HomeMy WebLinkAboutGPA 06-09; Muroya Subdivision; General Plan Amendment (GPA) (2)----
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Phase II Environmental Site Assessment f ·, t 7 :1 '; 1
Muroya Growers CITY OF CARLSBAD
APN 215-040-03 PLANNING DEPT
6697 Black Rail Road·
Carlsbad, California
Taylor Woodrow Homes
16745 West Bernardo Drive, Suite 140
San Diego, California 92127
DUDEK
Engineering + Environmental
605 Third Street
Encinitas, CA 92024
~ Glenna McMahon nv:nmei: En;:
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Table of Contents
1. EXECUTIVE SUMMARY ...................................................................................................................... 1
2. INTRODUCTION .......................................................•............................................................................ 2
2.1. ASSESSMENT PROCEDURE AND SCOPE OF INVESTIGATION ......................................................... 2
3. BACKGROUND INFORMATION ................................................................•..................................•.... 2
4. PHASE II ACTIVITIES ..............................................................•......................................................•.... 3
4.1 TPH SOIL SAMPLING ........................................................................................................................... 4
4.2 PESTICIDE SOIL SAMPLING .................................................................................................................. 4
5. PHASE II DATA EVALUATION .......................................................................................................... 5
5.1 TPH SOIL SAMPLING ........................................................................................................................... 5
5.2. PESTICIDE SOIL SAMPLING ................................................................................................................. 6
6. CONCLUSIONS ...............................................................................................................•....................... 7
7. LIMITATIONS ........................................................................................................................................ 7
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List of Figures
Vicinity Map
Site Map
Figure 1
Figure 2
Figure 3
Figure 4
Soil Sample Locations -Diesel AST
Pesticide Soil Sample Locations
List of Tables
TPH Soil Sample Data Table 1
Table 2 Organochlorine Pesticide Soil Sample Data
List of Appendices
Appendix A Laboratory Analytical Data
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1. Executive Summary
DUDEK Engineering & Environmental (Dudek) conducted this Phase II Environmental
Site Assessment (ESA) for the property located at 6697 Black Rail Road in Carlsbad,
California (subject property, Figure 1) in order to further investigate the recognized
environmental conditions noted in the Phase I ESA (April 2006 Phase I ESA prepared by
Dudek). The Phase I ESA identified records that indicated that the site may have been
used for agriculture prior to its current use as a nursery. Findings of the Phase I also
included the use of pesticides on site, as well as storage and use of diesel fuel. There was
indication that runoff containing pesticides from surrounding properties may have
impacted the subject property (Figure 2). Based on this information, Dudek
recommended that a Phase II ESA be performed at the subject property. The objectives of
the Phase II investigation were to: 1) determine if diesel is present in the soil beneath the
aboveground storage tank (AST) and 2) to determine if pesticides are present in the soil
due to former and current use of the site for agriculture and potential impact from
surrounding properties.
Dudek collected five soil samples at two locations adjacent to the AST for total
petroleum hydrocarbon analysis (TPH; Figure 3). The soil samples were collected at two
feet below ground surface (bgs) and four feet bgs at each of the locations. One sample
was collected at 1-3 inches bgs at one of the locations. TPH soil samples were analyzed
by D-TEK Analytical Laboratories, Inc. in San Diego, CA by Modified EPA Method
8015M. None ofthe eight soil samples had detectable concentrations ofTPH diesel. One
sample contained concentrations ofhydrocarbons in the motor oil range. This sample
was collected at a depth of approximately 1-3 inches bgs under the nozzle of the diesel
AST, and had a concentration of 10,520 milligrams per kilogram (mg/kg) motor oil.
However, the two and four foot samples at that location did not have detectable
concentrations of motor oil or diesel. Based on Regional Water Quality Control Board
(RWQCB) Region IV guidance, soils which are between 20 and 150 feet above
groundwater and have TPH concentrations above 1,000 mg/kg should be remediated.
Based on these findings and those of the Phase I ESA, no further assessment is
recommended for TPH. Dudek does recommend that the visibly stained soil be dug out
and properly disposed of prior to making any modifications in this area of the subject site.
Dudek collected eight soil samples from throughout the palm tree nursery for pesticides
analysis (Figure 4). The soil samples were sent to D-TEK to be analyzed for
organochlorine pesticides by EPA Method 8081A. All eight soil samples had detectable
concentrations of organochlorine pesticides. Based of the analytical results, none of the
samples contained concentrations greater than the US EPA Region IX's Residential
Preliminary Remediation Goals (PRGs) or the Cal/EP A California Human Health
Screening Levels (CHHSLs). PRGs and CHHSLs are established based on the
theoretical de minimis cancer risk (one in a million increased risk) for contaminants that
are considered carcinogenic. PRGs use USEP A toxicity factors, whereas CHHSLs use
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Cal/EP A toxicity factors if available. By comparison of the pesticide concentrations to
the PRGs and CHHSLs, the long term cancer risk is less than one in a million. Based on
these findings and those of the Phase I ESA, no further assessment is recommended for
pesticides.
2. Introduction
This Phase II ESA was performed according to the guidelines stipulated in the American
Society for Testing and Materials Standard E 1903-97, "Standard Guide for
Environmental Site Assessments: Phase II Environmental Site Assessment Process".
The subject property is located at 6697 Black Rail Road in Carlsbad, California and has
been used as an agricultural nursery, a residence, and open space.
2.1. Assessment Procedure and Scope of Investigation
Phase II ESAs evaluate the recognized environmental conditions identified in
the Phase I ESA for the purpose of providing sufficient information regarding
the nature and extent of contamination to assist in making informed business
decisions about the property.
The Phase I ESA identified that the site was used for agriculture and that
pesticides were used on the subject property. Although the type of pesticides
formerly applied on the site are not known, organochlorine pesticides were
used on the adjacent properties, from which storm water runoff flows onto the
subject property. Additionally, chemical storage on the property has included
an aboveground diesel storage tank. Staining was observed on the tank near
the dispenser connection, indicating that diesel has leaked from the tank.
Therefore, there is potential for contamination associated with the diesel tank.
Based on this information, Dudek recommended that a Phase II ESA be
performed at the subject property. The objectives of the Phase II investigation
were to: 1) determine if aboveground storage of diesel caused contamination
of soil on the subject property and 2) to determine if pesticides are present in
the soil due to use of the site and adjacent sites for agriculture.
3. Background Information
The subject property is an approximately 19 acre parcel located west of Black Rail Road
in Carlsbad, California (Figure 1 ). The address for the nursery, which occupies
approximately half of the subject property, is 6697 Black Rail Road in Carlsbad,
California. The APN for the subject property is 215-040-03. Structures on the property
include a residence, a maintenance building, and a small shack.
The topography of subject property generally slopes from the north to the south and from
east to west. The northeastern and eastern portions of the site are relatively flat, while
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drainages with topographic depressions are located in the southwest portion of the
property. The elevation of the subject property is approximately 300 feet above mean sea
level. The surrounding area to the north and east slopes toward the subject property.
The subject property is located north ofBatiquitos Lagoon. No surface water was
observed on the subject property during the site reconnaissance. Based on a site
investigation performed on the site to the north of the subject property, the depth to
groundwater in the vicinity of the site is 46 feet below ground surface.
The subject property was undeveloped until the mid-to late-1950s or early-1960s when it
was cleared and possibly used for agriculture purposes (the 1963 aerial photograph shows
a portion of the site as graded land, possibly used as a field). The current owner stated
that the site was vacant when they purchased it in 1973. In the 1970s, the owners grew
potted plants and ground cover on approximately half of the subject property. In 1980
they began to grow palm trees and phased out the potted plants and ground cover.
Currently two pounds per month of a fungicide, weedkiller, and oil spray are used for the
potted palm trees. More pesticides were used in the past for the potted plants and ground
cover, but the amounts and types were not recorded. The owner stated they did not use
DDT on the site.
One aboveground 500-gallon diesel storage tank was observed during the site
reconnaissance, south of the maintenance building. This tank replaced two former
aboveground diesel tanks formerly located in the same area. Those two tanks were
removed approximately 10 years ago. No stained soil was observed in this area during
the site reconnaissance; however, staining was observed on the tank near the dispenser
connection.
Due to these historical activities, the identified potential environmental concerns at the
site are the potential release of petroleum products to the soil and residual pesticides in
soil resulting from historical agricultural activities.
4. Phase II Activities
The objectives ofthe Phase II investigation were to: 1) determine if diesel-contaminated
soil is present beneath the aboveground storage tank (AST) and 2) to determine if
pesticides are present in the soil due to former and current use of the site and surrounding
sites for agriculture. Dudek accomplished this by 1) collecting soil samples from the
surface, two and four feet bgs to determine iftotal petroleum hydrocarbons (TPH) in the
diesel range were present in the soil and 2) collecting and analyzing shallow soil samples
for pesticides .
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4.1 TPH Soil Sampling
Dudek collected five soil samples at two locations adjacent to the AST for TPH diesel
analysis on April 19, 2006 (Figure 3). The samples were collected from underneath the
dispenser and from under the middle of the tank. Visibly stained soil was observed on
the ground surface under a piece of wood located under the dispenser. Additionally,
Dudek noticed that the tank was tilted slightly from back to front, toward the dispenser.
Soil sampling for TPH was conducted by Torin Snyder ofDudek. Four of the five soil
samples were collected using a hand auger. Soil collected using the hand auger was
placed in glass jars, which were labeled, placed in Ziploc bags, and placed in a cooler on
ice. The surface soil sample was collected using a clean, dedicated hand trowel. The soil
was also placed in a glass jar, which was labeled, placed in a Ziploc bag, and placed in a
cooler on ice. A chain-of-custody record was filled out with the sample identifiers and
sample time.
The hand auger was decontaminated in between sample collection by washing it using
water and alconox and then rinsing it using water. The decontamination water was stored
on site in a labeled bucket. Following receipt of the soil sample analysis for which TPH
diesel was not detected, the water was discarded.
The sample cooler was sent to D-TEK Laboratory via Fed-Ex. The TPH soil samples
were analyzed by Modified EPA Method 8015M (diesel) (Table 2; Appendix A). The
sample results and quality control are discussed in Section 5.1.
4.2 Pesticide Soil Sampling
Based on the aerial photograph review, approximately half the site (eight or nine acres)
has been used for agriculture back to the 1960s or early 1970s. Based on the interview
with the current owner, pesticides were used on the property; however, the owner could
not remember the types or quantities of pesticides used. However, she did state that DDT
was not used on the subject property.
Based on a review of County of San Diego closure letters for two sites located just north
and northeast of the subject property, chlorinated pesticides were used at those adjacent
sites. Concentrations of the chlorinated pesticides DDT, toxaphene, endosulfan, and
dieldrin were detected in the soil. Concentrations of toxaphene exceeded the EPA PRGs
and the CHHSLs for the residential scenario. At both sites, the upper one foot of soil was
removed from the site and placed at least five feet below ground surface under the streets
Corte Orchildia and Sito Cedrela during development of the residential neighborhoods.
During the Phase I ESA, Dudek noted that the topography of the site and surrounding
area is such that runoff from these neighboring properties may have run across the subject
site, toward the canyon, thus having an impact on the subject site .
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Organochlorine pesticides, such as DDT, were commonly used in the 1940s through the
1960s. Organophosphorus pesticides have commonly been used since the 1970s or
1980s. Organochlorine pesticides are persistent in the environment and are not very
mobile. Organochlorine pesticides are large molecules with a low water solubility and
high potential for sorption on soils. Therefore they tend not to migrate downward like
other chemicals with higher solubility and lower affinity for soil. Therefore,
concentrations of organochlorine pesticides are generally expected to be greatest in the
shallow soils .
Organophosphorus pesticides are not persistent in the environment. Concentrations of
organophosphorus pesticides are often non-detectable within a year of application. If
organophosphorus pesticides were used on the site several years ago, it is not likely that
they remain in the soil at concentrations above the regulatory limits. Therefore, Dudek
did not analyze the samples for organophosphorus pesticides.
On April 19, 2006, Dudek collected eight soil samples from approximately four to six
inches bgs uniformly throughout the agricultural areas and some key drainage areas of
the subject property. Samples from this depth interval are representative of surface soils
at this site. The sample locations are shown on Figure 4.
Soil samples were collected using disposable hand trowels. A hand trowel was used to
excavate a few inches of soil and then place the soil into 4 ounce glass jars. The glass
jars were labeled, taped, and placed in a cooler on ice. A chain-of-custody record was
filled out with the sample identifiers and sample time. The cooler was sent to D-TEK
Laboratory via FedEx on April 19, 2006.
The samples were analyzed by D-Tek for organochlorine pesticides by EPA Method
8081A. The sample results and quality control are discussed in Section 5.2.
5. Phase II Data Evaluation
5.1 TPH Soil Sampling
Dudek collected five soil samples at two locations adjacent to the AST for TPH analysis
(Figure 3). The TPH soil sampling data is summarized in Table 1. TPH was not detected
above the detection limit of 10 mg!kg in any of the samples collected on April 19, 2006.
Sample MS-11-1" was collected in an area of stained soil, at a depth of approximately 1-
3 inches bgs underneath the nozzle ofthe diesel AST. While sample MS-11-1" did not
contain TPH-diesel (C 10-C23) above the detection limit, the lab did report that the sample
contained hydrocarbons in the motor oil range (C10-C44) at a concentration of 10,520
mg/kg. Based on RWQCB Region IV guidance (Interim Site Assessment & Cleanup
Guidebook, May 1996. RWQCB Region IV), soils which are between 20 and 150 feet
above groundwater and have TPH concentrations above 1,000 mg/kg should be
remediated. While there is no specified action level for motor oil, Dudek recommends
removing the stained soil and properly disposing it.
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As part of the laboratory quality control, a laboratory control sample was spiked with
diesel. The percent recovery of the spike concentration for diesel was within the
acceptable limits established by the laboratory. A matrix spike duplicate was also
analyzed. The relative percent difference (RPD) between the sample result and the
duplicate result was 5% for diesel. No acceptable limits for RPD were provided by the
lab (Appendix A).
5. 2. Pesticide Soil Sampling
The pesticide soil sampling data is summarized in Table 2. 4,4' -DDD was detected in
five of the eight samples at concentrations ranging from 7.2 micrograms per kilogram
(f.lg/kg) to 58 f.lg/kg (Table 2). 4,4' -DDE was detected in seven of the eight samples at
concentrations ranging from 0.5 f.lg/kg to 134 f.lg/kg. 4,4' -DDT was detected in five of
the eight samples at concentrations ranging from 10 f.lg/kg to 83 f.lg/kg. Alpha-chlordane
was detected in three samples at concentrations ranging from 0.65 f.lg/kg to 2.4 f.lg/kg.
Gamma-chlordane was detected in three samples at concentrations ranging from 0.55
f.lg/kg to 2.4 f.lg/kg. The laboratory reports are included in Appendix A.
The US EPA Region IX has published Preliminary Remediation Goals (PRGs). The
Cal/EPA has published California Human Health Screening Levels (CHHSLs). Both
PRGs and CHHSLs have been established based on the theoretical de minimis cancer risk
(one in a million increased risk) for contaminants that are considered carcinogenic. The
residential PRG for both DDE and DDT is 1, 700 f.lg/kg. The residential CHHSLs for
both DDE and DDT is 1,600 f.lg/kg. The highest concentrations ofDDE and DDT on the
subject property were 134 f.lg/kg and 83 f.lg/kg, respectively. Both of these
concentrations are orders of magnitude below the residential PRG and CHHSL. The
residential PRG for DDD is 2,400 f.lg/kg. The residential CHHSL for DDD is 2,300
f.lg/kg. The highest concentration ofDDD on the subject property was 58 f.lg/kg, which
was also below the residential PRG and residential CHHSLs. The residential PRG for
technical chlordane or alpha-and gamma-chlordane is 1 ,600 f.lg/kg. There is no CHHSL
established for chlordane. The highest concentrations of alpha-chlordane and gamma-
chlordane on the subject property was 2.4 f.tg/kg for each, for a total of 4.8 f.lg/kg, which
is below the residential PRG. Based on comparison of these results to the PRGs and
CHHSLs, and the proposed residential use ofthe subject property, the DDD, DDE, DDT,
and chlordane concentrations detected on the subject property do not pose an increased
cancer risk greater than one in a million.
As part of the quality control of the laboratory analyses for organochlorine pesticides,
lindane, heptachlor, aldrin, dieldrin, endrin, and 4,4' -DDT were added as surrogates to
each sample at known concentrations for the EPA Method 8081A analysis. All of the
percent recovery results were within the quality control limits set for each compound
(Appendix A).
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A laboratory control sample was spiked with the surrogate pesticides. The percent
recovery of the spike concentration for each compound was within the acceptable limits
established by the laboratory. A matrix spike duplicate was analyzed for lindane,
heptachlor, aldrin, dieldrin, endrin, and 4,4' -DDT. The RPD between the sample results
and the duplicate results were between 0% and 11% (Appendix A).
6. Conclusions
Dudek conducted this Phase II ESA in order to further investigate the recognized
environmental conditions noted in the Phase I ESA (April 2006 Phase I ESA prepared by
Dudek). The Phase I ESA identified records that indicated that the site may have been
used for agriculture prior to its current use as a nursery. Findings of the Phase I also
included the use of pesticides on site, as well as storage and use of diesel fuel. There was
indication that runoff containing pesticides from surrounding properties may have
impacted the subject property. Based on this information, Dudek recommended that a
Phase II ESA be performed at the subject property. The objectives of the Phase II
investigation were to: 1) determine if diesel is present in the soil or beneath the AST and
2) to determine if pesticides are present in the soil due to former and current use of the
site for agriculture and potential impact from surrounding properties.
Dudek collected five soil samples at two locations adjacent to the AST for TPH analysis.
The soil samples were collected at two feet bgs and four feet bgs at each of the two
locations. In one of the locations a sample was collected within a few inches of the
ground surface. None of the soil samples had detectable concentrations ofTPH diesel.
One of the samples-the surface sample-had a detection of hydrocarbons in the motor
oil range. This sample was located approximately 1-3 inches bgs under the nozzle of the
diesel AST. The concentration was 10,520 mg/kg motor oil. Dudek recommends that
the visibly stained soil be dug out and properly disposed of prior to making any
modifications in this area ofthe subject site.
Dudek collected eight soil samples from throughout the palm tree nursery for pesticides
analysis. All eight soil samples had detectable concentrations of organochlorine
pesticides. However, none of the samples contained concentrations greater than the US
EPA Region IX's Residential PRGs or Cal/EPA Residential CHHSLs. Therefore, the
long term cancer risk is less than one in a million based on the pesticide concentrations
on the subject property .
Based on these findings and those of the Phase I ESA, no further assessment is
recommended for pesticides.
7. Limitations
The findings and conclusions presented in this report are professional opinions based
solely upon the indicated data described in this report, visual observations of the site and
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vicinity and our interpretation of the available historical information and documents
reviewed. Dudek makes no warranty as to the accuracy of statements made by others or
the accuracy of information included in documentation reviewed in connection with this
study. It should be recognized that this study was not intended to be a definitive
investigation of potential contamination at the site and that the recommendations do not
necessarily include all conditions that may be present. Because the scope ofthe
investigation was limited, it is possible that currently unrecognized conditions or
contamination might exist at the site.
No warranties or guarantees or representations, expressed or implied, are made by
Dudek, except that this report has been prepared in accordance with current generally
accepted practices and standards consistent with the level of care and skill exercised
under similar circumstances by other professionals performing the same or similar
services. The conclusions are intended exclusively for the purpose outlined herein and
may not be suitable to satisfy the needs of other users. Thus, any use or reuse of this
document is at the sole risk of said user.
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TABLE 1
Soil Sampling Data
Total Petroleum Hydrocarbons
(milligrams per kilogram)
SAMPLEID TPHDIESEL
MS-9-2' <10
MS-9-4' <10
MS-10-2' <10
MS-10-4' <10
MS-11-1 II <10
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DETECTION US EPA
LIMIT PRG
ANALYTE (ug/kg) (f.lg/kg)
4,4'-DDD 0.5 2,400
4,4'-DDE 0.5 1,700
4,4'-DDT 0.4 1,700
Aldrin 0.2
Alpha-BHC 0.6
Beta-BHC 0.6
Gamma-BHC 0.3
Delta-BHC 0.6
Alpha-chlordane 0.5 1,600* Gamma-chlordane 0.5
Dieldrin 0.3
Endosulfan I 0.3
Endosulfan II 0.5
Endosulfan Sulfate 0.4
Endrin 0.4
Endrin Aldehyde 0.5
Endrin Ketone 0.5
. Heptachlor 0.2
Heptachlor Epoxide 0.3
Methoxychlor 12
Toxaphene 25
TABLE2
Soil Sampling Data
Organochlorine Pesticides
(micrograms per kilogram)
US EPA
CHHSLs
(f.lg/kg) MS-1 MS-2
2,300 23.4 22.2
1,600 56 46.4
1,600 45 25.4
<0.2 <0.2
<0.6 <0.6
<0.6 <0.6
<0.3 <0.3
<0.6 <0.6
0.7 <0.5
0.64 <0.5
<0.3 <0.3
<0.3 <0.3
<0.5 <0.5
<0.4 <0.4
<0.4 <0.4
<0.5 <0.5
<0.5 <0.5
<0.2 <0.2
<0.3 <0.3
<12 <12
<25 <25
* PRG for technical Chlordane, which is the total of alpha-and gamma-chlordane.
Muroya Phase II
Carlsbad, CA
MS-3 MS-4 MS-5
41 7.2 <0.5
96 15.6 0.5
63 10 <0.4
<0.2 <0.2 <0.2
<0.6 <0.6 <0.6
<0.6 <0.6 <0.6
<0.3 <0.3 <0.3
<0.6 <0.6 <0.6
<0.5 <0.5 <0.5
1.5 <0.5 <0.5
<0.3 <0.3 <0.3
<0.3 <0.3 <0.3
<0.5 <0.5 <0.5
<0.4 <0.4 <0.4
<0.4 <0.4 <0.4
<0.5 <0.5 <0.5
<0.5 <0.5 <0.5
<0.2 <0.2 <0.2
<0.3 <0.3 <0.3
<12 <12 <12
<25 <25 <25
MS-6
58
134
83
<0.2
<0.6
<0.6
<0.3
<0.6
2.4
2.4
<0.3
<0.3
<0.5
<0.4
<0.4
<0.5
<0.5
<0.2
<0.3
<12
<25
MS-7
<0.5
<0.5
<0.4
<0.2
<0.6
<0.6
<0.3
<0.6
0.65
0.55
<0.3
<0.3
<0.5
<0.4
<0.4
<0.5
<0.5
<0.2
<0.3
<12
<25
MS-8
<0.5
1.0
<0.4
<0.2
<0.6
<0.6
<0.3
<0.6
<0.5
<0.5
<0.3
<0.3
<0.5
<0.4
<0.4
<0.5
<0.5
<0.2
<0.3
<12
<25
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Muroya Growers
Black Rail Road
Carlsbad, CA
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Figure 1
Vicinity Map
SOURCE: GOOGLE MAPS
SITE MAP
MUROY A GROWERS
CARLSBAD, CA
FIGURE2
DUDEK
LEGEND
MS-9-2', MS-9-4'
and MS-11-1"
MS-1 0-2' and MS-1 0-4'
L MS-1~-2' and J MS-10-4'
TPH SAMPLE LOCATION AND ID
TPH SOIL SAMPLE DATA
MUROY A GROWERS
CARLSBAD. CA
Diesel Dispenser
Above Ground
Diesel Tank
FIGURE 3
DUDEK
SOURCE: GOOGLE MAPS 0 SAMPLE LOCATION AND 10
ORGANOCHLORINE PESTICIDE SOIL SAMPLE DATA
MUROY A GROWERS
CARLSBAD, CA
FIGURE4
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APPENDIX A
D-TEK Analytical Laboratories, Inc. Report
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D-TEK Analytical Laboratories, Inc.
9020 Kcnamar Drive, Suite 205
San Diego. CA 92121
(858) 566-4540 FAX (858) 566-4542
DUDEK & ASSOCIATES, INC.
605 3~0 Street
Encinitas, CA 92024
Attn: Ms. Nicole Peacock
Date of Report:
Sampling Date:
Date Sample Received:
Date Extracted:
Date Analyzed:
Analyzed By:
Project Name:
Pro,ject Nmnber:
Method:
Sample Type:
Log Number:
4/24/06
4/l9/06
4/20/06
4/20/06
April 21, 2006
EA
Muroya Property .Phase 11
5089~02
EPA 8081A
Soil
06-2666 to 06-2673
The sample(s) were analyzed with EPA methodology or equivalent metltods as specified on the
attached "Analyses Results" •·eport. The symbol for "Jess than" indicates a value below the
re1>ortable detection limit.
The results of these analyses and the quality control data are enclosed.
~-U:._-
EIIen Atienza 0
Operations Manager
---------...
.... ..
-
---
D-TEK Analytical Laboratories, Inc.
9020 Kenamar :Orivc, Suite 205
San Diego, CA 92121
(858) 566-4540 FAX (858) 566-4542
DUDEK c.t:: ASSOCIATES, INC.
605 3nn Street
Encinitas, CA 92024
Attn~ Ms. Nicole Peacock
Date of Report:
Sampling Date:
Date Sample Received:
Date Extracted:
Date Analyzed:
Analyzed By:
Project Name:
Project Number:
Method:
Sample Type~
Log Number:
4/24/06
411.9/06
4/20/06
4/20/06
April21, 2006
EA
Muroya Property Phase 11
5089-02
OHS LUFT (TPH-Diesel)
Soil
06-2674 to 06-2678
The sample(s) were analyzed with EPA methodology or equivalent methods as specified on the
attached "Analyses Result.."" report. The symbol for "less than" indicates a value below the
reportable detectjon limit.
The results of these analyses and the quality control data are enclosed.
E!b~~ Ellen Atienz~
Operations Manager
-• ..
-------
• ..
• ...
D-TEK Analytical Laboratorie$, Inc.
9020 Kenamar Drive, Suite 205
.DUDEK & ASSOCIATES
605 Thir-d Street
Encinitas, CA 92024
Attn: Ms. Nicole Peacock
.Date of Report:
Sampling Date:
Date Sample Received:
Dntc Extracted:
.Dnte Analyzed
Analy7-ed By:
Sample Type:
Project Name:
Project Nutnber:
Method:
Units:
ANALYSlS
Detection
Limit
4,4'-ODD 0.5
4,4'-DD.E J.O
4~'-DDT ~8
Aldrin 0.2
Alpha-BHC 0.6
Beta-BHC 0.6
Gamma • BHC 0.3
Delta -BHC 0.6
Alpha-chlordnnc 0.5
Gnmmn-chlordane 0.5
Dieldrin 0.3
Endosutfan I 0.3
Endosulfan JI 0.5
Endosttlfan Sulfate 0.4
Endrin 0.4
Endrin Aldehyde 0.5
Endrin Ketone 0.5
Hcptacl1lor 0.2
Heptac!Jlor Epoxidc 0.3
Methoxychlor 12
Toxaphene 25
~7(== Ellen Atienza
Operations Manager
San Diego, CA 92121
(858) 566-4540 FAX (858) 566-4542
4/24/06
4/19/06
4/20/06
4/20/06
April21, 2006
EA
Soil
Muroyn Property Phase 11
5089-02
EPA8081A
~lg/kg
ANAJ.JYSES RESULTS
Log Number: 06-2666
Snmple ID: MS-1
23.4
56
45
<DL
<J)L
<DL
<DL
<DL
0.7
0.64
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
"'DF =Dilution Factor. The detection limits and analyses results were corrected accordingly.
*DF
2x
2x
....
------
...
..
-
--
'Ill ..
D-TEl< Analytical Laboratories, Inc.
DUDEK & ASSOCIATES
605 Third Street
Enclnltas, CA 92024
Attn: Ms. Nicole PencocJ<
Date of Report:
Sampling Date:
Date Sample Received:
Date Extracted:
Date Analyzed
Analyzed By:
Snmple Type:
Pto,ject Name:
Pro.tect Number:
Method:
Uttits:
Detection
ANALYSIS Limit
4~'-DDD 05
4~'-DDE 1~
4A"-DDT OA
Aldrin 0.2
Alpha-BHC 0.6
Beta -13I-IC 0.6
Gamma-BHC 0.3
Delta -BHC 0.6
Alpha-chlordane 0.5
Gamma-chlordane 0.5
Dieldrin 0.3
Endosulfan 1 0.3
Endosutfan II 0.5
Endosulfan Sulfate 0.4
Endrin 0.4
Endrin Aldehyde 0.5
Enclrin Ketone 0.5
Heptachlor 0.2
T-Ieptac:hlor Epoxide 0.3
Methoxychlor 12
Toxaphene 25
~~~~---------
Operations Manager
9020 Kennmnr Drive, Suite 205
Snn Diego, CA 92121
(858) 566-4540 FAX (858) 566-4542
4/24/06
4/19/06
4/20/06
4/20/06
April 21, 2006
EA
Soil
Muroya Property Phase 11
5089-02
EPA8081A
~tg/kg
ANALYSES RESULTS
Log Number: 06-2667
Sample ID: MS-2
22.2
46.4
25.4
<Dl.
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<Dl-
<D.L
*DP,., Dilution Factor. The detection. limits and analyses results were corrected accor.di.ugly.
*DF
2x
-
-------
-
-
------
---
-
Ill
ill
..
•
D-TEK Analytical Laboratories, Inc.
9020 Kennmar Drive! Suite 205
DtiDER & ASSOCIATES
605 Third Street
Ertc:ittitns, CA 92024
Attn: Ms. Nicole Peacock
Date of Report:
Sampling Date:
Date Sample Received:
Date Extracted:
Date Analyzed
Analyzed By:
Sample Type:
Project Name:
Project Number:
Method:
Units:
ANALYSIS
4,4' M DDD
4,4' M DDE
4,4' -DDT
Aldrin
Alpha· BHC
Beta -BHC
Gamma -BHC
Delta-BHC
Alpha-chlordane
Gamma~chlordane
Dieldrin
Endosulfan l
Endostllfan II
E11do!;ttlfan Sulfate
Endrin
Endrin Aldehyde
Endrin Ketone
Heptachlor
Heptachlm· Epmdde
Methoxychlor
i:opl-le__.n,..,el---'-....1.
Ellen Atienza
Operations Mnnnger
Detection
Limit
1.0
2.0
1.6
0.2
0.6
0.6
0.3
0.6
0.5
0.5
0.3
0.3
0.5
0.4
0.4
0.5
0.5
0.2
0.3
12
25
Snn Diego, CA 92121
(858) 566-4540 FAX (858) 566-4542
4/24/06
4/l9/06
4/20/06
4/20/06
April 21, 2006
EA
Soil
Muroya Property Phase 11
5089-02
EPA 808lA
~tg/kg
ANALYSES RESULTS
Log Number: 06-2668
Sample ID: MS-3
41
96
63
<DL
<DL
<DL
<DL
<DL
<DL
1.5
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
*DF = Dih1tion Factor. TI1e detection limits and analyses results were corrected accordingly .
*DF
2x
4x
4x
------
------
• ---------•
D-TEK Analytical Laboratories, [nc.
9020 Kenamar Drive, Sufte 205
DUDEK & ASSOCIATES
605 Third Street
Encinitas, CA 92024
Attn: Ms. Nicole·Peacock
Dnte of Report:
Sampling Dnte:
Date Sample :Rece1ved:
Date Extracted:
Date Analyzed
Analyzed By:
Sample Type:
Project Name:
l"rojcct Number:
Method:
lJnits:
ANALYSIS
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
A lpha-chlordnue
Gamma-chlordane
Dieldrin
Endosulfan T
Enclosulfan 11
Endosulfan Sulfate
Endrin
Endrin Aldehyde
E:ndrin Ketone
Heptachlor
Heptachlor Epoxidc
Methoxychlor
Tox11phene
~' v Ellen Atienza
Operations Manager
Detection
Limit
0.5
0.5
0.4
0.2
0.6
0.6
0.3
0.6
0.5
0.5
0.3
0.3
0.5
0.4
0.4
0.5
0.5
0.2
0.3
12
25
San Diego, CA 92121
(858) 566-4540 FAX (858) 56(,..4542
4/24/06
4/19/06
4/20/06
4/20/06
April 21, 2006
EA
Soil
Muroyn Property Phase 11
5089-02
RP.A 8081A
~Lg/kg
ANALYSES RESUT.J TS
Log Nuinber: 06-2669
Sample ID: MS-4
7.2
15.6
10
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
*DF =Dilution Factor. The detection limits and analyses results were corrected accordingly.
*DF
-----------
• -
---
IIIII
D-TEK Analytical l.Atboratories, Inc.
9020 Kenamar Drive, Suite 205
DUDEK & ASSOCIATES
605 Third Street
Encinitas, CA 92024
Attn: Ms. Nicole Peacock
.Date of Report:
Sampling Date:
.Date Sample Received:
.Date Extracted:
Date Analy:1-ed
Analyzed By:
Sample Type:
Project Name:
Project Number:
Method:
Units:
ANAINSTS
4,4'-DOD
4,4' -DDE
4,4'-DDT
Alddn
Alphn-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
Alpha-chlordane
Gamma-chlordane::
Dieldrin
Endosulfan T
Endosulfan II
Endosulfan Sulfate
Endrin
Endrin Aldehyde
Endrin .Ketone
Heptachlor
Be::ptachlot Epoxide
Methoxychlor
Toxaphene
Detection
l .. itnit
0.5
0.5
0.4
0.2
0.6
0.6
0.3
0.6
0.5
0.5
0.3
0.3
0.5
0.4
0.4
0.5
0.5
0.2
0.3
12
25
~Qo_)_J
Ellen Atienza (.._=---
Operations Mannger
Snn Diego, CA 92121
(858) 566-4540 FAX (858) 566~4542
4/24/06
4/19/06
4/20/06
4/20/06
Atnil 21, 2006
EA
Soil
Mnroya Property Phase ll
5089-02
EPA 8081A
J.tg/kg
ANALYSES RESULTS
Log Number: 06-2670
Sample ID: MS-5
<DL
0.5
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
*DF =Dilution Factor. The detection limits and analyses results were corr.ected accordingly.
*DF
----
IIIII
...
• -
-• ...
• ...
• ------
•
• ..
D-TEK Analytical Laboratories, Inc.
9020 Kenamar Drive. Suite 205
.DUDEK & ASSOCIATES
60S Third Street
Encinitas, CA 92024
Attn: Ms. Nicole Peacock
Date of Report:
Sampling Dnte:
Date Sample Received:
Date Extracted:
Date Analyzed
Analyzed By:
Sample Type:
Project Natne:
Pro.te~t Number:
Method:
Untts:
ANAl.YSJS_
4,4'-.ODD
4,4'-DDE
4,4'-DDT
Aldrin
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
Alpha-chlordane
Gnmmn-chlordane
Dieldrin
Endosulfan I
Endosulfan TI
Endosulfan Sulfate
Endrin
llndrin Aldehyde
Endrin Ketone
Heptachlor
Heptachlor Epoxide
Methoxychlor
Detection
J.,imit
2.5
2.5
2.0
0.2
0.6
0.6
0.3
0.6
0.5
0.5
0.3
0.3
0.5
0.4
0.4
0.5
0.5
0.2
0.3
12
aTo~~} 25
tp~
Ellen Atienza
Operations Manager
Snn Diego, CA 92121
(858) 566-4540 FAX (858) 566-4542
4/24/06
4/19/06
4/20/06
4/20/06
April 21, 2006
EA
Soil
Muroya Property Phase ll
5089-02
EPA8081A
~tglkg
ANALYSES RESULTS
Log Number: 06-2671.
Sample ID: MS-6
58
134
83
<DL
<DL
<DL
<DL
<DL
2.4
2.4
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
*DF =Dilution :Factor. The detection limits and analyses results were corrected accordingly.
*DF
5x
Sx
5x
-------------------------
•
IIIII
Ill
D-TEK Analytical Laboratories, Inc.
9020 Kenamnr Drive, S\lite 205
DUDEK & ASSOCIATES
605 Third Str-eet
Encinitas, CA 92024
Attn: Ms. Nicole Peacock
Date of Report:
Sampling Drtte:
Date Sample Received:
Date Extracted:
:Date Analy:T-ed
Analyzed By:
Sample Type:
Pro,ject Name:
Project Number:
Method:
Ur.lts:
ANALYSIS
4,4'. ODD
4,4' ·ODE
4.4'-DDT
Aldrin
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
Alpha-chlotdnne
Gamma-chlordane
Di.eldtin
Enclosulfan I
Endosulfan II
Endmmlfan Sulfate
Endrin
Endrin Aldehyde
Endt'in Ketone
Hcptnr:hlor
Heptachlor Epoxide
Mcthoxyr:hlor
Toxaphene
EJien Atienza
Operations Mannger-
Detection
Limit
0.5
0.5
0.4
0.2
0.6
0.6
0.3
0.6
0.5
0.5
0.3
0.3
0.5
0.4
0.4
0.5
0.5
0.2
0.3
12
25
San Diego, CA 92121
(858) 566-4540 -FAX {858) 566-4542
4/24/06
4/19/06
4/20/06
4/20/06
April 21, 2006
EA
Soil
Muroya Property Phase 11
5089-02
EPA 8081A
J.tg/kg
ANALYSES RESULTS
Log Number: 06-2672
Sample ID: MS-7
<DL
<DL
<DL
<DL
<D.L
<DL
<DL
<DL
0.65
0.55
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
*OF""' Dilution Far:tor. The detection limits and analyses results were corrected accordingly.
*DF
-
---
11111111
ill
..
---
•
Ill •
-------~---------------------------
D-TEK Analytical La.boratodes, Inc.
9020 Kennmar Drive, Suite 205
DUDEK & ASSOClATES
605 Third Street
Encinitas, CA 92024
Attn: Ms. Nicole Peacock
Date of Report~
Snmpling Dnte:
.Oatc Sample Received:
Date Extracted:
Date Analyzed
Analyzed By:
Sample Type;
Pro.iect Name:
Project Number:
Method:
Units:
ANALYSIS
.Detection
Limit
4.4'-DDD 0.5
4,4' -DD.E 0.5
4,4' ·DDT 0.4
Aldrin 0.2
Alpha-BHC 0.6
Beta • BHC 0.6
Gamma • BliC 0.3
Delta-BHC 0.6
Alpha-chlordane 0.5
Gamma-chlordane 0.5
Dieldrin 0.3
Endo!;ttlfan I 0.3
Endosulfan II 0.5
Endosulfan Sulfate 0.4
.Endrin 0.4
Endrin Aldehyde 0.5
Endtin Ketone 0.5
Heptachlor 0.2
Heptachlor Epoxide 0.3
Methoxychlor 12
Toxaphene 25
@'C>Qc:z~·
Ellen Atien:ln
Operations Manager
Snn Diego, CA 92121
(858) 566-4540 FAX (858) 566-4542
4/24/06
4/19/06
4/20/06
4/20/06
April 21, 2006
:EA
Soil
Muroya Property Phase 11
5089-02
EPA8081A
~Lgfkg
ANAl, YSES RESULTS
Log NumbeJ:: 06--2673
Snmple ID: MS-8
<DL
1.0
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
<DL
"'DF =Dilution Factor. The detection limits and analyses results were corrected accordingly.
*DF
-
----.. -
----
-
-----
--.. ..
1111
Dnte:
Attn:
Log#;
Dnte E:dl'Dcted;
Date Analyzed:
Analysis Method:
METHOD BLL\NK
D-TEK Analytical .Laboratories, Inc.
90ZO Kenamar Drive, Suite 205
San Diego, CA 92121
(858) 566-4540 FAX (858) 566-4542
QUALITY CONTROl .. DATA REPORT
4/24/06
Ms. Nicole Peacock
06-2666 to 06-2673
4/20/06
April 21, 2006
EPA 8081A
No target analytcs were detected in the method blank.
LABORATORY CONTROL SAMPLE
Compound
G-BHC (Lindane)
Heptachlor
Aldrin
Dieldrin
Endrin
4,4' DDT
1\;IATRJX SPIKE RESULTS (06-2672)
Compound
0-BHC (Lindane)
Heptachlor
Aldrin
Dieldrin
.Endrin
4,4-DDT
Spil<:e
0/o Recovery
74
100
98
93
114
85
* QC Limits: Applies to LCS, MS & MSD.
%Recovery
54
86
83
74
82
84
Spike Dup.
o/n Recovery
83
108
106
96
114
83
QUAUTY CONm.9J• TF,RMJNQLQGY
QC .Limits % *
32-127
34-111
42-122
36-146
30-147
25-160
MS/MSD
RPD %
11
8
8
3
0
2
I.C~-LABOitATORY CONTR.Ol. SAMPJ.F.. Reported a• % t'<:<!overy of an independent standard carried through ~II
sample pt·cparntion proccnme• to verify method perfonn:mcc. Acceptable range is ha•cll on hi•torieallaborntory conu·ol datlt
ancl EPA requirements. Any o•.ll·of-e<:>ntrol QC data iR clearly indicated.
Spike-environmental sample i~ matrix •piked with method compounds and %recovery of concentration •piked into sample is
cnlcul~tcd. Reported nR% recovery. Accept.1blc range for ''Normal Matrix Sample'' is based on hisloricollaboratory control
data. Any out-of-control QC data is clcarly inllkated.
Rnrl'OJ!;nt.,R-Compotmds rep•-e•entativc of:. group ofcompounr.ls. St.trr<)ente• ore •piked into environment:ll •ample• and%
recovery <tfconccntralion spiked is cnlcul~tcd 3nd reported. Acceptable mngc v~trics depending on sample matrix and analy•i~
mcthorl. Any out-of·comrol QC d~ta i• clearly indicated.
P:-tgc I of 2
---
-
Ill ----------
•
IIIII
•
IIIII
1111111
IIIII
n ... TEK Analytical Laboratories, Inc.
9020 Kcnnmnr Drive, Suite 205
Log#
Method Blank
06-2666
06-2667
06-2668
06-2669
06-2670
06-2671
06-2672
06-2673
LCS
06-2672 MS
06-2672 MSD
Ellen Atienza
Operations Manager
San Diego, CA 92121
(858) 566-4540 FAX (858) 566-4542
SURROGATE RECOVERJES
(Tctrachlm·o-M-Xylene)
Percent Recovery:
75
78
112
103
112
103
108
78
86
82
78
91
QC Limits: 43 to 169%
QUALITY CONTROL Tli:RMJNOLOGX
J"CS "T,ARORATORY CONTROL SAMPLE. Keported ns % l"Ccovcry of an independent Alllmlnrd CIIITied through 311
•ample preparation procedure~ to verify method performance. Acccptahlc range is based on historical laboratory control data
nncl EPA l'cquircmenl!;. Any out-of-control QC data is clearly fndfcllted.
Spike-environmental Hample is fll~trix ~piked with method compounds ~nd% recovery of concentration opikcd Into sample is
calculated. Reported as% recovery. Acceptable range for "Nom1al Matrix Sample" is bnsed on historical laboratory contrOl
dntn. Any out-of-control QC dato is cle~rly indicated.
~htrro,::atc~-Compounds representative of11 group or compound a. SurroglltC9 nre ~piked into cnvlmnmenL'Il .<ample~ and%
recovery of concentration spiked h calculnled nnd reported. Acceptable range vorics depending on sample m~triJC and snaly~i~
mctho<.l. Any out-of-control QC dnt.'l i$ clearly indicated .
Page 2 of2
-
... .. -..
------------
--.. ...
D-TEK Analytical Laboratories, Inc.
9020 Kcnam~tr Drive. Suite 205
DUD.EK & ASSOCIATES
605 Third Street
Encin.itas, CA 92024
Attn: Ms. Nicole Peacock
Date of Report:
Sampling Date:
.Date Sample Received:
Date Extracted:
Date Analyzed:
Analyzed By:
Sample Type:
Ptoject Number:
P1·ojcct Name:
Log#
06-2674
06~2675
06-2676
06-2677
*06-2678
Sample ID!
MS-9-2'
MS~9-4'
MS-10-2'
MS~l0-4'
MS-11-1"
San Diego, CA 92121
(858) 566-4540-FAX (858) 566-4542
4/24/06
4/19/06
4/20/06
4/20/06
April 21, 2006
EA
Soil
5089~02
Muroya Property Phase 11
ANALYSES RESULTS
Analysis:
Method:
Units:
TPH-Diesel
DHSJ.JUFT
mg/kg
<10
<10
<10
<10
<10
*Also contains Motor Oil _Concentration= 10520 ppm
Range: CJO-C44. Sample Quantita.ted against Motor Oil
~·
.Ellen Atienza
Operations Manager
TPH • Total Pctro!cun, Hydroc:ubons
DI--IS ·Recommended Procedure From Le~king Underground Fuel Tank Field Manual, May 19R9
·rotal Petroleum J-lydroc!ltbon analysis l'csulting in hydrocarbons of the mnge C10-C23. S"mple quantitated against diesel.
, ..
...
~··
.. --
----
.. • ...
• ...
•
• ..
.Oate:
Attn:
Date Analyzed:
AnJtlysis Method:
Snmple Log #:
METHOD BLANK
D-TEK Analytical Laboratories, lnc.
9020 Kenamar Drive, Suite 205
San Diego, CA 92121
(858) 566-4540 FAX (858) 566-4542
QUALITY CONTROJ.J DATA REPORT
4/24/06
Ms. Nicole Pencoclc
April 21, 2006
DHS LUFT (TPH-Diesel)
06-2674 to 06-2678
No target analytcs were detected in the method blank.
LABORATORY CONTROL SAMPI~E
Compound o/o Recovery Dup o/o Recovery
TPH-Dicscl 112 118
e;~---= Ellen Atien.z
Operations Manager
Q!M__l.._JTY CON'fROL TERMJ.tilli.OGY
5
LCS-J.AilORA'rORY CONTROL SAMI'Lt. Reported na %recovery of an independent atnndnrd cnrtlcd through oll sample
prtpamtion procedures to verify method pcrforrrwlcc. Acceptable range Is 80% -I 20"/n . Any out-of-contrul QC dam iA clearly
indicated .
Srll<~>-cnvironmclltal somLllc is mntrbc spiked with method compounds ~nd% rceovcty or conccntmtion spiked into Ramplc is calculated.
Reported ru;% recovery. Acceptable r:mgc for "Normal Mntrix Sample" is 75% 125%. Any out-of-control QC c.lnta is clearly ind\c~tcd .
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CHAIN·O F..CUSTODY RECORD AND ANALYSIS REQUEST FORM
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LAB SAMPI..E COL.l.!C:TtON MATRIX
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TOTAL Nllt.IBER OF COtiTAlHERS PSR ANAl. YSlS:
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Send RBsi.I!Utmd Jmrolcs To:
Peter Quinlan
Dudek & Associates, Inc.
605 Th in:l Str&et
Encinitas, CA 92024
Tel: 619/942-5147
Fax: 619{632.0164
SAMPlE CONTA!NI!RS
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ANALYSES REQUEST!!O
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