SG Production [315]
1.032; VI) 5.251 [RTECS# W9800000]
(HR: H3 F3 CORI
40 2172-02-3 L 100 Hafnium(IV)tert-butoxide(Aldrich FL1C,IR 5.0000 Gins 0.0000 Gins 0.0000 Gins V Existing-1969181-Chemical
445541): (mw 470.94 g/mol); [FP 82oF; . Production [315]
BP 19409; [SG 1.1661; [HO-F3-RO]
41 121-45-9 L 100 Tnmethyl Phosphite [TMPI] [Methyl CR, FL1C, OHH, 0.5000 GIns 185.0000 Gins 0.0000 Gins Y Existing - 1969181-Chemical
Phosphite] [Phosphorous Add, Tnmethyl WR1 Production (313,315,316]
Ester] [MP -78oC; BP illoC; FP 8209
[SG 1.054; VD 4.28) (RTECS#
TH14000001 (HR: H3 F3 Ri CORWR]
TOTAL - Flammable Liquids 1-CILIQUlDS 10.8000 Gins 370.0000 Gins 0.0000 Gins
AGGREGATE TOTAL - Flammable Liquids I-C/LIQUIDS 380.8000 Gins
Storage Amount = Ma)imumltotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 17
- - - - - - - - - - - - - - - Air Products -Existing H3H7 -Production [Rooms 313,315,- 316] -1969 Palomar Oaks Way, Carlsbad, CA: Highly ToxicsILlQUlDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
42 121-43-7 L 100 Trimethyl Borate [Methyl Borate) FL1B, HI, IR, Will 0.5000 Gins 223.0000 Gins 0.0000 Gins Y Existing - 1969/Bi-Chemical
(Trimethoxyborine) [Boric Acid, Tilmethyl Production 13131
Ester) (1MB) (MP -34oC; FP 8-17oF; BP
69oC) [SG 0.927; VD 3.59) (L050-0 140
mg/kg; LD50-S 198 mg/kg) [RTECS#
ED56000001 [Aldrich 447218] (HR: H4 F3
RI WR)
TOTAL - Highly Toxlcs/LiQUIDS •• 0.5000 Gins 223.0000 Gins 0.0000 Gins
AGGREGATE TOTAL - Highly ToxicsILlQUiDS 223.5000 Gins
Storage Amount= Maximumltotai amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at anytime.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 18
- - - - - - - - - - - - - - - - - - - Air Products -Existing H3H7 -Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Irritants/LIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
43 78-10-4 L 100 Tetraethylorthosilicate [Ethyl Olihosilicate) CL2, IR, OHH 5.0000 Gins 61.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
[Ethyl Silicate] (Tetraethyl Silicate] [TEOS] Production (313)
(LD50-0 6270 mg/kg; LD50-S 5878
mg/kg; 1C50-InhaIation: >2000 ppm) [FP
>125oF] [HR: H3 F2]
44 110-54-3 L 100 Hexane (n-) (BP 156oF; FP -100F] [LEL: FL1B, IR 15.0000 Gins 31.7007 Gins 0.0000 Gins V Existing - 19690-Chemical
1.1; UEL: 7.5] (SG 0.655; VD 2.983) Production [313, 315, 3161
[LD50-0 28710 mg/kg) [RTECS#
MN9275000) [HR: H2 F3]
45 71-55-6 L 475 Tnchloroethane(1,1,1-)[Methyt IR, OHH 0.3000 Gins 0.0000 Gins 0.0000 Gins Existing-1969/B1-Chemical
Chloroform] [CA] (Adhesive Thinner) Production [313]
[MP -35oC; BP 74oC/760mm; FP None]
[RTECS# KJ2975000] [HR: H2]
46 629-59-4 L 100 Tetradecane (N-) (MP 5.5oC; BP CL3B, IR 0.0000 Gins 5.0000 Gins 0.0000 Gins Existing - 1969/81-Chemical
252oCI760mm; FP 211o9 H2 Fl] Production [313,315,316]
47 12143-7 L 100 Tnmethyl Borate [Methyl Borate] FL1B, HT, IR, WR1 0.5000 Gins 223.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
(Trimethoxyborine) (Boric Acid, lnmethyl . Production (313]
Ester] [1'MB] (MP -34oC; FP 8-17oF; BP
69oC) [SG 0.927; VD 3.591 [LD50-0 140
mg/kg; 1050-S 198 mg/kg] (RTECS#
E05600000] (Aldrich 447218] [HR: H4 F3
Ri WRI
48 64742-54-7 L 100 Mineral Oil [Mineral Petroleum Distillate) CL3B, IR 0.0000 Gins 5.0000 Gins 0.0000 Gins Existing - 1969/81-Chemical
[AMOCO AW Oil) (Mobil Almo] (MX-237 Production (313,315,316)
Oil] [Cutting Oil] [Turbo T Oil 32] [Cindol]
[Vacuum Pump Oil] [Paraffinic Oil] (Tellus
Oil 321 (Waylube Spindle Oil) [FP 330-
475oF) (HR: Hi Fl]
49 9946-5 L 100 Terpinene (a-) [1-lsopropyl4Methyl-1,3- C12, IR 0.0000 Gins 260.0000 Gins 0.0000 Gins Existing - 1969/81-Chemical
Cyclohexadiene) [BP 173o; FP 115oF] Production [313]; New [315]
[RTECS# 0S8060000] [HR: H2 F2]
50 156-60-5 L 100 Trans-i ,2-Dichloroethene [Trans-1,2- FL1B, IR, OHH, 1.3000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
Dichloroethylene) [TRANS] [FP 39oF; BP WR1 Production [313]
59oC] [LEL: 9.70A LJEL: 12.80/4 [LD50-0
1235 mg/kg; 1050-S >5gm/kg; LCSO
24,100 ppm] [RTECS# KV9400000) (HR:
H2F3RI]
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 19
- - - - - - - - - - - - - - - - - - - Air Products -Existing H3H7 -Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Irritants/LIQUIDS
Item CAS# State Conc% Material I Hazard Class
51 512-56-1 L 100 Trimethyl Phosphate (TMPO] (Methyl CA, IR, OHH, P65
Phosphonate] IMP -46oC; BR 197oC; FP
None] [LD50-0 840 mglkg)(RTECS#
TC82250001 [Aldrich 241024] (HR: 1-121
-
52 67-64-1 L 100 Acetone [2-Propanone] [Autoignilion: FL1B, IR
869oF; FP loF; BP 13309 [LEL: 2.6°4
UEL: 12.8%] [VD: 2.01; SG 0.786; VP:
120.7] [FV per Gin: 2020 ci] (RTECS#
AL31500001 (HR: H2 F31
Storage Units Use-Closed Units Use-Open Units Cabs >15Psl Location
0.3000 Gins 88.5000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
Production [313, 315,316]
2.0000 Gins 2.0000 Gins 0.5000 Gins V Existing - 1969/B1 -Chemical
Production [313,315,316]
53 99-86-5 L 100 Terpinene (a-) (1 CL2, IR 0.0000 Gins 40.0000 Gins 0.0000 Gins V New-1 969/81-Chemical
1730; FR 115oF] Production 313 [former TEOS
)l [HR: H2 F21 area & Filling Station]
54 150-46-9 L 100 Triethylborate (TEB) (Triethoxyboranel FL1B, IR, OHH 1.0000 Gins 255.0000 Gins 0.0000 Gins V Existing - 19691B1-Chemical
[FP 52oF; BR 117oC] [RTECS# Production [313]
E050750001 IHR: F3 1-121
55 292-64-8 L 100 Cydooctane (FP 861 [HR: H2 F3] FL1C,IR 1.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
Production [315]
56 99-86-5 L 100 Terpinene(a-)[1-Isopropyl4-Methyl-1,3- CL2,IR 110.0000 Gins 40.0000 Gins 0.0000 Gins New-1969181-Chemical
Cydohexadiene)(BP 1730; FP 115oFJ Production 313 [former TEOS
[RTECS# 0S80600001 [HR: H2 1`21 area & Filling Station]
57 109-99-9 L 100 TelTahydrohjran [FP loF; BR 69oC)(LEL FL1B, IR, OHH, SN 5.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
1.8; UEL 11.8] (SG 0.889; VD 2.5] (LDSO- Production [315]
01650 mg/kg; LCSD 21,000 ppm)
[RTECS# L115950000] (HR: H2 F31
58 2172-02-3 L 100 Hafnium(IV) tert-butoxide [Aldrich FL1C, IR 5.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
4455411: (mw 470.94 glmol]; [FR 82oF; Production [315]
BP 19409; [SG 1.166]; (HO-F3-RO)
59 9016-00-6 L 100 Polydimethylsiloxane (Latex) [Dow CL3B, IR, OHH 0.0000 Gins 36.3000 Gins 0.0000 Gins Existing - 1969181-Chemical
Coming 3601 (Latex 25881 (FR >20009 Production (313, 315, 316]
(RTECS# TQ26900001 [HR: Fl Hi]
60 2031-624 L 100 Methydiethoxysilane (Diethoxy- FL1B, IR 0.0000 Gins 755.0000 Gins 0.0000 Gins New-19691B1-Chemical
melhylsilane) [Aldrich 666121: [mw 134.25 Production 316 [former BBr3 area
glmo; (FR 500F; BP 20109; (SG 0.838; & Filling Station)
VD 4.6]; 1-12-F3-R0]
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 20
- M M - M - - - M M - -
Air Products -Existing H3H7 -Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Irritants/LIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
61 121-46-0 L 100 Bicydo(2.2.1]hepta-2,5-diene12,5- FL1B,IR 1.3000 Gins 0.0000 Gins 0.0000 Gins Y Existing-1969181-Chemical
Norijomadiene) [Norbomadiene] (BP Production 13151
89oC; FP 1209 [Aldrich B33803] [HR: F3
H2]
62 67-63-0 L 470 Isopropanol [Isopropyl Alcohol] (2- FL1B.(R 0.0000 Gins 80.0000 Gins 0.0000 Gins Y New-1969181-Chemical
Propanol] [Alcohol] [A870-25 Solder Flux] Production 313 [former TEOS
[425 Thinner] (LD50-0 >1.840 mg/kg; area & Filling Station]
LD50-S13,000 mg/kg] [FP 53oF; BP
82.5oC](LEL: 2.50/6; UEL: 12%) [SG
0.785; VD 2.0791(L050-0 5045 mg/kgl
(RTECS# N18050000) [HR: H2 F31
63 2370-88-9 L 100 Tetramethylcydotetrasiloxane (1,3,5,7) FL1C, IR, WR2 1.0000 Gins 185.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
[2,4,6,8-Tetramethylcydotetrasiloxane] Production 13131
(1'MCTS] [TOMCATS] [MW 240.511 IMP -
69oC; BP 135oC/760mm; FP 75.2oF]
(LEL 0.7; UEL 10] (SG 0.991; VD 8] [HR:
H2 F3 R2 WR/Hydrogen Evolution]
64 67-63-0 L 470 Isopropanol (Isopropyl Alcohol] 12- FL1B, IR 110.0000 Gins 0.0000 Gins 0.0000 Gins New-1969/B1-Chemical
Propanol] [Alcohol] [A870-25 Solder Flux] Production 313 (former TEOS
[425 Thinner] [LD50-0 >1,840 mg/kg; area &Filling Station]
LD50-S13,000 mg/kg] [FP 53oF; BP
82.5oC] ILEL: 2.50A; UEL: 12%) [SG
0.785; VD 2.0791 [LD50-0 5045 mg/kg]
IRTECS# NT80500001 [HR: H2 F31
TOTAL - Irritants/LIQUIDS 258.7000 Gins 2067.5007 Gins 0.5000 Gins
AGGREGATE TOTAL - Irritants/LIQUIDS 2326.7007 Gins
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 21
- - - - - - = - M M - - - - - - - - _
Air Products - Existing H31-17 - Production [Rooms 313, 315, 316] - 1969 Palomar Oaks Way, Carlsbad, CA: Irritants/SOLIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psl Location I
65 00-01-146 S 100 Safe Step [Aluminum Silicates] [KR: H2] IR 0.0000 Lbs 60.0000 Lbs 0.0000 Lbs Existing - 1969/81-Chemical
Production (313,315:3161
66 13499-05-3 S 100 Hafnium chloride [MP 319oC](Acros IR 0.0000. Lbs 31.0000 Lbs 0.0000 Lbs New-1969!B1-Chemical
29325] [KR: H2] Production 316 [former POCI3
area & Filling Statibnj
67 128-37-0 S 100 Di-tert-Butyl4-Methylphenol (2,6-) (Butyl- IR 5.0000 Lbs 0.0500 Lbs 0.0000 Lbs V Existing - 1969/81-Chemical
4-Hydroxymethylphenolj [Butylated . . Production (313, 315]
Hydroxytoluene] [BHT] [Aldrich D47404]
(HR: H21 -
TOTAL - Irritants/SOLIDS. 5.0000 Lbs 91.0500 Lbs 0.0000 Lbs
AGGREGATE TOTAL - Irritants/SOLIDS 96.0500 Lbs
Storage Amount= Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at anytime.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 22
- - - - - - = - - - - - - - - -
Air Products - Existing H3H7 - Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Nonhazardous/Unregulated Materials/SOLIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs' >15Psl Location
68 744044-0 S 100 Carbon [Acvtivated Carbon NH 0.0000 Lbs 600.0000 Lbs 0.0000 Lbs Existing - 1969/81 -Chemical
Filtration/Treatment System - Production [313, 315,3161
.,. C.,...,..,..,,...41 ILID. fli
TOTAL - Nonhazardous/Unregulated Materials/SOLIDS 0.0000 Lbs 600.0000 Lbs 0.0000 Lbs
AGGREGATE TOTAL - Nonhazardous/Unregulated Materials1SOL 600.0000 Lbs
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at anytime.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 23
Air Products - Existing H3H7 - Production [Rooms 313, 315, 316] - 1969 Palomar Oaks Way, Carlsbad, CA: Other Health Hazards/LIQUIDS
Item CAS# State Conc% --Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >1513si Location
69 78-10-4 L 100 Tetraethylorthosilicate (Ethyl Orthosilicate] CL2, IR, OHH 5.0000 Gins 61.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
(Ethyl Silicate] [Tetraethyl Silicate] [EOS) Production (313)
(LD50-0 6270 mg/kg; LD50-S 5878
mg/kg; LC50-lnhalation: >2000 ppm) [FP
>12509 [HR H3 F2]
70 78-40-0 L 100 Triethyl Phosphate [Ethyl Phosphate] CL3B, OHH, WR1 1.0000 Gins 185.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
(TEPO) [BP 215oC; FP 24009 (RTECS# Production [313, 315, 3161
1C7900000) [HR: H2 Fl Ri]
71 15606-95-8 L 100 Triethylarsenate [TEASAT) [TEAsat] CL3B, CR, OHH, 6.0000 Gins 0.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
[Ethyl Arsenate, Arsenic Acid Triethyl CA, TX, SN, WR2 Production (315)
Ester]: [mw 226.1 gImo; (FP 2300F; BP
457°F]: [SG 1.302; VD 7]; [L050-Oral:
71mglkg]; [H3-F2-R2]
72 1759234)4-3 L 100 Tetrakis(ethylmethylamido)zirconium(IV) FL1B, CR, OHH, 55.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
[Aldrich 553131]: [mw 323.63 glmo: [FP WR3 Production [315]
500F; BP 17809; [SG 1.049]; [H3-F3-R2]
73 156-60-5 L 100 Trans-i ,2-Dichloroethene [Trans-1,2- FOB, IR, OHH, 1.3000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
Dichloroethylene] [TRANS] (FP 39oF; BP WR1 Production (313)
59oC] (LEL: 9.7%; UEL: 12.8Y4 (LD50-0
1235 mg/kg; LD50-S >5 gm/kg; LC50
24,100 ppm) [RTECS# KV9400000] [HR:
H2F3R1]
74 67-63-0 L >I70 Isopropanol Psopropyl Alcohol] [2- - FOB, IR 110.0000 Gins 0.0000 Gins 0.0000 Gins New-1969/81-Chemical
Propanol] [Alcohol] [A870-25 Solder Flux] Production 313 (former TEOS
(425 Thinner) (LD50-0 >1,840 mg/kg; area & Filling Station)
LD50-S13,000 mg/kg] [FP 53oF; BP
82.5oCJ(LEL: 2.5%: UEL: 120A) (SG
0.785; VD 2.079] [LD50-0 5045 mg/kg]
[RTECS# NT8050000) fHR: H2 F3)
75 9016-00-6 L 100 - Polydimethylsiloxane [Latex] (Dow CL3B, IR, OHH 0.0000 Gins 36.3000 Gins 0.0000 Gins Existing - 1969/81-Chemical
Coming 3601 [Latex 2588] [FP >20009 Production [313,315,316]
[RTECS#TQ2690000] [HR: Fl Hi]
76 512-56-1 L 100 Trimethyt Phosphate (TMPOJ [Methyl CA, IR, OHH, P65 0.3000 Gins 88.5000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
Phosphonate] [MP 46oC; BP 197oC; FP Production [313, 315, 3161
None) (LD50-0 840 mg/kg) (RTECS#
1C8225000) (Aldrich 2410241 (HR: 1-121
Storage Amount = Maximumltotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 24
- -. - - - - - - - - - - Air Products -Existing H3H7 -Production [Rooms 313, 315, 316] 1969 Palomar Oaks Way, Carlsbad, CA: Other Health Hazards/LIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
77 71-55-6 L >/75 Trichloroethane(1,1,1-)(Methyl IR, OHH 0.3000 Gins 0.0000 Gins 0.0000 Gins Existing-1969/B1-Chemical
Chloroform) IFCA) [Adhesive Thinner] Production [313)
[MP -35oC; BP 74oCI760mm; FP None]
[RTECS# KJ29750001 (HR: 1-12)
78 12145-9 L
79 109-99-9 L
80 .150-46-9 L
100 Trimethyl Phosphite [IMPl] (Methyl CR, FL1C, OHH,
Phosphite] [Phosphorous Acid, Tnmethyl WR1
Ester) [MP -78oC; BP liloC; FP 82019
[SG 1.054; VD 4.28) (RTECS#
TH1400000] [HR: H3 F3 RI CORWR)
100 Tetrahydrofuran [FP loF; BP 69oC] [LEL FL1B, IR, OHH, SN
1.8; UEL 11.8] [SG 0.889; VD 2.51 [U)50-
0 1650mg/kg; LC50 21,000 ppm)
(RTECS# LU5950000] [HR: H2 F3]
100 Triethylborate [1E81 (Triethoxyborane) FOB, IR, OHH
(FP 52oF; BP 117oC) [RTECS#
ED5075000] [HR: F3 H2)
0.5000 Gins 185.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
Production [313,315,316]
5.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
Production [315]
1.0000 Gins 255.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
Production [313]
I 67-63-0 L '/70 Isopropanol (Isopropyl Alcohol) [2- FL1B, IR
Propanol] [Alcohol] [A870-25 Solder Flux)
1425 Thinner] (L050-0 >1,840 mg/kg;
LD50-S13,000 mg/kg) [FP 53oF; BP
82.5oC) [LEL: 2.50%; UEL: 12%) (SG
0.785; /D 2.0791 (LD50-0 5045 mg/kg]
(RTECS# NT8050000) [HR: H2 F3]
0.0000 Gins 80.0000 Gins 0.0000 Gins V New-1969181-Chemical
Production 313 [former TEOS
area & Filing Station]
TOTAL - Other Health Hazards/LIQUIDS . 185.4000 Gin's 890.8000 Gins 0.0000 Gins
AGGREGATE TOTAL - Other Health IlazardsILIQUIDS 1076.2000 Gins
Storage Amount = Maximumltotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010- PAGE 25
- - - - - - - - - - - - - - Air Products -Existing 1-131-17 -Production [Rooms 313,315,316]-1969 Palomar Oaks Way, Carlsbad, CA: Oxidizer Gases/COMPRESSED GASES
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location I
82 778244-7 CG 100 Oxygen 1021 law: 32.001 [12.08 cfilbj [HR: OX 0.0000 Cf 90.0000 Cl 0.0000 Cf V Existing - 1969/81-Chemical
OXG] Production [313, 315,316]
TOTAL - Oxidizer GasesICOMPRESSED GASES 0.0000 Cf 90.0000 Cf 0.0000 Cf
AGGREGATE TOTAL - Oxidizer Gases/COMPRESSED GASES 90.0000 Cf
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS- KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 26
Air Products -.Existing 1-131-17 -Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: CA-Prop65ILlQUlDS
Item CAS# •.,. . -. State Conc% Material Hazard Class - Storage Units Use-Closed Units Use-Open Units Cabs >15Psl Location
83 512-56-1 , - L 100 lnmethyl Phosphate [MPO] (Methyl CA, IR, OHH, P65 0.3000W' Gins 88.5000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
Phosphonate) (MP 46oC; BP 197oC: FP . , Production [313, 315,316]
None] [LD50-0 840 mg/kg] IRTECS#
1C82250001 [Aldrich 2410241 IHR: 1-121 -
TOTAL - CA.Prop65!UQUIDS
-
0.3000 Gins 88.5000 Gins 0.0000 Gins
AGGREGATE TOTAL - CA-Prop65ILIQUlDS 88.8000 Gins
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. -711=010- PAGE 27
- - - - - - - - - - - - - - - Air Products - Existing H31-17 - Production [Rooms 313, 315 316] - 1969 Palomar Oaks Way Carlsbad, CA: RMP Table2!Federal Regulated Flammable Substances/CO
Item CAS# State Conc% Material - Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location I
84 1333-74-0 CG 100 Hydrogen [1-12] [mw: 2.02) [Flammable FG, RMP-T2 0.0000 Cf 600.0000 Cf 0.0000 Cf V Existing - 1969/81-Chemical
Range in Air: 4.1-74.2%) (192 cf/Ibi [HR: Production [313,315,316]
F4]
TOTAL - RMP Table2IFederaI Regulated Flammable Substances! 0.0000 Cf 600.0000 Cf 0.0000 Cf
AGGREGATE TOTAL RMP TabIe2!Federal Regulated Flammable 600.0000 Cf
Storage Amount = Maximumltotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at anytime.
Automatic fire sprinkler system protection. .
. HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 28
- - - - - - - - - - - - - Air Products - Existing 1-131-17 .Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Sensitizers/LIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
85 15606-95-8 L 100 Tnethylarsenate [EASA11 (TEAsat) CL3B. CR, OHH, 6.0000 Gins 0.0000 Gins 0.0000 Gins Y Existing - 1969/81-Chemical
(Ethyl Arsenate, Arsenic Acid Triethyl CA, TX, SN, WR2 Production [3151
Ester]: [mw 226.1 glmol]; [FP 2300F; BP
457oF]; (SG 1.302; VD 71; (LD50-oral:
71mg/kg); [H3-F2-R2]
86 109-99-9 L 100 Tetrahydrofuran (FP loF; BP 69oCflLEL FL1B, IR, OHH, SN 5.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
1.8; UEL 11.81 [SG 0.889; VD 2.5] (LD50- Production 13151
01650 mg/kg; LC50 21,000 ppm)
(RTECS# LU59500001 (HR H2 F3)
TOTAL - Sensitizers/LIQUIDS 11.0000 Gins 00000 Gins 0.0000 Gins
AGGREGATE TOTAL - Sensitizers/LIQUIDS 110000 Gins
Storage Amount = Maximumitotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 29
- - - - - - - - - - - - - = - - - - Air Products -Existing H3H7 -Production [Rooms 313, 315, 316] - 1969 Palomar Oaks Way, Carlsbad, CA: Toxics/LIQUIDS
Item. CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
87 15606-95-8 L 100 Triethylarsenate ITEASATI [rEAsati CL3B, CR, OHH, 6.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
(Ethyl Arsenate, Arsenic Acid Triethyl CA, TX, SN, WR2 Production (315]
Ester]: 1mw 226.1 glmol]; [FP 2300F; BP
45709; (SG 1.302; VD 7j; (LD50-Oral:
71mg/kg]; [H3-F2-R2]
88 186598-40-3 L 100 8i5(Tert-Butylamino)Silane IBTBASI (FP CR, FL1C, TX, . 2.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
300C (86oF); BP >195oF; Autoignition: WR2 Production (313]
374oF] (LEL: 0.5%] [LDSO-Oral: 78 mg/kg]
[HR:H3F3R2WR]
TOTAL - ToxlcsILlQUlDS 8.0000 Gins 0.0000 Gins 0.0000 Gins
AGGREGATE TOTAL. ToxlcsILlQUlDS
-
80000 Gins
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 30
- - - - - - - - - - - - - --
Air Products -Existing H3H7 -Production [Rooms 313, 315, 316] - 1969 Palomar Oaks Way, Carlsbad, CA: Water Reactives 1/LIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psl Location
89 78-40-0 L 100 Triethyl Phosphate [Ethyl Phosphate] CL3B, 01-11-1,WR1 1.0000 Gins 185.0000 Gins 0.0000 Gins V Existing - 1969/81 -Chemical
[FEPO) (BP 215oC; FP 24009 [RTECS# Production 1313, 315, 3161
1C79000001 (HR: 112 Fl Ri)
90 156-60-5 L 100 Trans-1,2-Dichloroethene [Trans-1,2- FL1B, IR, OHH, 1.3000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969/Bi-Chemical
Dichloroethylene] [TRANS] [FP 39oF; BP WR1 Production (313]
59oC) [LEL: 9.7%; UEL: 12.8%] [LD50-0
1235 mg/kg; LD50-S >5gm/kg; LC50
24,100 ppm] [RTECS# KV9400000] [KR:
H2F3R1]
91 121-46-9 L 100 Inmethyl Phosphite (TMPI] [Methyl CR, FL1C, OHH, 0.5000 Gins 185.0000 Gins 0.0000 Gins V Existing - 1969/131-Chemical
Phosphite] (Phosphorous Acid, Tilmethyl WR1 Production P13, 315, 3161
Ester) [MP -78oC; BP 111oC; FP 8209
(SG 1.054; VD 4.281 [RTECS#
TH1400000] [HR: H3 F3 Ri CORWR]
92 12143-7 L 100 Trimethyl Borate [Methyl Borate] FL1B, HI, IR, WR1 0.5000 Gins 223.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
(Trimethoxyboline) [Boric Acid, Trimethyl Production [313)
Ester) [FMB) [MP -34oC; FP 8-17oF; BP
69oC] [SG 0.927; VD 3.59] (LD5O-0 140
mg/kg; LD5O-S 198 mg/kg) [RTECS#
ED5600000) [Aldrich 447218] [KR: 114 F3
RI WR]
TOTAL -Water Reactives 1/LIQUIDS 3.3000 Gins 593.0000 Gins 0.0000 Gins
AGGREGATE TOTAL - Water Reactives 1/LIQUIDS 596.3000 Gins
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010- PAGE 31
- - - - - - - - - - - - - - -
Air Products -Existing H31-117 -Production (Rooms 313,315,3161-1969 Palomar Oaks Way, Carlsbad, CA: Water Reactives 2ILIQUIDS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location
93 15606-95-8 L 100 lnethylarsenate (TEASA1] (TEAsat) CL3B. CR, OHH, 6.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
(Ethyl Arsenate, Arsenic Acid Triethyl CA, TX, SN, WR2 Production [315]
Ester]: 1mw 226.1 glmoq; (FP 2300F; BP
457o9; [SG 1.302; VD 7]; (L050-Oral:
llmglkg]; (H3-F2-R2)
94 352535-01-4 L 100 Tetrakis(ethylmethylamido)hafnium(IV) FL18, CR, WR2 2.0000 Gins 0.0000 Gins 0.0000 Gins V Existing - 1969181-Chemical
[TEMAH] [Aldrich 553123]: [mw 410.9 Production (315)
glmol]; FP 52oF; BP 174.2019; (SG
1.324); (H3-F2-R2)
95 186598-40-3 L 100 Bis(rert-Butylamino)Silane [BTBAS] (FP CR, FL1C, TX, 2.0000 Gins 0.0000 Gins 0.0000 Gins Y Existing - 1969181-Chemical
30oC (866); BP >195oF; Autoignition: WR2 Production (313)
374oF] (LEL: 0.5%] [LD50-Oral: 78 mglkg]
[HR: H3 F3 R2 WR]
96 2370.88-9 L 100 Tetramethylcyclotetrasiloxane (1,3,5,7-) FL1C, IR, WR2 1.0000 Gins 185.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
(2,4,6,8-Tetramethylcydotetrasiloxane) Production [313]
[FMCTS] (TOMCATS] [MW 240.51] [MP -
69oC; BP 135oC!760mm; FP 75.209
[LEL 0.7; UEL 10] (SG 0.991; VD 8] [HR:
H2 F3 R2 WRlHydrogen Evolution]
97 3275-24-9 L 100 Tetrakis(Dimethytamino)litanium CR, FL1 B, WR2 0.5000 Gins 120.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
[TOMAT) [BP 50oCI0.5mm; FP 25oF; SG Production [313]
0.942; Density 0.947; VD 7.5; LEL 0.76;
UEL'4.1] [pH 111 [HR: H3 F3 R2 CDR
TOTAL - Water Reactives 2/LIQUIDS . 11.5000 Gins 305.0000 Gins 0.0000 Gins
AGGREGATE TOTAL - Water Reactives 2ILIQUIDS 316.5000 Gins
Storage Amount = Maximum/total amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at anytime.
Automatic fire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010 - PAGE 32
- - - - - - - - - - - - - - - - - - Air Products -Existing H3H7- Production [Rooms 313, 315, 316] -1969 Palomar Oaks Way, Carlsbad, CA: Water Reactives 31L1QU1DS
Item CAS# State Conc% Material Hazard Class Storage Units Use-Closed Units Use-Open Units Cabs >15Psi Location I
98 175923-04-3 L 100 Tetrakis(ethylmethylamido)zirconium(IV) FL1B, CR, OHH, 55.0000 Gins,. 0.0000 Gins 0.0000 Gins V Existing - 1969/81-Chemical
[Aldrich 553131]: (mw 323.63 g!mol): LFP WR3 Production (315)
500F; BP 178oFJ; [SG 1.0491; 1H3-F3-R2]
TOTAL - Water Reactives 3/LIQUIDS 55.0000 Gins 0.0000 Gins 0.0000 Gins
AGGREGATE TOTAL - Water Reactives 31L1QU1D5 55.0000 Gins
Storage Amount = Maximumitotal amount in use and storage, unless otherwise noted. Not all materials are in use at the same time, with <10% in use at any time.
Automatic lire sprinkler system protection.
HAZARDOUS MATERIALS/OCCUPANCY CLASSIFICATION ANALYSIS - KLAUSBRUCKNER & ASSOC. - 7/13/2010- PAGE 33
Hazardous Materials Classification Definitions Page 34
Class Name Hazard*
ALl Aerosols Level I P
AL2 Aerosols Level 2 P
AL3 Aerosols Level 3 P
CA Carcinogens . H
CD Combustible Dusts P
CF Combustible Fibers P
CL2 Combustible Liquids II P
CL3A Combustible Liquids Ill-A P_______
CUB Combustible Liquids Ill-B P_______
CR Corrosives H_______
EX Explosives P_______
FG Flammable Gases P_______
FLIA Flammable Liquids I-A P_______
FL1B Flammable Liquids I-B P_______
FLIC Flammable Liquids I-C P_______
FS Flammable Solids P
HT Highly Toxics H
IR Irritants H
NH Nonhazardous Materials
OHH Other Health Hazards H
OPI Organic Peroxides I P
0P2 Organic Peroxides II P
0P3 Organic Peroxides Ill P
ON Organic Peroxides IV P
OX Oxidizer Gases P
OXI Oxidizers 1 P
OX2 Oxidizers 2 P
OX3 Oxidizers 3 P
OX4 Oxidizers 4 P
py Pyrophorics P
RAD Radioactive H
RADA Radioactive - Alpha H
RADB Radioactive - Beta H
RADG Radioactive - Gamma H
SN Sensitizers H
TX Toxics H
UR1 Unstable Reactives 1 P
UR2 Unstable Reactives 2 P
UR3 Unstable Reactives 3 P
UR4 Unstable Reactives 4 P
WRI Water Reactives 1 P
WR2 Water Reactives 2 P
WR3 Water Reactives 3 P
OP Organic Peroxides - Unclassified Detonable P
CRY-NH Cryogenic Liquids - Non Hazardous P
CRY-F Cryogenic Liquids - Flammable P
CRY-OX Cryogenic Liquids - Oxidizing P
OP5 Organic Peroxides V P
CL2-NFP Combustible Liquids 11-No Fire Point P
CL3A-NFP Combustible Liquids Ill-A-No Fire Point P
CL3B-NFP Combustible Liquids Ill-B-No Fire Point P
*California Fire Code Health or Physical Hazards .
Hazardous Materials Classification Definitions Page 35
Class Name Hazard*
FLIA-NFP Flammable Liquids I-A-No Fire Point P
FLIB-NFP Flammable Liquids I-B-No Fire Point P
FL1C-NFP Flammable Liquids I-C-No Fire Point P
CA-CP Carcinogens-Consumer Products H
R-CP Irritants-Consumer Products H
OHH-CP Other Health Hazards-Consumer Products H
SN-CP Sensitizers-Consumer Products H
SlED Special Industrial Explosive Devices P
P65 CA-Prop65
PSM PSM-OSHA
RMP-T1 RMP Tablel/Federal Regulated Substances
RMP-12 RMP Table2/Federal Regulated Flammable Substances
RMP-13 RMP Table3/CA Regulated Substances
FRS Federal Regulated Substances
FRF Federal Regulated Flammable Substances
SRS State Regulated Substances
*California Fire Code Health or Physical Hazards
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I 2001 CALIFORNIA CODES ANALYSIS - HAZARDOUS MATERIALS DEFINITIONS
ACID
I
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Corrosive material whose water solutions contain hydrogen ions.
Will liberate hydrogen gas on contact with certain metals.
Forms a salt when it reacts with a base.
Tastes sour.
Turns blue litmus paper red.
Very chemically active.
Burn, irritate or destructively attack organic tissue such as the skin, lungs, stomach.
Generally incompatible with bases [alkalis].
pH=<I=lto<7
AEROSOL
A product dispensed from an aerosol container by a propellant.
Level 1: Chemical heat of combustion >0 and <1=8,600 Btu/lb.
Level 2: Chemical heat of combustion >8,600 Btu/lb and <13,000 Btu/lb.
Level 3: Chemical heat of combustion >13,000 Btu/lb.
AEROSOL CONTAINER
A metal can, up to a maximum size of 33.8 fluid ounces 11,000 mU designed to dispense an aerosol
product; or
A glass or plastic bottle, up to a maximum size of 4 fluid ounces [118 mL] designed to dispense an
aerosol product.
BASE (ALKALII
Corrosive materials whose water solutions contain hydroxyl ions.
Chemically opposite of an organic acid.
Forms a salt when it reacts with an acid.
Neutralies acids.
.. Very chemically active.
Burn, irritate or destructively attack organic tissues such as skin, lungs, stomach.
pH=>7t0>/=14
CARCINOGEN
I .• Substance that causes the development of cancerous growths in living tissue.
Chemical is considered to be a carcinogen if:
It has been evaluated by the International Agency for Research on Cancer [IARC] and found to be
a carcinogen; or
.
It is listed as a carcinogen or potential carcinogen in the Annual Report on Carcinogens published
by the National Toxicology Program; or
Regulated by OSHA as a carcinogen.
I CLOSED SYSTEM
See "Use-Closed System".
I COMBUSTIBLE DUST
Finely divided solid material which is </=420 microns in diameter and which, when dispersed in air in the
proper proportions, could be ignited by a flame, spark or other source of ignition.
I . Combustible dust will pass though a U.S. No. 40 Standard sieve.
Generally:
Particulate from wood sanding and grinding is "Combustible Dust".
Particulate from wood routing is not "Combustible Dust".
Particulate from wood sawing may or may not be "Combustible Dust".
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2001 CALIFORNIA CODES ANALYSIS - HAZARDOUS MATERIALS DEFINITIONS
I COMBUSTIBLE LIQUID
Flash point >/=1000F.
Class II Combustible Liquid: Flash point >/1000F and <1400F.
Class Ill-A Combustible Liquid: Flash point >/=1400F and <200oF.
I . Class Ill-B Combustible Liquid: Flash point >/=200oF.
DOT Class 3 Materials.
COMPRESSED GAS
I . A material, or mixture of materials, which:
Is a gas at 68oF or less at 14.7 psia of pressure; and
Has a boiling point of 68oF or less at 14.7 psia which is either liquefied, nonliquefied or in solution,
except those gases which have no other health or physical hazard properties are not considered to
I be compressed until the pressure in the packaging exceeds 41 psia at 68oF.
. The states of a compressed gas are categorized as follows:
Nonliquefied Compressed Gases: Gases, other than those in solution, which are in a packaging
1 .
under charged pressure and are entirely gaseous at a temperature of 68oF.
Liquefied Compressed Gases: Gases, which in a packaging under charged pressure are partially
liquid at a temperature of 68oF.
Compressed Gases in Solution: Nonliquefied gases which are dissolved in a solvent.
Compressed Gas Mixtures: 2 or more compressed gases contained in a packaging, the hazard
I properties of which are represented by the properties of the mixture as a whole.
CORROSIVE
Any solid, liquid or gas causing visible destruction of, or irreversible alterations in, living tissue by
I chemical action at the site of contact.
Burns or destructively attacks organic tissues such as the skin, lungs, stomach -- i.e.: acids, bases,
caustics.
I
. General 'rule of thumb": pH </=2-3 and >/12
Test Data - CFR 49 Part 173: Destroys or changes irreversibly the structure of tissue at the site of
contact on albino rabbits following an exposure period of 4 hours.
DOT Class 8 Materials.
I FLAMMABLE GAS
, Material which is a gas at 68oF or less at 14.7 psia which:
Is ignitable at 14.7 psia which in a mixture of </=13% by volume with air; or
I
. Has a flammable range at 14.7 psi with air of at least 12%, regardless of the lower limit.
, The limits specified are determined at 14.7 psi of pressure ad a temperature of 68oF.
FLAMMABLE LIQUEFIED GAS
Liquefied compressed gas, which under charged pressure is partially liquid at a temperature of 68oF
I and which is flammable. .
FLAMMABLE LIQUID
I
. Liquid having a flash point <1000F and having a vapor pressure </=40 psia.
, Does not include compressed gases or cryogenic fluids.
. Class I Liquids include those having flash point <1000F and are subdivided as follows:
Flammable Liquid I-A: Flash point <73oF and boiling point <1000F
I
. Flammable Liquid I-B: Flash point <73oF and boiling point >/100oF
Flammable Liquid I-C: Flash point >/73oF and <IDDoF
DOT Class 3 Materials.
I
FLAMMABLE MATERIAL
Material that will readily ignite from common sources of heat; and
Materials that will ignite at a temperature of <I=6000F.
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FLAMMABLE SOLID
.Solid substance, other than one which is defined as a blasting agent or explosive, that is liable to cause
fire through friction or as a result of retained heat from manufacture, which has an ignition temperature
<212oF; or
. Solid substance that burns so vigorously or persistently when ignited that it creates a serious fire
hazard. . Flammable Solids include finely divided solid materials which when dispersed in air as a cloud may be
ignited and cause an explosion.
.DOT Class 4.1 Materials.
HAZARDOUS MATERIALS
Chemicals or substances are physical hazards or health hazards as defined and classified in UFC/CFC
Article 80 whether the materials are in usable or waste condition.
HAZARD RATING [DEGREES OF HAZARD]
Health [Blue]: Hazard rating of health hazards ranked according to the probable severity of the
effects of exposure to personnel as follows:
4: Materials that on very short exposure could cause death or major residual injury, including those
too dangerous to be approached without specialized protection equipment - i.e.:
* Inhalation/Absorption - Skin: Materials that, under normal conditions or under fire
conditions, are extremely hazardous through inhalation of through contact with or absorption by
the skin.
* Ingestion - Oral: Materials whose LD50 for acute oral toxicity is <1= 5 milligrams per kilogram
[mg/kg].
Skin: Materials whose LD50 for acute dermal toxicity !s</=40 milligrams per kilogram [mg/kg].
* Dusts & Mists - Inhalation: Dusts& mists Whose LC50for acute inhalation -toxicity is </=0.5
milligrams per liter [mg/L).
* Liquids - Inhalation: Liquid whose saturated vapor concentration at 200C is >/= 10 times its
LC50 for acute inhalation toxicity, if its LC50 is </=1,000 parts per million [ppm].
* Gases - Inhalation: Gas whose LC50 for acute inhalation toxicity is </=1,000 parts per million
[ppm].
3: Materials that on short exposure could cause serious temporary or residual. injury, including
those requiring protection form all bodily contact - i.e.:
* Combustion Products: Materials that give off highly toxic combustion products.
* Ingestion - Oral: Materials whose LDSO for acute oral toxicity is >5 milligrams and <1=50
milligrams per kilogram [mg/kg].
* Skin: Materials whose LD50 for acute dermal toxicity is >40 milligrams and </=200 milligrams
per kilogram [mg/kg].
* Dusts & Mists - Inhalation: Dusts & mists whose LC50 for acute inhalation toxicity is >0.5
and <1=2 milligrams per liter [mg/L].
* Liquids - Inhalation: Liquid whose saturated vapor concentration at 200C is >/= its LC50 for
acute inhalation toxicity, if its LC50 is </=3,000 parts per million [ppm] and does not meet the
criteria for degree of hazard 4.
* Gases - Inhalation: Gas whose LC50 for acute inhalation toxicity is >1000 and <3,000 parts
per million [ppm].
* Corrosive: Materials that are either severely corrosive to skin on single, short exposure or
cause irreversible eye damage.
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2001 CALIFORNIA CODES ANALYSIS - HAZARDOUS MATERIALS DEFINITIONS
HAZARD RATING [DEGREES OF HAZARD] - continued
Health [Blue] - continued:
2: Materials that on intense or short exposure could cause temporary incapacitation or possible
residual injury, including those requiring the use of respiratory protective equipment that has an
independent air supply -- i.e.:
* Combustion Products: Materials that emit toxic or highly toxic irritating combustion products.
* Lack of Warning Properties: Materials that, under normal conditions or fire conditions, give
off toxic vapors that lack warning properties.
* Ingestion - Oral: Materials whose LD50 for acute oral toxicity is >50 milligrams and </=500
milligrams per kilogram [mg/kg].
* Skin: Materials whose LD50 for acute dermal toxicity is >200 milligrams and <1=1,000
milligrams per kilogram [mg/kg].
* Dusts & Mists - Inhalation: Dusts & mists whose LC50 for acute inhalation toxicity is >2 and
<1=10 milligrams per liter (mg/L].
* Liquids - Inhalation: Liquid whose saturated vapor concentration at 200C is >1= 1/5 its LC50
for acute inhalation toxicity, if its LC50 is <1=5,000 parts per million [ppm] and does not meet
the criteria for degree of hazard 3 or 4.
* Gases - Inhalation: Gas whose LC50 for acute inhalation toxicity is >3,000 and </=5,000
parts per million [ppm].
* Irritant: Materials that cause severe but reversible respiratory, skin or eye irritation.
1: Materials that on short exposure could cause irritation, but only minor residual injury, including
those requiring the use of an approved air-purifying respirator -- i.e.:
* Combustion Products: Materials that emit irritating combustion products.
* Fire Conditions: Materials that, under fire conditions, cause skin irritation, but not destruction
of tissue.
* Ingestion - Oral: Materials whose LD50 for acute oral toxicity is >500 milligrams and </=2,000
milligrams per kilogram [mg/kg].
* Skin: Materials whose LD50 for acute dermal toxicity is >1,000 milligrams and </=2,000
milligrams per kilogram [mg/kg].
* Dusts & Mists -inhalation: Dusts & mists whose LC50 for acute inhalation toxicity is >10 and
</=200 milligrams per liter [mg/L].
* Gases & Vapors - Inhalation: Gas & vapor whose LC50 for acute inhalation toxicity is >5000
and </=10,000 parts per million [ppm].
* Irritant: Materials that are moderate respiratory irritants, or that cause slight to moderate eye
irritation.
0: Materialsthat on short exposure under fire conditions offer no hazard beyond that of ordinary
combustible materials - i.e.:
* Ingestion - Oral: Materials whose LD50 for acute oral toxicity is >2,000 milligrams per
kilogram [mg/kg].
* Skin: Materials whose LD50 for acute dermal toxicity is >2000 milligrams per kilogram
(mg/kg].
Dusts & Mists - Inhalation: Dusts & mists whose LC50 for acute inhalation toxicity is >200
milligrams per liter (mg/L].
* Gases & Vapors - Inhalation: Gas & vapor whose LC50 for acute inhalation toxicity is
>10,000 parts per million (ppm].
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2001 CALIFORNIA CODES ANALYSIS - HAZARDOUS MATERIALS DEFINITIONS
I HAZARD RATING [DEGREES OF HAZARD] - continued
. Flammability [Red]: Hazard rating of flammability hazards ranked according to the susceptibility of
materials to burning as follows:
4: Materials that will rapidly or completely vaporize at atmospheric pressure and normal ambient
I temperature or that are readily dispersed in air, and which will burn readily - i.e.:
* Flammable Gases.
* Flammable cryogenics.
* Any liquid or gaseous material that is liquid while under pressure and has a flash point <73oF
I and a boiling point <1000F [i.e.: Class I-A Flammable Liquid].
* Materials that ignite spontaneously when exposed to air [i.e.: Pyrophorics].
3: Liquids and solids that can be ignited under almost all ambient temperature conditions.
Materials in this degree produce hazardous atmospheres with air under almost all ambient
I temperatures or, though unaffected by ambient temperatures, are readily ignited under almost all
conditions -- i.e.:
* Liquids having a flash point <730F and having a boiling point >/100oF and those liquids
having a flash point >/=73oF and ci OOoF [i.e.: Class I-B & I-C Flammable Liquids].
I• Materials that on aunt of their physical form or environmental conditions can form explosive
mixtures with air that are readily dispersed in air [i.e.: dusts of combustible/flammable solids,
mists of flammable/combustible liquid droplets].
a Materials that burn with extreme rapidity, usually by reason of self-contained oxygen [i.e.:
I many Organic Peroxides, dry nitrocellulose].
2: Materials that must be moderately heated or exposed to relatively high ambient temperatures
before ignition can occur. Materials in this degree would not under normal conditions form
hazardous atmospheres with air, but under ambient temperatures or under moderate heating may
I release vapor in sufficient quantities to produce hazardous atmospheres with air - i.e.
a Liquids having a flash point >100oF and <I-200oF [i.e.: Class II & Class Ill-A Combustible
Liquids].
* Solid materials in the form of coarse dusts that may burn rapidly but that generally do not form
I explosive atmospheres with air [i.e.: Flammable Solids].
a Solid materials in a fibrous or shredded form that may burn rapidly and create flash fire
hazards [i.e.: cotton, sisal, hemp].
a Solids and semisolids that readily give off flammable vapors.
I . 1: Materials that must be preheated before ignition can occur. Materials in this degree require
considerable preheating, under all ambient temperature conditions, before ignition and combustion
can occur - i.e.:
a Materials that will burn in air when exposure to a tempura of 1500oF for </5 minutes.
I a Liquids, solids & semisolids having a flash point >200oF [i.e.: Class Ill-B Combustible Liquids].
. 0: Materials that will not burn -- i.e.: material that will not burn in air when exposed to a
temperature of 1500oF for a period of 5 minutes.
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2001 CALIFORNIA CODES ANALYSIS - HAZARDOUS MATERIALS DEFINITIONS
HAZARD RATING [DEGREES OF HAZARD] - continued
Reactivity/Instability [Yellow]: Hazard rating of reactivity [instability] hazards ranked according to
ease, rate and quantity of energy release as follows:
4: Materials that in themselves are readily capable of detonation or explosive decomposition or
explosive reaction at normal temperatures and pressures - i.e.:
* Materials sensitive to localized thermal or mechanical shock at normal temperatures and
pressures.
3: Materials that in themselves are capable of detonation or explosive decomposition or explosive
reaction, but that require a strong initiating source or that must be heated under confinement before
initiation - i.e.:
Materials sensitive to thermal or mechanical shock at elevated temperatures and pressures.
* Materials that reactive explosively with water without requiring heat or confinement.
2: Materials that readily undergo violent chemical change at elevated temperatures and pressures
-- i.e.:
* Materials that exhibit an exotherm at temperatures </=150oC when tested by differential
scanning calorimetry.
* Materials that may react violently with water or form potentially explosive mixtures with water.
1: Materials that in themselves are normally stable, but that can become unstable at elevated
temperatures and pressure - i.e.:
* Materials that change or decompose on exposure to air, light or moisture.
* Materials that exhibit an exotherm at temperatures >1500C but </=3000C when tested by
differential scanning calorimetry.
0: Materials that in themselves are normally stable, even under fire conditions -- i.e.:
* Materials that do not react with water.
* Materials that exhibit an exotherm at temperatures >3000C but </=5000C when tested by
differential scanning calorimetry.
* Materials that do not exhibit an exotherm at temperature <I=500oC when tested by differential
scanning calorimetry.
HIGHLY TOXIC MATERIAL
Material which prodUces a lethal.dôse. or léthal concentration, as follows:
Oral Ingestion = LD50.= </=50 mg/kg - Rat: Median lethal dose [LD50] of 50 milligrams or less per
kilogram of body weight when administered orally to albino rats weighing between 200 and 300
grams each.
Skin Absorption = LD50 = </=200 mg/kg - Rabbit: Median lethal concentration [LD50] of 200
milligrams or less per kilogram of body weight when administered by continuous contact for 24
hours, or less if death occurs with 24 hours, with the bare skin of albino rabbits weighing between 2
and 3 kilograms each.
Inhalation = LC50 = </=200 ppm - Rat: Median lethal concentration [LC50] in air of 200 ppm by
volume or less of gas or vapor, or <1=2 milligrams per liter of mist, fume or dust, when administered
by continuous inhalation for 1 hour, or less if death occurs within 1 hour, to albino rats weighing
between 200 and 300 grams each.
Mixtures of these materials with ordinary materials, such as water, might not warrant classification as
highly toxic.
DOT Class 6.1 Materials.
IRRITANT
Chemical which is not corrosive, but which causes a reversible inflammatory effect on living tissue by
chemical action at the site of contact.
A chemical is a skin irritant if, when tested on the intact skin of albino rabbits by the methods of 16 CFR
1500.41 for 4 hours' exposure or by other appropriate techniques, it results in an empirical score of 5 or
more.
A chemical is an eye irritant if so determined under the procedure listed in 16 CFR 1500.42 or other
approved techniques.
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I 2001 CALIFORNIA CODES ANALYSIS - HAZARDOUS MATERIALS DEFINITIONS
I NONCOMBUSTIBLE
As applied to building construction materials means a material which, in the form in which it is used, is
either one of the following:
Material of which no part will ignite and burn when subjected to fire.
I . Material having a structural base of noncombustible materials, with a surfacing material <1=1/8"
thick which has a flame-spread rating of </=50.
Noncombustible does not apply to surface finish materials or to materials which are subject to increase
in combustibility through the effects of age, moisture or atmospheric condition.
I OCCUPANCY
General: Purpose for which a building or part thereof is used or intended to be used.
B Occupancy: Office, employee, administrative areas; R&D laboratory operations; ancillary facility &
site support operations.
H Occupancy: Building or room containing >Exempt Amounts of hazardous materials or specific
hazardous operations.
H2: >/=Exempt Amounts of one or more of the following Physical Hazard Materials:
* Class I organic peroxides.
Class 3 nondetonatable unstable (reactive) materials.
* Pyrophoric, flammable, oxidizing gases.
Class I, II or Ill-A liquids used or stored in normally open containers or systems, or in closed containers or
systems pressurized at >15 psig.
Class 3 oxidizers.
Class 3 water reactives.
H3: >/=Exempt Amounts of one or more of the following Physical Hazard Materials:
* Flammable solids are manufactured, used, generated in such a manner that creates a high fire hazard
potential.
* Class II, Ill or IV organic peroxides.
* Class I or 2 oxidizers.
* Class I, II or Ill-A liquids used or stored in normally closed containers or systems, or in closed containers or
systems pressurized at <1=15 psig.
* Pyrophoric liquids or solids.
* Class 1 or 2 water reactive materials.
* Flammable solids in storage.
* Flammable or oxidizing cryogenic fluids.
* Class I unstable (reactive) gas and Class 2 unstable (reactive) materials.
H7: >/=Exempt Amounts of one or more of the following Health Hazard Materials:
* Corrosives
* Highly Toxics
* Toxics
ORGANIC PEROXIDE.
Organic compound, containing the bivalent -0-0- structure and which may be considered to be a
structural derivative of hydrogen, peroxide where one,or both of the hydrogen atoms have been replaced
by an organic radical''
Organic peroxides may present an explosion hazard [detonation or deflagration], or they may be shock
sensitive.
Organic peroxides may decompose into various unstable compounds over an extended period of time.
DOT 5.3 Materials.
Unclassified Detonable Organic Peroxide:
Capable of detonation.
Present extremely high explosion hazard potential through rapid explosive decomposition.
Regulated as Class A explosives.
DOT Type A.
Class I Organic Peroxide:
Capable of deflagration but not detonation.
Present high explosion hazard potential through rapid decomposition.
DOT Type B.
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2001 CALIFORNIA CODES ANALYSIS - HAZARDOUS MATERIALS DEFINITIONS
• Class II Organic Peroxide:
I . Burn very rapidly.
Present a severe reactivity hazard potential.
DOT Type.C.
Class Ill Organic Peroxide:
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. Burn rapidly.
Present a moderate reactivity hazard potential.
DOT Type D.
I . Class IV Organic Peroxide:
Burn in same manner as ordinary combustibles.
Present a minimum reactivity hazard potential.
DOT Types E & F.
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. Class V Organic Peroxide:
Do not burn.
No reactivity hazard potential.
DOT Type G.
OTHER HEALTH HAZARD
, Hazardous material which affects target organs of both body including, but not limited to, those
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materials which produce liver damage, kidney damage, damage to the nervous system, act on the blood
to decrease hemoglobin function, deprive the body tissue of oxygen, or affect reproductive capabilities
including mutations [chromosomal damage] or teratogens [effects on fetuses].
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OXIDIZER
.
. . :. . ... . ........
Chemical other than a blasting agent or explosive that initiates or promotes combustion in other
materials, thereby causing fire either of itself or through the release of oxygen or other gases.
DOT Class 5.1 Materials.
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. Class 4 Oxidizer:
Can undergo an explosive reaction when catalyzed or exposed to heat, shock or friction.
Acceptable Test Criteria - DOT Packaging Group L. Material which, in either concentration tested,
exhibits a burning time equal to or less than that of potassium bromate.
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. Class 3 Oxidizer:
Will cause a severe increase in the burning rate of combustible materials with which it comes in
contact.
Acceptable Test Criteria - DOT Packaging Group II: Material, which, in either concentration tested,
I .
exhibits a burning time between that of potassium brornate and that of potassium perchlorate.
s 2 Oxidizer: Class
Will moderately increase the burning rate or which may cause a spontaneous ignition of
combustible materials with which it comes in contact.
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. Acceptable Test Criteria - DOT Packaging Group Ill: Material, which, in either concentration tested,
exhibits a burning time between that of potassium perchlorate and that of ammonium persuiphate.
, Class I Oxidizer: May increase the burning rate of combustible material with which it comes in contact.
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pH
Value used to represent the strength of an acid or base [alkali]:
pH 1-7: Acid [11 =Strong; 6=Weakj
pH 7: Neutral [i.e.: Water]
pH >7-14: Base [pH 11 = 10 times more corrosive than pH of 10]
I Skin: ph 6-8
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PYROPHÔRIC . . . . .
Chemical that will spontaneously ignite in air at or below 130oF.
SENSITIZER
Chemical that causes a substantial proportion of exposed people or animals to develop an allergic
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reaction in normal tissue after repeated exposure to the chemical.
. Chronic effect/reaction.
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2001 CALIFORNIA CODES ANALYSIS - HAZARDOUS MATERIALS DEFINITIONS
TOXIC MATERIAL
Material which produces a lethal dose or lethal concentration as follows:
Oral Ingestion = LD50 = >50 mg/kg to 500 mg/kg - Rat: Median lethal dose [LD50] of >50 milligrams but
not more than 500 milligrams per kilogram of body weight when administered orally to albino rats
weighing between 200 and 300 grams each.
Skin Absorption = LD50 = >200 mg/kg to 1,000 mg/kg - Rabbit: Median lethal concentration [LD50] of
>200 milligrams but not more than 1,000 milligrams per kilogram of body weight when administered by
continuous contact for 24 hours, or less if death occurs with 24 hours, with the bare skin of albino rabbits
weighing between 2 and 3 kilograms each.
Inhalation = LC50 = >200 ppm to 2,000 ppm - Rat: Median lethal concentration (LC50] in air of 200 ppm
but not more than 2,000 by volume of gas or vapor, or >2 milligrams but not more than 200 milligrams
per liter of mist, fume or dust, when administered by continuous inhalation for 1 hour, or less if death
occurs within 1 hour, to albino rats weighing between 300 and 300 grams each.
Mixtures of these materials with ordinary materials (e.g. water) might not warrant classification as toxic.
DOT Class 6.1 Materials.
UNSTABLE (REACTIVE) MATERIAL
Chemical which in the pure state, or as produced or transported, will vigorously polymerize, decompose,
condense or will become self-reactive under conditions of shock, pressure or temperature.
Class 4 Unstable (Reactive):
Capable of detonation, explosive decomposition or explosive reaction at NTP.
Includes materials sensitive to mechanical or localized thermal shock at NTP.
. Class 3 Unstable (Reactive):
Capable of detonation, explosive decomposition or explosive reaction but which requires a strong
initiating source or which must be heated under confinement before initiation.
Includes materials sensitive to thermal or mechanical shock at elevated temperatures and pressures.
Class 2 Unstable (Reactive):
Normally unstable, readily undergoes violent chemical change but will not detonate.
Includes materials can undergo chemical change with rapid release of energy at normal temperatures
and which can undergo violent chemical change at elevated temperatures and pressures.
Materials that exhibit an exotherm at temperatures </=15OoC when tested by differential scanning
calorimetry.
Class I Unstable (Reactive):
Normally stable but can become unstable t elevated temperatures and pressures.
Materials that change or decompose on exposure to air, light or moisture.
Materials that exhibit an exotherm at temperatures >1500C, but </=3000C, when tested by differential
scanning calorimetry.
USE (Material)
Placing in action or making àvailablé for service by opening or connecting anything utilized for
confinement of material whether a solid, liquid or gas.
USE - CLOSED SYSTEM
Use of a solid or liquid hazardous material in a closed vessel or system that remains closed during
normal operations where vapors emitted by the product are not liberated outside the vessel/system and
the product is not exposed to the atmosphere during normal operations.
Examples:
All uses of compressed gases.
Reaction process operations.
Product conveyed through a piping system into a closed vessel, system or piece of equipment.
Materials where vapors/gases/mists are retained or exhausted in a localized environment [fume
hoods, exhausted enclosures, etc.].
USE - OPEN SYSTEM
Use of a solid or liquid hazardous material in a vessel or system that is continuously open to the
atmosphere during normal operations and where vapors are liberated, or the product is exposed to the
atmosphere during normal operations.
Examples:
Dispensing from or into open beakers or containers.
Plating and dip tank operations outside of exhausted enclosures.
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2001 CALIFORNIA CODES ANALYSIS - HAZARDOUS MATERIALS DEFINITIONS
WATER REACTIVE MATERIAL
I . Material which may explode, violently react, produce flammable, toxic or other hazardous gases, or
evolve enough heat to cause self-ignition or ignition of nearby combustibles upon exposure to water or
moisture.
DOT Class 4.3 Materials.
I • Class 3 Water Reactive:
May react explosively with water without requiring heat or confinement.
Acceptable Test Criteria - DOT Packaging Group I: Spontaneous ignition occurs, or tendency of
spontaneous ignition, or the rate of evolution of-flammable gases is >1= 10 liters per kilogram of
I material over any one minute.
Class 2 Water Reactive:
May react violently with water or form potentially explosive mixtures with water.
Materials that exhibit an exotherm at temperatures cl=150oC when tested by differential scanning
I calonmetry.
Acceptable Test Criteria - DOT Packaging Group II: Rate of evolution of flammable gases is >/= 20
liters per kilogram of material per hour.
Class 1 Water Reactive:
I . May react with water with some release of energy but not violently.
Materials that change or decompose on exposure to moisture.
Materials that exhibit an exotherm at temperatures >1500C, but <ft3000C, when tested by
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differential scanning calorimetry.
Acceptable Test Criteria - DOT Packaging Group Ill: Rate of evolution of flammable gases is> I
liter per kilogram of material per hour.
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