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HomeMy WebLinkAbout08853-06-06; Buerger Property; Buerger Property; 1998-08-01U; •• i J. '*f T i ji* GEOCON LIMITED SOIL SAMPLING AND ANALYSIS REPORT BUERGER PROPERTY CARLSBAD, CALIFORNIA PREPARED FOR ERVIN, COHEN & JESSUP LLP BEVERLY HILLS, CALIFORNIA PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE AUGUST 1998 GEOCON GEOTECHNICAL AND ENVIRONMENTAL CONSULTANTS Project No. 08853-06-02 August 31, 1998 "MM %*•* "Ml Mr. Roger Holt Ervin, Cohen & Jessup LLP 9401 Wilshire Boulevard, 9th Floor Beverly Hills, California 90212-2974 Subject: BUERGER PROPERTY CARLSBAD, CALIFORNIA LIMITED SOIL SAMPLING AND ANALYSIS REPORT Dear Mr.Holt: In accordance with your request representing Ervin, Cohen & Jessup LLP (ECJ), on behalf of Western Pacific Housing Development, L.P. (Client), Geocon Environmental Consultants, Inc. (Geocon) has conducted limited soil sampling and analysis for the subject property identified as the Buerger Property. The approximately 5.05-acre subject property is located north of Aviara Parkway and adjacent to the east of proposed Black Rail Road in Carlsbad, California. The property is further identified by County of San Diego Assessor's Parcel Numbers 215-040-08 and -10. It is understood that ECJ is acting as the agent for Client. The accompanying report presents the details of the limited soil sampling and analysis. If questions concerning the contents of the report arise, or if Geocon may be of further service, please contact the undersigned at your convenience. Very truly yours, GEOCON ENVIRONMENTAL CONSULTANTS, INC. rian Office Manager KGB:BWS:sc (1) Addressee (3) Western Pacific Housing Development, L.P, Attention: Ms. Sondra Harris (1) Buerger Enterprises Incorporated Attention: Mr. William Buerger Kristen G. Boyce Senior Staff Engineer 6970 Flanders Drive • San Diego, California 92121-2974 • Telephone (619) 558-6100 • Fax (619) 558-8437 m TABLE OF CONTENTS * LIMITED SOIL SAMPLING AND ANALYSIS REPORT Page MM - 1. INTRODUCTION 1 1.1. Background and Purpose 1 1.2. Scope of Services 2 -* 1.3. Site Location 2 1.4. County of San Diego Department of Agriculture 2 ~ 2. SAMPLING AND ANALYSIS 3 2.1. Sample Locations 3 ** 2.2. Summary of Field Activities 3 M, 2.3. Laboratory Testing Rationale 4 2.4. Laboratory Test Results 5 m 2.4.1. Organochlorine Pesticides 5 -, 2.4.2. Chlorinated Herbicides 6 *• 3. DISCUSSION 6 ^ 3.1. Proposition 65 Requirements 6 3.2. Waste Characterization 7 ** 3,3. Preliminary Remediation Goals 7 ~ 4. CONCLUSIONS 9 M 5. LIMITATIONS 10«•« IN ""• 1. Vicinity Map 2. Site Plan Ml "- Tables: I. Summary of Analytical Results - Organochlorine Pesticides *MI Appendixes: A. Geocon Proposal No. LE-98132 ** B. Laboratory Reports and Chain of Custody Documentation m LIMITED SOIL SAMPLING AND ANALYSIS REPORT m 1. INTRODUCTION *• This report has been prepared by Geocon Environmental Consultants, Inc. (Geocon) in accordance m with the request of Roger J. Holt of Ervin, Cohen & Jessup LLP (ECJ) on behalf of Western Pacific Housing Development, L.P. (Client). The report presents the results of limited soil sampling and analysis for the approximately 5.05-acre property located north of Aviara Parkway and adjacent to «•the east of proposed Black Rail Road in Carlsbad, California. urn «• 1.1. Background and Purpose «M Aerial photograph research conducted during a Phase I Environmental Site Assessment (ESA) for the subject site indicated that the subject site has historically been utilized for agricultural purposes since at least 1960. The results of the ESA were presented in a report entitled Phase I Environmental *"" Site Assessment, Buerger Property, Carlsbad, California, prepared by Geocon and dated August 14, *" 1998. An interview with Mr. Bill Buerger, property owner, also indicated that there has been ^, historical agricultural use of the property. The property is currently occupied by two greenhouses ,_ utilized primarily for the growing of orchids and ferns. The western-most portion of the property is utilized for the growing of Bird-of-Paradise. According to the County of San Diego Department of Environmental Health (DEH), Site Assessment and Mitigation (SAM) Division, soil impacted by the legal application of pesticides/herbicides is not considered a hazardous waste assuming that the soil will not be transported off-site, will not be treated on-site, and will not pose a threat to public health or the environment. Substances, including some pesticides and herbicides, determined by the State of California to be known or suspected carcinogens or to cause reproductive toxicity, are regulated in accordance with the Safe Drinking Water and Toxic Enforcement Act of 1986, also known as Proposition 65. The soil sampling and laboratory testing activities summarized herein were conducted to evaluate the potential presence of organochlorine pesticides and herbicides in near- surface soil on-site and their levels vis-a-vis the levels that constitute hazardous waste or pose a significant risk of harm to human health under applicable law. Project No. 08853-06-02 -1 - August 31, 1998 PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE Hi «M, m 1.2. Scope of Services * Geocon's Proposal No. LE-98132, dated August 3, 1998, is included herein as Appendix A and m outlines the scope of services proposed for the limited soil sampling and analysis. <•! m 1.3. Site Location *™ The site is located north of Aviara Parkway and adjacent to the east of proposed Black Rail Road in «• Carlsbad, California. The site is bounded by property utilized for agricultural activity to the north • and south; undeveloped open space area and graded property to the east; and Black Rail Road under construction to the west. The approximate location of the site is depicted on the Vicinity Map presented as Figure 1. A Site Plan depicting the approximate site boundaries and soil sampling locations is included as Figure 2. The property is further identified by County of San Diego *" Assessor's Parcel Numbers 215-040-08 and -10. •»*• JHU 1.4. County of San Diego Department of Agriculture <•» During the referenced ESA, a representative of Geocon requested a search of County of San Diego 'ami Department of Agriculture records for information concerning agriculture-related permits and •r*violations for the site and the adjacent properties. As of the date of the ESA report, Department of *"' Agriculture personnel had not responded to Geocon's request for information. _, Department of Agriculture personnel have since indicated that records were available for the subject ^ site. Department personnel further indicated that records are maintained for two years prior. Information obtained from the Department of Agriculture referenced two permits for PACIFIC RIM FLOWERS & ORCHIDS for a flower greenhouse and outdoor flowers, respectively. The permit for the flower greenhouse indicated that on three occasions, January 25, February 22, and March 15, 1997, 4.00 ounces of CHIPCO 26019 BRAND FUNGICIDE was applied to 0.5 acres of the property. The permit further indicated that on May 17, 1997, 1.00 ounces of SPECTRACIDE ^ DIAZON LIQUID was applied to 1.00 acres of the property. The permit for the outdoor flowers ^ indicated that on June 15, 1997, 4.00 ounces of ROUNDUP HERBICIDE was applied to 0.50 acres of the property. These agricultural chemicals are not regulated as carcinogens or reproductive toxins 'ani by the State of California and application of the quantities referenced do not represent a significant "" risk to human health or the environment. Project No. 08853-06-02 -2- August 31, 1998 PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE During the referenced ESA the current property owner, Mr. Bill Buerger indicated that he has owned the property for approximately 16 years. Mr. Buerger further indicated that he has utilized the property only for the cultivation of orchids and plants similar to those observed during the site reconnaissance since purchasing the property. Mr. Buerger also indicated that fertilizing of the property has also been consistent with that observed during the site reconnaissance. The fertilizer and pesticides have been pre-mixed off-site and then pumped into the holding tank for delivery through the watering system, or mixed in the area adjacent to the pesticide/fertilizer storage cabinet and then piped through the watering system for the past 16 years. Although the Department of Agriculture does not have records for the year 1998, based on the 1997 permits and information provided by Mr. Buerger, it appears that the chemicals currently used are not regulated as carcinogens or reproductive toxins by the State of California and do not represent a significant risk to human health. 2. SAMPLING AND ANALYSIS 2.1. Sample Locations *• Seven sampling locations, three biased and four random, were selected throughout the subject site. — The biased sampling locations were selected at areas where the site reconnaissance or research had indicated the existing or historical presence of agricultural activity and at locations where pesticides/herbicides have been stored or handled. The approximate sampling locations are depicted on the Site Plan, Figure 2. The three biased locations, adjacent to the northern property boundary, in proximity to the holding tank, and in proximity to the storage cabinet, were identified as PRF1 """ through PRF3, respectively. The remaining four locations, PRF4 through PRF7 were selected at *- random since information obtained during the referenced ESA indicated that similar agricultural — chemicals have been applied throughout the subject site. Although sampling was conducted in the southern greenhouse, sampling was not conducted in the northern greenhouse because both greenhouses were subject to similar pesticide/herbicide use and the near-surface soil at both MM greenhouses likely contains similar residual concentrations of the chemicals used. *M 2.2. Summary of Field Activities Exploratory borings PRF1 through PRF7 were advanced by representatives of Geocon on August 12, 1998, utilizing a stainless-steel hand auger. Three soil samples were obtained from each boring at depths of approximately 0 to 6 inches, 1 to 1/2 feet, and 2 to 2!/2 feet below the ground surface with "*"" the exception of boring PRF5 at which refusal was encountered at approximately 11A feet. The soil Project No. 08853-06-02 - August 31, 1998 PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE samples were placed in 4-ounce glass jars, which were capped with Teflon-lined lids, labeled, and placed in a chilled cooler for transport to a laboratory for potential analyses. Ml Quality assurance/quality control procedures were implemented during the field activities. The * procedures included using chain-of-custody procedures when transferring the soil samples to the • laboratory for analyses and cleaning the hand augers in a trisodium phosphate solution followed by «• successive rinses in tap and deionized water between sampling events. -» 2.3. Laboratory Testing Rationale ** The 14 soil samples collected at the ground surface to approximately 6 inches and at a depth of *• between approximately 1 to 1 '/2 feet were analyzed for the presence of organochlorine pesticides •m following Environmental Protection Agency (EPA) Test Method 8080 and for organochlorine ^ herbicides following EPA Test Method 8150. The 6 soil samples collected at a depth of between approximately 2 and 2l/2 feet were initially held by the laboratory for potential future analyses. Concentrations of 4,4'-DDE, 4,4'-DDD, 4,4'-DDT, and Dieldrin were detected in the soil samples MM collected from six of the seven sampling locations (PRF1 through PRF3 and PRF5 through PRF7). '** At four of the sampling locations (PRF1, PRF2, PRF5, and PRF7) the detected concentrations of *"• certain organochlorine pesticides did not attenuate with depth. Subsequently the three soil samples ^ collected from 2 to 25/2 feet below the ground surface at the sampling locations where the detected ^ organochlorine pesticides did not attenuate with depth (PRF1, PRF2, and PRF7) were subjected to analyses for organochlorine pesticides following EPA Test Method 8080 (PRF5 encountered refusal M at l'/2 feet and no sample below this depth could be tested). The three soil samples collected from 2 to 2'/2 feet below the ground surface at the sampling locations where the detected organochlorine —' pesticides attenuated with depth to non-detect or were non-detect throughout (PRF3, PRF4, and — PRF6) were not subjected to analyses for organochlorine pesticides since it is unlikely that a non- -w-[ impacted middle layer would be present. MM Organochlorine pesticides/herbicides, as opposed to organophosphate pesticides/herbicides, were •H selected for analyses since, of the compounds which may have historically been applied on agricultural crops/flowers located on and/or in proximity to the site, organochlorine compounds are m relatively more environmentally-persistent and are more likely to be regulated by Proposition 65. «• Based on Geocon's knowledge of the area, organophosphate pesticides/herbicides were not generally m used historically and tend to degrade relatively quickly compared to organochlorine ~' Project No. 08853-06-02 -4- August 31, 1998 PRIVILEGED AND CONFIDENTIAL *" ATTORNEY-CLIENT PRIVILEGE _ ATTORNEY WORK PRODUCT *"* SELF-EVALUATIVE PRIVILEGE pesticide/herbicides. Waste classification of organophosphate pesticides/herbicides is therefore not an issue. IMh 2.4. Laboratory Test Results M Reproductions of the laboratory reports and chain-of-custody documentation are included as Appendix B. The results of the laboratory analyses are summarized in Table I. w* ^ 2.4.1. Organochlorine Pesticides «» Organochlorine pesticides were not detected in the soil samples collected from boring PRF4. The w pesticide 4,4'-DDT, its natural degradation product 4,4'-DDE, and Dieldrin were detected in the soil samples collected from boring PRF1. These compounds were detected at concentrations of 23, 79, and 16 micrograms per kilogram (ug/kg), respectively, at the ground surface to a depth of«•< approximately 6 inches; concentrations of 60, 180, and 31 ug/kg, respectively, at a depth of between approximately 1 and 11/2 feet; and concentrations of 30, 41, and 20, respectively, at a depth of "" between approximately 2 and 2!/2 feet. 4,4'-DDD, a natural degradation product of 4,4'-DDT, was *• detected at a concentration of 8.9 (ig/kg at a depth of between approximately 2 and 2'/2 feet. No other __, Organochlorine pesticides were detected in these soil samples. This boring was located near the northern boundary of the site. The pesticide 4,4'-DDT and its natural degradation product 4,4'-DDE were detected in the soil samples collected from boring PRF2. These compounds were detected at concentrations of 9.2 and *"" 18 jig/kg, respectively, at the ground surface to a depth of approximately 6 inches; and mm concentrations of 14 and 10 ^g/kg, respectively, at a depth of between approximately 1 and V/2 feet. *. 4,4'-DDT and 4,4'-DDE were not detected at a depth of between approximately 2 and 2'/2 feet. No other Organochlorine pesticides were detected in these soil samples. This boring was located near the pesticide/fertilizer holding tank. L^B The pesticide 4,4'-DDT and its natural degradation product 4,4'-DDE were detected in the soil ~ sample collected from boring PRF3 at the ground surface to a depth of approximately 6 inches. m These compounds were detected at concentrations of 14 and 18 ug/kg, respectively. The soil sample — collected from boring PRF3 at a depth of between approximately 1 and 1 !/2 feet did not exhibit detectable concentrations of 4,4'-DDT or 4,4'-DDE. No other Organochlorine pesticides were detected in these soil samples. This boring was located near the pesticide/fertilizer storage cabinet. Project No. 08853-06-02 -5- August 31, 1998 PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE The pesticide 4,4'-DDT and its natural degradation product 4,4'-DDE were detected in the soil samples collected from boring PRF5. These compounds were detected at concentrations of 20 and 77 •n ug/kg, respectively, at the ground surface to a depth of approximately 6 inches; and concentrationsing. of 30 and 127 p-g/kg, respectively, at a depth of between approximately 1 and VA feet. Dieldrin was * detected in sample PRF5-2 at a concentration of 13 ng/kg. No other organochlorine pesticides were m detected in these soil samples. This boring was also located along the northern boundary of the site. «H The pesticide 4,4'-DDE, a natural degradation product of 4,4'-DDT, was detected at a concentration of 54 ug/kg in the soil sample collected from boring PRF6 at the ground surface to a depth of Mi approximately 6 inches. The soil sample collected from boring PRF6 at a depth of between !•)•approximately 1 and l'/2 feet did not exhibit a detectable concentration of 4,4'-DDE. No other m> organochlorine pesticides were detected in these soil samples. This boring was located to the west of m the northern-most greenhouse. «•> The pesticide 4,4'-DDT and its natural degradation product 4,4'-DDE were detected in the soil samples collected from boring PRF7. These compounds were detected at concentrations of 7.0 and 13 M-g/kg, respectively, at the ground surface to a depth of approximately 6 inches; and_|I concentrations of 15 and 47 ng/kg, respectively, at a depth of between approximately 1 and VA feet. — 4,4'-DDT and 4,4'-DDE were not detected in the sample collected at a depth of between M approximately 2 and 2'/2 feet. No other organochlorine pesticides were detected in these soil samples. M, This boring was located near the southwest corner of the site. w _ 2.4.2. Chlorinated Herbicides *• The soil samples collected and analyzed by the laboratory did not exhibit detectable concentrations M of chlorinated herbicides. Hi' — 3. DISCUSSION ,m 3.1. Proposition 65 Requirements«* m The pesticides 4,4'-DDT, 4,4'-DDE, 4,4'-DDD, and Dieldrin are regulated by Proposition 65 as human carcinogens. Proposition 65 prohibits a person in the course of doing business from knowingly and intentionally exposing an individual to a chemical, known to the State to cause cancerurnor reproductive toxicity, at a concentration that poses a significant human health risk without first ^ giving that individual clear and reasonable warning. To waive this disclosure requirement, PrqjectNo. 08853-06-02 -6- August31, 1998 PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE Proposition 65 regulations require that an assessment of potential adverse human health effects be performed to determine whether potential exposures to 4,4'-DDT, 4,4'-DDE, 4,4'-DDD, and Dieldrin would result in a significant risk to human health. If the finding of the risk assessment is that potential exposure to 4,4'-DDT, 4,4'-DDE, 4,4'-DDD, and Dieldrin does not result in a significant risk to human health, disclosure of the presence of the 4,4'-DDT, 4,4'-DDE, 4,4'-DDD, and Dieldrin would not be required under applicable law. Based upon the concentrations of organochlorine pesticides detected, such an assessment would conclude that the organochlorine pesticides on-site do not constitute a significant risk to human health. 3.2. Waste Characterization According to the DEH SAM Division, the impacted surficial soil would not be considered a hazardous waste under any circumstances unless the soil is either treated on-site or is transported off-site. If the on-site pesticide-impacted soil, i.e., the upper approximately top 3 feet of on-site soil, is to be treated on-site or transported off-site, additional soil sampling and analyses would be required for waste classification purposes. However, grading, moving, or placing the affected soil as fill would not constitute treatment if the intent is not to render the soil less hazardous or non- hazardous. 3.3. Preliminary Remediation Goals A document issued by the EPA entitled Region 9 Preliminary Remediation Goals (PRGs), 1998 was reviewed to compare the concentrations of pesticides detected in on-site soil to the respective PRGs for soil in a residential setting. The PRGs are "risk-based tools for evaluating and cleaning up contaminated sites. The EPA Region 9 (in which the site is located) PRGs combine current EPA toxicity values with "standard" exposure factors to estimate contaminant concentrations in environmental media (soil, air, and water) that are considered protective of humans, including sensitive groups, over a lifetime." The PRGs are therefore conservative figures and thus "chemical concentrations above these levels would not automatically designate a site as "dirty" or trigger response action." However, concentrations below PRG levels would not pose a significant risk to human health. The PRGs for DDT, DDE, DDD, and Dieldrin in soil in a residential setting are 1,700, 1,700, 2,400, and 28 ug/kg, respectively. All of the concentrations of these chemicals detected at the subject site were less than the PRGs except for sample PRF1-2 collected at a depth of l!/2 feet which exhibited a Dieldrin concentration of 31|ig/kg. Considering that Dieldrin was detected in only 4 of 17 samples analyzed and that sample PRF1-3 collected from the same boring at a depth of Project No. 08853-06-02 -7- August 31, 1998 PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE approximately 2'/2 feet exhibited a Dieldrin concentration of only 20 Hg/kg, the concentration detected in PRF1-1 does not constitute a "representative" exposure concentration for risk assessment purposes. The EPA has also established generic soil screening levels (SSLs) for the protection of groundwater. These generic SSLs were derived using default values in standardized equations adopted by the EPA. Two different SSLs for DDT, DDE, ODD, and Dieldrin are listed by the EPA depending on the degree of dilution and attenuation between the source and a receptor well. However, based on the anticipated depth to groundwater, geologic conditions, and the fact that the agricultural chemicals were applied at the surface and not released below the ground, attenuation of the concentrations detected to insignificant levels likely occurs at a depth that would not adversely affect groundwater quality. Project No. 08853-06-02 -8- August 31, 1998 PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE to 4. CONCLUSIONS Based on a comparison of the concentrations of organochlorine pesticides detected with the PRGs, ** the fact that the property will be graded prior to residential development, and the general attenuation IM of concentrations with depth combined with the anticipated depth to groundwater, the laboratory test )to results suggest that near-surface on-site soil is not impacted by organochlorine pesticides or herbicides at concentrations which would likely pose a significant risk to human health or threat to ^^groundwater. If export or treatment of the upper approximately 3 feet of soil, i.e. pesticide-impacted soil, is contemplated during future development of the property, additional soil sampling and ** analyses in accordance with applicable regulations would be required for waste classification • purposes. However, grading, moving, or placing the affected soil as fill would not constitute pi treatment if the intent is not to render the soil less hazardous or non-hazardous. In addition, ^ additional sampling and analyses for waste classification purposes is not necessary for soil exported from depths greater than approximately 3 feet below the existing ground surface. to * Project No. 08853-06-02 -9- August 31, 1998 PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE SOURCE: 1998 THOMAS BROTHERS MAP SAN DIEGO COUNTY, CALIFORNIA REPRODUCED WITH PERMISSION GRANTED BY THOMAS BROTHERS MAPS. THIS MAP IS COPYRIGHTED BY THOMAS BROS. MAPS. IT IS UNLAWFUL TO COPY OR REPRODUCE ALL OR ANY PART THEREOF, WHETHER FOR PERSONAL USE ORRESALE, WITHOUT PERMISSION M NO SCALE GEOCON ENVIRONMENTAL CONSULTANTS INCORPORATED 6970 FLANDERS DRIVE - SAN DIEGO, CALIFORNIA 92121 - 2974 PHONE 619 558-6100 - FAX 619 558-8437 VICINITY MAP BUERGER PROPERTY CARLSBAD, CALIFORNIA JAK/ RSS DSK / EOOOO DATE 8-31-1998 PROJECT NO. 08853 - 06 - 02 FIG. 1 1VICMAP PRF7 LEGEND APPROXIMATE LOCATION OF BORING M SCALE: 1"=100' GEOCON ENVIRONMENTAL CONSULTANTS INCORPORATED 6970 FLANDERS DRIVE - SAN DIEGO, CALIFORNIA 92121 - 2974 PHONE 619 558-6100 • FAX 619 558-8437 SITE PLAN BUERGER PROPERTY CARLSBAD, CALIFORNIA KGB/RSS DSK / EOOOO DATE 8-31-1998 PROJECT NO. 08853 - 06 - 02 FIG. 2 8853KB TABLE I SUMMARY OF ANALYTICAL RESULTS Oreanochlorine Pesticides SAMPLE IDENTIFICATION PRF1-1 PRF1-2 PRF1-3 PRF2-1 PRF2-2 PRF2-3 PRF3-1 PRF3-2 PRF4-1 PRF4-2 PRF5-1 PRF5-2 PRF6-1 PRF6-2 PRF7-1 PRF7-2 PRF7-3 Approx. Depth (feet) '/2 l!/2 2'/2 '/2 11/2 2/2 '/Z T/Z '/2 l'/2 '/2 l'/Z '/Z l'/2 !/2 I'/Z 2'/2 4,4>-DDE (Hg/kg) 79 180 41 18 10 ND 18 ND ND ND 77 127 54 ND 13 47 ND Dieldrin (US/kg) 16 31 20 ND ND ND ND ND ND ND ND 13 ND ND ND ND ND 4,4'-DDD (Hg/kg) ND ND 8.9 ND ND ND ND ND ND ND ND ND ND ND ND ND ND 4,4'-DDT (Hg/kg) 23 60 30 9.2 14 ND 14 ND ND ND 20 30 ND ND 7.0 15 ND Note: jag /kg = micrograms per kilogram ND = not detected above laboratory detection limit The compounds analyzed by EPA Test Method 8150 (organochlorine herbicides) were not detected above their respective detection limits. Project No. 08853-06-02 PRIVILEGED AND CONFIDENTIAL ATTORNEY-CLIENT PRIVILEGE ATTORNEY WORK PRODUCT SELF-EVALUATIVE PRIVILEGE August 31, 1998 f c c c i: c t GEOCON GEOTECHNICAL AND ENVIRONMENTAL CONSULTANTS Project No. 08853-06-02 Proposal No. LE-98132 Augusts, 1998 VIA FACSIMILE AND U.'S. MAIL Roger Holt, Esq. Ervin, Cohen & Jessup LLP 940 IWilshire Boulevard, 9th Floor Beverly Hills, California 90212-2974 Subject: BUERGER PROPERTY CARLSBAD, CALIFORNIA PROPOSAL - LIMITED SOIL SAMPLING AND ANALYSIS Dear Mr. Holt: In accordance with your request on behalf of Western Pacific Housing (Client), Geocon Environmental Consultants, Inc. (Geocon) is pleased to present this proposal to perform limited soil sampling and analysis for the subject site. The approximately 5.05-acre subject site is located north of Aviara Parkway and adjacent to the east of proposed Black Rail Road in Carlsbad, California. Aerial photograph research conducted during a Phase I Environmental Site Assessment (ESA) for the subject site indicated that the subject site has historically been utilized for agricultural purposes since at least 1960. An interview with Mr. Bill Buerger, property owner, also indicated that there has been historical agricultural use of the property. The property is currently occupied by two greenhouses utilized primarily for the growing of orchids and ferns. The western-most portion of the property is utilized for the growing of Bird-of-Paradise. Residual concentrations of pesticides and/or herbicides, regulated as chemicals known to the State of California to cause cancer or reproductive toxicity through Proposition 65, may be present in the near-surface soil on-site. PURPOSE AND SCOPE OF SERVICES Based on information obtained during the referenced Phase I ESA, the following scope of work would be performed to evaluate the potential presence of organochlorine pesticide and herbicide impacts to near-surface soil at the subject site: Task I - Pre-Field Activities Prepare a Health and Safety Plan for the use of Geocon employees during the field activities. The Health and Safety Plan would recommend levels of personal protective equipment (PPE) during the field activities and would outline general health and safety considerations. 6970 Flanders Drive • San Diego, California 92121-2974 • Telephone (619) 558-6100 • Fax 1619} 558-8437 Task II - Field Activities Wf' • At 7 random and biased sampling locations, soil samples would be collected from 0 to 6 inches ^' below the existing ground surface, approximately 1 to 1/2 feet below the existing ground surface, •»»' and approximately 2 to 2Vz feet below the existing ground surface. The samples would be collected utilizing a hand auger, transferred to laboratory-supplied glass jars, capped with Teflon- lined lids, labeled, placed in a cooler with ice, and transported to a California Department of *"1 Health Services (CDOHS)-certified analytical laboratory. am • The 14 soil samples collected from 0 to 6 inches below the existing ground surface and *"* approximately 1 to I'/z feet below the existing ground surface would be subjected to analyses for ^ organochlorine pesticides following United States Environmental Protection Agency (EPA) Test Method 8080, and for organochlorine herbicides following EPA Test Method 8150. Samplesgggi collected from 2 to 2'/z feet below the ground surface would be held for potential future testing, *•' pending the results of the initial analyses. tftt*• Backfill the resulting hand-augered borings with the soil cuttings generated. vt*** • Perform quality assurance/quality control procedures during the field activities. These procedures be' would include cleansing the sampling equipment in a trisodium phosphate solution followed by """ successive rinses in tap and deionized water prior to each sampling effort and providing chain-of- ^ custody documentation for each sample collected and transferred to the laboratory. mf Task III - Report Preparation Prepare a report of the findings of the soil sampling and laboratory testing. A figure depicting the ^. locations of the borings, the results of the laboratory analyses, and the results of the quality assurance/quality control measures would be included in the report. PROPOSED FEE Geocon proposes to perform the scope of services outlined herein on a "lump sum" basis for a fee of The fee is based on the anticipated conditions presented herein. The fee also assumes the laboratory test results would be provided on a standard turn-around time basis of seven to ten working days. If different conditions are identified or as additional information is obtained, it may become necessary to revise the scope of services and associated fee. Please carefully review the contents of this proposal and the enclosed Change Order Agreement for Professional Services (Change Order No. 001-KGB). If they meet with your approval, execute both copies of the Change Order, and return one fully-executed copy to our office. Project No. 08853-06-02 - 2 - August 3, 1998 Proposal No. LE-98132 Should you have any questions regarding this proposal, or if Geocon may be of further service, please contact the undersigned at your convenience. Very truly yours, GEOCON ENVIRONMENTAL CONSULTANTS, INC. Irian W. Sta^f^r ~ Kxisten G. Boyce Office Manager Senior Staff Engineer KGB:BWS:sc (1) Addressee (1) Western Pacific Housing Attention: Ms. Sondra Harris Project No. 08853-06-02 - 3 - August 3, 1998 Proposal No. LE-98132 I I I I I I I I I I I • P" I I I I Advanced Technology Laboratories August 21,1998 ELAPNo.: 1838 Geocon Environmental 6970 Flanders Drive San Diego, CA 92121 ATTN: Ms. Kristen Boyce Client's Project: Buerger Property, 08853-06-02 Lab No.: 28274-001/020 Gentlemen: Enclosed are the results for sample(s) received by Advanced Technology Laboratories and tested for the parameters indicated in the enclosed chain of custody. The samples for EPA 8150 were sub-contracted out to APCL with DOHS certification # 1431. Thank you for the opportunity to service the needs of your company. Please teel free to call me at (562) 989 - 4045 if 1 can be of further assistance to your company. Sincerely, Cheryl Db Los Reyes Technical Operations Manager CDR/Ib Enclosures This cover letter is an integral part of this analytical report. Tlus report pertains only to the samples investigated and does not necessarily apply to other apparently identical or similar materials. Tliis report is submitted tor the exclusive use of the client to whom it is addressed. Any reproduction of this report cruse of tliis Laboratory's name for advertising or publicity purpose without aiithonzaflon is prolubiled. Mailing Address: P.O. Box 9JOS Newport Beach, CA 92658 1510 E. 33rd Street Signal Hill, CA 90807 Tel: 562 989-4045 Fax: 562 989-4040 Client: Geocon Environmental Attn: Ms. Kris ten Boyce Client's Project: Date Received: Extraction Method: Matrix: Units: Date Amended: Buerger Property, 08853-06-02 08/13/98 3550 Soil ug/kg 08/19/98 Lab No.: Client Sample ID.: Date Sampled: QC Batch #: Date Extracted: Date Analyzed : Analyst Initials: Dilution Factor: S3S5SSS^SS«s:*M*»:W«M!S!A!^l:!iy:iS4&!XVXf&m&&&xSiEti&SK&&^ZW^SS$S^s Alpha-BHC Gamma-BHC (Lindane) Beta-BHC Heptachlor Delta-BHC Aldrin Heptachlor Epoxide Endosulfan I 4,4'-DDE Dieldrin Endrin 4,4'-DDD Endosulfan II 4,4'-DDT Endrin Aldehyde Endosulfan Sulfate Methoxychlor Chlordane Toxaphene 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 Method Blank — —H988080S274 08/15/98 08/18/98 DT 1 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 'flliHiaip; ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 28274-001 PRF1-1 —H988080S274 08/15/98 08/18/98 DT 1 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 :;:««&*; ND ND ND ND ND ND ND ND 79 16 ND ND ND 23 ND ND ND ND ND 28274-002 PRF1-2 —H988080S274 08/15/98 08/18/98 DT 1mm 2 2 2 2 2 2 2 2 8 4 4 4 4 4 4 4 17 17 170 ND ND ND ND ND ND ND ND 180* 31 ND ND ND 60 ND ND ND ND ND 28274-004 PRF5-1_ H988080S274 08/15/98 08/18/98 DT 1mm 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 Ifcsaife ND ND ND ND ND ND ND ND 77 ND ND ND ND 20 ND ND ND ND ND 28274-005 PRF5-2 —H988080S274 08/15/98 08/18/98 DT 1mm 2 2 2 2 2 2 2 2 8 4 4 4 4 4 4 4 17 17 170 mm# ND ND ND ND ND ND ND ND 127" 13 ND ND ND 30 ND ND ND ND ND 28274-006 PRF7-1 —H988080S274 08/15/98 08/18/98 DT 1 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 &M&: ND ND ND ND ND ND ND ND 13 ND ND ND ND 7.0 ND ND ND ND ND MDL = Method Detection Limit ND = Not Detected (Below DLR) DLR = MDL X Dilution Factor NA = Not Analyzed* = Dilution Factor Is Z Reviewed/Approved By: Lee Ingvaldson Department Supervisor Date: The cover letter is an integral part of this analytical report. ^Advanced Technology Laboratories 1510 E. 33rd Street Signal Hilt, CA 90807 Tel: 562 989-4045 Fax: 562 989-4040 Client: Geocon Environmental Attn: Ms. Kristen Bovce Client's Project: Date Received: Extraction Method: Matrix: Units: Buerger Property, 08853-06-02 08/13/98 3550 Soil ug/kg Lab No.: Client Sample I.D.: Date Sampled: QC Batch #: Date Extracted: Date Analyzed : Analyst Initials: Dilution Factor: Alpha-BHC Gamma-BHC (Lindane) Beta-BHC Heptachlor Delta-BHC Aldrin Heptachlor Epoxide Endosulfan I 4,4'-DDE Dieldrin Endrin 4,4'-DDD Endosulfan n 4,4'-DDT Endrin Aldehyde Endosulfan Sulfate Methoxychlor Chlordane Toxaphene $pm$ 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 Method Blank — —H988080S274 08/15/98 08/18/98 DT 1 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 mftW ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 28274-007 PRF7-2 —H988080S274 08/15/98 08/18/98 DT 1 PHRg 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 :;::;Re*Btw:;;i ND ND ND ND ND ND ND ND 47 ND ND ND ND 15 ND ND ND ND ND 28274-009 PRF6-1 —H988080S274 08/15/98 08/18/98 DT 1 ifld@ft! 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 ttasato ND ND ND ND ND ND ND ND 54 ND ND ND ND ND ND ND ND ND ND 28274-010 PRF6-2 —H988080S274 08/15/98 08/18/98 DT 1 :;:tofc»:; 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 Resale ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 28274-012 PRF2-1 08/12/98 H988080S274 08/15/98 08/18/98 DT 1•mm 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 m&m ND ND ND ND ND ND ND ND 18 ND ND ND ND 9.2 ND ND ND ND ND 28274-013 PRF2-2 08/12/98 H988080S274 08/15/98 08/18/98 DT 1mm 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 Mfti ND ND ND ND ND ND ND ND 10 ND ND ND ND 14 ND ND ND ND ND MDL = Method Detection Limit ND = Not Detected (Below DLR). DLR = MDL X Dilution Factor NA = Not Analyzed Reviewed/Approved By: Lee Ingvaluson Department Supervisor Date: The cover letter is an integral part of this analytical report. Advanced Technology Laboratories 1510 E. 33rd Street Signal Hill, CA 90807 Tel: 562 989-4045 Fax: 562 989-4040 Client: Geocon Environmental Attn: Ms. Kris ten Boyce Client's Project: Date Received: Extraction Method: Matrix: Units: Buerger Property, 08853-06-02 08/13/98 3550 Soil ug/kg Lab No.: Client Sample LD.: Date Sampled: QC Batch #: Date Extracted: Date Analyzed : Analyst Initials: Dilution Factor: Alpha-BHC Gamma-BHC (Lindane) Beta-BHC Heptachlor Delta-BHC Aldrin Heptachlor Epoxide Endosulfan I 4,4'-DDE Dieldrin Endrin 4,4'-DDD Endosulfan n 4,4'-DDT Endrin Aldehyde Endosulfan Sulfate Methoxychlor Chlordane Toxaphene 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 Method Blank — —H988080S274 08/15/98 08/18/98 DT 1 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 28274-015 PRF3-1 08/12/98 H988080S274 08/15/98 08/18/98 DT 1 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 ND ND ND ND ND ND ND ND 18 ND ND ND ND 14 ND ND ND ND ND 28274-016 PRF3-2 08/12/98 H988080S274 08/15/98 08/18/98 DT 1mm 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 ttessitt ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 28274-018 PRF4-1 08/12/98 H988080S274 08/15/98 08/18/98 DT 1 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 28274-019 PRF4-2 08/12/98 H988080S274 08/15/98 08/18/98 DT 1mm 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 &w$* ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND MDL = Method Detection Limit ND =• Not Detected (Below DLR). DLR = MDL X Dilution Factor NA = Not Analyzed Reviewed/Approved By: Lee Ingyaldson Department Supervisor Date: The cover letter is an integral part of this analytical report. Advanced Technology Laboratories 1510 E. 33rd Street Signal Hill, CA 90807 Tel: 562 989-4045 Fax: 562 989-4040 Method Title Last Update Spike Recovery and RPD Summary Report - SOIL(ug/kg} : C:\HPCHEM\1\METHODS\PCBPEST.M (Chemstation Integrator) : 8080 Pesticides : Sun Jul 12 19:04:32 1998 Response via : Initial Calibration Non-Spiked Sample: HB0818A.D Spike Sample Spike Duplicate Sample File ID : HMS0818A.D Sample : Blank MS E:8/15/98 Acq Time: 18 Aug 1998 6:45 pm HMD0818A.D Blank MSD E:8/15/98 18 Aug 1998 7:23 pm Compound Sample Spike Spike Dup Spike Dup RPD QC Limits Cone Added Res Res %Rec %Rec RPD % Rec gamma -BHC Heptachlor Aldrin Dieldrin Endrin 4,4 ' -DDT 0.0 0.0 0.0 0.0 0.0 0.0 40 40 40 80 80 80 37 37 45 91 90 82 37 37 46 91 90 84 92 93 112 114 112 102 93 94 114 114 113 105 1 1 1 0 1 2 15 20 22 18 21 27 56-123 40-131 40-120 52-126 56-121 38-127 QC Batch #:H988080S274 Reviewed and Approved by:Date Ingvaldson Organics Supervisor dvanced Technology Laboratories 1510 E. 33rd Street Signal Hill, CA 90807 Tel: 562 989-4045 Fax: 562 989-4040 19-98 04:39P APCL Documentation Applied P &: CK Laboratory 13T60 Magnolia AVP. Chino CA 91T1O /\ i-* | Tel: (909)580-1828 Fax: (9O9) 5BO-1496 Submitted to: Advanced Technology Lab Attention: Rachelle Arada 1500 E. 33rd St. Signal Hill CA 90807 Tel: (562)989-4045 Fax: (562)989-4040 Analysis of Soil Samples Component Analyzed Method Unit PQt Chlorinated barbie idea 2,4-D 8150 Hg/kg 10 2,4-DB 8150 ^g/kg 10 Dalapon (dichloro acetic acid) 8150 ^g/kg 20 Dicamba 8150 ^g/kg 10 Dichloroprop 8150 ^g/kg 10 Dinoseb (DNBP) 8150 ^g/kg 20 MCPA 8150 mg/kg .3 MCPP 8150 mg/kg 5 2,4,5'T 8150 ^g/kg 10 2,4,5-TP (Silvex) 8150 ^g/kg 10 ^L Ai Service IF Collected Collected Sample 1 Project 28274-001 /Pi" 98-04431-1 ND ND MD ND ND ND ND ND ND ND Component Analyzed Method Unit PQL Chlorinated herbicides 2,4-D 8150 pg/kg 10 2,4-DB 8150 ^g/kg 10 Dalapon (dichloroacetic acid) 8150 tfg/kg 20 Dicamba 8150 ^g/kg 10 Dichloropiop 8150 ^g/kg 10 Dinoseb (DNBP) 8150 pg/kg W MCPA 8150 mg/kg 5 MCPP 8150 mg/kg 5 2,4,5-T 8150 ^g/kg 10 2,4,5-TP (Silvex) 8150 ^g/kg 10 28274-005/PR] 98-04431-4 ND ND ND SD ND i ND ND ND ND ND CADHS ELAP No.: 1431 (9<19) 59O-149S p. Lal^'tical Report #: 801 >y- m: 08/ escripti esctipt t 984431 Received: 08/14/98 Extracted: 08/18/98 2/98 Tested: 08/18-19/98 Reported: 08/19/98 in: Soil m: P.O. # 20416 .nalysis Result 1-1 282JT4-Q02/PRF1-2 28274-004/PRF5-1 j 98-04431-2 98-04431-3 ND ND ND N'D ND ND ND ND 1 ND ND !ND ND 5-2 28 ND ND ND ND ND ND ND ND Analysis Result T4-006/PRF7-1 28274-007/PRF7-2 98-04431-5 98-04431-6 j ND ND11KD ND ND ND ND ND ND ND ND ND ND ND ND ND j ND ND t ND SD CI-OG20 U 98-4431 t Page: 1 01 Aug-19-98 O4:4OP APCL. Documentation Applied 1 &: Cn Laboratory 13T6U Magnolia Avc;. Chino CA 91710 Teh (909)590-1838 Fax: (DOB) 59O-149C APCL Analytical Report Component Analyzed Method Unit PQL 28274-009/PRF 98-04431-7 Chlorinated harbicid«i 2,4-D 8150 2,4-DB 8150 Dalapon (dichloroacetic acid) 8150 Dicamba S150 10 10 20 10 ND ND ND KD Dichlotoprop Dinoseb (DNBP) MCPA MCPP 2,4V5-T 2,4,5-TP (Silvex) 8150 8150 8150 8150 8150 8150 /*g/kg 10 ,.gAg w mg/kg 5 ing/ kg 5 j/gAg 10 jig Ag 10 ND ND ND ND ND ND Component Analyzed Chlorinated herbicides 2,4-D 2,4-DB Method 8150 8150 Unit PQt, /igAg 10 jigAg 10 28274-013/PRF 98-04431-10 ND ND > 2-2 282 ND ND ND ND ND ND nalysis Result r4-015/PRF3-| J8- 04431-11 ND ND ND ND ND ND ND ND 28274-016/PRF3-2 98-04431-12 ND ND (909) 59O-1498 P. O2 Analysis Result i-1 282T4-010/PRK6-2 28274-Q12/PRF2-1 (98-04431-8 98-04431-9 ND ND ND SD ND ND KD ND Dalapon (dichloroacetic acid) 8150 Dicamba 8150 Dichloroprop 8150 Dinoseb (DNBP) 8150 MCPA 8150 MCPP 8150 2,4,5-T 8150 2,4,5-TP (Silvex) 8150 mg/kg 20 10 10 20 5 5 JO 10 ND ND ND ND ND ND ND ND PQL: Practical Quantit.ition Limit. MDL: Method Detection Limit. N.D.: Nut Detected or leas than the practical quantitation limit.. J: Reported between PQL and MDL. CR:JL CADHS ELAP No.: 1431 ,: Cont Analysis ND "D ND ND ND ND ND ND ND ND ND ND ND ND ND ND pet Required Detection Limit is not required. itted, lboratory Director Applied P & Ch Laboratory Cl-0t,20 U 98-4431 t Page 2 Aug-2O-98 O4:5OP APCU Documentation iea r &: Lli_J^aboratory J3TCO Magnolia Avp. Chino CA 91710 Tel: (909) 500-1828 Fax: (908)590-1498 oSO-1498 P.01 i j APCL Analytical Report Submitted to: Service ID #: 8(1 Advanced Technology Lab . Collected by: Attention: Rachelle Arada Collected on: Of ' 1500 E. 33rd St. I Signal HiJ! CA 90807 Sample C Tel: (562)989-4045 Fax: (562)989-4040 Pr- _: Analysis of Soil Samples 'V Component Analyzed Method Unit PQL Sf8273-010/t 1 98-04477- Cblorinated herbicides 2,4-D 8150 ^g/kg 10 ND 2,4-DB 8150 ^g/kg 10 ND Dalapon (dichloro acetic acid) 8150 jig/kg 20 ND Dicamba 8150 ,,g/kg 10 KD Dichloroprop 8150 ^g/kg 10 ND Dinoseb (DNBP) 8150 ^g/kg 20 ND MCPA 8150 mg/kg 2 ND MCPP 8150 mg/kg 2 ND 2,4,5-T 8150 ^g/kg 10 ND 2.4,5-TP (Silvex) 8150 ^g/kg in ND PQL: Practical Quantit&tion Limit. MDL: Method Detection Limit. CH N.D.: Not Detected or less than the practical quantitation lituit- "-" J: Reported between PQL and MDL. CADHS ELAP Wo.: 1431 >escrip i •ipi -i 28; ' DL: Conl Analyst -984477 Received: 08/18/98 Extracted: 08/19/98 12/98 Tested: 08/19-20/98 Reported: 08/20/98 on: Soil on: P.0.# 20416 Analysis Result M-OI8/PRF4-1 28274-019/PRF4-2 98-04477-2 98-04477-3 KD ND ND KD KD ND ND KD ND ND ND ND ND ND ND ND ND ND HD ND •act Required Detection Limit is not requin-d. ^ , /I 'RespectftJh^stibmM^B, i!//!/ c_L T -*horatory Director Applied P &: Ch Laboratory Cl-nii20 K 98-4477 t] Page: 1 , * . - . -- . --,-... - - •. . • .-.-,.- Sent By: QEOCON ENV. CONSULTANTS, INC.; 619 bhU FAX \Dats [Numb TO:fiance. ATL P/tone Fax Phone S62-989-4Q45 562-989-4040 CO FROi f. Aug-i**--au August I4f 199S f ofpoges indudin&c.ovf-r sheet Pttont Fax? tone REMARKS: Subject: Buerger Property Carlsbad. California For your review Q ^ tply ASAP Pursuant to your request and our telephone conversation on August 13, 998, th have requested quicker turn-around times for the above referenced job. JL is my exception of the organochlorine herbicide results we will have the analy Tuesday August IS4. It is also my understanding that we will have the a of the working day on Wednesday August 19*. I realize that we will be turn-around time. If you have any questions please call our office. Kristen G. Boyce Geocon Environmental Consultants, Inc. 6970 Flanders Drive San Diego CA 92121 ; 619.558.6100 \ 619.558,8437 Comment s letter serves as statement that I understanding that with the ical datp by the end of the working day on ganochlorine herbicide results by the end barged la 20% surcharge for the revised • • • i • I t I I I I I I 1CK..IN L.lCV-fOI JRK-BRB I I I • I ff I I ' loi JCl_ Advanced Technology Laboratories 1510 E. 33rd Street Signal Hill, CA 90807 (562) 989-4045 • FAX (562) 989-4040 FOR LABORATORY USE ONLY: Batch ft: P.O.#: D.O. # Logged By:Date:Time: Method of Transport Walk-in D Courier D UPS D FED. EXP. ATL 1. CHILLED Sample Condition Upon Receipt 4. SEALED YD N B 2. HEADSPACE (VOA) YD ND 5. t OF SPLS MATCH COG Y'D N D 'D h3. CONTAINER INTACT YD ND 6. PRESERVED YD N D Client: GEOCON ENVIRONMENTAL - SAN DIEGO Address: 697Q Flanders Drive City San Diego State CA Zip Code 92121 TEL{ 619 ) 558-6100 FAX:( 619 ) 558-8437 Project Name:Project #:-Ot -Sampler: (pfinted Name)(Signature) Relinquished by: (s.9™tu Date Time:Received by: (Signature and Primed Nam.) Relinquished by: (Sgnatur* and Pnnled Name)Date:Time:Received by: (SigrwluraTand PrimedHunt} f Dale:Time: Relinquished by: (Signalure and Printed Nama)Date :Time:Received by: (Signature and Printed Nam*)Date:Time: SHIP TO LAB: (SUB CONTRACT) TEST: , ATL »: DATE: , .,_._ CLIENT I.D. I hereby authorize ATL to perform the work indicated below: Project Mgr /Submitter: Ppjppfi VAV\eS Date: & / \S Print Name Signature Send Report To: Attn: ________ Co: Address ^ Cit>^__-Zip- Special Instructions/Comments: Unless otherwise requested, all samples will be disposed 45 days after receipt. Sample Archive/Disposal: D Laboratory Standard D Other D Return To: * $10.00 FEE PER HAZARDOUS SAMPLE DISPOSAL. LAB USE ONLY: Batch #:Sample Description Lab No.Sample I.D.Date Time CIRCLE APPROPRIATE MATRIX TAT Container(s) Type Q A/QC BTNE RWQCB D WIP D NAVY D CT D OTHER REMARKS 00 U.I I U1H oct/- \X \ TAT starts 8 a.m. following day if samples received after 5 p.m. TAT: A=Overnight <24hr B=Emergency Next workday Critical 2 Workdays D=Urgent 3 Workdays Routine 7 Workdays Container Types: T=Tube V=VOA L=Liter P=Pint J^Jar B=Tedlaf G=Glass P=Plastic M=Metal Preservatives: H=Hcl N=HN Z=2n(AC)z 0=NaOH « C=4'C DISTRIBUTION: White with report, Yellow to folder, Pink to submitter. iltliliiiiil i 1C* JNLJCU~rOl.lRB. *RB I I I § I f I I I pg i...J <* Jl- m ^^^^^v-^^rAdvanced Technology ^^^J Laboratories 1510E. 33rd Street Signal Hill, CA 90807 (562) 989-4045 - FAX (562) 989-4040 Client: GEOCON ENVIRONMENTAL - Project Name: -p — .., ^ Relinquished by: (Signature and rVinled Name) ' Relinquished by: (Signature and Printed Name) Relinquished by: (Signature and Printed Name) SHIP TO LAB:(SUB CONTRACT) TES ATL DAT F: CLIENT I.D. Unless otherwise requested, all samples will be disposed 45 days after receipt. 1 T E M LAB USE ONLY: Batch #: Lab No. '2$3^' 0 \ ( O\*L £/3 o^\ 01 5~ OH* Ofy 6>/r oft • TAT starts 8 a.m. following samples received after 5 p FOR LABORATORY USE ONLY: Batch #: P.O.It: D.O. * Logqed By: Dale: Time: SAN DIEGO Method of Transport Walk-in D Courier P UPS O FED. EXP. D^ ATL p Sample Condition Upon Receipt 1. CHILLED YCKND 4. SEALED YD N-d 2. HEADSPACE (VGA) YD NO 5. S OF SPLS MATCH COC Y-ON D 3. CONTAINER INTACT YD^ND 6. PRESERVED YDND Address: 6970 Flanders Drive City San Diego State CA Zip Code 92121 TEL:( 619 ) 558-6100 FAX:( 619 ) 558-8437 Project #: Sampler;— (P*t*l Name) ^ -^ (Sigralure) ^ O f y £"£*• G(e - o^ {^v^jC^Ct ^ VT^ OJ&^ C "Vo»j-v\fXQ_ ^C</ir\J&A Date: Time: Received by: (Signaiu™ and Printed Na™t f\ i ^_-— Date:,^ I, -« /s C> Time: tJ "* ?^t1 jC*f*^f* ft // ^/7 *^ ' ' *^ Date : Time: Received by: isignaiur* and Primed NWTH) / Date: " Time: Date : Time: Received by: (Signaiuie and Primed Name) Date: Time: 1 hereby authorize ATL to perform the work indicated below: Project Mgr /Submitter: (~*i ^^— . Prinl Name V"/T2/Y\ fl 0 . ^-O/Y\Jjk Signature Sample Archive/Disposal: D Laboratory Standard n Other G Return To: * $10.00 FEE PER HAZARDOUS SAMPLE DISPOSAL. Sample Description Sample I.O. P^Cp-"? Ml^ -I PQF3-& -^ ? £rvi ?(Uv^ PfU'Vi Popu^\ $Q£^r & day if TAT: A= fgfiW B= Date ^ Time |l'34 N W* U*W _llA5^ v lll^ \\:*t )\:£lt W-HPmi Emergency Next workday Send Report To: Attn: Co: t~?~' Address ^~$^ C\TtS^ Stale Circle or Add / /&/ / / Analysis(es) /<0\J/ / / Requested / ^/jj/r-^/ / /*/*///?// /$//////?///*/*f/m/*/f/$/f///ff/i///*//////*///&7 &/&/$/&/*/ &/ &/&/&/&/&/§ /<? J[ X X u ^t _ Critical u- 2 Workdays Special Instructions/Comments: n.uc Zip M////^/&/ $/ /& /Wf/ /// /P D= X J X X X X X Urgent 3 Workdays ^•^AprHA / / / / / CIRCLE APPROPRIATE / / / / / MATRIX ////«f///j ///////////*//Y / /P/&/*/// M+// /$/?/&/£/ At//// ///^/////m///^ T V _ Routine fc- 7 Workdays Container Types: T=Tube V=VOA L=Liter P=Pint J=Jar B=Tedlaf G=Glass P=Plastic M=Metal C t - / Containers] tt 1 *i i\ \ i i ii Type rt, / ( ") / x. / ( ^PRESERVATIONQ A/QC RWQCB DWIP n NAVY DCT n OTHER REMARKS Preservatives: H=Hcl N=HNO3 S=H,SO« C=4'C Z=Zn(AC)2 O=NaOH T=Na2SzQ3 DISTRIBUTION: White with report, Yellow to folder, Pink to submitter. i i i i I i I I I I I i I ICK 1SIC~lCir~TOIt IRETHRII I I I I i I I I Advanced Technology Laboratories 1510 E. 33rd Street Signal Hill, CA 90807 (562) 989-4045 • FAX (562) 989-4040 FOR LABORATORY USE ONLY: Batch #; P.O.It. D.O. # Logged By:Date:Time: Method of Transport Walk-in D Courier D UPS D FED. EXP. U, ATL £T Sample Condition Upon Receipt 4. SEALED1. CHILLED Y&NO 4. SEALED YD 2. HEADSPACE (VGA) YD ND 5. t OF SPLS MATCH COC Y 1 N C 3. CONTAINER INTACT tfl ND 6. PRESERVED YDNC \fl N ( Client: GEOCON ENVIRONMENTAL - SAN DIEGO Atln: Address: 6970 Flanders Drive City San Diego State CA Zip Code 92121 TEL:( 619 ) 558-6100 FAX:{ 619 ) 558-8437 Project Name:Project #: __ _ Relinquished by: (Signature and Prinld Nama) ' Sampler (PrintedName)(Signature) Date:Time:——— —. . Received by: (Signature and PrinUdNurw)Date: Relinquished by: (Sgnalu™ and Prinled Mama)Date :Time:Received by: (Signature and PiintadNanw}Date:Time: Relinquished by: (Signalura and Printed Hanu,]Date Time:Received by: {Signature and Primed Nanw)Date:Time: SHIP TO LAB: (SUB CONTRACT)_ TEST: ATL#: DATE: CLIENT I.D.. I hereby authorize ATL to perform the work indicated below: Project Mgr/Submitter: Date:III Prtnl Name Signature Send Report To: Attn:^ Co: Address City State_-Zip- Special Instructions/Comments: Unless otherwise requested, all samples will be disposed 45 days after receipt. Sample Archive/Disposal: O Laboratory Standard D Other D Return To: Circle or Add Analysis(es) Requested CIRCLE APPROPRIATE MATRIX * $10.00 FEE PER HAZARDOUS SAMPLE DISPOSAL. LAB USE ONLY: Batch #:Sample Description Lab No.Sample I.D.Date Time Containers] Type QA/QC RTNE 0" RWQCB D WIP D NAVY DCT n OTHER REMARKS '020 AtB TAT starts 8 a.m. following day if samples received after 5 p.m. TAT: A=Overnight <24hr Emergency Next workday C=Critical 2 Workdays Urgent 3 Workdays Routine 7 Workdays Container Types: T=Tube V=VOA L=Liter P^Pint J=Jar B^Tedlaf G=Glass P=Piastic M=Metal Preservatives: H=Hcl N=HNOS S=H Z=Zn(AC)2 O=NaOH C=4'C DISTRIBUTION: White with report, Yellow to folder, Pink to submitter. Advanced Technology Laboratories August 20, 1998 ELAPNo.: 1838 Geocon Environmental 6970 Flanders Drive San Diego, CA 92121 ATTN: Ms. Kristen Boyce Client's Project: Buerger Property, 08853-06-02 Lab No.: 28380-001/003 Gentlemen: Enclosed are the results for sample(s) received by Advanced Technology Laboratories and tested for the parameters indicated in the enclosed chain of custody. Thank you for the opportunity to service the needs of your company. Please feel free to call me at (562) 989 - 4045 if I can be of further assistance to your company. Sincerely, Cheryl De Los Reyes Technical Operations Manager CDR/ms Enclosures This cover letter is an integral part of this analytical report. This report pertains only lo the samples investigated and does not necessarily apply to other apparently identical or similar materials. This report is submitted for the exclusive use of the client to whom it is addressed. Any reproduction of this report or use of this Laboratory's name for advertising or publicity purpose without authorization is prohibited. Mailing Address: P.O. Box 9108 Newport Beach, CA 92658 1510 E. 33rd Street Signal Hill. CA 90807 Tel: 562 989-4045 Fax: 562 989-4040 Client: Geocon Environmental Attn: Ms. Kristen G. Boyce Client's Project: Date Received: Extraction Method: Matrix: Units: Buerger Property, 08853-06-02 08/13/98 3550 Soil ug/kg Lab No.: Client Sample I.D.: Date Sampled: QC Batch* Date Extracted: Date Analyzed : Analyst Initials: Dilution Factor: Alpha-BHC Gamma-BHC (Lindane) Beta-BHC Heptachlor Delta-BHC Aldrin Heptachlor Epoxide Endosulfan I 4,4'-DDE Dieldrin Endrin . 4,4'-DDD Endosulfan II 4,4'-DDT Endrin Aldehyde Endosulfan Sulfate Methoxychlor Chlordane Toxaphene 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 Method Blank - —G988080S282 08/20/98 08/20/98 LI 1*& 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 WffH ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 28380-001 PRF1-3 08/12/98 G988080S282 08/20/98 08/20/98 LI 1 dtahflfe 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 83ttg$ttK ND ND ND ND ND ND ND ND 41 20 ND 8.9 ND 30 ND ND ND ND ND 28380-002 PRF7-3 08/12/98 G988080S282 08/20/98 08/20/98 LI 1 attfefe 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 28380-003 PRF2-3 08/12/98 G988080S282 08/20/98 08/20/98 LI 1s» 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 17 17 170 gngfailig ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ffflSBSHSffirv-.Vfc.'&W-w; MDL = Method Detection Limit ND = Not Detected (Below DLR). DLR = MDL X Dilution Factor NA = Not Analyzed Reviewed/Approved By:Date: Lee Ingvaia Department Supervisor The cover letter is an integral part of this analytical report. dvanced Technology Laboratories 1510 E. 33rd Street Signal Hilt, CA 90807 Tel: 562 989-4045 Fax: 562 989-4040 Method Title Last Update Response via Spike Recovery and RPD Summary Report - SOIL(ug/kg) : C:\HPCHEM\1\METHODS\PCBPEST1.M (Chemstation Integrator) : 8081 Pesticides Advanced Technology Laboratory Sun Aug 23 13:40:26 1998 Initial Calibration Non-Spiked Sample: GB0818A.D Spike Sample Spike Duplicate Sample File ID : GMS0821A.D Sample : Blank MS E:8/20/98 Acq Time: 21 Aug 1998 9:48 pm GMD0821A.D Blank MSD E:8/20/98 21 Aug 1998 10:17 pm Compound Sample Spike Spike Dup Spike Dup Cone Added Res Res %Rec %Rec RPD QC Limits RPD % Rec gamma -BHC Heptachlor Aldrin Dieldrin Endrin 4,4 ' -DDT 0.0 0.0 0.0 0.0 0.0 0.0 40 40 40 80 80 80 29 29 35 64 69 65 30 29 37 63 70 62 73 73 88 80 86 81 74 72 93 79 87 78 2 1 5 2 1 5 9 12 15 8 16 22 50-127 35-136 43-147 54-134 61-138 15-155 QC Batch #:G988080S282 Reviewed and Approved by:Date: Lee Ingvaldson Organics Supervisor 'vanced Technology Laboratories 1510 E. 33rd Street Signal Hill, CA 90807 Tel: 562 989-4045 Fax: 562 989-4040 Sent By: GEOCON ENV. CONSULTANTS, INC.; 619 558 6437; FAX \Date TO: Phone Fax Phone Lance ATL 562-939-404$ 562-9S9-4040 \CC: Aug-13-98 16:51; Phon Fax Phone For your reviewREMARKS: D Urgent Subject: Buerger Property Carlsbad, California Pursuant to our telephone conversation today, August 19,1998, this letter serve PRF1-3, PRF2-3, and PRF7-3 should be analyzed for 8080 organochl for PCBs. Your lab number is 28274. Please analyze these samples on a|48 hou understanding that we will receive the results before 5 PM on Friday An just 21 please call our office. Page 1/1 Augwit 19, 1998 | Numh rofpqg >s including cover sheet Kristen G. Geocon Environmental Consultants, Inc. 6970 Flanders Drive San DieK<> CA 92121 A ?pty AH 4P [3 Please Comment 629.5SS.S437 as statement that sample numbers ;ides. Do not analyze the samples turn-around-timc. It is my 1998, If you have any questions I I I I I I I i I I I I I I II II II I I I 1 I Iof Advanced Technology Laboratories 1510 E. 33rd Street Signal Hill, CA 90807 (562) 989-4045 • FAX (562) 989-4040 FOR LABORATORY USE ONLY: Batch #:. P.O.#: D.O. # Logged By:.Date:Time: Method of Transport Walk-in D Courier D UPS D FED. EXP. D ATL O Sample Condition Upon Receipt 1. CHILLED YD ND 4. SEALED YD NC 2.HEADSPACE(VOA) YD ND 5. * OF SPLS MATCH COG Y D N C 3. CONTAINER INTACT YD ND 6. PRESERVED Y D N C Attn- Address: State Project Name:Project #:Sampler: (printed Name>(Signature) Relinquished by: (Signature «nd>flnl«d Hunt)Date:Time:Received by:Date:Time: Relinquished by: (Signature and Printed Name)Date:Time:Received by: (si Date:Time: Relinquished by: (Signature and Pnnled Kanw)Date:Time:Received by:Date:Time: SHIP TO LAB: (SUB CONTRACT) TEST: ATL #: DATE: CLIENT 1.0 I hereby authorize ATL to perform the work indicated below: Project Mgr /Submitter: Date: / / Print Name Signature Send Report To: Attn: Co: Address City State.-Zip- Special Instructions/Comments: Unless otherwise requested, all samples will be disposed 45 days after receipt. Sample Archive/Disposal: G Laboratory Standard D Other D Return To: * $10.00 FEE PER HAZARDOUS SAMPLE DISPOSAL. LAB USE ONLY: _ Batch #:Sample Description Lab No.Sample I.D.Date Time CIRCLE APPROPRIATE MATRIX Type QA/QC RTNE Q RWQCB D WIP NAVY CT OTHER aDa REMARKS (XfL Vi/ , 'ON/ TAT starts 8 a.m. following day if samples received after 5 p.m. TAT: A=Overnight <24hr B=Emergency Next workday Critical 2 Workdays D=Urgent 3 Workdays E=Routine 7 Workdays Container Types; T=Tube V=VOA L=Liter P=Pint J=Jar B=Tedlaf G=Glass P^Plastic M=Metal Preservatives H=Hcl N= Z=Zn(AC); O^NaOH DISTRIBUTION: White with report, Yellow to folder, Pink to submitter.